TW200932770A - Metallocene catalysts and their use in polymerization processes - Google Patents
Metallocene catalysts and their use in polymerization processes Download PDFInfo
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- TW200932770A TW200932770A TW097137567A TW97137567A TW200932770A TW 200932770 A TW200932770 A TW 200932770A TW 097137567 A TW097137567 A TW 097137567A TW 97137567 A TW97137567 A TW 97137567A TW 200932770 A TW200932770 A TW 200932770A
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- Prior art keywords
- catalyst system
- polymer
- ethylene
- activator
- monomer
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- 238000006116 polymerization reaction Methods 0.000 title claims description 39
- 239000012968 metallocene catalyst Substances 0.000 title abstract description 46
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- 239000003054 catalyst Substances 0.000 claims abstract description 91
- 238000000034 method Methods 0.000 claims abstract description 79
- 239000012190 activator Substances 0.000 claims abstract description 52
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- 239000003446 ligand Substances 0.000 claims abstract description 38
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- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims abstract description 5
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- GELSGNUIXDWNAL-UHFFFAOYSA-H [Al+3].C(CCC)CC(=O)[O-].[Al+3].C(CCC)CC(=O)[O-].C(CCC)CC(=O)[O-].C(CCC)CC(=O)[O-].C(CCC)CC(=O)[O-].C(CCC)CC(=O)[O-] Chemical compound [Al+3].C(CCC)CC(=O)[O-].[Al+3].C(CCC)CC(=O)[O-].C(CCC)CC(=O)[O-].C(CCC)CC(=O)[O-].C(CCC)CC(=O)[O-].C(CCC)CC(=O)[O-] GELSGNUIXDWNAL-UHFFFAOYSA-H 0.000 description 1
- YJVLTVKSLWZPOB-UHFFFAOYSA-N [Cr+3].[O-2].[Ce+3].[O-2].[O-2] Chemical compound [Cr+3].[O-2].[Ce+3].[O-2].[O-2] YJVLTVKSLWZPOB-UHFFFAOYSA-N 0.000 description 1
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- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- 239000001164 aluminium sulphate Substances 0.000 description 1
- 235000011128 aluminium sulphate Nutrition 0.000 description 1
- JNDMLEXHDPKVFC-UHFFFAOYSA-N aluminum;oxygen(2-);yttrium(3+) Chemical compound [O-2].[O-2].[O-2].[Al+3].[Y+3] JNDMLEXHDPKVFC-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
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- TZIBOXWEBBRIBM-UHFFFAOYSA-N cerium(3+) oxygen(2-) titanium(4+) Chemical compound [O--].[O--].[Ti+4].[Ce+3] TZIBOXWEBBRIBM-UHFFFAOYSA-N 0.000 description 1
- DRVWBEJJZZTIGJ-UHFFFAOYSA-N cerium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Ce+3].[Ce+3] DRVWBEJJZZTIGJ-UHFFFAOYSA-N 0.000 description 1
- DFGSACBYSGUJDZ-UHFFFAOYSA-M chloro(dihexyl)alumane Chemical compound [Cl-].CCCCCC[Al+]CCCCCC DFGSACBYSGUJDZ-UHFFFAOYSA-M 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
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- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 1
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- PTCGDEVVHUXTMP-UHFFFAOYSA-N flutolanil Chemical compound CC(C)OC1=CC=CC(NC(=O)C=2C(=CC=CC=2)C(F)(F)F)=C1 PTCGDEVVHUXTMP-UHFFFAOYSA-N 0.000 description 1
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- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 125000003936 heterocyclopentadienyl group Chemical group 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
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- GSCGQEWSUMGSEY-UHFFFAOYSA-N methoxyhydrazine Chemical compound CONN GSCGQEWSUMGSEY-UHFFFAOYSA-N 0.000 description 1
- MAQCMFOLVVSLLK-UHFFFAOYSA-N methyl 4-(bromomethyl)pyridine-2-carboxylate Chemical compound COC(=O)C1=CC(CBr)=CC=N1 MAQCMFOLVVSLLK-UHFFFAOYSA-N 0.000 description 1
