TW200537757A - Planar connector - Google Patents

Planar connector Download PDF

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Publication number
TW200537757A
TW200537757A TW94107779A TW94107779A TW200537757A TW 200537757 A TW200537757 A TW 200537757A TW 94107779 A TW94107779 A TW 94107779A TW 94107779 A TW94107779 A TW 94107779A TW 200537757 A TW200537757 A TW 200537757A
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Taiwan
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fibrous filler
resin composition
composite resin
patent application
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TW94107779A
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Chinese (zh)
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TWI343676B (en
Inventor
Hiroki Fukatsu
Kazufumi Watanabe
Toshio Shiwaku
Hirokazu Oshiba
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Polyplastics Co
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • C08L101/12Compositions of unspecified macromolecular compounds characterised by physical features, e.g. anisotropy, viscosity or electrical conductivity
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00Characterised by the use of unspecified polymers
    • C08J2300/12Polymers characterised by physical features, e.g. anisotropy, viscosity or electrical conductivity

Abstract

It is an object of the present invention to provide a very thin planar connector having 2 mm or smaller contact pitch at the grid section and 0.5 mm or smaller thickness of the grid section, giving excellent performance in the whole performances such as moldability, flatness, warp-deformation, and heat resistance. A planar connector having a grid structure within an outer frame is molded by using (C) a complex resin composition prepared by blending (A) a liquid-crystalline polymer with (B) a fibrous filler, while the relation between the blending quantity and the weight-average length of (B) the fibrous filler is controlled to a specified range.

Description

200537757 九、發明說明: 【發明所屬之技術領域】 本發明係關於在C P U插座等外框内部具有晶格構造的平 _ 面狀連接器。 【先前技術】 液晶性聚合物於熱可塑性樹脂中已知有尺寸精確度、防 震性、流動性優良,且成形時極少發生溢料的材料。以往, 多活用此類特徵,將液晶性聚合物採用作為各種電子零件 •的材料。200537757 IX. Description of the invention: [Technical field to which the invention belongs] The present invention relates to a flat surface connector having a lattice structure inside an outer frame such as a CP socket. [Prior art] Liquid crystalline polymers are known in thermoplastic resins as materials with excellent dimensional accuracy, shock resistance, and fluidity, and they are extremely free from flashover during molding. In the past, many of these characteristics have been used, and liquid crystal polymers have been used as materials for various electronic parts.

尤其,隨著近年來的電子機器之高性能化,亦有所謂之 連接器的高耐熱化(以安裝技術提高生產性)、高密度化(多 芯化)、小型化之時代性的要求’已有活用上述液晶性聚合 物的特徵,並將經玻璃纖維強化的液晶性聚合物組成物採 用作為連接器(全調查 Engineering Plastics ’92-’93, 182〜194頁,1992年發行,]?_八9-204951、1?-八6-240115)。 於CPU插座所代表的外框内部具有晶格構造的平面狀連接 器中,上述高耐熱化、高密度化、小型化的傾向顯著,多 採用經玻璃纖維強化的液晶性聚合物組成物。 但是,即使為具有某程度良好流動性的玻璃纖維強化液 晶性聚合物組成物,於使用作為近年所要求之晶格部間距 間隔為 2mm 以下、保持端子之晶格部的樹脂部分厚度為 0. 5 m m以下之非常薄身的平面狀連接器方面,性能仍不充 分。即,於此類晶格部之非常薄身的平面狀連接器中,若 欲對晶格部填充樹脂,則因流動性不夠充分而使填充壓力 6 326\專利說明書(補件)\94-07\94107779 200537757 變高,結果具有所得之平面狀連接器之彎曲變形量變多的 問題。 為解決此問題,雖考慮使用玻璃纖維添加量減少之流動 性良好的液晶性聚合物組成物,但此類組成物強度不足, 產生因安裝時的迴焊而變形的問題。 如此,目前狀況為仍未取得性能平衡優良的液晶性聚合 物製平面狀連接器。 【發明内容】In particular, with the recent high performance of electronic equipment, so-called high-temperature-resistant connectors (increased productivity through mounting technology), high-density (multi-core), and miniaturization are also required. The characteristics of the above-mentioned liquid crystal polymers have been used, and glass fiber-reinforced liquid crystal polymer compositions have been adopted as connectors (full survey Engineering Plastics '92 -'93, pages 182 ~ 194, issued in 1992,]? _ 8-9-204951, 1?-8-240115). In a planar connector having a lattice structure inside an outer frame represented by a CPU socket, the above-mentioned tendency of high heat resistance, high density, and miniaturization is remarkable, and a glass fiber-reinforced liquid crystal polymer composition is often used. However, even for glass fiber-reinforced liquid crystalline polymer compositions having a certain degree of good fluidity, the spacing between the lattice portions required to be used in recent years is 2 mm or less, and the thickness of the resin portion of the lattice portion holding the terminals is 0. In the case of very thin flat connectors below 5 mm, performance is still insufficient. That is, in a very thin flat connector of such a lattice portion, if the lattice portion is to be filled with resin, the filling pressure is insufficient due to insufficient fluidity. 6 326 \ Patent Specification (Supplement) \ 94- 07 \ 94107779 200537757 becomes high, as a result, there is a problem that the amount of bending deformation of the obtained planar connector is increased. In order to solve this problem, although it is considered to use a liquid crystal polymer composition having good fluidity with a reduced amount of glass fiber added, such a composition has insufficient strength and causes a problem of deformation due to reflow during mounting. Thus, the present situation is that a flat connector made of a liquid crystal polymer having excellent performance balance has not yet been obtained. [Summary of the Invention]

如上所述,關於具有晶格構造之平面狀連接器中所用的 液晶性聚合物組成物雖已進行各式各樣的檢討,但尤其關 於晶格部之間距間隔為2 m m以下、晶格部之厚度為 0 . 5 hi m 以下之非常薄身的平面狀連接器,並未存在成形性、平面 度、彎曲變形、耐熱性等性能均優良的材料。 本發明者等人有鑑於上述問題點,為了提供性能平衡優 良之液晶性聚合物製平面狀連接器而進行深入研究、檢 討,發現於纖維強化液晶性聚合物組成物中,在所配合之 纖維狀填充劑的重量平均長度與配合量具有一定的關係之 情況,可取得成形性良好、平面度、彎曲變形、耐熱性等 性能均優良的平面狀連接器,遂完成本發明。 即,本發明為由於(A )液晶性聚合物中配合有(B )纖維狀 填充劑之(C )複合樹脂組成物(但,配合之(B )纖維狀填充劑 的配合量與重量平均長度的關係滿足以下區域(D )的規定 内)所形成,且於外框的内部具有晶格構造的平面狀連接 器。 326\專利說明書(補件)\94-07\94107779 Ί 200537757 [區域(D )] X軸為(B )纖維狀填充劑之配合量((C )複合樹脂組成物 中之重量% )、Y軸為(B )纖維狀填充劑之重量平均長度(// hi ),且以下列(1 )〜(5 )之函數所包圍的區域 (1 ) X = 36 (2) X=53 (3) Y-l 60 (4) Υ-360As mentioned above, although various investigations have been made on the liquid crystal polymer composition used in a planar connector having a lattice structure, it is particularly related to the distance between the lattice portions of 2 mm or less and the lattice portions. A very thin, flat connector with a thickness of 0.5 hi m or less has no materials with excellent properties such as formability, flatness, bending deformation, and heat resistance. In view of the above-mentioned problems, the present inventors have conducted intensive research and review in order to provide a flat connector made of a liquid crystalline polymer with excellent performance balance. In the case where the weight average length of the filler has a certain relationship with the blending amount, a planar connector having good formability, flatness, bending deformation, heat resistance and other properties can be obtained, and the present invention has been completed. That is, the present invention is a (C) composite resin composition in which (B) a fibrous filler is blended in a (A) liquid crystalline polymer (however, the blending amount and weight average length of the (B) fibrous filler are blended) Is a planar connector formed by satisfying the following area (D), and has a lattice structure inside the outer frame. 326 \ Patent Specification (Supplement) \ 94-07 \ 94107779 Ί 200537757 [Zone (D)] The X axis is the blending amount of (B) the fibrous filler ((C) wt% in the composite resin composition), Y The axis is (B) the weight-average length of the fibrous filler (// hi), and the area surrounded by the following functions (1) to (5) (1) X = 36 (2) X = 53 (3) Yl 60 (4) Υ-360

(5) Υ = ( 1 8 2 2 2 /Χ)-84. 44 又,本發明係為上述(C )複合樹脂組成物於外框之内部 具有晶格構造之平面狀連接器的用途。 【實施方式】 以下,詳細說明本發明。本發明所使用之液晶性聚合物 (A ),係指具有可形成光學異向性熔融相性質的熔融加工性 聚合物。異向性熔融相的性質可根據利用垂直偏振光鏡之 慣用的偏振光檢查法加以確認。更具體而言,異向性熔融 相之確認可經由使用L e i t z偏振光顯微鏡,將L e i t z熱台 上承載的熔融試料於氮環境下以 40倍之倍率觀察而實 施。本發明中可適用的液晶性聚合物在垂直偏振光鏡之間 檢查時,即使為熔融靜止狀態,通常仍可使偏振光通過, 且顯示光學上的異向性。 如前述之液晶性聚合物(A )並無特別限定,但以芳香族 聚酯或芳香族聚酯醯胺為佳,且於同一分子鏈中部分地含 有芳香族聚酯或芳香族聚酯醯胺的聚酯亦在此範圍。該等 8 326\專利說明書(補件)\94-07\94107779 200537757 係使用在6 0 °C下於五氟化酚中以濃度0 . 1重量%溶解時, 較佳為至少具有約2 . 0 d 1 / g、更佳為2 . 0〜1 0 . 0 d 1 / g的對數 黏度(I · V ·)者。 本發明中可應用之作為液晶性聚合物(A )的芳香族聚酯 或芳香族聚醋醯胺,特佳為具有選自芳香族經基魏酸、芳 香族羥基胺、芳香族二胺群組之至少一種以上的化合物作 為構成成分的芳香族聚酯、芳香族聚酯醯胺。 更具體而言,可列舉(5) Υ = (1 8 2 2 2 / ×) -84. 44 In addition, the present invention is a use of the planar connector having the lattice structure inside the outer frame of the (C) composite resin composition. [Embodiment] Hereinafter, the present invention will be described in detail. The liquid crystalline polymer (A) used in the present invention refers to a melt-processable polymer having a property of forming an optically anisotropic melt phase. The properties of the anisotropic molten phase can be confirmed by a conventional polarization inspection method using a vertical polarizer. More specifically, the confirmation of the anisotropic molten phase can be performed by observing the molten sample carried on the Leite t hot stage under a nitrogen environment at a magnification of 40 times using a Leite z polarized light microscope. When the liquid crystalline polymer applicable in the present invention is inspected between vertical polarizers, it can usually pass polarized light even when it is in a molten stationary state, and exhibit optical anisotropy. The liquid crystalline polymer (A) is not particularly limited as described above, but it is preferably an aromatic polyester or an aromatic polyester fluorene amine, and partially contains an aromatic polyester or an aromatic polyester fluorene in the same molecular chain. Amine polyesters are also in this range. The 8 326 \ Patent Specification (Supplement) \ 94-07 \ 94107779 200537757 is used when it is dissolved in pentafluorophenol at a concentration of 0.1% by weight at 60 ° C, preferably at least about 2. 0 d 1 / g, more preferably 2. 0 to 1 0. 0 d 1 / g logarithmic viscosity (I · V ·). As the liquid crystalline polymer (A), the aromatic polyester or aromatic polyacetamide which can be used in the present invention, it is particularly preferred to have an aromatic diamine group, an aromatic hydroxyamine, or an aromatic diamine group. Aromatic polyester and aromatic polyester amidamine having at least one compound of the group as a constituent. More specifically, it can be enumerated

