TW200410726A - High-colority composition of titanium oxide, coating compositions, cosmetic compositions and processes thereof - Google Patents
High-colority composition of titanium oxide, coating compositions, cosmetic compositions and processes thereof Download PDFInfo
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200410726 五、發明說明(1) 【發明所屬技術領域】 本發明係有關高虹彩色氧化鈦組成物;具體而言,係有 關於薄片狀基質表面被覆組成物,進而使該被覆鈦組成物 剝離,形成一種嶄新鈦組成物。本發明另有關配合上述剝 離組成物,以製作化妝品。詳細言之,此化妝品組成物使 用觸感滑潤、透明性自然、且其干涉作用可抑制色斑(肌 膚缺陷補正效果),並具UV防曬與光致變色 (photochromi c)效果 〇 母上被覆氧 澤之塗料, 輝度不足、 母為原料, 光澤塗料。 法處理,其 白色度均高 質。另為提 為基質,被 化鐵、 係屬習 色彩不 則能得 但合成 表面平 ,可作 高干涉 覆氧化 氧化鈦 知技術 夠鮮豔 透明度 雲母結 滑性反 為被覆 色輝度 鈦等薄 等金屬 。此種 、餘色 極高之 晶過硬 劣於天 氧化鈦 ,亦以 膜以作 【先前技術 於天然雲 產生珍珠光 塗料,具有 若以合成雲 優異之珍珠 若以通常方 其透明性與 光澤塗料基 片狀氧化硅 料0 氧化物,藉以 習知珍珠光澤 渾濁等缺點。 製品,可用作 ’易生劈理, 然雲母;但因 等薄膜之珍珠 片狀氧化鋁或 為珍珠光澤塗 但利用氧化鈦所 料,雖廣泛用於化 者為習知方法所製 著性、分散性等方 特有白色性、遮蔽紫 妝品、樹脂或紙類添 造之等粒狀微粒子, 面皆有缺憾。而片狀 外線等特徵之塗 加材,但因其利用 因此於塗布性、密 氧化鈦之製造方200410726 V. Description of the invention (1) [Technical field to which the invention belongs] The present invention relates to a high iridescent titanium oxide composition; specifically, it relates to a coating composition on the surface of a flaky substrate, and then the coated titanium composition is peeled off. Forms a brand new titanium composition. The present invention also relates to the preparation of a cosmetic by combining the above-mentioned peeling composition. In detail, this cosmetic composition uses smooth touch, natural transparency, and its interference effect can suppress pigmentation (skin defect correction effect), and has UV sun protection and photochromic c effects. Oxygen coating on the mother Paint, lack of brightness, base material, gloss paint. Method, its whiteness is high. In addition, as a substrate, the color of iron and iron is not available but the synthetic surface is flat. It can be used as a high interference titanium oxide coating technology. It is bright and transparent. Mica has a slippery property. It is coated with thin metals such as titanium. . This kind of crystal with extremely high after-color is too inferior to natural titanium oxide. It is also used as a film [previous technology to produce pearlescent coatings on natural clouds. The substrate-like silicon oxide is 0 oxide, so that the pearl luster and turbidity are known. Products can be used as' easy cleaving, but mica; but because of such films as pearl flake alumina or pearl gloss coating but using titanium oxide, it is widely used for chemical conversion by conventional methods , Dispersibility, and other characteristics of white particles, masking purple makeup, resin or paper and other granular particles, there are defects in the surface. Coating materials with sheet-like outer lines and other characteristics, but because of its use,