- DVSDBMFJEQPWNO-UHFFFAOYSA-N methyllithium Chemical compound C[Li] DVSDBMFJEQPWNO-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
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- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
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- 230000003647 oxidation Effects 0.000 description 1
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- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
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- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Chemical class C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- KHIWWQKSHDUIBK-UHFFFAOYSA-N periodic acid Chemical compound OI(=O)(=O)=O KHIWWQKSHDUIBK-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
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- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 239000010959 steel Substances 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
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- 150000003440 styrenes Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- HEPBQSXQJMTVFI-UHFFFAOYSA-N zinc;butane Chemical compound [Zn+2].CCC[CH2-].CCC[CH2-] HEPBQSXQJMTVFI-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/49—Hafnium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US99990307P | 2007-10-22 | 2007-10-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW200932770A true TW200932770A (en) | 2009-08-01 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW097137567A TW200932770A (en) | 2007-10-22 | 2008-09-30 | Metallocene catalysts and their use in polymerization processes |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8598287B2 (OSRAM) |
| EP (1) | EP2207618B1 (OSRAM) |
| JP (1) | JP5544294B2 (OSRAM) |
| CN (1) | CN101842158B (OSRAM) |
| CL (1) | CL2008003100A1 (OSRAM) |
| ES (1) | ES2624753T3 (OSRAM) |
| RU (1) | RU2455316C2 (OSRAM) |
| TW (1) | TW200932770A (OSRAM) |
| WO (1) | WO2009054889A2 (OSRAM) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200932762A (en) * | 2007-10-22 | 2009-08-01 | Univation Tech Llc | Polyethylene compositions having improved properties |
| CN103319810B (zh) * | 2013-06-17 | 2016-06-15 | 内蒙古亿利塑业有限责任公司 | 沙柳/聚氯乙烯木塑复合材料及其制作方法 |
| CN104736579A (zh) | 2013-06-28 | 2015-06-24 | 株式会社Lg化学 | 弹性二烯三元共聚物及其制备方法 |
| KR101585204B1 (ko) | 2013-06-28 | 2016-01-13 | 주식회사 엘지화학 | 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법 |
| EP2883891A4 (en) | 2013-06-28 | 2016-06-01 | Lg Chemical Ltd | TERNARY ELASTOMER COPOLYMER WITH A DIEN AND METHOD FOR THE PRODUCTION THEREOF |
| WO2014209082A1 (ko) | 2013-06-28 | 2014-12-31 | 주식회사 엘지화학 | 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법 |
| JP6201853B2 (ja) * | 2014-03-25 | 2017-09-27 | 日本ポリプロ株式会社 | メタロセン錯体及びオレフィン重合体の製造方法 |
| KR101617870B1 (ko) * | 2014-09-05 | 2016-05-03 | 주식회사 엘지화학 | 가공성이 우수한 올레핀계 중합체 |
| SG11201708626SA (en) * | 2015-04-27 | 2017-11-29 | Univation Tech Llc | Supported catalyst compositions having improved flow properties and preparation thereof |
| US11193008B2 (en) | 2017-04-10 | 2021-12-07 | Exxonmobil Chemical Patents Inc. | Methods for making polyolefin polymer compositions |
| EP3621996B1 (en) * | 2017-05-10 | 2023-01-18 | Univation Technologies, LLC | Catalyst systems and processes for using the same |
| WO2020078932A1 (en) * | 2018-10-15 | 2020-04-23 | Total Research & Technology Feluy | Polyethylene resins |
| KR102285140B1 (ko) * | 2018-12-03 | 2021-08-02 | 한화솔루션 주식회사 | 올레핀 중합용 촉매의 제조방법 |
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| US5281679A (en) * | 1991-11-07 | 1994-01-25 | Exxon Chemical Patents Inc. | Catalyst and method of broadening polymer molecular weight distribution and increasing polymer tensile impact strength and products made thereof |