(1) 主要由芳香族羥基羧酸及其衍生物之一種或二種 以上所構成的聚酯; (2) 主要由(a)芳香族羥基羧酸及其衍生物之一種或二 種以上;(b )芳香族二羧酸、脂環族二羧酸及其衍生物之一 種或二種以上;及(c )芳香族二醇、脂環族二醇、脂肪族二 醇及其衍生物之至少一種或二種以上所構成的聚酯; (3 )主要由(a )芳香族羥基羧酸及其衍生物之一種或二 種以上;(b )芳香族羥基胺、芳香族二胺及其衍生物之一種 或二種以上;及(c )芳香族二羧酸、脂環族二羧酸及其衍生 物之一種或二種以上所構成的聚酯醯胺; (4)主要由(a)芳香族羥基羧酸及其衍生物之一種或二 種以上;(b )芳香族經基胺、芳香族二胺及其衍生物之一種 或二種以上;(c )芳香族二羧酸、脂環族二羧酸及其衍生物 之一種或二種以上;及(d )芳香族二醇、脂環族二醇、脂肪 族二醇及其衍生物之至少一種或二種以上所構成的聚酯醯 胺等。更且,於上述之構成成分中視需要亦可併用分子量 9 326\專利說明書(補件)\94_07\941〇7779 200537757 調整劑。 構成本發明中可適用之前述液晶性聚合物(A )的具體化 合物的較佳例,可列舉對-羥基苯曱酸、6 -羥基-2 -萘曱酸 等之芳香族羥基羧酸、2, 6-二羥基萘、1,4 -二羥基萘、4, 4’-二羥基聯苯、氫醌、間苯二酚、下述一般式(I )及下述一般 式(I I )所示之化合物等之芳香族二醇;對苯二曱酸、間苯 二曱酸、4, 4’-二苯基二羧酸、2, 6 -萘二羧酸及下述一般式 (I I I )所示化合物等之芳香族二羧酸;對-胺基酚、對-伸苯 _ 二胺等之芳香族胺類。 H0 Ό - X""0-(1) Polyester composed mainly of one or more aromatic hydroxycarboxylic acids and their derivatives; (2) Polyester mainly composed of (a) one or more aromatic hydroxycarboxylic acids and their derivatives; (B) one or more of aromatic dicarboxylic acids, alicyclic dicarboxylic acids and their derivatives; and (c) aromatic diols, alicyclic diols, aliphatic diols and their derivatives Polyester composed of at least one or two or more; (3) one or two or more of (a) aromatic hydroxycarboxylic acids and their derivatives; (b) aromatic hydroxyamines, aromatic diamines, and One or two or more derivatives; and (c) one or more polyester amidamines composed of one or more aromatic dicarboxylic acids, alicyclic dicarboxylic acids, and derivatives thereof; (4) mainly composed of (a ) One or two or more aromatic hydroxycarboxylic acids and their derivatives; (b) one or two or more aromatic mesialamines, aromatic diamines and their derivatives; (c) aromatic dicarboxylic acids, One or more of alicyclic dicarboxylic acids and derivatives thereof; and (d) aromatic diols, alicyclic diols, aliphatic diols, and The at least one biological or polyester Amides like composed of two or more. In addition, among the above constituents, a molecular weight of 9 326 \ patent specification (supplement) \ 94_07 \ 941〇7779 200537757 regulator can be used in combination as needed. Preferred examples of specific compounds constituting the aforementioned liquid crystalline polymer (A) to which the present invention is applicable include aromatic hydroxycarboxylic acids such as p-hydroxybenzoic acid, 6-hydroxy-2 -naphthoic acid, and 2 , 6-dihydroxynaphthalene, 1,4-dihydroxynaphthalene, 4, 4'-dihydroxybiphenyl, hydroquinone, resorcinol, the following general formula (I) and the following general formula (II) Aromatic diols such as compounds; terephthalic acid, isophthalic acid, 4, 4'-diphenyl dicarboxylic acid, 2, 6-naphthalenedicarboxylic acid, and the following general formula (III) Aromatic dicarboxylic acids such as compounds; aromatic amines such as p-aminophenol and p-phenylene diamine. H0 Ό-X " " 0-

OH (I )OH (I)

HO (I)HO (I)

HOOC hQ)-Y-£^-C00H (Π)HOOC hQ) -Y- £ ^ -C00H (Π)

(其中,X:伸烧基(Cl 〜C4)、亞烧(alkylidene)基、-〇-、 -SO-、-S〇2-、-S-、一 CO-中選出之基,Y: -(CH2)n-(n = l 〜4)、 - 0(CH2)n〇-(n = l〜4)中選出之基。) 本發明中適用之特佳的液晶性聚合物(A )為以對-羥基 苯曱酸、6 -羥基-2 -萘曱酸作為主構成單位成分的芳香族聚 酯。 本發明所使用之(C )複合樹脂組成物為於上述(A )液晶 性聚合物中配合(B )纖維狀填充劑者,所配合之(B )纖維狀 326\專利說明書(補件)\94-07\94107779 10 200537757 填充劑的配合量與重量平均長度的關係必須滿足以下區域 (D )的規定内。 [區域(D )] X軸為(B )纖維狀填充劑之配合量((C )複合樹脂組成物 中之重量% )、Y軸為(B )纖維狀填充劑之重量平均長度(// m ),以下列(1 )〜(5 )之函數所包圍之區域 (1 ) X = 36 (2) X=53(Wherein: X: selected from the group consisting of Cl ~ C4, alkylidene, -〇-, -SO-, -S〇2-, -S-, -CO-, Y:- (CH2) n- (n = 1 to 4), -0 (CH2) n0- (n = 1 to 4).) A particularly preferred liquid crystal polymer (A) suitable for use in the present invention is Aromatic polyester containing p-hydroxybenzoic acid and 6-hydroxy-2-naphthoic acid as main constituent units. The (C) composite resin composition used in the present invention is one in which (B) a fibrous filler is blended in the (A) liquid crystalline polymer, and the (B) fibrous filler 326 \ Patent Specification (Supplement) \ 94-07 \ 94107779 10 200537757 The relationship between the compounding amount of filler and the average weight must meet the requirements of the following area (D). [Region (D)] X-axis is the blending amount of (B) fibrous filler ((C) wt% in composite resin composition), and Y-axis is the average weight of (B) fibrous filler (// m), the area surrounded by the following functions (1) to (5) (1) X = 36 (2) X = 53

(3) Y = 1 60 (4) Y=360 (5) Υ = ( 1 8 2 2 2 /Χ)-84. 44 上述區域(D)為圖1之Ζ所示之區域,基本上,(Β)纖維 狀填充劑之重量平均長度必須為(3 ) Υ = 1 6 0 // m 以上且 (4)Y = 360//m 以下。 (B )纖維狀填充劑之重量平均長度未滿1 6 0 // m之情況, 補強效果小,即使增多配合量亦無法取得所欲的效果。又, (B )纖維狀填充劑之重量平均長度若超過 3 6 0 // m,則即使 減少配合量仍令流動性惡化,無法作成優良平面度的連接 器。另外,本發明所指之(B )纖維狀填充劑的重量平均長 度,係成形品中之值,可根據後述之方法測定。又,(B) 纖維狀填充劑之纖維徑並無特別限制,一般為使用5〜1 5 // m左右者。 又,關於(B )纖維狀填充劑之配合量((C )複合樹脂組成 物中之配合比率),必須為(1 ) X = 3 6重量%以上且(2 ) X = 5 3 11 326\專利說明書(補件)\94-07\94107779 200537757 重量%以下。 (B )纖維狀填充劑之配合量若未滿 36重量%,則即便使 用重量平均長度相對較長的纖維狀填充劑,補強效果仍 小,無法取得所欲之效果。又,(B )纖維狀填充劑之配合量 若超過5 3重量%,則即便使用重量平均長度相對較短的纖 維狀填充劑,流動性仍惡化,無法作成優良平面度的連接 器〇(3) Y = 1 60 (4) Y = 360 (5) Υ = (1 8 2 2 2 / χ) -84. 44 The above-mentioned area (D) is the area shown by Z in Fig. 1, basically, ( Β) The average weight of the fibrous filler must be (3) Υ = 1 6 0 // m or more and (4) Y = 360 // m or less. (B) In the case where the weight-average length of the fibrous filler is less than 16 0 // m, the reinforcing effect is small, and the desired effect cannot be obtained even if the blending amount is increased. In addition, if the weight-average length of the (B) fibrous filler exceeds 3 6 0 // m, even if the blending amount is reduced, the fluidity is deteriorated, and a connector with excellent flatness cannot be made. The weight average length of the fibrous filler (B) referred to in the present invention is a value in a molded product and can be measured by a method described later. (B) The fiber diameter of the fibrous filler is not particularly limited, and it is generally about 5 to 1 5 // m. The blending amount of the (B) fibrous filler (the blending ratio in the (C) composite resin composition) must be (1) X = 36 or more by weight and (2) X = 5 3 11 326 \ Patent Specification (Supplement) \ 94-07 \ 94107779 200537757 Weight% or less. (B) If the blending amount of the fibrous filler is less than 36% by weight, even if a fibrous filler having a relatively long weight average length is used, the reinforcing effect is still small, and the desired effect cannot be obtained. In addition, if the blending amount of the (B) fibrous filler exceeds 53% by weight, even if a fibrous filler having a relatively short weight average length is used, the fluidity is deteriorated, and a connector having excellent flatness cannot be made.

