TW200800021A - Pest-controlling agent and a method for using the same - Google Patents

Pest-controlling agent and a method for using the same Download PDF

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TW200800021A
TW200800021A TW095121359A TW95121359A TW200800021A TW 200800021 A TW200800021 A TW 200800021A TW 095121359 A TW095121359 A TW 095121359A TW 95121359 A TW95121359 A TW 95121359A TW 200800021 A TW200800021 A TW 200800021A
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halogen
compound
alkyl
activity
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TW095121359A
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Chinese (zh)
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Kazuyuki Sakata
Tetsuyoshi Nishimatsu
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Nihon Nohyaku Co Ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/541,3-Diazines; Hydrogenated 1,3-diazines
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/16Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

To provide a pest-controlling agent comprising at least one compound selected from a substituted aminoquinazolinone compound and salts thereof represented by general formula(1) (wherein, R represents hydrogen atom, (C1-C6)) alkylcarbonyl, (C1-C6) alkoxycarbonyl, (C1-C6)alkoxycarbonyl(C1-C3)alkyl, R1 represents pyridyl and the like, Z represents-N(R3)-CH(R2)-(in formula, R2 represents a hydrogen atom or (C1-C6)alkyl and the like, R3 represents a hydrogen atom or(C1-C6)alkyl and the like), each X is same or different, and represents bromine atom, halo (C1-C8)alkyl, halo(C1-C6)alkoxy, halo(C1-C6)alkylthio and the like, n represents an integral of 1 to 4, and at least one compound selected from a compound having insecticidal, acaricidal, or nematocidal activity, as effective ingredient, and a method for using the same.

Description

200800021 ,九1發明說明:- — — — — 【發明所屬之技術領域】 .本發明乃關於藉由含有做為殺蟲劑或殺蜗劑用途之經 取代之胺基喹唑啉酮化合物或其鹽,以及含有選擇自具= 殺蟲活性、殺蟎活性或殺線蟲活性之化合物中丨種或2'種 以上之化合物,而能發揮協同作用之有害生物防除劑及其 使用方法。 八 【先前技術】 • 本發明之有害生物防除劑之有效成分之經取代之胺基 喹唑啉酮化合物乃周知化合物,據記載具有殺蟲活性或殺 線蟲活性(例如參考專利文獻〗及2,特別是參照專利文獻 2為要)。 又,具有殺蟲活性、殺蟎活性或殺線蟲活性之化合物 分別係文獻中周知者(例如參照非專利文獻i、專利文獻 3),專利文獻4中揭示含有經取代之胺基喹唑啉酮(硫酮) ⑩衍生物以及具有殺蟲活性或殺蟎活性之化合物可提供防除 有害生物用途。 專利文獻1:日本專利特開平8-325239號公報 專利文獻2:日本特開2〇〇1-342186號公報 專利文獻3:日本特開2〇〇1-131141號公報 專利文獻4 :日本特開2〇〇1_64107號公報 非專利文獻 1 · The Pesticide Manual 第 13 版,2003 年 【發明内容】 318305 5 200800021 &quot;(發明所欲解決之課題)-- ----------------------- 一 ------------ 本發明之目的乃提供在分別單獨使用經取代之胺基喹 唑啉酮化合物或具有殺蟲活性,殺蟎活性或殺線蟲活性之 化合物時’不可能防除或很難防除之有害生物能加以有效 防除之有害生物防除劑及其使用方法。 (解決課題之手段) 本發明研究者為解決上記課題,經努力再三研究結 果’發現將下列一般式⑴所示經取代之胺基喹唑啉酮化合 ⑩物,其中,特別是使用^乙醯基_3,4•二羥-3_[(3_吡啶甲基) 胺基]-6_[1,2,2,2-四氟·ι_(三氟甲基)乙基](1H)_喹唑啉 酮,以及選擇自具有殺蟲、殺蟎或殺線蟲活性之化合物中 1種或2種以上之化合物加以併用,能有效率地防除包括 上述各單一化合物所難以防除之有害生物之複數個有害生 物,而完成了本發明。 換言之,本發明由下列項目所構成·· _ π]—種有害生物防除劑,係含有一般式(1)所示經取代之胺 基喹唑啉酮化合物及其鹽類中選擇1種以上之化合物,以 及自具有殺蟲活性、殺蟎活性或殺線蟲活性之化合物中選 擇1種或2種以上之化合物作為有效成分, 一般式[I]200800021, IX1 invention description: - - - - - [Technical field of the invention] The present invention relates to a substituted aminoquinazolinone compound or the like thereof, which is used as an insecticide or a sizing agent A salt, and a pest control agent capable of exerting a synergistic effect and a method for using the same, which comprises a compound selected from the group consisting of insecticidal activity, acaricidal activity or nematicidal activity, or a compound of 2' or more. VIII [Prior Art] The substituted amino quinazolinone compound which is an active ingredient of the pest control agent of the present invention is a known compound which has been described as having insecticidal activity or nematicidal activity (for example, refer to Patent Documents and 2, In particular, reference is made to Patent Document 2). Further, compounds having insecticidal activity, acaricidal activity or nematicidal activity are known in the literature, respectively (for example, refer to Non-Patent Document i, Patent Document 3), and Patent Document 4 discloses a substituted aminoquinazolinone. (thione) 10 derivatives and compounds having insecticidal or acaricidal activity provide pest control. Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. 2〇〇1_64107 Bulletin Non-Patent Document 1 · The Pesticide Manual 13th Edition, 2003 [Invention Content] 318305 5 200800021 &quot;(The subject of the invention) ------------ ------------------------------ The object of the present invention is to provide a substituted amino quinazolinone compound or insecticidal activity, respectively. , a compound of acaricidal activity or nematicidal activity, a pest control agent which is impossible to control or difficult to control, and a method for using the same. (Means for Solving the Problem) In order to solve the above problem, the inventors of the present invention have tried to reproduce the results of the above-mentioned 'the following general formula (1) substituted amino quinazolinone compound 10, wherein, in particular, _3,4•Dihydroxy-3_[(3_pyridylmethyl)amino]-6_[1,2,2,2-tetrafluoro·ι_(trifluoromethyl)ethyl](1H)_quin Oxazolinone, and one or more compounds selected from compounds having insecticidal, acaricidal or nematicidal activity, can be used in combination to effectively control a plurality of pests which are difficult to control by including the above single compounds. The present invention has been completed by pests. In other words, the present invention is composed of the following items: _ π π - a pest control agent, which contains one or more selected ones of the substituted amino quinazolinone compounds represented by the general formula (1) and salts thereof. a compound, and a compound having one or more compounds selected from the group consisting of insecticidal activity, acaricidal activity or nematicidal activity as an active ingredient, general formula [I]

318305 200800021 * 、上式中,R,:— — — 一 - (1) 氫原子, (2) 曱醯基, (3) (Ci_Ci2)烧基’ (4) 鹵化(CVC6)烷基, (5) (C2-C6)烯基, (6) (C2-C6)炔基, (7) (。-(:6)烷硫基, 參 ⑻鹵化(CVC6)燒硫基, (9)(CVC6)烷基羰基, (l〇)(C3-C6)環烷基羰基, (11XCKC6)烷氧基羰基, (12)(CVC6)烷氧基羰基(CVC3)烷基, (1 3)(Ci_C6)烧氧基(C1-C3)烧基幾基, (14)苯基羰基, φ (15)具有自鹵素原子、硝基、氰基、(CVC6)烷基、s (CVC6)烧基、(Cl-C6)烧氧基、鹵(C]rc6)烧氧基、(Cl_C6) 烷硫基及鹵(CrC:6)烷硫基所構成群中選擇丨至5個取代基 之苯基羰基(具有複數個取代基時,該取代基可為相同或不 同), (16) 苯基(C2-C6)烯基, (17) 在其環上具有自幽素原子、硝基、氰基、(Ci_C6) 烧基、函(Cl-C6)烧基、(Ci_C6)烧氧基、函(C1_C6)烧氧基、 (CVQ)烧硫基、鹵(Ci_c6)烧硫基及(CVC2)伸烧基二氧基中 318305 7 200800021 選擇Γ至5個取代基之苯-基(C!尤6)婦1 (具,複數個取代-¾ 時,該取代基可為相同或不同)1 (18) 苯基(c2_C6)炔基,或 (19) 在其環上具有自鹵素原子、硝基、氰基、(C^CO 烷基、鹵(Κ6)烧基、(C「C6)烷氧基、鹵(CVC6)烷氧基、 (Ci-C6)烧硫基、鹵(Ci-Ce)燒硫基及(C^-C^)伸烧基二氧基中 選擇1至5個取代基之苯基(C2-C4)炔基(具有複數個取代基 時,該取代基可為相同或不同), R1示吡啶基或吡啶-N-氧化物基、Z示_N=C(R2)_(式 中,R2示氫原子、(CVC6)烷基或鹵(CirC6)烷基)或 n(r3)-ch(r2H式中,r2 示氫原子、(cr_c6)烧基或 _ (c^-q) 烷基,R3示氫原子或(CrQ)院基,X示: (1) 溴原子, (2) 碘原子, (3) 羥基, (4) (CVC6)烷基, (5) (C2-C6)烯基, (6) (CVC6)炔基, (7) 幽(CVC8)烷基, (8) ((^/6)烷氧基, (9) 鹵(CVC6)烷氧基, (10) 鹵(Ci-C6)烷硫基, (11) 鹵(Ci-C6)烧基亞石黃酸基, (12) 鹵(CVQ)烷基磺醯基, 318305 8 200800021 … Γ13)鹵(CfCJ炫氧基鹵化XCi-CJ烷氧基「 _ 一 (14) 羧基, (15) ((^^6)烷氧基羰基’ (16) 胺基羰基, (17) 具有自(Q-C6)烷基、(C2-C6)烯基及(C2_C6)炔基中 選擇1至2個取代基之經取代胺基羰基(具有複數個取代基 時,該取代基可為相同或不同), (18) 苯基, ⑩ (19)具有自鹵素原子、硝基、氰基、(CVC6)烧基、鹵 (Ci_C6)烧基、(Ci-C6)烧氧基、鹵(Ci.Cg)烧氧基、(Ci_C6) 烷硫基及鹵(CrC6)烷硫基中選擇1至5個取代基之經取代 苯基(具有複數個取代基時,該取代基可為相同或不同構 造), (20) 苯基(Ci-C3)烧基, (21) 在其壤上具有自鹵素原子、石肖基、氰基、(c^cj 鲁烷基、鹵(CVQ)烷基、(CVCd烷氧基、鹵(CVC6)烷氧基、 (G-C6)烧硫基及鹵(CrC6)烧硫基中選擇1至5個取代基之 經取代苯基(CkC3)烧基(具有複數個取代基聘,該取代基可 為相同或不同), (22) 苯基氧基,或 (23) 具有自鹵素原子、硝基、氰基、(Ci_C6)烷基、齒 (CVC6)烧基、(CrC6)烧氧基、4(Ci_c6)^氧基、(Ci_c6) 烷硫基及鹵(Ci-C:6)烷硫基中選擇丨至5個取代基之經取代 苯基氧基(具有複數個取代基時,該取代基可為相同或不 318305 9 200800021 w 1¾ ) ’ η 示 1 至 4 之签數}; ------------— — —— — — [2] 上述[1]項之有害生物防除劑,其中,R示氫原子、 声基、(c2-c6)烯基、(cvc6)炔基、(Cl-c6)烧基M基、(CkC6) 烧氧基幾基、或(CKC6)烷氧基(CVC3)烷基羰基, -Z-R1 示-NH-CHyR1 或-N^CH-Rk式中,R1 示吡啶基 或吼啶氧化物基), X不溴原子、碘原子、鹵(Cr_C8)烷基、(cvc6)烷氧基、 鹵(eve:6)烷氧基、鹵(Cl_C6)烷硫基、鹵(Ci_c6)烷氧基鹵 ⑩(Ci_C6)烧氧基、或(c^c:6)烧氧基羰基,1至2之整數; [3] 上述[1]項之有害生物防除劑,其中,r示(Ci_c6)烷基羰 基、-Z-R1 *_NH-CH2_ri(式中,Rl 示吡啶基),χ 示鹵(Ci_C8) 烧基’η示1之整數; [4] 上述[1 ]項之有害生物防除劑,其中,經取代之胺基啥峻 琳酮化合物或其鹽類係乙醯基_3,4_二氫_3_[(3_σ比咬甲基) 版基]-6-[1,2,2,2-四氟_1-(三氟甲基)乙基]-2(111)啥唾嘛酮 •或其鹽類, [5] 上述[η項之有害生物防除劑,其中,具有殺蟲活性、殺 蟎活性或殺線蟲活性之化合物係乙醯膽鹼酯酶阻礙劑、乙 醯膽鹼受體阻礙劑、GABA調控氯化物通道促效劑、鈉通 道調控劑、尼古丁性乙醯膽鹼受體促效劑、乙醯膽鹼受體 促效劑、氯化物通道活化劑、保幼激素(juvenilehQi&gt;mQn0 模擬物、氧化性磷酸化阻礙劑及ATP形成阻礙劑、氯離子 梯度擾亂所致氧化性填酸化之解偶聯劑,對於同翅目之幾 丁生合成阻礙劑(丨型)、蜆皮素促效劑/脫皮阻礙劑、章备 318305 10 200800021 …涎胺促1劑、1置Γ電子傳遞系阻礙(ME T I劑)「位置Π -電子傳遞系阻礙劑、脂質生合成阻礙劑、蘭尼定受體調控 劑或具有非特異性作用機制(選擇性攝食阻礙)之化合物; [6]上述[1]項之有害生物防除劑,其中,具有殺蟲活性、殺 蟎活性或殺線蟲活性之化合物係METI劑系殺蟲劑、殺蟎 劑、噻二畊IGR系殺蟲劑、擬除蟲菊酯系殺蟲劑、鈉通道 封阻系殺蟲劑、胺基曱酸系殺蟲劑、有機磷系殺蟲劑、具 鈣通道活化作用殺蟲劑、苯甲醯苯基脲系殺蟲劑、二醯肼 β系殺蟲劑; [7]上述[1]項之有害生物防除劑,其中,具有殺蟲活性、殺 虫高活性或殺線蟲活性之化合物係亞滅培(acetamiprid)、益 達胺(imidacloprid)、吡蟲胺(nitenpyram)、賽速安 (thiamethoxam)、可尼丁(cl〇thianidin)、狄諾呋喃318305 200800021 * , in the above formula, R,: — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — (C2-C6) alkenyl, (6) (C2-C6) alkynyl, (7) (.-(:6)alkylthio, quinone (8) halogenated (CVC6) sulfur-burning, (9) (CVC6) Alkylcarbonyl, (l〇)(C3-C6)cycloalkylcarbonyl, (11XCKC6)alkoxycarbonyl, (12)(CVC6)alkoxycarbonyl(CVC3)alkyl, (1 3)(Ci_C6) Oxy (C1-C3)alkyl, (14) phenylcarbonyl, φ (15) having a halogen atom, a nitro group, a cyano group, a (CVC6) alkyl group, an s (CVC6) alkyl group, (Cl- C6) a phenylcarbonyl group having an alkyl group selected from the group consisting of an alkoxy group, a halogen (C) rc6) alkoxy group, a (Cl_C6) alkylthio group and a halogen (CrC: 6) alkylthio group (having a plurality of substituents) a substituent, which may be the same or different, (16) phenyl (C2-C6) alkenyl, (17) having a self-clearing atom, a nitro group, a cyano group, (Ci_C6) on its ring Burning base, functional (Cl-C6) alkyl group, (Ci_C6) alkoxy group, functional (C1_C6) alkoxy group, (CVQ) sulfur-burning group, halogen (Ci_c6) sulfur-burning group and (CVC2) stretching base dioxygen Base 318305 7 200 800021 Select phenyl group based on 5 substituents (C! You 6) 1 (with multiple substitutions -3⁄4, the substituents may be the same or different) 1 (18) Phenyl (c2_C6) alkynyl Or (19) has a halogen atom, a nitro group, a cyano group, a (C^CO alkyl group, a halogen (Κ6) alkyl group, a (C "C6) alkoxy group, a halogen (CVC6) alkoxy group) , (Ci-C6) thiol group, halogen (Ci-Ce) thiol group and (C^-C^) decyl dioxy group selected from 1 to 5 substituents of phenyl (C2-C4) alkyne a group (when having a plurality of substituents, the substituents may be the same or different), R1 represents a pyridyl group or a pyridine-N-oxide group, and Z represents _N=C(R2)_ (wherein R2 represents a hydrogen atom (CVC6)alkyl or halo(CirC6)alkyl) or n(r3)-ch (in the formula r2H, r2 represents a hydrogen atom, (cr_c6)alkyl or _(c^-q) alkyl, and R3 represents hydrogen Atom or (CrQ), X shows: (1) bromine atom, (2) iodine atom, (3) hydroxyl group, (4) (CVC6) alkyl group, (5) (C2-C6) alkenyl group, (6) (CVC6) alkynyl, (7) sec (CVC8) alkyl, (8) ((^/6) alkoxy, (9) halogen (CVC6) alkoxy, (10) halogen (Ci-C6) Alkylthio, (11) halogen (Ci-C6) pyridene, (12) halogen ( CVQ) Alkylsulfonyl, 318305 8 200800021 ... Γ13) Halogen (CfCJ oxooxy halogenated XCi-CJ alkoxy" _-(14) carboxy, (15) ((^^6) alkoxycarbonyl' ( 16) an aminocarbonyl group, (17) a substituted aminocarbonyl group having 1 to 2 substituents selected from (Q-C6)alkyl, (C2-C6)alkenyl and (C2_C6)alkynyl groups (having plural In the case of a substituent, the substituent may be the same or different), (18) phenyl, 10 (19) having a halogen atom, a nitro group, a cyano group, a (CVC6) alkyl group, a halogen (Ci_C6) alkyl group, (Ci -C6) a substituted phenyl group having a substituent of 1 to 5 substituents selected from an alkoxy group, a halogen (Ci.Cg) alkoxy group, a (Ci_C6) alkylthio group and a halogen (CrC6) alkylthio group (having a plurality of substituents) Wherein, the substituent may be of the same or different structure), (20) phenyl (Ci-C3) alkyl, (21) having a halogen atom, a stone succinyl group, a cyano group, (c^cj rualkyl group) on its soil. a substituted benzene having 1 to 5 substituents selected from the group consisting of a halogen (CVQ) alkyl group, a (CVCd alkoxy group, a halogen (CVC6) alkoxy group, a (G-C6) thiol group, and a halogen (CrC6) sulphur group. a base (CkC3) alkyl group (having a plurality of substituents, the substituent may be a phase Or different), (22) phenyloxy, or (23) having a halogen atom, a nitro group, a cyano group, a (Ci_C6) alkyl group, a dentate (CVC6) alkyl group, a (CrC6) alkoxy group, and a (Ci_c6) group. a substituted phenyloxy group selected from the group consisting of an oxy group, a (Ci_c6) alkylthio group and a halogen (Ci-C: 6) alkylthio group to 5 substituents (having a plurality of substituents, the substituent may be For the same or not 318305 9 200800021 w 13⁄4 ) ' η shows the number of signatures 1 to 4}; ------------ — — — — — [2] The pests of [1] above a controlling agent, wherein R represents a hydrogen atom, an acyl group, a (c2-c6)alkenyl group, a (cvc6)alkynyl group, a (Cl-c6)alkyl group, a (CkC6) alkoxy group, or (CKC6) Alkoxy (CVC3) alkylcarbonyl, -Z-R1 shows -NH-CHyR1 or -N^CH-Rk wherein R1 represents pyridyl or acridine oxide), X is not a bromine atom, an iodine atom or a halogen (Cr_C8)alkyl, (cvc6)alkoxy, halo(eve:6)alkoxy,halo(Cl_C6)alkylthio,halo(Ci_c6)alkoxyhalo10(Ci_C6)alkoxy, or (c ^c: 6) an alkoxycarbonyl group, an integer of 1 to 2; [3] The pest control agent of the above [1], wherein r is a (Ci_c6) alkyl group a group, -Z-R1 *_NH-CH2_ri (wherein R1 represents a pyridyl group), and a halogen (Ci_C8) alkyl group η is an integer of 1; [4] the pest control agent of the above [1], wherein The substituted amino-based quinone ketone compound or a salt thereof is acetyl group _3,4_dihydro_3_[(3_σ ratio methyl group) -6][1,2,2,2 -tetrafluoro-1-(trifluoromethyl)ethyl]-2(111)啥 嘛 酮 • 或其 或其 或其 或其 或其 或其 或其 或其 或其 或其 或其 η η η η η η η η η η η η η η η η η η η η η η η Acaricidal or nematicidal activity compounds are acetylcholinesterase inhibitors, acetylcholine receptor inhibitors, GABA-regulated chloride channel agonists, sodium channel modulators, nicotine acetylcholine receptors Agonists, acetylcholine receptor agonists, chloride channel activators, juvenile hormones (juvenilehQi>mQn0 mimics, oxidative phosphorylation inhibitors and ATP formation inhibitors, oxidative properties caused by chloride ion gradient disturbance Acid-filled uncoupling agent, for the homopterin synthesis inhibitor (丨 type), quercetin agonist / peeling inhibitor, Zhang Bei 318305 10 200800021 ... guanamine promotes 1 dose, 1 set Electricity Delivery line obstruction (ME TI agent) "position Π - electron transport system inhibitor, lipid biosynthesis inhibitor, ryanodine receptor modulator or compound with non-specific mechanism of action (selective food barrier); [6] The pest control agent according to the above [1], wherein the compound having insecticidal activity, acaricidal activity or nematicidal activity is a METI agent, an insecticide, an acaricide, a thiazide IGR insecticide, and a pyrolysis agent. Pyrethroid insecticide, sodium channel blocking insecticide, amine phthalic acid insecticide, organophosphorus insecticide, calcium channel activating insecticide, benzamidine phenyl urea [7] The pest control agent according to the above [1], wherein the compound having insecticidal activity, insecticidal activity or nematicidal activity is acetamiprid, Imidacloprid, nitenpyram, thiamethoxam, cl〇thianidin, dinofuran

(dinotefuran)、提銨(thiacloprid)、氟啶蟲醯胺 (Flonicamid)、卡巴利(carbaryl)、免扶克(BPMC ; fenobucarb)、滅必蝨(MIPC ; isoprocarb)、愛芬克 (ethiofencarb)、比加克(卩11111^〇31*1))、歐殺滅(〇乂&amp;111)^1)、免 扶克(benfuracarb)、滅賜克(methiocarb)、滅財填 (mecarbam)、硫敵克(thiodicarb)、得滅克(aldicarb)、棉鈴 威(alanycarb)、必芬治(metolcarb)、黃利克(xylycarb)、安 丹(propoxur)、卡波呋喃(carbofuran)、丁基加保扶 (carbosulfan)、σ夫線威(furathiocarb)、安殺番(endosulfan)、 涕滅威(aldoxycarb)、納乃得(11^1;11〇11^1)、氣氟氰菊酯 (cyhalothrine)、百滅寧(permethrin)、赛滅寧 11 318305 200800021 -(c^permetHrin)、 石夕護芬(silafluofen)、賽扶寧(cyfiuthrin)、貝他賽扶寧 (beta-cyfluthrin)、泰滅寧(traiomethrin)、除蟲菊素 (pyrethrin)、右旋烯丙菊酯(aiiethrin)、阿納寧 (acrinathrin)、普列亞寧(praliethrin)、異列滅寧 (esmethrin)、七氟菊酯(tefluthrin)、芬普寧(fenpropathrin)、 亞滅寧(alpha_cypermethrin)、赛洛寧 (lambda-cyhalothrin)、第滅寧(deltamethrin)、芬化利 _ (fenva-lerate)、艾芬利(esfenvalerate)、護賽寧 (flucythrinate)、福化利(fluvalinate)、乙氰菊酯 (cycloprothrin)、醚菊酯(ethofenprox)、阿維菌素(dinotefuran), thiacloprid, flonicamid, carbaryl, BPMC, fenobucarb, miPC; isoprocarb, ethiofencarb, Bigac (卩11111^〇31*1)), euthium (〇乂&amp;111)^1), benfuracarb, methocarb, mecarbam, sulfur Thiodicarb, aldicarb, alanycarb, metolcarb, xylycarb, propoxur, carbofuran, butyl plus (carbosulfan), furathiocarb, endosulfan, aldoxycarb, nanet (11^1;11〇11^1), cyhalothrine, Permethrin, 赛灭宁11 318305 200800021 -(c^permetHrin), silafluofen, cyfiuthrin, beta-cyfluthrin, and tyranoline Traiomethrin), pyrethrin, aiiethrin, acrinathrin, praliethrin, heterologous Esmethrin, tefluthrin, fenpropathrin, alpha_cypermethrin, lambda-cyhalothrin, deltamethrin, fenva- Lerate), esfenvalerate, flucythrinate, fluvalinate, cycloprothrin, ethofenprox, avermectin

(avermectin)、密滅汀(milbemectin)、因滅汀(emamectin)、 賜諾殺(spinosad)、撲滅松(fenitrothion)、馬拉松 (malathion)、滅大松(methidathion)、芬殺松(fenthion)、大 利松(diazinon)、異亞颯填(oxydeprofos)、凡米松 (vamidothion)、亞特松(pirimiphos-methyl)、陶斯松 (chlorpyriphos)、托福松(terbufos)、普伏松(ethoprophos)、 雙特松(cadusafos)、芬滅松(fenamiphos)、凡福松 (fensulfothion)、DSP、除線鱗(dichlofenthion)、福赛絕 (fosthiazate)、依賽米多扶(isamidofos)、丁硫環鱗 (fosthietan)、依殺松(isazofos)、谷速松(azinphos-methyl)、 二硫扶(disulfotion)、乙醯曱石粦胺(oxydemeton-methyl)、巴 拉松(parathions)、特布皮利扶(tebupirimfos)、艾殺松 (ethion)、三氯松(trichlorfon)、曱胺石粦(metamidophos)、二 12 318305 200800021 …氯松XdichBrvosX、美文松(nrevlnplios)、—亞素靈 — 一 (monocrotophos)、大滅松(dimethoate)、覆滅(formetanate)、 扶木松(formothion)、乃力松(naled)、甲基巴拉松 (methylparathion)、殺模腈(cyanophos)、二米達松 (diamidafos)、加護松(propaphos)、甲丙硫石粦(sulprofos)、 普硫松(prothiofos)、佈飛松(profenofos)、亞芬松 (isofenphos)、亞培松(temephos)、赛達松(phenthoate)、三 峻硫填(&lt;1丨11^1;1171¥丨叩]1〇3)、氯芬硫鱗(〇111〇1£6¥丨叩1108)、樂本 參松(tetrachlorvinphos)、肟硫構(phoxim)、加福松 (isoxathion)、白克松(pyraclofos)、陶斯松 (chlorpyrifos-methyl)、必芬松(pyridafenthion)、飛賽隆 (phasalone)、飛斯美(phasmet)、殺力松(dioxabenzofos)、 拜裕松(quinalphos)、甲硫松(11^5111[61^〇5)、歐殺松 (acephate)、培丹(cartap)、硫賜安(thiocyclam)、免速達 (bensultap)、硫速達(thiosultap)、芬普瞒(fenpyroximate)、 φ畢達本(pyridaben)、σ比蜗胺(tebufenpyrad)、唾蟲蜗胺 (tolfenpyrad)、芬殺(fenazaquin)、畢汰芬(pyrimidifen)、魚 藤精(rotenone)、愛美隆(117(!以11^1:1171|1〇11)、亞酉昆 (acequinocyl)、嘴蜗醋(][111&amp;。7卩}^111)、氟唆胺(1!11&amp;2111&amp;111)、 氟苯二醯胺(flubendiamide)、氟蟲清(fipronil)、乙醢普 (acetoprole)、乙蟲清(ethiprole)、歐蟎多(卩1*〇卩&amp;巧^6)、因得 克(indoxacarb)、美他氟米隆(metaflumizone)、滅蟎猛 (quinomethionate)、汰芬諾克(diafenthiuron)、賽海克汀 (cyhextin)氫氧化物、芬佈賜(fenbutatin oxide)、三亞蜗 13 318305 200800021(avermectin), milbemectin, emamectin, spinosad, fenitrothion, malathion, methidathion, fenthion, ali Diazinon, oxydeprofos, vamidothion, pirimiphos-methyl, chlorpyriphos, terbufos, ethoprophos, bis-spec pine Cadusafos), fenamiphos, fensulfothion, DSP, dichlofenthion, fosthiazate, isamidofos, fosthietan, Isazofos, azinphos-methyl, disulfotion, oxydemeton-methyl, parathions, tebupirimfos, Ethion, trichlorfon, metamidophos, II 12 318305 200800021 ...Clison XdichBrvosX, nrevlnplios, sulphate-monocrotophos, amazepine (dimethoate), destroy (fo Rmetanate), formothion, naled, methylparathion, cyanophos, diamidafos, propaphos, methyl propane sulphide Sulprofos, prothiofos, profenofos, isofenphos, temephos, phenthoate, sanjun sulfur (&lt;1丨11 ^1;1171¥丨叩]1〇3), Chlorpheniramine scales (〇111〇1£6¥丨叩1108), tetrachlorvinphos, phoxim, isoxathion , pyraclofos, chlorpyrifos-methyl, pyridafenthion, phasalone, phasmet, dioxabenzofos, quinalphos, methyl sulphide Pine (11^5111[61^〇5), acephate, cartap, thiocyclam, bensultap, thiosultap, fenpyroximate Φpyridaben, σ than tebufenpyrad, tolfenpyrad, fenazaquin, dysentery (Pyrimidifen), rotenone (Rotenone), Emilion (117 (at 11 ^ 1:! 1171 | 1〇11), ethylene unitary Queensland (acequinocyl), vinegar nozzle scroll (] [111 &amp;. 7卩}^111), fluridamide (1!11 &amp; 2111 &amp; 111), flubendiamide, fipronil, acetoprole, ethiprole,螨 螨 (卩1*〇卩&amp;巧^6), indoxacarb, metaflumizone, quinomethionate, diafenthiuron, seyheike Cyhextin hydroxide, fenbutatin oxide, Sanya snail 13 318305 200800021

