TW200947051A - Manufacture method of image display devices - Google Patents

Manufacture method of image display devices Download PDF

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Publication number
TW200947051A
TW200947051A TW097147191A TW97147191A TW200947051A TW 200947051 A TW200947051 A TW 200947051A TW 097147191 A TW097147191 A TW 097147191A TW 97147191 A TW97147191 A TW 97147191A TW 200947051 A TW200947051 A TW 200947051A
Authority
TW
Taiwan
Prior art keywords
polarizing plate
film
display unit
release film
optical
Prior art date
Application number
TW097147191A
Other languages
Chinese (zh)
Other versions
TWI383216B (en
Inventor
Mitsuru Suzuki
Shouji Yamamoto
Kentarou Takeda
Original Assignee
Nitto Denko Corp
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Publication date
Application filed by Nitto Denko Corp filed Critical Nitto Denko Corp
Publication of TW200947051A publication Critical patent/TW200947051A/en
Application granted granted Critical
Publication of TWI383216B publication Critical patent/TWI383216B/en

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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3025Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G02B5/3033Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
    • G02B5/3041Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks
    • G02B5/305Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks including organic materials, e.g. polymeric layers
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133528Polarisers

Abstract

The present invention illustrates a manufacture method of image display devices, which laminate a polarized plate made of polyester membrane as polarizer to the optical display unit, such as LCD unit. The manufacture method of image display devices comprises the following steps in order: transporting the polarized plate, which temporarily attached to the tensile releasing membrane, to a position opposite to the optical display unit; a first attaching step, which is to detach one end of the polarized plate from the releasing membrane and to attach at least one detached portion to the surface of the optical display unit; and a second attaching step, which is to detach the remained portion of the polarized plate from the releasing membrane while attaching the rest of the polarized plate to the optical display unit.

Description

200947051 九、發明說明: 【發明所屬之技術領域】 本發明係關於一種於光學顯示單元之至少一主表面上貼 合有偏光板的圖像顯示裝置之製造方法。本發明尤其是關 於一種於液晶單元之至少單面上貼合有偏光板的液晶面板 之製造方法。 【先前技術】 通常,液晶顯示裝置係將作為光學顯示單元之液晶單 元、與背光單元等之光源裝置或驅動電路等加以組合而形 成,就其圖像形成方式而言,必不可少地須要於形成液晶 單元表面之玻璃基板上配置偏光板。作為此種液晶面板之 製造方法,先前廣泛採用使用黏著劑等將切斷成既定大小 之偏光板、與液晶單元貼合之方法β x,自提昇良率或降 低成本等之觀點考慮, 尺寸之偏光板移送至液 提出有使用吸附機構將切斷成既定 晶單元上,且使用輥將偏光板貼合 於液晶單元上之方法(例如專利文獻1}。 另一方面,作為液晶面板中所使用之偏光板,通常使用BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method of manufacturing an image display device in which a polarizing plate is bonded to at least one main surface of an optical display unit. More particularly, the present invention relates to a method of manufacturing a liquid crystal panel in which a polarizing plate is bonded to at least one surface of a liquid crystal cell. [Prior Art] In general, a liquid crystal display device is formed by combining a liquid crystal cell as an optical display unit, a light source device such as a backlight unit, or a driving circuit, etc., and an image forming method is indispensable for A polarizing plate is disposed on the glass substrate on which the surface of the liquid crystal cell is formed. As a method for producing such a liquid crystal panel, a method of cutting a polarizing plate of a predetermined size and bonding it to a liquid crystal cell using an adhesive or the like has been widely used, from the viewpoint of improving yield or reducing cost, etc. The transfer of the polarizing plate to the liquid is performed by a method in which the polarizing plate is bonded to the liquid crystal cell by using a suction mechanism, and the polarizing plate is bonded to the liquid crystal cell by using a roller. For example, Patent Document 1 is used. Polarizer, usually used

136641 .doc 200947051 護膜(例如,參照專利文獻2、3)。聚對苯二甲酸乙二酯膜 之價格低並且機械強度或耐濕性等特性優異。因此,藉由 使用5亥5^對本一甲酸乙二醋膜作為偏光元件保護膜,可低 成本地製作咼品質之偏光板,因此業界正在研究其於偏光 . 元件保護膜中之應用。 . 專利文獻1 :曰本專利特開2007-140046號公報 專利文獻2:曰本專利特開平8_271733號公報 專利文獻3:日本專利特開平8_271734號公報 ❹ 【發明内容】 發明所欲解決之問題 另一方面,使用聚對苯二甲酸乙二酯等聚酯膜作為偏光 兀件保護膜的偏光板存在容易產生彎曲(捲曲)之傾向。因 此,先前之圖像顯示裝置之製造方法中,存在難以將上述 偏光板精度良好地貼合於液晶單元等光學顯示單元上的傾 向。 φ 自上述觀點考慮,本發明之目的在於提供一種可將彎曲 之偏光板精度良好地貼合於液晶單元等光學顯示單元上的 圖像顯示裝置之製造方法。 解決問題之技術手段 上述課題可藉由如下方式解決:將偏光板於暫時貼附於 作為賦予有張力之搬送片材的脫模膜上之狀態下,朝與光 學顯示單元相對向之位置搬送,一面於經由該脫模膜而賦 予有張力之狀態下抑制變曲,一面將偏光板貼合於光學顯 示單元上。 136641.doc 200947051 即’本發明係關於一種圖像顯示裝置之製造方法,其係 將於偏光70件上積層有至少1片聚酯膜之偏光板經由黏著 劑層而貼合於光學顯示單元之表面。本發明之製造方法依 序包括.搬送步驟,其係將暫時貼附於賦予有張力之脫模 膜上之偏光板搬送至與光學顯示單元相對向之位置;第1 黏貼步驟,將偏光板之一方端部自脫模膜上剝離,並且將 偏光板之自脫模膜上剝離之部分的至少一部分貼合於光學 顯不單兀之表面;及第2黏貼步驟,一面自偏光板中於第工 黏貼步驟中仍暫時貼附於脫模膜上之剩餘部分將脫模膜剝 離,一面將該偏光板之剩餘部分貼合於該光學顯示單元 上。 根據本發明之一實施形態,上述脫模膜與上述偏光板係 經由黏著劑層而暫時貼Μ,並且可使用黏著劑層作為用以 將偏光板與光學顯示單元貼合之黏著劑層。 再者,根據本發明之其他實施形態,於上述搬送步驟之 則進一步包括切斷步驟,由暫時貼附有上述脫模膜與上述 偏光板之積層光學製品,保留脫模膜而將積層光學 其他構件切斷成特定尺寸。於切斷步驟之一形態中,可將 自暫日守貼附有脫模膜與偏光板之長條狀積層光學製品捲繞 而成的捲軸素材將該積層光學製品拉開者切斷成特定尺 寸。 於本發明之製造方法之—實施形態中,上述偏光板較好 的是於聚3旨膜之與偏光元件相對向之主表面上形成有易接 136641.doc 200947051 發明之效果 根據本發明之製造方法,將偏光板於暫時貼附於作為賦 予有張力之搬送片材之脫模膜上的狀態下,朝與光學顯示 單元相對向之位置搬送,因此可一面於對偏光板賦予張力 之狀態下抑制其彎曲’ 一面將偏光板貼合於光學顯示單元 上。因此,即便是如使用聚酯膜作為偏光元件保護膜之偏 光板般容易彎曲之偏光板,亦可精度良好地貼合於光學顯 示單元上。136641 .doc 200947051 Protective film (for example, refer to Patent Documents 2 and 3). The polyethylene terephthalate film is inexpensive and excellent in mechanical strength or moisture resistance. Therefore, the use of the bismuth ethane vinegar film as a polarizing element protective film can be used to produce a bismuth-quality polarizing plate at a low cost. Therefore, the industry is investigating its application in a polarizing element protective film. Patent Document 1: Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. On the other hand, a polarizing plate using a polyester film such as polyethylene terephthalate as a polarizing element protective film tends to be easily bent (curled). Therefore, in the method of manufacturing an image display device of the prior art, it is difficult to adhere the polarizing plate to the optical display unit such as a liquid crystal cell with high precision. φ From the above viewpoints, an object of the present invention is to provide a method of manufacturing an image display device which can accurately bond a curved polarizing plate to an optical display unit such as a liquid crystal cell. Means for Solving the Problem The above-described problem can be solved by temporarily attaching a polarizing plate to a position corresponding to an optical display unit while temporarily attaching it to a release film as a transport sheet to which tension is applied. The polarizing plate is bonded to the optical display unit while suppressing the deformation in a state where tension is applied through the release film. 136641.doc 200947051 That is, the invention relates to a method for manufacturing an image display device, which is characterized in that a polarizing plate having at least one polyester film laminated on 70 pieces of polarized light is attached to an optical display unit via an adhesive layer. surface. The manufacturing method of the present invention includes, in order, a transporting step of transporting a polarizing plate temporarily attached to a release film having tension to a position facing the optical display unit; and a first bonding step of the polarizing plate One end portion is peeled off from the release film, and at least a part of the portion of the polarizing plate peeled off from the release film is bonded to the surface of the optical display; and the second pasting step is performed on the polarizing plate. In the pasting step, the remaining portion temporarily attached to the release film peels off the release film, and the remaining portion of the polarizing plate is attached to the optical display unit. According to an embodiment of the present invention, the release film and the polarizing plate are temporarily attached via an adhesive layer, and an adhesive layer can be used as an adhesive layer for bonding the polarizing plate to the optical display unit. According to still another embodiment of the present invention, in the transferring step, the cutting step further includes a cutting step of temporarily attaching the laminated optical product of the release film and the polarizing plate, and retaining the release film to deposit the optical layer. The member is cut to a specific size. In one aspect of the cutting step, the reel material obtained by winding the long laminated optical product with the release film and the polarizing plate attached to the temporary sealing film can cut the laminated optical product into a specific one. size. In the embodiment of the manufacturing method of the present invention, the polarizing plate is preferably formed on the main surface of the film which is opposite to the polarizing element and has an easy connection. 136641.doc 200947051 Effect of the Invention According to the invention In the state in which the polarizing plate is temporarily attached to the release film as the transport sheet to which the tension is applied, the polarizing plate is transported toward the position facing the optical display unit, so that the tension can be applied to the polarizing plate. The polarizing plate is attached to the optical display unit while suppressing its bending. Therefore, even if the polarizing plate is easily bent like a polarizing plate using a polyester film as a polarizing element protective film, it can be attached to the optical display unit with high precision.

又,藉由於搬送步驟之前,由暫時貼附有上述脫模膜與 上述偏光板之積層光學製品保留該脫模膜而將該積層光學 製品之其他構件切斷成特定尺寸,可以一系列之步驟來實 施自偏光板之切割至對光學顯示單元之貼合,因此可削減 步驟數’並且亦可期待提昇良率。 【實施方式】 本發明係關於一種圖像顯示裝置之製造方法,尤其是一 種光學顯示單元與偏光板之貼合方法。首先,就本發明之 製造方法中所使用之偏光板以及光學顯示單元的較佳形態 加以說明。 <偏光板> 本發明之製造方法中所使用之偏光板之積層形態的—例 示於叫⑷中。該偏光板中積層有至少以聚總與 偏光元件p。 [聚酯膜] 對形成聚酯膜之材 聚酯膜E係用作偏光元件保護膜者。 136641.doc 200947051 料並無特別限定,你丨 例如可列舉:將對苯二甲酸、間苯二尹 酸、鄰苯二F酸、 ’-萘二 f 酸、2,6-萘二 f 酸、ι,4-萘二 曱酸、1,5-萘二甲酸、— —本基甲酸、二苯氧基乙烷二f 酸、二苯基硬甲酸、苜_ , , _ m —甲酸、13-環戊烷二甲酸、1,3- 私·己撰1 甲酸、I 4 - r» V·»· 卜 ,衣已烧二甲酸、六氳對苯二f酸、六 氫間苯二甲酸、丙二酴 __田蚊工 _ k、一甲基丙二酸、丁二酸、3,3_二 乙基丁二酸、戊二酸、- 2,2-—甲基戊二酸、己二酸、2-甲 基己二酸、=审其;3 _ —土己一酸、庚二酸、壬二酸、二聚酸、癸 一酉夂辛一酸、十二烷二甲酸等二羧酸,以及乙二醇、丙 醇己一醇新戊二醇、1,2-環己烧二甲醇、i,4-環己 烷二甲醇、癸二醇、u_丙二醇、…丁二醇、以-戊二 醇1,6_己一醇、2,2-雙(4-羥基苯基)丙烷、雙(4_羥基苯 基)砜等二醇中的各1種進行聚縮合而得之均聚物,或將1 種以上之二甲酸與2種以上之二醇進行聚縮合而得之共聚 物,或者將2種以上之二甲酸與丨種以上之二醇進行聚縮合 而得之共聚物’以及將2種以上的該等之均聚物或共聚物 摻合而得之掺合樹脂中的任—種聚s旨樹脂。其中,較好的 是使用聚對苯二甲酸乙二酯樹脂。 聚酯膜例如可藉由將上述聚酯樹脂熔融擠出成膜狀,並 使用洗鑄滾筒進行冷卻固化而形成膜之方法等而獲得。作 為聚酯膜E’可使用未延伸膜、延伸膜中之任一種膜。例 如,於要求雙折射較小者之情形時,可適宜使用未延伸 膜。又,於將雙折射用於液晶顯示裝置之光學補償之情形 等時,可適宜使用延伸膜。又,延伸膜、尤其是雙轴延伸 136641.doc • 10- 200947051 膜自強度方面來考慮亦可適宜使用。 於聚醋膜E為延㈣之情科,對其延伸方法並益特別 限定,可採用縱向單轴延伸法、橫向單轴延伸法、縱橫逐 次雙軸延伸法、縱橫同時雙轴延伸法等。作為延伸機構, •彳使用㈣㈣、拉幅延伸機、縮放儀式或線性馬達式之 • 雙軸延伸機等任意合適之延伸機。 上述聚醋膜E之厚度較好的是5〜5〇〇μιη,更好的是5〜· ㈣’進而更好的是10〜150 _。若厚度小於上述範圍,則 罾#在膜變得容易斷裂、應用於偏光板時強度產生問題、或 者水分阻隔性變得不充分而導致偏光元件之耐久性較差的 情形。若厚度大於上述範圍,則存在膜缺乏可撓性而使得 才呆作性下降、或者聚酯膜本身變得難以製造之情形。 [易接著層] 就提高與偏光元件Ρ之接著性之觀點而言,上述聚酯膜Ε 較好的是在與偏光元件Ρ貼合之側之面上,形成有易接著 ❷層Η者。作為該易接著層Η,可列舉由以下化合物形成 者.親水性纖維素衍生物、聚乙烯醇系化合物、親水性聚 S曰系化合物、聚乙烯系化合物、(曱基)丙烯酸化合物、環 氧秘脂、聚胺基曱酸酯化合物、天然高分子化合物等。 作為親水性纖維素衍生物,可列舉曱基纖維素、羧曱基 纖維素、羥基纖維素等。 作為聚乙烯醇系化合物,可列舉:聚乙烯醇、乙酸乙烯 醋-乙烯醇共聚物、聚乙酸乙烯酯、聚乙烯縮醛、聚乙烯 甲經、聚乙烯亞苄基等。尤其是就與聚酯膜之接著性之觀 136641.doc -11 - 200947051 點而言’較好的是調配父聯劑。較好的交聯劑將於後文中 說明。 作為親水性聚酯系化合物’可列舉磺化聚對苯二甲酸乙 二S旨等。 作為聚乙烯系化合物’可列舉:聚-N_乙烯吡咯烧酮、 聚丙烯醯胺、聚乙烯咪唑、聚乙烯吡唑等。 作為(甲基)丙烯酸系化合物,可列舉:丙烯酸、丙烯酸 缓基烧基酯、丙烯酸烷基酯、丙烯酸羥基烷基酯、丙烯酸 羥基烷基酯、甲基丙烯酸、甲基丙烯酸羧基烷基酯、曱基 丙烯酸烷基酯、甲基丙烯酸羥基烷基酯、甲基丙烯酸羥基 烧基酯等。 作為環氧樹脂,可列舉:雙酚型環氧樹脂、酚醛清漆型 環氧樹脂、環氧化聚乙烯苯料之芳香族環氧樹脂類,芳 香:環氧樹脂之氳化物’環己烷系環氧樹脂、環己基甲醚 系衣氧树〜等之脂環式環氧樹脂類’聚環氧烧縮水甘油 鍵聚醚多7L醇縮水甘油峻、聚醚多元醇縮水甘油謎等之 脂肪族環氧樹脂類。 為聚胺基曱酸酯化合物,可列舉:丙烯酸多元醇、聚 =夕醇、聚_多元醇等多元醇類與四亞甲基二異氛酸 西曰異佛爾酮二異氰酸龜等聚異氰酸醋類的反應物等。其 中就與聚騎模之接著性之觀點而言,適宜使用聚醋系之 聚胺基曱酸酯。 為天然N分子化合物,可列舉明膠、酪蛋白、 膠等。 136641.doc 200947051 上述中,就接著性之觀點而言,可適宜使用聚乙稀醇系 衍生物或者聚胺基曱酸酯化合物。Further, before the transfer step, the release film is temporarily held by the laminated optical product to which the release film and the polarizing plate are temporarily attached, and the other member of the laminated optical product is cut into a specific size, and a series of steps can be performed. Since the cutting from the polarizing plate is performed to the bonding to the optical display unit, the number of steps can be reduced and the yield can be expected to be improved. [Embodiment] The present invention relates to a method of manufacturing an image display device, and more particularly to a method of bonding an optical display unit to a polarizing plate. First, a preferred embodiment of the polarizing plate and the optical display unit used in the manufacturing method of the present invention will be described. <Polarizing Plate> The laminated form of the polarizing plate used in the production method of the present invention is exemplified in (4). The polarizing plate is laminated with at least a total of the polarizing element p. [Polyester film] The material for forming a polyester film The polyester film E is used as a protective film for a polarizing element. 136641.doc 200947051 is not particularly limited, and for example, terephthalic acid, metaphthalic acid, phthalic acid, '-naphthalene di-acid, 2,6-naphthalene di-f-acid, I,4-naphthalene dicarboxylic acid, 1,5-naphthalene dicarboxylic acid, —benzoic acid, diphenoxyethane di-f acid, diphenyl hard acid, 苜_ , , _ m —carboxylic acid, 13- Cyclopentane dicarboxylic acid, 1,3- private hexyl 1 formic acid, I 4 - r» V·»· Bu, succinated dicarboxylic acid, hexamethylene terephthalic acid, hexahydroisophthalic acid, C二酴__田蚊工_ k, monomethylmalonic acid, succinic acid, 3,3_diethyl succinic acid, glutaric acid, - 2,2-methylglutaric acid, hexane Acid, 2-methyladipate, = trial; 3 _ - hexamethylene monophosphate, pimelic acid, sebacic acid, dimer acid, bismuth octanoic acid, dodecane dicarboxylic acid, etc. Acid, and ethylene glycol, propanol, neopentyl glycol, 1,2-cyclohexane dimethanol, i,4-cyclohexanedimethanol, decanediol, u-propylene glycol, ... butanediol, One of each of the diols such as pentanediol 1,6-hexanol, 2,2-bis(4-hydroxyphenyl)propane, and bis(4-hydroxyphenyl)sulfone a homopolymer obtained by polycondensation, or a copolymer obtained by polycondensing one or more kinds of dicarboxylic acid with two or more kinds of diols, or a mixture of two or more kinds of dicarboxylic acids and diols of more than one kind The copolymer obtained by condensation and the resin of any one of the blended resins obtained by blending two or more of these homopolymers or copolymers. Among them, it is preferred to use a polyethylene terephthalate resin. The polyester film can be obtained, for example, by melt-extruding the above-mentioned polyester resin into a film form, and forming a film by cooling and solidifying using a washing drum. As the polyester film E', any of an unstretched film and a stretched film can be used. For example, in the case where the birefringence is required to be small, an unstretched film can be suitably used. Further, when birefringence is used for the optical compensation of a liquid crystal display device or the like, a stretched film can be suitably used. Further, the stretch film, especially the biaxial stretching 136641.doc • 10-200947051 The film may be suitably used in terms of strength. The polyacetate film E is a genus of Yan (4), and its extension method is particularly limited, and a longitudinal uniaxial stretching method, a transverse uniaxial stretching method, a vertical and horizontal sequential biaxial stretching method, a vertical and horizontal simultaneous biaxial stretching method, and the like can be employed. As an extension mechanism, • use any suitable extension machine such as (4) (4), tenter extension machine, zooming ceremony or linear motor type • biaxial extension machine. The thickness of the above-mentioned polyester film E is preferably 5 to 5 Å μm, more preferably 5 to (4)' and further preferably 10 to 150 Å. When the thickness is less than the above range, 罾# is likely to be broken when the film is easily broken, a problem occurs in strength when applied to a polarizing plate, or moisture barrier properties are insufficient, resulting in poor durability of the polarizing element. If the thickness is larger than the above range, there is a case where the film lacks flexibility to cause a decrease in the workability, or the polyester film itself becomes difficult to manufacture. [Easy adhesive layer] From the viewpoint of improving the adhesion to the polarizing element, the polyester film 较好 is preferably formed on the side of the side opposite to the polarizing element ,. Examples of the easily-adhesive layer include a hydrophilic cellulose derivative, a polyvinyl alcohol-based compound, a hydrophilic poly-S-based compound, a polyethylene-based compound, a (fluorenyl)acrylic compound, and an epoxy resin. A secret lipid, a polyamino phthalate compound, a natural polymer compound, and the like. Examples of the hydrophilic cellulose derivative include mercaptocellulose, carboxymethylcellulose, and hydroxycellulose. Examples of the polyvinyl alcohol-based compound include polyvinyl alcohol, vinyl acetate-vinyl alcohol copolymer, polyvinyl acetate, polyvinyl acetal, polyethylene methyl phthalate, and polyethylene benzylidene. In particular, in view of the adhesion to the polyester film 136641.doc -11 - 200947051, it is preferable to formulate a parent-linking agent. A preferred crosslinking agent will be described later. The hydrophilic polyester compound 'is sulfonated polyethylene terephthalate S or the like. Examples of the polyethylene-based compound include poly-N-vinylpyrrolidone, polypropylene decylamine, polyvinylimidazole, and polyvinylpyrazole. Examples of the (meth)acrylic compound include acrylic acid, acrylic acid slow-base alkyl ester, alkyl acrylate, hydroxyalkyl acrylate, hydroxyalkyl acrylate, methacrylic acid, carboxyalkyl methacrylate, and the like. Alkyl methacrylate, hydroxyalkyl methacrylate, hydroxyalkyl methacrylate, and the like. Examples of the epoxy resin include a bisphenol epoxy resin, a novolac epoxy resin, and an aromatic epoxy resin of an epoxidized polyethylene benzene material, and an aromatic: epoxy resin halide "cyclohexane ring" Oxygen resin, cyclohexyl methyl ether, epoxide resin, etc. alicyclic epoxy resin type polyepoxy condensed glycerin bond polyether 7L alcohol glycidol, polyether polyol glycidol mystery, etc. Oxygen resin. Examples of the polyamino phthalate compound include polyhydric alcohols such as acrylic polyols, poly-l-alcohols, and poly-polyols, and tetramethylene diiso-succinic acid, oxime isophorone diisocyanate, and the like. A reaction product of polyisocyanuric acid or the like. Among them, from the viewpoint of adhesion to a polyhedral mold, a polyacetic acid polyamic acid phthalate is suitably used. Examples of the natural N molecule compound include gelatin, casein, gum, and the like. 136641.doc 200947051 In the above, from the viewpoint of adhesion, a polyethylene glycol derivative or a polyaminophthalate compound can be suitably used.

進而’上述易接著層时、可含有交聯劑。尤其是當易接 著層主要為如聚乙烯醇系化合物或聚乙烯系化合物等般與 聚醋膜之接著性(密著性)通常較低者之情形時,易接著層 H較好的是含有交聯劑。作為該交聯劑,例如可列舉:丙 料系:苯乙烯系、環氧系、紛系、苯氧基㈣、苯氧基 酯系、三聚氰胺系、胺基甲酸酯系等之交聯劑。其中,就 提昇聚醋與易接著層之密著性之觀點而言,可適宜使用具 有仿唑啉基、二醯亞胺基、肼基、環氧基之交聯劑。 易著層Η較好的疋藉由將上述化合物製成溶液、分散 5者乳化液並塗佈於㈣膜上而形成。塗料,就防止 環境污染、獲得防爆性之觀點而言,較好的是製成水性塗 =使用°又’自促進水性塗佈液潤濕聚S旨膜之觀點或者 提昇;k佈液之穩定性之觀點來考慮,亦可調配界面活性 片!對塗佈液調配的界面活性劑適當調配量根據界面活性 劑之種類而有所不同,可適當地調整該調配量,以使易接 著層Η與偏光元件具有充分之接著性。例如,相對於水性 塗佈液之固形分】ηΛ壬θ ,、 刀1〇〇重1份’可含有1〜10份左右之界面活 性劑。 界面活性劑可使用陰離子型、陽離子型、非離子型令之 任一種,例如聚氧乙稀-脂肪酸醋、山梨糖醇酐脂肪酸 酯、脂肪酸甘油酯、脂肪酸金屬纟、烷基硫酸鹽、烷基磺 酸鹽、烧基確甚丁 _似 J — S文鹽、氯化四級銨鹽、烷基胺鹽酸、 136641.doc -13- 200947051 甜菜驗型界面活性劑等。 塗佈液中亦可進一步添加抗靜電劑、著色劑、紫外線吸 收劑、交聯劑、顏料、有機填料、無機填料。 塗佈液之固形分濃度通常為20重量%以下,較好的是 1〜10重量%。若固形分濃度過小,則有時對聚酯膜之塗佈 性會變得不充分,若固形分濃度過大,則有時塗佈液之穩 定性、塗佈層之均一性以及外觀會惡化。 水性塗佈液對聚酯膜之塗佈可於任意階段實施。於聚酯 膜為未延伸膜之情形時,可於形成膜後之任意階段進行塗 佈。又,於聚酯膜為延伸膜之情形時,於形成膜後的延伸 之前、延伸之後或者延伸期間中之任一階段進行塗佈均 可。所謂於延伸期間進行塗佈,係指例如於採用縱橫逐次 雙軸延伸時,在將膜縱向延伸之後' 橫向延伸之前進行塗 佈之情形。尤其是’在使用拉幅延伸機、縮放儀式或線性 馬達式之雙軸延伸機等進行延伸時,於延伸步驟中無須使 膜與輥相接觸’因此藉由在即將延伸之前塗佈塗佈液,、可 幻個步驟來實施延伸及塗佈液之乾燥,故為較好的構 成。 將塗佈液塗佈於聚醋膜上時,自提昇塗佈性之觀點來考 慮’亦可預先對膜表面實施電暈處理、電漿處理等。 塗佈液之塗佈量較好的是調整成使易接著層之厚声為 〇·〇〇Η〇μιη左右,更好的是0 001〜5μιη左右,特別ς的 是cum〜i叫左右。若塗佈層之厚度過小,則存在與偏光 元件之接著力不足之情形,若厚度過大,則存在產生站 136641.doc 200947051 塊、或者霧度上升之情形。 作為塗佈方法,可摩用八土 J應用&知之任意塗佈法。例如可提 供:輥塗法、凹版印刷式法、 孝昆式刷塗法、喷塗法、氣刀 塗佈法、含浸法、簾塗法。該 寻了早獨使用’亦可組合使 用。塗佈於聚酯膜上之塗佈 怖履错由加熱等而乾燥,藉此作 為易接著層而形成於膜上。 [偏光元件]Further, when the above-mentioned easy-adhesion layer is used, a crosslinking agent may be contained. In particular, when the adhesion layer is mainly such that a polyethylene (polyvinyl alcohol-based compound) or a polyethylene-based compound is usually lower in adhesion (adhesion) to the polyester film, the easy-to-attach layer H preferably contains Crosslinker. Examples of the crosslinking agent include a crosslinking agent such as a styrene-based system, a styrene-based compound, an epoxy-based compound, a phenoxy group, a phenoxy ester-based compound, a melamine-based compound, and a urethane-based compound. . Among them, a crosslinking agent having a oxazoline group, a diimine group, a fluorenyl group or an epoxy group can be suitably used from the viewpoint of enhancing the adhesion between the vinegar and the easy-adhesion layer. The ruthenium layer is preferably formed by dissolving the above compound into a solution, dispersing the emulsion, and applying it to the film. Coatings, in terms of preventing environmental pollution and obtaining explosion-proof properties, it is better to make water-based coatings = use ° and 'self-promoting aqueous coating liquids to wet the poly-S film. From the perspective of sex, you can also deploy interface active tablets! The appropriate amount of the surfactant to be added to the coating liquid varies depending on the kind of the surfactant, and the amount can be appropriately adjusted so that the layer and the polarizing element have sufficient adhesion. For example, the solid content of the aqueous coating liquid η Λ壬 θ , and the weight of the knife 1 ’ 1 may contain about 1 to 10 parts of the interface active agent. The surfactant may be any of anionic, cationic or nonionic, such as polyoxyethylene-fatty acid vinegar, sorbitan fatty acid ester, fatty acid glyceride, fatty acid metal hydrazine, alkyl sulfate, alkane. The base sulfonate and the alkyl group are succinct-like, such as J-S salt, quaternary ammonium chloride, alkylamine hydrochloric acid, 136641.doc -13-200947051 beet test surfactant. Further, an antistatic agent, a colorant, an ultraviolet absorber, a crosslinking agent, a pigment, an organic filler, or an inorganic filler may be further added to the coating liquid. The solid content concentration of the coating liquid is usually 20% by weight or less, preferably 1 to 10% by weight. When the solid content concentration is too small, the coating property to the polyester film may be insufficient. When the solid content concentration is too large, the stability of the coating liquid, the uniformity of the coating layer, and the appearance may be deteriorated. The application of the aqueous coating liquid to the polyester film can be carried out at any stage. In the case where the polyester film is an unstretched film, it may be applied at any stage after the film formation. Further, in the case where the polyester film is a stretched film, it may be applied at any stage before, after, or during the stretching after the film formation. The application of the coating during the stretching means, for example, the case where the coating is carried out before the lateral stretching after the film is longitudinally stretched by the longitudinal and transverse directions. In particular, 'when extending with a tenter stretching machine, a zooming ceremony or a linear motor type biaxial stretching machine, it is not necessary to bring the film into contact with the roll during the stretching step', so by applying the coating liquid just before the extension , a step can be performed to carry out the stretching and drying of the coating liquid, so that it is a preferable composition. When the coating liquid is applied onto the polyester film, it is considered from the viewpoint of improving the coating property. The surface of the film may be subjected to corona treatment, plasma treatment, or the like in advance. The coating amount of the coating liquid is preferably adjusted so that the thick sound of the easy-adhesive layer is about 〇·〇〇Η〇μιη, more preferably about 0 001 to 5 μιη, and particularly cum~i is called left and right. If the thickness of the coating layer is too small, the adhesion to the polarizing element may be insufficient. If the thickness is too large, there may be a case where the station 136641.doc 200947051 is generated or the haze is increased. As a coating method, it is possible to use any of the eight soil J applications & For example, a roll coating method, a gravure printing method, a filial brushing method, a spray coating method, an air knife coating method, an impregnation method, and a curtain coating method can be provided. It can be used in combination as early as possible. The coating applied to the polyester film is dried by heating or the like, and is formed on the film as an easy-adhesion layer. [Polarizing element]