更且,上述區域(D )必須滿足(5 ) Y = ( 1 8 2 2 2 / X ) - 8 4 · 4 4的 要件。即,即使為用上述(1 )〜(4 )之函數所包圍之區域,隨 著(B )纖維狀填充劑之配合量增加(4 1重量%以上),若未使 用(B )纖維狀填充劑之重量平均長度短者,則流動性和強 度·平面度的平衡變差,無法取得本發明所期望之效果。 本發明中所使用之(B )纖維狀填充劑可列舉玻璃纖維、 碳纖維、晶鬚、無機系纖維、礦石系纖維等,以玻璃纖維 為佳。 本發明所使用之(C)複合樹脂組成物之流動性必須優 良,若由黏度方面來規定,則使用L = 2 0 m m、d = 1 m m之毛細 管式流變儀,以溫度 3 6 0 °C 、剪切速度 1 0 0 0 / s並且根據 I S 0 1 1 4 4 3所測定之表觀熔融黏度為5 5 P a · s以下為佳。 具有此類表觀熔融黏度之組成物,係使用一般熔融黏度 的液晶性聚合物(1 0〜1 0 0 P a · s、較佳為 1 0〜4 0 P a · s ),可 在於其中以滿足前述條件之範圍下配合(B )纖維狀填充劑 之情況取得。 取得此類組成物之方法並無特別限制,但一般係使用擠 12 326\專利說明書(補件)\94-07\94107779 200537757 壓機予以熔融混練。但,於熔融之液晶性聚合物中由側面 進料纖維狀填充劑的一般擠壓方法多無法取得。因此,必 須使用將經一次熔融混練之配合有纖維狀填充劑之液晶性 聚合物組成物予以再度熔融混練之方法、由側面進料纖維 狀填充劑及粒狀(粒徑 1mm 以上)之液晶性聚合物的方法 等。較佳為熱經歷少且由側面進料粒狀液晶性聚合物的方 法。又,所使用之擠壓機亦以容易側進料的雙螺桿擠壓機 為佳。Furthermore, the above-mentioned area (D) must satisfy the requirement of (5) Y = (1 8 2 2 2 / X)-8 4 · 4 4. That is, even in the area surrounded by the functions of (1) to (4), as the blending amount of (B) fibrous filler increases (41% by weight or more), if (B) fibrous filler is not used If the weight average length of the agent is short, the balance between fluidity, strength, and flatness is deteriorated, and the desired effect of the present invention cannot be obtained. Examples of the fibrous filler (B) used in the present invention include glass fibers, carbon fibers, whiskers, inorganic fibers, and mineral fibers, and glass fibers are preferred. The (C) composite resin composition used in the present invention must have excellent fluidity. If it is specified by viscosity, use a capillary rheometer with L = 20 mm and d = 1 mm at a temperature of 3 6 0 ° C. Shear speed 1 0 0 0 / s and the apparent melt viscosity measured according to IS 0 1 1 4 4 3 is preferably 5 5 P a · s or less. The composition having such an apparent melt viscosity is a liquid crystal polymer (10 to 100 Pa · s, preferably 10 to 40 Pa · s) with a general melt viscosity. Obtained in the case where the (B) fibrous filler is blended within a range satisfying the aforementioned conditions. The method for obtaining such a composition is not particularly limited, but it is generally melt-kneaded using an extruder 12 326 \ Patent Specification (Supplement) \ 94-07 \ 94107779 200537757. However, many conventional extrusion methods for feeding a fibrous filler from the side of a molten liquid crystalline polymer are not available. Therefore, it is necessary to use a method of remelting and kneading the liquid crystalline polymer composition mixed with a fibrous filler once melt-kneaded, feeding the fibrous filler from the side, and granular (particle diameter 1 mm or more) liquid crystallinity. Methods of polymers, etc. A method in which the granular liquid crystalline polymer is fed from the side with less heat history is preferred. The extruder used is preferably a twin-screw extruder for easy side feeding.

經由將本發明之(C )複合樹脂組成物成形,可取得各種 平面狀連接器,於習知技術無法提供工業上具實用性之晶 格部之問距間隔為2mm以下、保持端子之晶格部的樹脂部 分厚度為0. 5mm以下、製品全體之高度為5. Omm以下之非 常薄身的平面狀連接器方面特別有效。 若進一步詳細說明此類平面狀連接器,則為實施例中所 成形之如圖2所示的連接器,於40mmx40mmxlmm左右之製 品中具有數百個針腳(p i η)孔數者。如圖2所示般,本發明 所指之平面狀連接器當然亦可於晶格部之中具有適當大小 的開口部。 經由使用本發明之(C )複合樹脂組成物,則如圖 2所示 般,可令晶格部之間距間隔為2 m m以下(1 · 2 m m )、保持端子 之晶格部的樹脂部分之厚度為0 . 5 m m以下(0 · 1 8 m m )之非常 薄身的平面狀連接器以良好成形性成形,且其平面度亦優 良。 若數值性地規定其平面度,則在經過以波峯溫度 13 326\專利說明書(補件)\94-07\94107779By forming the (C) composite resin composition of the present invention, various planar connectors can be obtained, and the conventional lattice technology cannot provide an industrially practical lattice section with an interval distance of 2 mm or less and a lattice retaining terminal. The thickness of the resin portion of the portion is 0.5 mm or less, and the height of the entire product is 5. 0 mm or less, which is particularly effective in a very thin body-shaped connector. If such a planar connector is further described in detail, it is the connector shown in FIG. 2 formed in the embodiment, and has a number of hundreds of pins (p i η) in a product of about 40mmx40mmxlmm. As shown in FIG. 2, the planar connector referred to in the present invention may of course have an opening of an appropriate size in the lattice portion. By using the (C) composite resin composition of the present invention, as shown in FIG. 2, the distance between the lattice portions can be set to 2 mm or less (1.2 mm). Very thin flat connectors with a thickness of 0.5 mm or less (0.18 mm) are formed with good formability, and their flatness is also excellent. If its flatness is specified numerically, the peak temperature after the peak temperature 13 326 \ Patent Specification (Supplement) \ 94-07 \ 94107779