CamitrazT、螺蟎 1旨(spiroiirclofen:)、季®T曱蟎酯一 — (spiromesifen)、螺四蟎酯(Spir〇tetramat)、溴蟲腈 (chlorfenapyr)、百蟎克(binapacryl)、克氯苯 (chlorbenzilate)、紛硫殺(phenisobromolate)、TPIC、於驗 硫酸鹽(nicotine-sulfate) 、瀏陽黴素(polynactins)複合物、 印楝素(azadirachtin)、經丙基澱粉(hydroxyprOpyl starch)、 摩朗得(morantel)酒石酸鹽、油酸鈉鹽、油酸鉀、啶蟲丙醚 (pyridalyl)、替扶苯隆(teflubenzuron)、克福隆CamitrazT, spiroiirclofen:, piromesifen, spir〇tetramat, chlorfenapyr, binapacryl, chlorobenzene (chlorbenzilate), phenisobromolate, TPIC, nicotine-sulfate, polynactins complex, azadirachtin, hydroxyprOpyl starch, morron Morantel tartrate, sodium oleate, potassium oleate, pyridalyl, teflubenzuron, kefulong

(chlorfluazuron)、二氟苯隆(diflubenzuron)、六伏隆 (hexaflumuron)、敵草胺(novaluron)、祿芬隆(lufenuron)、 氟蟲脲隆(fluenoxuron)、得芬諾(tebufenozide)、曱氧芬諾 (methoxyfenozide)、克馬芬諾(chromafenozide)、鹵芬諾 (halofenozide)、二芬隆(diofenolan)、布芬淨(buprofezin)、 丙胺明1 (cyromazine)、烯蟲酯(methoprene)、烯蟲乙酯 (hydroprene)、百利普芬(pyriproxyfen)、芬諾克 (fenoxycarb)、派滅淨(pymetrozine)、克芬淨(clofentezine)、 合赛多(hexythiazox)、芬硫克(fenothiocarb)、依殺螨 (etoxazole)、聯苯菊酯(bifenazate)、大克蟎(kelthane ; dicofol)、西脫蟎(benzoximate)、得脫瞒(tetradifon)、邁隆 (dazomet)、填克敵(phosphocarb)、左咪唆鹽酸鹽(levamisol HC1)、阿苯達唾(albendazole)、奥苯達峻(oxibendazole)、 芬苯達唑(fenbendazole)、奥芬達峻(oxfendazole)、威百故 (metam-sodium)、唾虫牙威(triazamate)或蘇力菌(Bacillus thuringiensis ; BT); 14 318305 200800021 ,[8]王:述[1]項有害生物餘除劑,其中,具有殺蟲活性、殺蟎 活性或殺線蟲活性之化合物係芬普蜗(fenpyroximate)、免 扶克(fenobucarb ; BPMC)、滅必兹(isoprocarb ; MIPC)、口比 蜗胺(tebufenpyrad)、峻蟲瞒胺(tolfenpyrad)、布芬淨 (buprofezin)、美他氣米隆(metaflumizone)、得芬諾 (tebufenozide)、溴蟲腈(chlorfenapyr)、福化利 (fluvalinate)、替扶苯隆(teflubenzuron)或氟苯二醯胺 (flubendiamide); ⑩[9]上述[1]至[8]項中任一項之有害生物防除劑,其中,經 取代之胺基喹唑啉酮化合物係1-乙醯基-3,4-二氫-3-[(3-吡 啶曱基)胺基]·6_[1,2,2,2-四氟_1-(三氟甲基)乙基]-2(1Η)-喹 唾淋酮,而具有殺蟲活性、殺瞒活性或殺線蟲活性之化合 物係布芬淨(buprofezin)、美他氣米隆(metaflumizone)或氟 苯二醯胺(flubendiamide); [10] 上述[1]至[9]項中任一項之有害生物防除劑,其中,相 0對於1重量份之經取代之胺基喧唾淋酮化合物,自具有殺 蟲活性、殺蟎活性或殺線蟲活性之化合物中選擇1種或2 種以上之化合物之比例為0.01至2000重量份; [11] 一種有害生物防除劑之使用方法,用於自有害生物保 護有用植物,係以有效量之上述[1]至[1〇]項中任一項之有 害生物防除劑,處理對象之有害生物、對象之有用植物、 對象之有用植物之種子、土壤或栽培介質; [12] —種有害生物之防除方法,用於防除有害生物,係將 上述[1]之一般式⑴所示經取代之胺基喹唑啉酮化合物及 15 318305 200800021 …其鹽類中選擇i-種以上之化合物,以及自具有殺蟲-活性 殺蟎活性或殺線蟲活性之化合物中選擇1種或2種以上之 化合物作為有效成分之有害生物防除劑,以有效成分量 計’每公故以0·1至1000g進行處理; [13] —種上述[1 ]所記載之一般式⑴所示經取代之胺基啥 唾啉酮化合物及其鹽類中選擇一種以上之化合物之用途, 係用於製造含有自上述[1]項所記載之一般式⑴所示經取 代之胺基喹唑啉酮化合物及其鹽類中選擇一種以上之化合 _物,以及自具有殺蟲活性、殺蟎活性或殺線蟲活性之化合 物中選擇1種或2種以上之化合物之有害生物防除劑;以 及 Π4]—種為防除有害生物使用而包裝之有害生物防除劑, 係以相對於上述[1]項所記載之一般式⑴所示經取代之胺 基喹唑啉酮化合物或其鹽類1重量份,含有自具有殺蟲活 性、殺蟎活性或殺線蟲活性之化合物中選擇1種或2種以 φ上之化合物以0·01至2000重量份之比例,並將自上述[1] 項所記載之一般式(I)所示經取代之胺基啥峻琳酮化合物 及其鹽類中選擇1種以上之化合物,以及自具有殺蟲活 性、殺蜗活性或殺線蟲活性之化合物中選擇1種或2種以 上之化合物,每公故以〇·1至l〇〇〇g之比例,加以包裝而 成。 (發明之效果) 含有自一般式(I)所示經取代之胺基喹唑啉酮化合物 及其鹽類中選擇一種以上之化合物,以及自具有殺蟲活 16 318305 200800021 -性、殺瞒活性-或殺線蟲活I之―化合物中選擇1種或2種汉 上之化合物作為有效成分之有害生物防除劑(以下,簡稱為 —本,,之有害生物防除劑),於各個單劑無法獲得充分效果 的藥里也能發揮顯著效果,於單劑無法防除之有害生物及 表現抗藥性等之有害生物類等,皆具有顯著之防㈣果, 因此,對於作物之更一層之生產效率有其貢獻。 【實施方式】 ' 本發明之一般式(1)所示經取代之胺基喹唑啉酮化人 •物或其鹽類中,各取代基之定義裡,「鹵素原子」示氣原子、 漠原子1原子或氟原子。「㈣基」示例如2+定基、 &gt;比唆基、44唆基等。「„比料·氧化物」補如2“比咬 -N-氧化物、3_吡啶_N_氧化物、4•吡啶-氧化物等。 又,「(Ci-Cy烷基」乃示碳原子數為1至12之直鏈狀 或支鏈狀之院基,例如甲基、乙基、正丙基、異丙基、i 丁基、異丁基、第二丁基、第三丁基、正戊基、異戊基、 # 2•甲基丁基、新戊基、卜乙基丙基、正己基、異己基、‘ 甲基戊基、3·甲基戊基、2_甲基戊基、1-甲基戊基、3,3_ 二甲基丁基、2,2-二甲基丁基、u_二甲基丁基、! 2-二甲 基丁基、二甲基丁基、2,3_二甲基丁基、^乙基丁基、 2-乙基丁基、正庚基、正辛基、正壬基、正癸基、正十一 烷基、正十二烷基等(但是略字中,「n_」示正,「i·」示異, 「s-」示第二,「t_」表示第三,以下皆同。) 八 「(c】_c8)烷基」乃示碳原子數為】至8之直鏈狀或支 鏈狀之烷基’例如甲基、乙基、正丙基、異丙基、正丁基、 318305 17 200800021 —異丁基、第二了基、第三-丁基―、正戍基、-異戊-基、L甲墓 丁基、新戊基、1 -乙基丙基、正己基、異己基、甲基戊 基、3-甲基戊基、2-甲基戊基、甲基戊基、3二甲基丁 基、2,2-二甲基丁基、ι,ΐ-二甲基丁基、it二甲基丁基、 1,3-二甲基丁基、2,3-二曱基丁基、^乙基丁基、孓乙基丁 基、正庚基、正辛基等。 「(Ci-C6)烧基」乃示碳原子數為i至6之直鏈狀或支 鏈狀之烷基,例如甲基、乙基、正丙基、異丙基、正丁基、 ♦異丁基、第二丁基、第三丁基、正戊基、異戊基、2_甲基 丁基、新戊基、1-乙基丙基、正己基、異己基、4_甲基戊 基、3-曱基戊基、2_曱基戊基、L曱基戍基、3,3_二曱基丁 基、2,2-二曱基丁基、U_二甲基丁基、u二甲基丁基、 1,3_二甲基丁基、2,3-二甲基丁基、j•乙基丁基、2_乙基丁 「(CkCO烷基」乃示碳原子數為i至3之直鏈狀或支 鏈狀之烷基’例如甲基、乙基、正丙基、異丙基等。 「(CVC2)伸烧基二氧基」乃示亞甲基二氧基 二氧基等。 产,a(,:C6)環燒基」乃示例如環丙基、環丁基、環戊 衣己基專%狀之碳原子數為3至6之烷基。 ^-〇6)燒氧基」乃示上述「(c^)燒基」中之 η烧氧基者,具體例如甲氧基、乙氧基、丙氧基 =基、丁氣基、異丁氧基、第三丁氧基、戊氧基” 318305 18 200800021 -「(C2_C6)烯基」乃示至—少具有一福雙鍵之碳-雇子數為 2至k直鏈狀或支鏈狀之烯基’例如乙婦基、卜丙稀基、 異丙烯基、1-丁烯基、2 - 丁擒其、7田甘 _ ^ 那丞 丁肺基甲基丙烯基、戊烯基、 戊二烯基、己烯基或已二烯基等。 …2丄6)炔基」乃不至少具有—卿二鍵之碳原子數/ 2至6之直鏈狀或支鏈狀之炔基,例如乙炔基、2_丙快基 丁块基、戊炔基、戊二炔基、己块基或己二炔基等。 「鹵(CkC8)烧基」乃示以相同或不同之一個以上之虐 ^原子所取友代之碳原子數為」至8之直鏈狀或支鏈狀之娱 如一亂甲基、五氟乙基、七氟丙基、“2,2,2·四氟-H; 氣土)乙基、2,2,2_三氟小(三氟甲基)乙基等。 「鹵(CVC6)院基」乃示以相同或不同之_個以上之產 所取代之碳原子數為1至6之直鏈狀或支鏈狀之炫 基’例如三敦甲基、五氟乙基、七氟丙基、咖四亂评 鼠甲基)乙基、2,2,2-三(三就甲基)乙基等。 又’「鹵(:❿烷氧基」、「鹵(C2_C6)烯基」或「鹵《。2心: 狀id&quot;7別為—個以上之上述鹵素原子所取代之直鏈 狀或支鏈狀之碳料數為〗至6巧氧基 數 =稀基或碳原子數為2至6之快基。當為2二 素原子取代時,該南素原子可為相同或不同。 基(c再:)二上,代基所聯結之基,例如「(cvc綱 土 i 6)、元土」乃示以(Ci_C6)烷基為主 1 “减取代時,該(Ci_c6)燒氧基可為相同或 318305 19 200800021 不同ο 又,一般式(I)所示經取代之胺基喹唑啉酮化合物之 -鹽,例如與鹽酸、硫酸、硝酸、磷酸等無機酸之鹽外,可 例示與鈉、鉀等鹼金屬鹽,鈣、鎂等鹼土類金屬鹽等,又, 該經取代之胺基喹唑啉酮化合物亦可為與銅、辞、鐵等過 渡金屬之鹽或其配位化合物。 本發明之一般式(I)所示經取代之胺基喹唑啉酮化合 物或其鹽類,在其構造式中存在有起因於碳_氮雙鍵之2種 _幾何異構物’本發明包括全部該各個幾何異構物以及其任 意比例之混合物。 一般(I)所示經取代之胺基喹唑啉酮化合物或其鹽類 中,較佳如R示氳原子,(Cl_Cl2)烷基、(C2_C6)烯基、(C2-C6) 快基、(CVC6)烷基幾基、(CVC6)烧氧基幾基,或(Ci_c6) 烧氧基(CVC3)烷基羰基、-Z-R1係-NH-CH2-R1,或 式中,Ri示吡啶基或吡啶-N_氧化物基),X係 ⑩溴原子、碘原子、鹵(Cl-c8)烷基、(Ci_C6)烷氧基、鹵(Ci_C6) 烷氧基、齒(cvc6)烷硫基、鹵(Cl_C6)烷氧£i(Ci_C6)烷氧 基,或(CrC6)烧氧基羰基,n示1至2之整數,更佳為i。 更佳例如R係(CVC6)娱:基幾基,-Z-R1係-NH-CH-R1 (式 中R示吼σ疋基),X係鹵(c〗_c8)烧基,η係1。上述中r1 所示吡啶基或吡啶-N-氧化物基,以3_吡啶基或弘吡啶_斗 氧化物基為更佳。 本發明中所使用第一有效成分之一般式(1)所示經取 代之胺基喹唑琳酮化合物,可按照日本專利特開平 318305 20 200800021 -8-325239號公報及特開2001-342186號公報中所記載方法 或類似方法製造之。特別是1-乙醯基-3,4-二氫-3-[(3-吡啶 甲基)胺基]-6-[1,2,2,2-四氟-1-(三氟甲基)乙基]-2(111)-喹唑 淋酮(1 -acetyl-3,4-dihydr0-3-[(3-pyridylmethyl)amino]-6-[l?25252-tetrafluoro-l-(trifluoromethyl)ethyl]-2(lH)-quinaz olinone(乃下列第1表中,Νο·15之化合物,下文中簡稱為 化合物(a),或表中單記載為(a))乃可按照日本專利特開 2001-342186號公報中所記載方法或類似方法製造之。 • 第1表或第2表中雖例示典型之化合物,惟本發明不 侷限於該範圍,可例舉例如日本專利特開平8-325239號公 報及特開2001-342186號公報中所公開化合物。 一般式(I)所示化合物包括一般式(I-1)所示化合物及 一般式(1-2)所示化合物。 一般式(1-1): 21 318305 200800021(chlorfluazuron), diflubenzuron, hexaflumuron, novaluron, lufenuron, fluenoxuron, tebufenozide, oxime Methoxyfenozide, chromafenozide, halofenozide, diofenolan, buprofezin, cyromazine, methoprene, eneph Hydroprene, pyriproxyfen, fenoxycarb, pymetrozine, clofentezine, hexythiazox, fenothiocarb, Etoxazole, bifenazate, kelthane; dicofol, benzoximate, tetradifon, dazomet, phosphocarb, Lemamisol HC1, albendazole, oxibendazole, fenbendazole, oxfendazole, metam-sodium ), Triazamate or Bacillus thur Ingiensis ; BT); 14 318305 200800021 , [8] Wang: [1] harmful pesticides, wherein the compound having insecticidal activity, acaricidal activity or nematicidal activity is fenpyroximate, Fenobucarb (BPMC), isoprocarb (MIPC), tebufenpyrad, tolfenpyrad, buprofezin, metaflumizone, Tebufenozide, chlorfenapyr, fluvalinate, teflubenzuron or flubendiamide; 10[9] above [1] to [8] A pest control agent according to any one of the preceding claims, wherein the substituted aminoquinazolinone compound is 1-ethylindolyl-3,4-dihydro-3-[(3-pyridinyl)amino] 6_[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]-2(1Η)-quinaldine, a compound having insecticidal activity, acaricidal activity or nematicidal activity a buprofezin, a metaflumizone or a flubendiamide; [10] the pest control agent according to any one of the above [1] to [9], wherein Phase 0 For 1 part by weight of the substituted aminoguanylidene compound, one or more compounds are selected from the compounds having insecticidal activity, acaricidal activity or nematicidal activity in a ratio of 0.01 to 2000% by weight. [11] A method for using a pest control agent for protecting a useful plant from a pest, and treating the object with an effective amount of the pest control agent according to any one of the above [1] to [1〇] a pest, a useful plant of a subject, a seed of a useful plant of a subject, a soil or a cultivation medium; [12] a method for controlling a pest, for controlling a pest, as shown in the general formula (1) of the above [1] Substituted amine quinazolinone compounds and 15 318305 200800021 ... among which a compound of i-type or more is selected, and one or two kinds of compounds having insecticidal-active acaricidal activity or nematicidal activity are selected. The above-mentioned compound as a pesticidal agent of an active ingredient is treated in an amount of from 0.1 to 1000 g per gram of the active ingredient; [13] is substituted by the general formula (1) described in the above [1]. Amine The use of one or more compounds selected from the group consisting of a sulfinone compound and a salt thereof for producing a substituted amino quinazolinone compound represented by the general formula (1) described in the above [1], and a salt thereof Selecting one or more compounds, and a pest control agent for selecting one or more compounds from compounds having insecticidal activity, acaricidal activity or nematicidal activity; and Π4]-species for controlling pests The pesticidal agent to be packaged is contained in an insecticidal activity per 1 part by weight of the substituted aminoquinazolinone compound or a salt thereof, which is represented by the general formula (1) described in the above [1]. One or two of the compounds having acaricidal activity or nematicidal activity are used in a ratio of from 0. 01 to 2000 parts by weight of the compound of φ, and the general formula (I) described in the above [1] One or more selected from the group consisting of a substituted amino group sulfonate compound and a salt thereof, and one or more compounds selected from compounds having insecticidal activity, bactericidal activity or nematicidal activity, Everything is 〇·1 L〇〇〇g proportion of, and to be packaged. (Effect of the Invention) A compound containing one or more selected from the group consisting of substituted amino quinazolinone compounds represented by the general formula (I) and salts thereof, and having insecticidal activity of 16 318305 200800021 - or a pest control agent (hereinafter, abbreviated as "the present, a pest control agent") which selects one or two kinds of compounds of the Han Chinese as a active ingredient in the compound of nematicidal activity I, which cannot be obtained in each single agent. The full-effect medicine can also exert significant effects, and the pests that cannot be prevented by a single dose and the harmful organisms that exhibit resistance, etc., have significant prevention (4). Therefore, the production efficiency of the crop layer is contribution. [Embodiment] In the substituted amino quinazolinone-containing compound or a salt thereof represented by the general formula (1) of the present invention, in the definition of each substituent, "halogen atom" means gas atom and desert. Atom 1 atom or a fluorine atom. Examples of "(4) base" are 2+ base, &gt; 唆 base, 44 唆, etc. "„Materials·oxides” complements 2 “Bit-N-oxide, 3_pyridine_N_oxide, 4•pyridine-oxide, etc. Also, “(Ci-Cy alkyl” is carbon a linear or branched chain of 1 to 12, such as methyl, ethyl, n-propyl, isopropyl, i-butyl, isobutyl, t-butyl, tert-butyl , n-pentyl, isopentyl, # 2 methyl butyl, neopentyl, ethyl propyl, n-hexyl, isohexyl, 'methylpentyl, 3 ·methylpentyl, 2 -methylpentyl , 1-methylpentyl, 3,3-dimethylbutyl, 2,2-dimethylbutyl, u-dimethylbutyl, ! 2-dimethylbutyl, dimethylbutyl, 2,3_Dimethylbutyl, ^ethylbutyl, 2-ethylbutyl, n-heptyl, n-octyl, n-decyl, n-decyl, n-undecyl, n-dodecyl Etc. (But in the abbreviation, "n_" is positive, "i·" is different, "s-" is second, and "t_" is third, the following are the same.) Eight "(c]_c8)alkyl" a linear or branched alkyl group having a carbon number of from 8 to 8, such as methyl, ethyl, n-propyl, isopropyl, n-butyl, 318305 17 200800021—isobutyl, second benzyl, tert-butyl-, n-decyl, iso-pentyl, L-tolyl butyl, neopentyl, 1-ethylpropyl, n-hexyl, isohexyl ,methylpentyl, 3-methylpentyl, 2-methylpentyl, methylpentyl, 3-dimethylbutyl, 2,2-dimethylbutyl, ι,ΐ-dimethylbutyl Base, it dimethylbutyl, 1,3-dimethylbutyl, 2,3-didecylbutyl, ethyl ethyl butyl, decyl ethyl butyl, n-heptyl, n-octyl and the like. "(Ci-C6)alkyl" is a straight or branched alkyl group having from 1 to 6 carbon atoms, such as methyl, ethyl, n-propyl, isopropyl, n-butyl, ♦ Isobutyl, t-butyl, tert-butyl, n-pentyl, isopentyl, 2-methylbutyl, neopentyl, 1-ethylpropyl, n-hexyl, isohexyl, 4-methyl Pentyl, 3-mercaptopentyl, 2-decylpentyl, L-decyldecyl, 3,3-didecylbutyl, 2,2-didecylbutyl, U-dimethylbutyl , u-dimethylbutyl, 1,3-dimethylbutyl, 2,3-dimethylbutyl, j-ethylbutyl, 2-ethylbutyl "(CkCO alkyl) is a carbon atom a linear or branch of the number i to 3 An alkyl group such as a methyl group, an ethyl group, a n-propyl group, an isopropyl group or the like. "(CVC2) a dialkyloxy group" is a methylene dioxydioxy group or the like. The "C6) cycloalkyl group is exemplified by an alkyl group having 3 to 6 carbon atoms in the form of a cyclopropyl group, a cyclobutyl group or a cyclopentahexyl group. ^-〇6) alkoxy group is shown above. (c^) methoxy group in the alkyl group, specifically, for example, methoxy, ethoxy, propoxy=yl, butylene, isobutoxy, tert-butoxy, pentyloxy" 318305 18 200800021 - "(C2_C6)Alkenyl" is a carbon which has a double bond and has a linear or branched alkenyl group of 2 to k, such as an ethyl group or a propylene group. Base, isopropenyl, 1-butenyl, 2-butane, 7 tian _ ^ 丞 肺 lung methacryl, pentenyl, pentadienyl, hexenyl or hexadienyl Wait. (2丄6) alkynyl) is a straight or branched alkynyl group having at least a carbon atom of 2 - 6 or a branched chain, such as an ethynyl group, a 2-propyl group, a pentyl group Alkynyl, pentadiynyl, hexyl or hexadiynyl, and the like. "Chalogen (CkC8) base" means that the number of carbon atoms in the same or different one or more atoms is "linear" or "chain" in the order of 8 to a linear or branched chain. Ethyl, heptafluoropropyl, "2,2,2·tetrafluoro-H; gaseous earth" ethyl, 2,2,2-trifluoro (trifluoromethyl)ethyl, etc. "halogen (CVC6) "hospital base" means a linear or branched singular group of 1 to 6 carbon atoms substituted with the same or different y or more productions, such as Sandon methyl, pentafluoroethyl, heptafluoro The propyl group and the coffee bean are all evaluated as methyl, ethyl, 2,2,2-tris(trimethyl)ethyl and the like. Also, 'halogen (: decyloxy), "halogen (C2_C6) alkenyl" or "halogen". 2 heart: id&quot; 7 is more than one of the above-mentioned halogen atoms substituted by linear or branched The number of carbonaceous materials is from 〗 〖 to 6 oxyl groups = dilute groups or fast radicals having 2 to 6 carbon atoms. When substituted with 2 dioxin atoms, the ruthenium atoms may be the same or different. :) On the second, the base to which the base is attached, for example, "(cvc subsoil i 6), meta-soil" is based on (Ci_C6) alkyl as the main 1 "substitution of substitution (Ci_c6) alkoxy can be The same or 318305 19 200800021 is different. Further, the salt of the substituted aminoquinazolinone compound represented by the general formula (I), for example, a salt with an inorganic acid such as hydrochloric acid, sulfuric acid, nitric acid or phosphoric acid, can be exemplified with sodium. An alkali metal salt such as potassium, an alkaline earth metal salt such as calcium or magnesium, or the like, and the substituted amino quinazolinone compound may be a salt of a transition metal such as copper, rhodium or iron or a complex thereof. The substituted aminoquinazolinone compound represented by the general formula (I) of the present invention or a salt thereof has two kinds of geometry derived from a carbon-nitrogen double bond in its structural formula The present invention includes all of the respective geometric isomers and a mixture thereof in any ratio. Among the substituted aminoquinazolinone compounds represented by the above (I) or a salt thereof, R is preferably a halogen atom. (Cl_Cl2)alkyl, (C2_C6)alkenyl, (C2-C6) fast radical, (CVC6) alkyl radical, (CVC6) alkoxy group, or (Ci_c6) alkoxy (CVC3) alkylcarbonyl , -Z-R1 is -NH-CH2-R1, or wherein R is pyridyl or pyridine-N-oxide, X is a 10 bromine atom, an iodine atom, a halogen (Cl-c8) alkyl group, Ci_C6) alkoxy, halo(Ci_C6)alkoxy, dentate (cvc6)alkylthio, halo(Cl_C6)alkoxy (i), or (CrC6) alkoxycarbonyl, n is 1 An integer of 2, more preferably i. More preferably, for example, R system (CVC6) entertainment: benzyl group, -Z-R1 system -NH-CH-R1 (wherein R represents 吼σ疋 group), X system halogen (c _c8) a base, η system 1. The above pyridyl group or pyridine-N-oxide group represented by r1 is more preferably a 3-pyridyl group or a rhodium-platinum oxide group. The first one used in the present invention The substituted amino quinazolinone compound represented by the general formula (1) of the active ingredient can be used in accordance with Japan. It is produced by the method described in the Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. -pyridylmethyl)amino]-6-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]-2(111)-quinazolinone (1-acetyl-3) , 4-dihydr0-3-[(3-pyridylmethyl)amino]-6-[l?25252-tetrafluoro-l-(trifluoromethyl)ethyl]-2(lH)-quinaz olinone (in the following Table 1, Νο· The compound of 15, hereinafter abbreviated as the compound (a), or the one shown in the table (a)) can be produced by the method described in Japanese Patent Laid-Open Publication No. 2001-342186 or the like. In the first or second table, a typical compound is exemplified, and the present invention is not limited to the above-mentioned range, and a compound disclosed in Japanese Laid-Open Patent Publication No. Hei 8-325239 and JP-A No. 2001-342186 can be exemplified. The compound represented by the general formula (I) includes a compound represented by the general formula (I-1) and a compound represented by the general formula (1-2). General formula (1-1): 21 318305 200800021

