GB1431697A - Decorative film laminates slit fibres thereof and method for their preparation - Google Patents

Decorative film laminates slit fibres thereof and method for their preparation

Info

Publication number
GB1431697A
GB1431697A GB1909673A GB1909673A GB1431697A GB 1431697 A GB1431697 A GB 1431697A GB 1909673 A GB1909673 A GB 1909673A GB 1909673 A GB1909673 A GB 1909673A GB 1431697 A GB1431697 A GB 1431697A
Authority
GB
United Kingdom
Prior art keywords
mol percent
coating
film
copolymers
vinyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1909673A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Teijin Ltd
Original Assignee
Teijin Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP47040767A external-priority patent/JPS5143067B2/ja
Priority claimed from JP5297072A external-priority patent/JPS4910937A/ja
Priority claimed from JP47063184A external-priority patent/JPS4923271A/ja
Priority claimed from JP47087904A external-priority patent/JPS4944081A/ja
Priority claimed from JP8910772A external-priority patent/JPS4945187A/ja
Priority claimed from JP570773A external-priority patent/JPS4998477A/ja
Application filed by Teijin Ltd filed Critical Teijin Ltd
Publication of GB1431697A publication Critical patent/GB1431697A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • C08J5/124—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives using adhesives based on a macromolecular component
    • C08J5/125—Adhesives in organic diluents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • B05D5/067—Metallic effect
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
    • B05D7/04—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber to surfaces of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C09D133/16—Homopolymers or copolymers of esters containing halogen atoms
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/42—Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments
    • D01D5/426—Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments by cutting films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Laminated Bodies (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1431697 Coated film TEIJIN LTD 19 April 1973 [22 April 1972 30 May 1972 26 June 1972 4 Sept 1972 7 Sept 1972 10 Jan 1973] 19096/73 Heading B2E A decorative film comprises a synthetic resin base film having deposited thereon a metal layer and a coating formed on the metal layer of fluorine resin having a solubility such that it dissolves in 100 cc of methylethyl ketone in an amount of at least 1 g at 20‹C. A fibre may be obtained by slitting the film. An interlayer of a synthetic resin may be formed between the metal layer and the coating of the fluorine resin, between the metal layer and the synthetic resin film base, or both. The interlayer may be coloured and may be an epoxy resin or an acrylic resin. The synthetic resin base film may be a polyester, polyamide, polyimide, polyamideimide and polyolefine. The fluorine resin may be selected from (1) copolymers of not more than 50 mol percent of at least one polyfluorine-containing 2-3 C alpha-olefine and not less than 50 mole percent of at least one monomer selected from vinyl fluoride and vinylidene fluoride not more than 5 mole percent of which may be replaced by a monomer selected from vinyl esters of 1-4 C fatty acids and glycidyl methacrylate, (2) copolymers of at least 35 mol percent of at least one polyfluorinecontaining 2-3 C alpha olefine and not more than 65 mol percent of a monomer selected from vinyl chloride and vinylidene chloride not more than 5 mol percent of which may be replaced by a monomer selected from acrylic acid, 1-4 C alkyl esters thereof, methacrylic acid, 1-4 C alkyl esters thereof, vinyl fluoride and vinylidene fluoride, (3) homo- or copolymers of compounds of formula wherein R f is a perfluoroether or perfluoroalkyl having 3-12 carbon atoms, copolymers of at least 50 mol percent of at least one compound of formula and not more than 50 mol percent of at least one monomer selected from acrylic acid, 1-2 C alkyl esters thereof, methacrylic acid, 1-2 C alkyl esters thereof, vinyl esters of 1-4 C fatty acids, styrene, alpha-methyl styrene, vinyl fluoride, vinylidene fluoride, vinyl chloride, vinylidene chloride and polyfluorine-containing aplha-olefines, and (4) copolymers of units in a total amount of 100 mol percent derived from 70-85 mol percent of vinylidene fluoride, 10-25 mol percent of a polyfluorine-containing 2-3 C alpha-olefine and 5-20 mol percent of a compound of the formula wherein A is a hydrogen atom, a 1-10 C alkyl or RZ, wherein R is -(CH 2 ) n , n being 0-10, and Z is selected from CO 2 R<SP>1</SP>, SO 3 R<SP>1</SP> or PO(OR<SP>1</SP>) 2 wherein R<SP>1</SP> is selected from a hydrogen atom, 1-6 C alkyl, 1-6 C monochloroalkyl, alkali metals and ammonium, and B is selected from a hydrogen atom, 1-2 C alkyl, chlorine and RZ. The metal may be aluminium, silver, tin or gold which may be deposited on one or both surfaces of the based film. The coating of fluorine resin may be applied by doctor blade coating, brush coating, roll coating, spray coating, dip coating or gravure coating a solution of the fluorine resin in an organic solvent. An aliphatic or aromatic polyamine selected from polyalkylene polyamines, and phenylene diamines may be included in the solution. The fibres slit from the decorative film may be woven or knitted with natural, regenerated or synthetic fibres.
GB1909673A 1972-04-22 1973-04-19 Decorative film laminates slit fibres thereof and method for their preparation Expired GB1431697A (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP47040767A JPS5143067B2 (en) 1972-04-22 1972-04-22
JP5297072A JPS4910937A (en) 1972-05-30 1972-05-30
JP47063184A JPS4923271A (en) 1972-06-26 1972-06-26
JP47087904A JPS4944081A (en) 1972-09-04 1972-09-04
JP8910772A JPS4945187A (en) 1972-09-07 1972-09-07
JP570773A JPS4998477A (en) 1973-01-10 1973-01-10

