TW200830985A - Paper-made agricultural coating material - Google Patents

Paper-made agricultural coating material Download PDF

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Publication number
TW200830985A
TW200830985A TW096133908A TW96133908A TW200830985A TW 200830985 A TW200830985 A TW 200830985A TW 096133908 A TW096133908 A TW 096133908A TW 96133908 A TW96133908 A TW 96133908A TW 200830985 A TW200830985 A TW 200830985A
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Taiwan
Prior art keywords
oil
paper
wax
japan
dry
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TW096133908A
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Chinese (zh)
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TWI387435B (en
Inventor
Yutaka Nishida
Yoshiaki Takagi
Yasushi Kametani
Satoshi Fukumoto
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Nisshin Oillio Group Ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G13/00Protecting plants
    • A01G13/02Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
    • A01G13/0256Ground coverings
    • A01G13/0268Mats or sheets, e.g. nets or fabrics
    • A01G13/0275Films
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G13/00Protecting plants
    • A01G13/02Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings

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  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Protection Of Plants (AREA)
  • Paper (AREA)
  • Catching Or Destruction (AREA)

Abstract

To provide a paper-made agricultural coating material having high safety, and strength enough to accept machine wiring without spoiling function as an agricultural coating material. The paper-made agricultural coating material is obtained by adding an oil-and-fat composition containing drying oil, semi-drying oil and wax which is solid at normal temperature and has a melting point of < 100 DEG C by including it to part or the whole of paper degradable in the soil, wherein the compounding ratio (pts.mass) of the composition is as follows: the drying oil:the semi-drying oil:the wax = 1.0: ≤ 1.0: ≤ 0.3.

Description

200830985 九、發明說明: 【發明所屬之技術領域】 本發明係關於一種紙製農業用被覆材,特別是關於一 種在農作物育成方面具有必要機能,同時亦具有可由機械 展開之強度,而以紙作為骨材之紙製農業用被覆材。 【先前技術】200830985 IX. INSTRUCTIONS OF THE INVENTION: TECHNICAL FIELD The present invention relates to a paper agricultural covering material, and more particularly to a function capable of growing crops, and also having mechanical strength, and using paper as a Paper-based agricultural coverings for aggregates. [Prior Art]

作為農業用資材的被覆材正逐漸形成很大的市場。其 目的在於藉由遮蔽光線以抑制雜草生長、調整地溫,且發 揮保持土壤水分、防止土壤浸蝕、防止肥料流失、抑制病 蟲害發生等之效果,而可有助於作物的生長發育。 目前,聚乙烯膜等之聚烯烴類薄膜成為主流,透明、 黑色、綠色等依用途而著色之薄膜廣為使用。聚烯烴類之 薄膜,具有價格便宜、重量輕、保存時之劣化較少等優點, 又,其關於作物生長發育之問題亦少,甚至成為對農家而 言不可或缺的資材。 但是,此聚乙烯膜等之聚烯烴類薄膜的最大缺點,乃 是其無法分解於土壤中。亦即,使用後須以機械或人工將 其捲繞、回收,這項回收作業對體力與金錢均為龐大負擔。 又,在這些回收作業中,碎屑總會殘留在土壤中,而 永久殘留於農地。作為回收後被覆材之處置而許可至今的 燃燒處理,也隨著法律修正而轉為禁止田間焚燒,因此所 回收之使用完畢的薄膜也不得不加以妥善處置。如此則在 處理的場所方面會產生問題,其處理費用也對於農家之經 5Covering materials as agricultural materials are gradually forming a large market. The purpose is to help crop growth and development by masking light to suppress weed growth, adjust ground temperature, and maintain soil moisture, prevent soil erosion, prevent fertilizer loss, and inhibit the occurrence of diseases and insect pests. At present, polyolefin-based films such as polyethylene films have become mainstream, and films which are colored according to the use such as transparent, black, and green are widely used. Polyolefin films have the advantages of being inexpensive, light in weight, and less deteriorated during storage. Moreover, they have few problems with regard to crop growth and development, and even become indispensable materials for farmers. However, the biggest disadvantage of the polyolefin film such as the polyethylene film is that it cannot be decomposed into the soil. That is to say, it must be wound up and recycled mechanically or manually after use. This recycling operation is a huge burden on both physical strength and money. Also, in these recycling operations, the debris always remains in the soil and remains permanently in the agricultural land. The combustion treatment that has been approved since the disposal of the recovered coating material has been changed to prohibit field burning with legal amendments, so that the used film that has been recovered must be disposed of properly. In this way, problems will arise in the place where the treatment is carried out, and the processing cost is also for the farmer's experience.

200830985 營造成很大的衝擊。 更且,雖然亦提出將土去除以再利用 決此問題,但其具有無法完全將土除去, 展開此被覆材,則若不整齊地捲繞則次年 的大問題,因此實際上關於再利用方面遲这 作為其解決方法,利用生物可分解高 開發正逐步進行中。實際上,使用澱粉類 多生物可分解高分子所生產之農業用被覆 別是必須在夏季進行回收作業之玉米栽培 始利用這些可直接將其鋤入土中之商材。 然而,以生物可分解高分子製造之被 於價格昂貴,以至於在市場上尚未能佔有 若為生物可分解高分子,則由於保存期間 而會有在流通上無法持有庫存之重大課題 離實用化尚有很大之困難。 同樣是在土中容易分解之材料,許多 材的開發亦正進行中。特別是若使用紙, 即使保存於倉庫也不會隨時間劣化,其在 上,相較於生物可分解高分子亦非常有利 紙之農業用被覆材已經在各地的農業試驗 用(紙製農業用被覆材,一般亦稱覆蓋紙薦 覆蓋物(mulching))。 然而,紙的最大缺點,在於其會因隨 線、熱等以及雨、風而加速劣化,且其與 的方法而應可解 以及如欲以機械 度將無法使用等 I無法有所進展。 分子之被覆材的 、聚乳酸類等許 材已經上市,特 ,有一部分已開 覆材,其瓶頸在 一席之地。又, 内會持續劣化, ,不得不謂其距 使用紙作為被覆 則由於在流通上 作為商品之價值 。實際上,使用 場供實用試驗使 (mulch sheet)或 曰照發生之紫外 土接觸部分的崩 6The 200830985 battalion caused a big impact. Furthermore, although it is also proposed to remove the soil for reuse, it is impossible to completely remove the soil, and if the covering material is unfolded, if it is not wound neatly, the next year will be a big problem, so actually it is about recycling. In terms of its lateness as a solution, the use of biodegradable high development is gradually being carried out. In fact, the agricultural use produced by the use of starchy multi-biodegradable polymers is the cultivation of corn which must be recycled in the summer and the use of these materials which can be directly poured into the soil. However, the manufacture of biodegradable polymers is so expensive that it is not yet commercially available as a biodegradable polymer, and there is a major problem that it is impossible to hold inventory in circulation due to the preservation period. There are still great difficulties in practical use. It is also a material that is easily decomposed in the soil, and the development of many materials is also in progress. In particular, if paper is used, it will not deteriorate over time even if it is stored in a warehouse. It is also very advantageous for bio-decomposable polymers. Paper-coated agricultural materials have been used in agricultural trials in various places (for paper agriculture). Covering material, generally referred to as covering paper mulching. However, the biggest disadvantage of paper is that it will accelerate deterioration due to randomness, heat, etc., as well as rain and wind, and its method should be solvable and if it is not mechanically usable, I cannot make progress. Molecular coated materials, polylactic acid and other materials have been put on the market, and some have been opened, and their bottlenecks are in a place. In addition, the inside will continue to deteriorate, and it has to be said that it is used as a cover from the use of paper, because it is the value of the product in circulation. In fact, the field is used for practical tests to make the mulch sheet or the UV-contact portion of the exposure to collapse.