3/NH—CH2R1 Ή 8 N^IUDn3/NH—CH2R1 Ή 8 N^IUDn

(Ι-D 第1表 No· R R1 In 物性 1 H Q! 6-CFs Bp. 191.0-193· It: 2 &amp; Ql 6HBr Bp· &gt;300*0 3 H a1 6-C2Fs p. ISS-HSt: 4 H Q1 6-CF(CF 山 1P.1S9.4-I6K01C 5 H Q1 e-n-CgFjj mp.I53.9-lM.7lC 6 H Ql 6-0CF, nD 1.5233(22· fit:) 7 H Q1 6-OCHF, up. 129.7-130.2^ 8 H Q1 6-SC,F7-i p. 50.3-53· 11C 9 H Q1 6-OCFiCHF, mp.I68.7-173.9 10 H Ql e-CFCCFi), 屋 p· 239· 7-243· 5 11 COCH, Q1 6-0CF, nD 1.5478(24. 11C) 12 C0C2H5 Q1 6-0CF, nD 1· 5174(25· 90 13 CH.CsCH Q1 6-0CF, dD 1.5325(24.21C) 14 COCH, Ql 6-0CHF2 nD 1.5503(26.110) 15 COCH3 Ql 6-CF(CF,)t BP.132-134TC 16 COOKCH,)、 Q1 fi-CFCCF,), nD 1.5051 (22·It:) 17 C0C2H5 Qr 6-CF(CFs), p. 10S1C 18 COC3H7-11 Q1 6-CF(CF3)2 nD 1.510(22.2*0 19 H Q1 6-C00C2Hs ρ·168· 7-171.9*0 20 C0C,Hs Q1 6-CF3 nD K5400(21·11C) 21 COOCH3 Q1 6-CF(CF3)2 P.I30-135X: 22 COOCA Ql 6-CF(CFs)2 23 C00C4H,-1 Ql 6-CF(CF 山 &amp;D 1.5598(23.4t:) 24 COCHjOCH, Q1 6-CF(CF3h nD 1.5106(21. St:&gt; 一般式(1-2): 22 318305 200800021(Ι-D No. 1 No. R R1 In Physical property 1 HQ! 6-CFs Bp. 191.0-193· It: 2 &amp; Ql 6HBr Bp· &gt;300*0 3 H a1 6-C2Fs p. ISS-HSt : 4 H Q1 6-CF(CF山1P.1S9.4-I6K01C 5 H Q1 en-CgFjj mp.I53.9-lM.7lC 6 H Ql 6-0CF, nD 1.5233(22· fit:) 7 H Q1 6-OCHF, up. 129.7-130.2^ 8 H Q1 6-SC, F7-i p. 50.3-53· 11C 9 H Q1 6-OCFiCHF, mp.I68.7-173.9 10 H Ql e-CFCCFi), House p· 239· 7-243· 5 11 COCH, Q1 6-0CF, nD 1.5478 (24. 11C) 12 C0C2H5 Q1 6-0CF, nD 1· 5174 (25· 90 13 CH.CsCH Q1 6-0CF, dD 1.5325 (24.21C) 14 COCH, Ql 6-0CHF2 nD 1.5503 (26.110) 15 COCH3 Ql 6-CF(CF,)t BP.132-134TC 16 COOKCH,), Q1 fi-CFCCF,), nD 1.5051 (22·It :) 17 C0C2H5 Qr 6-CF(CFs), p. 10S1C 18 COC3H7-11 Q1 6-CF(CF3)2 nD 1.510(22.2*0 19 H Q1 6-C00C2Hs ρ·168· 7-171.9*0 20 C0C , Hs Q1 6-CF3 nD K5400 (21·11C) 21 COOCH3 Q1 6-CF(CF3)2 P.I30-135X: 22 COOCA Ql 6-CF(CFs)2 23 C00C4H,-1 Ql 6-CF(CF Mountain &amp; D 1.5598 (23.4t:) 24 COCHjOCH, Q1 6-CF (CF3h nD 1.5106 (21. St:&gt; General formula (1-2): 22 318305 200800021

(1-2)(1-2)

No· R R1 Xn ~ 物性 25 Η Ql TTt 26 Η Ql 6,C,FS p.298-30〇r 27 Η Q1 6-CF(CFJ, p.&gt;300t: 28 Η Q1 δ-n-CtFii p.&gt;300t: 29 Η Q, TocFT Βφ· 264· (H266· (TC 30 Η Q1 Tochf, - ap· 260.1-264.St: 31 Η ar 6*~SCjF^-i ap· 252·4-255. ITC 32 ch,ch:ch2 Ql 6·Ι P.162-1641C 33 Η Ql J - 0CF,CHFt p. 251.6-263.31C 34 C0C,H5-c Q1 6_I p. 172-1761C 35 Η Q1 lF〇CH(CF,). ^ \φ·&gt;300Χ: 36 Η Q1 卜 〇CFtCHF0CFs p. 240.2-241.3X: 37 COOCHs Q1 卜CF(CF山 P.160H65X: 38 C0CHa Q1 p.186-188T: 39 C0C,Hs Q1 6-f P.135-1391C 40 CiHs Q1 6-1 ΒΡ·19Ι.5·194·δΤ: 又,第1表及第2表中之符號有以下意義:η示正,i 示異’t示第三’ c示脂環式烴基(例如C3H5-C示環丙基), Ph示苯基、Q1示3-吡啶基、Q2示3-吡啶-N-氧化物基。 具有殺蟲活性、殺蟎活性或殺線蟲活性之化合物,例 如可例舉乙醯膽驗酯酶阻礙劑(例如胺基甲酸鹽系化合 物、有機磷系化合物)、乙醯膽鹼受體阻礙劑(例如培丹 (cartap)等)、GABA調控氯化物通道促效劑、鈉通道調控 知】(例如Μ除去菊醋糸化合物)、尼古丁性乙醯膽驗受體促 318305 23 200800021 效劑(例如終驗籬氯系化合物)、乙醯膽驗受體健效齊》(例&amp; 刺糖菌素(spinosyn))、氯化物通道活化劑、保幼激音 t 承姨擬 劑、氧化性磷酸化阻礙劑及ATP形成阻礙劑(例如有機锡 化合物)、氫離子梯度擾亂所致氧化性填酸化之解偶胃〆、 (例如溴蟲腈(chlorfenapyr)),對於同翅目之幾丁生合成戸且 礙劑(1型)(例如布芬淨(buprofezin))、脫皮素促效劑/脫&amp; 阻礙劑(例如二酿基肼(diacylhydrazine))、章魚延胺促力文巧 (例如三亞瞒(amitraz))、位置I電子傳遞系阻礙劑(例如 METI劑)、位置II電子傳遞系統阻礙劑、脂質生合成阻匕 劑(例如,河J豕酸系化合物)、蘭尼定受體調控劑(例如氣笨 二醯胺(flubendiamide))、或非特異性作用機制(選擇性攝々 阻礙)之化合物(例如氟°定蟲醯胺(Flonicamid))等。 其中,具有殺蟲活性、殺螨活性或殺線蟲活性之化人 物以METI劑系殺蟲、殺蟎劑、噻二畊IGR系殺虫添彳、: 4、擬 除蟲菊酯系殺蟲劑、鈉通道阻斷系殺蟲劑、胺基甲酸_系 殺蟲劑、有機磷系殺蟲劑、具有鈣通道活化作用之殺蟲_ 苯曱醯苯基脲系殺蟲劑、二醯基肼系殺蟲劑等為較佳。 上述例如可舉下列一般名稱所示具體化合物為例,作 本發明不侷限在該範圍。 例如具有殺蟲活性、殺蟎活性或殺線蟲活性之化合物 有亞滅培(acetamiprid)、益達胺(imidacloprid)、吡蟲胺 (nitenpyram)、賽速安(thiamethoxam)、可尼丁 (clothianidin)、狄諾 σ夫喃(dinotefuran)、提铵(thiacloprid)、 氟啶蟲醯胺(Flonicamid)等氯尼古丁基系化合物,卡巴利 24 318305 200800021 •一(carbaryl)、免秩克(611〇511(^作;61&gt;]\4(:);滅必蝨 — (isoprocarb ; MIPC)、愛芬克(ethiofencarb)、比加克 (pyrimicarb)、歐殺滅(oxamyl)、免扶克(benfuracarb)、滅 賜克(methiocarb)、滅蚜鱗(mecarbam)、硫敵克 (thiodicarb)、得滅克(aldicarb)、棉鈴威(alanycarb)、必芬 治(metolcarb)、昔利克(xylycarb)、安丹(propoxur)、芬硫 克(fenothiocarb)、卡波呋喃(carbofuran)、丁基加保扶 (carbosulfan)、呋線威(furathiocarb)、安殺番(endosulfan)、 ⑩涕滅威(aldoxycarb)、納乃得(methomyl)等胺基曱酸鹽系化 合物,氯氟氰菊酯(cyhalothrine)、百滅寧(permethrin)、賽 滅寧(cypermethrin)、畢芬寧(bifenthrin)、合芬寧 (halfenprox)、矽護芬(silafluofen)、赛扶寧(cyfluthrin)、貝 他赛扶寧(beta_cyfluthrin)、泰滅寧(tralomethrin)、除蟲菊 素(pyrethrins)、右旋烯丙菊酯(allethrin)、阿納寧 (acrinathrin)、普列亞寧(prallethrin)、異列滅寧 鲁(remethrin)、七氟菊酯(tefluthrin)、芬普寧(fenpropathrin)、 亞滅寧(alpha-cypermethrin)、賽洛寧 (lambda-cyhalothrin)、第滅寧(delta_methrin)、芬化利 (fenvalerate)、艾芬利(esfenvalerate)、護赛寧 (flucythrinate)、福化利(fluvalinate)、乙氰菊酯 (cycloprothrin)、醚菊酯(ethofenprox)等擬除蟲菊酯系化合 物,阿維菌素(avermectin)、因滅灯-苯曱酸鹽 (emamectin-benzoate)、密滅汀(milbemectin)等氯化物通道 活化作用之化合物,賜諾殺(spinosad)等乙醯膽驗受體促效 25 318305 200800021 劍之巨內酯系化合物,撲滅松(fenitrothion)、焉拉本 (malathion)、滅大松(methidathion)、芬殺松(fenthion)、大 利松(diazinon)、異亞颯填(oxydeprofos)、凡来松 (vamidothion)、亞特松(pirimiphos-methyl)、陶斯松 (chlorpyriphos)、托福松(terbufos)、普扶松(ethoprophos)、 雙特松(cadusafos)、芬滅松(fenamiphos)、凡福松 (fensulfothion)、DSP、除線構(dichlofenthion)、福赛絕 (fosthiazate)、依赛米多扶(isamidofos)、丁 硫環填 (fosthictan)、依殺松(isazofos)、蟲線構(thionazin)、谷速 松(azinphos-methyl)、二硫扶(disulfoton)、乙醯甲石粦胺 (oxidemeton-methyl)、巴拉松(parathions)、特布皮利扶 (tebupirimphos)、艾殺松(ethion)、三氯松(trichlorfon ; DEP)、曱胺磷(metamidophos)、二氯松((11〇111〇1^〇5;00\^)、 美文松(mevinphos)、亞素靈(monocrotophos)、大滅松 (dimethoate)、覆減(formetanate)、扶木松(formothion)、硫 滅松(thiometon)、乃力松(naled ; BRP)、甲基巴拉松 (methylparathion)、殺模腈(cyanophos)、二米達松 (diamidafos)、加護松(propaphos)、曱丙硫碟(sulprofos)、 普硫松(prothiofos)、佈飛松(profenofos)、亞芬松 (isofenphos)、亞培松(temephos)、賽達松(phenthoate)、三 唾硫填(dimethylvinphos)、氯芬硫構(chlorferinphos)、樂本 松(tetrachlorvinphos)、两硫填(phoxim)、加福松 (isoxan1;hin)、白克松(pyraclofos)、陶斯松 (chlorpyrifos-methyl)、必芬松(pyridafenthion)、飛赛隆 26 318305 200800021 • (pHosaIone)T飛斯美(phosmet)、殺力崧 cdi〇xal)enz^p〇s)、 拜裕松(quinalphos)、甲硫松(mesulfenfos)、歐殺松(acephate) 等有機磷系化合物, 培丹(cartap)、硫賜安(thiocyclam)、免速達 (bensultap)、硫速達(thiosultap)等沙蠶毒素(nereistoxin)類 似化合物,芬普蟎(fenpyroximate)、畢達本(pyridaben)、吡 蟎胺(tebufenpyrad)、唑蟲蟎胺(tolfenpyrad)、芬殺 (fenazaquin)、畢汰芬(pyrimidifen)、魚藤精(rotenone)等位 Φ置II電子傳遞系統阻礙化合物,Itσ定胺(fluazinam)等粒線 體内電子傳遞系之氧化性磷酸化阻礙化合物,氟苯二醯胺 (flubendiamide)(日本專利特開2001-131141號公報所記載 之Νο·124之化合物)等具鈣通道活化作用之化合物,氟蟲 清(fipronil)、乙醯普(acetoprole)、乙蟲清(ethiprole)等具 GABA調控氯化物通道促效劑活性之苯基唑系化合物,歐 蟎多(propargite)等亞硫酸酯系化合物,因得克 馨(indoxacarb)、美他氟米隆(metflumizone)等曰本專利特開 平5-17428號公報所記載化合物等之鈉通道阻斷系化合· 物,滅瞒猛(quinomethionate)等啥噚琳系化合物,汰芬諾 克(diafenthiuron)、赛海克汀(cyhexatin)、芬布賜(fenbutatin oxide)等有機錫系化合物等之具有氧化性磷酸化之阻礙、 ATP形成阻礙活性之化合物,三亞蜗(amitraz)等具章魚延 胺促效劑作用之曱脒系化合物,螺蜗酯(spirodiclofen)、季 酮甲瞒酯(spiromesifen)、螺四端酯(spirotetramat)等具脂質 生合成阻礙作用之河豚酸系化合物,溴蟲腈 27 318305 200800021 • (cHorfenapyr)、百琢克(13111而&amp;。71)琴—氧化性屬酸化之解偶 聯劑之硝基苯基巴豆酸系化合物,克氯苯 (chlorbenzilate)、盼硫殺(phenisobromolate)、異氰脲酸三 丙基S旨(TPIC ; tripropylisocyanurate)等防蟻性化合物,於 驗硫酸鹽(nicotine-sulfate)、劇陽黴素(polynactins)、印棟 素(azadirachtin)、羥丙基殿粉(hydroxy propyl starch)、摩 朗得(morantel)酒石酸鹽等天然物質系化合物、油酸鈉鹽、 油酸鉀鹽等脂肪酸鹼金屬鹽系化合物,具有蛋白質合成阻 #礙作用之咬蟲丙醚(pyridalyl)等, 昆蟲生長调節物質(IGR)系化合物之例如替扶苯隆 (tefiubenzuron)、克福隆(chlorfluazuron)、二氟苯隆 (diflubenzuron)、六伏隆(hexaflumuron)、敵草胺 (novaluron)、祿芬隆(lufenuron)、氟蟲脲隆(flufenoxuron) 等具有幾丁合成阻礙作用之苯甲醯苯基脲系化合物,得芬 諾(tebufenozide)、曱氧芬諾(methoxyfenozide)、克馬芬諾 ⑩(chromafenozide)、鹵芬諾(halofenozide)等具有脫皮激素促 效劑作用之二醯基肼系化合物,二芬隆(diofenolan)等脫皮 阻礙物質,布芬淨(buprofezin)等具有同翅目之脫皮阻礙作 用之嗟二哄系化合物,丙胺畊(cyromazine)等雙翅目脫皮阻 礙化合物’烯蟲醋(methoprene)、烯蟲乙酷(117(11*〇卩16116)、 百利普芬(pyriproxyfen)、芬諾克(fenoxycarb)等保幼激素狀 化合物,派滅淨(pymetrozine)、克芬淨(clofentezine)、合 赛多(hexythiazox)、芬硫克(fenothiocarb)、依殺蟎 (etoxazole)、聯苯菊酯(bifenazate)、大克蟎(dicofol)、西脫 28 318305 200800021 * ^{benzoximate) - ^ (tetradifon) # ^ t 之化合物i其他如邁隆(dazomat)、鱗克敵(phosphocarb)等 化合物,左咪唑鹽酸鹽(levamisol HC1)、阿苯達唑 (albendazole)、奥苯達唾(oxibendazole)、芬苯達口坐 (fenbendazole)、奥芬達唑(oxfendazol)等化合物,威百畝 (metam-sodium)等甲基二硫胺基曱酸鹽系化合物,唑蚜威 (triazamate)、或蘇力菌(Bacillus thuringiensis ; BT)劑等。 其中,以芬普蜗(fenpyroximate)、免扶克(fenobucarb ; - _ BPMC)、滅必蝨(isoprocarb ; MIPC)、吡蟎胺 (tebufenpyrad)、嗤蟲瞒胺(tolfenpyrad)、布芬淨 (buprofezin)、美他氟米隆(metaflumizone)、得芬諾 (tebufenozide)、溴蟲腈(chlorfenapyr)、福化利 (fluvalinate)、替扶笨隆(^£11^6112111*〇11)或氟苯二醯胺 (flubendiamide)為較佳。又以芬普蟎(fenpyroximate)、吡蟎 胺(tebufenpyrad)、峻蟲蜗胺(tolfenpyrad)、布芬淨 贏(buprofezin)、美他氟米隆(metaflumizone)、得芬諾 (tebufenozide)、溴蟲腈(chlorfenapyr)、福化利 (fluvalinate)、替扶苯隆(teflubenzuron)或氟苯二酿胺 (flubendiamide)為更佳。尤以布芬淨(buprofezin)、美他氟 米隆(metalfumizone)或氟苯二醯胺(flubendiamide)為最佳。 、 本發明之有害生物防除劑之典型具體例如1 -乙醯基 -3,4-二氫-3-[(3-吼啶甲基)胺基]-6_[U2,2,2-四氟-1-(三氟曱 基)乙基]-2(1H)-喹唑啉酮或其鹽類,以及布芬淨 (buprofezin)、美他版米隆(metalfumizone)或氟苯二酿胺 29 318305 200800021 .(frubendiamrde)—’ 最佳—為含布芬淨(bupro—fezin)之製 使用本發明之有害生物防除劑時,所使用該組成物 1 〇〇重畺伤中之有效成分化合物之添加量宜自0.1重量份 至50重量份範圍中選擇適度者,其中以選擇自i至重 量份範圍為較佳。又,所使用有效成分化合物中之經取代 之胺基喹唑啉酮化合物(1)自具有殺蟲活性、殺蟎活性或殺 線蟲活性之化合物中選擇丨種或2種以上之化合物之添加 比例’相對於經取代之胺基喹唑啉酮化合物(1)1重量份, •自具有殺蟲活性、殺蜗活性或殺線蟲活性之化合物中選擇 1種或2種以上之化合物宜自〇 〇1至2〇〇〇重量份範圍中 選擇適度範圍為佳,其中以自们至1〇〇重量份範圍内選 擇為更佳。 本發明之有害生物防除劑可按照農藥製劑上之一般方 法製成適當之固態、液態或粉體等形態,必要時還可以在 該組成物中,藉適當比例調配補助劑等載劑、增量劑、賦 鲁形劑、界面活性劑、固體流動性改善劑、懸濁劑、膠溶劑、 消泡劑、防腐劑、展著劑、防止分解劑、紫外光吸收劑等 添加劑,加以熔融、粉碎、懸濁、混合、浸潰、吸附或附 著,依使用目的而製成適當劑型,例如乳劑、乳懸濁劑、 粉劑、粒劑、顆粒水合劑、水合劑、懸濁劑、可流動劑、 液劑、大量包裝型劑,或喷霧劑等而利用。 ^本發明之有害生物防除劑適用於水稻、蔬菜、果樹、 化卉等之各種農林害蟲、園藝害蟲、貯藏害蟲或衛生害蟲 或線蟲等之害蟲防除甩途,具體例如半翅目(Hem咖a)中 318305 30 200800021 • 異翅類(Heteroptera)之班黠嚴―椿象(Megacopta punctatissimum)、金綠寬龜椿象(Eysarcoris lewisi)、綠寬 龜椿象(Eysarcoris parvus)、南綠龜椿象(Nezara viridula)、 茶綠龜椿象(Plautia stali)、稻棘緣椿象(Cletus punctigen)、 中華稻緣椿象(Leptocorisa chinensis)、點蜂緣椿象 (Riptortus clavatus)、半翅緣椿象(Togo hemipterus)、梨冠 網椿(Stephanitis nashi)、杜鵃冠網椿(Stephanitis pyrioides)、薄綠盲椿(Apolygus spinolai)、紅細盲椿 ⑩(Stenotus rubrovittalus)、條赤盲椿(Trigonotylus coelestialium)等,例如同翅類(Homoptera)之二點浮塵子 (Arboridia apicalis)、茶綠浮塵子(Empoasca onukii)、黑尾 浮塵子(Nephotettix cincticeps)、黑尾葉蟬(Nephotettix virescens)、群灰飛蟲(Laodelphax striatellus)、褐飛蟲 (Nilaparvata lugens)、白背飛蟲(Sogatella furcifera)、柑桔 木蝨(Diaphorina citri)、茶樹黑刺粉蟲(Aleurocanthus spiniferus)、銀葉粉益(Bemisia argentifolii)、煙粉兹 (Bemisia tabaci)、柑桔粉兹(Dialeurodes citri)、溫室白粉 兹(Trialeurodes vaporariorum)、葡萄根瘤虫牙(Viteus vitifolii)、顏果棉辑(Eriosoma lanigerum)、橘捲葉虫牙(Aphis citricola)、豆虫牙(Aphia craccivora)、棉虫牙(Aphis gossypii)、 馬鈴薯虫牙(Aulacorthum solani)、甘藍虫牙(Brevicoryne brassicae)、大戟長管财(Macrosiphum euphorbiae)、煙桃虫牙 (Myzus persicae)、禾穀經管虫牙(Rhopalosiphum padi)、小麥 長角財(Sitobion akebiae)、康氏粉虫介(Pseudococcus 31 318305 200800021 ’ comsiocki)、角虫鼠琢(Ceroplastes ceriferus)、福紅只圓虫介 (Aonidiella aurantii)、梨圓介殼蟲(Comstockaspis perniciosa)、桑介殼蟲(Pseudaulacaspispentagoa)、箭頭介 殼蟲(Unaspisyanonensis)等。 例如鱗翅目(Lepidoptera)中之棉褐帶捲蛾 (Adoxophyes orana fasciate)、茶小捲葉蛾(Adoxophyes honmai)、_L 紋蘋果捲葉蛾(Archips fuscocupreanus)、桃小 食心蟲(Caposina niponensis)、梨小食心蟲(Grapholita ⑩molesta)、茶長捲葉蛾(Homonamagnanima)、茶細蛾 (Caloptilia theivora)、桑青尺蠖(Ascotis selenaria)、葡萄果 實蛀蟲(Endopiza viteana)、蘋果橐蛾(Laspeyresia pomonella)、金紋小潛細蛾(Phyllonorycter ringoniella)、金 紋潛蛾(Lyonetia pnmifoliella malinella)、柑桔潛葉蛾 (Phyllocnistis citrella)、小葉蛾(Plutella xylostella)、棉紅 鈐蟲(Pectinophora gossypiella)、桃小食心蟲(Carposina niponensis)、二模化蟲(Chilo suppressalis)、三化模 # (Scirpophagaincertulas)、稻縱捲葉模(Cnaphalocrocis medinalis)、菜心填(Hellullaundalis)、柑桔鳳蝶(Papilio xuthus)、紋白蝶(Pieris rapae crucivora)、黃褐天幕毛蟲 (Malcosoma neustria testacea)、美國白蛾(Hyphantria cunea)、草坪苞蛾(Parapediasia teterrella)、棉鈴蟲 (Helicoverpa armigera)、鈴蟲(Heliothis spp·)、蕪菁夜蛾 (Agrotis segetum)、豆銀紋夜蛾(Autographa nigrisigna)、甘 32 318305 200800021 —如巧11〇)、斜紋夜蛾(8?〇(^〇卩{6^111;1^)等厂 例如鞘翅目(Coleoptera)中之金銅金龜(Anomala cuprea)、曰本金龜(Popillia japonica)、褐粉兹(Lyctus brunneus)、雜擬穀盜(Tribolium confusum)、二十八星瓢嘉 (Epilachna vigintiocto punctate)、星天牛(Anoplophora malasiaca)、松斑天牛(Monochamus alternatus)、綠豆象 (Callosobruchus chinensis) ^ $ (Aulacophora femoralis) ^ 玉米根蟲(Diabrotica spp·)、棉鈴象曱蟲(Anthonomus gradis _ grandis)、墨西哥黑豆瓢蟲(Epilachnavarivestis)、科羅拉 多金花蟲(Leptinotarssa decemlineats)、稻水象蟲 (Lissorhoptrus oryzophilus)、水稻負泥蟲(Oulema oryzae)、 草皮步行象鼻蟲(Sphenophrus venotus vestitus)等, 例如膜翅目(Hymenoptera)中之紅角菜葉蜂(Athalia rosae ruficornis)、月季葉蜂(Arge pagana)、日本黑褐蟻 (Formica japanica)等,No· R R1 Xn ~ Physical property 25 Η Ql TTt 26 Η Ql 6, C, FS p.298-30〇r 27 Η Q1 6-CF(CFJ, p.&gt;300t: 28 Η Q1 δ-n-CtFii p .&gt;300t: 29 Η Q, TocFT Βφ· 264· (H266· (TC 30 Η Q1 Tochf, - ap· 260.1-264.St: 31 Η ar 6*~SCjF^-i ap· 252·4-255 ITC 32 ch,ch:ch2 Ql 6·Ι P.162-1641C 33 Η Ql J - 0CF,CHFt p. 251.6-263.31C 34 C0C,H5-c Q1 6_I p. 172-1761C 35 Η Q1 lF〇CH (CF,). ^ \φ·&gt;300Χ: 36 Η Q1 〇CFtCHF0CFs p. 240.2-241.3X: 37 COOCHs Q1 Bu CF (CF Hill P.160H65X: 38 C0CHa Q1 p.186-188T: 39 C0C, Hs Q1 6-f P.135-1391C 40 CiHs Q1 6-1 ΒΡ·19Ι.5·194·δΤ: Also, the symbols in Tables 1 and 2 have the following meanings: η shows positive, i shows difference' t indicates that the third 'c represents an alicyclic hydrocarbon group (for example, C3H5-C shows a cyclopropyl group), Ph represents a phenyl group, Q1 represents a 3-pyridyl group, and Q2 represents a 3-pyridine-N-oxide group. A compound having acaricidal activity or nematicidal activity, for example, an acetylcholinesterase inhibitor (for example, an aminoformate compound, an organophosphorus compound) or an acetylcholine Alkaline receptor inhibitors (such as cartap, etc.), GABA-regulated chloride channel agonists, sodium channel regulation (such as sputum removal of veterinary vinegar compounds), nicotine acetylcholine receptors 318305 23 200800021 Pharmacological agents (such as the final check chlorine compound), acetylcholine receptors and health effects (example & spinosyn), chloride channel activator, health care Agent, oxidative phosphorylation inhibitor and ATP formation inhibitor (for example, organotin compound), oxidative acidification of sedative stomach sputum caused by hydrogen ion gradient disturbance (for example, chlorfenapyr), for Homoptera Chitin-synthesis and anti-inducing agents (type 1) (such as buprofezin), ecdysone agonist / de- amp; inhibitors (such as diacylhydrazine), octopus Wen Qiao (such as amitraz), position I electron transport system inhibitor (such as METI agent), position II electron transport system inhibitor, lipid biosynthesis blocker (for example, river J acid compound), blue Nitidine receptor modulators (eg, flubendiamid) e)), or a compound that has a non-specific mechanism of action (selective inhibition) (e.g., Flonicamid). Among them, people with insecticidal activity, acaricidal activity or nematicidal activity are METI-based insecticides, acaricides, thiazoline IGR-based insecticides, and: 4. Pyrethroid-based insecticides, Sodium channel blocking insecticide, amide formic acid insecticide, organophosphorus insecticide, insecticidal agent with calcium channel activation _ phenyl phenyl ureido insecticide, diterpene lanthanide Insecticides and the like are preferred. The above specific examples are exemplified by the following specific names, and the present invention is not limited to the scope. For example, compounds having insecticidal activity, acaricidal activity or nematicidal activity are acetamiprid, imidacloprid, nitenpyram, thiamethoxam, and clothianidin. , chloramphenicol compounds such as dinotefuran, thiacloprid, flonicamid, etc., Kabali 24 318305 200800021 • carbaryl, 免 gram (611〇511 ( ^作;61&gt;]\4(:); extinction - (isoprocarb; MIPC), ethiofencarb, pyrimicarb, oxamyl, benfuracarb, Methicarb, mecarbam, thiodicarb, aldicarb, alanycarb, metolcarb, xylycarb, Andan Propoxur), fenothiocarb, carbofuran, carbosulfan, furathiocarb, endosulfan, aldoxycarb, nanet Aminomethane compound such as methodoy, cyhalothrin (cyhalothrine), permethrin, cypermethrin, bifenthrin, halfenprox, silafluofen, cyfluthrin, beta vasine Beta_cyfluthrin), tramomethrin, pyrethrins, allethrin, acrinathrin, prallethrin, remethrin , tefluthrin, fenpropathrin, alpha-cypermethrin, lambda-cyhalothrin, delta_methrin, fenvalerate, fennelly (esfenvalerate), flucythrinate, fluvalinate, cycloprothrin, ethofenprox, pyrethroid compounds, avermectin, A compound that activates chloride channels such as emamectin-benzoate and milbemectin, and sputum receptors such as spinosad. 25 318305 200800021 Ester compound (fenitrothion), malathion, methidathion, fenthion, diazinon, oxydeprofos, vamidothion, pirimiphos -methyl), chlorpyriphos, terbufos, ethoprophos, cadusafos, fenamiphos, fensulfothion, DSP, deichlofenthion , fosthiazate, isamidofos, fosthictan, isazofos, thionazin, azinphos-methyl, disulfide Disulfoton, oxidemeton-methyl, parathions, tebupirimphos, ethion, trichlorfon (DEP), 曱Meimidophos, diclofen ((11〇111〇1^〇5; 00\^), mevinphos, monocrotophos, dimethoate, formetanate , formothion, thiometon, naled (BRP), methyl Methylparathion, cyanophos, diamidafos, propaphos, sulprofos, prothiofos, profenofos, alfene Isofenphos, temephos, phenthoate, dimethylvinphos, chlorferinphos, tetrachlorvinphos, phoxim, plus Fukusong (isoxan1; hin), pyraclofos, chlorpyrifos-methyl, pyridafenthion, feisailong 26 318305 200800021 • (pHosaIone) T phosmet, killer 嵩cdi〇xal )enz^p〇s), quinalphos, mesulfenfos, acephate and other organophosphorus compounds, cartap, thiocyclam, free speed ( Bensultap), thiosultap, and other nereistoxin-like compounds, fenpyroximate, pyridaben, tebufenpyrad, tolfenpyrad, and fentanyl Fenazaquin), pirimifife n), rotenone (rotenone), Φ, II, electron transport system, hinder compound, fluazinam, etc., oxidative phosphorylation inhibitory compound, flubendiamide A compound having a calcium channel activating action such as a fipronil, an acetoprole, or an ethiprole, etc., such as a compound of Νο·124 described in JP-A-2001-131141. GABA regulates the activity of chloride channel agonist phenylazole compounds, sulfite compounds such as propargite, indoxacarb, metflumizone, etc. A sodium channel blocking system compound such as a compound described in Japanese Patent Publication No. 5-17428, a quinomethionate, a phthalate compound, a diafenthiuron, a cyhexatin, and a fen An organotin-based compound such as fenbutatin oxide, which has an inhibitory effect of oxidative phosphorylation, a compound which inhibits ATP formation, and a steroidal compound having an octopus extended amine agonist such as amitraz A spirulina compound, such as spirodiclofen, spiromesifen, and spirotetramat, which has a lipid-synthesis-inhibiting effect, chlorfenapyr 27 318305 200800021 • (cHorfenapyr), Baikeke (13111 and &amp;. 71) Qin-oxidation is an acidified uncoupling agent of nitrophenyl crotonic acid compound, chlorbenzilate, phenisobromolate, isocyanuric acid tripropyl S (TPIC; tripropylisocyanurate And other anti-ant compounds, such as nicotine-sulfate, polynactins, azadirachtin, hydroxy propyl starch, morantel tartaric acid A fatty acid alkali metal salt compound such as a natural substance such as a salt, a sodium oleate or a potassium oleate, and a pyridalyl such as a protein synthesis inhibitor, an insect growth regulating substance (IGR) Compounds such as tefiubenzuron, chlorfluazuron, diflubenzuron, hexaflumuron, novaluron, lufenuron, flubendiles Flubenoxuron and other benzamidine phenylurea compounds having a hindrance to chitin synthesis, tebufenozide, methoxyfenozide, chromafenozide, halfino (ha) Lofenozide), such as a dimercapto steroid compound having a ecdysone agonist, a peeling inhibitor such as diofenolan, and a diterpenoid compound having a homotropanic peeling hindrance such as buprofezin , cyromazine (cyromazine) and other diptera peeling hindering compounds 'methoprene, methionine (117 (11 * 〇卩 16116), pyriproxyfen, fenoxycarb (fenoxycarb), etc. Juvenile hormone-like compounds, pymetrozine, clofentezine, hexythiazox, fenothiocarb, etoxazole, bifenazate, large Dicofol, Cet. 28 318305 200800021 * ^{benzoximate) - ^ (tetradifon) # ^ t Compound i Others such as dazomat, phosphocarb, etc., levamisole hydrochloride ( Levamisol HC1), albendazole, oxibendazole, fenbendazole, oxfendazol, etc., methyl for metam-sodium a dithiol phthalate compound, Triazamate, or Bacillus thuringiensis (BT) agent. Among them, fenpyroximate, fenobucarb (-_BPMC), isoprocarb (MIPC), tebufenpyrad, tolfenpyrad, buprofezin ), metaflumizone, tebufenozide, chlorfenapyr, fluvalinate, tifuton (^£11^6112111*〇11) or fluorobenzene Flubendiamide is preferred. Also known as fenpyroximate, tebufenpyrad, tolfenpyrad, buprofezin, metaflumizone, tebufenozide, bromo More preferably, chlorfenapyr, fluvalinate, teflubenzuron or flubendiamide. Especially buprofezin, metalfumizone or flubendiamide is preferred. Typical examples of the pest control agent of the present invention are, for example, 1-ethylindolyl-3,4-dihydro-3-[(3-acridinylmethyl)amino]-6_[U2,2,2-tetrafluoro 1-(Trifluoromethyl)ethyl]-2(1H)-quinazolinone or a salt thereof, and buprofezin, metalfumizone or fluorobenzamide 29 318305 200800021 .(frubendiamrde)—“Best—when using the pest control agent of the present invention for a bupro-fezin-containing system, the composition 1 is used as an active ingredient compound The amount to be added is preferably selected from the range of from 0.1 part by weight to 50 parts by weight, preferably from i to parts by weight. Further, the substituted amino quinazolinone compound (1) in the active ingredient compound is selected from the compounds having insecticidal activity, acaricidal activity or nematicidal activity, and the ratio of the addition of the compound or the two or more compounds 'Compared to 1 part by weight of the substituted aminoquinazolinone compound (1), • one or more compounds selected from compounds having insecticidal activity, bactericidal activity or nematicidal activity are preferred A moderate range is preferably selected from the range of 1 to 2 parts by weight, and it is preferably selected from the range of from 1 part by weight to 1 part by weight. The pest control agent of the present invention can be prepared into a suitable solid, liquid or powder form according to the general method of the pesticide preparation, and if necessary, the carrier can be formulated in an appropriate proportion by using a proper ratio of the carrier and the like. Additives such as agents, sclerosing agents, surfactants, solid fluidity improvers, suspending agents, peptizers, antifoaming agents, preservatives, spreading agents, decomposing agents, ultraviolet light absorbers, etc., are melted and pulverized , suspension, mixing, impregnation, adsorption or adhesion, according to the purpose of use to prepare appropriate dosage forms, such as emulsions, milk suspensions, powders, granules, granule hydrating agents, hydrating agents, suspending agents, flowable agents, It is used as a liquid agent, a large amount of packaging agent, or a spray. The pest control agent of the present invention is suitable for pest control of various agricultural and forest pests, horticultural pests, storage pests or sanitary pests or nematodes such as rice, vegetables, fruit trees, chemical plants, etc., for example, Hemiptera (Hemcaa) ) 318305 30 200800021 • Heteroptera (Megacopta punctatissimum), Eysarcoris lewisi, Eysarcoris parvus, Nezara viridula, Plautia stali, Cletus punctigen, Leptocorisa chinensis, Riptortus clavatus, Togo hemipterus, Pear crown net ( Stephanitis nashi), Stephanitis pyrioides, Apolygus spinolai, Stenotus rubrovittalus, Trigonotylus coelestialium, etc., such as the homoptera (Homoptera) Arboridia apicalis, Empoasca onukii, Nephotettix cincticeps, black tail Nephotettix virescens, Laodelphax striatellus, Nilaparvata lugens, Sogatella furcifera, Diaphorina citri, Aleurocanthus spiniferus ), Bemisia argentifolii, Bemisia tabaci, Dialeurodes citri, Trialeurodes vaporariorum, Viteus vitifolii, Eriosoma lanigerum , Aphis citricola, Aphia craccivora, Aphis gossypii, Aulacorthum solani, Brevicoryne brassicae, Macrosiphum euphorbiae, nectarine Myzus persicae, Rhopalosiphum padi, Sitobion akebiae, Pseudococcus 31 318305 200800021 'comsiocki, Ceroplastes ceriferus, Fuhong only Aonidiella aurantii, Comstockaspis perniciosa, mulberry Insect shell (Pseudaulacaspispentagoa), arrow worms dielectric housing (Unaspisyanonensis) and the like. For example, Adoxophyes orana fasciate, Adoxophyes honmai, Archips fuscocupreanus, Caposina niponensis, and Grapholita 10molesta in Lepidoptera ), Homonamagnanima, Caloptilia theivora, Ascotis selenaria, Endopiza viteana, Laspeyresia pomonella, Phyllonycter ringoniella , Lyonetia pnmifoliella malinella, Phyllocnistis citrella, Plutella xylostella, Pectinophora gossypiella, Carposina niponensis, Chilo Suppressalis), Sanhua Momo# (Scirpophagaincertulas), Cnaphalocrocis medinalis, Hellullaundalis, Papilio xuthus, Pieris rapae crucivora, Yellow caterpillar caterpillar (Malcosoma Neustria testacea), American white moth (Hyph Antria cunea), Parapediasia teterrella, Helicoverpa armigera, Heliothis spp., Agrotis segetum, Autographa nigrisigna, Gan 32 318305 200800021 — Such as 11 〇), Spodoptera litura (8? 〇 (^〇卩{6^111; 1^) and other plants such as Coleoptera, Anomala cuprea, Popillia japonica, Lyctus brunneus, Tribolium confusum, Epilachna vigintiocto punctate, Anoplophora malasiaca, Monochamus alternatus, and green bean (Callosobruchus) Chinensis) ^ $ (Aulacophora femoralis) ^ corn rootworm (Diabrotica spp.), cotton boll weevil (Anthonomus gradis _ grandis), Mexican black bean ladybug (Epilachnavarivestis), Colorado golden flower worm (Leptinotarssa decemlineats), rice water weevil (Lissorhoptrus oryzophilus), Oulema oryzae, Sphenophrus venotus vestitus, etc., such as Hymenoptera (Hym) Enoptera) Athalia rosae ruficornis, Arge pagana, Formica japanica, etc.