所謂偏光元件,係指可將自然光或偏光轉換成任意偏光 之膜。作為用於本發財m件,可採用任意合適之 偏光元件’較好的是使用將自’然光或偏光轉換成直線偏光 者。 本發明中所使用之偏光板中,作為偏光元件p,可根據 目的而採用任意合適者。例如可列舉:使聚乙稀醇系棋、 部分縮甲醛化聚乙烯醇系膜、乙烯_乙酸乙烯酯共聚物系 ^为皂化膜等之親水性高分子膜上吸附碘或二色性染料等 一色性物質,並加以單軸延伸所得者;以及聚乙烯醇之脫 水處理物或聚氯乙烯之脫鹽酸處理物等之多烯系配向膜 等。又,亦可使用:美國專利5,523,863號等中所揭示的使 包含二色性物質及液晶性化合物之液晶性組合物朝固定方 向配向所得的賓主型之〇型偏光元件,以及美國專利 6,049,428號等中所揭示之使溶致型液晶朝固定方向配向所 得的E型偏光元件等。 上述偏光元件中,就具有高偏光度之觀點、以及與聚酷 膜之接著性之觀點而言,適宜使用由含有碘之聚乙稀醇系 136641.doc -15- 200947051 膜所形成之偏光元件。作為應用於偏光元件的聚乙烯醇系 膜之材料,係使用聚乙烯醇或其衍生物。作為聚乙烯醇之 衍生物,可列舉聚乙烯曱醛、聚乙烯縮醛等,除此以外可 列舉··乙烯、丙烯等之烯烴,丙烯酸、甲基丙烯酸、丁烯 酸等之不飽和羧酸或其烷基酯、以及以丙烯醯胺等加以改 性所得者。通常使用聚乙烯醇之聚合度為1000〜10000左 右、皂化度為80〜1〇〇莫耳%左右者。 [接著劑層] 上述聚酯膜E與偏光元件P較好的是經由接著劑層〇而積 層。此時理想的是,利用接著劑層無空氣隙地將兩者積 層。又’當聚酯膜E於一主表面上具有易接著層時,較好 的是如圖1(a)〜(c)所示,以使該易接著層Η形成面與偏光元 件Ρ相對向之方式經由接著劑層G而積層。接著劑層g係由 接著劑所形成。對接著劑之種類並無特別限制,可使用各 種接著劑。 [偏光板之積層形態] 上述偏光板中,聚酯膜Ε係積層於偏光元件Ρ之至少一主 表面上。作為此種實施形態,例如可列舉如圖丨〜(幻之 形態。以下,依序對該等之構成加以詳細說明。 [積層形態a] 圖1(a)為於偏光元件ρ之兩主表面上積層有聚酯膜ε之形 態。於該形態中,較好的是如圖l(a)所示,於兩聚酯膜E 上均形成有易接著層H。又,積層於偏光元件P之一主表面 上之聚酯膜E、與積層於另一主表面上聚酯膜E可為相同 136641.doc -16- 200947051 者,亦可為不同者。 (偏光元件與聚酯膜之積層) " 利用效率之觀點而言,偏光元件P與聚酯膜E之積 層車,子的疋如圖l(a)所*,兩聚醋膜E經由接著劑層G而與 偏光元件P積層。 ' [積層形態b] 圖(b)為於偏光元件p之一主表面上積層有聚醋膜e,且The term "polarizing element" means a film that converts natural light or polarized light into any polarized light. As the present invention, any suitable polarizing element can be employed. It is preferable to use a person who converts the light or the polarized light into a linear polarized light. In the polarizing plate used in the present invention, as the polarizing element p, any suitable one may be employed depending on the purpose. For example, iodine or a dichroic dye is adsorbed on a hydrophilic polymer film such as a polyvinyl alcohol-based chess, a partially formalized polyvinyl alcohol-based film, or an ethylene-vinyl acetate copolymer-based saponified film. A monochromatic substance obtained by uniaxial stretching; and a polyene-based alignment film such as a dehydrated material of polyvinyl alcohol or a dehydrochlorinated product of polyvinyl chloride. Further, a bismuth-type polarizing element of a guest-host type obtained by aligning a liquid crystal composition containing a dichroic substance and a liquid crystal compound in a fixed direction, as disclosed in U.S. Patent No. 5,523,863, and the like, and U.S. Patent No. 6,049,428, etc. The E-type polarizing element or the like obtained by aligning the lyotropic liquid crystal in a fixed direction as disclosed therein. In the above polarizing element, from the viewpoint of having a high degree of polarization and the adhesion to the film, it is preferable to use a polarizing element formed of a film of iodine-containing polyethylene 136641.doc -15-200947051. . As a material of the polyvinyl alcohol film applied to the polarizing element, polyvinyl alcohol or a derivative thereof is used. Examples of the polyvinyl alcohol derivative include polyethylene furfural and polyvinyl acetal, and examples thereof include an olefin such as ethylene or propylene, and an unsaturated carboxylic acid such as acrylic acid, methacrylic acid or crotonic acid. Or an alkyl ester thereof, and a modification obtained by acrylamide or the like. Usually, the polymerization degree of polyvinyl alcohol is about 1000 to 10,000, and the degree of saponification is about 80 to 1 〇〇 mol%. [Adhesive Layer] The polyester film E and the polarizing element P are preferably laminated via an adhesive layer. At this time, it is desirable to laminate the two layers with an air gap without an air gap. Further, when the polyester film E has an easy-adhesion layer on a main surface, it is preferably as shown in Figs. 1(a) to (c) such that the easy-adhesion layer forming surface faces the polarizing element Ρ The method is laminated via the adhesive layer G. The subsequent agent layer g is formed of a subsequent agent. The kind of the adhesive is not particularly limited, and various adhesives can be used. [Laminate Form of Polarizing Plate] In the above polarizing plate, the polyester film is laminated on at least one main surface of the polarizing element. As such an embodiment, for example, the shape of the phantom is shown in the following. The configuration of the phantom is described in detail below. [Layered form a] FIG. 1(a) shows the two main surfaces of the polarizing element ρ. The upper laminate has a form of a polyester film ε. In this embodiment, as shown in Fig. 1(a), an easy adhesion layer H is formed on both polyester films E. Further, a layer is laminated on the polarizing element P. The polyester film E on one of the main surfaces may be the same as the polyester film E laminated on the other main surface. 136641.doc -16- 200947051, or different. (Lamination of polarizing element and polyester film) " From the viewpoint of efficiency, the laminated vehicle of the polarizing element P and the polyester film E, as shown in Fig. 1(a), the two polyester films E are laminated with the polarizing element P via the adhesive layer G '[Layered form b] Figure (b) shows a layer of polyester film e deposited on one of the major surfaces of the polarizing element p, and

於偏光元件卩之另—士主TThe other part of the polarizing element

表面上積層有除聚醋以外之透明膜T 來作為保護膜的形態。 (透明膜) 對除聚醋以外之透明膜τ並無特別限定,可使用任意 者作為此種透明膜之材料,例如可使用透明性、機械強 度熱穩疋性、水分阻隔性、等向性等優異之熱塑性樹 月曰作為此種熱塑性樹脂之具體例,可列舉:三乙_維 素等之纖維素系樹脂、聚醋系樹脂、㈣㈣樹脂、聚硬 系樹脂、聚碳酸酯系樹脂'聚醯胺系樹脂、聚醯亞胺系樹 月曰聚稀烴系樹脂、(甲基)丙婦酸系樹脂、環狀稀煙系樹 脂(降冰片烯系樹脂)、聚芳酯系樹脂、聚苯乙稀㈣脂、 聚乙烯醇系樹脂以及該等之混合物。再者,作為透明膜 T,亦可使用(甲基)丙烯酸系、胺基甲酸醋系、丙稀酸胺 基f fed系、%氧系、矽氧系等之熱硬化性樹脂或紫外線 硬化型樹脂。 又,作為透明臈T,可列舉日本專利特開2〇〇1_343529號 公報(wool/37007)中戶斤記載之聚合物膜,例如含有⑴側鏈 136641.doc 17 200947051 上具有經取代及/或未經取代之醯亞胺基之熱塑性樹脂、 以及(II)側鏈上具有經取代及/或未經取代之苯基及腈基之 熱塑性樹脂的樹脂組合物。作為具體例,可列舉含有包含 異丁烯與N-曱基順丁烯二醯亞胺之交替共聚物、以及丙烯 腈-苯乙烯共聚物之樹脂組合物的膜。膜可使用由樹脂組 合物之混合擠出品等所形成之膜。該等膜之相位差小,且 光彈性係數小,因此可消除由偏光板之應變所引起之不均 等不良狀況’而且,由於該等膜之透濕度小,故而加濕耐 久性優異。A transparent film T other than polyacetal is laminated on the surface as a protective film. (Transparent film) The transparent film τ other than the vinegar is not particularly limited, and any material can be used as the material of the transparent film. For example, transparency, mechanical strength, thermal stability, moisture barrier property, and isotropic property can be used. As a specific example of such a thermoplastic resin, a thermoplastic resin such as triacetin, a polyester resin, a (four) (four) resin, a polyhard resin, or a polycarbonate resin may be mentioned. Polyammonium resin, polyamidene tree sulphate polysaturated resin, (meth) propylene glycol resin, cyclic smoky resin (norbornene resin), polyarylate resin, Polystyrene (tetra) resin, polyvinyl alcohol resin, and mixtures thereof. Further, as the transparent film T, a thermosetting resin such as a (meth)acrylic acid, an amino carboxylic acid vinegar, an acrylamide-based f fed system, a % oxygen system or a ruthenium oxide type, or an ultraviolet curing type may be used. Resin. Further, as the transparent crucible T, a polymer film described in Japanese Patent Publication No. 2-343529 (wool/37007), for example, contains (1) a side chain 136641.doc 17 200947051 having a substitution and/or An unsubstituted quinone imine-based thermoplastic resin, and (II) a resin composition having a substituted and/or unsubstituted phenyl and nitrile-based thermoplastic resin in a side chain. Specific examples thereof include a film containing a resin composition comprising an alternating copolymer of isobutylene and N-fluorenylmethyleneimine and an acrylonitrile-styrene copolymer. As the film, a film formed of a mixed extrusion of a resin composition or the like can be used. Since the film has a small phase difference and a small photoelastic coefficient, it is possible to eliminate the unevenness caused by the strain of the polarizing plate. Further, since the film has a small moisture permeability, it is excellent in humidifying durability.