Publications (1)

Publication Number Publication Date
GB1431697A true GB1431697A (en) 1976-04-14

Family

ID=27547930

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1909673A Expired GB1431697A (en) 1972-04-22 1973-04-19 Decorative film laminates slit fibres thereof and method for their preparation

Country Status (3)

Country Link
FR (1) FR2181967B1 (en)
GB (1) GB1431697A (en)
NL (1) NL7305569A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009127170A2 (en) * 2008-04-15 2009-10-22 Elmarco S.R.O. Method for production of nanofibres from fluorated copolymers and terpolymers through electrostatic spinning, nanofibres and fabrics
WO2012078956A1 (en) * 2010-12-10 2012-06-14 Ppg Industries Ohio, Inc. Polymeric substrates having a thin metal film and fingerprint resistant clear coating deposited thereon and related methods
CN102921760A (en) * 2012-10-16 2013-02-13 福建省安溪宏源工艺有限公司 Machining process for metal handicraft wire with plating layer
WO2013058333A1 (en) * 2011-10-19 2013-04-25 ダイキン工業株式会社 Surface treatment agent composition, and use thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009127170A2 (en) * 2008-04-15 2009-10-22 Elmarco S.R.O. Method for production of nanofibres from fluorated copolymers and terpolymers through electrostatic spinning, nanofibres and fabrics
WO2009127170A3 (en) * 2008-04-15 2009-12-03 Elmarco S.R.O. Method for production of nanofibres from fluorinated copolymers and terpolymers through electrostatic spinning, nanofibres and fabrics
WO2012078956A1 (en) * 2010-12-10 2012-06-14 Ppg Industries Ohio, Inc. Polymeric substrates having a thin metal film and fingerprint resistant clear coating deposited thereon and related methods
CN103249498A (en) * 2010-12-10 2013-08-14 Ppg俄亥俄工业股份有限公司 Polymeric substrates having a thin metal film and fingerprint resistant clear coating deposited thereon and related methods
WO2013058333A1 (en) * 2011-10-19 2013-04-25 ダイキン工業株式会社 Surface treatment agent composition, and use thereof
CN102921760A (en) * 2012-10-16 2013-02-13 福建省安溪宏源工艺有限公司 Machining process for metal handicraft wire with plating layer
CN102921760B (en) * 2012-10-16 2014-12-24 福建省安溪宏源工艺有限公司 Machining process for metal handicraft wire with plating layer

Also Published As

Publication number Publication date
FR2181967A1 (en) 1973-12-07
DE2320705B2 (en) 1976-08-19
FR2181967B1 (en) 1976-09-10
NL7305569A (en) 1973-10-24
DE2320705A1 (en) 1973-11-15

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee