200829694 九、發明說明： 【發明所屬之技術領域】 本發明係有關一種清潔劑，尤指一種具有良好油污 去除能力與抗菌能力，且生物分解度100%之萬用清潔 【先前技術】 舊有的洗衣粉製造技術，是必須將不同的原料溶解 於水中，再乾燥脫水，喷出粉粒。較進步的環保洗衣粉 製造技術，是用預拌水泥機將粉狀不同的原料混合，再 喷入少許液態原料或香精，使粉狀原料吸入液態原料， 但是此方式容易造成結塊問題。也有環保洗衣粉製造技 術，是用臥式攪拌機，是可使粉狀原料攪拌較為均勻， 但是配方的選擇及比例，卻是影響原料濃縮的程度，也 影響了使用的功效及殺菌能力。 習知清潔劑之組成物係仰賴使用水溶性無機石粦酸鹽 或 EDTA(Ethylene Diamine Tetraacetic Acid ;二胺四乙 酸），其被添加做為硬水軟化劑。其中所含的_排入承 受水體後，將造成湖泊、河川的優養化 (Eutrophication)，使水中有毒藻類與浮游生物大量繁 殖、造成惡臭及懸浮固體增加，及水中缺氧等惡化現 象。 據調查，所有河川及海洋的廢水有97%來自家庭污 5 200829694 染廢水’而大多數的家庭渣 λα 傲，月’糸七都會加石粦酸鹽或EDTA 的化+物質，藉此增進去污 ’ 疋匕們到了河川和湖泊， ,就會導致澡類迅速繁殖，把皮 中所有的氧氣都吸收光， m 而使其他生物窒息，這就是 優養化」的現象。當水中 沾主本^ ^ 生物死亡’其屍體腐散產生 的毋素，再透過水庫集中 是新的疾病又誕生了。刀达到母個家庭來飲用，於200829694 IX. Description of the invention: [Technical field of the invention] The present invention relates to a cleaning agent, especially a universal cleaning device having good oil removal ability and antibacterial ability, and having a biodegradability of 100% [Prior Art] The washing powder manufacturing technology is that it is necessary to dissolve different raw materials in water, then dry and dehydrate, and spray the powder. The more advanced environmentally friendly washing powder manufacturing technology uses a premixed cement machine to mix different powdered raw materials, and then sprays a little liquid raw material or flavor to make the powdery raw materials inhaled into the liquid raw material, but this method is liable to cause agglomeration problems. There is also an environmentally friendly washing powder manufacturing technology. The horizontal mixer is used to make the powdery raw materials stir more evenly. However, the choice and proportion of the formula affect the degree of concentration of the raw materials, and also affect the efficacy and sterilization ability. Conventional detergent compositions rely on the use of water soluble inorganic sulphate or EDTA (Ethylene Diamine Tetraacetic Acid; diamine tetraacetate) which is added as a hard water softener. The _ contained in the water body will cause Eutrophication of lakes and rivers, causing the proliferation of toxic algae and plankton in the water, causing the increase of malodor and suspended solids, and the deterioration of oxygen in the water. According to the survey, 97% of all rivers and marine wastewater are from household pollution. 5200829694 Dyeing wastewater's, and most of the household slag λα is proud, and the moon's seven will add sulphate or EDTA. Staining 'When we get to rivers and lakes, it will cause the bath to multiply rapidly, so that all the oxygen in the skin absorbs light, so that other organisms suffocate, which is the phenomenon of eutrophication. When the water is stained with the main body ^ ^ biological death 'the corpse of the corpse rot, and then concentrated through the reservoir is a new disease was born. The knife reaches the mother's family to drink,
或是加人㈣劑來使衣物顯得亮麗潔白，螢 子對光線的吸收能力稂％ , 认“ b力很強，在吸收光能後會產生離子化 总並發？出藍白色的螢光，而產生視覺上潔白的 J g光劑疋致癌毒物’也是十大致癌原因之-，歐 吴先進國家已嚴禁使用。但是―般業者為了加強潔白效 果’在洗妹中添加螢光劑，本身完全沒有潔淨功能， 而且會刺激皮膚’容易發生紅腫、過敏、富貴手等現 象，如果殘留在衣物上長期接觸皮膚亦會造成皮膚病 、又，Θ漂劑溶液被微生物分解消化之百分比，分解 度越高表示殘留於水體中之清潔劑就越少。環保標章規 才° "^準要求清潔用品的生物分解度達90%以上，洗碗 精的生物分解度更高達95%以上，且須含5〇%以上的天 :、、、:原料，天然原料是指由動、植物提煉之原料（如脂肪 酸鈉、脂肪酸鉀）所製成之界面活性劑。所以標示生物 分解度亦代表清潔劑的安全性。清潔劑所使用的界面活 性劑經洗蘇之後排放到河川和湖泊，能夠被微生物分 200829694 解，就表示生物分解度很高，因此洗滌衣物後的廢水是 否能夠迅速被生物分解，對河川、湖泊、海洋的污染是 非常重要。生物分解度也會影響人體的分解排除能力。 當生物分解度越高對人體就越安全，就像吃食物一樣。 然一般清潔劑的生物分解度只有30〜40%。對此，在環 保意識覺醒高漲的時代，含有磷酸鹽或EDTA，且生物 分解度低的清潔劑特別受到排斥。 如此需要一種具有良好油污去除能力與抗菌能力， ^ 且生物分解度高之清潔劑，而不含有危害環境的成份利 如磷酸鹽或EDTA之萬用清潔劑。 【發明内容】 爰是，本發明之主要目的係揭露一種清潔劑組合 物，其無需使用遭人排斥的磷酸鹽或EDTA的化學物 質，可以直接當作洗碗精、洗衣精、蔬果清潔劑、廚房 清潔劑、浴廁清潔劑、地板清潔劑、玻璃清潔劑、洗車 ί 3| 精、殺菌洗手乳等，既可有效作為清潔手段同時也為環 保所接受的萬用清潔劑。 本發明之另一目的係揭露一種清潔劑組合物，其生 物分解度高達100%，使被使用過的清潔劑排放到河川 和湖泊，能夠被微生物完全分解。生物分解度也會影響 人體的分解排除能力，當生物分解度越高對人體就越安 全，就像一般可食用之食物一樣安全。 本發明係一種萬用清潔劑，其包括：45%至55%的 7 200829694 碳酸鹽（sodium carbonate)及4%至6%的石夕酸納（sodium orthosilicate )，作為分解污垢用；25%至35%的疏酸納 水合物（sodium sulfate decahydrate)，作為滲透劑；4% 至6%的椰子油（coconut oil)及4%至6%的椰子油脂肪酸 (coconut oil fatty acid)，屬於陰離子界面活性劑，用 以分離污垢；以及4%至6%的過碳酸鹽 (peroxocarbonates)，作為殺菌材料。 其中，該碳酸鹽係重質碳酸鹽及輕質碳酸鹽其中之 -—、 〇 進一步本發明可依使用上的需要加入6至8倍重於前 述混合材料的水，調製成乳狀用劑；或18至22倍重於 前述混合材料的水，調製成液狀用劑；或1000至2000 倍重於前述混合材料的水，調製成稀釋之液狀用劑。 又本發明之萬用清潔劑進一步可包含一香料，其 中，該香料係擇自茴香籽油、香脂、羅勒、樟腦、桂 皮、香茅、丁子香、芫荽、香豆素、桉、小茴香、薑、 葡萄柚、刺柏莓、檸檬、楓茅油、麝香酮、豆肉蔻、柳 橙、廣藿香、薄荷、鼠尾草、黃樟、留蘭香、薰衣草、 冬綠、香葉醇等組合的組群。 【實施方式】 茲有關本發明之詳細内容及技術說明，現詳細說明 如下： 本發明係一種萬用清潔劑，該萬用清潔劑包括： 200829694Or add people (four) to make the clothes look bright and white, the fluorescing ability of the fluorescing light is 稂%, and the "b force is very strong. After absorbing the light energy, the ionization will always be combined and the blue-white fluorescent light will be emitted. Producing visually white J g light agent, carcinogenic toxins is also the cause of ten cancers. It has been strictly forbidden in the advanced countries of Ouwu. However, in order to enhance the whitening effect, the industry has added no fluorescent agent to the washing girl. Cleansing function, and it will irritate the skin 'prone to redness, allergies, rich hands and other phenomena. If it remains on the clothes for a long time, it will cause skin disease, and the percentage of the bleaching agent solution is decomposed and digested by microorganisms. The higher the degree of decomposition, the higher the degree of decomposition. Indicates that the amount of detergent remaining in the water is less. The environmental labeling rules are required to require more than 90% of the biodegradability of the cleaning products, and the biodegradability of the dishwashing essence is more than 95%, and must be included. More than 5〇% of the day:,,,: raw materials, natural raw materials refer to the surfactants made from animal and plant-derived raw materials (such as fatty acid sodium, fatty acid potassium). The degree also represents the safety of the cleaning agent. The surfactant used in the cleaning agent is discharged to the rivers and lakes after being washed, and can be solved by the microorganisms 200829, which means that the degree of biodegradation is high, so whether the wastewater after washing the clothes can It is quickly decomposed by bacteria and is very important for pollution of rivers, lakes and oceans. The degree of biodegradation also affects the ability of the human body to decompose and eliminate. The higher the degree of biodegradation, the safer it is to the human body, just like eating food. The biodegradability of the agent is only 30 to 40%. In this era, in the era of high awareness of environmental awareness, detergents containing phosphate or EDTA and low biodegradability are particularly excluded. Therefore, a good oil removal ability and antibacterial are required. A cleaning agent having a high degree of biodegradability without containing environmentally harmful components such as phosphate or EDTA. SUMMARY OF THE INVENTION The main object of the present invention is to disclose a detergent composition. It does not require the use of phosphates that are rejected by phosphate or EDTA, and can be used directly as dishwashing detergents and laundry detergents. , vegetable and fruit cleansers, kitchen cleaners, toilet cleaners, floor cleaners, glass cleaners, car washes ί 3| fine, sterilized hand lotion, etc., can be effectively used as a cleaning method and also a universal cleaner accepted by the environment. Another object of the present invention is to disclose a detergent composition which has a biodegradability of up to 100%, so that the used detergent is discharged into rivers and lakes, and can be completely decomposed by microorganisms. The degree of biodegradation also affects the human body. Decomposition and elimination ability, the higher the degree of biodegradation, the safer it is to the human body, just as safe as general edible food. The present invention is a universal cleaning agent comprising: 45% to 55% of 7 200829694 carbonate (sodium Carbonate) and 4% to 6% of sodium orthosilicate for decomposition of soil; 25% to 35% of sodium sulfate decahydrate as penetrant; 4% to 6% Coconut oil and 4% to 6% of coconut oil fatty acid, an anionic surfactant used to separate soils; and 4% to 6% percarbonate (peroxocarbona) Tes), as a germicidal material. Wherein, the carbonate-based heavy carbonate and the light carbonate are further--, and further, the invention can be added to the water of the foregoing mixed material by adding 6 to 8 times the weight of the mixture according to the use, to prepare a milk-like agent; Or 18 to 22 times more water than the above-mentioned mixed material, and prepared into a liquid preparation; or 1000 to 2000 times the weight of water of the above-mentioned mixed material to prepare a diluted liquid preparation. The universal cleaning agent of the present invention may further comprise a fragrance selected from the group consisting of fennel seed oil, balsam, basil, camphor, cinnamon, lemongrass, butyl scent, medlar, coumarin, alfalfa, cumin, Ginger, grapefruit, juniper, lemon, maple oil, musk ketone, bean glutinous rice, orange, patchouli, mint, sage, sassafras, spearmint, lavender, winter green, geraniol, etc. Combined group. [Embodiment] The detailed description and technical description of the present invention will now be described in detail as follows: The present invention is a universal cleaning agent, and the universal cleaning agent includes: 200829694
45/。至55/6的兔酸鹽及4%至6%的石夕酸納，該碳酸鹽及 4%至6%的矽酸鈉係用以作為分解污垢用，其中，該碳 酸鹽係重質碳鹽及輕質礙酸鹽其中之—；2现至％% 的石瓜S义鈉水合物，用以作為滲透劑，例如帶前述分解污 垢用兀素滲透導入至衣物深層纖維用；4%至6%的椰子 油及4%至6%的椰子油脂肪酸，屬於陰離子界面活性 劑，用以分離污垢，也就是作為界面活性劑用，其會使 水和油的界面張力消失，使油混入水中，如此一來就能 夠將衣物或餐具清洗乾淨；以及加有4%至心的過碳酸 鹽’用以作為殺菌用劑，依此本發明形成粉狀之萬 潔劑。 本I月在使用上可將前述製成之粉狀萬用清潔劑用 =別薪的衣物，如衣領、機底，可直接用粉擦拭。而 針對重油污處’如油煙、油污，可直接_上，再噴 少許的水，即可容易去污，或用微濕的清潔布沾粉捧、 ^少不贫明可依使用上的需要加入不同比例的 水’使本發明成乳狀或液狀之清潔劑。當其加人6至… 成=劑，可直接當作洗碗精、洗衣精、i 用劑。或18至22倍重的水調製成液狀用劑，可直 接虽作廚房清潔劑、浴廟清_、地板清_ =劑等中度清潔㈣。或倍麵水财: 釋之液狀用劑，可稀釋成玻璃清潔劑等輕度清潔用 9 200829694 或拿來洗花草，改善土壤酸驗值，預防蟲害，促進植物 的生長茂盛。 本發明因為水溶性高，所以容易清洗，用水量少， 可節省清潔中的電力與水力等能源，且高效率的清潔能 力，對油污、血潰清洗效果快速，殺菌用劑也使得被清 潔物不易滋生細菌、延長被清潔物的使用期限。 本發明之萬用清潔劑進一步可包含一番料成份，其 中香料可選擇自茴香籽油、香脂、羅勒、樟腦、桂皮、 r I 香茅、丁子香、芫荽、香豆素、桉、小茴香、薑、葡萄 柚、刺柏莓、檸檬、楓茅油、麝香酮、豆肉蔻、柳橙、 廣藿香、薄荷、鼠尾草、黃樟、留蘭香、薰衣草、冬 綠、香葉醇等組合的組群。 本發明的製做方式係利用刀式切割推擠攪拌，將前 述的粉狀原料攪拌均勻，依照其主要清潔用途，本發明 之水性混合物配方可更改不同的比例，但需注意混合物 間的聚合能力，當粉狀加入水後，攪拌均勻不會變成稠 ί) 狀。 