例如雙翅目(Diptera)中之水稻潛蠅(人$1*〇111}^&amp; oryzae)、稻小葉潛蠅(Hydrellia griseola)、非洲菊斑潛蠅 (Liriomyzatrifolii)、蔥蠅(Delia antiqua)、家繩(Musca domestica)、地下家蚊(Culex pipiens molestus)、淡色庫蚊 (Culex pipiens pallens)等, 例如薊馬目(Thysanoptera)中之小黃薊馬(Scirtothrips dorsalis)、南黃薊馬(Thrips palmi)、蔥薊馬(Thrips tabaci)、 西方花薊_ 馬(Frankliniella occidentalis)等, 例如白蟻目(Isoptera)中之家白蟻(Coptotermes 33 318305 200800021 • formosanus)、黃胸散 * ^(Reticulitermes speratus)Ti 目(Psocoptera)、嗜卷書蝨(Liposcelis bostrychophilus)等。 例如直翅目(Orthoptera)中之小翅稻蝗(〇xya yezaensis)、螻蛄(Gryllotalpa sp·)、美洲蜚蠊(Pedplaneta Americana)、德國姬蠊(Blattella germanica)等, 例如蜗目(Acarina)中之柑桔葉蜗(Panonychus citri)、 歐洲葉瞒(Panonychus ulmi)、二點葉瞒(Tetranychus urticae)、神澤氏葉蜗(Tetranychus kanzawai)、紫紅短鬚蜗 馨(Brevipalpus phoenicis)、苜蓿苔蟎(Bryobia praetiosa)、桔 刺皮節蜱(Aculops pelekassi)、二十世紀梨銹蜱(Eriophyes chibaensis)、茶黃蟎(Polyphagotarsonemuslatus)、長毛根 瞒(Rhizoglyphus robini)、腐食酪蟎(Tyrophagus putrescontiae)等, 例如針線蟲目(Tylenchida)中之根腐線蟲(Pratylenchus coffeae)、穿刺短體線蟲(Pratylenchus penetrans)、黃金線 ⑩蟲(Globodera rastochiensis)、南方根結線蟲(Meloidogyne incognita)等, 例如偽針線蟲目(Dorylaimida)中之長針線蟲 (Longidorus sp.)等, 例如軟體動目門腹足綱(Gastropoda)中之雙線始蝓 (Incilariabilineats)等。 本發明之有害生物防除劑所使用對象之有用植物並無 特別限制,例如穀類(例如水稻、大麥、小麥、黑麥、燕麥、 玉米等)、豆類(例如黃豆、紅豆、喬豆、碗豆、菜豆、花 34 318305 200800021 .1等)、果樹、果實—類(例如蘋果、柑ϋ-利 一For example, in the Diptera (Diptera), the rice larvae (human $1*〇111}^&amp; oryzae), Hydrellia griseola, Liriomyzatrifolii, Delia antiqua, Musca domestica, Culex pipiens molestus, Culex pipiens pallens, etc., such as the small yellow horse (Scirtothrips dorsalis) in the Thysanoptera, the southern yellow horse (Thrips) Palmi), Thrips tabaci, Frankliniella occidentalis, etc., for example, termites in the family Apoptera (Coptotermes 33 318305 200800021 • formosanus), yellow chest loose * ^ (Reticulitermes speratus) Ti (Psocoptera), Liposcelis bostrychophilus, and the like. For example, in the Orthoptera, 小xya yezaensis, Gryllotalpa sp., Pedplaneta Americana, Blattella germanica, etc., for example, in Acarina Panonychus citri, Panonychus ulmi, Tetranychus urticae, Tetranychus kanzawai, Brevipalpus phoenicis, Brassica (Bryobia praetiosa), Aculops pelekassi, 20th century Eriophyes chibaensis, Polyphagotarsonemuslatus, Rhizoglyphus robini, Tyrophagus putrescontiae, etc. For example, the root rot nematode (Pratylenchus coffeae), the pratylenchus penetrans, the Globodera rastochiensis, the Meloidogyne incognita, etc. in the case of Tylenchida, such as pseudo-nematodes (Dorylaimida), such as Longidorus sp., etc., for example, in the soft-skinned gastropod (Gastropoda) Wire began snail (Incilariabilineats) and so on. The useful plant of the object to be used for the pest control agent of the present invention is not particularly limited, and examples thereof include cereals (for example, rice, barley, wheat, rye, oats, corn, etc.), and beans (for example, soybeans, red beans, peas, beans, and beans). Beans, flowers 34 318305 200800021 .1, etc.), fruit trees, fruits - such as apples, citrus-li