200537757 230〜280 °C進行用以表面安裝之IR迴焊步驟前的平面 0.09mm以下,且迴焊前後之平面度差為0.02mm以下 可謂於實用上具有優良的平面度。 取得具有此類優良平面度之連接器的成形方法並 別限制,較佳為使用經濟性的射出成形方法。為了以 成形取得具有此類優良平面度之連接器上,其重要事 使用前述之液晶性聚合物組成物,且以選擇無殘留内 力的成形條件為佳。為了減低填充壓力,並降低所得 器之殘留内部應力,令成形機之汽缸溫度在液晶性聚 之熔點 T °C以上的溫度為佳,若汽缸溫度過高,則隨 脂分解等而由汽缸噴嘴發生黏絲等之問題,故令汽缸 為T °C〜(T + 3 0 ) °C、較佳為T °C〜(T + 1 5 ) °C。又,模具溫 7 0〜1 0 0 °C為佳。模具溫度若低,則引起填充樹脂組成 流動不良,較不佳,模具溫度若過高,則產生發生溢 之問題,較不佳。關於射出速度,以1 5 0 m m / s e c以上 為佳。射出速度若低,則有僅取得未填充成形品之情 或即便取得完全填充的成形品仍為填充壓高且殘留内 力大的成形品,有僅能取得平面度差之連接器的情況 另外,對於(C)複合樹脂組成物添加成核劑、碳黑 機般燒顏料等之顏料、抗氧化劑、安定劑、可塑劑、 劑、脫模劑及難燃劑等之添加劑,賦予所欲特性的組 亦被包含於本發明之(C)複合樹脂組成物的範圍内。 (實施例) 以下,根據實施例具體說明本發明,但本發明並非 326\專利說明書(補件)\94-07\94107779 14 度為 者, 無特 射出 項為 部應 連接 合物 著樹 溫度 度為 物為 料等 成形 況、 部應 〇 、無 潤滑 成物 限定200537757 230 ~ 280 ° C The surface before IR reflow step for surface mounting is 0.09mm or less, and the flatness difference before and after reflow is 0.02mm or less. It can be said that it has excellent flatness in practice. The molding method for obtaining a connector having such excellent flatness is not limited, and an economical injection molding method is preferably used. In order to obtain a connector having such excellent flatness by molding, it is important to use the aforementioned liquid crystalline polymer composition, and it is preferable to select molding conditions without residual internal force. In order to reduce the filling pressure and reduce the residual internal stress of the device, the temperature of the cylinder of the forming machine is preferably above the melting point T ° C of the liquid crystal polymer. If the temperature of the cylinder is too high, the cylinder nozzle will be used as the fat is decomposed. Problems such as sticky wires occur, so the cylinder is T ° C ~ (T + 3 0) ° C, preferably T ° C ~ (T + 1 5) ° C. The mold temperature is preferably 70 to 100 ° C. If the mold temperature is low, it causes poor flow of the filling resin composition, which is not good, and if the mold temperature is too high, the problem of overflow occurs, which is not good. Regarding the injection speed, it is preferably 150 m m / s e c or more. If the injection speed is low, only the unfilled molded product may be obtained, or even if the completely filled molded product is obtained, the molded product has a high filling pressure and a large residual internal force, and may only obtain a connector with a poor flatness. (C) Additives such as nucleating agents, carbon black machine-burning pigments, antioxidants, stabilizers, plasticizers, agents, release agents, and flame retardants to the composite resin composition to impart desired characteristics The group is also included in the range of the (C) composite resin composition of the present invention. (Examples) Hereinafter, the present invention will be described in detail based on examples. However, the present invention is not 326 \ Patent Specification (Supplement) \ 94-07 \ 94107779 14 degrees, and there is no special injection term for the attachment linking tree temperature. The degree of forming is the same as the material, the part should be 0, and the non-lubricating product is limited.

200537757 於此。另外,實施例中之物性測定及試驗 行。 (1 ) 玻璃纖維之重量平均長度的測定 將樹脂組成物丸粒5克以6 0 0 °C加熱2 將灰化殘渣於5 %聚乙二醇水溶液中充分免 移至玻璃m,並以顯微鏡觀察玻璃纖維。 析裝置(Nireco(股)製LUZEX FS)測定玻璃 長度。另外,於影像解析時,將重疊的纖 Φ 纖維,應用求出各長度的子程序。另外, 玻璃纖維除外而進行測定。 (2) 表觀熔融黏度 使用 L = 2 0 m m、d = 1 m m 的毛細管式流變 製 Capilograph 1B 型),以溫度 360 °C、 並根據I S 0 1 1 4 4 3,測定表觀熔融黏度。 (3 ) 連接器平面度之測定 由樹脂組成物丸粒,以下述成形條件, 大小 39. 82mmx36. 82mmxlmm t、中央部 1 9 . 0 2 m m之開孔,且晶格部間距間隔1 . 2 ί 器(針腳孔數494pin)。 另外,閘極係使用來自樹脂滯留反面的 厚度為3 m m。 將所得之連接器靜置於水平桌上,並 Q u i c k V i s i ο η 4 0 4 P R 0 C N C影像測定機測定 此時,由連接器端面將0 . 5 m m之位置以1 0 326\專利說明書(補件)\94-07\94107779 15 係以下列方法進 小時,予以灰化。 >散後,以注射器 同時使用影像解 纖維的重量平均 維分離成各別的 將5 0 // m以下之 I (東洋精機(股) 剪切速度1 0 0 0 / s 射出成形出整體 具有 19.02mmx nm的平面狀連接 薄膜閘極,閘極 以 Mitutoyo 製 連接器之高度。 m m間隔測定,並 200537757 將最大高度與最小高度之差視為平面度。 更且,使用日本PULSE技術研究所製大型桌上型迴焊焊 接裝置R F - 3 0 0,以波峯溫度2 5 0 °C 、加熱時間5分鐘之條 件加熱後,以上述方法測定平面度,求出迴焊前後之平面 度之差。 [成形條件] 成形機:F A N U C α - 5 0 C (使用中徑長喷嘴) 汽缸溫度:3 5 0 °C - 3 5 0 °C - 3 4 0 °C - 3 3 0 °C (喷嘴)200537757 here. In addition, physical properties were measured and tested in the examples. (1) Determination of the weight-average length of glass fiber 5 g of resin composition pellets are heated at 600 ° C 2 The ashing residue is completely removed from the glass m in a 5% polyethylene glycol aqueous solution, and the microscope is Observe the glass fibers. An analysis device (LUZEX FS, manufactured by Nireco Co., Ltd.) was used to measure the glass length. In addition, during image analysis, the superimposed fibers Φ fibers are subjected to a subroutine for obtaining each length. In addition, it measured except glass fiber. (2) Apparent melt viscosity: Capilograph 1B with capillary rheology of L = 20 mm and d = 1 mm) was measured at a temperature of 360 ° C and according to IS 0 1 1 4 4 3 . (3) The connector flatness is measured from the resin composition pellets, with the following molding conditions, a size of 39. 82mmx36. 82mmxlmm t, an opening at the center of 19.2 mm, and a lattice interval of 1.2 ί device (pin hole number 494pin). The gate system uses a thickness of 3 mm from the reverse side of the resin retention. Place the obtained connector on a horizontal table, and measure it with a Q uick V isi ο η 4 0 4 PR 0. At this time, the position of 0.5 mm from the connector end surface is 1 0 326 \ Patent Specification (Supplements) \ 94-07 \ 94107779 15 It is ashed in the following way. > After dispersing, separate the weight average dimension of the image using a syringe while disintegrating the fiber to separate each I below 5 0 // m (Toyo Seiki Co., Ltd.) Shear speed 1 0 0 0 / s 19.02mmx nm plane-connected thin-film gate, the gate is the height of Mitutoyo connector. The mm interval is measured, and 200537757 regards the difference between the maximum height and the minimum height as the flatness. In addition, Japan PULSE Technology Research Institute The large tabletop reflow soldering equipment RF-300 was heated under the conditions of a peak temperature of 250 ° C and a heating time of 5 minutes, and then the flatness was measured by the above method, and the flatness difference before and after reflow was obtained. [Forming conditions] Molding machine: FANUC α-5 0 C (using a medium diameter nozzle) Cylinder temperature: 3 5 0 ° C-3 5 0 ° C-3 4 0 ° C-3 3 0 ° C (nozzle)