例如將50%的碳酸鹽、5%矽酸鈉及30%的硫酸鈉水 合物，放入臥式擾拌機中擾拌10分鐘；在擾拌的狀態下 加入5%的椰子油，再攪拌10分鐘後，於攪拌狀態下加 入5%的椰子油脂肪酸，於攪拌狀態下續加入5%的過碳 酸鹽，再攪拌10分鐘，最後加入適當倍數於前述混合材 料之水（如7倍）即可進行分裝。其中再加入過碳酸鹽後 可在攪拌狀態下加入需要的香料原料。 10 200829694 化學清 >糸劑因為有二次污染的疑慮，所以在環保上 強調無磷、軟性及較高的生物分解度。所以「生物分解 度」代表清潔劑的安全性，越天然的清潔劑其「生物分 解度」越高，而石化類的清潔劑其生物分解度極低，因 此石化類的清潔劑不容易被微生物分解，會殘留於水中 污染環境外，如使用於個人的清潔，經由皮膚吸收後亦 不易代謝，會在人體内蓄積，造成慢性的毒害，並有致 癌的危險。 ^ 只要用是界面活性劑（不論天然或合成，軟性或硬 性）’都會有不同程度的污染。市面上的「界面活性 劑」種類眾多，有天然的也有石化類合成的「界面活性 劑」，要如何分辨好壞呢？其實所有的「界面活性劑」 都可以被大自然的活菌分解，只是有些比較容易，有些 比較不容易的差異而已，這便是「生物分解度」的高低 之分。「生物分解度」的高低一般用生化需氧量 (BOD)來測量，依照標準「生物分解度」是含有清潔 J 劑的溶液經過八天後被微生物分解消化之百分比，分解 度越高表示清潔劑原料的成份具有越多的天然物質:環 保標章規格標準要求清潔用品的「生物分解度」達· 以上。而本發明之水性混合物配方都是採用可以被大自 然活菌分解的原料，所以本發明之混合物之 高達職，就像一般可食用之食物一樣安全。刀解度 惟上述僅為本發明之較佳實施例而已，並非用來限 定本發明實施之範圍。即凡依本發明中請專利範圍所做 200829694 ‘的均等變化與修飾，皆為本發明專利範圍所涵蓋。 【圖式簡單說明】 無。 【主要元件符號說明】 無0 Ο 1245/. To 55/6 of the tartrate and 4% to 6% of sodium silicate, the carbonate and 4% to 6% of sodium citrate are used as decomposing soil, wherein the carbonate is heavy carbon Salt and light catalyzed acid salt - 2, present to %% of the saguaro S-sodium hydrate, used as a penetrating agent, for example, with the aforementioned decomposition of the soil into the deep fibers of the clothing with the penetration of bismuth; 4% to 6% coconut oil and 4% to 6% coconut oil fatty acid, an anionic surfactant used to separate dirt, that is, as a surfactant, which will make the interfacial tension between water and oil disappear, and the oil will be mixed into the water. In this way, the laundry or the tableware can be cleaned; and the 4% to the heart of the percarbonate is used as a sterilizing agent, whereby the present invention forms a powdery versatile agent. In the use of this month, the powdered general purpose cleaner prepared above can be used as a non-paying clothing, such as a collar or a machine bottom, which can be directly wiped with powder. For heavy oil stains such as oil smoke, oil stains, you can directly _, and then spray a little water, you can easily decontaminate, or use a slightly damp cleaning cloth dipped in powder, ^ less not poor can be used according to the needs Adding different proportions of water' makes the invention a creamy or liquid detergent. When it is added to 6 to ... into the agent, it can be directly used as dishwashing detergent, laundry detergent, and i. Or 18 to 22 times the weight of water to prepare a liquid agent, which can be used as a kitchen cleaner, bathing _ _, floor cleaning _ = agent and other moderate cleaning (four). Or double-faced water: release liquid agent, can be diluted into glass cleaner and other mild cleansing 9 200829694 Or use to wash flowers, improve soil acid value, prevent pests and promote plant growth. Since the invention has high water solubility, it is easy to clean, has a small amount of water, can save energy such as electric power and hydraulic power during cleaning, and has high-efficiency cleaning ability, and has a quick cleaning effect on oil stains and blood ulcers, and the sterilizing agent also makes the object to be cleaned. It is not easy to breed bacteria and prolong the service life of the materials to be cleaned. The universal cleaning agent of the present invention may further comprise a ingredients, wherein the flavoring agent may be selected from the group consisting of fennel seed oil, balsam, basil, camphor, cinnamon, r I