TW200944629A - Method for production of nanofibres from fluorated copolymers and terpolymers through electrostatic spinning, nanofibres and fabrics - Google Patents
Method for production of nanofibres from fluorated copolymers and terpolymers through electrostatic spinning, nanofibres and fabrics Download PDFInfo
- Publication number
- TW200944629A TW200944629A TW098108132A TW98108132A TW200944629A TW 200944629 A TW200944629 A TW 200944629A TW 098108132 A TW098108132 A TW 098108132A TW 98108132 A TW98108132 A TW 98108132A TW 200944629 A TW200944629 A TW 200944629A
- Authority
- TW
- Taiwan
- Prior art keywords
- copolymer
- spinning
- solution
- tri
- nanofiber
- Prior art date
Links
- 229920001577 copolymer Polymers 0.000 title claims abstract description 68
- 239000004744 fabric Substances 0.000 title claims description 12
- 238000004519 manufacturing process Methods 0.000 title abstract description 7
- 229920001897 terpolymer Polymers 0.000 title abstract 3
- 238000010041 electrostatic spinning Methods 0.000 title abstract 2
- 238000009987 spinning Methods 0.000 claims abstract description 78
- 239000007788 liquid Substances 0.000 claims abstract description 18
- 239000002904 solvent Substances 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 230000005686 electrostatic field Effects 0.000 claims abstract description 13
- RXKJFZQQPQGTFL-UHFFFAOYSA-N dihydroxyacetone Chemical compound OCC(=O)CO RXKJFZQQPQGTFL-UHFFFAOYSA-N 0.000 claims abstract description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052799 carbon Inorganic materials 0.000 claims abstract 2
- 239000002121 nanofiber Substances 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 25
- 239000000835 fiber Substances 0.000 claims description 10
- 238000001523 electrospinning Methods 0.000 claims description 9
- 229920000642 polymer Polymers 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical group CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims description 6
- -1 aliphatic ketones Chemical class 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 230000000694 effects Effects 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 3
- 230000002093 peripheral effect Effects 0.000 claims description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims 3
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 claims 2
- DIIIISSCIXVANO-UHFFFAOYSA-N 1,2-Dimethylhydrazine Chemical compound CNNC DIIIISSCIXVANO-UHFFFAOYSA-N 0.000 claims 1
- 229920000877 Melamine resin Polymers 0.000 claims 1
- RYFOQDQDVYIEHN-ZETCQYMHSA-N N,N-Dimethyllysine Chemical group CN(C)[C@H](C(O)=O)CCCCN RYFOQDQDVYIEHN-ZETCQYMHSA-N 0.000 claims 1
- 241000555745 Sciuridae Species 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 150000001733 carboxylic acid esters Chemical class 0.000 claims 1
- 238000007334 copolymerization reaction Methods 0.000 claims 1
- 230000005611 electricity Effects 0.000 claims 1
- 238000003682 fluorination reaction Methods 0.000 claims 1
- 238000002309 gasification Methods 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims 1
- 230000003068 static effect Effects 0.000 claims 1
- 235000011149 sulphuric acid Nutrition 0.000 claims 1
- 239000001117 sulphuric acid Substances 0.000 claims 1
- 150000003512 tertiary amines Chemical class 0.000 claims 1
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract description 10
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 abstract description 5
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 abstract description 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 19
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- KHIPEWLRUGVKIC-UHFFFAOYSA-N 4-Mercapto-2-pentanone Chemical group CC(S)CC(C)=O KHIPEWLRUGVKIC-UHFFFAOYSA-N 0.000 description 5
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- YWWNNLPSZSEZNZ-UHFFFAOYSA-N n,n-dimethyldecan-1-amine Chemical compound CCCCCCCCCCN(C)C YWWNNLPSZSEZNZ-UHFFFAOYSA-N 0.000 description 4
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 3
- 229940113088 dimethylacetamide Drugs 0.000 description 3
- 229920002313 fluoropolymer Polymers 0.000 description 3
- JOWBFITYYIZBFK-UHFFFAOYSA-N 2,2-bis(sulfanyl)acetamide Chemical compound NC(=O)C(S)S JOWBFITYYIZBFK-UHFFFAOYSA-N 0.000 description 2
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- QLIMAARBRDAYGQ-UHFFFAOYSA-N 1,6-diiodohexane Chemical compound ICCCCCCI QLIMAARBRDAYGQ-UHFFFAOYSA-N 0.000 description 1
- WOQLPPITHNQPLR-UHFFFAOYSA-N 1-sulfanylpyrrolidin-2-one Chemical compound SN1CCCC1=O WOQLPPITHNQPLR-UHFFFAOYSA-N 0.000 description 1
- 229920001410 Microfiber Polymers 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 239000003658 microfiber Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000002070 nanowire Substances 0.000 description 1
- 239000012811 non-conductive material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000007847 structural defect Effects 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000002207 thermal evaporation Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0015—Electro-spinning characterised by the initial state of the material