梅、櫻桃、胡桃、板果、杏、、香萑柑葡萄、F 罐如甘藍、番兹、波菜、青葉菜·果菜 :子二,,二二洋:藷青r 如棉化、麻、火焰菜、蛇麻 &quot;刃⑴ 咖啡、菸草、苹等)、庶、甜采、撖欖、橡膠、 甜;LA 南瓜、胡瓜、越瓜、西瓜、 甜瓜4)、牧草類(例如果園 媸 四瓜 i音允曾Μ笠、哲山早ψ蜀黍、梯牧卓、苜稽、 糸化目伯4)、卓皮類(例如高 疋透香、百里香、香荽、刼 ^ 等)、花卉類(例如菊花、玫魂花、康乃馨、蘭::: 树木類(例如銀杏、櫻其知* 、園 奏未、μ Γ 桃謂鱗)、林木類(冷杉、蝦 夷松、松類、絲柏、杉、檜木等)等植物。 又’該有用㈣可包括藉基因重組等 生產殺蟲性有效成分之始札# 長過転中 等。 放成刀之植物。該殺蟲有效成分例如出毒素 為防除各種病害蟲,本發明之有害生 接,或以水等適當豨經弋辟π 于片J τ以直 有兮旦#用^稀釋或懸濁之形態,將防除有害生物之 :效里使用在可預測到有害生物產生之植 分之外,-、主強十 生有害生物而撒布在莖葉部 理入声=藥劑,利用粉衣、果皮處理等種子處 栽植二理Γ合、施條、栽培床土混合、種苗箱處理、 *八处艮基處理、土面施肥、稻秧苗箱處理、水面 施用等’或處理土壌等自根部吸收而利用。另外,也可以 318305 35 200800021 在水耕栽培中施哥於培養灰、燻蒸或瓦入樹幹等^使用。 本尚可以散布在例如貯穀害蟲、家屋害蟲、衛生害蟲、 ^木林吾蟲等使用之外,也能利用在家屋建材之塗裝、燻煙 脫灰液等用途。 …、 處理種子之方法,例如可舉出將液狀或固狀之 m ^ ^ . 接或經稀釋後藉液狀浸潰種子,使藥劑浸透之方法 ==劑或液狀製劑和種子混合,或經粉衣處理而附著在 合物等體ί=劑或液狀製劑,用樹脂、聚 戰體此合而塗布於種子之方法,或播種之回 日守將固形製劑或液狀製劑散布於種子附近之方法等。° 上述處理種子中所述「種 今 期之植物體,例如可舉出插…….1物繁殖用栽培初 羊、嫉法^ 子之外,包括球根、塊莖、種 、珠牙、鱗莖或插穗等各種繁殖體。 ^施本發明之使用方法時,所述植物之「 所$土瓖、二#貝並無特別限制,祇要梭物能生長之材質, 經:、二:=、水等均可,具體材料之例如砂,石 蛭石石夕凍土、瓊脂、凝膠狀物質、高 幸“ 玻璃柏、木材片、樹皮、紙等。…子物貝、岩棉、 狀製劑或水合劑或顆粒狀水合::二:可流動劑等液 後之“:1=稀釋適# 襄之方法’例如可舉出將液狀製劑用水稀釋 318305 36 200800021 ,前散布粉劑、水合劑、顆:狀:::方二:種前或移損 .混合之方法,或播種前或裁植前散;^接土壤加以 狀水合劑、粒劑等於栽植穴、栽料=、、=合劑、顆粒 水稻育苗箱t所施用之劑 隨:: 化期施用、移植期施用等施用時期而有:播=二、綠 劑、顆粒狀水合劑、粒劑等劑型即可。將=吊’利用粉 合劑或粒劑等和培養土、、θ a 、〜顆粒狀水 培養土整體混合等遮合、覆土混合、 以層狀實施亦可行。5僅將各種製劑和培養土交互 水:中施用方法,通常,在積水狀之水田中 士:大量包裝型劑、粒劑、顆粒狀水合劑等固形製劑、ς ==製劑、乳劑等液狀製劑等散布之方法。其他 ^秧W可將適t製劑錢纽合肥料散布纽入 =又,水源頭或灌规裝置等水田用水之流入水源頭利用 礼刎,可流動性製劑等藥液而隨供水施用可省時省力。 ,旱地作物之施用,可自播種、育苗期、生長期中, 製劑處理在種子上或接近植物體之栽培介質等。直接播種 在旱地之植物,除直接處理製劑於種子之外,以製劑處理 在栽培中之植株基部為較佳。可用粒劑散布處理,或亦可 用水稀釋或不必稀釋之藥劑以液狀灌注處理。粒劑和播種 前之栽培介質混合後,再行播種也是很好之方法。 需要移植之栽培植物,在播種、育苗期之處理方法, 318305 37 200800021 除直接將製翁理在種子之外―’以液狀製劑雜處理或粒 狀製劑散布處理在育苗用苗床為佳。又,定植時以粒劑處 .理栽植穴,或混合在移植處鄰近之栽培介質也是很好之處 理方法。 &gt;本^明之有告生物防除劑製造成一般齊㈣,例如可以 礼劑、礼狀懸濁劑、水合劑、顆粒狀水合劑、懸濁劑、可 流動性劑、液劑、粒劑、粉劑、大量包裝型劑、嗔霧劑、 燻煙劑等劑型而使用,該組成物之㈣量,财效成分之 调配合比例、氣象條件、製劑形態、施用時期、施用方法、 施用場所、防除對象有害生物、對象作物等而異,通常,i 公故計,製财有效成分(包括一般式(1)所示化合物以及且 妓蟲活性、殺蜗活性或殺線蟲活性之化合物之總和)換 异,自〇.ig至iooog範圍中適當選擇施用就行,其中,以 ig,500§範圍中選擇施用為較佳。處理種子時,和種子 重里比車乂卩製劑中有效成分換算,可能在Μ至%%範 圍中使用’其中,較佳為以〇1至1〇%範圍中使用。用水 稀釋乳劑、水合劑等而施用時,其施用濃度在0.00001至 〇·1%範圍’粒劑、粉劑或種子處理用之液劑等,通常不必 稀釋而直接使用即可。χ ’本發明中所述%,通常係指重 量 %(w/w) 0 士又,本發明之有害生物防除劑之使用時期,為防止同 時發生之病害及/或雜草,將其他有效成分之具有殺蟲活 性、殺蜗活性或殺線蟲活性之化合物,以具有殺菌活性或 除草活性之化合物跟具有殺蟲活性m性或殺線蟲活 318305 38 200800021 τ 性之化合物同時彳吏用,可擴大防除對象之病蟲害範圍,減一 低藥量,尚可在除草劑效果上期待其協同效果。 該具有殺菌活性或除草活性之化合物,例如下列化合 物。具有殺菌活性化合物之例如亞托敏(azoxystrobin)、雙 氣氰菌胺(diclocymet)、咯酮(pyroquilon)、嘉賜黴素 (kasugamycin)、丙基喜樂松(^1'〇七&amp;1^〇5;16?)、殺紋寧 (hymexazol)、滅普寧(mepronil)、三賽口坐(tricyclazole)、護 粒松(edifenphos)、亞賜圃(isoprothiolane)、柏拉西汀 ⑩(blastcidin)、福多寧(flutolanil)、達滅淨((11(;1〇11^211]^)、赛 得克利(pencycuron)、多菌靈(carbendazin)、多果定 (dodine)、普拔克(propamocarb)、。密黴胺(pyrimethanil)、 氟喹唑(fluquinconazole)、福賽得(focetyl-AL)、溴克座 (bromuconazole)、滅菌嗤(triticonazole)、氟美脫弗 (flumetover)、咪嗤菌酮(fenamidone)、甲基益發靈 (tolylfluanid)、益發靈(dichlofluanid)、三氟敏 馨(trifloxystrobin)、三泰隆(triadimenol)、螺沙敏 (spiroxamine)、環酿菌胺(fenhexamid)、異丙菌胺 (iprovalicarb)、熱必斯(fthalide)、異菌脲(iprodione)、多保 淨(thiophanate)、免賴得(benomyl)、赛福座(triflumizole)、 扶吉胺(fluazinam)、代森鋅(zineb)、蓋普丹(captan)、代森 錳鋅(manzeb)、芬瑞莫(fenarimol)、鈣硫合劑(calcium polysulfide)、三泰芬(triadimefon)、免克寧(vinclozolin)、 腈硫醌(dithianon)、比多農(bitertanol)、聚胺曱酯 (polycarbamate)、克熱淨(iminoctadine-DBS)、克草敵 39 318305 200800021 • (pebulate)、多抗黴素(polyoxin-B)、甲基鋅乃浦(propineby、 離丹(chinomethionat)、益發靈(dichlofluanid)、四氯異苯腈 (chlorothalonil)、待克利(difenoconazole)、峻吱草 (fluoroimide)、賽福寧01^〇1^1^)、歐殺斯(〇父&amp;(!1又71)、鏈黴 素(streptomycin)、鋅猛乃浦(111&amp;11(;〇2613)、歐索林酸(〇\〇1111沁 acid)、滅普寧(mepronil)、滅達樂(metalaxyl)、普克利 (propiconazole)、菲克利(hexaconazole)、硫(sulfur)、吼芬 諾(pyrifenox)、驗性硫酸銅(basic copper sulfate)、嘴黴胺 # (pyrimethanil)、丙基喜樂松(iprobenfos)、脫克松 (tolclofos-methyl)、代森猛(maneb)、曱基多保淨 (thiophanate-methyl)、噻氟菌胺(trifluzamide)、福拉比 (furametpyr)、氟硫滅(flusulfamide)、克收欣 (kresoxim_methyl)、卡普邁(carpropamid)、經異喔嗤 (hydroxyisoxazole)、異樂美唾(echlomezole)、撲滅寧 (procymidone)、免克寧(vinclozolin)、種菌唾(ipconazole)、 ⑩口夫菌唾(furconazole)、邁克尼(myclobutanil)、四克利 (tetraconazole)、得克利(tebuconazole)、易胺座 (imibenconazole)、撲克拉(卩1^〇(:111〇^2)、稻瘦酯 (pefurazoate)、環克座(cyproconazole)、滅派林 (mepanipyrim)、代森環(thiadiazin)、撲殺熱(probenazole)、 苯并嗟二唑(acibenzolar-S-methyl)、有效黴素 (validamycin-A)、氰菌胺(fenoxanil)、噻醯菌胺(tiadinil) 等殺菌劑,可供混合使用。 其次,具有除草活性之化合物,例如免速隆 40 318305 200800021 ^ (bensulfuron-metliyl)、四 口巫 口密磺隆(azlmsulfuron)、醚石黃隆 (cinosulfuron)、環績隆(cyclosulfamuron)、°比峻石黃隆 (pyrazosulfuron-ethyl)、依速隆(imazosulfuron)、草酮 (indanofan)、丁基賽伏草(cyhalofopbutyl)、欣克草 (thenylchlor)、戊草丹(esprocarb)、乙氧苯草胺 (etobenzanid)、嗤草胺(cafenstrole)、克普草(clomepTop)、 戊草津(dimethametryn)、殺草隆(daimuron)、必芬諾 (bifenox)、稗草丹(pyributicarb)、σ密草醚 φ (pyriminobac-methyl)、普拉草(pretilachlor)、溴 丁草胺 (bromobutide)、口比草酮(benzofenap)、殺丹(benthiocarb)、 苯沙隆(bentoxazone)、苯草石黃(benfuresate)、滅芬草 (mefenacet)、乙基精噪唾禾草靈(fenoxaprop-P_ethyl)、甜 菜寧(phenmedipham)、禾草靈(diclofop-methyl)、甜菜靈 (desmedipham)、乙吱草石黃(ethofumesate)、異丙隆 (isoproturon)、。密石黃隆(amidosulfuron)、莎稗鱗(anilofos)、 苯草石黃(benfuresate)、乙氧石黃隆(ethoxysulfuron)、°引°朵石黃隆 9 (iodosufluron)、雙苯σ惡峻酸(isoxadifen)、甲醯胺石黃隆 (foramsulfuron)、雙口坐草(卩)^&amp;〇1〇1111)、曱基二磺隆 (mesosulfuron)、達有隆(diuron)、尼布隆(neburon)、特樂 酚(dinoterb)、雙草胺(carbetamide)、溴苯腈(bromoxynil)、 氧二隆(oxyadiazon)、惡唾隆(dimefuron)、吼氣草胺 (diflufenican)、苯草醚(aclonifen)、σ比草酮(benzofenap)、 17惡哄草酮(oxaziclomefone)、異噪嗤草酮(isoxaflutole)、丙 炔惡草酮(oxadiargyl)、吱草酮(flurtamone)、滅必淨 41 318305 200800021 • (metribuzin)、甲基笨σ塞隆(methabenzthiazuron)、脫葉碟 (tribufos)、苯哄草酮(metamitron)、乙草酮(ethiozin)、敦售 草胺(flufenacet)、硫克草酮(sulcotrion)、四峻草胺 (fentrazamide)、丙苯石黃隆(卩1*〇卩〇\}^&amp;1^&amp;2〇1^)、就酮石黃隆 (flucarbazone)、磺草嗤胺(metosulam)、胺唾草酮 (amicarbazone)等除草劑,可供混合使用。 又,下列一般名稱所記載之除草劑也可能混合使用。 例如嘉磷塞異丙胺(glyphosate-isopropyl amine)、嘉填塞三 ⑩曱基硫鹽(glyphosate-trimesium)、固殺草 (glufosinate-ammonium)、畢拉草(bialaphos)、抑草構 (butamifos)、普草丹(prosulfocarb)、填草靈(asulam)、理有 隆(linuron)、舞過氧化物(calcium、peroxide)、拉草 (alachlor)、施得圃(pendimethalin)、西氟禾草靈 (acifluofen-sodium)、乳氟禾草靈(lactofen)、辛蛾苯 (ioxynil-octanoate)、亞汰草(alloxydim)、西殺草 ⑩(sethoxydim)、萘氧丙草胺(napropamide)、口比口坐特 (pyrazolate)、°比敗苯草酯(pyraflufen-ethyl)、依滅草 (imazapyr)、甲石黃草胺(sulfentrazone)、樂滅草(oxadiazon)、 巴拉刈(paraquat)、敵草快(diquat)、西瑪津(simazine)、阿 特拉津(atrazine)、氟嗔甲草酯(fluthiacet-methyl)、精啥禾 靈(quizalofop-ethyl)、本達隆(bentazone)、BAS-3510-H、 三氟草胺(triaziflam)等。又,具有植物生長調節作用之賽 苯隆(thidiazuron)、嗤解草酯(mefenpyr)、益收生長素 (ethephon)、環丙醯胺酸(cyclanilide)等也可混合使用。 42 318305 200800021 一— 更進之τ本普明之有害IT物防除劑泰▼和生物性農藥一 併用,該生物性農藥之例如核多角體病毒(Nuclear polyhedrosis virus,NPV)、顆粒病病毒(Granulosis virus, GV)、細胞質多角體病病毒(Cytoplazmic polyhedrosis virus, 簡稱CPV),昆蟲痘病毒(Entomopox virus,EPV)等病毒製 劑,單頂孢菌(Monacrosporium phymatophagum)、斯氏線 蟲(Steinernema carpocapsae、Steinernema kushidai)、穿刺 巴桿菌(Pasteuria penetrans)等殺蟲或殺線蟲劑用途利用之 _微生物性農藥,木黴菌(Trichodermalignorum)、放射土壤 桿菌(Agrobacterium radiobacter)、非病原性之胡蘿蔔軟歐 氏桿菌(Erwinia carotovora)、枯草芽孢桿菌(Bacillus subtilis)、單頂孢菌(Monacrosporium phymatophagum)等殺 菌劑用途使用之微生物性農藥、野菜黃單孢桿菌 (Xanthomonas campestris)等除草劑用途之生物性農藥等, 可供混合使用而期待得到同樣效果。Plum, cherry, walnut, fruit, apricot, citrus grape, F cans such as cabbage, sage, bok, green leaf, fruit and vegetable: sub-two, two-two ocean: potato green r such as cotton, hemp, Flame vegetables, hops &quot; blade (1) coffee, tobacco, apple, etc.), 庶, sweet, 撖 、, rubber, sweet; LA pumpkin, courgette, squash, watermelon, melon 4), pasture (for example, garden瓜伊音允曾Μ笠, Zheshan early ψ蜀黍, 提牧卓, 苜 、, 糸化目伯 4), Zhuopi (such as sorghum, thyme, fragrant, 刼^, etc.), flowers (such as chrysanthemum, rose flower, carnation, orchid::: trees (such as ginkgo, cherry blossoms *, garden music, μ Γ peach scales), forest trees (fir, shrimp, pine, pine, cypress, Plants such as cedar, eucalyptus, etc.. 'This useful (4) may include the production of insecticidal active ingredients by genetic recombination, etc. #长过転中. Plants that are placed into a knife. The active ingredients of the insecticide, such as toxins, are controlled. Various pests and diseases, the harmful connection of the present invention, or the appropriate enthalpy of water, such as water, can be used to dilute π in the sheet J τ to be diluted with The form of suspension will prevent pests: the effect is used in addition to the plants that can predict the production of harmful organisms, - the main strong ten pests are scattered in the stems and leaves, the sound is into the medicine = the medicine, using the powder coating Seeds such as peel treatment, planting, planting, planting, soil mixing, seedling box treatment, * eight sputum treatment, soil fertilization, rice seedling box treatment, water surface application, etc. or treatment of soil and other roots In addition, it can also be used in hydroponic cultivation. In the hydroponic cultivation, Shige is used for cultivating ash, fumigation or stalking into the trunk, etc. It can also be distributed in, for example, storage pests, house pests, sanitary pests, and wood worms. In addition to use, it can also be used for painting of home building materials, fumigation de-ashing liquid, etc. ..., methods of treating seeds, for example, m ^ ^ in liquid or solid form, or after dilution The method of infiltrating the seed by liquid, soaking the agent == the agent or the liquid preparation and the seed are mixed, or the powder coating is applied to the body or the like, and the resin or the liquid preparation is used. a method of applying to a seed, Or the method of dispersing the solid preparation or the liquid preparation in the vicinity of the seed, etc. in the back of the seeding. The above-mentioned treatment of the seed described in the above-mentioned plant, for example, the insertion of the plant. In addition to 嫉 method, including various bulbs, tubers, seeds, beads, bulbs or cuttings, etc. ^ When using the method of the invention, the plant "the soil, two #贝Special restrictions, as long as the material that can be grown by the shuttle, can be:, two: =, water, etc., such as sand, stone, stone, frozen, agar, gelatinous material, high-quality "glass cedar, wood chips" , bark, paper, etc.... sub-objects, rock wool, preparations or hydrating agents or granular hydration: 2: the method of ": 1 = dilution method # 襄" after the flowable agent, for example, Liquid preparation diluted with water 318305 36 200800021, pre-dispersed powder, hydrating agent, granules:::: square 2: before or after transplanting. Mixing method, or before planting or before planting; Mixture, granules are equal to planting points, planting =,, = mixture, granule rice seedling box t :: administration of the agent with the administration of transplantation period of administration, etc. while administering: Multicast = two, green agent, granular wettable powder, granules and the like dosage forms can. The sling can be mixed with the culture soil, the θ a , or the granulated water culture soil by mixing with the granules or granules, and the soil can be mixed and coated in a layer form. 5 only the various preparations and culture soil cross-water: medium application method, usually, in the water-like paddy field sergeant: a large amount of packaging agents, granules, granular hydrating agents and other solid preparations, ς == preparations, emulsions, etc. A method of dispersing a preparation or the like. Others can be used to distribute the fertilizers into the water source. The water source or the irrigation device can be used for water supply. Labor saving. The application of dryland crops can be carried out on the seeds or in the cultivation medium close to the plant body during the self-seeding, seedling period and growth period. Direct sowing In plants in dry land, in addition to directly treating the preparation to the seed, it is preferred to treat the base of the plant in the cultivation with the preparation. It may be treated by granule dispersion, or may be treated by liquid infusion with a drug diluted with or without dilution. It is also a good method to mix the granules with the cultivation medium before sowing. The cultivated plants that need to be transplanted are treated in the sowing and seedling stage, 318305 37 200800021. In addition to the direct treatment of the seeds, it is better to disperse the liquid preparation or the granular preparation in the seedling bed for seedlings. In addition, it is also a good method to plant the acupoints at the time of planting, or to mix the cultivation medium adjacent to the transplant site. &gt; The bio-control agent of the present invention is generally manufactured (4), for example, a ritual, a ritual suspension, a hydrating agent, a granular hydrating agent, a suspending agent, a flowable agent, a liquid agent, a granule, A dosage form of a powder, a bulk packaging agent, a misting agent, a fumigant, etc., the amount of the composition, the blending ratio of the financial effect component, the meteorological condition, the form of the preparation, the application period, the application method, the application site, and the control It is different from the target pests, the target crops, etc., and usually, the effective components of the production (including the compound of the general formula (1) and the sum of the compounds of the aphid activity, the bactericidal activity or the nematicidal activity) are exchanged. The application may be appropriately selected from the range of .ig to iooog, and it is preferred to select the application in the range of ig, 500 §. When the seed is treated, and the seed weight is converted to the active ingredient in the rut preparation, it may be used in the range of Μ to %%, among which it is preferably used in the range of 〇1 to 1%. When it is applied by diluting an emulsion, a hydrating agent or the like with water, it is applied at a concentration of 0.00001 to 1·1%, granules, powders or liquid preparations for seed treatment, and the like, and it is usually used without being diluted. χ '% in the present invention, generally means % by weight (w/w) 0. In addition, the period of use of the pest control agent of the present invention, in order to prevent simultaneous diseases and/or weeds, other active ingredients a compound having insecticidal activity, bactericidal activity or nematicidal activity, which can be used simultaneously with a compound having bactericidal activity or herbicidal activity and a compound having insecticidal activity m or nematicidal activity 318305 38 200800021 τ It is expected that the synergistic effect of the herbicide effect can be expected by controlling the range of pests and diseases of the object and reducing the amount of the drug. The compound having bactericidal activity or herbicidal activity, such as the following compounds. Examples of bactericidal active compounds such as azoxystrobin, dilococymet, pyroquilon, kasugamycin, propyl chelsone (^1'〇7 &amp; 1^ 〇5;16?), hymexazol, mepronil, tricyclazole, edifenphos, isoprothiolane, blastcidin , flutolanil, dynasty ((11(;1〇11^211]^), pencycuron, carbendazin, dodine, puffer ( Propamocarb), pyrimethanil, fluquinconazole, focetyl-AL, bromuconazole, triticonazole, fluxetover, imipenem Fenamidone, tolylfluanid, dichlofluanid, trifloxystrobin, triadimenol, spiroxamine, fenhexamid, Iprovalicarb, fthalide, iprodione, thio Phanate), benomyl, triflumizole, fluazinam, zineb, captan, manzeb, fenremore Fenarimol), calcium polysulfide, triadimefon, vinclozolin, dithianon, bitertanol, polycarbamate, gram heat (iminoctadine-DBS), gram grass enemy 39 318305 200800021 • (pebulate), polyoxin-B (polyoxin-B), methyl zinc napro (propineby, chinomethionat, dichlofluanid, tetrachloroiso Chlorothalonil, difenoconazole, fluoroimide, 赛福宁 01^〇1^1^), octopus (uncle &amp; (!1 and 71), streptomycin ( Streptomycin), zinc mannep (111 &amp; 11 (; 〇 2613), oxolinic acid (〇 〇 1111 沁 acid), mepronil, metalaxyl, propiconazole, phenanthrene Hexaconazole, sulfur, pyrifenox, basic copper sulfate, Mouth # (pyrimethanil), iprobenfos, tolclofos-methyl, maneb, thiophanate-methyl, trifluzamide, flor Ratio (furametpyr), flusulfamide, kresoxim_methyl, carpropamid, hydroxyisoxazole, echlomezole, procymidone, gram Vinclozolin, ipoconazole, furconazole, myclobutanil, tetraconazole, tebuconazole, imibenconazole, poker 卩1 ^〇(:111〇^2), pefurazoate, cyproconazole, mepanipyrim, thiadiazin, probenazole, benzoxadiazole Acibenzolar-S-methyl), validamycin-A, fenoxanil, tiadinil and other fungicides can be used in combination. Secondly, compounds with herbicidal activity, such as free radical 40 318305 200800021 ^ (bensulfuron-metliyl), four azlmsulfuron, cinosulfuron, cyclosulfamuron, ° ratio Pyrazosulfuron-ethyl, imazosulfuron, indanofan, cyhalofopbutyl, thenylchlor, esprocarb, acetophenone Amine (etobenzanid), cafestrole, clomepTop, dimethametryn, daimuron, bifenox, pyributicarb, sigma φ (pyriminobac-methyl), pretilachlor, bromobutide, benzofenap, benthiocarb, bentoxazone, benfuresate , mefenacet, ethyl fenoxaprop-P_ethyl, phenmedipham, diclofop-methyl, desmedipham, ethofumesate ), isoproturon,Amidosulfuron, anilofos, benfuresate, ethoxysulfuron, ° iodosufluron, diphenyl sulphur acid (isoxadifen), methamsulfuron, foramsulfuron, double-mouthed grass (卩)^&amp;〇1〇1111), mesosulfuron, diuron, niblon Neburon), dinoterb, carbeamide, bromoxynil, oxyadiazon, dimefuron, diflufenican, dipivoxil Aclonifen), benzofenap, 17 oxaziclomefone, isoxaflutole, oxadiargyl, flurtamone, chlorhexidine 41 318305 200800021 • (metribuzin), methabenzthiazuron, tribufos, metamitron, ethiozin, flufenacet, thioglycone (sulcotrion), fentrazamide, propylidene huanglong (卩1*〇卩〇\}^&amp;1^&amp;2〇1^) On one Danhuang Long (flucarbazone), sulcotrione laugh amine (metosulam), saliva oxadiazon amine (amicarbazone) and other herbicides, for a mixture. Further, the herbicides described in the following general names may also be used in combination. For example, glyphosate-isopropyl amine, glyphosate-trimesium, glufosinate-ammonium, bialaphos, butamifos, Prosulfocarb, asulam, linuron, calcium, peroxide, alachlor, pendimethalin, acifluofen- Sodium), lactofen, ioxynil-octanoate, alloxydim, sethoxydim, napropamide, mouth-to-mouth (pyrazolate), pyraflufen-ethyl, imazapyr, sulfentrazone, oxadiazon, paraquat, diquat ( Diquat), simazine, atrazine, fluthiacet-methyl, quizalofop-ethyl, bentazone, BAS-3510- H, triaziflam (triaziflam) and the like. Further, thidiazuron, mefenpyr, ethephon, cyclanilide or the like having plant growth regulating effects may be used in combination. 42 318305 200800021 I. Further τ Ben Puming's harmful IT control agent 泰 ▼ is used together with biological pesticides, such as nuclear polyhedrosis virus (NPV), Granulosis virus (Granulosis virus) , GV), Cytoplazmic polyhedrosis virus (CPV), Entomopox virus (EPV) and other viral preparations, Monacrosporium phymatophagum, Steinernema carpocapsae, Steinernema kushidai For the use of insecticidal or nematicidal agents such as Pasteuria penetrans, microbial pesticides, Trichodermalignorum, Agrobacterium radiobacter, and non-pathogenic carrots Erwinia carotovora And biological pesticides such as microbial pesticides used in fungicides such as Bacillus subtilis and Monacrosporium phymatophagum, and herbicides such as Xanthomonas campestris, can be used in combination. And look forward to getting the same fruit.

^ 另外,生物性農藥尚有例如麗輯小蜂(Encarsia W^ In addition, biological pesticides such as Encarsia W

Formosa)、棉对寄生蜂(Aphidius colemani)、食辑癭蚊 (Aphidoletes aphidimyza)、外寄生蜂(Diglyphus isaea)、内 寄生蜂(Dacnusa sibirica)、智利捕植蜗(Phytoseiulus persimilis)、黃瓜鈍綏蜗(Amblyseius cucumeris)、小黑花椿 象(Oriussauteri)等天敵生物、布氏白僵菌(Beauveria brongniartii)等微生物農藥、(Z)-10-十四烯基乙酸酯、 (E,Z)-4,10-十四碳二烯基乙酸酯、(Z)-8_十二烯基乙酸酯、 (Z)-ll-十四烯基乙酸酯、(Z)-13-二十烯-10-酮、(Z)_ll-十 43 318305 200800021 四細基乙酸S旨、(Z)-13 -二十細-10·嗣、14-曱基-1 -十八炸等 贺爾蒙劑,尚可併用本發明之有害生物防除劑。 貫施例 本發明舉典型之實施例及試驗例如下,惟本發明不受 其侷限。又,實施例中,份量指重量份。實施例及試驗例 中,「化合物(a)」或試驗例之表中之「(a)」乃指表1中所 記載之化合物Νο·15(即,本發明研究者所申請日本專利特 開2001-342186號公報中表4所記載之化合物號碼448所 ⑩示經取代之胺基喹唑啉酮化合物。) 實施例1 化合物(a) 20份 芬普蜗(fenpyroximate) 5 份 含水矽酸 30份 HITENOLN08(第一工業製藥製品) 5份 木質石黃酸詞 3份 A黏土水合劑 42份Formosa), Aphidius colemani, Aphidoletes aphidimyza, Diglyphus isaea, Dacnusa sibirica, Phytoseiulus persimilis, Cucumber blunt (Amblyseius cucumeris), natural enemies such as Oriussauteri, microbial pesticides such as Beauveria brongniartii, (Z)-10-tetradecyl acetate, (E, Z)-4 , 10-tetradecadienyl acetate, (Z)-8-dodecenyl acetate, (Z)-ll-tetradecenyl acetate, (Z)-13-epexene -10-ketone, (Z)_ll-Ten 43 318305 200800021 tetrakilytic acid S, (Z)-13 - 20 fine -10 · 嗣, 14-mercapto-1 - 18 fried and other hormones The pest control agent of the present invention can also be used in combination. DETAILED DESCRIPTION OF THE INVENTION The present invention is exemplified by typical examples and tests, but the invention is not limited thereto. Further, in the examples, the parts are parts by weight. In the examples and the test examples, "(a)" in the table of the "compound (a)" or the test examples means the compound Νο·15 described in Table 1 (that is, the Japanese patent application filed by the researcher of the present invention) Compound No. 448, shown in Table 4 of JP-A-2001-342186, shows a substituted aminoquinazolinone compound. Example 1 Compound (a) 20 parts fenpyroximate 5 parts aqueous citric acid 30 HITENOLN08 (first industrial pharmaceutical product) 5 parts of woody rubic acid word 3 parts A clay hydrating agent 42 parts

W 將有效成分化合物浸潰於含水梦酸之後,和其他成分 混合均一而成水合劑。 實施例2 化合物(a) 20份 11比瞒胺(tebufenpyrad) 10份 ΝΡΕ·100(第一工業製藥製品) 20份 丙二醇 5份 羅多波兒23(羅奴布朗公司製品) 2份 44 318305 200800021 水 43份 將上述成分混合均一後,分散水中而成可流動性劑 實施例3 化合物(a) 15 份 替扶苯隆(teflubenzuron) 5份 SP-3005X(東邦化學製品) 10 份 N-甲基吡咯烷酮 15 份 二甲苯 55 份W After immersing the active ingredient compound in aqueous dream acid, it is mixed with other ingredients to form a hydrating agent. Example 2 Compound (a) 20 parts of 11 decylamine (tebufenpyrad) 10 parts ΝΡΕ·100 (first industrial pharmaceutical product) 20 parts of propylene glycol 5 parts of Rodolfo 23 (product of Ronald Brown) 2 parts 44 318305 200800021 43 parts of water, the above components are uniformly mixed, and dispersed in water to form a flowable agent. Example 3 Compound (a) 15 parts tebufenzuron 5 parts SP-3005X (Toho Chemicals) 10 parts N-methyl Pyrrolidone 15 parts xylene 55 parts

將以上成分混合融解均一而成乳劑。 20份 10份 20份 2份 1份 47份 實施例4 化合物(a) 得芬諾(tebufenozide) NPE-100(第一工業製藥製品) 丙二醇 羅多波兒23 水 將上述成分混合均一後,分散水中而成可流動劑。 實施例5 化合物(a) 20份 布芬淨(buprofezin) 20份 含水珍酸 34份 HITENOL N08 3份 得莫兒T 2份 碳酸躬粉末 21份 45 318305 200800021 蔣有致成分化合物浸潰含水矽酸之後,和耳他成分混 合均一而成水合劑。 實施例6 化合物(a) 10份 唾蟲瞒胺(tolfenpyrad) 10份 SP-3005X 10份 N-甲基吡咯烷酮 15份 二曱苯 55份 將以上成分混合融解均勻而成乳劑。 實施例7 化合物(a) 20份 福化利(fluvalinate) 10份 NPE-100 20份 丙二醇 2份 羅多波兒23 1份 水 47份 將上述成分混合均一 實施例8 ,分散水中而成可流動劑。 化合物(a&gt; 20份 溴蟲腈(chlorfenapyr) 10份 NPE-100 35份 丙二醇 3份 羅多波兒23 2份 水 30份 46 318305 200800021 ' — 將上述成分混吾均一一,分散水中;成可1奈動爾。 實施例9 化合物(a) 2份 氟苯二酿胺(flubendiamide) 1份 黏土粉末 82份 矽藻土粉末 15份 Μ驗例1 對於甘藍之小菓蛾(Plutella xvlostella)及煙桃虫牙 • (Myzus persicae)之防除效果 將以上成分混合粉碎均一而成粉劑。 定植甘藍(品種:YR晴德)於圃場,定植約1個月後調 查每30株之寄生蟲數目,並充分散布稀釋調製成為有效濃 度之藥液。散布後約1星期後再調查每30株之寄生蟲數 目,而以下式計算得防除率(%)。每一區二重複。其結果示 於表3。 防除率=100_{(TaxCb)/(TbxCa)}xl00 φ Ta :處理區在散布後之寄生蟲數目The above ingredients are mixed and melted to form an emulsion. 20 parts 10 parts 20 parts 2 parts 1 part 47 parts Example 4 Compound (a) Tebufenozide NPE-100 (first industrial pharmaceutical product) Propylene glycol Rodolol 23 water After mixing the above ingredients, the dispersion A flowable agent in water. Example 5 Compound (a) 20 parts of buprofezin 20 parts of water-containing acid 34 parts of HITENOL N08 3 parts of Moer T 2 parts of strontium carbonate powder 21 parts 45 318305 200800021 After the composition of the compound is impregnated with aqueous citric acid , and the ingredients of the ear are mixed to form a hydrating agent. Example 6 Compound (a) 10 parts Tolfenpyrad 10 parts SP-3005X 10 parts N-methylpyrrolidone 15 parts Diphenylbenzene 55 parts The above ingredients were mixed and melted to form an emulsion. Example 7 Compound (a) 20 parts of fluvalinate 10 parts of NPE-100 20 parts of propylene glycol 2 parts of rodolol 23 1 part of water 47 parts The above ingredients were mixed in a uniform example 8 to be dispersed in water to form a flowable Agent. Compound (a> 20 parts chlorfenapyr 10 parts NPE-100 35 parts propylene glycol 3 parts Rodolfo 23 2 parts water 30 parts 46 318305 200800021 ' - Mix the above ingredients one by one, disperse the water; Example 9 Compound (a) 2 parts flubendiamide 1 part clay powder 82 parts diatomaceous earth powder 15 parts Μ test example 1 For the cabbage fruit moth (Plutella xvlostella) and The control effect of Myzus persicae (Myzus persicae) is to mix and pulverize the above ingredients into a powder. The planted cabbage (variety: YR Qingde) is planted in the market, and the number of parasites per 30 plants is investigated after planting for about 1 month. The drug solution was diluted and prepared to have an effective concentration, and the number of parasites per 30 plants was investigated about one week after the dispersion, and the control rate (%) was calculated by the following formula. The results were shown in Table 3. Control rate = 100_{(TaxCb) / (TbxCa)} xl00 φ Ta : number of parasites after treatment in the distribution area

Tb:處理區在散布前之寄生蟲數目 Ca:無處理區在散布後寄生蟲數目 Cb:無處理區在散布前寄生蟲數目 莖驗你I 2對於茄子棉铃為(Helicoverpa armigera)、南黃薊 遍(Thrips palmi)及溫室白粉益(Trialeurodes vaporarionim) 之防除效果 調查種植在圃場之茄子(品種:千兩2號)每10株計之 棉鈐蟲幼蟲數目及每100葉片計之南黃薊馬幼蟲數目和溫 47 318305 200800021 …室白粉蝨之寄生蟲1目,潘後,充分散布舞释調製成有效 濃度之藥液。散布藥液1星期後調查每1 〇株計之棉鈴蟲幼 蟲數目及每100葉片計之南黃薊馬幼蟲數目和溫室白粉蝨 寄生蟲數目,分別按照下式計算其防除率(%)。其結果示於 表4 〇 防除率(%)=100_{(TaxCb)/(TbxCa)}xl00Tb: number of parasites before treatment in the treatment area Ca: number of parasites after dispersal in the treatment area Cb: number of parasites before treatment in the untreated area stems test I 2 for eggplant bolls (Helicoverpa armigera), southern jaundice The control effect of Thrips palmi and Trialeurodes vaporarionim on the number of cotton aphid larvae per 10 strains of eggplant planted in the market (variety: thousand two 2) and the southern yellow pheasant per 100 leaves Number of larvae and temperature 47 318305 200800021 ... The parasite of the whitefly of the whitefly is 1 mesh, after the pan, fully spread the dance to a concentration of the drug solution. One week after the dispersion of the drug solution, the number of cotton bollworm larvae per cockroach and the number of larvae of the yellow cockroach and the number of larvae of the greenhouse whitefly were counted per 100 leaves, and the control rate (%) was calculated according to the following formula. The results are shown in Table 4. 〇 Control rate (%) = 100_{(TaxCb) / (TbxCa)} xl00

Ta ··處理區之散布後之寄生蟲數目Number of parasites after the spread of the Ta·· treatment area

Tb ··處理區之散布前之寄生蟲數目 # Ca :無處理區之散布後寄生蟲數目Number of parasites before the spread of Tb·· treatment area # Ca : Number of parasites after dispersal in the treatment area

Cb:無處理區之散布前寄生蟲數目 試驗例3 對於蘋果之康氏粉紛(Pseudococcus comstocki) 及二黑占葉瞒(Tetranychus urticae)之防除效果 調查種植在圃場之蘋果樹(品種:富士,8年生)每20 支枝條計之康氏粉蚧之寄生數目及每100葉片計之二點葉 蟎雌成蟲數目,充分散布稀釋調製成為有效濃度之藥液。 I然後,在散布藥液2星期後,再調查每20支枝條之康氏粉 響 蚧之寄生數目,以及散布1、2、3、4星期後,每100葉片 之二點葉蟎雌成蟲數目,分別按照下式求得防除率(%)(康 氏粉蚧)及防除效率(%)(二點葉蟎)。其結果示於表5。 防除率(%)=100-{(TaxCb)/(TbxCa)}xl00 Ta :處理區之散布後之寄生蟲數目 Tb ··處理區之散布前之寄生蟲數目 Ca:無處理區之散布後寄生蟲數目 Cb:無處理區之散布前寄生蟲數目 48 318305 200800021 一 — — — - rr — — :n ^ 防除效率(%)={1 -(CtXETa) / (TbXSCa) } X100 \ = I i 552 1 n :散布後之調查次數 Ta :處理區在散布後第i次調查密度 Tb :處理區之散布前調查密度 Ca :無處理區在散布後第i次調查密度 Cb :無處理區之散布前調查密度 試驗例4 對於柑桔之箭頭介殼蟲(Unaspis yanonensis)、 φ 棉虫牙(Aphis gossypii)及掛桔葉瞒(Panonychus (^忭〇之防除 效果 調查種植在圃場之柑桔樹(品種:興津早生,8年生) 每20支枝條上之箭頭介殼蟲寄生雌蟲數目,棉蚜寄生蟲數 目,以及每100葉片計棉蚜寄生蟲數目及柑桔葉螨雌成蟲 數目,並充分散布稀釋調製成為有效濃度之藥液。然後, 在散布2星期後調查每20枝條之矢根介殼蟲之寄生蟲數 赢目,以及散布1、2、3、4星期後每20支枝條上之棉蚜寄 生數目和每100葉片計之柑桔葉螨雌成蟲數目,分別按照 上記相同計算式計算防除率(%)(箭頭介殼蟲、棉蚜)及防除 效率(%)(柑桔葉蟎)。其結果示於表6。 試驗例5 對於水稻之稻縱捲葉鎮(Cnaphalocrocis medinalis)及褐飛益(Nilaparuata lugens)之防除效果 移植稻秧(品種:越光)於水田(5月中旬),在8月上旬 調查處理區每100株計之稻縱捲葉螟為害葉數及褐飛蝨之 成幼蟲數,並充分散布稀釋調製成為有效濃度之藥液。然 49 318305 200800021 ^ 後,在散布約7星期後調查海TOO株&quot;計之^縱捲葉螟爲害 葉數及褐飛蝨成幼蟲數,再按照下式計算其防除率(%),其 一結果示於表7 〇 防除率(%)=100-{(TaxCb)/(TbxCa)}xl00Cb: Number of pre-spreading parasites in the untreated area Test Example 3 For the control effect of Pseudococcus comstocki and Tetranychus urticae, the apple trees planted in the market were investigated (variety: Fuji, 8 years old) The parasitic number of Kang's whitefly per 20 branches and the number of female adults of the two leaf spiders per 100 leaves, fully diffused to make the effective concentration of the liquid. I then, after 2 weeks of dispersing the drug solution, investigate the parasitic number of each 20 branches of the Kang's powder, and the number of females of the two leaf spiders per 100 leaves after 1, 2, 3, and 4 weeks of dissemination. According to the following formula, the control rate (%) (Kang's whitefly) and the control efficiency (%) (two-point leafhopper) were obtained. The results are shown in Table 5. Control rate (%)=100-{(TaxCb)/(TbxCa)}xl00 Ta : number of parasites after the spread of the treatment zone Tb ··number of parasites before the spread of the treatment zone Ca: post-dispatch parasitization without treatment zone Number of insects Cb: Number of pre-spreading parasites without treatment area 48 318305 200800021 I — — — — rr — — : n ^ Control efficiency (%)={1 -(CtXETa) / (TbXSCa) } X100 \ = I i 552 1 n : number of investigations after dissemination Ta : treatment area after the second survey density Tb: density of the treatment area before the investigation of the density Ca: no treatment area after the distribution of the i-th survey density Cb: before the distribution of the treatment area Investigating Density Test Example 4 For citrus arrow insects (Unaspis yanonensis), φ cotton worms (Aphis gossypii), and hanging orange leaf mites (Panonychus (忭〇 忭〇 防 效果 调查 调查 调查 调查 调查 调查 调查 调查 调查 调查 调查 调查 调查 调查 调查 调查 调查 调查 兴 兴 兴 兴Early birth, 8 years old) The number of parasitic females on each 20 branches, the number of cotton aphid parasites, and the number of cotton parasitic insects per 100 leaves and the number of female adults of citrus leaf mites, fully dispersed and diluted Effective concentration of the drug solution. Then, spread 2 stars After the investigation, the number of parasites per 20 branches of the root-web scale insects was won, and the number of cotton mistletoe on every 20 branches after 1, 2, 3, and 4 weeks and the number of female adults of citrus leaf mites per 100 leaves were investigated. The control rate (%) (arrow beetle, cotton aphid) and control efficiency (%) (citrus leafhopper) were calculated according to the same calculation formula above. The results are shown in Table 6. Test Example 5 Rice vertical rolls The control effect of Cnaphalocrocis medinalis and Nilaparuata lugens was transplanted in rice paddy (variety: Koshihikari) in paddy field (mid-May), and in the first half of August, the rice leaf curls were counted in 100 per plant.螟 螟 数 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 The number of damaged leaves and the number of larvae of brown planthopper were calculated, and the control rate (%) was calculated according to the following formula. The results are shown in Table 7. 〇 control rate (%) = 100-{(TaxCb)/(TbxCa)}xl00

Ta :處理區之散布後被害葉數/100株 Tb :處理區之散布前被害葉數/100株 Ca:無處理區之散布後被害葉數/100株 Cb :無處理區之散布前被害葉數/100株 • 防除率(%)=100-{(TaxCb)/(TbxCa)}xl00Ta : number of damaged leaves after treatment area / 100 strains of Tb : number of damaged leaves before treatment area / 100 strains of Ca: number of damaged leaves after spreading without treatment area / 100 strains of Cb : scattered leaves before treatment of untreated areas Number / 100 strains • Control rate (%) = 100 - {(TaxCb) / (TbxCa)} xl00

Ta :處理區之散布後寄生蟲數目/100株 Tb :處理區之散布前寄生蟲數目/100株 Ca:無處理區之散布後寄生蟲數目/100株 Cb:無處理區之散布前寄生蟲數目/100株 下列表中所記載(a)指化合物(a),乃表1中之化合物 No· 15。又,試驗例之表中記以「一」示未實施試驗。Ta : number of parasites after spreading in the treatment area / 100 strains of Tb : number of pre-spreading parasites in the treatment area / 100 strains of Ca: number of post-spreading parasites without treatment area / 100 strains of Cb: pre-distributed parasites without treatment area The number / 100 of the following list (a) means the compound (a), which is the compound No. 15 in Table 1. In addition, in the table of the test example, "1" is shown, and the test is not performed.