200830985 壞劇烈,而在等到農作物生長發育之前即逐漸劣化、 又,若其有缺陷則容易裂開,因此難以利用機械展 際上在農家使用時,並不甚耐用,此為目前的實際 為解決此問題,目前正探討使其與土接觸部分 黴劑及/或抗菌劑之方法(參照專利文獻1 ),以及利 溝紋(flute)加工或塵紋(emboss)加工來減少與土壤 面積、延遲分解之試行(參照專利文獻 2)等。又, 由使紙製被覆材含有耐水、排水效果高且較易處理 油,而延遲農作物育成中被覆材之分解劣化的提案 專利文獻3)。 [專利文獻1]曰本特開平9-20590 1號公報 [專利文獻2]日本特開平1 0-943 3 5號公報 [專利文獻3]日本特開2000- 1 1 6249號公報 【發明内容】 [發明所欲解決之問題] 然而,若是以往之紙製農業用被覆材,則其會琴 安全性、強度等方面之問題。例如,若以專利文獻 利文獻2而言,其均關係到成本昂貴,且亦無法得 本相對應之強度;又,若以專利文獻3而言,其即 了成本面的問題卻仍無法得到強度,故並未實用化 因此,本發明之目的在於提供一種紙製農業 材,其無損於作為農業用被覆材之機能且安全性高 有能以機械展開之強度。 .崩壞。 開,實 情況。 含有防 用進行 的接觸 亦有藉 之乾性 (參照 成本、 1及專 到與成 使解決 〇 用被覆 ,並具 7 200830985 [解決問題之技術手段] 本發明為了達到上述目的,而提供一種紙製農業用被 覆材,其係使可分解於土中之紙的一部分或全體,含有油 脂組成物而構成,該油脂組成物含有乾性油、半乾性油、 及常溫下為固體且熔點小於1 0 0 °c之蠟,且其混合比例(質 量比)為乾性油:半乾性油··壤=1.0 : 1.0以下·· 0.3以下。200830985 is bad and violent, and it gradually deteriorates before the growth of crops, and if it is defective, it is easy to crack, so it is difficult to use the mechanical exhibition when it is used in farmhouses, it is not very durable, this is the current actual solution. This problem is currently being explored to contact some soil molds and/or antibacterial agents (see Patent Document 1), as well as flute processing or emboss processing to reduce soil area and delay. Trial of decomposition (see Patent Document 2) and the like. In addition, it is proposed that the paper-coated material contains water-resistant, high-drainage effect, and is easy to handle oil, and delays decomposition and deterioration of the covering material during crop growth. Patent Document 3). [Patent Document 1] Japanese Laid-Open Patent Publication No. Hei. No. 2000-161. [Problems to be Solved by the Invention] However, in the case of conventional paper-based agricultural covering materials, there are problems in terms of safety, strength, and the like. For example, in the case of Patent Document 2, both of them are costly and cannot achieve the corresponding strength; and, in Patent Document 3, the problem of cost is still not available. Since the strength is not practical, it is therefore an object of the present invention to provide a paper agricultural material which is not detrimental to the function as an agricultural covering material and which has high safety and mechanical strength. . Collapsed. Open, the actual situation. Contact with anti-use is also dry (refer to cost, 1 and specialization and application to solve the problem, and has 7 200830985 [Technical means for solving the problem] The present invention provides a paper system for the above purpose An agricultural coated material comprising a part or the whole of a paper which can be decomposed in soil, and comprising a fat or oil composition containing a dry oil, a semi-drying oil, and a solid at a normal temperature and having a melting point of less than 1 0 0 The wax of °c, and the mixing ratio (mass ratio) thereof is a dry oil: semi-drying oil · soil = 1.0 : 1.0 or less · · 0.3 or less.