透明膜T之厚度可適當地確定,與上述聚酯膜之情形同 樣,較好的是5〜500 μϊη,更好的是5〜2〇〇 μηι,進而更好的 是 10〜15 0 μηι 〇 作為透明膜Τ,亦可使用雙折射小且不會轉換偏光狀 者可發揮相位差板之作用者中之任一種。 於使用可發揮相位差板之作用者作為透明膜了之情 時作為其南分子素材,例如可列舉:#乙稀醇、聚乙 ❹ 丁醛、聚甲基乙烯醚、聚丙烯酸羥基乙醋、羥基乙基纖: 素、羥基丙基纖維素、甲基纖維素、聚碳酸醋、聚芳醋 聚礪、聚對苯二甲酸乙二醋、聚萘二甲酸乙二酿、以 砜、聚苯硫醚、聚苯醚、聚烯丙基礪、聚醯胺、聚醯3 ,、聚稀烴、聚氯乙烤、纖維素樹脂、環狀稀煙樹叩 ,片烯系樹脂)或該等之二元系、三元系之各種共聚物、 接枝共聚物、摻合物等。該等高分子素材_由延伸等而 形成配向物(延伸膜)。 13664J.doc -38- 200947051 光元件P與t g旨膜E之積層較好的是如上所述,經由接 著劑層G而進行。又’偏光元件p與透明膜τ之積層亦同 樣,較好的是經由接著劑層G而進行。 [積層形態c] 圖Uc)為於偏光元件p之一主表面上積層有聚酯膜e,且 於另一主表面上未積層膜之形態。於此種形態中,偏光元 件P〃、tS曰膜E之積層較好的是如上所述,經由接著劑層〇 而進行。 [其他光學層] (表面處理層之形成) 若本發明之製造方法中所使用之偏光板中積層有至少i 片聚醋膜E以及偏光元件p,則其形態並不限定於上述積層 形態⑷〜⑷所列舉者,可追加任意之光學層。作為此種光 學層,例如可於上述聚酯膜E&/或透明膜丁的未積層偏光 元件P之主表面上,使用硬塗層或經實施抗反射處理及以 防黏、擴散或防眩為目的之處理者。除此以外,作為可應 用於偏光板之光學層之例,可列舉增亮模、反射層相位 差板等。 [光學層之積層] 增亮膜、反射層、相位差板等之料層,可於製造圖像 顯示裝置之過程中以依序分別積層之方式而形成,預先積 層者有品質穩定性或組裝作業性等優異、可改善製造步驟 之優點。積層時可使用黏著劑層等適當之接著機構。於該 等積層中’各光學層之光學軸(相位差膜之慢轴、或偏光 136641.doc •19- 200947051 位差特性等而形成適 元件之吸收軸等)可根據目標之相 之配置角度。 (黏著劑層) 另外’較好的是於上述偏光板之—主表面上,預先設置 黏著劑層以貼合光學顯示單元。對形成黏著劑層之黏著劑 並無特別限制,例如可適當地選擇使用以丙晞酸系聚合 物、矽氧系聚合物、聚醋、聚胺基曱酸酯、聚醯胺、: 醚、氟系或橡膠系等之聚合物作為基礎聚合物I。可特別 好地使用如丙烯酸系黏著劑般光學透明性優異,表現出適 度之潤濕性、凝集性及接著性之黏著特性,且耐候性及耐 熱性等優異者。 (脫模膜) 對於黏著劑層之露出s,至提供給實際應用為止之期 間,係暫時貼附脫模膜(間隔片)而將其覆蓋以防止受到污 染等。藉此,可防止於通常之操作狀態下接觸黏著劑層。 作為脫模膜,例如可使用:塑膠膜,橡膠片材,紙,布, 不織布,網狀物’發泡片材或金屬片#,以及對該等之層 壓體等適當之薄片體視需要时氧系或長鏈烧烴系、氣系 或石1化鉬等適當之剝離劑加以塗佈處理所得者等的依據先 前之適當者。 再者,亦可將直至將偏光板提供給實際應用即貼合於液 晶單70等之光學顯示單元上為止之期間,為防止黏著劑層 之露出面受到污染等而暫時貼附之脫模膜,作為後述之用 以將偏光板搬送至與光學顯示單元相對向之位置的搬送片 136641.doc -20- 200947051 材。於此情形時,該脫模膜較好的是即便施加張力亦不會 伸長或者伸長較小者,亦即由拉伸彈性模數較大之材料所 形成者。可較好地用於此種作為搬送用片材之脫模膜,例 如可列舉金屬片材、聚醯亞胺膜、聚對苯二甲酸乙二酯膜 等。 <光學顯示單元>The thickness of the transparent film T can be appropriately determined, and as in the case of the above polyester film, it is preferably 5 to 500 μϊη, more preferably 5 to 2 μηηι, and even more preferably 10 to 15 0 μηι 〇. As the transparent film, any one of those having a small difference in birefringence and capable of exhibiting a phase difference plate can be used. When the function of the phase difference plate is used as a transparent film, as the south molecular material, for example, #乙醇醇, polyvinyl butyl aldehyde, polymethyl vinyl ether, polyacrylic acid hydroxyacetic acid, Hydroxyethyl cellulose: hydroxypropyl cellulose, methyl cellulose, polycarbonate, polyaryl phthalate, polyethylene terephthalate, polyethylene naphthalate, sulfone, polybenzene Thioether, polyphenylene ether, polyallyl hydrazine, polyamine, polyfluorene 3, poly (hydrocarbon), polyvinyl chloride, cellulose resin, ring-shaped smoky tree, olefinic resin) or these Various binary, ternary copolymers, graft copolymers, blends, and the like. These polymer materials are formed into an alignment product (stretched film) by stretching or the like. 13664J.doc -38- 200947051 The laminate of the optical element P and the tg film E is preferably carried out via the adhesive layer G as described above. Further, the laminate of the polarizing element p and the transparent film τ is also preferably formed via the adhesive layer G. [Laminated Form c] Fig. Uc) is a form in which a polyester film e is laminated on one main surface of the polarizing element p, and a film is not laminated on the other main surface. In such a form, the laminate of the polarizing element P 〃 and the t 曰 film E is preferably carried out via the adhesive layer 如上 as described above. [Other Optical Layers] (Formation of Surface Treatment Layer) When at least i of the polyacetal film E and the polarizing element p are laminated in the polarizing plate used in the production method of the present invention, the form is not limited to the above laminated form (4). Any of the optical layers listed in ~(4) can be added. As such an optical layer, for example, a hard coat layer or an anti-reflection treatment may be applied to the main surface of the unstacked polarizing element P of the polyester film E&/or the transparent film, and anti-sticking, diffusion or anti-glare may be applied. For the purpose of the processor. In addition, examples of the optical layer which can be applied to the polarizing plate include a brightness enhancement mode, a reflection layer phase difference plate, and the like. [Lamination of optical layer] A material layer such as a brightness enhancement film, a reflection layer, or a phase difference plate can be formed by sequentially laminating in the process of manufacturing an image display device, and the pre-layered person has quality stability or assembly. Excellent workability and the like, and the advantages of the manufacturing steps can be improved. An appropriate bonding mechanism such as an adhesive layer can be used for lamination. In the laminates, the optical axes of the optical layers (the slow axis of the retardation film, or the polarization 136641.doc •19-200947051, etc., which form the absorption axis of the suitable component, etc.) can be arranged according to the phase of the target phase. . (Adhesive layer) Further, it is preferable that an adhesive layer is provided in advance on the main surface of the polarizing plate to fit the optical display unit. The adhesive for forming the adhesive layer is not particularly limited, and for example, a propionic acid-based polymer, a fluorinated polymer, a polyester, a polyamino phthalate, a polyamine, an ether, or the like can be appropriately selected and used. A polymer such as a fluorine-based or rubber-based polymer is used as the base polymer I. It is excellent in optical transparency such as an acrylic adhesive, and exhibits excellent wettability, cohesiveness, and adhesion properties, and is excellent in weather resistance and heat resistance. (Release film) For the exposure s of the adhesive layer, the release film (spacer) is temporarily attached and covered to prevent contamination or the like until it is provided for practical use. Thereby, it is possible to prevent contact with the adhesive layer in a normal operation state. As the release film, for example, a plastic film, a rubber sheet, a paper, a cloth, a non-woven fabric, a meshed "foamed sheet or a metal sheet #", and a suitable sheet such as the laminate may be used as needed. A suitable one of the oxygen-based or long-chain hydrocarbon-based, gas-based, or molybdenum-based molybdenum is applied as it is before. In addition, the release film may be temporarily attached to prevent the exposed surface of the adhesive layer from being contaminated, etc., until the polarizing plate is applied to the optical display unit such as the liquid crystal cell 70, which is applied to the actual application. A transfer sheet 136641.doc -20-200947051 for transporting the polarizing plate to a position facing the optical display unit, which will be described later. In this case, the release film is preferably one which does not elongate or elongate even if tension is applied, i.e., is formed of a material having a large tensile modulus. The release film which is such a sheet for conveyance can be preferably used, and examples thereof include a metal sheet, a polyimide film, and a polyethylene terephthalate film. <Optical display unit>

作為本發明之製造方法中所使用之光學顯示單元,例如 可列舉液晶單元之玻璃基板單元、有機EL發光體單元等。 於光學顯示單元為液晶單元之情形時,例如可使用 TN(Twisted Nematic,扭轉向列)型或 STN(Super TwistedExamples of the optical display unit used in the production method of the present invention include a glass substrate unit of a liquid crystal cell, an organic EL emitter unit, and the like. In the case where the optical display unit is a liquid crystal cell, for example, TN (Twisted Nematic) type or STN (Super Twisted) can be used.