50 318305 200800021 表3 甘藍上小菜蛾及煙桃騎之,除政果 供試藥劑 濃度(ppm) 防除率(%) 小菜蛾 煙桃虫牙 (a)+芬普瞒(fenpyroximate) 50+50 94 100 (a)+a比瞒胺(tebufenpyrad) 50+100 96 100 (a)+嗤蟲蟎胺(tolfenpyrad) 50+150 100 100 (a)+布芬淨(buprofezin) 50+200 55 100 (a)+得芬諾(tebufenozide) 50+100 100 100 (a)+福化利(fluvalinate) 50+100 60 100 (a)+替扶苯隆(teflubenzuron) 50+25 70 100 (a)+ 免扶克(fenobucarb ; 50+500 80 100 BPMC) (a)+ 滅必盘(isoprocarb ; 50+500 70 100 MIPC) (a)+歐殺松(acephate) 50+500 100 100 (a) 50 25 100 芬普蜗(fenpyroximate) 50 45 55 °比瞒胺(tebufenpyrad) 100 55 65 σ坐蟲蜗胺(tolfenpyrad) 150 97 95 布芬淨(buprofezin) 200 0 10 得芬諾(tebufenozide) 100 75 15 福化利(fluvalinate) 100 5 100 替扶苯隆(teflubenzuron) 25 15 18 免扶克(BPMC) 500 20 50 滅必蝨(MIPC) 500 20 一 歐殺松(acephate) 500 60 65 51 318305 200800021 表4茄子棉鈐蟲、南黃莉馬及-溢室一白粉蝨之下方除致果 供試藥劑 濃度 防除率 (ppm) 棉铃蟲 南黃薊馬 溫室白粉蝨 (a)+芬普瞒(fenpyroximate) 50+50 75 95 100 (a)+n比蜗胺(tebufenpyrad) 50+100 80 93 100 (a)+嗤蟲瞒胺(tolfenpyrad) 50+150 100 100 100 (a)+得芬諾(tebufenozide) 50+100 100 90 100 (a)+福化利(fluvalinate) 50+100 80 96 100 (a)+替扶苯隆(teflubenzuron) 50+25 100 93 100 (a)+1 苯二醯胺(flubendiamide) 50+100 100 97 100 (a)+美他 It 米隆(metaflumizone) 50+250 100 95 100 (a)+免扶克(fenobucarb ; BPMC) 50+500 90 93 100 (a)+滅必兹(isoprocarb ; MIPC) 50+500 75 80 100 (a)+歐殺松(acephate) 50+500 100 95 100 (a) 50 15 85 100 芬普蜗(fenpyroximate) 50 30 25 85 °比瞒胺(tebufenpyrad) 100 35 20 83 °坐蟲蜗胺(tolfenpyrad) 150 93 90 84 得芬諾(tebufenozide) 100 78 18 15 福化利(fluvalinate) 100 25 85 45 替扶苯隆(teflubenzuron) 25 100 90 16 苯二醯胺(flubendiamide) 100 100 20 12 美他氟米隆(metaflumizone) 250 100 10 10 免扶克(fenobucarb ; BPMC) 500 50 80 20 滅必兹(isoprocarb ; MIPC) 500 30 65 20 聲殺松(acephate) 500 95 90 50 52 318305 200800021 — 表5 —蘋果上康氏粉^及二^ 供試藥劑 濃度(ppm) 防除率(%) 康氏粉虫介 二點葉蟎 (a)+嗤蟲蟎胺(tolfenpyrad) 67+150 100 100 ⑻+布芬淨(buprofezin) 67+200 100 60 • (a)+得芬諾(tebufenozide) 67+100 100 65 (a)+替扶苯隆(teflubenzliron) 67+50 100 85 (a) 67 100 35 峻蟲蟎胺(tolfenpyrad) 150 50 65 布芬淨(buprofezin) 200 100 10 得芬諾(tebufenozide) 100 20 15 替扶苯隆(teflubenzuron) 50 21 35 表6 柑桔上箭頭介殼蟲、棉蚜及柑桔葉蟎之防除效果 供試藥劑 濃度 (PPm) 防除率(%) 箭頭 介殼蟲 棉蚜 柑桔 葉螨 (a)+唾蟲蜗胺(tolfenpyrad) 67+150 100 100 85 ⑻+布芬淨(buprofezin) 67+200 100 100 65 (a)+得芬諾(tebufenozide) 67+100 100 100 75 (a)+溴蟲腈(cMorfenapyr) 67+50 100 100 85 (a)+福化利(fluvalinate) 67+100 100 100 90 (a)+替扶苯隆(teflubenzuron) 67+25 100 100 85 (a)+ 說苯二醯胺(flubendiamide) 67+100 100 100 90 ⑻ 67 100 100 25 峻蟲蜗胺(tolfenpyrad) 150 45 100 65 布芬淨(buprofezin) 200 100 20 25 得芬諾(tebufenozide) 100 25 25 35 溴蟲腈(chlorfenapyr) 25 45 35 45 福化利(fluvalinate) 100 43 85 50 替扶苯隆(teflubenzuron) 25 25 28 40 氟苯二醯胺(flubendiamide) 100 22 25 30 53 318305 200800021 1 7 水稻工稻搜捲葉螟及福C兹之防療效&gt; 供試藥劑 濃度(ppm) 防除尋 K%) 稻縱捲葉螟 褐飛兹 (a)+布芬淨(buprofezin) 50+200 55 100 (a)+得芬諾(tebufenozide) 50+100 100 100 (a)+ 氣苯二醯胺(flubendiamide) 50+25 100 100 (a)+美他氟米隆(metaflumizone) 50+250 100 100 (a)+免扶克(fenobucarb ; BPMC) 50+500 100 100 (a)+滅必兹(isoprocarb ; MIPC) 50+500 100 100 (a)+歐殺松(acephate) 50+500 100 100 (a) 50 10 90 布芬淨(buprofezin) 200 15 100 得芬諾(tebufenozide) 100 100 13 氟苯二醯胺(flubendiamide) 100 100 35 美他 It 米隆(metaflumizone) 250 100 0 免扶克(fenobucarb ; BPMC) 500 90 90 滅必為(isoprocarb ; MIPC) 500 90 90 歐殺松(acephate) 500 100 80 試驗例6 對於青葱之競萷馬(Thrips tabaci丫之防除效I 調查栽植於圃場之青葱(品種:九條葱)每1〇株計之葱 薊馬之成蟲及幼蟲數目,充分散布稀釋調製成為有效濃度 _之藥液。然後,在散布10日後調查每10株計之葱薊馬之 成蟲及幼蟲數目,分別按照下式計算防除率(%)。其結果示 於表8 〇 防除率(%)=100-{(TaxCb)/(TbxCa)}xl00 Ta:處理區之散布後寄生蟲數目 Tb :處理區之散布前寄生蟲數目 Ca :無處理區之散布後寄生蟲數目 Cb :無處理區之散布前寄生蟲數目 54 318305 200800021 表8青m薊馬之防除政果 供試藥劑 濃度(ppm) 防除率(%) (a)單用 100 62 唑蟲螨胺(tolfenpyrad)單用 150 65 (a)+唑蟲蟎胺(tolfenpyrad) 100+150 98 試驗例7 對於痴子之西方花薊馬(Frankliniella occidentalis)之防除效果 調查種植於圃場之茄子(品種:千兩2號)每10株計之 _西方花莉馬之成蟲及幼蟲數目,充分散布稀釋調製成為有 效濃度之藥液。散布10日後再調查西方花薊馬之成蟲及幼 蟲數目,分別按照下式計算防除率(%)。其結果示於表9。 防除率(%)=100_{(TaxCb)/(TbxCa)}xl00 Ta :處理區之散布後寄生蟲數目 Tb:處理區之散布前寄生蟲數目 Ca:無處理區之散布後寄生蟲數目 A Cb:無處理區之散布前寄生蟲數目 表9 #子上西方花IS馬之防除效果 供試藥劑 濃度(ppm) 防除率(%) (a)單用 唑蟲蟎胺(tolfenpyrad)單用 (a)+峻蟲螨胺(tolfenpyrad) 100 150 100+150 8 71 91 倒..8—對於·杳—如之美洲良潛纖(Liriomyza sativae)之防 除效果 種植於圃場之蕃茄(品種:家庭桃太郎),充分散布以 318305 55 200800021 j 稀释調製成爲有效濃度之藥液。故布I星期後調查# To 株計美洲斑潛蠅之為害數目,分別按照下式計算防除率 (%) 〇其結果示於表10〇 P方除率(%)=10(HT/C)X100 T:處理區散布藥液後之數目 C :無處理區散布藥液後之數目 表10 蕃茄上之美洲斑潛蠅之防除效果 供試藥劑 濃度(ppm) 防除率(%) (a)單用 100 2 嗤蟲蜗胺(tolfenpyrad)單用 150 61 (a)+嗤蟲蜗胺(tolfenpyrad) 100+150 90 56 31830550 318305 200800021 Table 3 Plutella xylostella and nectarines on cabbage, except for the concentration of the test drug (ppm). Control rate (%) Plutella xylostella (a) + fenpyroximate 50+50 94 100 (a) +a than mebendpyrad 50+100 96 100 (a) + tolfenpyrad 50+150 100 100 (a) + buprofezin 50+200 55 100 (a) +tebufenozide 50+100 100 100 (a)+fluvalinate 50+100 60 100 (a)+teflubenzuron 50+25 70 100 (a)+ Fuke (fenobucarb; 50+500 80 100 BPMC) (a) + extepor (isoprocarb; 50+500 70 100 MIPC) (a) + acephate 50+500 100 100 (a) 50 25 100 Fenpu Fenpyroximate 50 45 55 ° than sulphonic acid (tebufenpyrad) 100 55 65 snail snail (tolfenpyrad) 150 97 95 buprofezin 200 0 10 tefenfen (idebufenozide) 100 75 15 Fuhuali ( Fluvalinate) 100 5 100 tebufenzuron 25 15 18 biceps (BPMC) 500 20 50 chlorhexidine (MIPC) 500 20 acephate 500 60 65 51 318305 200800021 Table 4 Eggplant Cotton aphid, Nanhuang Lima and - spilling room-white powder mites except the fruit concentration test concentration (ppm) Helicoverpa armigera South Yellow Stork horse greenhouse whitefly a (a) + fenpyroximate (fenpyroximate) 50+ 50 75 95 100 (a) +n than tebufenpyrad 50+100 80 93 100 (a) + tolfenpyrad 50+150 100 100 100 (a) + teffenozide 50+ 100 100 90 100 (a) + fluvalinate 50+100 80 96 100 (a) + tebufenzuron 50+25 100 93 100 (a) +1 flubendiamide 50 +100 100 97 100 (a)+美他 It milfumimizone 50+250 100 95 100 (a)+funk (fenobucarb; BPMC) 50+500 90 93 100 (a) + exteriz (isoprocarb ; MIPC) 50+500 75 80 100 (a) + acephate 50+500 100 95 100 (a) 50 15 85 100 fenpyroximate 50 30 25 85 ° peamine (tebufenpyrad) 100 35 20 83 ° tolfenpyrad 150 93 90 84 tebufenozide 100 78 18 15 fuvalinate 100 25 85 45 tebufenzuron 25 100 90 16 benzodiazepine (flubendiamide) 100 100 20 12 Methaflumone (me Taflumizone) 250 100 10 10 Fenbubucarb (BPMC) 500 50 80 20 Exoprocarb (MIPC) 500 30 65 20 Acoustic acephate 500 95 90 50 52 318305 200800021 — Table 5 — Apple Shangkang Powder and 2^ Test concentration (ppm) Control rate (%) Conifer powder worm (2) leafhopper (a) + locust amide (tolfenpyrad) 67+150 100 100 (8) + buffing net (buprofezin 67+200 100 60 • (a)+tebufenozide 67+100 100 65 (a)+teflubenzliron 67+50 100 85 (a) 67 100 35 lf 螨 螨 (tolfenpyrad 150 50 65 buprofezin 200 100 10 tebufenozide 100 20 15 teflubenzuron 50 21 35 Table 6 Control of arrow scale insects, cotton aphid and citrus leaf stalks on citrus Effect Test concentration (PPm) Control rate (%) Arrow scale insect cotton citrus leaf 螨 (a) + larvae (tolfenpyrad) 67+150 100 100 85 (8) + buprofezin 67+200 100 100 65 (a) + tebufenozide 67+100 100 100 75 (a) + chlorfenapyr (cMorfenapyr) 67+50 100 100 85 (a) + fuvalinate 67+100 100 100 90 (a) + tebufenzuron 67+25 100 100 85 (a) + flubendiamide 67+100 100 100 90 (8) 67 100 100 25 Tolfenpyrad 150 45 100 65 buprofezin 200 100 20 25 tebufenozide 100 25 25 35 chlorfenapyr 25 45 35 45 fuvalinate 100 43 85 50 tebufenzuron 25 25 28 40 Flubendiamide 100 22 25 30 53 318305 200800021 1 7 Rice industry rice search leafhopper and Fu CZ's anti-effects> Test agent concentration (ppm) Control K%) Rice vertical roll Leaf 螟 飞 ( (a) + buprofezin 50+200 55 100 (a) + tebufenozide 50+100 100 100 (a) + flubendiamide 50+25 100 100 (a) + metaflumizone 50+250 100 100 (a) + fokebucarb (BPMC) 50+500 100 100 (a) + extprozil (MIPC) 50+ 500 100 100 (a) + acephate 50+500 100 100 (a) 50 10 90 buprofezin 200 15 100 tebufenozide 100 100 13 flubendiamide 100 100 35 He It milfumizone 250 100 0 Fenbubucarb (BPMC) 500 90 90 Destruction (isoprocarb; MIPC) 500 90 90 Acetophenes 500 100 80 Test Example 6 For the lush horse (Thrips tabaci丫 control effect I Investigate the number of adult larvae and larvae of the onion and stalks of the scallions (variety: nine onions) planted in the market, and fully spread the diluted solution to become the effective concentration _ the liquid. Then, the number of adult larvae and larvae of each of the 10 plants was counted after 10 days of spreading, and the control rate (%) was calculated according to the following formula. The results are shown in Table 8. 〇 Control rate (%) = 100 - {(TaxCb) / (TbxCa)} xl00 Ta: number of parasites after dispersal in the treatment zone Tb: number of pre-spread parasites in the treatment zone Ca: no treatment zone Number of parasites after dispersal Cb : Number of parasites before dispersal in the treatment area 54 318305 200800021 Table 8 Concentration of the test agent (ppm) of the control group of the green m horses (%) Control rate (%) (a) 100 62 azole alone Tolfenpyrad alone 150 65 (a) + tolfenpyrad 100+150 98 Test Example 7 For the control effect of Frankliniella occidentalis, the eggplant planted in the market : 千二二号) The number of adult larvae and larvae of each of the 10 strains of the western flower, fully dispersed and diluted to become an effective concentration of the drug solution. After 10 days of dissemination, the number of adults and larvae of the western flower thrips was investigated, and the control rate (%) was calculated according to the following formula. The results are shown in Table 9. Control rate (%)=100_{(TaxCb)/(TbxCa)}xl00 Ta : number of parasites after dispersal in the treatment zone Tb: number of pre-spread parasites in the treatment zone Ca: number of parasites after dispersal of the treatment zone A Cb : Number of pre-discretions in the untreated area Table 9 #子上西花 IS horse control effect Test agent concentration (ppm) Control rate (%) (a) Tolfenpyrad alone (tolfenpyrad) alone (a ) + lf 螨 ( ( 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 , fully spread with 318305 55 200800021 j diluted to become the effective concentration of the drug solution. Therefore, after I week, I investigated the number of damages caused by #To strains of Liriomyza sativae, and calculated the control rate according to the following formula (%). The results are shown in Table 10. 〇P square removal rate (%) = 10 (HT/C) X100 T: Number of dispersing liquid after treatment area C: Number of untreated area after dispersing liquid medicine Table 10 Control effect of Liriomyza sativae on tomato Test substance concentration (ppm) Control rate (%) (a) Single Use 100 2 locust oleamine (tolfenpyrad) alone with 150 61 (a) + aphid snail (tolfenpyrad) 100+150 90 56 318305

Claims (1)