又,本發明為了達成上述目的,而提供一種紙製農業 用被覆材,其特徵係在可分解於土中之紙的一部分或全體 的任意部位,含有乾性油、半乾性油、及常溫下為固體且 熔點小於 1 00°c之蠟,且其含有質量比為乾性油··半乾性 油:蠟=1.0 : 1.0以下:0 · 3以下。 [功效] 藉由本發明,則能提供一種紙製農業用被覆材,其無 損於作為農業用被覆材之機能且安全性高,並具有能以機 械展開之強度。 【實施方式】 [實施發明的較佳形態] [關於本發明的實施形態之紙製農業用被覆材] 關於本發明的實施形態之紙製農業用被覆材,其在可 分解於土中之紙的一部分或全體,含有油脂組成物而構 成,該油脂組成物含有乾性油、半乾性油、及常溫下為固 8 200830985 〇〇 體且熔點小於10()V 油··半乾性油:蠟二之%,且其混合比例(質量比)為乾性 分解於土中之紙故I·0 · i·0以下:〇·3以下。也可以使可 為乾性油:半乾=、部分或全體,含有混合比例(質量比) 性油的油脂組成=油H〗·0以下之含有乾性油與半乾 含有與乾性油之斯=谈,再使該紙之含油脂级成物部分, 藉此 貝星比為1.0:0.3以下的蠟。 曰0,可得到— 土中之乾的一部分:種紙製農業用被覆材’其在可分解於 性油、及常溫下刀气全體的任意部位’含有乾性油、半乾 質量比為乾:油為:體且溶點小於丨帆之蠟’且其含有 以下 半乾性油:蠟 (紙製農業用被覆材) 本發明中所袖沾 i Φ ^ ^ 明的紙製農業用被覆材,意指以γ八g # 土中之轶所製作的 了刀解於 被覆材,音扑在卷用被覆材。本發明中所謂的農業用 之土壤表面:的心農作物…被覆於農作物以外部分 外部分之土壌表面由於農業用被覆材覆蓋於農作物以 土壤水八“,可有抑制雜草生長、調整地溫、保持 土 m水分、防止土瓖 展以蝕、防止肥料流失、抑制病蟲害發 :果,而破用以幫助農作物生長發育。又,本發明中 辰業被覆材亦被稱為覆蓋紙蓆(mulch sheet)或覆蓋 物(mulching) 〇 (乾性油) 所謂的乾性油,係表示在使用植物油於塗料、墨水中 9 200830985 時’被歸類為易於氧化聚合之物者。在定義上,係表示碘 價為1 3 0以上者,一般有亞麻仁油、紅花籽油、大豆油、 桐油、匍萄籽油、胡桃油、月見草油、芬子油、大麻籽油 (hempseed oil)等,學術上則相當於漆樹核果油、石榴籽 油、菸草籽油等。這些乾性油,可使用1種或2種以上。 (半乾性油)Moreover, in order to achieve the above object, the present invention provides a paper agricultural covering material which is characterized in that it contains dry oil, semi-dry oil, and at room temperature in any part of the paper which can be decomposed in the soil or all of the paper. A wax having a solid content and a melting point of less than 100 ° C, and having a mass ratio of a dry oil··semi-drying oil: wax=1.0: 1.0 or less: 0·3 or less. [Effect] According to the present invention, it is possible to provide a paper agricultural covering material which is not detrimental to the function as an agricultural covering material and which has high safety and has mechanical strength. [Embodiment] [Preferred Embodiment of the Invention] [Paper-made agricultural covering material according to an embodiment of the present invention] A paper agricultural covering material according to an embodiment of the present invention is a paper which can be decomposed in soil. A part or the whole of the oil composition comprising a dry oil, a semi-drying oil, and a solid at room temperature, 200810985, and having a melting point of less than 10 () V oil · semi-drying oil: wax two %, and the mixing ratio (mass ratio) is dry-decomposed into the paper in the soil, so I·0 · i·0 or less: 〇·3 or less. It can also be made into a dry oil: semi-dry =, partial or whole, containing a mixture of ratios (mass ratio) of oil and fat composition = oil H 〗 8.0 below the dry oil and semi-dry and dry oil = Talk And then, the paper contains a grease-containing fraction, whereby the ratio of the shellfish is 1.0:0.3 or less.曰0, available - part of the dryness in the soil: the paper-based agricultural coating material 'in any part that can be decomposed into the oil and at the normal temperature, the whole part of the knife gas' contains dry oil, and the dry mass ratio is dry: The oil is: the body and the melting point is smaller than the wax of the sails' and it contains the following semi-drying oil: wax (paper agricultural covering material). The paper agricultural covering material which is sleeved in the invention is Φ ^ ^ It refers to a knife made of γ 八g #土中轶, which is made of a knife, and the sound is applied to the coated material. The so-called agricultural soil surface of the present invention: the surface of the soil that is covered by the outer part of the crop, the surface of the soil covered with the agricultural covering material is covered with the soil water, and the weed growth can be suppressed, and the ground temperature can be adjusted. Maintain soil moisture, prevent soil erosion, prevent fertilizer loss, inhibit pests and diseases: fruit, and break to help grow crops. In addition, the present invention is also called mulch sheet. ) or covering (mulching oil) 干 (drying oil) The so-called dry oil is expressed in the use of vegetable oil in paints and inks 9 200830985 'is classified as easy to oxidize and polymerize. By definition, it means iodine price For those above 130, there are generally linseed oil, safflower seed oil, soybean oil, tung oil, glutinous seed oil, walnut oil, evening primrose oil, fennel oil, hempseed oil, etc. In the lacquered stone, pomegranate seed oil, tobacco seed oil, etc. These dry oils can be used in one or more types. (Semi-drying oil)

所謂的半乾性油,係指同樣在塗料領域中,雖然不像 乾性油般容易地氧化聚合而形成被膜,但會隨時間經過而 逐漸聚合,而可與通常完全不乾燥之不乾性油明確區分 者。在定義上,係表示碘價1 〇〇以上、小於13 0者,有麻 油、棉籽油、玉米油、菜耔油、米油、扁桃仁油(almond oil) 等’學術上則相當於杏核仁油(apricot oil)、撥軒油等。這 些半乾性油,可使用1種或2種以上。 (蠟) 所謂的蠟,係在常溫下為固形物者,而並無明確之定 義,在本實施之形態中,則將常溫(20〜35 °C )下為固體且熔 點小於1 00°C之有機化合物定義為蠟。符合這些條件者, 有堪地里拉蠟(Candelilla wax)、棕櫚蠟(carnauba wax)、 米糠蠟、荷荷芭油(jojoba oil)、木蠟、羊毛脂(lanolin)、 蜜蠟、褐煤蠟(montan wax)、地蠟(ceresin)、石蠟' 微晶蠟 (microcrystalline wax)、氫化蓖麻油(hydrogenated castor oil)等。這些蠟可使用1種或2種以上。 10 200830985 (油I旨組成物之組合) 乾性油、半乾性油、樣之組合並未特別限定,而有許 多種組合。由於這些物質是以自然產物為原料,其價格會 依狀況而有很大變動,因此最好能應當時之情勢而變更 之。其中,從最適合於乾燥作業之觀點而言,以乾性油為 亞麻仁油、半乾性油為菜籽油、蠟為石蠟之組合為佳。The term "semi-drying oil" refers to the same in the field of coatings. Although it is not easily oxidized and polymerized to form a film like a dry oil, it will gradually polymerize over time, and can be clearly distinguished from the dry oil which is usually not dried at all. By. In terms of definition, it means that the iodine value is more than 1 、 and less than 13 0. There are sesame oil, cottonseed oil, corn oil, rapeseed oil, rice oil, almond oil, etc. Apricot oil, dial Xuan oil, etc. These semi-drying oils may be used alone or in combination of two or more. (Wax) The so-called wax is a solid substance at normal temperature and is not clearly defined. In the embodiment of the present embodiment, it is solid at normal temperature (20 to 35 ° C) and has a melting point of less than 100 ° C. The organic compound is defined as a wax. Those who meet these conditions are Candelilla wax, carnauba wax, rice bran wax, jojoba oil, wood wax, lanolin, beeswax, montan wax (montan) Wax), celesin, paraffin' microcrystalline wax, hydrogenated castor oil, and the like. These waxes may be used alone or in combination of two or more. 10 200830985 (Combination of oil I composition) Dry oil, semi-dry oil, and the combination of the samples are not particularly limited, and there are many combinations. Since these substances are based on natural products, the price will vary greatly depending on the situation, so it is best to change them in a timely manner. Among them, from the viewpoint of the most suitable drying operation, it is preferred that the dry oil is linseed oil, the semi-dry oil is rapeseed oil, and the wax is a combination of wax and wax.