Nematic,超扭轉向列)型、兀型等之任意類型者。於液晶 顯示裝置中’自其圖像形成方式考慮,必不可少地須要於 液晶單元之玻璃基板單元上配置偏光板。可將使用聚醋膜 作為偏光元件保護膜之上述偏光板,設置於液晶單元之玻 璃基板單元之單側或者兩側。當於兩側設置上述偏光板之 情形時’肖等偏光板可為相同者,亦可為不同者。 於光學顯示單元為有機肛發光體單元之情形時,作為其 有機發光層,可應用各種有機薄膜之積㈣,例如已知有 具有以下各種組合之構成:包含三苯胺衍生物等之電洞佈 植層、與包含蒽等螢光性有機固體之發光層的積層體,此 種發光層與包含苑衍生物等之電子佈㈣的積㈣,❹ 該等電洞佈植層、發光層、及電子佈植層之積層體等。. 於上述構成之有機EL顯示裝置中,有機發光層係以厚度 為10 nm左右之極薄之膜所并;士 m /成。因此,有機發光層亦與 136641.doc 21 200947051 透明電極同樣,可大致完全地透射光。其結果,當不發光 時自透明基板之表面射入,透射過透明電極及有機發光層 並由金屬電極反射之光再次射出至透明基板之表面側,因 此自外部目視時,有機EL顯示裝置之顯示面看上去如同鏡 面。 相位差板及偏光板由於具有使自外部射入並由金屬電極 反射而來之光偏振的作用,因此有藉由該偏光作用而使得 無法自外部目視到金屬電極之鏡面的效果。尤其是,若以 1/4波片構成相位差板,且將偏光板與相位差板之偏振方 向所成的角度調整為π/4(90。),則可將金屬電極之鏡面完 全遮蔽。 即,射入至該有機EL顯示裝置之外部光中,藉由偏光板 僅直線偏光之成分透射。該直線偏光通常藉由相位差板會 成為擴圓偏A,尤#當相位差板為1/4波[幻烏光板與 相位差板之偏振方向所成的角度為π/4(9〇。)時,會成為圓 偏光。 … 該圓偏光透射過透明基板、透明電極、有機薄膜,並由 金屬電極反射,再次透射過有機薄膜、透明電極、透明基 板,並藉由相位差板而再次成為直線偏光。並且,由於該 直線偏光與偏光板之偏振方向相互正交,因此無法透射過 偏光板。其結果,可將金屬電極之鏡面完全遮蔽。 藉由使用為獲得該圓偏光而積層有例如1/4波片作為光 學補償層之上述偏光板,可抑制外部光之反射,獲得室外 之視認性亦較高之有機EL顯示裝置。又,與上述液晶顯示 136641.doc -22- 200947051 裝置同樣,該有機扯顯示裝置就耐擦傷性優異之方面而言 亦較好。 於將上述偏光板用於此種有機示裝置中之情形時, 可採用將聚酯膜用作光學補償層即1/4波片之構成、以及 . 將聚酯膜僅用作偏光元件保護膜之構成中的任一種。 [圖像顯示裝置之形成] 如圖2所示,圖像顯示裝置100係藉由將上述偏光板u , 、經由黏著劑層Η貼合於上述光學顯示單元w之表面而形 成先則於形成圖像顯示裝置時,係採用下述方法:自配 a液sa單元或有機EL發光體單元等將要貼合之光學顯示單 元之尺寸而切斷成既定尺寸的偏光板,剝離脫模膜而形成 黏著劑層露出之狀態,然後將其對向地貼合於光學顯示單 元上。 仁是於形成液晶顯示裝置或有機BL顯示裝置等圖像顯 不裝置時,當使用如上述積層形態b(圖明)所示般偏光元 參 #P之1表面與另—主表面上所積層之膜並不相同,或 者如上述積層形態c(圖i(c))所示般僅於偏光元件p之一主 纟_L積層有膜之構成的偏光板時,存在於積層有聚睹膜 E之侧之主表面與另—主表面,對偏光元件p的膜界面所賦 予之應力不同之情形。又,於如積層形態a(圖1(a))所示般 在偏光tl件P之兩主表面上均積層有聚酯膜£之形態中,亦 存在較多下述情形:由於對偏光元件之與光學顯示單元相 對向之側的主表面、及相反侧之主表面所要求的光學特性 不同’因此厚度或延伸倍率不同,導致於偏光元件之—主 136641.doc •23- 200947051 表面與另一主表面’對偏光元件p之膜界面所賦予之應力 不同。即’於使用聚酯膜作為偏光元件保護膜之偏光板 中’存在由於偏光元件P之表背側之層結構不同,而導致 對偏光元件所賦予之外部應力於膜之表背側不同之情形。 由於該外部應力之差,膜容易具有彎曲性。先前技術中, 難以將如此之容易產生彎曲(捲曲)之偏光板精度良好地貼 合於光學顯示單元上,鑒於此,本發明係藉由依序進行搬 送步驟、第1黏貼步驟、第2黏貼步驟,而將偏光板u與光 學顯不單元w相貼合。以下,對各步驟加以說明。 [搬送步驟] 搬送步驟係如圖3(a)中以模式方式所表示般,將暫時貼 附於賦予有張力之脫模膜12上之偏光板11,搬送至與光學 ‘.、具不單7L W相對向之位置。如此,藉由以脫模膜丨2作為搬 片材可於藉由脫模膜之搬送張力而抑制偏光板之彎曲 行為之狀態下,將偏光板搬送至光學顯示單元附近。再 者’所謂偏光板與光學顯示單元「相對向」,不僅指兩者 之主表面平行且相互面對之狀態,並且如圖3(a)所示,以 ◎ 兩者可貼合之程度相互面對即已足夠。 =為搬送片材之職膜12,可直接使用如上所述為防止 黏者劑層之露出面受到污染等而暫時貼附之脫模膜亦V 與/、不同而另外暫時貼附者。作為可適宜用作此種搬 、合脫模膜者’較好的是如上所述般,即便施加張力亦 _長或者伸長較小者即由拉伸彈性模數較大之材料 者例如可列舉金屬片材、聚醯亞胺膜、聚對苯二 136643.doc -24- 200947051 甲酸乙二酯等。 就與偏光板之暫時貼附性或搬送性、或者經濟性優異之 觀點而言,作為搬送片材之脫模膜之厚度較好的是ι〇 μιη〜100 μχη,更好的是 25 μηι〜50 μηι。 對將偏光板與作為搬送片#之脫模膜暫時貼附的機構並 無特別限制,例如可使用黏著劑、黏著帶、水性暫時接合 劑等。其中,較好的是使用黏著劑層作為暫時貼附機構, 並且使用該黏著劑層作為於後述第〗及第2黏貼步驟中用以 將偏光板與光學顯示單元相貼合之黏著劑層。就上述觀點 而言,較好的是將作為暫時貼附機構之黏著劑層設計為, 在將偏光板與脫模膜剝離時,該黏著劑層會殘留於偏光板 側。就該觀點而言,脫模膜之與偏光板暫時貼附之側之面 較好的是用矽氧系或長鏈烷烴系、氟系或硫化鉬等適當之 剥離劑加以塗佈處理者。 至於用以搬送脫模膜12之張力,例如於長條狀片材之情 形時’可藉由對用以捲取長條狀脫模膜之捲取裝置加以控 制而控制該張力。又,亦可使用各種公知之張力控制裝 置。對作為搬送片材之脫模膜施加之張力較好的是根據偏 光板之彎曲容易度、或脫模膜之厚度而適當調整。例如, 於使用聚對本二甲酸乙二酯膜作為脫模膜之情形時,脫模 膜之厚度d與脫模膜之每單位寬度之張力ρ之下限值的關係 係如表1中所示。由表1可知,若d與f之平方的乘積dF2約 為2.5xl〇-i N2/m以上,則可一面抑制偏光板彎曲一面搬 送。另一方面’就防止脫模膜伸長而斷裂、或者偏光板之 136641.doc •25- 200947051 光學特性產生變化的觀點而言’脫模膜之每單位寬度之張 力F較好的是1000 N/m以下。 [表1] 脫棋膜之厚度 ά(μιη) 每單位寬度之張力 F(N/m) 應力 a(MPa) dF2(N2/m) 25 100 4.0 0.25 38 90 2.4 0.3078 50 80 1.6 0.32 75 60 0.8 0.27 ~ 對將暫時貼附於脫模膜12上之偏光板11搬送至與光學顯 示單元W相對向之位置的方法並無特別限制,可手動搬 送,亦可用搬送輥等自動搬送。就如上所述控制張力之觀 點而言,較好的是使用具備控制機構之輥搬送機進行搬 送。 [第1黏貼步驟] 繼上述搬送步驟之後,進行^黏貼步驟。第m貼步驟 以及後述之第2黏貼步驟,係—面自偏光板u上去除脫模 膜⑴-面將經去除該脫模膜之偏光板經由黏著劑層(未 圖示)而貼合於光學顯示單元上的步驟。第】黏貼步驟為如 下步驟: >圖3附以模式方式所表*般,將偏光板之— 端部自脫模膜12上剝離,並且如圖3⑷式方式所表 示般,將該偏光板之自脫模媒上部分^少 貼合於光學顯示單元W之表面。藉由上述步驟,在將:: 模膜12上㈣之偏光板之-料貼合於光學㈣單元I 時’在仍暫時㈣於脫_上之剩餘部分經由脫模膜而繼 136641.doc •26- 200947051 續受到張力的狀態’因此可抑制偏光板產生彎曲βAny type of Nematic, super twisted nematic, scorpion, etc. In the liquid crystal display device, it is indispensable to arrange a polarizing plate on the glass substrate unit of the liquid crystal cell in view of the image forming method. The polarizing plate using the polyacetal film as the polarizing element protective film may be provided on one side or both sides of the glass substrate unit of the liquid crystal cell. When the above polarizing plates are disposed on both sides, the polarizing plates such as the shaws may be the same or different. In the case where the optical display unit is an organic anal light-emitting unit, as the organic light-emitting layer, a product of various organic thin films can be applied. (IV) For example, a configuration having various combinations of the following is known: a hole cloth containing a triphenylamine derivative or the like a laminate, a laminate comprising a light-emitting layer comprising a fluorescent organic solid such as ruthenium, a product of the light-emitting layer and an electronic cloth (4) containing a garden derivative, and the like, a layer of the hole, a light-emitting layer, and A laminate of an electronic implant layer or the like. In the organic EL display device having the above configuration, the organic light-emitting layer is formed by an extremely thin film having a thickness of about 10 nm; Therefore, the organic light-emitting layer can transmit light substantially completely similarly to the transparent electrode of 136641.doc 21 200947051. As a result, when the light is not emitted, the light is incident from the surface of the transparent substrate, and the light transmitted through the transparent electrode and the organic light-emitting layer and reflected by the metal electrode is again emitted to the surface side of the transparent substrate. Therefore, the organic EL display device is visually viewed from the outside. The display surface looks like a mirror. Since the phase difference plate and the polarizing plate have a function of polarizing light which is incident from the outside and reflected by the metal electrode, there is an effect that the mirror surface of the metal electrode cannot be visually observed from the outside by the polarizing action. In particular, when the retardation plate is formed of a quarter-wave plate and the angle formed by the polarization directions of the polarizing plate and the phase difference plate is adjusted to π/4 (90 Å), the mirror surface of the metal electrode can be completely shielded. That is, it is incident on the external light of the organic EL display device, and the component of the linearly polarized light is transmitted through the polarizing plate. The linearly polarized light is usually rounded off by the phase difference plate, and the angle is 1/4 of the phase difference plate. The angle formed by the polarization direction of the opaque plate and the phase difference plate is π/4 (9 〇. ), it will become a circular polarized light. The circularly polarized light is transmitted through the transparent substrate, the transparent electrode, and the organic thin film, and is reflected by the metal electrode, transmitted again through the organic thin film, the transparent electrode, and the transparent substrate, and is again linearly polarized by the phase difference plate. Further, since the linear polarization and the polarization directions of the polarizing plates are orthogonal to each other, they cannot be transmitted through the polarizing plate. As a result, the mirror surface of the metal electrode can be completely shielded. By using the above-mentioned polarizing plate in which, for example, a quarter-wave plate is laminated as an optical compensation layer in order to obtain the circularly polarized light, reflection of external light can be suppressed, and an organic EL display device having high outdoor visibility can be obtained. Further, similarly to the above-described liquid crystal display device 136641.doc -22-200947051, the organic pull display device is also excellent in terms of excellent scratch resistance. When the above polarizing plate is used in such an organic display device, a polyester film can be used as an optical compensation layer, that is, a quarter-wave plate, and a polyester film can be used only as a polarizing element protective film. Any of the components. [Formation of Image Display Device] As shown in FIG. 2, the image display device 100 is formed by bonding the polarizing plate u to the surface of the optical display unit w via an adhesive layer. In the case of the image display device, a method is employed in which a polarizing plate of a predetermined size is cut into a size of an optical display unit to be bonded, such as a liquid sa unit or an organic EL illuminator unit, and the release film is peeled off. The adhesive layer is exposed and then attached to the optical display unit in a facing manner. When forming an image display device such as a liquid crystal display device or an organic BL display device, the surface of the polarizing element #P1 and the other main surface are laminated as shown in the above-mentioned laminated form b (shown). When the film is not the same, or as shown in the laminated form c (Fig. i(c)), only one of the polarizing elements p is formed by a film having a film of the main layer _L, and the polylayer film is present in the layer. The main surface on the side of E and the other main surface have different stresses imparted to the film interface of the polarizing element p. Further, in the form in which the polyester film is laminated on both main surfaces of the polarized light piece P as shown in the laminated form a (Fig. 1 (a)), there are also many cases in which the polarizing element is present. The main surface of the opposite side of the optical display unit and the main surface of the opposite side are different in optical characteristics. Therefore, the thickness or the stretching ratio is different, resulting in the surface of the polarizing element - main 136641.doc • 23- 200947051 A main surface 'has a different stress to the film interface of the polarizing element p. That is, 'in the polarizing plate using the polyester film as the protective film of the polarizing element', there is a case where the external stress imparted to the polarizing element is different on the back side of the film due to the difference in the layer structure of the front side of the polarizing element P. . Due to the difference in external stress, the film is easily bendable. In the prior art, it is difficult to adhere the polarizing plate which is easily bent (curled) to the optical display unit with high precision. In view of the above, the present invention performs the transport step, the first pasting step, and the second pasting step in sequence. And the polarizing plate u is bonded to the optical display unit w. Hereinafter, each step will be described. [Transfer step] The transfer step is temporarily attached to the polarizing plate 11 to which the tension release film 12 is applied, as shown in the mode of Fig. 3 (a), and is transported to the optical '. W is relatively opposite. By using the release film 2 as a conveyance sheet, the polarizing plate can be conveyed to the vicinity of the optical display unit while the bending behavior of the polarizing plate is suppressed by the conveyance of the release film. Furthermore, the term "opposing the polarizing plate and the optical display unit" means not only the state in which the main surfaces of the two are parallel and facing each other, but also as shown in Fig. 3(a). The face is enough. In the case of the film 12 for transporting the sheet, the release film which is temporarily attached to prevent the exposed surface of the adhesive layer from being contaminated or the like is also used as it is. As a material which can be suitably used as such a mold release film, it is preferable to use a material which has a large tensile modulus and a large elongation even when the tension is applied as long as the tension is applied as described above. Metal sheet, polyimide film, polyparaphenylene 136643.doc -24- 200947051 ethylene formate and the like. The thickness of the release film as the conveyance sheet is preferably ι〇μιη to 100 μχη, more preferably 25 μηι~ from the viewpoint of temporary adhesion to the polarizing plate or transportability or economy. 50 μηι. The mechanism for temporarily attaching the polarizing plate to the release film as the transfer sheet # is not particularly limited, and for example, an adhesive, an adhesive tape, a water-based temporary adhesive or the like can be used. Among them, it is preferred to use an adhesive layer as a temporary attaching means, and to use the adhesive layer as an adhesive layer for bonding a polarizing plate and an optical display unit in the second and second pasting steps described later. In view of the above, it is preferred that the adhesive layer as the temporary attaching means is designed such that the adhesive layer remains on the side of the polarizing plate when the polarizing plate is peeled off from the release film. From this point of view, the side of the release film which is temporarily attached to the side of the polarizing plate is preferably coated with a suitable release agent such as a halogen-based or long-chain alkane-based, fluorine-based or molybdenum sulfide. As for the tension for conveying the release film 12, for example, in the case of a long sheet, the tension can be controlled by controlling the winding device for winding the long release film. Further, various known tension control devices can be used. The tension applied to the release film as the conveying sheet is preferably adjusted in accordance with the ease of bending of the polarizing plate or the thickness of the release film. For example, when a polyethylene terephthalate film is used as a release film, the relationship between the thickness d of the release film and the lower limit of the tension ρ per unit width of the release film is as shown in Table 1. . As can be seen from Table 1, when the product dF2 of the square of d and f is about 2.5 x 1 〇 - i N2 / m or more, the polarizing plate can be prevented from being bent while being conveyed. On the other hand, 'the tensile force F per unit width of the release film is preferably 1000 N/ from the viewpoint of preventing the elongation of the release film from being broken, or the change in optical characteristics of the polarizing plate 136641.doc • 25- 200947051. m or less. [Table 1] Thickness of the film ά (μιη) Tension per unit width F (N/m) Stress a (MPa) dF2 (N2/m) 25 100 4.0 0.25 38 90 2.4 0.3078 50 80 1.6 0.32 75 60 0.8 0.27 ~ The method of transporting the polarizing plate 11 temporarily attached to the release film 12 to the position facing the optical display unit W is not particularly limited, and it can be manually transferred or automatically conveyed by a transfer roller or the like. In order to control the tension as described above, it is preferable to carry it by using a roller conveyor having a control mechanism. [First Adhesion Step] Following the above-described transfer step, a paste step is performed. The m-th bonding step and the second pasting step described later, the release film (1)-surface is removed from the polarizing plate u, and the polarizing plate from which the release film is removed is bonded to the polarizing plate (not shown) via an adhesive layer (not shown). The steps on the optical display unit. The affixing step is as follows: > Fig. 3 is attached to the release film 12 at the end of the polarizing plate as shown in the mode, and the polarizing plate is as shown in Fig. 3 (4) The upper portion of the self-release medium is less attached to the surface of the optical display unit W. By the above steps, when the material of the polarizing plate on the film of (4) is bonded to the optical (four) unit I, the remaining portion of the film (4) is still temporarily removed (via) the release film, and then 136641.doc. 26- 200947051 Continued tension state 'Therefore it can suppress the deflection of the polarizer β