200800021 ‘十、申請專利範圍^ ^ ^ 一 ^ 1 · 一種有害生物防除劑,其特徵為含有自下列一般式所示 經取代之胺基喹唑啉酮化合物及其鹽類中選擇丨鐘以卜 之化合物’以及自具有殺蟲活性、殺蜗活性或殺線 性之化合物中轉〗種或2種以上之化合物,作為有效 成分, 一般式[I]200800021 '10. Patent application scope ^ ^ ^ 一 ^ 1 · A pest control agent characterized by containing a substituted quinolinone compound and its salts from the following general formula: a compound 'and a compound derived from a compound having insecticidal activity, bactericidal activity or linear killing or two or more compounds as an active ingredient, general formula [I] {式中,R示: (1) 氫原子, (2) 甲醯基, (3) (CVC12)烷基, (4) 鹵(CKC6)烷基, (5) (C2-C6)烯基, (6) (CVC6)炔基, ⑺(CkD烧硫基, ⑻鹵((VG)烧硫基, (9)(C〗-C6)烧基叛基, (i〇)(c3-c6)環烷基羰基,| (iiXCkCo烷氧基羰基, 318305 57 200800021 (14) 苯基幾基, (15) 具有自鹵素原子、硝基、氰基、(CVC6)烷基、 , 鹵(C^C^)烷基、(CrQ)烷氧基、鹵(CVC6)烷氧 基、(C!-C6)烧硫基及鹵(Ci-C6)烧硫基中選擇1 至5個取代基之苯基羰基(惟,具有複數個取代 基時,該取代基可為相同或不同), (16) 苯基(C2-C6)烯基, ⑩ (17)於環上具有自鹵素原子、硝基、氰基、(CVC6) 烧基、鹵((VC6)烷基、(cKc6)烷氧基、鹵(Cl_c6) 烧氧基、(Ci-C6)烧硫基、鹵(cvc6)烧硫基及 (CkC2)伸烷基二氧基中選擇1至5個取代基之 苯基(CVC6)烯基(惟,具有複數個取代基時,該 取代基可為相同或不同), (18)苯基(C2-C6)炔基,或 # U9)於環上具有自鹵素原子、硝基、氰基、(CVC6) 院基、鹵(CVC6)烧基、(Ci-C^)烧氧基、痛(CrC^) 烧氧基、(Cj-C6)烧硫基、鹵(CrQ)^硫基及 (CrC:2)伸烷基二氧基中選擇1至5個取代基之 苯基(C2_C4)炔基(惟,具有複數個取代基時,該 取代基可為相同或不同), R1示吡啶基或吡啶-N-氧化物基、z i_N=c(R2)_ (式中,R2示氫原子、(CVC:6)烷基或鹵(Ci_C6)烷基) 或示離3)韻(的_(式中,r2*氫原子、(Ci_C6)炫 318305 58 200800021 … —基或鹵(C7-C6)燒基-,妒示氫廣手-或(Ci-Cj炫基^ 不 · - (1)溴原子, (2) 蛾原子, (3) 經基, (4) (Ci_C6)炫基, (5) (C2-C6)烯基, (6) (C2-C6)炔基, ⑩ (7)鹵(Ci-Cg)烧基, (8) (CVC6)烷氧基, (9) 鹵(CVC6)烷氧基, (10) 鹵(CVCe)烧硫基, (11) 鹵(Ci-Cg)燒基亞石黃酿基, (12) 鹵(Ci-C6)烧基石黃醯基, (13) 鹵(Ci-Q)烧氧基鹵(CVC6)烧氧基, • (14)羧基, (15XCVC6)烷氧基羰基, (16) 胺基羰基, (17) 具有自(C1:C6)烷基、(C2-C6)烯基及(C2-C6)炔基 中選擇1至2個取代基之胺基羰基(惟,具有複 數個取代基時,該取代基可為相同或不同), (18) 苯基, (19) 具有自鹵素原子、硝基、氰基、(Cl-C6)烷基、 i (C1 _C6)烧基、(Ci-Cg)烧氧基、鹵(Ci-Cg)燒氣 59 318305 200800021 —— 基、瓜 至5個取代基之苯基(惟,具有複數個取代基 時’該取代基可為相同或不同), (20) 苯基(Cr_C3)烧基, (21) 於環上具有自鹵素原子、硝基、氰基、(Ci_c6) 烧基、鹵(CVC6)烷基、(CVC6)烷氧基、鹵(cvc6) 统氧基、(CVC6)烷硫基及鹵(CVC6)烷硫基中選 擇1至5個取代基之經取代苯基(Ci-C3)烷基 (惟,具有複數個取代基時,該取代基可為相同 或不同), (22) 苯基氧基,或 (23) 具有自鹵素原子、硝基、氰基、(Ci_C6)烷基、 鹵(CkC6)烷基、(Cl-C6)烷氧基、鹵(Cl-C6)烷氧 基、(CfC6)烧硫基及鹵院硫基中選擇1 至5個取代基之經取代苯基氧基(惟,具有複數 個取代基時,該取代基可為相同或不同),η示 1至4之整數} 〇 2·如申請專利範圍第1項之有害生物防除劑,其中,11示 氫原子、(Crc12)烧基、(C2-C6&gt;烯基、(C2-C6)炔基、(Ci 烷基羰基、(Cl-C6)烷氧基羰基、或(Cr-C6)烷氧基(κ3) 烷基羰基,-Z-R1表示-NH-CHrRi,或式中, 1 R表示吡啶基或吡啶-N-氧化物基), X表示溴原子、碘原子、鹵(c「c8)烷基、(cvq) 烷氧基、鹵(CVC6)烷氧基、鹵(cvc6)烷硫基、鹵(CVC6) 318305 60 200800021 烧氧基鹵(c「C6)燒氧基τ或TCi^ 1至2之整數。 .3·如申請專利範圍第〗項之有害生物防除劑,其中,r表 不(Cl-C6)烷基羰基,-Z-R1表示NH-CHyR1(式中,Ri 表示吼啶基),X示齒(CVC6)烷基,n各別表示為】。 /·如申請專利範圍第丨項之有害生物防除劑,其中,該經 取代之胺基喹唑啉酮化合物或其鹽類係^乙醯基_3,4_ 二氫-3-[(3·-比啶甲基)胺基]_6-[1,2,2,2-四氟_1-(三氟甲 _ 基)乙基]-2(1 Η)-喧唾淋酮或其鹽類。 5·如申請專利範圍第1項之有害生物防除劑,其中,具有 殺蟲活性、殺蟎活性或殺線蟲活性之化合物係乙醯膽鹼 酯酶阻礙劑、乙醯膽鹼受體阻礙劑、GABA調控氯化物 通道促效劑、鈉通道調控劑、尼古丁性乙醯膽鹼受體促 效劑、乙醯膽驗受體促效劑、氯化物通道活化劑、保幼 激素模擬物、氧化性磷酸化阻礙劑及Ατρ形成阻礙劑、 _ 氫離子梯度擾亂所致氧化性磷酸化之解偶聯劑,對於同 翅目之幾丁生合成阻礙劑(I型)、蜆皮素促效劑/脫皮阻 礙劑、章魚涎胺促效劑、位置I電子像遞系阻礙(METI 劑)、位置II電子傳遞系阻礙劑、脂質生合成阻礙劑、 蘭尼疋文體調控劑或具有非特異性作用機制(例如選擇 性攝食阻礙)之化合物。 6·如申请專利範圍第1項之有害生物防除劑,其中,具有 救触活性、殺瞒活性或殺線蟲活性之化合物係METI劑 系殺蟲劑、殺螨劑、噻二畊IGR系殺蟲劑、擬除蟲菊酯 318305 61 200800021 一東一系&gt;殺蟲劑v鈉通道身阻系殺蟲劑、胺基卞酸系氣蟲劑、 有機鱗糸殺蟲劑、具有躬通道活化作用之殺蟲劑、苯曱 醯基苯脲系殺蟲劑、二醯基肼系殺蟲劑。 7·如申請專利範圍第1項之有害生物防除劑,其中,具有 殺蟲活性、殺蟎活性或殺線蟲活性之化合物係亞滅培 (acetamiprid)、益達胺(imidacloprid)、吡蟲胺 (nitenpyram)、赛速安(thiamethoxam)、可尼丁 (clothianidin)、狄諾呋喃(dinotefuran)、提銨 Φ (thiacloprid)、氟唆蟲醢胺(Flonicamid)、卡巴利 (carbaryl)、免扶克(BPMC ; fenobucarb)、滅必兹(MIPC ; isoprocarb)、愛芬克(ethiofencarb)、比加克(pirimicarb)、 歐殺滅(oxanyl)、免扶克(benfuracarb)、滅賜克 (methiocarb)、滅虫牙鱗(11^〇&amp;1^&amp;111)、硫敵克(1;1^〇(1^&amp;1*1))、 得滅克(aldicarb)、棉铃威(alanycarb)、必芬治 (metolcarb)、黃利克(xylycarb)、安丹(propoxur)、卡波 馨 吱喃(carbofuran)、丁基加保扶(carbosulfan)、吱線威 (furathiocarb)、安殺番011(1〇511]^11)、涕滅威 . - --(aldoxycarb)、納乃得(methomyl)、氯氟氰菊酯 (cyhalothrine)、百滅寧(permethrin)、賽滅寧 (cypermethrin)、畢芬寧〈1&gt;1€611也1:丨11)、合芬寧 (halfenprox)、石夕護芬(silafluofen)、賽扶寧(〇&gt;^1111:111^11)、 貝他賽扶寧(beta-cyfluthrin)、泰滅寧(tralomethrin)、除 蟲菊素(pyrethrin)、右旋烯丙菊酯(&amp;以1;111^11)、阿納寧 (acrinathrin)、普列亞寧(prallethrin)、異列滅寧 62 318305 200800021 」 Cesmethrin)、七1齋酯 OefluthrL·)「芬鲁豕―—— (fenpropathrin)、亞滅寧(alpha-cypermethrin)、賽洛寧 (lambda-cyhalothrin)、第滅寧(deltamethrin)、芬化利 (fenva-lerate)、艾芬利(esfenvalerate)、護赛寧 , (flucythrinate)、福化利(fluvalinate)、乙氰菊酯 (cycloprothrin)、醚菊酯(ethofenprox)、阿維菌素 (avermectin)、密滅汀(milbemectin)、因滅汀 (emamectin)、賜諾殺(spinosad)、撲滅松(fenitrothion)、 Ο 馬拉松(malathion)、滅大松(methidathion)、芬殺松 (fenthion)、大利松(diazinon)、異亞颯碗(oxydeprofos)、 凡米松(vamidothion)、亞特松(pirimiphos-methyl)、陶斯 松(chlorpyriphos)、托福松(terbufos)、普伏松 (ethoprophos)、雙特松(cadusafos)、芬滅松 (fenamiphos)、凡福松(fensulfothion)、DSP、除線鱗 (dichlofenthion)、福賽絕(fosthiazate)、依賽米多扶 馨 (isamidofos)、丁 硫環填(fosthietan)、依殺松(isazofos)、 谷速松(azinphos-methyl)、二硫扶(disulfotion)、乙醯甲 填胺(oxydemeton-metliyl)、巴拉松(parathions)、特布皮 利扶(tebupirimfos)、艾殺松(ethion)、三氯松 (trichlorfon)、甲胺磷:(metamidophos)、二氯松 (dichlorvos)、美文松(mevinphos)、亞素靈 (monocrotophos)、大滅松(dimethoate)、覆滅 (formetanate)、扶木松(formothion)、乃力松(naled)、甲 基巴拉松(methylparathion)、殺模腈(cyanophos)、二米 63 318305 200800021 ------- _ -^ 广-.1—» — · · -· ' γ%----- v*-----— ______ , ------——-- - -—- - --------- ——1-- 」 ..... .............. . 達松(diamidafos)、加護松(propaphos)、曱丙硫鱗 (sulprofos)、普硫松(prothiofos)、佈飛松(profenofos)、 亞芬松(isofenphos)、亞培松(temephos)、賽達松 (phenthoate)、三唾硫構(dimethylvinphos)、氯芬硫構 (chlorfevinphos)、樂本松(tetrachlorvinphos)、肟石泉構 (phoxim)、力口褐松(isoxathion)、白克松(pyraclofos)、陶 斯松(chlorpyrifos-methyl)、必芬松(pyridafenthion)、飛 賽隆(phasalone)、飛斯美(phasmet)、殺力松 Ο (dioxabenzofos)、拜裕松(quinalphos)、甲硫松 (mesulfenfos)、歐殺松(acephate)、培丹(cartap)、硫賜 安(thiocyclam)、免速達(bensultap)、硫速達 (thiosultap)、芬普瞒(fenpyroximate)、畢達本 (pyridaben)、口比蜗胺(tebufenpyrad)、吐蟲蜗胺 (tolfenpyrad)、芬殺(fenazaquin)、畢汰芬(pyrimidifen)、 魚藤精(rotenone)、愛美隆(hydramethylnon)、亞酉昆 (acequinocyl)、口密瞒 |旨(fluacrypyrim)、氟咬胺 (fluazinam)、氟苯二隨胺(flubendiamide)、氟蟲清 (fipronil)、乙醯普(acetoprole)、乙蟲清(ethipiole)、歐 . - · ·* 蜗多(propargite)、因得克(indoxacarb)、美他就米隆 (metaflumizone)、滅蟎猛(quinomethionate)、汰芬諾克 (diafenthiuron)、赛海克汀(cyhextin)氫氧化物、芬佈賜 (fenbutatin oxide)、三亞蟎(amitraz)、螺蟎酯 (spirodiclofen)、季酮甲蜗酉旨(spiromesifen)、螺四蟎醋 (spirotetramat)、溴蟲腈(chlorfenapyr)、百蟎克 64 318305 200800021 • — (binapacryl)、克氣笨(chldrbenzilate)、驗咸殺 (phenisobromolate)、TPIC、於驗硫酸鹽 (nicotine-sulfate)、_ 陽黴素(polynactins)複合物、印楝 素(azadirachtin)、經丙基澱粉(hydroxypropyl starch)、 摩朗得(morantel)酒石酸鹽、油酸鈉鹽、油酸_、啶蟲 丙醚(pyridalyl)、替扶苯隆(teflubenzuron)、克福隆 (chlorfluazuron)、二氟苯隆(diflubenzuron)、六伏隆 (hexaflumuron)、敵草胺(novaluron)、祿芬隆 O (lufenuron)、氟蟲脲隆(fluenoxuron)、得芬諾 (tebufenozide)、甲氧芬諾(methoxyfenozide)、克馬芬諾 (chromafenozide)、鹵芬諾(halofenozide)、二芬隆 (diofenolan)、布芬淨(buprofezin)、丙胺哄(cyromazine)、 婦蟲醋(methoprene)、稀蟲乙酯(hydroprene)、百利普芬 (pyriproxyfen)、芬諾克(fenoxycarb)、派滅淨 (pymetrozine)、克芬淨(ciofentezine)、合賽多 - * · · . (hexythiazox)、芬硫克(fenothiocarb)、依殺蟎 (etoxazole)、聯苯菊醋(bifenazate)、大克蟎(kelthane ; dicofol)、西脫蜗(benzoximate)、得脫蜗(tetradifon)、邁 隆(dazomet)、鱗克敵(phosphocarb)、左咪嗤鹽酸鹽 (levamisol HC1) ' 阿苯達唑(aibendazole)、奥苯達唑 (oxibendazole)、芬苯達嗤(fenbendazole)、奥芬達嗤 (oxfendazole)、威百 ^(metam-sodium)、峻財威 (triazamate)或蘇力菌(Bacillus thuringiensis ; BT)。 8·如申請專利範圍第1項之有害生物防除劑,其中,具有 65 318305 200800021 L -氣蟲活性' 殺蜗活性或敲線蟲活性之化合物-係棼普蟎 (fenpyroximate)、免扶克(fenobucarb ; BPMC)、滅必蟲 (isoProcarb,MIPC)、σ比蜗胺(tebufenpyrad)、唾蟲蜗胺 (tolfenpyrad)、布芬淨(bUpr〇fezin)、美他氟米隆 (metaflumizone)、得芬諾(tebufenozide)、溴蟲腈 (chlorfenapyr)、福化利(fiuvalinate)、替扶苯隆 (teflubenzuron)或氟笨二醯胺(fiubendiamide)。 9·如申請專利範圍第1項至第8項中任一項之有害生物防 一 除劑,其中,經取代之胺基喹唑啉酮化合物係1 -乙醯基 -3,4-二氫-3-[(3_吡啶甲基)胺基]-6·[1,2,2,2-四氟-1·(三 氟甲基)乙基&gt;2(1 Η)·喹唑啉酮,而具有殺蟲活性、殺螨 活性或殺線蟲活性之化合物係布芬淨(buprofezin)、美他 敗米隆(metaflumizone)或氟苯二醯胺(fiubendiamide)。 10·如申請專利範圍第1項至第9項中任一項之有害生物防 除劑,其中,相對於1重量份之經取代之胺基喹唑啉酮 ^ 化合物,自具有殺蟲活性、殺蟎活性或殺線蟲活性之化 合物中選擇1種或2種以上之化合物之調配比例係0.01 至2000重量份。 Π·—種有害生物防除劑之使用方法,其特徵為自有害生物 保護有用植物,以申請專利範圍第1項至第10項中任 一項之有害生物防除劑之有效量處理對象有害生物、對 象有用植物、對象有用植物之種子、土壤或栽培介質。 12·—種有害生物之防除方法,其特徵為防除有害生物,將 申請專利範圍第1項之一般式(I)所示經取代之胺基喹 66 318305 200800021 m &quot; 唾啉酮化合物及其鹽窺冲選擇1種以上之化合物,―以及 自具有殺蟲活性、殺蟎活性或殺線蟲活性之化合物中選 ”擇1種或2種以上之化合物,作為有效成分之有害生物 防除劑’以有效成分量計,每一公畝處理〇. 1至^ 。 13. —種化合物之用途,該化合物係自申請專利範圍第J項 之一般式(I)所示經取代之胺基喹唑啉酮化合物及其鹽 類中選擇1種以上之化合物,其特徵為用於製造含有自 如申明專利範圍弟1項之一般式(I)所示經取代之胺基 一 喹唑啉厕化合物及其鹽類中選擇1種以上之化合物,以 及自具有殺蟲活性、殺蟎活性或殺線蟲活性之化合物中 選擇1種或2種以上之化合物之有害生物防除劑。Wherein R is: (1) a hydrogen atom, (2) a decyl group, (3) a (CVC12) alkyl group, (4) a halogen (CKC6) alkyl group, (5) a (C2-C6) alkenyl group, (6) (CVC6) alkynyl, (7) (CkD sulphur-based, (8) halogen ((VG) sulphur-based, (9) (C-C6) sulphur-based, (i〇) (c3-c6) ring Alkylcarbonyl, | (iiXCkCo alkoxycarbonyl, 318305 57 200800021 (14) Phenyl group, (15) having a halogen atom, a nitro group, a cyano group, a (CVC6) alkyl group, a halogen group (C^C^ a phenylcarbonyl group having 1 to 5 substituents selected from the group consisting of an alkyl group, a (CrQ) alkoxy group, a halogen (CVC6) alkoxy group, a (C!-C6) thiol group, and a halogen (Ci-C6) thiol group. (However, when a plurality of substituents have a plurality of substituents, the substituents may be the same or different), (16) a phenyl (C2-C6) alkenyl group, 10 (17) having a halogen atom, a nitro group, and a cyano group on the ring. , (CVC6) alkyl, halo ((VC6) alkyl, (cKc6) alkoxy, halogen (Cl_c6) alkoxy, (Ci-C6) sulphur-based, halogen (cvc6) sulphur-based and (CkC2) a phenyl (CVC6) alkenyl group having 1 to 5 substituents selected from alkylenedioxy groups (only, when having a plurality of substituents, the substituents may be the same or different), (18) Phenyl (C2-C6) alkynyl, or #U9) having a halogen atom, a nitro group, a cyano group, a (CVC6) group, a halogen (CVC6) group, (Ci-C^) on the ring. Selective 1 to 5 substituents for activating oxygen, pain (CrC^) alkoxy, (Cj-C6) thiol, halogen (CrQ) thio, and (CrC: 2) alkyl dioxy Phenyl (C2_C4) alkynyl (except when a plurality of substituents may be the same or different), R1 represents pyridyl or pyridine-N-oxide, z i_N=c(R2)_ Wherein R 2 represents a hydrogen atom, (CVC: 6) alkyl or halo (Ci_C6) alkyl) or 3) rhyme (in the formula, r 2 * hydrogen atom, (Ci_C6) dazzle 318305 58 200800021 ... Or halogen (C7-C6) alkyl-, 妒 indicates hydrogen wide-hand- or (Ci-Cj 炫基^不· - (1) bromine atom, (2) moth atom, (3) thiophene, (4) ( Ci_C6) thiol, (5) (C2-C6) alkenyl, (6) (C2-C6) alkynyl, 10 (7) halo (Ci-Cg) alkyl, (8) (CVC6) alkoxy, (9) Halogen (CVC6) alkoxy, (10) Halogen (CVCe) sulphur, (11) Halogen (Ci-Cg) sulphate, (12) Halogen (Ci-C6) sill Astragalus, (13) Halogen (Ci-Q) alkoxy halide (CVC 6) alkoxy, • (14) carboxyl, (15XCVC6) alkoxycarbonyl, (16) aminocarbonyl, (17) having (C1:C6)alkyl, (C2-C6)alkenyl and (C2) -C6) an aminocarbonyl group having 1 to 2 substituents selected from alkynyl groups (except that when a plurality of substituents are present, the substituents may be the same or different), (18) phenyl group, (19) having a halogen atom , nitro, cyano, (Cl-C6) alkyl, i (C1 _C6) alkyl, (Ci-Cg) alkoxy, halogen (Ci-Cg) gas 59 318305 200800021 - base, melon to 5 a phenyl group of a substituent (only, when having a plurality of substituents, the substituent may be the same or different), (20) a phenyl (Cr-C3) group, (21) having a halogen atom and a nitro group on the ring , cyano, (Ci_c6) alkyl, halogen (CVC6) alkyl, (CVC6) alkoxy, halogen (cvc6) oxy, (CVC6) alkylthio and halogen (CVC6) alkylthio selected from 1 to a substituted phenyl (Ci-C3) alkyl group of 5 substituents (except that, when having a plurality of substituents, the substituents may be the same or different), (22) phenyloxy, or (23) Halogen atom, nitro group, cyano group, (Ci_C6) alkyl group, a substituted phenyl group having 1 to 5 substituents selected from the group consisting of a halogen (CkC6) alkyl group, a (Cl-C6) alkoxy group, a halogen (Cl-C6) alkoxy group, a (CfC6) thiol group, and a halogen group. An oxy group (except that when a plurality of substituents are present, the substituents may be the same or different), and η is an integer of 1 to 4} 〇2. The pest control agent according to claim 1 of the patent application, wherein Hydrogen atom, (Crc12) alkyl group, (C2-C6&gt; alkenyl group, (C2-C6) alkynyl group, (Ci alkylcarbonyl group, (Cl-C6) alkoxycarbonyl group, or (Cr-C6) alkoxy group (κ3) an alkylcarbonyl group, -Z-R1 represents -NH-CHrRi, or wherein 1 R represents a pyridyl group or a pyridine-N-oxide group, and X represents a bromine atom, an iodine atom, or a halogen (c"c8) Alkyl, (cvq) alkoxy, halogen (CVC6) alkoxy, halogen (cvc6) alkylthio, halogen (CVC6) 318305 60 200800021 alkoxy halide (c "C6" alkoxy tau or TCi ^ 1 An integer of up to 2. .3. The pest control agent according to the scope of the patent application, wherein r represents a (Cl-C6) alkylcarbonyl group, and -Z-R1 represents NH-CHyR1 (wherein Ri represents an acridinyl group), X Shows the tooth (CVC6) alkyl, and n is denoted as 】. / / As claimed in the scope of the patent scope of the pest control agent, wherein the substituted amino quinazolinone compound or its salt is ethoxylated _3,4_ dihydro-3-[(3· -bipyridylmethyl)amino]_6-[1,2,2,2-tetrafluoro_1-(trifluoromethyl)ethyl]-2(1 Η)-quinone or its salts . 5. The pest control agent according to claim 1, wherein the compound having insecticidal activity, acaricidal activity or nematicidal activity is an acetylcholinesterase inhibitor, an acetylcholine receptor inhibitor, GABA regulates chloride channel agonist, sodium channel modulator, nicotine acetylcholine receptor agonist, acetylcholine receptor agonist, chloride channel activator, juvenile hormone mimic, oxidative Phosphorylation inhibitor and Ατρ formation inhibitor, _ oxidative phosphorylation uncoupling agent caused by hydrogen ion gradient disturbance, for Hidadin synthesis inhibitor (type I), quercetin agonist / Peeling inhibitor, octopine amine agonist, position I electron image delivery inhibitor (METI agent), position II electron transport system inhibitor, lipid biosynthesis inhibitor, ryanoprohness regulator or non-specific mechanism of action Compounds such as selective food intake barriers. 6. The pest control agent according to item 1 of the patent application, wherein the compound having the tactile activity, the acaricidal activity or the nematicidal activity is a METI agent, an insecticide, an acaricide, a thiazolidine IGR insecticide. Agent, pyrethroid 318305 61 200800021 一东一系&gt;Insecticide v sodium channel body block insecticide, amine phthalic acid insecticide, organic squamous insecticide, with sputum channel activation Insecticide, phenylmercaptophenone-based insecticide, diterpene-based insecticide. 7. The pest control agent according to claim 1, wherein the compound having insecticidal activity, acaricidal activity or nematicidal activity is acetamiprid, imidacloprid, imidacloprid (imidacloprid) Nitenpyram), thiamethoxam, clothianidin, dinotefuran, thiacloprid, Flonicamid, carbaryl, defec BPMC; fenobucarb), imipenem (MIPC; isoprocarb), ethiofencarb, pirimicarb, oxanyl, benfuracarb, metimocarb, extinction Insect scale (11^〇&1^&111), sulfur enemy (1;1^〇(1^&amp;1*1)), aldicarb, alanycarb, bifen (metolcarb), xylycarb, propoxur, carbofuran, carbosulfan, furathiocarb, amphibious 011 (1〇511) ]^11), aldicarb. - --(aldoxycarb), methomyl, cyhalothrine, perphenazine (permet) Hrin), cypermethrin, bifennin <1>1€611 also 1: 丨11), halfenprox, silafluofen, 赛福宁(〇&gt;^1111:111 ^11), beta-cyfluthrin, tralmethrin, pyrethrin, dextromethrin (&1; 111^11), analin ( Acrinathrin), prallethrin, isofenin 62 318305 200800021 ” Cesmethrin), acetylene OefluthrL·) fenpropathrin, alpha-cypermethrin, race Lamma-cyhalothrin, deltamethrin, fenva-lerate, esfenvalerate, flucythrinate, fluvalinate, fenpropathrin (cycloprothrin), ethofenprox, avermectin, milbemectin, emamectin, spinosad, fenitrothion, marathon (malathion) ), methidathion, fenthion, diazinon, bismuth bowl (ox Ydeprofos), vamidothion, pirimiphos-methyl, chlorpyriphos, terbufos, ethoprophos, cadusafos, fenamiphos, Fensulfothion, DSP, dichlofenthion, fosthiazate, isamidofos, fosthietan, isazofos, valsone (azinphos-methyl), disulfotion, oxydemeton-metliyl, parathions, tebupirimfos, ethion, triclosan (trichlorfon), methamidophos: (metamidophos), dichlorvos, mevinphos, monocrotophos, dimethoate, formetanate, formothion , naled, methylparathion, cyanophos, two meters 63 318305 200800021 ------- _ -^ 广-.1—» — · · -· ' γ%----- v*------ ______ , ------——-- - --- -- --------- —1-- ” ... .............. . diamidafos, propaphos, sulprofos, prothiofos ), profenofos, isofenphos, temephos, phenthoate, dimethylvinphos, chlorfevinphos, tetrachlorvinphos ), phoxim, isoxathion, pyraclofos, chlorpyrifos-methyl, pyridafenthion, phasalone, phasmet, Dioxabenzofos, quinalphos, mesulfenfos, acephate, cartap, thiocyclam, bensultap, sulphur (thiosultap), fenpyroximate, pyridaben, tebufenpyrad, tolfenpyrad, fenazaquin, pyrimidifen, vine (rotenone), hydramethylnon, acequinocyl, 瞒 瞒 旨 | ), fluazinam, flubendiamide, fipronil, acetoprole, ethipiole, eur. - · · * propargite , indoxacarb, meta-miflumizone, quinomethionate, diafenthiuron, cyhextin hydroxide, fenbutatin oxide , amitraz, spirodiclofen, spiromesifen, spirotetramat, chlorfenapyr, baifenke 64 318305 200800021 • — (binapacryl) , chldrbenzilate, phenisobromolate, TPIC, nicotine-sulfate, _ yangmycin (polynactins) complex, azadirachtin, propylpropyl Starch), morantel tartrate, sodium oleate, oleic acid _, pyridalyl, teflubenzuron, chlorfluazuron, diflubenzuron ), hexaflumuron, diquat (novaluron), lufenuron, fluenoxuron, tebufenozide, methoxyfenozide, chromafenozide, halofenozide, two Diofenolan, buprofezin, cyromazine, metoprene, hydroprene, pyriproxyfen, fenoxycarb, pie Pymetrozine, ciofentezine, 赛赛多- * · · (hexythiazox), fenothiocarb, etoxazole, bifenazate, big gram (kelthane; dicofol), benzoximate, tetradifon, dazomet, phosphocarb, levamisol hydrochloride (levamisol HC1) 'abendazole (aibendazole) ), oxibendazole, fenbendazole, oxfendazole, metam-sodium, triazamate or Bacillus thuringiensis; BT ). 8. The pest control agent according to claim 1 of the patent scope, wherein the compound having 65 318305 200800021 L - aerobic activity 'coccidicidal activity or nematode activity - is fenpyroximate, fenobucarb ; BPMC), isopropcarb (MIPC), σ than tebufenpyrad, tolfenpyrad, bupr〇fezin, metaflumizone, defenofol (tebufenozide), chlorfenapyr, fiuvalinate, teflubenzuron or fiubendiamide. The pest control agent according to any one of claims 1 to 8, wherein the substituted amino quinazolinone compound is 1-ethenyl-3,4-dihydrogen -3-[(3_pyridylmethyl)amino]-6·[1,2,2,2-tetrafluoro-1·(trifluoromethyl)ethyl&gt;2(1 Η)·quinazoline Ketones, and compounds having insecticidal activity, acaricidal activity or nematicidal activity are buprofezin, metaflumizone or fiubendiamide. The pest control agent according to any one of claims 1 to 9, wherein the compound has an insecticidal activity and kills relative to 1 part by weight of the substituted aminoquinazolinone compound. The compounding ratio of one or two or more compounds selected from the group consisting of hydrazine active or nematicidal activity is 0.01 to 2000 parts by weight. A method for using a pest control agent, which is characterized in that a pest is protected by a pest, and an effective amount of a pest control agent according to any one of claims 1 to 10 is applied to treat a pest The object is a useful plant, a seed of a useful plant, a soil or a cultivation medium. 12. A pest control method characterized by controlling pests, and the substituted amino quinone 66 318305 200800021 m &quot; sinolinone compound represented by the general formula (I) of claim 1 Selecting one or more compounds from salt scouring, and selecting one or more compounds from compounds having insecticidal activity, acaricidal activity or nematicidal activity as a pest control agent as an active ingredient The effective ingredient amount is measured per 10,000. The use of the compound is the substituted amino quinazoline represented by the general formula (I) in the Jth article of the patent application. One or more compounds selected from the group consisting of a ketone compound and a salt thereof, and are characterized in that it is used for producing a substituted amino-quinazoline toilet compound of the general formula (I) and a salt thereof, which are free from the patent claim 1 One or more compounds selected from the class, and a pest control agent which selects one or more compounds from compounds having insecticidal activity, acaricidal activity or nematicidal activity. 318305 67 200800021 4、指定代表圖:本案無圖式 (一) 本案指定代表圖為:第()圖。 (二) 本代表圖之元件符號簡單說明·· 八、本案若有化學式時,請揭示最能顯示發明特徵的化學式:318305 67 200800021 4. Designated representative map: There is no schema in this case (1) The representative representative map of this case is: (). (2) A brief description of the symbol of the representative figure. · 8. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: RR 4 318305 2008000214 318305 200800021 第95121359號專利申請案 申請專利範圍修正本Patent Application No. 95121359 (95年11月14曰)2 1 · 一種有害生物防除劑,其特徵為含有自下列一般式所示 經取代之胺基喹唑啉酮化合物及其鹽類中選擇1種以上 之化合物,以及自具有殺蟲活性、殺瞒活性或殺線蟲活 性之化合物中選擇1種或2種以上之化合物,作為有效(November 14, 1995) 2 1 · A pest control agent characterized by containing one or more compounds selected from the group consisting of substituted amino quinazolinone compounds and salts thereof as shown in the following general formula, and Selecting one or more compounds from compounds having insecticidal activity, acaricidal activity or nematicidal activity as effective 成分, 一般式[I] {式中,R示: (1)氫原子, • (2)曱醯基, (3) (C〗-C12)烷基, (4) 鹵(CVQ)烷基, (5) (C2-C6)烯基, (6) (C2-C6)炔基, (7) (€νί:6)烷硫基, (8) 鹵(CVC6)烷硫基 (9) (CVC6)烷基羰基, (10) (C3-C6)環烷基羰基, 318305劃線本 200800021 (11) (c]-c6)l;氧基羰基-,——一 (12) (cvc6)烧氧基 m 基(c]-c3)烧基, (13) (Ci-c6)燒氧基(c】-c3)烧基羰基, (14) 苯基幾基, (15) 具有自鹵素原子、硝基、氰基、(CVC6)烷基、 函(CA)院基、(Cl_c6)烧氧基、鹵(Ci_c6)烧氧 基、(C]-C6)烷硫基及_(Ci_C6)烷硫基中選擇J • 至2個取代基之苯基羰基(惟,具有複數個取代 基時,該取代基可為相同或不同), (16) 苯基(c2-c6)烯基, (17) 於環上具有自鹵素原子、硝基、氰基、(C^C6) 烧基、函(CVC6)烧基、(Cl-C6)燒氧基、齒(Ci-C6) 烷氧基、(cvc:6)烷硫基、鹵(c^-c^)烷硫基及 (Ci-C:2)伸烷基二氧基中選擇1至5個取代基之 苯基(CVC:6)浠基(惟,具有複數個取代基時,該 取代基可為相同或不同), (18) 本基(C2-C6)快基,或 (19) 於環上具有自鹵素原子、硝基、氰基、(〔I_c6) 烧基、鹵(CfCg)烷基、(CnC6)烷氧基、鹵(c^cd 烧氧基、(CkC6)烧硫基、鹵(Ci-Q)烧硫基及 (CKC2)伸烷基二氧基中選擇1至5個取代基之 苯基(C2_C4)炔基(惟,具有複數個取代基時,該 取代基可為相同或不同), R〗示吡啶基或吡啶氧化物基、z示-N=C(R2)- 2 318305劃線本 200800021 基或函(c]-c6)烷基’ R3示氫原子或(Ci_C6)烷基,χ 不· t 5 R2 7F A4 ^ 7 (crc6)^^ i (C\-C6m^) 或示N岭CH(RV(式中,r2示氫原子、(Ci_C6)烧 (1) 溴原子, (2) 碘原子, (3) 羥基,Ingredients, General formula [I] {wherein, R is: (1) a hydrogen atom, (2) a fluorenyl group, (3) a (C)-C12) alkyl group, (4) a halogen (CVQ) alkyl group, (5) (C2-C6) alkenyl, (6) (C2-C6) alkynyl, (7) (€νί: 6) alkylthio, (8) halogen (CVC6) alkylthio (9) (CVC6 Alkylcarbonyl, (10) (C3-C6)cycloalkylcarbonyl, 318305 underline 200800021 (11) (c)-c6)l; oxycarbonyl-,--(12) (cvc6) oxygenated Base m group (c]-c3) alkyl group, (13) (Ci-c6) alkoxy group (c)-c3) alkylcarbonyl group, (14) phenyl group, (15) having a halogen atom, a nitrate , cyano, (CVC6) alkyl, functional (CA), (Cl_c6) alkoxy, halogen (Ci_c6) alkoxy, (C]-C6) alkylthio and _(Ci_C6) alkylthio The phenylcarbonyl group of J to 2 substituents is selected (only, when a plurality of substituents are present, the substituents may be the same or different), (16) phenyl (c2-c6) alkenyl group, (17) The ring has a halogen atom, a nitro group, a cyano group, a (C^C6) alkyl group, a (CVC6) alkyl group, a (Cl-C6) alkoxy group, a tooth (Ci-C6) alkoxy group, (cvc: 6) alkylthio, halo(c^-c^)alkylthio and (Ci-C: 2) a phenyl (CVC: 6) fluorenyl group having 1 to 5 substituents selected from the group consisting of alkyl dioxy groups (only, when having a plurality of substituents, the substituents may be the same or different), (18) the group (C2) -C6) a fast group, or (19) having a halogen atom, a nitro group, a cyano group, ([I_c6) alkyl group, a halogen (CfCg) alkyl group, a (CnC6) alkoxy group, a halogen (c^cd) a phenyl (C2_C4) alkynyl group having 1 to 5 substituents selected from the group consisting of an alkoxy group, a (CkC6) thiol group, a halogen (Ci-Q) thiol group and a (CKC2) alkylenedioxy group (only, When a plurality of substituents are used, the substituents may be the same or different), R is a pyridyl or pyridyl oxide group, and z is -N=C(R2)-2 318305 underline 200800021 base or letter (c)- C6)alkyl 'R3 represents a hydrogen atom or (Ci_C6)alkyl group, χ not · t 5 R2 7F A4 ^ 7 (crc6)^^ i (C\-C6m^) or N-CH (RV (in the formula, R2 represents a hydrogen atom, (Ci_C6) burns (1) a bromine atom, (2) an iodine atom, (3) a hydroxyl group, (4) (CVC6)烷基, (5) (C2-C6)烯基, (6) (C2_C6)炔基, ⑺鹵(CVCs)烧基, (8) (C!-C6)烧氧基, (9) 鹵(Ci_C6)烧氧基, (10) 鹵(CkQ)烷硫基, (11) 鹵(C^Q)烷基亞磺醯基, (12) 自(Ci-CJ烧基續酿基, (13) 鹵(C「C6)烧氧基!|(Ci_C6)烧氧基, (14) 羧基, (15) (CVC6)院氧基羰基, (16) 胺基幾基, (17) 具有自(C】-C6)烧基、(C2-C6)稀基及(C2-C6)炔基 中選擇1至2個取代基之胺基羰基(推,具有複 數個取代基時,該取代基可為相同或不同), (18) 苯基, 3 318305劃線本 200800021 (19) 具有自ί素原子7頌基、—氰基、(cvc6)垸基、 _(CkC6)烧基、(CVC6)烧氧基、鹵(CVC6)院氧 基、(CrC6)烧硫基及鹵(c〗-C6)烧硫基中選擇1 至5個取代基之苯基(惟,具有複數個取代基 時,該取代基可為相同或不同), (20) 苯基(CKC3)烧基, (21) 於環上具有自鹵素原子、硝,基、氰基、(Cj-Ce) 烧基鹵(Ci_C6)院基、(c〗-C6)烧氧基、鹵 烷氧基、(CVC6)烷硫基及鹵(Cl_C6)烷硫基中選 擇1至5個取代基之經取代苯基(C^C3)烷基 (惟,具有複數個取代基時,該取代基可為相同 或不同), (22) 本基氧基,或 (23) 具有自鹵素原子、石肖基、氮基、(CA)燒基、 鹵(Cl-C6)烷基、(CI_C6)烷氧基、鹵(CVC6)烷氧 基、(C「C6)院硫基&amp;_(Ci_C6)烧硫基中選擇i 至5個取代基之經取代苯基氧基(惟,具有複數 個取代基時,該取代基可為相同或不同),^示 1至4之整數}。(4) (CVC6) alkyl, (5) (C2-C6) alkenyl, (6) (C2_C6) alkynyl, (7) halogen (CVCs) alkyl, (8) (C!-C6) alkoxy, (9) Halogen (Ci_C6) alkoxy, (10) halogen (CkQ) alkylthio, (11) halogen (C^Q) alkylsulfinyl, (12) from (Ci-CJ) Base, (13) halogen (C "C6" alkoxy!|(Ci_C6) alkoxy, (14) carboxyl, (15) (CVC6) alkoxycarbonyl, (16) amino group, (17) An aminocarbonyl group having 1 to 2 substituents selected from (C)-C6)alkyl, (C2-C6), and (C2-C6)alkynyl groups (in the case of a plurality of substituents, the substitution) The base may be the same or different), (18) phenyl, 3 318305 underline 200800021 (19) having a 7-mercapto group, a cyano group, a (cvc6) fluorenyl group, a _(CkC6) alkyl group, CVC6) a phenyl group having 1 to 5 substituents selected from the group consisting of an alkoxy group, a halogen (CVC6) alkoxy group, a (CrC6) thiol group and a halogen (c)-C6) group (only, having a plurality of substituents) When the substituents may be the same or different, (20) phenyl (CKC3) alkyl, (21) having a halogen atom, a nitrate, a cyano group, a (Cj-Ce) alkyl halide on the ring ( Ci_C 6) a substituted phenyl group of 1 to 5 substituents selected from the group consisting of a base group, (c)-C6) an alkoxy group, a haloalkoxy group, a (CVC6) alkylthio group and a halogen (Cl_C6) alkylthio group (C^) C3) an alkyl group (except that when a plurality of substituents are present, the substituents may be the same or different), (22) a benzyloxy group, or (23) having a halogen atom, a schlossyl group, a nitrogen group, or a (CA) group. Selective i to 5 substituents for the group, the halogen (Cl-C6) alkyl group, the (CI_C6) alkoxy group, the halogen (CVC6) alkoxy group, the (C"C6) thiol &amp; _(Ci_C6) sulphur group Substituted phenyloxy (wherein, with a plurality of substituents, the substituents may be the same or different), an integer from 1 to 4}. ,基羰基、或(CVQ)统氧基(Ci_C3) NH-CHrR1,或式中, 烧基幾基、(cKC6)烷氧基羰基、或(Ci, carbonyl, or (CVQ) oxy (Ci_C3) NH-CHrR1, or, in the formula, alkyl, (cKC6) alkoxycarbonyl, or (Ci 3】W05劃線本 4 200800021 / ^ ^ ^ ^ ^^ ^ . iTcT-Ce)^^ . (Ci.C6) 烷氧基、鹵(Cl_C6)烧氧基、齒(CVC6)垸硫基、鹵(Ci_c6) 烧氧基鹵(C]_C6)烧氧基、或(C】-C6)烧氧基幾基,以示 1至2之整數。 3.如申明專利範圍第1項之有害生物防除劑,其中,r表 不(CVC6)烷基羰基,·z_Ri表示·nh-c^r汶式中,反】 表示錢基),X * 4 (Ci_C6)録,n各別表示為!。 春(如中請專利範圍第1項之有害生物防除劑,其中,該經 取代之胺基喧唾嘛酮化合物或其鹽類係i _乙酿基_ 3,心 二氫·3-[(3·啦咬甲基)胺基四氟]_(三氟甲 基)乙基]-2(1 H)-喧唾琳_或其鹽類。 5.如申請專利範圍第i項之有害:物防除劑,其中,呈有 殺蟲活性、殺瞒活性或殺線蟲活性之化合物係乙醯膦驗 醋酶阻礙劑、乙醯膽驗受體阻礙劑、G A B A調控氣化物 通道促效劑、料道難劑、尼古了性乙賴驗受體促 修效劑、乙醯膽驗受體促效劑、氯化物通道活化劑、保幼 ,素棋擬物、减性魏化阻礙劑及ATp形成阻礙劑、 氫#子梯度擾亂所致氧化性鱗酸化之解偶聯劑,對於同 翅目之幾丁生合成阻礙劑(1型)、銳皮素促效劑/脫皮阻 礙劑、章魚誕胺促效劑、位置j電子傳遞系阻礙⑽打 :1)、位置11電子傳遞系阻礙劑、脂質生合成阻礙劑、 闌尼定受體調控劑或具有非特異性作用機制(例如選擇 性攝食阻礙)之化合物。 6·如申凊專利範圍第i項之有害生物防除劑,其中,具有 318305劃線本 5 200800021 殺蟲活性、殺蟎活性或殺線蟲活性之化合物係meti劑 系殺蟲劑、殺蟎劑、嘆二哄IGR系殺蟲劑、擬除蟲菊酯 系殺蟲劑、鈉通道封阻系殺蟲劑、胺基甲酸系殺蟲劑、 有機磷系殺蟲劑、具有鈣通道活化作用之殺蟲劑、苯曱 醯基苯脲系殺蟲劑、二醯基肼系殺蟲劑。 7·如申請專利範圍第1項之有害生物防除劑,其中,具有 殺蟲活性、殺蟎活性或殺線蟲活性之化合物係亞滅培 (acetamiprid)、益達胺(imidacloprid)、吡蟲胺 (nitenpyram)、賽速安(thiamethoxam)、可尼丁 (clothianidin)、狄諾吱喃(dinotefuran)、提銨 (thiacloprid)、氟咬蟲醯胺([1〇111〇&amp;1111(1)、卡巴利 (carbaryl)、免扶克(BPMC ; fenobucarb)、滅必蟲(MIPC ; isoprocarb)、愛芬克(ethiofencarb)、比加克(pirimicarb)、 歐殺滅(oxanyl)、免扶克(benfuracarb)、滅賜克 (methiocarb)、滅財填(mecarbam)、硫敵克(thiodicarb)、 _ 得滅克(aldicarb)、棉鈐威(alanycarb)、必芬治 (metolcarb)、黃利克(xylycarb)、安丹(propoxur)、卡波 呋喃(carbofuran)、丁基加保扶(carbosulfan)、呋線威 (furathiocarb)、安殺番(endosulfan)、涕滅威 (aldoxycarb)、納乃得(methomyl)、氣氟氰菊酯 (cyhalothrine)、百滅寧(permethrin)、賽滅寧 (cypermethrin)、畢芬寧(bifenthrin)、合芬寧· (halfenprox)、石夕護芬(silafluofen)、赛扶寧(cyfluthrin)、 貝他賽扶寧(beta-cyfluthrin)、泰滅寧(tralomethrin)、除 6 318305劃線本 200800021 蟲菊素(pyrethrin)、右旋烯丙菊酯(aiiethrin)、阿納寧 (acrinathrin)、普列亞寧(praiiethrin)、異列滅寧 (esmethrin)、七氟菊酷(tefluthrin)、芬普寧 (fenpropathrin)、亞滅寧(&amp;1卩11&amp;_〇}^卩61&gt;11161:111^11)、賽洛寧 (lambda-cyhalothrin)、第滅寧(deltamethrin)、芬化利 (fenva_lerate)、艾芬利(esfenvalerate)、護赛寧 (fiucythrinate)、福化利(fluvaiinate)、乙氰菊酯 ^ (cycloprothrin)、醚菊酯(ethofenprox)、阿維菌素 (avermectin)、密滅汀(milbemectin)、因滅汀 (emamectin)、賜諾殺(spinosad)、撲滅松(fenitrothion)、 馬拉松(malathion)、滅大松(methidathion)、芬殺松 (fenthion)、大利松(diazinon)、異亞颯磷(oxydeprofos)、 凡米松(vamidothion)、亞特松&amp;^11^卩]1〇5-11^化}^1)、陶斯 松(chlorpyriphos)、托福松(terbufos)、普伏松 (ethoprophos)、雙特松(cadusafos)、芬滅松 ⑩ (fenamiphos)、凡福松(fensulfothion)、DSP、除線石粦 (dichlofenthion)、福賽絕(fosthiazate)、依賽米多扶 (isamidofos)、丁 硫環填(fosthietan)、依殺松(isazofos)、 谷速松(azinphos-methyl)、二硫扶(disulfotion)、乙酿曱 填胺(oxydemeton-methyl)、巴拉松(parathions)、特布皮 利扶(tebupirimfos)、艾殺松(ethion)、三氯松 (trichlorfon)、曱胺填(metamidophos)、二氯松 (dichlorvos)、美文松(mevinphos)、亞素靈 (monocrotophos)、大滅松(dimethoate)、覆滅 7 318305劃線本 200800021 (formetanate)、扶木松(formothion)、乃力松(naled)、曱 基巴拉松(methylparathion)、殺埃腈(cyanophos)、二米 達松(diamidafos)、加護松(propaphos)、甲丙硫鱗 (sulprofos)、普硫松(prothiofos)、佈飛松(profenofos)、 亞芬松(isofenphos)、亞培松(temephos)、賽達松 (phenthoate)、三 口坐硫填(dimethylvinphos)、氯芬石荒石粦 (chlorfevinphos)、樂本松(tetrachlorvinphos)、肟硫磷 • (phoxim)、力口 褐松(isoxathion)、白克松(pyraclofos)、陶 斯松(chlorpyrifos-methyl)、必芬松(pyridafenthion)、飛 賽隆(phasalone)、飛斯美(phasmet)、殺力松 (dioxabenzofos)、拜裕松(qUinaiph〇s)、甲硫松 (mesulfenfos)、歐殺松(acephate)、培丹(cartap)、硫賜 安(thiocyclam)、免速達(bensultap)、硫速達 (thiosultap)、芬普蝶(fenpyroximate)、畢達本 (pyridaben)、°比瞒胺(tebufenpyrad)、峻蟲蜗胺 ⑩(t〇lfenPyrad)、务殺汾11&amp;2&amp;911111)、畢汰芬(卩}^111[(^611)、 魚藤精(rotenone)、愛美隆(hydramethylnon)、亞酉昆 (acequinocyl)…密蜗酷(fiuacrypyrim)、氟 σ定胺 (fluazinam)、氟苯二酿胺(fiubendiamide)、氟蟲清 (fipronil)、乙酸普(acetoprole)、乙蟲清(ethiprole)、歐 蟎多(propargite)、因得克(ind〇xacarb)、美他氣米隆 (metaflumizone)、滅蜗猛(qUin〇methi〇nate)、汰芬諾克 (diafenthiuron)、赛海克、汀(cyhextin)氫氧化物、芬佈賜 (fenbutatin oxide)、三亞蜗(amitraz)、螺瞒 |旨 31们05劃線本 200800021 « (spirodiclofen)、季酮曱蜗酷(spiromesifen)、螺四蜗酉旨 (spirotetramat)、溴蟲腈(〇111(^£6113口)^)、百蜗克 (binapacryl)、克氣苯(chlorbenzilate)、紛硫殺 (phenisobromolate)、TPIC、菸鹼硫酸鹽 (nicotine-sulfate)、劇陽黴素(polynactins)複合物、印楝 素(azadirachtin)、經丙基澱粉(hydroxypropyl starch)、 摩朗得(morantel)酒石酸鹽、油酸鈉鹽、油酸鉀、啶蟲 丙 S^(pyridalyl)、替扶苯隆(teflubenzuron)、克福隆 (chlorfluazuron)、二氟苯隆(diflubenzuron)、六伏隆 (hexaflumuron)、敵草胺(n〇valuron)、祿芬隆 (lufenuron)、氟蟲脲隆(fluenoxuron)、得芬諾 (tebufenozide)、甲氧芬諾(methoxyfenozide)、克馬芬諾 (chromafenozide)、鹵芬諾(halofenozide)、二芬隆 (diofenolan)、布芬淨(buprofezin)、丙胺哄(cyromazine)、 燁蟲醋(methoprene)、烯蟲乙酯(11}^1'〇卩代1^)、百利普芬 • (Pyriproxyfen)、芬諾克(fen〇xycarb)、派滅淨 (pymetrozine)、克芬淨(ciofentezine)、合赛多 (hexythiazox)、芬硫克(fenothi〇carb)、依殺蟎 (etoxazole)、聯笨菊酯(bifenazate)、大克蟎(kelthane ; dicofol)、西脫蜗(benzoximate)、得脫瞒(tetradifon)、邁 隆(dazomet)、碟克敵(phosphocarb)、左17米唾鹽酸鹽 (levamisolHCl)、阿苯達唑(albendazole)、奥苯達唑 (oxibendazole)、芬苯達唑(fenbendazole)、奥芬達唑 (oxfendazole)、威百故(metam_sodium)、嗤财威 9 318305劃線本 200800021 (triazamate)或蘇力菌(Bacillus thuringiensis ; BT)。 8 ·如申請專利範圍第1項之有害生物防除劑,其中,具有 殺蟲活性、殺蜗活性或殺線蟲活性之化合物係芬普蜗 (fenpyroximate)、免扶克(fen〇bucarb ; BPMC)、滅必蝨 (isoprocarb ; MIPC)、η比瞒胺(tebufenpyrad)、哇蟲瞒胺 (tolfenpyrad)、布芬淨(buprofezin)、美他氟米隆 (metaflumizone)、得芬諾(tebufenozide)、溴蟲腈 (chlorfenapyr)、福化利(fluvalinate)、替扶苯隆 響 (teflubenzuron)或氟苯二醯胺(flubendiamide)。 9·如申請專利範圍第1項至第8項中任一項之有害生物防 除劑,其中,經取代之胺基喹唑啉酮化合物係1-乙醯基 -3,4-二氫-3-[(3-吼啶甲基)胺基]-6-[1,2,2,2-四氟-1-(三 氟曱基)乙基]·2(1Η)_喹唑啉酮,而具有殺蟲活性、殺蟎 活性或殺線蟲活性之化合物係布芬淨(buprofezin)、美他、 氟米隆(metaflumizone)或氟苯二酿胺(flubendiamide)。 ❿10·如申請專利範圍第1項至第9項中任一項之有害生物防 除劑,其中,相對於1重量份之經取代之胺基喹唑啉酮 化合物,自具有殺蟲活性、殺蜗活性或殺線蟲活性之化 合物中選擇1種或2種以上之化合物之調配比例係〇.〇1 至2000重量份。 11·一種有害生物防除劑之使用方法,其特徵為自有害生物 保護有用植物,以申請專利範圍第1項至第10項中任 一項之有害生物防除劑之有效量處理對象有害生物、對 象有用植物、對象有用植物之種子、土壤或栽培介質。 10 318305劃線本 200800021 12二種有害生物之防除方法,其特徵為防除有害生物,將 申請專利範圍第i項之—般式⑴所示經取代之胺基喧 唑啉酮化合物及其鹽類中選擇1種以上之化合物,:及 自具有殺蟲活性、殺蜗活性或殺線蟲活性之化合物中選 擇1種或2種以上之化合物’作為有效成分之有害生物 防除劑’以有效成分量計,每一公敗處理01至腦g。 13.—種化合物之用途,該化合物係自申請專利範圍第}項 之一般式(I)所示經取代之胺基喹唑啉酮化合物及其鹽、 類中選擇1種以上之化合物,其特徵為用於製造含有自 如申請專利範圍第1項之一般式(1)所示經取代之胺基 喹唑啉酮化合物及其鹽類中選擇1種以上之化合物,以 ^自具有殺蟲活性、殺蟎活性或殺線蟲活性之化合物中 造擇1種或2種以上之化合物之有害生物防除劑。 有害生物 青專利範Bii項之一船式⑴所彔 喧唾琳酮化合物或其_麵1舌旱份 、…羞^1.種以上選擇自殺蟲活性、躲栊法 ϋ·或叙線蟲2|」性之化合物中之化合物以〇 〇1 1 2〇〇〇番 盖伤之比例二j將1種以上選擇自如申請專利範圍对I -紅·^1)所示具有取代基之胺基啥唾咐酮化合物 A其鹽類土匕合物’以及1種或2種以上撰禪白呈 1森活性二活性或殺線蟲活性之化合铷中之化会 〇·1至l〇〇〇g之比例,加以句f而 Π 318305劃線本3]W05 lined book 4 200800021 / ^ ^ ^ ^ ^^ ^ . iTcT-Ce)^^ . (Ci.C6) alkoxy, halogen (Cl_C6) alkoxy, tooth (CVC6) sulfonyl, halogen (Ci_c6) An alkoxy halide (C)-C6) alkoxy group or a (C)-C6) alkoxy group to give an integer of 1 to 2. 3. The pest control agent according to claim 1 of the patent scope, wherein r represents (CVC6) alkylcarbonyl, · z_Ri represents · nh-c^r, in the formula, reverse] represents money base, X * 4 (Ci_C6) recorded, n each is expressed as! . Spring (such as the pest control agent of the scope of the patent scope, wherein the substituted amino-based sulfonium ketone compound or its salt is i _ ethyl ketone _ 3, heart dihydrogen 3- [( 3. A bit of methyl)aminotetrafluoro]-(trifluoromethyl)ethyl]-2(1 H)-喧 琳 _ _ or its salts. 5. Harmful as claimed in item i: An anti-inhibitor, wherein the compound having insecticidal activity, acaricidal activity or nematicidal activity is an acetaminophen acetal test inhibitor, an acetaminophen receptor inhibitor, a GABA-regulated vapor channel agonist, and a material Difficulty agent, Nicholas Beneficial receptor-sensing effect agent, acetaminophen receptor agonist, chloride channel activator, preservative, sputum, degenerative Weihua inhibitor and ATp Formation of an unblocking agent for oxidative sulphation caused by a hindrance agent and a hydrogen gradient, and a hindrance inhibitor (type 1), a quercetin agonist/peeling inhibitor, and a octopus for Homoptera Amine agonist, position j electron transport system hinder (10): 1), position 11 electron transport system inhibitor, lipid biosynthesis inhibitor, monatinidine receptor modulator or non-specific Mechanism of action (e.g., hindered selective feeding) of the compound. 6. The pest control agent according to item yi of the patent application scope, wherein the compound having the insecticidal activity, the acaricidal activity or the nematicidal activity of the 318305 lined line 5 200800021 is an insecticide, an acaricide, Iridium IGR insecticide, pyrethroid insecticide, sodium channel blocking insecticide, aminocarboxylic acid insecticide, organophosphorus insecticide, killing with calcium channel activation Insecticide, phenylmercaptophenylurea insecticide, diterpene based insecticide. 7. The pest control agent according to claim 1, wherein the compound having insecticidal activity, acaricidal activity or nematicidal activity is acetamiprid, imidacloprid, imidacloprid (imidacloprid) Nitenpyram), thiamethoxam, clothianidin, dinotefuran, thiacloprid, flubendiamide ([1〇111〇&amp;1111(1), Kabbah Carbaryl, Fenbucarb, MIPC; isoprocarb, ethiofencarb, pirimicarb, oxanyl, benfuracarb ,methiocarb, mecarbam, thiodicarb, aldicarb, alanycarb, metolcarb, xylycarb, Propoxur, carbofuran, carbosulfan, furathiocarb, endosulfan, aldoxycarb, methodyl, Cyhalothrine, permethrin, cypermethr In), bifenthrin, halfenprox, silafluofen, cyfluthrin, beta-cyfluthrin, tralmethrin, 6 318305 underline 200800021 pyrethrin, aiiethrin, acrinathrin, praiiethrin, esmethrin, sevoflurane Tefluthrin), fenpropathrin, arsenin (&amp;1卩11&amp;_〇}^卩61&gt;11161:111^11), laminda (lambda-cyhalothrin), deltamethrin, fen芬va_lerate, esfenvalerate, fiucythrinate, fluvaiinate, cycloprothrin, ethofenprox, avermectin , milbemectin, emamectin, spinosad, fenitrothion, marathion, methidathion, fenthion, diazinon ), oxydeprofos, vamidothion, sub Tesong &amp;^11^卩]1〇5-11^化}^1), chlorpyriphos, terfufos, ethoprophos, cadusafos, fensamine 10 (fenamiphos), fensulfothion, DSP, dichlofenthion, fosthiazate, isamidofos, fosthietan, isazofos , azinphos-methyl, disulfotion, oxydemeton-methyl, parathions, tebupirimfos, ethion , trichlorfon, metamidophos, dichlorvos, mevinphos, monocrotophos, dimethoate, annihilation 7 318305 underline 200800021 ( Formetanate), formothion, naled, methylparathion, cyanophos, diamidafos, propaphos, methyl propane sulphide Sulprofos, prothiofos, profenofos, alfifen (isofenphos), temephos, phenthoate, dimethylvinphos, chlorfevinphos, tetrachlorvinphos, phoxim, (phoxim), Isoxathion, pyraclofos, chlorpyrifos-methyl, pyridafenthion, phasalone, phasmet, dioxabenzofos, baiyu Pine (qUinaiph〇s), mesulfenfos, acephate, cartap, thiocyclam, bensultap, thiosultap, fenbuter ( Fenpyroximate), pyripaben, tebufenpyrad, t〇lfenPyrad, scorpion 11 &amp;2&amp;911111, dynasty (卩}^111[(^ 611), rotenone, hydramethylnon, acequinocyl, fiuacrypyrim, fluazinam, fiubendiamide, flubendiamide (fipronil), acetoprole, ethiprole, euro Propargite, indxxacarb, metaflumizone, qUin〇methi〇nate, diafenthiuron, seyheke, cyhextin ) hydroxide, fenbutatin oxide, amitraz, snail | syllabus 31 05 lined 200800021 « (spirodiclofen), quaternone snails (spiromesifen), snails Spirotetramat), chlorfenapyr (〇111 (^£6113)^), binapacryl, chlorbenzilate, phenisobromolate, TPIC, nicotine-sulfate , polynactins complex, azadirachtin, hydroxypropyl starch, morantel tartrate, sodium oleate, potassium oleate, acetamiprid S^ (pyridalyl), teflubenzuron, chlorfluazuron, diflubenzuron, hexaflumuron, n〇valuron, lufenuron, Fluenoxuron, tebufenozide, methoxyfenozi De), chromafenozide, halofenozide, diofenolan, buprofezin, cyromazine, methoprene, methacrylate (11) }^1'〇卩代1^), Pyriproxyfen, fen〇xycarb, pymetrozine, ciofentezine, hexythiazox, Fenothi〇carb, etoxazole, bifenazate, kelthane; dicofol, benzoximate, tetradifon, milong Dazomet), phosphocarb, left 17 m salivasolHCl, albendazole, oxibendazole, fenbendazole, oxfendazole Oxfendazole), metam_sodium, 嗤财威 9 318305 underline 200800021 (triazamate) or Bacillus thuringiensis (BT). 8 · The pest control agent according to claim 1 of the patent scope, wherein the compound having insecticidal activity, bactericidal activity or nematicidal activity is fenpyroximate, fen〇bucarb (BPMC), Isoprocarb (MIPC), η, tebufenpyrad, tolfenpyrad, buprofezin, metaflumizone, tebufenozide, bromo Nitrogen (chlorfenapyr), fluvalinate, teflubenzuron or flubendiamide. The pest control agent according to any one of claims 1 to 8, wherein the substituted aminoquinazolinone compound is 1-ethylmercapto-3,4-dihydro-3 -[(3-Acridinemethyl)amino]-6-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]·2(1Η)_quinazolinone, The compound having insecticidal activity, acaricidal activity or nematicidal activity is buprofezin, metopine, metaflumizone or flubendiamide. The pest control agent according to any one of the items 1 to 9 wherein the substituted amino quinazolinone compound has an insecticidal activity and a bactericidal activity. The compounding ratio of one or more compounds selected from the active or nematicidal activity is 〇1 to 2000 parts by weight. A method for using a pest control agent, which is characterized in that a useful plant is protected from a pest, and an effective amount of a pest control agent according to any one of claims 1 to 10 is applied to treat a target pest or object. A useful plant, a seed of a useful plant, a soil, or a cultivation medium. 10 318305 underline 200800021 12 two pest control methods, which are characterized by pest control, and the substituted amino oxazolinone compounds and their salts as shown in general formula (1) of the scope of patent application i One or more compounds selected from the group consisting of: one or more compounds selected from the group consisting of insecticidal activity, bactericidal activity or nematicidal activity as a pesticidal agent of the active ingredient' , each failure to deal with 01 to brain g. 13. The use of a compound selected from the group consisting of substituted amino quinazolinone compounds of the general formula (I) and salts thereof, and one or more compounds selected from the group consisting of It is characterized in that one or more selected ones of the substituted amino quinazolinone compounds represented by the general formula (1) and the salts thereof, which are contained in the first paragraph of the patent application scope, are selected to have an insecticidal activity. A pest control agent for one or more compounds selected from the group consisting of acaricidal activity or nematicidal activity. One of the pests of the patents, the patent class Bii, the ship type (1), the scorpion ketone compound or its _ face 1 tongue dry, ... shy ^ 1. species above selected suicide insect activity, dodge 栊 ϋ or nematode 2 The compound in the compound of the formula is 盖1 1 2 〇〇〇 盖 盖 盖 二 j j j j j j 选择 选择 选择 选择 选择 选择 选择 选择 选择 选择 选择 选择 选择 选择 选择 选择 选择 具有 具有 具有 具有 具有 具有 具有 具有 具有咐 咐 化合物 其 其 其 其 其 其 其 其 其 其 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐 咐Proportion, add sentence f and 318 318305 line
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