(油I旨組成物之混合比例) 為保持能以機械展開之強度,紙所含有之油脂組成物 中的乾性油、半乾性油、壤之混合比例相當重要。亦即, 將其混合比(質量比)設成乾性油:半乾性油··瑕=1.0 ·· 1.0 以下:0.3以下。若超過半乾性油與蠟之混合上限,則在 乾燥步驟將會引起裂化等問題。乾性油:半乾性油:蠟= 1 · 0 : 1 · 0以下:0 · 2以下較佳,而乾性油:半乾性油:蠟= 1,0: 0.9以下:0.15以下為更佳。 下限值雖無限定,但其混合比例(質量比)以乾性油: 半乾性油:壌=1.0 : 0 · 6以上:0 · 0 3以上為佳。半乾性油 與蠟之混合比例近似於 0時,以機械展開之強度將會低 下,因此實際應用上,合適的下限值以如上述設定者為佳。 因塗佈於紙之狀況(含有量),而亦會出現些許差異。乾性 油:半乾性油··填=1.0 ·· 0.6以上·· 0.0 5以上者較佳,而 乾性油:半乾性油:蠟=1 · 0 : 0 · 7以上:0.0 7以上者為更 佳。 11(Oil I composition ratio of the composition) In order to maintain the strength of mechanical expansion, the mixing ratio of the dry oil, the semi-dry oil, and the soil in the oil and fat composition contained in the paper is important. In other words, the mixing ratio (mass ratio) is set to dry oil: semi-drying oil··瑕=1.0 ·· 1.0 or less: 0.3 or less. If the upper limit of mixing of the semi-drying oil and the wax is exceeded, problems such as cracking will occur in the drying step. Dry oil: semi-drying oil: wax = 1 · 0 : 1 · 0 or less: 0 · 2 or less is preferred, and dry oil: semi-drying oil: wax = 1,0: 0.9 or less: 0.15 or less is more preferable. Although the lower limit is not limited, the mixing ratio (mass ratio) is dry oil: semi-drying oil: 壌 = 1.0 : 0 · 6 or more: 0 · 0 3 or more is preferable. When the mixing ratio of the semi-drying oil and the wax is approximately 0, the strength of the mechanical unwinding will be low, so that the practical lower limit is preferably set as described above. There are also some differences due to the condition (content) applied to the paper. Dry oil: semi-drying oil ··filling =1.0 ·· 0.6 or more · 0.0 5 or more is preferred, and dry oil: semi-drying oil: wax = 1 · 0 : 0 · 7 or more: 0.0 7 or more is better . 11

200830985 根據上述,相對於乾性油1 0 0質量份,以 設為60〜100質量份、蠟設為3〜30質量份之比 為佳。此外,將紙著色而稍加使用顏料等亦可 (紙製農業用被覆材中之油脂組成物的含量) 紙製農業用被覆材中之油脂組成物的含量 特別限定,但以相對於紙之乾燥質量,為2〜20 佳,以2〜10質量%者為較佳,以4〜8質量%者 製農業用被覆材中之油脂組成物的含量,若設 内,則被覆材將在農作物之育成中不分解劣化 作為被覆材之機能,又,其在機械展開之作業 良好之物。若厚塗則雖能提升強度,但由於原 量亦增大,而可能導致作業性不佳。 在此所謂的含有,並不僅限於塗佈於紙表 使紙製農業用被覆材含有油脂組成物之方法, 泡、塗佈(塗刷)、喷塗、印刷等。工業上較偏 或浸泡後使其乾燥之步驟。 油脂組成物,係含於紙之一部分或全體。 分,乃是特指埋於土中之邊緣部分或與土壤接 (紙) 作為可使用之紙,係指所謂以木漿做為原丨 維為主體之紙),而可分解於土中之紙。亦即, 漿為原料而將其分散於水中後,經脫水、乾燥 將半乾性油 例(質量比) ,雖然並無 質量%者為 為特佳。紙 於上述範圍 而能保持其 性上亦成為 紙本身之質 面。亦即, 可舉出如浸 好採用印刷 所謂的一部 觸之部分。 14之紙(以纖 可使用以木 使纖維纏繞 12In the above, it is preferable that the ratio is from 60 to 100 parts by mass and the wax is from 3 to 30 parts by mass based on 100 parts by mass of the dry oil. In addition, the content of the oil and fat composition in the paper agricultural covering material may be particularly limited, but it is relative to paper. The dry mass is preferably 2 to 20, preferably 2 to 10% by mass, and the content of the oil and fat composition in the agricultural coating material is 4 to 8 mass%, and if it is set, the coated material is in the crop. In the breeding process, the function of the coating material is not decomposed and deteriorated, and the operation of the machine is good. If the thick coating is used, the strength can be increased, but the original amount is also increased, which may result in poor workability. The term "containing" as used herein is not limited to a method of applying a grease composition to a paper agricultural covering material, such as foaming, coating (painting), spraying, printing, or the like. The step of drying it in the industry or drying it after soaking. The oil composition is contained in one part or the whole of the paper. The point is the paper that is buried in the edge of the soil or connected to the soil (paper) as a usable paper, which refers to the so-called wood pulp as the main paper, and can be decomposed into the soil. paper. That is, after the slurry is used as a raw material and dispersed in water, the semi-drying oil (mass ratio) is dehydrated and dried, although it is not particularly good. The paper's ability to maintain its properties in the above range also becomes the quality of the paper itself. That is, a part called "touch" which is printed by dipping is mentioned. 14 paper (with fiber can be used to make fiber winding 12

200830985 而成之物。例如可舉出牛皮紙、報紙、塗料 paper)、道林紙(上質紙,woodfree paper)、肯特会 麻紙(kenaf paper)等。使用再生紙漿亦可。至於 法分解之以合成樹脂類接著劑壓著而成的不織布 於其在農地中無法分解而不希望使用。 [本發明實施形態之效果] 根據本發明之實施形態,可達到以下效果。 (1) 由於在農作物育成期間不易分解劣化,而 物育成期間(例如 1個月〜3個月)保持其作為被 能。200830985 made of things. For example, kraft paper, newspaper, paint paper, wood free paper, kenaf paper, and the like can be mentioned. It is also possible to use recycled pulp. As for the decomposition of the method, a non-woven fabric which is pressed by a synthetic resin-based adhesive agent cannot be decomposed in agricultural land and is not intended to be used. [Effect of the embodiment of the present invention] According to the embodiment of the present invention, the following effects can be obtained. (1) Since it is not easy to decompose and deteriorate during the cultivation of crops, it is maintained as a function during the breeding period (for example, 1 month to 3 months).

(2) 由於作物收成後將其埋入土中即可分解, 農作物收成後加以回收或廢棄,而可減輕回收作I (3) 可提供具有能以機械展開之伸張性、強度 業用被覆材。藉由調整乾性油、半乾性油、蠟之 可調整以機械展開之強度,且在使用中與土接觸 定期間維持其強度,因此可耐用於實際的農業現 (4) 由於其為以紙為基材而含有乾性油、半乾 之物,而可提供較便宜之生物分解性被覆材。 (5) 由於其使用安全性高之乾性油、半乾性油 些物質塗佈於紙表面可延遲其與土壤接觸所致之 其能抗雨水,具有防止雨滴所致之崩壞的效果。 (6) 可提供在流通上易於庫存保管之農業用# (coated 、和紙、 在土中無 等,則由 能在農作 覆材之機 故不需於 t之負擔。 之紙製農 比例,而 亦能在一 場上。 性油及蠟 、壤,這 分解,且 L覆材。 13(2) It can be decomposed after being buried in the soil after harvesting, and the crops can be recycled or discarded after harvesting, and the recycling can be reduced. I (3) It can provide mechanically stretchable and strength-used covering materials. By adjusting the strength of the oil, semi-drying oil and wax to adjust the mechanical expansion, and maintaining its strength during contact with the soil during use, it can be used for practical agriculture (4) because it is paper The base material contains a dry oil and a semi-dry material, and a biodegradable covering material which is relatively inexpensive can be provided. (5) Due to its high safety, dry oil and semi-dry oil can be applied to the surface of paper to delay the contact with the soil. It is resistant to rain and has the effect of preventing collapse caused by raindrops. (6) It is possible to provide agricultural use # (coated, paper, and soil in the soil, which can be used in farming, and therefore does not need to bear the burden of t. It can also be in a field. Sex oil and wax, soil, which decomposes, and L is covered. 13