Φ模具溫度:8 0 °C 射出速度:200mm/sec 保壓力:2 9 MPa 填充時間:0 . 0 8 s e c 保壓時間:1 s e c 冷卻時間:5 s e c 螺桿迴轉數:1 2 0 r p m 螺桿背壓:0 . 5 Μ P aΦ Mold temperature: 8 0 ° C Injection speed: 200mm / sec Holding pressure: 2 9 MPa Filling time: 0. 0 8 sec Holding time: 1 sec Cooling time: 5 sec Screw revolutions: 1 2 0 rpm Screw back pressure : 0.5 Μ Pa

(4) 彎曲彈性率 使用 125mmxl2.7mmx0.8mm之射出成形片,根據 ASTM D 7 9 0測定。 <實施例1〜5及比較例1〜9 > 以下述條件,製作含有玻璃纖維之液晶性聚合物組成物 的上述試驗片,並且進行評價,得到表2所示之結果。 [製造條件] (使用成分) 16 326\專利說明書(補件)\94-07\94107779 200537757 •聚合物:液晶性聚合物丸粒(寶理塑料(股)製,V e c t r a E 9 5 0 i ),熔點3 3 5 °C、黏度3 0 P a · s的基質聚合物(3 5 0 °C , 以剪切速度1 0 0 0 / s測定),丸粒尺寸:約5〜3 m m x約3〜2 m m x約3〜1 m m •玻璃纖維 (1 ) 實施例1〜5、比較例1〜8所使用者: 旭Fiber Glass(股)製CS03JA419(纖維徑10"m之切斷 束纖維) 鲁 (2 )比較例9所使用者: 曰東紡(股)製P F 7 0 (纖維徑1 0 μ m、纖維長8 0 // m軋製纖 維) •潤滑劑:日本油脂(股)製U n i s t e r Η - 4 7 6 (複合設備) •擠壓機:日本製鋼所製,雙螺桿擠壓機 ΤΕΧ-30 α (螺桿 徑 32mm, L/D: 38.5) 擠壓機之螺桿概略示於圖3。(4) Flexural modulus of elasticity It was measured in accordance with ASTM D 790 using a 125 mmxl2.7mmx0.8mm injection molded sheet. < Examples 1 to 5 and Comparative Examples 1 to 9 > The above-mentioned test pieces of a liquid crystal polymer composition containing glass fibers were produced and evaluated under the following conditions, and the results shown in Table 2 were obtained. [Manufacturing conditions] (Ingredients used) 16 326 \ Patent specification (Supplement) \ 94-07 \ 94107779 200537757 • Polymer: Liquid crystal polymer pellets (manufactured by Polyplastics Co., Ltd., V ectra E 9 5 0 i ), A matrix polymer with a melting point of 3 3 5 ° C and a viscosity of 3 0 P a · s (3 5 0 ° C, measured at a shear rate of 1 0 0 0 / s), pellet size: about 5 ~ 3 mmx about 3 to 2 mmx about 3 to 1 mm • Glass fiber (1) Examples 1 to 5 and Comparative Examples 1 to 8 Users: CS03JA419 (Cut fiber bundle with fiber diameter 10 " m) manufactured by Asahi Fiber Glass Co., Ltd. Lu (2) User of Comparative Example 9: PF 7 0 (fiber diameter 10 μm, fiber length 8 0 // m rolled fiber) made by Tobo (Joint) • Lubricant: Made by Japan Grease (Stock) U nister Η-4 7 6 (composite equipment) • Extruder: Tex-30 α (screw diameter 32mm, L / D: 38.5) twin screw extruder made by Nippon Steel Co., Ltd. The outline of the extruder screw is shown in the figure 3.

主進料口 1 1 ·· C1 可塑化部1 2 : C 4〜C 5 (構成:由上游側順捏和、逆捏和,長 度 1 2 8 m m ) 側進料口 1 3 : C 5 混練部1 4 : C 6〜C 8 (構成:由上游側順捏和、垂直捏和、逆 捏和、逆旋溝、順捏和、逆捏和、逆旋溝,長度3 5 2 m m ) 對主進料口的進料器:日本製鋼所製螺桿式 Loss-in W e i g h t進料器 326\專利說明書(補件)\94-07\94107779 17 200537757 對側進料口的進料器: 丸粒樹脂:K - T R 0 N公司製螺桿式L 〇 s s - i n W e i g h t進料 器 玻璃纖維:曰本製鋼所製螺桿式Loss-in Weight進料器 (擠壓條件) 汽缸溫度:僅主進料口 1 1的汽缸C1為2 0 0 °C ,其他之汽 缸溫度均為3 5 0 °C。Main feed port 1 1 ·· C1 Plasticizing part 1 2: C 4 ~ C 5 (Composition: upstream kneading, reverse kneading, length 1 2 8 mm) Side feed port 1 3: C 5 kneading Section 1 4: C 6 ~ C 8 (Composition: Upstream side kneading, vertical kneading, counter-kneading, counter-rotating groove, counter-kneading, counter-kneading, counter-rotating groove, length 3 5 2 mm) Feeder of main feed port: Screw-type Loss-in W eight feeder made by Japan Steel Co., Ltd. 326 \ Patent Specification (Supplement) \ 94-07 \ 94107779 17 200537757 Feeder of contralateral feed port: Pill Granular resin: K-TR 0 N screw type L 〇ss-in W eight feeder glass fiber: screw-type Loss-in Weight feeder (squeeze condition) made by Japan Steel Co., Ltd. cylinder temperature: main feed only The cylinder C1 of the material port 11 is 200 ° C, and the other cylinder temperatures are 350 ° C.