第6頁 200410726 五、發明說明(2) 法雖曰見於日本特許第2979132號等,但皆為不具光澤 及干涉色之氧化鈦。 处^彩係影響人類心理、生理之重要因素。為求活用色彩 月Γ =響人類身心之所及範圍,以創造安全、高效率之工作 環境’以及健康舒適之生活環境,遂將色彩學調整技術活 用於各個領域上。 ,二般而言,欲賦予物體色彩,係利用各種著色塗料。此 ,著色塗料係藉光之吸收、反射等現象以呈現各種不同色 彩’但光罪著色塗料,逐漸無法應付近年來增加之多樣化 感.性=及眾人要求。因此,將光干涉現象加入著色塗料 中’,有二氧化鈦被覆雲母等珍珠光澤塗料遂而誕生。此 珍珠塗料一大特徵,係隨觀察角度不同,其色調亦隨之變 化’此即所謂「變色龍效果(fl ip-flop)」。 此類珍珠光澤塗料,可用於化妝品、塗料、粘著劑、印 刷墨水、樹脂混合(inc〇rp〇rat i〇n)等這種領域;但卻明 顯存有下列缺點,例如··珍珠光澤塗料若以天然雲母、合 成雲母、氧化鋁、二氧化硅、硅酸玻璃、硼酸玻璃等薄片 狀、j狀粒子為核,後被覆二氧化鈦,藉控制該二氧化鈦 被覆里使其呈現具各種干涉色之珍珠光澤。若將此類珍珠 光澤塗料以外用組成物塗料用作化妝品、塗料、印刷墨 ,、粘著劑、樹脂混合上時,將產生粒子過厚無法形成超 薄膜’且粒子邊緣光散亂過強,無法有效發揮應有之「變 色龍效果」。 另’關於氧化鈦片狀粒子之合成,如特許第2979132號 第7頁 200410726 五、發明說明(3) η己載薄片狀氧化鈦,係於具大比面積之多孔質體上,使鈦 J鉋接觸氫氧溶液以使層狀結晶剥離、加#,後得薄片狀 氧化鈦。將鈦酸所得層狀結晶剝離至一層後,可得厚度僅 ,納米等級之超薄氧化鈦。但因厚度過薄,致使該薄片狀 氧化欽不具任何干涉色。 另,特開昭62-237936、特開昭62_247834、特開昭 = -213833號所記片狀氧化鈦,係將烷氧基金屬以溶膠-凝 ^方式(So 1 Ge 1 )附於輥箱後加熱,形成氧化物,再以 刮:將其自輥箱㈣,加熱燒成若干珍珠狀片狀氧化鈦; ^為^刮77剝_’粒子須呈捲曲狀,且粒子厚度係微米等 、、及’導致所有干涉色皆無法發色。 述習知 明色彩 使用觸 曬與光 上述問 成物時 被覆層 組成物 狀基質 之金屬 層添加 【發明内 本發明 越之輝度 鈦組成物 制色斑, 亦即本發 局虹彩色 物被覆層 新高虹彩 具體而 石型氧化 之被覆層 容】 為解決上 、以及鮮 ’達到高 並具UV防 明為解決 氧化鈦組 ,剝離該 色氧化欽 言,薄片 鈦為基礎 ,此被覆 問題,遂 ,且餘色 感、透明 致變色效 題,經深 ,其薄片 後即可得 〇 表面上, 氧化物, 驗化合物 以一種具干涉色新穎卓 不渾濁之高虹彩色氧化 性、且其干涉作用可抑 果。 入研究後,發現於製造 狀基質表面形成鈦組成 足以解決上述問題之嶄 形成以欽礦型或金紅 或金屬氫氧化物所被覆 後’即可得自薄片狀基Page 6 200410726 V. Description of the invention (2) Although the method is described in Japanese Patent No. 2979132, etc., it is all titanium oxide without gloss and interference color. Department of color is an important factor affecting human psychology and physiology. In order to make full use of color month Γ = to reach the range of human body and mind, to create a safe and efficient working environment ’and a healthy and comfortable living environment, we have applied chromatics adjustment technology to various fields. In general, in order to impart color to objects, various colored paints are used. Therefore, the colored paint is based on the absorption and reflection of light to show various colors. However, the light-sin paint has gradually failed to cope with the increasing sense of diversity in recent years. Therefore, the light interference phenomenon was added to the coloring paint ', and pearlescent paints such as titanium dioxide-coated mica were born. A major feature of this pearl paint is that the hue changes with different viewing angles. This is the so-called "fl ip-flop". This kind of pearl gloss coating can be used in such fields as cosmetics, coatings, adhesives, printing inks, resin blending (incorprat), but it has the following disadvantages, such as pearl gloss coatings If flake-shaped, j-shaped particles such as natural mica, synthetic mica, alumina, silica, silicate glass, and borate glass are used as the core, then titanium dioxide is coated, and the titanium dioxide coating can be controlled to show pearls with various interference colors. luster. If such a coating composition other than pearl gloss coatings is used as cosmetics, coatings, printing inks, adhesives, and resins, the particles will be too thick to form ultra-thin films, and the edges of the particles will be scattered too much. The "Chameleon effect" cannot be exerted effectively. In addition, on the synthesis of titanium oxide flake particles, such as Patent No. 2979132, page 7, 200410726 V. Description of the invention (3) η flake titanium oxide has been deposited on a porous body with a large specific area, so that titanium J The planer is brought into contact with the hydrogen and oxygen solution to peel off the layered crystals, and # is added to obtain a flaky titanium oxide. After exfoliating the layered crystals obtained from titanic acid into one layer, ultra-thin titanium oxide with a thickness of only nanometers can be obtained. However, because the thickness is too thin, the flaky oxide does not have any interference color. In addition, JP-A-Sho 62-237936, JP-A-Sho 62_247834, and JP-A-Sho = -213833 describe the flake-shaped titanium oxide in which an alkoxy metal is attached to a roll box by a sol-coagulation method (So 1 Ge 1). After heating, the oxide is formed, and then scraped: it is rolled from the roll box, and heated to form a number of pearl-like flakes of titanium oxide; , And 'cause all interference colors cannot be developed. It is known that the color uses the metal layer of the coating-like composition matrix when the above-mentioned objects are exposed to sunlight and light. [In the invention, the brighter titanium composition of the present invention makes color spots, which is the new highest level of the rainbow-colored material coating layer of the Bureau. Hongcai specific and stone-type oxidation coatings] To solve the problem of high and high UV protection, to solve the problem of titanium oxide group, stripping the color oxidation, thin film based titanium, this coating problem, and After-sense, transparent color-changing effect, after deep, it can be obtained after thin flakes. On the surface, the oxide and the test compound have a high iridescent color oxidation with a novel interference color and no turbidity, and its interference effect can be suppressed. fruit. After entering the research, it was found that the formation of a titanium composition on the surface of the manufactured substrate was sufficient to solve the above problems. The formation of the titanium substrate was covered with a chinite type or gold red or metal hydroxide.
第8頁 200410726 五、發明說明(4) — "" ' ---- 質表面所剝離之剝離組成物。此剝離組成物,能做為同時 具有理想光澤且發出干涉色之組成物。 亦即本發明所涉組成物,係自天然雲母、合成雲母、玻 璃薄片、二氧化硅薄片、氧化鋁薄片、硫酸鋇中:選一種 或二種,上薄片狀基質,以及於其表面被覆氧化鈦組成 物、或虱氧化鈦組成物所成。因此,高虹彩色氧化鈦組成 物之剝離組成物,係自該被覆組成物所剝離出之鈦組成 物。 、 關於上述剝離組成物之光澤;將壓克力系透明硝基漆3〇 部與上述剝離組成物1部加以混合,後用塗布機於白黑隱 蔽率試紙JISK5400上行4密耳塗布;後以堀場製光澤測定 。器IG-330型測試該隱蔽率試紙之黑底,求其光澤值於6〇 °C下為55〜90。係一以光干涉作用進行發色之高虹彩氧化 欽組成物。 【實施方式】 本發明之高虹彩色氧化鈦組成物之被覆組成物,以及高 虹彩色氧化鈦組成物製法,係提供一種於薄片狀基質表 面,由氧化鈦、氫氧化鈦之鈦組成物所形成之被覆層組成 物’自該被覆層剝離厚所得剝離組成物,以及其製法。與 習知技術相異處在於,藉該特定條件所得之剝離組成物, 可用作化妝品等廣泛領域上,可藉光干涉作用得到前所未 有之高虹彩色發色。 本發明之高虹彩色氧化鈦組成物被覆組成物,如第i圖Page 8 200410726 V. Description of the Invention (4) — " " '---- Peeling composition peeled off from the surface. This peeling composition can be used as a composition that simultaneously has ideal gloss and emits interference colors. That is, the composition according to the present invention is selected from the group consisting of natural mica, synthetic mica, glass flakes, silica flakes, alumina flakes, and barium sulfate: one or two kinds are selected, the flake-shaped substrate is coated, and the surface is covered with oxidation It is made of titanium composition or titanium oxide composition. Therefore, the peeling composition of the high iridescent titanium oxide composition is a titanium composition peeled from the coating composition. About the gloss of the peeling composition; 30 parts of acrylic transparent nitro lacquer and 1 part of the peeling composition were mixed, and then coated with a coating machine on the white and black concealment rate test paper JISK5400 upward 4 mils; Horiba gloss measurement. The IG-330 type tester measures the black background of the concealment rate test paper, and finds its gloss value at 55 ~ 90 at 60 ° C. It is a high iridescent oxidant composition that develops color by light interference. [Embodiment] The coating composition of the high iridescent colored titanium oxide composition and the method for preparing the high iridescent colored titanium oxide composition of the present invention are provided on the surface of a flaky substrate and are composed of titanium oxide and titanium hydroxide. The formed coating layer composition 'is peeled from the coating layer to obtain a peeling composition, and a method for producing the same. It is different from the conventional technology in that the peeling composition obtained under the specific conditions can be used in a wide range of fields such as cosmetics, and can obtain unprecedented high-irid color hair color by light interference. The high rainbow colored titanium oxide composition coating composition of the present invention is shown in FIG. I
Μ 200410726 五、發明說明(5) 所不’薄片狀基質1表面含有以銳鈦礦型或金紅石型氧化 鈦為基礎之金屬氧化物或金屬氫氧化物被覆層2。為一具 光澤其特定厚度〇·〇5〜0.6//m之被覆組成物。範圍以 =〇〜70 0 為理想,若低於1〇〇 ,則後述剝離組 :過細,高虹彩色之干涉色發色過弱。弱基質粒子 V m,則尚虹彩色之干涉色發色過強,粒子即易帶有粗Μ 200410726 V. Description of the invention (5) The surface of the flaky substrate 1 contains a metal oxide or metal hydroxide coating layer 2 based on anatase or rutile titanium oxide. It is a coating composition having a gloss of a specific thickness of 0.05 to 0.6 // m. The range is preferably from 0 to 70 0. If it is less than 100, the peeling group described later is too thin, and the interference color of the high iridescent color is too weak. Weak matrix particles V m, the interference color of the iridescent color is too strong, and the particles are prone to be coarse
糙感。再者若處於100〜300 “瓜間,則光澤夠強且容 離。 J 具體而言,能符合此粒子徑範圍之薄片狀基質丨,以 ::雲母、合成雲母、玻璃薄片、二氧化硅薄片、、氧化鋁 比:硫酸鋇等為代表。二氧化娃薄片其形狀、纟面平滑性 白合易控制,再者,其表面均一被覆層2因易帶光澤,因 作為薄片狀基質1甚為理想。薄片狀基質1粒子厚度 .、,Ά限,但以〇.卜10 _為理想。粒子厚度若低於〇. VA Λ邊即易彎曲’導致被覆之氧化鈦、氫氧化鈦干 無法完全發揮。另,粒子厚度若超過10 _,則被 J於粒,平面、側面之氧化鈦、氫氧化鈦則與剝離之氧化 鈦、氳氧化鈦干涉色相異,導致全體干涉光澤不足。 亩,,2 氧化鈦、氫氧化鈦組成物,被 2 = =。以硫酸二氧化欽或四氯化欽可溶性水 Λ Λ 水分解所得者為理想。另,被覆層 ^止有一硅、氧化鋁、Zr、Ce、Ζη等補強劑,可提高 ί光性、剝離組成物粉碎強度。 各粒子之大小為UHL又則.Q2〜q,q4_為理Roughness. Furthermore, if it is between 100 ~ 300 ", the luster is strong enough and can be separated. J Specifically, a flaky substrate that can meet this particle diameter range 丨: Mica, synthetic mica, glass flakes, silicon dioxide The ratio of flakes, alumina: barium sulfate, etc. is representative. The shape and smoothness of the silicon dioxide flakes are easy to control. Furthermore, the uniform coating layer 2 on the surface is easy to be shiny, and it is used as a flaky substrate It is ideal. The particle thickness of the flaky substrate 1 is limited. However, it is preferable that the particle thickness is less than 0.1 Å. If the particle thickness is less than 0.5 VA, the edges are easily bent, and the coated titanium oxide and titanium hydroxide cannot be dried. Full play. In addition, if the thickness of the particles exceeds 10 mm, the particles will be treated, and the interference color of the titanium oxide and titanium hydroxide on the plane and side will be different from the peeled titanium oxide and titanium oxide, resulting in insufficient interference gloss. The composition of 2 titanium oxide and titanium hydroxide is 2 ==. It is preferably obtained by dissolving ammonium sulfate or ammonium tetrachloride in soluble water Λ Λ. In addition, the coating layer has only silicon, alumina, and Zr , Ce, Zn and other reinforcing agents can improve ί Resistance, crush strength release composition. The particle size of each of the UHL and .Q2~q, q4_ of Li
11^ 第10頁 200410726 五、發明說明(6) ------ 想之集,體,基質i粒子大小為3〇〇 ^^時,以〇 〇2 “之氧 化鈦或氫氧化鈦組成為最易剝離,基質i粒子大小為 m時,被覆層2即使為〇 · 〇 1 v m之細小粒子徑亦可輕易剝 離,基質1粒子徑小於100 ^^時,被覆層2粒子徑若無 # m則無法剝離。亦即基質丨粒子徑與被覆層2粒子徑互成 反比。 本發明中,先完成上述第丨圖所示被覆組成物,次而如 第2圖所示,自該被覆組成物剝離出被覆層2, 物2a。亦即本發明之高虹彩色氧化鈦組成物,係為〗 覆組成物被覆層2之金屬氧化物,或金屬氫氧化物為自薄 片狀基質1表面剝離所形成之剝離組成物2 a。 薄片狀基質1,可利用市售薄片狀粉體,或天缺φ母、 合成雲母、玻璃薄片、=氧化硅薄片、氧化鋁薄片'硫酸 鋇等。例如將印度片狀天然雲母置於大氣8〇〇它溫度下2小 時,後將燒成之片狀天然雲母浸於飲用水中5日,再以超 微粒磨碎機粉碎片狀天然雲母,經分級後即可得。 ^,剝離前先以水玻璃、有機二氧化石圭、可溶性紹鹽等 一乳化硅或鋁化合物被覆表面,待剝離被覆組成物後,可 得一耐候性良好且不彎曲之剝離組成物。 被覆組成物,如上所述,先於薄片狀基質丨表面被覆特 定厚度之氧化鈦或氫氧化鈦組成物直至發出光澤為止,此 即被覆層2^。其中以硫酸二氧化鈦或四氯化鈦可溶性水溶 液或鈦烷氧基金屬加水分解所得者為理想。欲得剝離組成 物時,須預先將被覆組成物經3〇〇〜8〇(rc燒成,置於鹼性 200410726 五、發明說明(7) 環境下(PH8以上),自薄板狀基質剝離出被覆層,得一無 捲曲且具優異平滑性之剝離組成物。 藉。此提高剝離組成物光澤與干涉色。若燒成溫度低於 30 0 °C ’剝離組成物粒子即有捲曲現象,若高於8〇〇 〇c,剝 離組成物之氧化鈦或氫氧化鈦即行凝集,造成剝離後光澤 與干涉色。低劣。剝離組成物經過濾、水洗、乾燥後,行 5 0 0 9 0 0 C燒成’以保持光澤、防止捲曲。$,其他剝離 後置處理,尚包括外覆氧化鐵、始、H納、_、著 色無機化合物,或有機塗料著色物,可藉各種公知方式實 類η"!式所得剝離組成物之高虹彩色鈦組成物,厚度 Γ fti〜〇·6”,又以光學厚度ο·1〜0·9㈣範圍為理 :、厘薄,即不易生成所欲干涉色;反之若組成物 =。 ”強度會因厚度而產生散亂,致使干涉強度低 紙高虹彩色鈦組成物塗布於紙帶上,將此塗布 係=第\表上。’其干涉色與欽組成物之幾何學厚度間關 藉散亂光仍可得色欽組成物粒子雖不-,但 狀ΐ整ΐί :中雷:彩色:組成物粒徑與薄板形 處於A+ 4财二射散亂徑之平均粒徑為“m,而以 —4厂111範圍内分布60%以上體積,其式7η〇/ Λ 度為理想’·另’關於薄板形狀,以掃晦式電 200410726 五、發明說明(8) — =声:率2_倍計算粒子數目時,薄板形與粒子接線, 厚度超過1· 5倍以上粒子數未滿1 0 %為理想。 為保持粒徑均一性,於調整薄片狀基質平^ =碎與分粒為理想。若選用天然雲母,以濕丄;: 者為佳祠眼之原礦石,後行水力淘析,以選擇均一性優異 更甚者,粒子徑平滑整齊之薄片狀基質表 物,剝離該鈦組成物之後’可使干涉色更為覆 i之被:剝離組成物’本發明高虹彩色氧化鈦組成 2接表面反射光入射、穿透同時,所反射之 太ϊ Υ涉,因位相差異即可得高虹彩色干涉色。 曰虹彩色氧化鈦組成物均一塗布於塗布面時,- 來自塗布面粒子表面之反射★,以及因屈折 色。此干涉色可藉被覆組成物之被覆層厚度加 (對照例1 ) 第8圖係本發明剝離組成物 光澤計分析結果圖表。&之氧化鈦組成物,經三次元 將本發明剝離組成物丨部,盥 如以混合,後用塗布機於白里隱Λ力糸透明硝基漆30部 密耳塗布;後對準隱蔽率試上行4 π…、底,以三次元光澤計 第13頁 $14 1200410726 五、發明說明(9) 間 以 GCMS-4型、入射角45。、反射角(測色角)〇〜75 每5 °為間隔進行測色,求其Lab。 其對照塗料,則使用德國默克(Merck )公司所製 Iriodin珠光塗料(以下簡稱Π0 225、219、235。自分析結 果可看出本發明氧化鈦組成物可表現廣泛之干涉色。 以下列舉具體製造範例,另,此製造例並不限於本發明技 術範圍。 (製造例1) 將印度片狀天然雲母1· 0公斤置於大氣8〇〇 t溫度下2小 時燃燒,冷卻後將此片狀天然雲母浸於飲用水j 〇升中,於 室溫下放置5日,後以增幸產業社製超微粒磨碎機處理該 片狀燒成天然雲母2回以行粉碎,將粉碎後之燒成天然雲 母移入谷篁50升之聚乙浠水槽中,加入QQ2%之六偏填酸 水溶液,總計45升。 以螺旋攪拌機攪拌,靜置5分鐘,將上層澄清液移至其 他容器,反覆此步驟3次,分粒出〇 ·丨mm以上大粒子,用標 準篩10網眼(800 //m)與65網眼(2〇3 /zm)進行篩選分粒,得 到10〜65網眼粒子徑150g。 之後將分粒後雲母150g加入硫酸鈦4〇〇g與飲用水4· 5升 中,以螺旋式攪拌機攪拌、溶解硫酸鈦。待其溶解後,攪 拌並同時加熱,於90 °C以上溫度行4小時加水分解處理。 冷卻後經水洗、濾過、1 5 0。(:乾燥。而後經3 〇 〇 t燒成2小 時。為觀察表面狀態取1部,以日.立(Hi tachi )S 21〇〇B型11 ^ Page 10 200410726 V. Description of the invention (6) ------ When the particle size of the desired set, body, matrix i is 300 × ^^, the titanium dioxide or titanium hydroxide group It becomes the easiest to peel off. When the particle size of the substrate i is m, the coating layer 2 can be easily peeled even with a small particle diameter of 0 · 〇1 vm. When the particle diameter of the substrate 1 is less than 100 ^^, the particle diameter of the coating layer 2 is not # m cannot be peeled off. That is, the particle diameter of the substrate 丨 and the particle diameter of the coating layer 2 are inversely proportional to each other. In the present invention, the coating composition shown in FIG. 丨 is completed first, and then as shown in FIG. The coating layer 2 and the product 2a are peeled off, that is, the high iridescent titanium oxide composition of the present invention is: the metal oxide or metal hydroxide of the coating layer 2 of the composition is peeled from the surface of the sheet-like substrate 1. The formed peeling composition 2 a. The flaky substrate 1 may be a commercially available flaky powder, or natural φ master, synthetic mica, glass flakes, silicon oxide flakes, aluminum oxide flakes, barium sulfate, etc. Indian flake natural mica is placed in the atmosphere at 800 ° C for 2 hours and then fired The flake-shaped natural mica is immersed in drinking water for 5 days, and then the flake-shaped natural mica is crushed by an ultra-fine particle mill, and can be obtained after classification. ^, Before peeling, use water glass, organic dioxide, and soluble salt. Wait for an emulsified silicon or aluminum compound to cover the surface, and after peeling the coating composition, a peeling composition with good weather resistance and no bending can be obtained. The coating composition, as described above, is coated with a specific thickness on the surface of the sheet-like substrate. The titanium oxide or titanium hydroxide composition until the gloss is emitted, this is the coating layer 2. Among them, a titanium sulfate sulfate or a titanium tetrachloride soluble aqueous solution or a titanium alkoxy metal hydrolyzed is ideal. When the composition is to be peeled off The coating composition must be calcined at 300 ~ 80 (rc and placed in alkaline 200410726. V. Description of the invention (7) under the environment (above pH 8), the coating layer is peeled from the thin plate-like substrate, and nothing is obtained. A peeling composition that is curled and has excellent smoothness. By this. This improves the gloss and interference color of the peeling composition. If the