200830985 [實施例] (實施例1〜4 ) 如下所述,製造表1所示之含有所混合的油 之實施例1〜4的紙製農業用被覆材。 將表1之所混合的油脂組成物(塗佈油)於槽 於各自之蠟熔點以上加熱融解後混合至均勻為 油、半乾性油、壤之混合比例,各相對於乾性油 份,將半乾性油設為8 0質量份、蠟設為1 0質量 以此油脂組成物將牛皮紙的兩面浸泡後,使 在本實施例1〜4中,分別使油脂組成物相對於原ϊ 質量%(實施例1)、6,5質量%(實施例2)、4.8質 例3)、5·6質量%(實施例4)。 (比較例1 ) 如下所述,製造表1所示之含有所混合的油 之比較例1的紙製農業用被覆材。 在比較例 1,以不乾性油之山茶油與棕櫚蠟 將牛皮紙的兩面浸泡後,使之乾燥。山茶油與棕 合比例,係將山茶油設為1 8 0質量份、棕櫚蠟設J 份。相對於原紙,使油脂組成物佔5 8.7質量%。 然而,比較例1之紙製農業用被覆材,在之 步驟中完全無法乾燥,紙的表面滲出油脂,若將 繞則油脂將緊黏在一起。如此則無法捲繞於展 械,非常難以使用。 脂組成物 中調合, 止。乾性 100質量 份。 之乾燥。 ^而佔5.0 量%(實施 脂組成物 的混合物 櫚蠟之混 &amp; 10質量 後的處理 其直接捲 開用之機 14 200830985 t气」„·] 乏jgja成物之混合 乾性油 半乾性油 蠟 實施例1 紅花籽油 棉轩油 掠櫚壤 ' ' ~ (CERARICA NODA株式會社製,商品名:棕櫚蠟) 實施例2 亞麻仁油 菜籽油 ' ' (曰本精蠟株式會社製,商品名:pALVAX-1230) 實施例3 大豆油 玉米油 蜜蠟 — (CERARICANODA株式會社製,商品名:密罐、 實施例4 桐油 米油 米糠壌 一 --- (小倉合成工業株式會社製,商品名:米糠勒 比較例1 使用山茶油(不乾性油) 棕櫚蠟 &quot;----- (CERARICANODA株式會社製,商品名:棕櫚蠟) 在表1中,使用紅花籽油(曰清奥利友株式會社製,商 品名:曰清紅花油)、亞麻仁油(曰清奥利友株式會社製, 商品名:N/B亞麻仁油)、大豆油(曰清奥利友株式會社製, 商品名.大豆白絞油(S))、桐油(Cosmo油化株式會社製, 商品名:桐油)、棉籽油(日清奥利友株式會社製,商品名: 曰清棉籽沙拉油)、菜籽油(曰清奥利友株式會社製,商品 名:菜籽白絞油)、玉米油(曰清奥利友株式會社製,商品 名:曰清玉米油)、米油(曰清奥利友株式會社製,商品名: 曰清米白絞油)、山茶油(大島捲株式會社製,商品名:山 茶天婦羅油)。 (實施例5〜6、比較例2〜3 ) 接著,將表1中所示實施例2之組合(乾性油:亞麻仁 油,半乾性油:菜籽油,蠟:石蠟)中的混合比例改變如表 2所示,而實施例5〜6與比較例2〜3之紙製農業用被覆材 則以如同上述實施例與比較例之方法製造。 比較例2乃是半乾性油與蠟混合比例不足之例(此處 為不使用之例)’為僅浸泡乾性油之紙製農業用被覆材。 15 200830985 又’比較例3則為半乾性油與蠟之混合比例過多之例。 [气..2l—油之混合比例 _ 乾性油 半乾性油 蠟 實施例5 100質量份 100質量份 3〇質量份 實施例6 (-實施例2、 100質量份 80質量份 1〇質量份 實施例2 100質量份 0質量份 〇質量份 實施例3 L· 1〇〇質量份 120 f量份 50質量份 (強度之評價) 表3係有關於上述實施例與比較例所製造之紙製農業 用被覆材’將其強度遵循日本工業規格之japan Industrial Standard (JIS法)分析的結果。強度係進行關於抗拉強度 (JIS P8113)、濕抗拉強度(縱)(JIS p8135)、撕裂強度 (縱)(JIS P8116)、破裂強度(JIS P8112)之各種測定。 另外’雖然全部使用相同的紙作為原紙,但由於所含 油脂組成物之量相異,因此各強度係採用基重(每單位面積 的質量)所換算之值。又,以原紙之原始數據的數值為 1 〇 〇,各強度以相對於其之數值表示之。 結果,如同表3所示,實施例之紙製農業用被覆材在 至外栽培時,在作為對雨或風之重要耐久性指標的濕抗拉 強度上,全部均能提升原紙之強度,甚至亦有數值達5倍 以上的紙製農業用被覆材。又,關於其他強度,實施例之 紙製農業用被覆材’其強度亦較原紙提升或與原紙程度相 同,在作為農業用被覆材之使用上乃是沒有問題之強度。 由上述可知,實施例之紙製農業用被覆材在室外環境 栽種之情形下乃極為有用之物。 相較於此,不使用半乾性油及蠟(混合比例不充足)的 16 200830985 比較例2,則如表3所示,其撕裂強度顯著低下,僅能得 到原紙之一半以下的數值。撕裂強度若低下,則無法以機 械展開,即使展開也會在風的影響下,呈現全體裂開之重 大缺陷。又,在半乾性油及壤之混合比例過多之比較例3, 撕裂強度亦顯著低下,無法以機械展開,更加上表面所形 成之膜由於產生皺紋,而被確認有裂化現象。 [表3]評價結果 抗拉強度(縱) 濕抗拉強度(縱) 撕裂強度(縱) 破裂強度 實施例1 96.5 201.0 99.2 97.4 實施例2 (=實施例6) 97.4 124.6 105.9 117.0 實施例3 95.1 151.3 102.6 112.1 實施例4 93.2 132.4 99.8 98.5 實施例5 94.0 507.8 96.3 110.7 比較例1 一 一 — — 比較例2 72.0 261.6 36.4 94.0 比較例3 92.3 112.3 21.6 74.3 ※比較例1由於其無法乾燥而會污染裝置,故無法測定。 (貫地試驗) 在實際之蘿蔔田中,使用實施例2(實施例6)所製造之 被覆材,進行展開試驗、自播種至收成之栽培試驗及土壤 中之分解試驗。200830985 [Examples] (Examples 1 to 4) Paper agricultural covering materials of Examples 1 to 4 containing the mixed oil shown in Table 1 were produced as follows. The oil and fat composition (coating oil) mixed in Table 1 is heated and melted in the tank above the melting point of each wax, and then mixed to a uniform ratio of oil, semi-dry oil, and soil, each of which is half relative to the dry oil. The dry oil was set to 80 parts by mass, and the wax was set to 10%. The oil and fat composition was immersed on both sides of the kraft paper, and in the first to fourth embodiments, the fat and oil composition was respectively made to be relative to the original mass%. Examples 1), 6, 5 mass% (Example 2), 4.8 mass method 3), and 5.6 mass% (Example 4). (Comparative Example 1) A paper agricultural covering material of Comparative Example 1 containing the mixed oil shown in Table 1 was produced as follows. In Comparative Example 1, the both sides of the kraft paper were soaked with the camellia oil and palm wax of the non-drying oil, and then dried. The ratio of camellia oil to brown is set to 1 80 parts by weight of camellia oil and J parts by palm wax. The oil and fat composition accounts for 58.7 mass% with respect to the base paper. However, the paper agricultural covering material of Comparative Example 1 did not dry at all in the step, and the surface of the paper exuded grease, and if it was wound, the grease would stick together. In this case, it cannot be wound on the exhibition and it is very difficult to use. The fat composition is blended and stopped. Dry 100 parts by weight. Dry. ^ and accounting for 5.0% (the mixture of the composition of the fat composition of the mixture of palm wax &amp; 10 after the treatment of its direct roll-off machine 14 200830985 t gas „·] lack of jgja mixture of dry oil semi-dry oil Wax Example 1 safflower seed oil, cotton scented oil, palm sapling '' (CERARICA NODA CORPORATION, trade name: palm wax) Example 2 Linseed rapeseed oil ' ' (made by 曰本精蜡株式会社, trade name (pALVAX-1230) Example 3 Soybean oil corn oil beeswax - (manufactured by CERARICANODA Co., Ltd., trade name: close can, example 4, tung oil rice oil rice bran--- (made by Ogura Synthetic Industry Co., Ltd., trade name: MITSUBISHI Comparative Example 1 Use of Camellia Oil (No Dry Oil) Palm Wax &quot;----- (CERARICANODA CORPORATION, trade name: palm wax) In Table 1, safflower seed oil Co., Ltd., product name: 曰红红花油), linseed oil (made by Minqing Aoliyou Co., Ltd., trade name: N/B linseed oil), soybean oil (made by Minqing Aoliyou Co., Ltd., trade name . Soybean white skein (S)), tung oil (Cosmo oil Co., Ltd., product name: Tung oil), cottonseed oil (produced by Nisshin Olympus Co., Ltd., trade name: 曰清棉籽沙拉油), rapeseed oil (made by Minqing Olympus Co., Ltd., trade name: rapeseed White stalked oil), corn oil (made by 曰清奥利友株式会社, trade name: 曰清 corn oil), rice oil (made by Minqing Aoliyou Co., Ltd., trade name: 曰清米白白绞油), camellia Oil (manufactured by Oshima Co., Ltd., trade name: Camellia tempura oil). (Examples 5 to 6, Comparative Examples 2 to 3) Next, the combination of Example 2 shown in Table 1 (drying oil: linseed) The mixing ratio in the oil, semi-drying oil: rapeseed oil, wax: paraffin) was changed as shown in Table 2, and the paper agricultural covering materials of Examples 5 to 6 and Comparative Examples 2 to 3 were as in the above examples. It was produced by the method of the comparative example. Comparative Example 2 is an example in which the ratio of the semi-drying oil to the wax is insufficient (herein is not used) 'is a paper-based agricultural covering material which is only immersed in the dry oil. 15 200830985 Example 3 is an example of excessive mixing ratio of semi-dry oil and wax. [Gas..2l-oil Mixing ratio _ dry oil semi-drying oil wax Example 5 100 parts by mass 100 parts by mass 3 〇 parts by mass Example 6 (-Example 2, 100 parts by mass 80 parts by mass 1 〇 parts by mass Example 2 100 parts by mass 0 parts by mass 〇质量份Example 3 L·1〇〇 parts by mass 120 f parts by weight 50 parts by weight (Evaluation of strength) Table 3 relates to the paper agricultural covering materials manufactured in the above examples and comparative examples, The result of the Japanese industrial specification japan Industrial Standard (JIS method) analysis. The strength was measured for various kinds of tensile strength (JIS P8113), wet tensile strength (longitudinal) (JIS p8135), tear strength (longitudinal) (JIS P8116), and burst strength (JIS P8112). Further, although all of the same paper is used as the base paper, since the amount of the oil and fat composition contained therein is different, each strength is a value converted by basis weight (mass per unit area). Further, the value of the raw data of the base paper is 1 〇 〇, and each intensity is expressed by a value relative to the same. As a result, as shown in Table 3, in the case of externally cultivated paper-based agricultural covering materials, the wet tensile strength as an important durability index for rain or wind can all increase the strength of the base paper, and even There are also paper agricultural coated materials with a value of more than 5 times. Further, regarding the other strengths, the paper-based agricultural covering material of the example has a strength higher than that of the base paper or the same as that of the base paper, and has no problem in use as an agricultural covering material. From the above, it can be seen that the paper agricultural covering material of the embodiment is extremely useful in the case of planting in an outdoor environment. In contrast, in Comparative Example 2, which does not use a semi-drying oil and a wax (the mixing ratio is insufficient), as shown in Table 3, the tear strength is remarkably low, and only a value of one half or less of the base paper can be obtained. If the tear strength is low, it cannot be mechanically deployed. Even if it is unfolded, it will show the major defects of the whole crack under the influence of the wind. Further, in Comparative Example 3 in which the mixing ratio of the semi-dry oil and the soil was too large, the tear strength was remarkably lowered, and it was impossible to mechanically spread, and the film formed on the upper surface was confirmed to have cracking due to wrinkles. [Table 3] Evaluation results Tensile strength (longitudinal) Wet tensile strength (longitudinal) Tear strength (longitudinal) Burst strength Example 1 96.5 201.0 99.2 97.4 Example 2 (=Example 6) 97.4 124.6 105.9 117.0 Example 3 95.1 151.3 102.6 112.1 Example 4 93.2 132.4 99.8 98.5 Example 5 94.0 507.8 96.3 110.7 Comparative Example 1 One--Comparative Example 2 72.0 261.6 36.4 94.0 Comparative Example 3 92.3 112.3 21.6 74.3 ※Comparative Example 1 is contaminated because it cannot be dried The device cannot be measured. (Continuous test) In the actual radish field, the coated material produced in Example 2 (Example 6) was used, and the development test, the cultivation test from the seeding to the harvest, and the decomposition test in the soil were carried out.