模頭溫度:3 5 0 °CDie head temperature: 3 5 0 ° C

(組成物之混練及擠壓方法) 使用上述雙螺桿擠壓機,將液晶性聚合物之丸粒由主進 料口 1 1及側進料口 1 3供給,將潤滑劑由主進料口 1 1、玻 璃纖維由側進料口 1 3供給。於側進料口使用雙螺桿側進料 器供給,使液晶性聚合物丸粒、滑劑、玻璃纖維之比例為 如表1之比例般,使用重量進料器加以控制。螺桿迴轉數 及擠壓量為如表1般設定,並將自模頭1 6束狀吐出的嫁融 樹脂組成物以Tanaka製作所製Mesh Belt conveyer搬送, 同時以噴霧器之喷霧水冷卻後,取得經切割的丸粒。由此 丸粒以射出成形機製作上述試驗片,並且進行評價,取得 表2所示之結果。 另外,將實施例•比較例之各複合樹脂組成物中之玻璃 纖維的配合量和重量平均長度的關係描繪於圖1。 326\專利說明書(補件)\94-07\94107779 18 200537757(Composition and Extruding Method of Composition) Using the above-mentioned twin-screw extruder, pellets of the liquid crystalline polymer are supplied from the main feed port 11 and the side feed port 13 and the lubricant is fed from the main feed port. 1 1. Glass fiber is supplied from the side feed port 1 3. A twin-screw side feeder was used at the side feed port, so that the ratio of liquid crystal polymer pellets, lubricants, and glass fibers was as shown in Table 1, using a weight feeder to control. The number of screw revolutions and the amount of extrusion were set as shown in Table 1. The graft resin composition discharged from the die 16 in a bundle was transported by a Mesh Belt conveyer manufactured by Tanaka Manufacturing Co., Ltd. and cooled with spray water from a sprayer. Cut pellets. From the pellets, the test pieces described above were produced by an injection molding machine and evaluated, and the results shown in Table 2 were obtained. The relationship between the blended amount of glass fibers and the weight average length in each composite resin composition of Examples and Comparative Examples is shown in FIG. 1. 326 \ Patent Specification (Supplement) \ 94-07 \ 94107779 18 200537757

擠壓量 (kg/hr) t 1_ LO CO LO CO LO CO in CNI LO CN1 LO CO LO CNI LO CX1 LO CO LO οα LO CNI LO (N1 LO CNI LO CNI 1迴轉數 (rpm) 1_ 〇 ο ο CD 另 〇 ◦ 〇 〇 CD 另 〇> Ο 另 Ο Ο 茭 CZ> 來自側進料口 13的添加量 (重量%) 玻璃纖維 LO S LO CO LO CO LO CO LO 寸 s LO LO 1液晶性聚合物 CZD CO S LO 寸 LO CO S 1 1 LO LO 1 1 LO LO 1 11的添加量 1%) 潤滑劑 CO 〇 CO ◦· CO ◦· CO cz> CO ◦· CO ◦· CO 〇· CO ◦· CO ◦· CO ◦· CO 〇· CO CD CO CD CO 〇) 來自主進料口 (重: 液晶性聚合物 卜 σί οα 卜 卜 卜 卜 寸· 卜 CT) 卜 CO 卜 寸· CO 卜 σί 卜 cr! LO 卜 寸· LO 卜 卜 CO 卜 LO 實施例1 實施例2 實施例3 |實施例4 I |實施例5 1 比較例1 比較例2 P比較例3 |比較例4 1 1比較例5 比較例6 1比較例7 |比較例8 比較例9 61 6/,αοι 寸 6\Δ9寸 6\ipsi)#^^^*\9(Ne 200537757 表2 玻璃纖維 添加量 (重量» 玻璃纖維之 重量平均纖維長 (//m) 熔融黏度 (Pa · s) 迴焊前 之平面度 (mm) 迴焊前後 之平面度差 (mm) 彎曲彈性率 (GPa) 實施例1 40 320 40 0.073 0.009 16.2 實施例2 40 190 36 0.059 0.003 15.6 實施例3 40 226 31 0.048 0.002 15.6 實施例4 45 264 37 0.083 0.009 18.5 實施例5 50 255 39 0.083 0. 007 20.0 比較例1 30 214 32 0.061 0.045 14.0 比較例2 35 370 57 0.073 0.021 17.8 比較例3 35 430 59 0.069 0.027 17.9 比較例4 35 229 32 0.067 0.102 15.8 比較例5 40 397 56 0.092 0.010 19.4 比較例6 45 359 60 氺 氺 20.5 比較例7 50 315 67 * 氺 20.9 比較例8 55 305 80 氺 氺 22.0 比較例9 40 80 57 0.072 0.088 15.5 *因流動性差故僅得到未填充的成形品。Extrusion (kg / hr) t 1_ LO CO LO CO LO CO in CNI LO CN1 LO CO LO CNI LO CX1 LO CO LO οα LO CNI LO (N1 LO CNI LO CNI 1 revolutions (rpm) 1_ 〇ο ο CD 〇◦ 〇〇CD 〇 > 〇 〇 〇 茭 CZ> Addition amount (% by weight) from side feed port 13 Glass fiber LO S LO CO LO CO LO CO LO inch s LO LO 1 Liquid crystal polymer CZD CO S LO inch LO CO S 1 1 LO LO 1 1 LO LO 1 11 1%) Lubricant CO 〇CO ◦ CO ◦ CO cz > CO ◦ CO ◦ CO 〇 CO ◦ CO ◦ · CO ◦ · CO 〇 · CO CD CO CD CO 〇) From the main feed port (weight: liquid crystal polymer σσ οα Β 卜卜卜 寸 · 卜 CT) 卜 CO 卜 inch · CO 卜 σί 卜 cr! LO 寸 · LO CO CO 卜 LO Example 1 Example 2 Example 3 | Example 4 I | Example 5 1 Comparative Example 1 Comparative Example 2 P Comparative Example 3 | Comparative Example 4 1 1 Comparative Example 5 Comparative Example 6 1Comparative example 7 | Comparative example 8 Comparative example 9 61 6 /, αοι inch 6 \ Δ9 inch 6 \ ipsi) # ^^^ * \ 9 (Ne 200537757 Table 2 Glass fiber addition amount (weight »glass fiber weight average Fiber length (// m) Viscosity (Pa · s) Flatness before re-welding (mm) Flatness difference before and after re-welding (mm) Flexural modulus (GPa) Example 1 40 320 40 0.073 0.009 16.2 Example 2 40 190 36 0.059 0.003 15.6 Implementation Example 3 40 226 31 0.048 0.002 15.6 Example 4 45 264 37 0.083 0.009 18.5 Example 5 50 255 39 0.083 0. 007 20.0 Comparative Example 1 30 214 32 0.061 0.045 14.0 Comparative Example 2 35 370 57 0.073 0.021 17.8 Comparative Example 3 35 430 59 0.069 0.027 17.9 Comparative Example 4 35 229 32 0.067 0.102 15.8 Comparative Example 5 40 397 56 0.092 0.010 19.4 Comparative Example 6 45 359 60 氺 氺 20.5 Comparative Example 7 50 315 67 * 氺 20.9 Comparative Example 8 55 305 80 氺 氺 22.0 Comparative Example 9 40 80 57 0.072 0.088 15.5 * Due to poor fluidity, only unfilled molded products were obtained.