citronella, edulis, medlar, coumarin, alfalfa, cumin. , ginger, grapefruit, juniper, lemon, maple oil, musk ketone, bean glutinous rice, orange, patchouli, mint, sage, sassafras, spearmint, lavender, winter green, geraniol Such a combined group. The preparation method of the invention adopts knife-cutting and pushing and stirring, and the aforementioned powdery raw material is uniformly stirred. According to the main cleaning application, the aqueous mixture formula of the invention can be changed in different proportions, but attention should be paid to the polymerization ability between the mixtures. When the powder is added to the water, the mixing will not become thick. For example, 50% carbonate, 5% sodium citrate and 30% sodium sulphate hydrate are placed in a horizontal scrambler for 10 minutes; 5% coconut oil is added in a disturbed state, and then stirred. After 10 minutes, add 5% coconut oil fatty acid under stirring, continue to add 5% percarbonate under stirring, stir for another 10 minutes, and finally add appropriate multiples of water (such as 7 times) of the above mixture. Can be dispensed. After the addition of the percarbonate, the desired perfume raw material can be added under stirring. 10 200829694 Chemical clearing > Because of the secondary pollution, the tincture emphasizes phosphorus-free, soft and high biodegradability. Therefore, "biodegradability" represents the safety of detergents. The more natural detergents have higher "biodegradability", and the petrochemical cleaners have very low biodegradability, so petrochemical cleaners are not easily affected by microorganisms. Decomposition will remain in the water and pollute the environment. If it is used for personal cleansing, it will not be easily metabolized after absorption through the skin. It will accumulate in the human body, causing chronic toxicity and risk of carcinogenesis. ^ As long as it is a surfactant (whether natural or synthetic, soft or hard), there will be different degrees of contamination. There are many types of "surfactants" on the market, and there are natural and "synthesis agents" synthesized by petrochemicals. How do you distinguish between good and bad? In fact, all of the "surfactants" can be decomposed by the living bacteria of nature, but some are relatively easy, and some are not easy to distinguish, this is the level of "biodegradability". The degree of "biodegradation" is generally measured by biochemical oxygen demand (BOD). According to the standard "biodegradability", the percentage of the solution containing the clean J agent is decomposed and decomposed by microorganisms after eight days. The ingredients of the raw materials of the raw materials have more natural substances: the environmental labeling standards require that the "biodegradability" of the cleaning products reach above. While the aqueous mixture formulation of the present invention is a raw material which can be decomposed by a large natural living bacteria, the mixture of the present invention is as safe as a general edible food. The above is only the preferred embodiment of the present invention and is not intended to limit the scope of the practice of the present invention. That is, the equivalent changes and modifications made by the patent scope of the invention in the invention are covered by the scope of the invention. [Simple description of the diagram] None. [Main component symbol description] No 0 Ο 12