在蘿蔔田中,以覆蓋機展開實施例2(實施例6)之被覆 材,在100公尺之展開中能夠全無破裂。 又,使用實施例2(實施例6)之被覆材,在播種至收成 之間的 6 0日進行蘿蔔之栽培,則如同第1圖(照片)所示 般,至收成為止,使用此被覆材亳無疑問地能夠抑制雜草 生長,且被覆材並無破損之狀態。 更且,在蘿蔔於秋季收成之後,將實施例2(實施例6) 之被覆材埋於土中,結果被覆材受到分解而到了春季時已 17 200830985 徹底消失。 【圖式簡單說明】 第1圖係表示實地試驗結果的照片。 【主要元件符號說明】 無In the radish field, the covering material of Example 2 (Example 6) was developed by a covering machine, and it was possible to completely rupture at 100 m. In addition, when the radish was cultivated on the 60th day between the sowing and the harvest, the coated material of Example 2 (Example 6) was used as shown in Fig. 1 (photograph), and the coated material was used. There is no doubt that weeds can be inhibited from growing and the coated material is not damaged. Further, after the radish was harvested in the autumn, the coated material of Example 2 (Example 6) was buried in the soil, and as a result, the coated material was decomposed and completely disappeared in the spring of 17 200830985. [Simple description of the drawing] Fig. 1 is a photograph showing the results of the field test. [Main component symbol description] None