- D01D5/003—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion
- D01D5/0038—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion the fibre formed by solvent evaporation, i.e. dry electro-spinning
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/32—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising halogenated hydrocarbons as the major constituent
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Artificial Filaments (AREA)
- Nonwoven Fabrics (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CZ20080226A CZ2008226A3 (cs) | 2008-04-15 | 2008-04-15 | Zpusob výroby nanovláken z fluorovaných kopolymeru a terpolymeru elektrostatickým zvláknováním, nanovlákna a textilie |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW200944629A true TW200944629A (en) | 2009-11-01 |
Family
ID=41092097
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW098108132A TW200944629A (en) | 2008-04-15 | 2009-03-13 | Method for production of nanofibres from fluorated copolymers and terpolymers through electrostatic spinning, nanofibres and fabrics |
Country Status (3)
| Country | Link |
|---|---|
| CZ (1) | CZ2008226A3 (cs) |
| TW (1) | TW200944629A (cs) |
| WO (1) | WO2009127170A2 (cs) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130268062A1 (en) | 2012-04-05 | 2013-10-10 | Zeus Industrial Products, Inc. | Composite prosthetic devices |
| CN104178926B (zh) | 2009-01-16 | 2018-02-09 | Zeus工业品公司 | 利用高粘度材料对ptfe进行电纺丝 |
| CN102596534B (zh) | 2009-08-07 | 2015-04-29 | 宙斯工业产品股份有限公司 | 多层复合材料 |
| RU2581871C2 (ru) | 2011-01-28 | 2016-04-20 | Мерит Медикал Системз, Инк. | Стент, покрытый электроспряденным птфэ, и способ применения |
| TWI453312B (zh) * | 2011-02-18 | 2014-09-21 | Univ Kun Shan | 太陽能面板及光激發光元件用之有機纖維 |
| WO2012122485A2 (en) * | 2011-03-09 | 2012-09-13 | Board Of Regents Of The University Of Texas System | Apparatuses and methods for the production of fibers |
| US11623438B2 (en) | 2012-01-16 | 2023-04-11 | Merit Medical Systems, Inc. | Rotational spun material covered medical appliances and methods of manufacture |
| US9353229B2 (en) | 2012-08-14 | 2016-05-31 | Gabae Technologies Llc | Compositions incorporating dielectric additives for particle formation, and methods of particle formation using same |
| US10507268B2 (en) | 2012-09-19 | 2019-12-17 | Merit Medical Systems, Inc. | Electrospun material covered medical appliances and methods of manufacture |
| US9198999B2 (en) | 2012-09-21 | 2015-12-01 | Merit Medical Systems, Inc. | Drug-eluting rotational spun coatings and methods of use |
| CA2887914A1 (en) | 2012-10-12 | 2014-04-17 | Gabae Technologies Ulc | High dielectric compositions for particle formation and methods of forming particles using same |
| WO2014159710A1 (en) | 2013-03-13 | 2014-10-02 | Merit Medical Systems, Inc. | Serially deposited fiber materials and associated devices and methods |
| EP2967929B1 (en) | 2013-03-13 | 2017-11-29 | Merit Medical Systems, Inc. | Methods, systems, and apparatuses for manufacturing rotational spun appliances |
| EP2999809A1 (en) | 2013-05-21 | 2016-03-30 | Gabae Technologies, LLC | High dielectric compositions for particle formation and methods of forming particles using same |
| ES2989899T3 (es) | 2015-02-26 | 2024-11-28 | Merit Medical Systems Inc | Aparatos médicos en capas |
| US12310987B2 (en) | 2021-02-26 | 2025-05-27 | Merit Medical Systems, Inc. | Fibrous constructs with therapeutic material particles |
| CN119905300A (zh) * | 2022-09-28 | 2025-04-29 | 胡星维 | 一种防水耐冲击的防火电缆 |
| CN115504527A (zh) * | 2022-11-09 | 2022-12-23 | 上海纳米技术及应用国家工程研究中心有限公司 | 纳米纤维模板诱导制备三元纳米材料的方法及产品和应用 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7305569A (cs) * | 1972-04-22 | 1973-10-24 | ||
| KR20020063020A (ko) * | 2001-01-26 | 2002-08-01 | 한국과학기술연구원 | 미세 섬유상 고분자웹의 제조 방법 |
| DE102005008927A1 (de) * | 2005-02-24 | 2006-08-31 | Philipps-Universität Marburg | Hydrophobe fluorierte Polymeroberflächen |
| CZ299537B6 (cs) * | 2005-06-07 | 2008-08-27 | Elmarco, S. R. O. | Zpusob a zarízení k výrobe nanovláken z polymerního roztoku elektrostatickým zvláknováním |
| WO2007013858A1 (en) * | 2005-07-25 | 2007-02-01 | National University Of Singapore | Method & apparatus for producing fiber yarn |
| CZ299549B6 (cs) * | 2006-09-04 | 2008-08-27 | Elmarco, S. R. O. | Rotacní zvláknovací elektroda |
| CN101069821A (zh) * | 2007-03-06 | 2007-11-14 | 天津大学 | 交联改性的pvdf－hfp超细纤维膜及其制备方法 |
-
2008
- 2008-04-15 CZ CZ20080226A patent/CZ2008226A3/cs unknown
-
2009
- 2009-03-13 TW TW098108132A patent/TW200944629A/zh unknown
- 2009-04-03 WO PCT/CZ2009/000048 patent/WO2009127170A2/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| WO2009127170A2 (en) | 2009-10-22 |
| WO2009127170A3 (en) | 2009-12-03 |
| CZ2008226A3 (cs) | 2009-10-29 |
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