| DE69422410T2 (de) * | 1993-08-06 | 2000-07-06 | Exxon Chemical Patents, Inc. | Polymerisationskataylsatoren, ihre herstellung und verwendung |
| UA47394C2 (uk) * | 1995-05-16 | 2002-07-15 | Юнівейшн Текнолоджіз, Ллс | Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер |
| US6339134B1 (en) * | 1999-05-06 | 2002-01-15 | Univation Technologies, Llc | Polymerization process for producing easier processing polymers |
| ATE309259T1 (de) | 2000-06-30 | 2005-11-15 | Exxonmobil Chem Patents Inc | Überbrückte bisindenylmetallocenverbindungen |
| CA2430197C (en) * | 2000-12-04 | 2008-02-12 | Univation Technologies, Llc | Polymerization process |
| US6960634B2 (en) * | 2001-10-31 | 2005-11-01 | Univation Technologies, Llc | Methods for adjusting melt properties of metallocene catalyzed olefin copolymers |
| US6841504B2 (en) * | 2002-01-28 | 2005-01-11 | Univation Technologies, Llc | Polymerization catalyst activator and its use in a polymerization process |
| US6806328B2 (en) | 2002-01-28 | 2004-10-19 | Univation Technologies, Llc | Polymerization catalyst activator complexes and their use in a polymerization process |
| US7319125B2 (en) | 2002-09-20 | 2008-01-15 | Exxonmobil Chemical Patents Inc. | Supercritical polymerization process and polymers produced therefrom |
| WO2004046214A2 (en) | 2002-10-15 | 2004-06-03 | Exxonmobil Chemical Patents Inc. | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
| US7223822B2 (en) * | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| US7265193B2 (en) * | 2003-01-31 | 2007-09-04 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| US6958306B2 (en) * | 2003-08-28 | 2005-10-25 | Univation Technologies, Llc | Activated catalyst systems from substituted dialuminoxane complexes |
| US7244795B2 (en) * | 2003-12-08 | 2007-07-17 | Univation Technologies, Llc | Polymerization process using metallocene catalyst systems |
| US7741417B2 (en) * | 2004-01-07 | 2010-06-22 | Exxonmobil Chemical Patents Inc. | Preparation of polymerization catalyst activators utilizing indole-modified silica supports |
| WO2007106238A1 (en) * | 2006-03-02 | 2007-09-20 | Exxonmobil Chemical Patents Inc. | Process for producing propylene copolymers |
| TW200932762A (en) * | 2007-10-22 | 2009-08-01 | Univation Tech Llc | Polyethylene compositions having improved properties |
-
2008
- 2008-09-30 TW TW097137567A patent/TW200932770A/zh unknown
- 2008-10-09 RU RU2010120469/04A patent/RU2455316C2/ru active
- 2008-10-09 US US12/739,308 patent/US8598287B2/en active Active
- 2008-10-09 WO PCT/US2008/011607 patent/WO2009054889A2/en not_active Ceased
- 2008-10-09 JP JP2010530999A patent/JP5544294B2/ja not_active Expired - Fee Related
- 2008-10-09 CN CN200880112554.3A patent/CN101842158B/zh active Active
- 2008-10-09 EP EP08842160.7A patent/EP2207618B1/en active Active
- 2008-10-09 ES ES08842160.7T patent/ES2624753T3/es active Active
- 2008-10-20 CL CL2008003100A patent/CL2008003100A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RU2455316C2 (ru) | 2012-07-10 |
| US8598287B2 (en) | 2013-12-03 |
| JP5544294B2 (ja) | 2014-07-09 |
| CN101842158B (zh) | 2015-10-21 |
| CL2008003100A1 (es) | 2009-03-06 |
| JP2011500937A (ja) | 2011-01-06 |
| WO2009054889A3 (en) | 2010-06-17 |
| EP2207618B1 (en) | 2017-03-08 |
| ES2624753T3 (es) | 2017-07-17 |
| EP2207618A2 (en) | 2010-07-21 |
| RU2010120469A (ru) | 2011-11-27 |
| WO2009054889A2 (en) | 2009-04-30 |
| CN101842158A (zh) | 2010-09-22 |
| US20100298511A1 (en) | 2010-11-25 |
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