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Claims (1)

200830985 十、申請專利範圍: 1. 一種紙製農業用被覆材,其係使可分解於土中 一部分或全It,含有油脂組成物而構成,該油脂组 有乾性油、半乾性油、及常溫下為固體且熔點小於 之蠟,且其混合比例(質量比)為乾性油:半乾性油 1 · 0 : 1 · 0以下:0.3以下。 2. 一種紙製農業用被覆材,其特徵係在可分解於 紙的一部份或全體的任意部位,含有乾性油、半乾 及常溫下為固體且熔點小於 1 0 0 °C之蠟,且其含有 為乾性油:半乾性油:蠟=1.0 : 1 · 0以下:0.3以一 3. 如申請專利範圍第1項所述之紙製農業用被覆 中上述之混合比(質量比)為乾性油:半乾性油:蠟 0.6以上:0.03以上。 4. 如申請專利範圍第2項所述之紙製農業用被覆 中上述之含有質量比為乾性油:半乾性油:蠟=1 以上:0.03以上。 5. 如申請專利範圍第1項所述之紙製農業用被覆 中上述之紙,相對於該紙的乾燥質量,含有2〜20 上述油脂組成物。 之紙的 成物含 1 0 0 °c :壤= 土中之 性油、 質量比 F ° 材,其 = 1.0: 材,其 •0 : 0.6 材,其 量%的 19200830985 X. Patent application scope: 1. A paper agricultural covering material which is made up of a part or all of It in the soil and contains a fat composition, which has dry oil, semi-dry oil, and room temperature. The following is a solid and the melting point is smaller than the wax, and the mixing ratio (mass ratio) thereof is a dry oil: a semi-drying oil 1 · 0 : 1 · 0 or less: 0.3 or less. 2. A paper agricultural covering material characterized in that it is soluble in a part or all of the paper, and contains a dry oil, a semi-dry and a wax which is solid at normal temperature and has a melting point of less than 100 ° C. And the content thereof is a dry oil: semi-drying oil: wax = 1.0: 1 · 0 or less: 0.3 to 3. The paper mixture for agricultural use as described in claim 1 of the patent application is a mixture ratio (mass ratio) Dry oil: semi-drying oil: wax 0.6 or more: 0.03 or more. 4. The paper-based agricultural coating described in the second paragraph of the patent application is in the above-mentioned mass ratio: dry oil: semi-drying oil: wax = 1 or more: 0.03 or more. 5. The above-mentioned paper of the paper agricultural coating according to the first aspect of the patent application, comprising 2 to 20 of the above-mentioned fat or oil composition with respect to the dry mass of the paper. The composition of the paper contains 100 °c: soil = soil oil, mass ratio F ° material, which = 1.0: material, its 0: 0.6 material, the amount of 19 200830985 6. 如申請專利範圍第2項所述之紙製農業用被覆 中上述之紙,相對於該紙的乾燥質量,含有總量i 質量%的上述乾性油、上述半乾性油及上述蠟。 7. 如申請專利範圍第1項至第6項之任一項所述 農業用被覆材,其中上述乾性油,為自亞麻仁油、 油、大豆油 '桐油、葡萄籽油、胡桃油、月見草油 油、大麻籽油所組成之群組中選擇1種或2種以上 8. 如申請專利範圍第1項至第6項之任一項所述 農業用被覆材,其中上述半乾性油,為自麻油、棉 玉米油、菜軒油、米油、扁桃仁油所組成之群組中 種或2種以上。 9. 如申請專利範圍第1項至第6項之任一項所述 農業用被覆材,其中上述蠟,為自堪地里拉蠟、棕 米糠蠟、荷荷芭油、木蠟、羊毛脂、蜜蠟、褐煤蠟、 石蠟、微晶蠟、氫化蓖麻油所形成之群組中選擇1 種以上。 材,其 》2〜20 之紙製 紅花籽 、芬子 〇 之紙製 籽油、 選擇1 之紙製 櫚蠟、 1地填、 種或2 20 200830985 七、指定代表圖: (一) 、本案指定代表圖為:無 (二) 、本代表圖之元件代表符號簡單說明:無 八、本案若有化學式時,請揭示最能顯示 發明特徵的化學式: 無 200830985 發明專利說明書200830985 6. The above-mentioned paper of the paper agricultural coating according to the second aspect of the patent application, comprising the above-mentioned dry oil, the semi-drying oil and the wax in a total amount of i% by mass based on the dry mass of the paper. 7. The agricultural covering material according to any one of claims 1 to 6, wherein the above dry oil is from linseed oil, oil, soybean oil 'tung oil, grape seed oil, walnut oil, evening primrose The above-mentioned semi-drying oil is the above-mentioned semi-drying oil, which is one or more of the group consisting of the oil oil and the hemp seed oil. It is a group of two or more kinds of sesame oil, cotton corn oil, vegetable oil, rice oil, and almond oil. 9. The agricultural covering material according to any one of claims 1 to 6, wherein the wax is a corian wax, a brown rice wax, a jojoba oil, a wood wax, a lanolin, One or more selected from the group consisting of beeswax, montan wax, paraffin wax, microcrystalline wax, and hydrogenated castor oil. Wood, its 2~20 paper safflower seeds, fennel scorpion paper seed oil, 1 paper palm wax, 1 landfill, seed or 2 20 200830985 VII. Designated representative map: (1) The designated representative figure is: None (2), the representative symbol of the representative figure is a simple description: No. 8. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: No 200830985 Patent Description (本說明書格式、順序及粗體字,請勿任意更動,※記號部分請勿填寫) ※申請案號:96133908 分類:(The format, order and bold type of this manual, please do not change it at will, please do not fill in the ※ mark) ※Application number: 96133908 Category: ※申請日期:2007年9月11曰 一、發明名稱:(中文) 紙製農業用被覆材 二、 申請人:(共1人) 姓名或名稱:(中文/英文) 曰商·曰清奥利友集團股份有限公司 The Nisshin OilliO Group, Ltd. 代表人··(中文/英文) 大込一男 / OGOME,KAZUO 住居所或營業所地址:(中文/英文) 曰本國東京都中央區新川1 丁目23番1號 23-1,Shinkawa 1-chome,Chuoku,Tokyo 104-8285, Japan 國籍:(中文/英文) 曰本/ Japan 三、 發明人:(共4人) 姓名:(中文/英文) 1. 西田穰/NISHIDA,YUTAKA 2. 高木良彰/TAKAGI,YOSHIAKI 3. 龜谷泰志/KAMETANI,YASUSHI 4·福本諭/FUKUMOTO, SATOSHI 國籍:(中文/英文) 1. 曰本/ Japan 2. 曰本/ Japan 1 200830985 : 年月曰 發明專利說明書 (本說明書格式、順序及粗體字,請勿任意更動,※記號部分請勿填寫) ※申請案號:96133908 ※申請日期:2007年9月11日 叕1?(:分類: 一、發明名稱:(中文) 紙製農業用被覆材 二、申請人:(共1人) 姓名或名稱:(中文/英文) 曰商·日清奥利友集團股份有限公司 The Nisshin OilliO Group, Ltd. 代表人:(中文/英文) 大込一男 / OGOME,KAZUO 住居所或營業所地址:(中文/英文) 曰本國東京都中央區新川1 丁目23番1號 23-1,Shinkawa 1-chome,Chuoku,Tokyo 104-8285, Japan 國籍:(中文/英文) 日本/ Japan 參 三、發明人:(共4人) 姓名:(中文/英文) 1. 