作為用以將偏光板之一端部自脫模膜12上剝離之剝離機 構’例如可適宜使用前端尖銳之刀刀Ν。可構成為如下. 將脫模膜12捲搭於該刀刀Ν上後反轉移送,藉此剝離去除 脫模膜,並且將剝離脫模膜後之偏光板丨丨送出至光學顯示 單元w面上。此時,可與自偏光板11之-端部剝離脫模: 12之同時或者於剛剝離後,將該經剝離之部分貼合於光學 顯示單元W面上。所謂剛剝離脫模膜後,表示至偏光板= 生妨礙貼合之彎曲為止之時間。藉由使自偏光板之一端部 剝離脫模膜後至將該_離之部分貼合於光㈣示單元: 上為止之時間為5秒以β ’較好的是3秒以内可抑制彎 曲,提昇偏光板與光學顯示單元之貼合精度。 對將偏光板η與光學顯示單元…面貼合之方法並無特別 限制’就均-地貼合之觀點而言,較好的是利用按壓幸昆 3〇5 ’將偏光板U一面朝光學顯示單元w面上壓抿,—面 貼合。按壓輕305可為橡膠輥,亦可為金屬輥。又,按壓 輥較好的是以可升降之方今财供 ^ 斤丨兮之方式配備,並且較好的是,於上 搬送步驟中將偏光板丨丨朝盥杏風 朝興九學顯不单TO W相對向之位w 搬送時’按壓輥上升至 離開先學顯不單元之位置,例如齡 光學顯示單元之上表面#古 表面更尚之位置為止’以打開輥間隔。 較305之按壓壓力、#放么 動作係由適當之控制機構控制。 [第2黏貼步驟] 於上述第1黏貼步驟 _ 您後進仃弟2黏貼步驟。第2黏壯 步驟為如下步驟 罘福貼 圖3⑷中以模式方式所表示般,-面 136641.doc •27· 200947051 自於第1黏貼步驟中未黏貼於光學顯示單元w上而 2附於脫模膜12上的偏以u之剩餘部分將脫模臈剝離, 一面將該偏光板之剩餘部分貼合於該光學顯示單元上。該 步驟可與第i黏貼步驟分開進行,亦可連續進行。於本= 明中,藉由依序包括上述搬送步驟、第磷貼步驟及第冰 貼步驟,可-面抑制膜之一面進行貼合,因此即便是 如於偏光元件上積層有聚醋膜之偏光板等容易料的偏光 板,亦可將其精度良好地貼合於光學顯示單元上。As the peeling mechanism for peeling one end portion of the polarizing plate from the release film 12, for example, a sharp-edged knife blade can be suitably used. The release film 12 can be wound up on the knife blade and then transferred back, thereby peeling off the release film, and the polarizing plate 剥离 after peeling off the release film is sent out to the optical display unit w surface. on. At this time, the release portion can be peeled off from the end portion of the polarizing plate 11 at the same time as or immediately after the peeling off, and the peeled portion is bonded to the surface of the optical display unit W. The film is peeled off immediately after the release film, and the time until the polarizing plate = the bending which hinders the bonding is shown. By peeling one end of the polarizing plate from the release film until the portion to be bonded to the light (four) display unit: the time until the upper side is 5 seconds, and β ' is preferably within 3 seconds to suppress the bending. Improve the bonding accuracy of the polarizing plate and the optical display unit. There is no particular limitation on the method of bonding the polarizing plate η to the surface of the optical display unit. From the viewpoint of uniform bonding, it is preferable to press the polarizing plate U toward the side of the button. The optical display unit w is pressed on the surface, and the surface is bonded. The pressing light 305 can be a rubber roller or a metal roller. In addition, the pressing roller is preferably equipped in such a manner that it can be lifted and lowered, and it is better to use the polarizing plate in the upper conveying step. When transporting to the position w, the pressure roller is raised to a position away from the first unit, such as the upper surface of the optical display unit (the position of the surface of the optical display unit is more than the position of the ancient surface) to open the roller interval. The pressing pressure and the 305 pressing action are controlled by appropriate control mechanisms. [Second Adhesion Step] In the above-mentioned first pasting step _ you will enter the 2nd paste step. The second sticking step is as follows. In the following manner, the pattern is shown in Fig. 3 (4), and the surface 136641.doc • 27· 200947051 is not attached to the optical display unit w in the first pasting step and 2 is attached to the mold release. The remaining portion of the film 12 is peeled off by the remaining portion of the u, and the remaining portion of the polarizing plate is attached to the optical display unit. This step can be performed separately from the ith pasting step or continuously. In the present invention, the surface of the surface-reducing film is bonded by sequentially including the above-described carrying step, the phosphorus-paste step, and the ice-paste step, so that even a polarizing film is laminated on the polarizing element. A polarizing plate that is easy to feed, such as a plate, can be attached to the optical display unit with high precision.

對第2黏貼步驟中的自偏光板上剝離脫模膜之剝離方法 並無特別限制,例如可採用與上述^黏貼步驟相同之剝 離方法。另外,亦可採用如下方法:㈣長條狀之膜作為 脫模膜,-面對其施加張力一面捲取,藉此一面自偏光板 上制離脫模膜’一面將所暫時貼附之偏光板之剩餘部分黏 貼於光學顯示單元上。此時之脫模膜之捲取張力相對於脫 模膜之單位寬度,較好的是80 N/m以上,更好的是 100〜1000 N/m。藉由使張力為該範圍,可進一步提高偏光 板對光學顯示單元之黏貼精度。 再者,圖3(a)〜(d)中係圖示使光學顯示單元W之位置固 疋,且刀刃N及按壓輥3〇5可動之形態,但是本發明並不限 定於該形態。例如亦可如圖4(a)〜⑷所示,具備與按壓輥 305對向配置之導輥3〇51 ,且導輥可驅動,藉此,一面將 光學顯不單元W搬送至導輥與按壓輥之間’ 一面連續進行 上述各步驟。又’光學顯示單元W較好的是於提供給第1 黏貼步驟之前加以清洗。 136641.doc -28· 200947051 又本發明之製造方法較好的是於上述搬送步驟之前進 -步包括切斷步驟’由暫時貼附有上述脫模膜與上述偏光 板之積層光學製品,保留該脫模膜而將該積層光學製品之 其他構件切斷成既定尺寸。例如,於脫模膜經由黏著劑層 而暫時貼附於偏光板上之情形時,將偏光板以及黏著劑層 切斷成依據光學顯示單元之尺寸的既定尺寸而保留該脫模 ❹ ❹ 膜。作為切斷步驟中之切斷機構,例如可列舉雷射裝置、 切割機以及其他公知之切斷機構等。 ;將如積層有聚s曰膜作為偏光元件之保護膜的偏光板般 容易青曲之偏光板預先切斷成既定尺寸之情形時,存在由 於弯曲而變得難以谁并# 、進仃該刼作之傾向。針對此,藉由在即 將搬送偏光板至與光學顯示單元相對向之位置之前,以保 留錢換膜之方式進行切斷,可一面利用對脫模膜所施加 張力來抑制偏光板之彎曲,一面切斷臈,操作性優異。 進而》本發明t較好的是,自將脫模膜與 :::所得之長條狀之積層光學製品捲繞而成的捲轴素材, 光學製品,並將其切斷成既定尺寸。藉由如此 2=材而切斷成既定尺寸,可於連續之生產線上實行 準備、切斷步驟,以及偏光板與光學顯示單元 之貼合,因此如圖4() 入於选圖⑷⑷所不,可將偏光板11連續地貼 :斷=學顯示單元…上。進而,無需於將偏光板 效率。…早片狀態下進行操作,因此可提高生產 拿置時由於4场所,連續地進行先前製造圖像顯示 由光學膜製造廠家與面板加工礙家分別進行的偏光 136641.doc •29- 200947051 板之固定尺寸切斷以及朝光學顯示單元之貼合,因此無需 光學膜製造廠家之偏光板之端面加工或無塵包裝、運輸打 包或者面板加工廠家之解包。 又’作為本發明之一實施形態,亦可於自捲軸素材拉開 該積層光學製品之後、切斷之前進行瑕疵檢查步驟,用以 檢查偏光板等是否存在瑕疵。於在切斷步驟之前進行瑕疵 . 檢查步驟之情形時,較好的是在檢查之前,去除暫時貼附 - 於偏光板上之第1脫模膜。藉此,可無需考慮附著於第1脫 模膜12上或者其内在之異物或到痕等之瑕疵、或者第丨脫 ❹ 模膜内在之相位差而對偏光板〗丨進行瑕疫檢查。 繼而,於脫模膜去除步驟之後進行瑕疵檢查。瑕疵檢查 可應用公知之方法,例如可列舉自動檢查裝置、以及檢查 者之目視檢查。 於在瑕疵檢查之前,將暫時貼附於偏光板11上之脫模膜 12去除之情形時,就防止由於切斷而導致偏光板彎曲之觀 站而5,較好的是在瑕疵檢查之後於偏光板1丨上暫時貼附 另外之脫模膜22。進行暫時貼附時,較好的是以不產生氣 ❹ 泡等之起泡之方式來進行,此由於可維持平面性而較好。 作為暫時貼附方法,例如自脫模膜之捲軸素材322拉開脫 ' 模膜22,以1對或者複數對之輥對夾持脫模膜12與偏光板 U利用遠輕對使既定之壓力發揮作用而將其等貼合。輥 轉速度、壓力控制、搬送控制係由適當之控制機構 控制。 進而亦可採用下述方法:根據由瑕疵檢查所獲得之瑕 136641.doc -30- 200947051 疵之位置座標,以避開瑕疵部分之方式,於切斷步驟中切 斷成既定尺寸(有時稱為跳越切割)。將包含瑕疵之部分去 除或者貼合於非光學顯示單元之構件上,並將切斷成既定 尺寸之判定為合格品之偏光板貼合於光學顯示單元上。藉 • 此,可大幅提昇光學顯示單元之良率,降低需進行重工^ 理之頻率。 以上,關於本發明之圖像顯示裝置之製造方法的各步 ,驟,係以於光學顯示單元之-主表面上貼合偏光板之例: 中心而進行說明,但是亦可於光學顯示單元之兩主表面上 貼合偏光板。例如,於使用液晶單元作為光學顯示單元來 形成液晶顯示裝置之情形時,較好的是於液晶單元之兩主 表面上貼合偏光板。 以下,關於利用本發明之製造方法於光學顯示單元之— 主纟面上貝占合偏光板而形成圖像顯示裝置之實施形態,根 據圖6之步驟流程圖以及圖7之步驟概念圖來對跳越切割之 ⑩ #斷方式的步驟流程之例加以說明。 (1)捲軸素材準備步驟(圖6,Sl) 丨備形成為長條狀之積層光學製品1,作為捲軸素材 201如以所示,該積層光學製品^中積層有:由至少1片 聚-曰膜E與偏光兀件p積層所得之偏光板1工、黏著劑層μ、 第1脫模膜12。具去.. 丹者’偏光板11亦可包含聚酯膜及偏光元 件以外之光聲思 r 。又,於如上述積層形態c(圖l(c))所示, 偏=板11為僅於偏光元件P之一主表面上積層有膜的構成 之情形時,鲂杯 傅取 野的疋於偏光板11的偏光元件P側之面上, 136641.doc -31 · 200947051 具有黏著劑層14及第i脫模膜12。捲軸素材係設置於輥座 裝置301上,該輥座裝置301與馬達等連動以進行自由旋轉 或者以固定之旋轉速度旋轉。 (2) 第1脫模膜去除步驟(圖6,S2) 繼而,一面利用搬送機構302自準備且設置之捲轴素材 2〇1拉開積層光學製品i並搬送,一面去除上述第i脫模膜 . 12。作為脫模膜12之去除方法,例如可列舉:如圖7所示 以將所剝離之膜捲繞於輥212a上之方式連續地剝離之方 法,以及僅將脫模膜切割成既定尺寸單位並且用黏著帶將 其剝離去除之方法等。作為剝離機構,可採用以下方法: 與在上述第1黏貼步驟中自偏光板上剝離脫模膜12時同 樣,利用前端尖銳之刀刃N1進行刺離及反轉移送之方法 (參照圖7);或者沿著構成一對爽輥之2根輥分別搬送第域 模膜及偏光板來進行剝離之方法等。 (3) 瑕疲檢查步驟(圖6,§3) 繼而,於第1脫模臈去除步驟之後,進行瑕疵檢查。將 由瑕疵檢查機構303所獲取的瑕疵之位置座標提供給後述 ❹ 切斷機構之跳越切割。 (4) 第2脫模膜貼合步驟(圖6,S4) - 接著,於瑕疵檢查步驟之後,將第2脫模膜22經由上述 _ 黏著劑層14而暫時貼附於上述偏光板11上。可適宜採用下 述方法.如圖7所示,自第2脫模膜之捲轴素材222拉開第2 脫松膜22 ’以1對或者複數對之輥對夾持第2脫模膜與偏光 板’利用該親對使既定之壓力發揮作用而將其等貼合。 I36641.doc -32· 200947051 (5) 切斷步驟(圖6,§5) 然後’使用切斷機構304將上述偏光板11及上述黏著劑 層14切斷成既定尺寸,但不切斷上述第2脫模膜22。切斷 機構304係根據瑕疵檢查步驟中所檢測出的瑕疵之位置座 標,以避開瑕疵部分之方式進行切斷。即,將包含瑕疵部 分之切斷品作為不合格品而於後續步驟中除去。或者,切 斷機構304亦可忽略瑕疵之存在,連續地切斷成既定尺 寸。於此情形時,亦可於後述之搬送步驟、第1黏貼步 驟、第2黏貼步驟中,不將該部分貼合於光學顯示單元 上’而將其去除或者貼合於臨時板單元上。 (6) 搬送步驟以及第1黏貼步驟(圖6,S6,S7) 繼而,於切斷步驟之後,將於第2脫模膜上經由黏著劑 層14而暫時貼附之偏光板u,搬送至與光學顯示單元霤相 對向之位置(S6:板搬送步驟),將該偏光板之一端部自該 脫模膜上剝離,並且將該偏光板之自脫模膜上剝離之部分 的至少一部分貼合於光學顯示單元w之表面(s7:第1黏貼 步驟)。 ⑺第2黏貼步驟(圖6,S8) 之後,一面自該偏光板中於上述第丨黏貼步驟中仍暫時 貼附於第2脫模膜22上的剩餘部分將脫模膜剝離,一面將 该偏光板之剩餘部分貼合於該光學顯示單元评上,藉此, 可一面去除第2脫模膜22, 一面將經去除該第2脫模膜22之 偏光板11,經由上述黏著劑層14而貼合於光學顯示單元w 上。因此,即便將脫模膜剝離,亦可於偏光板丨丨之彎曲得 136641.doc -33· 200947051 到抑制之狀態下’將偏光板11貼合於光學顯示單元W上。 偏光板貼合機構係於切斷處理之後,一面去除第2脫模 膜’一面將經去除該第2脫模膜之偏光板’經由黏著劑層 而貼合於光學顯示單元。如圖3及圖4所示,貼合時較 好的是利用按壓輥305,將偏光板11 一面朝光學顯示單元 w面上壓抵一面進行貼合。輥3〇5之按壓壓力、動作係由 適當之控制機構來控制。作為剝離機構,可適宜採用下述 - 方法:如上所述’使用前端尖銳之刀刃N,將第2脫模膜22 捲搭於該刀刃上後朝相反方向搬送(反轉移送),藉此一面 ❹ 自與第2脫模膜22—起搬送之偏光板η上剝離去除第2脫模 膜,一面搬送經剝離第2脫模膜後之偏光板丨丨,直至其前 端到達按壓輥305之中央下部為止,由此將其送出至光學 顯示單元W面上。 該等捲軸素材準備步驟、切斷步驟、搬送步驟、第1黏 貼步驟、第2黏貼步驟之各步驟係於連續之生產線上實 行。於以上之一系列製造步驟中,係於光學顯示單元貿之 一主表面上貼合偏光板11,但是亦可於另一主表面上貼合 偏光板或其他光學膜。再者,於不採用跳越切割之切斷方 式的製造方法中,可省略第1脫模膜去除步驟、瑕疵檢查 步驟、第2脫模膜貼合步驟。 (8)製品檢查步驟(圖6,S9) 較好的是’連續步驟中進一步具有製品檢查步驟。作為 製品檢查步驟,可例示檢查貼合狀態之檢查步驟、以及檢 查貼合後之瑕寐之檢查步驟。製品檢查可僅為其中任一種 136641.doc -34- 200947051 檢查’但較好的是進行兩種檢查。 (9)安裝步驟(圖6,S10)The peeling method of peeling off the release film from the polarizing plate in the second pasting step is not particularly limited, and for example, the same peeling method as the above-mentioned pasting step can be employed. In addition, the following method may be employed: (4) a strip-shaped film is used as a release film, and the film is wound while being applied thereto, whereby the film is temporarily attached to the release film from the polarizing plate. The remainder of the board is attached to the optical display unit. The take-up tension of the release film at this time is preferably 80 N/m or more, more preferably 100 to 1000 N/m, with respect to the unit width of the release film. By setting the tension to this range, the adhesion accuracy of the polarizing plate to the optical display unit can be further improved. Further, in Figs. 3(a) to 3(d), the position of the optical display unit W is fixed, and the blade N and the pressing roller 3〇5 are movable. However, the present invention is not limited to this embodiment. For example, as shown in FIGS. 4(a) to 4(4), the guide roller 3〇51 disposed opposite to the pressing roller 305 may be provided, and the guide roller may be driven, whereby the optical display unit W is transported to the guide roller and The above steps are continuously performed on the one side between the pressing rolls. Further, the optical display unit W is preferably cleaned before being supplied to the first pasting step. 136641.doc -28-200947051 Further, in the manufacturing method of the present invention, it is preferred that the step further comprises a cutting step of "splicing the optical article temporarily attached with the release film and the polarizing plate before the transfer step, and retaining the The release film is used to cut the other members of the laminated optical article into a predetermined size. For example, when the release film is temporarily attached to the polarizing plate via the adhesive layer, the polarizing plate and the adhesive layer are cut into a predetermined size depending on the size of the optical display unit to retain the release film. Examples of the cutting mechanism in the cutting step include a laser device, a cutter, and other known cutting mechanisms. When the polarizing plate which is easy to be curved like a polarizing plate having a protective film of a polarizing element is cut into a predetermined size in advance, there is a case where it is difficult to bend due to bending. The tendency to make. In this case, by cutting the film so as to change the film before moving the polarizing plate to the position opposite to the optical display unit, it is possible to suppress the bending of the polarizing plate by applying tension to the release film. When the crucible is cut, the workability is excellent. Further, the present invention is preferably an optical article obtained by winding a release film and a long laminated optical product obtained by :::, an optical product, and cutting it into a predetermined size. By cutting into a predetermined size by such a material, the preparation and cutting steps can be performed on a continuous production line, and the polarizing plate and the optical display unit are attached. Therefore, as shown in FIG. 4(), the selection is not shown in (4) and (4). The polarizing plate 11 can be continuously attached: on the display unit. Further, it is not necessary to use the polarizing plate. ...operating in the early film state, it is possible to improve the polarization of the previously manufactured image display by the optical film manufacturer and the panel processing due to the four places when the production is taken. 136641.doc •29- 200947051 The fixed size is cut and attached to the optical display unit, so there is no need for the end face processing of the polarizing plate of the optical film manufacturer or the dust-free packaging, the shipping package or the unpacking of the panel processing manufacturer. Further, as an embodiment of the present invention, it is also possible to perform a flaw check step after the laminated optical product is pulled from the reel material and before the cutting, to check whether or not flaws are present in the polarizing plate or the like. In the case of the inspection step, it is preferred to remove the first release film temporarily attached to the polarizing plate before the inspection. Thereby, the plaque inspection can be performed on the polarizing plate without considering the phase difference between the foreign matter attached to the first release film 12 or the foreign matter or the mark or the like, or the phase difference in the first release film. Then, a flaw check is performed after the release film removing step.瑕疵 Inspection A well-known method can be applied, and for example, an automatic inspection device and a visual inspection by an examiner can be cited. When the release film 12 temporarily attached to the polarizing plate 11 is removed before the inspection, the polarizing plate is prevented from being bent due to the cutting, and 5 is preferably after the inspection. Another release film 22 is temporarily attached to the polarizing plate 1A. When the temporary attachment is carried out, it is preferred to carry out the foaming without generating gas bubbles or the like, which is preferable because the planarity can be maintained. As a temporary attaching method, for example, the take-up film 22 of the release film is pulled apart from the release film 22, and the pair of rolls or the pair of rolls is used to hold the release film 12 and the polarizing plate U by using a light weight to make a predetermined pressure. Play a role and fit them together. The roll speed, pressure control, and conveyance control are controlled by appropriate control mechanisms. Further, the following method may be employed: according to the position coordinates of 瑕 641 641 641 641 641 641 641 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕 瑕For skipping the cut). The portion including the crucible is removed or attached to the member of the non-optical display unit, and the polarizing plate which is cut into a predetermined size and judged to be a good product is attached to the optical display unit. By this, the yield of the optical display unit can be greatly improved, and the frequency of rework can be reduced. As described above, each step of the method of manufacturing the image display device of the present invention is described by arranging a polarizing plate on the main surface of the optical display unit: a center, but it may be used in an optical display unit. A polarizing plate is attached to both main surfaces. For example, when a liquid crystal display unit is used as an optical display unit to form a liquid crystal display device, it is preferable to apply a polarizing plate to both main surfaces of the liquid crystal cell. Hereinafter, an embodiment in which an image display device is formed by using a manufacturing method of the present invention on a main surface of an optical display unit to form an image display device will be described based on the step flow chart of FIG. 6 and the step conceptual diagram of FIG. The example of the step flow of the 10 break mode of the skip cut is explained. (1) Reel material preparation step (Fig. 6, S1) A laminated optical product 1 formed as a long strip, as shown in the reel material 201, the laminated optical product is laminated with at least one sheet- The polarizing plate 1 and the adhesive layer μ and the first release film 12 are obtained by laminating the enamel film E and the polarizing element p. With the go.. Dan's polarizing plate 11 can also include the polyester film and the optical sounds r other than the polarizing element. Further, as shown in the above-described laminated form c (Fig. 1(c)), when the deflector 11 is a structure in which only a film is laminated on one main surface of the polarizing element P, the 鲂 cup The surface of the polarizing plate 11 on the side of the polarizing element P, 136641.doc - 31 · 200947051, has an adhesive layer 14 and an i-th release film 12. The reel material is disposed on a roll holder device 301 that is rotatably coupled to a motor or the like for free rotation or at a fixed rotational speed. (2) The first release film removal step (FIG. 6, S2), and then the first imaginary release is removed while the laminated optical product i is pulled and transported by the transfer mechanism 302 from the prepared reel material 2〇1. Membrane. 12. As a method of removing the release film 12, for example, a method of continuously peeling off the peeled film on the roll 212a as shown in FIG. 7 and cutting the release film into a predetermined size unit and A method of peeling and removing it with an adhesive tape, and the like. As the peeling means, the following method may be employed: in the same manner as in the case where the release film 12 is peeled off from the polarizing plate in the first pasting step, a method of piercing and reverse transfer is performed by the sharp-edged edge N1 (see FIG. 7); Alternatively, a method of peeling off the first domain film and the polarizing plate by two rolls constituting a pair of smooth rolls may be performed. (3) The fatigue inspection step (Fig. 6, § 3) Then, after the first mold release step, the flaw check is performed. The position coordinates of the cymbal obtained by the 瑕疵 inspection mechanism 303 are supplied to the skip cutting of the ❹ cutting mechanism described later. (4) Second release film bonding step (Fig. 6, S4) - Next, after the 瑕疵 inspection step, the second release film 22 is temporarily attached to the polarizing plate 11 via the _ adhesive layer 14 . The following method can be suitably employed. As shown in Fig. 7, the second release film 22' is pulled from the reel material 222 of the second release film by a pair or a plurality of pairs of rollers to hold the second release film and The polarizing plate 'adapts the predetermined pressure by the pair of the pair to bond them. I36641.doc -32· 200947051 (5) Cutting step (Fig. 6, § 5) Then, the polarizing plate 11 and the above-mentioned adhesive layer 14 are cut into a predetermined size by using the cutting mechanism 304, but the above-mentioned 2 release film 22. The cutting mechanism 304 performs cutting in such a manner as to avoid the 瑕疵 portion based on the position coordinates of the cymbal detected in the 瑕疵 inspection step. That is, the cut product including the crotch portion is removed as a defective product in the subsequent step. Alternatively, the cutting mechanism 304 can also ignore the presence of the crucible and continuously cut into a predetermined size. In this case, it may be removed or bonded to the temporary plate unit in the transport step, the first pasting step, and the second pasting step, which will be described later, without attaching the portion to the optical display unit. (6) Transfer step and first pasting step (Fig. 6, S6, S7) Then, after the cutting step, the polarizing plate u temporarily attached to the second release film via the adhesive layer 14 is transferred to a position facing the optical display unit (S6: plate transport step), one end of the polarizing plate is peeled off from the release film, and at least a part of the portion of the polarizing plate peeled off from the release film is attached The surface of the optical display unit w is combined (s7: first bonding step). (7) After the second pasting step (Fig. 6, S8), the release film is peeled off from the remaining portion of the polarizing plate which is temporarily attached to the second release film 22 in the second adhesive step, and the release film is peeled off. The remaining portion of the polarizing plate is bonded to the optical display unit, whereby the second release film 22 can be removed, and the polarizing plate 11 from which the second release film 22 is removed can pass through the adhesive layer 14 It is attached to the optical display unit w. Therefore, even if the release film is peeled off, the polarizing plate 11 can be bonded to the optical display unit W in a state where the bending of the polarizing plate 得 136641.doc - 33 · 200947051 is suppressed. The polarizing plate bonding mechanism is bonded to the optical display unit via the adhesive layer while removing the second release film ' while removing the second release film'. As shown in Fig. 3 and Fig. 4, it is preferable that the bonding roller 305 is used for bonding, and the polarizing plate 11 is pressed against the surface of the optical display unit w to be bonded. The pressing pressure and action of the roller 3〇5 are controlled by an appropriate control mechanism. As the peeling mechanism, the following method can be suitably employed: "Using the sharp-edged cutting edge N as described above, the second release film 22 is wound around the blade and conveyed in the opposite direction (reverse transfer).剥离 The second release film is peeled off from the polarizing plate η transported from the second release film 22, and the polarizing plate 经 after the second release film is peeled off is conveyed until the leading end reaches the center of the pressing roller 305 The lower portion is thus sent out to the surface of the optical display unit W. The steps of the reel material preparation step, the cutting step, the transport step, the first bonding step, and the second bonding step are performed on a continuous production line. In one of the above series of manufacturing steps, the polarizing plate 11 is attached to one main surface of the optical display unit, but a polarizing plate or other optical film may be attached to the other main surface. Further, in the manufacturing method which does not employ the cutting method of skipping cutting, the first release film removing step, the flaw detecting step, and the second release film bonding step can be omitted. (8) Product inspection step (Fig. 6, S9) It is preferred that the product inspection step is further carried out in the continuous step. As the product inspection step, an inspection step of inspecting the bonding state and an inspection step of inspecting the bonding state can be exemplified. Product inspections may be performed only for any of them 136641.doc -34- 200947051 'but it is better to perform both inspections. (9) Installation steps (Figure 6, S10)

於製品檢查步驟中,將判定為合格品之光學顯示單元W 安裝於圖像顯示裝置中。例如,若為液晶顯示裝置,則係 於兩主表面上黏貼有偏光板之液晶單元,即於液晶面板的 適當位置上’視需要配置i層或2層以上的例如擴散板、防 眩層、k反射膜、保護板、稜鏡陣列、透鏡陣列片材、光In the product inspection step, the optical display unit W determined to be a good product is mounted in the image display device. For example, in the case of a liquid crystal display device, a liquid crystal cell having a polarizing plate adhered to both main surfaces, that is, an appropriate layer of the i-layer or two or more layers, such as a diffusion plate or an anti-glare layer, is disposed at an appropriate position on the liquid crystal panel. k reflective film, protective plate, tantalum array, lens array sheet, light

擴散板、背光等適當之零件’並組入驅動電路而形成。 又,於光學顯示單元被判定為不合格品之情形時,對其實 施重工處理’重新貼合偏光板’㈣進行檢查,若判定為 合,品’則敍至安裝步驟1歡為不合格品,則再次 移父至重工處理或者作廢棄處理。 與利用先前之製造方法而製造之圖像顯示裝置同樣,以 此種方式而製造之圖像顯示裝置可應諸各種公知之用途 中。 [實施例] 但是本發明並不限制 以下,列舉實施例來說明本發明 於以下所示之實施例。 &lt;製造例&gt; [偏光板之製造] 對厚度為3 8 μιη之雙細证从w 延伸聚對苯二曱酸乙二酯膜(三菱 化學聚酯膜製造之T_1〇〇) 变 ^ )進仃電軍處理之後,使用具備網 眼# 200之凹版輥之塗佈 m ^ 邱°式驗機來塗佈聚酯系水分散咹美 曱酸酯接著劑(第一工業制 基 '、衣樂製造,商品名「Superflex 136641.doc *35 - 200947051 SF210」),於15(TC下乾燥i分鐘,從而於該聚對笨二曱酸 乙一醋膜上形成厚度為〇·3 μπι之易接著層。 於將聚乙烯醇膜延伸並且用碘染色所得之偏光元件(厚 度為28 μηι)的一主表面上,經由以聚乙烯醇作為主成分之 水溶性接著劑,而將對上述積層面實施有易接著處理之雙 軸延伸聚對苯二曱酸乙二酯膜作為偏光元件保護膜來積 層。於上述偏光元件之另一側,經由上述水溶性接著劑而 積層厚度為40 μηι之三乙酸纖維素膜(柯尼卡美能達(K〇nica Minolta)公司製造之KC4UY),製作出偏光板。 將該偏光板裁剪成A4尺寸之長方形並於室溫下放置,則 該偏光板以雙轴延伸聚對苯二曱酸乙二酯膜側作為内侧而 彎曲成筒狀。 [液晶單元] 自對角尺寸為30英吋的市售之液晶電視(夏普(Sharp)製 造,商品名「AQUOS LC-M30TV」)甲,取出所搭載之液 B曰面板,將黏貼於液晶面板上之光學膜全部除掉,準備未 黏貼有光學膜之液晶單元之玻璃單元。 &lt;實施例1 &gt; #將上述製造例中所獲得之偏光板,以使對角尺寸成為30 ' ’ 式而切斷,並經由丙稀酸系黏著劑而暫時貼附於 靶加有150 N/rn之張力的厚度為38 μπ1且為長條狀之由雙軸 I伸咸對苯二曱酸乙二酯膜所形成之脫模膜(積層面經實 施矽氧脫模處理者)上,搬送至上述液晶單元之上部。之 後以如圖3(a)及(b)所示之方法,將上述脫模膜之一部分 136641.doc 200947051 剝離’使上述丙烯酸系黏著劑殘存於上述偏光板上並露 出。在剝離上述脫模膜後之2秒之内,以如圖3(c)所示之方 法將上述偏光板之經剝離之部分,經由上述丙烯酸系黏著 劑而黏貼於該液晶單元之玻璃面上。 繼而’一面對上述長條狀之脫模膜施加150 張力一 面捲取,藉此,一面將上述暫時貼附之偏光板之剩餘部 分’以如圖3(d)所示之方法自上述脫模膜上剝離,一面經 由上述丙烯酸系黏著劑而將其黏貼於液晶單元之玻璃表 面’製作出液晶面板。 於上述製造步驟中,偏光板1次都不會產生彎曲。並 且’所獲得之液晶面板中’偏光板不會自液晶單元偏移, 而以高精度黏貼。 如上所述,於產生捲曲之狀態下,以單片操作偏光板變 得困難,藉由應用本發明之連續方式之製造方法,則無論 是否產生捲曲均可製造圖像顯示裝置。 【圖式簡單說明】 圖1 (a)〜(c)係表示偏光板之積層形態的概略剖面圖。 圖2係表示圖像顯示裝置之積層形態的概略剖面圖。 圖3(a)〜(d)係用以說明本發明之製造方法之—實施形態 的概念圖。 圖4(a)〜(d)係用以說明本發明之製造方法之—實施形態 的概念圖。 圖5係表示積層光學製品之積層形態的概略剖面圖。 圖6係表示本發明之製造方法之一例的流程圖。 136641.doc -37- 200947051 圖7係用以說明本發明之製造方法之一例的步驟概要的 概念圖。 【主要元件符號說明】 1 積層光學製品 11 偏光板 12 脫模膜 22 脫模膜 100 圖像顯示裝置 305 按壓輥 E 聚酯膜 G 接著劑層 Η 易接著層 Ν 刀刃 Ρ 偏光元件 Τ 透明膜 W 光學顯示單元 136641.doc -38-A suitable part such as a diffusion plate or a backlight is formed and incorporated in a drive circuit. Further, when the optical display unit is judged to be a defective product, the rework processing 're-bonding the polarizing plate' (4) is inspected, and if it is determined that the product is closed, the product is described as a defective product in the mounting step 1. , then move the parent to the heavy work again or discard it. The image display device manufactured in this manner can be used in various known applications, similarly to the image display device manufactured by the prior art manufacturing method. [Examples] However, the present invention is not limited to the following examples, and the examples of the present invention described below will be described by way of examples. &lt;Manufacturing Example&gt; [Manufacture of polarizing plate] The polyethylene terephthalate film (T_1〇〇 manufactured by Mitsubishi Chemical Polyester Film) was changed from w to a thickness of 3 8 μm. After processing by the electric power company, the polyester water-dispersed bismuth phthalate adhesive (the first industrial base) was coated with a coating m ^ Qiu ° test machine with a mesh #200 gravure roll. Manufactured under the trade name "Superflex 136641.doc *35 - 200947051 SF210"), dried at 15 °C for 1 minute to form a thickness of 〇·3 μπι on the poly(p-bismuthic acid) film. The above-mentioned layer is applied to a main surface of a polarizing element (having a thickness of 28 μm) obtained by stretching a polyvinyl alcohol film and dyeing with iodine via a water-soluble adhesive containing polyvinyl alcohol as a main component. A biaxially-stretched polyethylene terephthalate film which is easy to be processed is laminated as a polarizing element protective film. On the other side of the polarizing element, a triacetate having a thickness of 40 μηη is deposited via the above water-soluble adhesive. Cellulose film (K〇nica Minolta) KC4UY), made of polarizing plate. The polarizing plate is cut into an A4-size rectangle and placed at room temperature, and the polarizing plate is biaxially stretched on the polyethylene terephthalate film side as the inner side. [Liquid Crystal Unit] A commercially available LCD TV (manufactured by Sharp, trade name "AQUOS LC-M30TV") A with a diagonal size of 30 inches, and the liquid B panel mounted. The optical film adhered to the liquid crystal panel is completely removed, and the glass unit of the liquid crystal cell to which the optical film is not adhered is prepared. <Example 1> The polarizing plate obtained in the above production example is made to have a diagonal size It is cut into 30'' type, and is temporarily attached to the target with a tension of 150 N/rn via an acrylic adhesive. The thickness is 38 μπ1 and the strip shape is biaxial I. The release film formed by the ethylene diacetate film (the layer is subjected to the oxygen release treatment) is transferred to the upper portion of the liquid crystal cell, and then as shown in FIGS. 3(a) and (b). Method, stripping one part of the above release film 136641.doc 200947051 to make the above propylene The adhesive remains on the polarizing plate and is exposed. Within 2 seconds after the release film is peeled off, the peeled portion of the polarizing plate is passed through the acrylic system as shown in FIG. 3(c). Adhesively adhered to the glass surface of the liquid crystal cell. Then, the film is wound while applying 150 tension to the strip-shaped release film, whereby the remaining portion of the temporarily attached polarizing plate is As shown in FIG. 3(d), the liquid crystal panel was produced by peeling off from the release film and adhering it to the glass surface of the liquid crystal cell via the acrylic adhesive. In the above manufacturing steps, the polarizing plate does not bend once. Further, the polarizing plate in the obtained liquid crystal panel is not offset from the liquid crystal cell, but is adhered with high precision. As described above, it is difficult to operate the polarizing plate in a single sheet in a state where the curl is generated, and by applying the continuous method of the manufacturing method of the present invention, the image display device can be manufactured regardless of whether or not curling occurs. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 (a) to (c) are schematic cross-sectional views showing a laminated form of a polarizing plate. Fig. 2 is a schematic cross-sectional view showing a laminated form of an image display device. 3(a) to 3(d) are conceptual views for explaining an embodiment of the manufacturing method of the present invention. 4(a) to 4(d) are conceptual views for explaining an embodiment of the manufacturing method of the present invention. Fig. 5 is a schematic cross-sectional view showing a laminated form of a laminated optical product. Fig. 6 is a flow chart showing an example of a manufacturing method of the present invention. 136641.doc -37- 200947051 Fig. 7 is a conceptual diagram for explaining an outline of steps of an example of the manufacturing method of the present invention. [Main component symbol description] 1 laminated optical product 11 polarizing plate 12 release film 22 release film 100 image display device 305 pressing roller E polyester film G subsequent layer Η easy adhesion layer 刀 blade 偏 polarizing element 透明 transparent film W Optical display unit 136641.doc -38-

Claims (1)

200947051 十、申請專利範圍: 種圖像顯不裳置之製造方法,其係將於偏光元件上積 層有至V 1片聚酯膜之偏光板’經由黏著劑層而貼合於 光學顯示單元之表面者,且依序包括: 〔步驟λ將暫時貼附於賦予有張力之脫模膜上之偏 . 光板搬送至與光學顯示單元相對向之位置; 第1黏貼步驟,將該偏光板之一方端部自該脫模膜上 剝離’並且將偏光板之自脫模膜上剝離之部分的至少一 ❹ 冑分貼合於光學顯示單元之表面;及 第黏貼V驟,—面自該偏光板中於第1黏貼步驟中仍 暫時貼附於4脫模膜上之剩餘部分將脫模膜剝離,一面 將偏光板之剩餘部分貼合於該光學顯示單元。 2.如請求項1之圖像顯示裝置之製造方法,其中上述脫模 膜,、上述偏光板係經由黏著劑層而暫時貼附,並使用該 黏者劑層作為用以將上述偏光板與上述光學顯示單元貼 合之黏著劑層。 _ 3.如請求項_之圊像顯示裝置之製造方法,其中於上述 搬送步驟之前,進-步包括切斷步驟,由暫時貼附有上 述脫㈣與上述偏光板之㈣光學製品,保留該脫模膜 而將該積層光學製品之其他構件切斷成特定尺寸。 4.如請求項3之圖像顯示裝置之製造方法,其中上述切斷 步驟係將自暫時貼附有脫模膜與偏光板之長條狀積層光 學製品捲繞而成的捲軸素材將該積層光學製品拉開者切 斷成特定尺寸。 136641.doc 200947051 5.如請求項1或2之圖像顯示裝置之製造方法,其中上述偏 光板係於聚酯膜之與偏光元件相對向之主表面上形成有 易接著層者。 136641.doc200947051 X. Patent application scope: A manufacturing method for displaying an image in which a polarizing plate of a polyester film laminated on a polarizing element is attached to an optical display unit via an adhesive layer. The surface includes, in order, the following steps: [Step λ is temporarily attached to the biasing film to which the tension is applied. The light plate is transported to a position opposite to the optical display unit; and the first pasting step is performed on one side of the polarizing plate. The end portion is peeled off from the release film and at least one part of the portion of the polarizing plate peeled off from the release film is attached to the surface of the optical display unit; and the first paste is applied to the polarizing plate. The remaining portion which is temporarily attached to the 4 release film in the first pasting step is peeled off, and the remaining portion of the polarizing plate is bonded to the optical display unit. 2. The method of manufacturing an image display device according to claim 1, wherein the release film, the polarizing plate is temporarily attached via an adhesive layer, and the adhesive layer is used as the polarizing plate The adhesive layer to which the optical display unit is attached. 3. The method of manufacturing the image display device of claim 1, wherein before the transferring step, the step further comprises a cutting step of temporarily attaching the (four) optical article to the polarizing plate and retaining the optical article The release film is used to cut the other members of the laminated optical article into specific dimensions. 4. The method of manufacturing an image display device according to claim 3, wherein the cutting step is to laminate the reel material obtained by winding a long laminated optical product temporarily attached with a release film and a polarizing plate. The optical article puller is cut to a specific size. The method of manufacturing the image display device according to claim 1 or 2, wherein the polarizing plate is formed on the main surface of the polyester film opposite to the polarizing element to form an easy-to-layer layer. 136641.doc
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