【圖式簡單說明】 圖1為示出本發明所規定之複合樹脂組成物中纖維狀填 充劑之配合量與重量平均長度之關係的區域之圖。 圖 2為示出實施例所形成之平面狀連接器之圖,(a)為 平面圖、(b)為右側面圖、(c)為正面圖、(d)為示出A部之 詳細圖、(e )為示出B部之詳細圖。另外,圖中之數值單位 為 m m 〇 圖3為示出實施例所使用之擠壓機的螺桿概略之圖。 【主要元件符號說明】 1 樹脂滯留 2 間距間隔 326\專利說明書(補件)\94-07\94107779 20 200537757 部之厚度 料口 化部 料口 部 口 裝置 3 晶格 11 主進 12 可塑 13 側進 14 混練 15 通氣 16 塑模 17 減壓[Brief description of the drawings] FIG. 1 is a diagram showing a region showing the relationship between the blending amount of the fibrous filler and the weight average length in the composite resin composition specified in the present invention. 2 is a view showing a planar connector formed in the embodiment, (a) is a plan view, (b) is a right side view, (c) is a front view, (d) is a detailed view showing Part A, (E) is a detailed diagram showing Part B. In addition, the numerical unit in the figure is m m. FIG. 3 is a diagram showing the outline of the screw of the extruder used in the example. [Description of main component symbols] 1 Resin retention 2 Pitch interval 326 \ Patent specification (Supplement) \ 94-07 \ 94107779 20 200537757 Thickness of the material mouth of the material mouth of the mouth of the mouth of the mouth of the mouth 3 device of the lattice 11 main entrance 12 plastic 13 sides Into 14 Mixing 15 Ventilation 16 Mould 17 Decompression

326\專利說明書(補件)\94-07\94107779 21326 \ Patent Specification (Supplement) \ 94-07 \ 94107779 21

Claims (1)

200537757 十、申請專利範圍: 1 . 一種平面狀連接器,其特徵為由在(A )液晶性聚合物 中配合有(B )纖維狀填充劑的(C )複合樹脂組成物(其中,配 合之(B )纖維狀填充劑的配合量與重量平均長度的關係滿 足以下區域(D )的規定内)所形成,於外框内部具有晶格構 造; [區域(D )] X軸為(B )纖維狀填充劑之配合量((C )複合樹脂組成物 # 中之重量% )、Y軸為(B )纖維狀填充劑之重量平均長度(// m ),且以下列(1 )〜(5 )之函數所包圍住區域: (1 ) X = 36 (2) X=53 (3) Y=160 (4) Υ-360 (5) Υ二( 1 8 2 2 2 /Χ)- 8 4. 4 4 ° 2 .如申請專利範圍第1項之平面狀連接器,其中,連接200537757 10. Scope of patent application: 1. A flat connector, characterized by (C) composite resin composition (B) with fibrous filler in (A) liquid crystal polymer (B) The relationship between the blending amount of the fibrous filler and the weight average length satisfies the following area (D), and has a lattice structure inside the outer frame; [Area (D)] The X axis is (B) The amount of the fibrous filler ((C) wt% in the composite resin composition #), the Y-axis is (B) the weight average length of the fibrous filler (// m), and the following (1) ~ ( 5) The area enclosed by the function: (1) X = 36 (2) X = 53 (3) Y = 160 (4) Υ-360 (5) Υ 二 (1 8 2 2 2 / Χ)-8 4 4 4 ° 2. As for the flat connector of the scope of patent application item 1, wherein the connection 器為晶格部之間距間隔2 m m以下、晶格部之厚度0 . 5 m m以 下、製品整體之高度5. 0 m m以下者。 3 .如申請專利範圍第1或2項之平面狀連接器,其中, (C )複合樹脂組成物使用L = 2 0 m m、d = 1 m m之毛細管式流變儀 以溫度3 6 0 °C 、剪切速度1 0 0 0 / s並且根據I S 0 1 1 4 4 3所測 定之表觀熔融黏度為55Pa· s以下。 4.如申請專利範圍第1或2項之平面狀連接器,其中, 經過以波峯溫度2 3 0〜2 8 0 °C之用以進行表面安裝之I R迴焊 22 326\專利說明書(補件)\94-07\94107779 200537757 步驟前的平面度為0.09mm以下,且迴焊前後之平面度差 0 · 0 2 m m 以下。 5 .如申請專利範圍第1或2項之平面狀連接器,其中 (C )複合樹脂組成物使用L = 2 0 m m、d = 1 m m之毛細管式流變 以溫度3 6 0 °C 、剪切速度1 0 0 0 / s並且根據I S Ο 1 1 4 4 3所 定之表觀熔融黏度為 5 5 Pa · s 以下,經過以波峯溫 230〜280 °C之用以進行表面安裝之IR迴焊步驟前的平面 為0.09mm以下,且迴焊前後之平面度差為0.02mm以下The device is one with an interval of less than 2 mm between the lattice parts, a thickness of less than 0.5 m m, and a height of the entire product of less than 5.0 m. 3. The flat connector according to item 1 or 2 of the scope of patent application, wherein (C) the composite resin composition uses a capillary rheometer with L = 20 mm and d = 1 mm at a temperature of 3 60 ° C The shear rate is 1 0 0 0 / s and the apparent melt viscosity measured according to IS 0 1 1 4 4 3 is 55 Pa · s or less. 4. As for the flat connector of item 1 or 2 of the scope of patent application, in which IR reflow soldering for surface mounting at a peak temperature of 2 3 0 ~ 2 0 0 ° C 22 326 \ Patent Specification (Supplement) ) \ 94-07 \ 94107779 200537757 The flatness before the step is 0.09mm or less, and the flatness difference before and after reflow is 0 · 0 2 mm or less. 5. For the flat connector of item 1 or 2 of the patent application scope, in which (C) the composite resin composition uses capillary rheology of L = 20 mm, d = 1 mm, with a temperature of 3 60 ° C, shear The cutting speed is 1 0 0 0 / s and the apparent melting viscosity according to IS 0 1 1 4 4 3 is 5 5 Pa · s or less. After IR reflow for surface mounting at a peak temperature of 230 ~ 280 ° C The plane before the step is 0.09mm or less, and the flatness difference before and after reflow is 0.02mm or less 23 326\專利說明書(補件)\94-07\9410777923 326 \ Patent Specification (Supplement) \ 94-07 \ 94107779
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