西田穰/NISHIDA,YUTAKA 2. 高木良彰/TAKAGI,YOSHIAKI 3. 龜谷泰志/KAMETANI,YASUSHI 4. 福本諭/FUKUMOTO, SATOSHI 國籍:(中文/英文) 1·日本/Japan 2.日本/ Japan 1 200830985 3. 日本/ japan 4. 曰本/ japan 四、聲明事項: □主張專第二十二條第二項□第-款或□第二款規定之事實’其 事實發生曰期為:年月曰。 0申請前已向下列國家(地區)中請專利: 【格式請依··受理國家(地區)、申請曰、申請銳祕註記】 E有主張專利法第二十七條第_項國際優先權: 日本;2006 年 9 月 15 日;2006-251750 □無主張專利法第二十七條第一項國際優先權: □主張專利法第二十九條第—項關優先權: 【袼式請依:申請日、申請案號順序註記】 口主張專利法第三十條生物材料:-D須寄存生物材料者: 國内生物材料【格式請依:寄存機構、日期、號碼順序註記】 國外生物材料【格式請依:寄存國家、機構、曰期、號碼順序註記】 Ο不須寄存生物材料者: 所屬技術領域巾具魏常知識者綠獲得時,不須寄存。 200830985 3. 日本/ japan 4. 曰本/ japan 四、聲明事項: □主張專第二十二條第二項□第-款或□第二款規定之事實’其 事實發生曰期為:年月曰。 0申請前已向下列國家(地區)中請專利: 【格式請依··受理國家(地區)、申請曰、申請銳祕註記】 E有主張專利法第二十七條第_項國際優先權: 日本;2006 年 9 月 15 日;2006-251750 □無主張專利法第二十七條第一項國際優先權: □主張專利法第二十九條第—項關優先權: 【袼式請依:申請日、申請案號順序註記】 口主張專利法第三十條生物材料:-D須寄存生物材料者: 國内生物材料【格式請依:寄存機構、日期、號碼順序註記】 國外生物材料【格式請依:寄存國家、機構、曰期、號碼順序註記】 Ο不須寄存生物材料者: 所屬技術領域巾具魏常知識者綠獲得時,不須寄存。※Application date: September 11, 2007. Name of the invention: (Chinese) Covering material for paper agriculture II. Applicant: (1 in total) Name or Name: (Chinese/English) 曰商·曰清奥利Representative Group of The Nisshin OilliO Group, Ltd. (Chinese / English) Otsuka I / OGOME, KAZUO Residence or Business Office Address: (Chinese / English) 新Nippon, Tokyo, Chuo-ku, Shinagawa 1-chome 23 Fan 1-23-1, Shinkawa 1-chome, Chuoku, Tokyo 104-8285, Japan Nationality: (Chinese / English) 曰本 / Japan III, Inventor: (Total 4 people) Name: (Chinese / English) 1. Nishida NI / NISHIDA, YUTAKA 2. Takagi Ryo Akira / TAKAGI, YOSHIAKI 3. Kameya Tai Chi / KAMETANI, YASUSHI 4 · Fumoto 谕 / FUKUMOTO, SATOSHI Nationality: (Chinese / English) 1. 曰本 / Japan 2. 曰本 / Japan 1 200830985 : The invention of the invention patent (in the format, order and bold text of this manual, please do not change it at will, please do not fill in the ※ part) ※Application number: 96133908 ※Application date: September 11, 2007 叕1 ?(: Class: 1. Name of the invention: (Chinese) Covering material for paper agriculture II. Applicant: (1 person in total) Name or Name: (Chinese/English) The Nisshin OilliO Group Co., Ltd. Group, Ltd. Representative: (Chinese / English) Otsuka I / OGOME, KAZUO Residence or establishment address: (Chinese / English) 曰 东京 东京 曰 新 新 新 新 新 新 新 23 23 23 23 23 23 23 23 23 23 23 23 kawa kawa kawa -chome,Chuoku,Tokyo 104-8285, Japan Nationality: (Chinese/English) Japan/Japan Participation III, inventor: (4 persons in total) Name: (Chinese/English) 1. Nishida NI / NISHIDA, YUTAKA 2. Takagi良彰/TAKAGI, YOSHIAKI 3. Kameya Tai Chi / KAMETANI, YASUSHI 4. Fukumoto / FUKUMOTO, SATOSHI Nationality: (Chinese / English) 1 / Japan / Japan 2. Japan / Japan 1 200830985 3. Japan / japan 4. 曰本/ japan IV. Declarative matters: □ Proposal for the facts of Article 22, Paragraph 2, Paragraph- or Paragraph 2, the facts of which occur in the following year: 0 The patent has been filed in the following countries (regions) before the application: [Format please accept the country (region), application, application for sharp note] E has the patent law, Article 27, Article _ International Priority : Japan; September 15, 2006; 2006-251750 □ No claim for patent law Article 27: First international priority: □ Claim Patent Law Article 29 - Item Priority: [袼式According to: application date, application case number note] mouth claim patent law Article 30 biological materials: -D must deposit biomaterials: domestic biomaterials [format please follow: registration agency, date, number order note] foreign Biomaterials [format: please note: country, organization, period, number order note] Ο Do not need to deposit biomaterials: When the technical field of the towel is known to the general knowledge, it is not necessary to deposit. 200830985 3. Japan / japan 4. Sakamoto / japan IV. Declarative matters: □ Proposal for the facts of Article 22, Paragraph 2, Paragraph- or Paragraph 2, the facts of which occur: Years and months Hey. 0 The patent has been filed in the following countries (regions) before the application: [Format please accept the country (region), application, application for sharp note] E has the patent law, Article 27, Article _ International Priority : Japan; September 15, 2006; 2006-251750 □ No claim for patent law Article 27: First international priority: □ Claim Patent Law Article 29 - Item Priority: [袼式According to: application date, application case number note] mouth claim patent law Article 30 biological materials: -D must deposit biomaterials: domestic biomaterials [format please follow: registration agency, date, number order note] foreign Biomaterials [format: please note: country, organization, period, number order note] Ο Do not need to deposit biomaterials: When the technical field of the towel is known to the general knowledge, it is not necessary to deposit.
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