firing temperature is lower than 300 ° C, the peeling composition particles will curl, if it is higher than 8000c, the titanium oxide or titanium hydroxide of the peeling composition will agglomerate, causing gloss and interference color after peeling. Inferior. After filtering, washing and drying the peeling composition, firing at 5 0 0 9 0 C 'In order to maintain gloss and prevent curling. $, Other post-peeling treatments, including covering with iron oxide, starting, H nano, _, coloring inorganic compounds, or organic coatings, can be realized by various known methods η "! The high rainbow colored titanium composition of the peeling composition obtained by the formula has a thickness Γ fti ~ 〇 · 6 ", and the optical thickness ο · 1 ~ 0 · 9㈣ is the reason: thin, that is, it is not easy to generate the desired interference color; otherwise If the composition =. "The strength will be scattered due to the thickness, resulting in a low interference strength paper high iridescent titanium composition coated on a paper tape, and this coating system = the \ table. 'The interference color and the geometric thickness of the Qin composition can still be obtained through scattered light. Although the Qin composition particles are not-, but the shape is neat. :: Medium Thunder: Color: The particle size of the composition and the thin plate shape are in A + The average diameter of the scattered diameters of the four fortunes is "m", and more than 60% of the volume is distributed within the range of -4 plant 111. The formula 7η〇 / Λ degree is ideal. Electricity 200410726 V. Explanation of the invention (8) — = Acoustic: When the number of particles is calculated by 2 times, the thin plate shape is connected to the particles, and the thickness is more than 1.5 times and the number of particles is less than 10%. In order to maintain uniform particle size It is ideal to adjust the flaky substrate level ^ = crushing and granulation. If natural mica is used, wet soaking :: The original ore of Jiaci Eye, followed by hydraulic elutriation, to choose the one with better uniformity After the titanium composition is peeled off, the flaky substrate surface with a smooth and neat particle diameter can be used to 'cover the interference color: the peeling composition'. The high iridescent titanium oxide composition of the present invention is connected to the surface to reflect light incident and penetrate. At the same time, the reflected light is too involved, and high rainbow colors can be obtained due to phase differences. When the iridescent titanium oxide composition is uniformly coated on the coating surface,-the reflection from the particle surface of the coating surface ★, and the color due to inflection. This interference color can be added by the thickness of the coating layer of the coating composition (Comparative Example 1) Fig. 8 is a graph showing the analysis results of the gloss composition of the peeling composition of the present invention. For the titanium oxide composition, the peeling composition of the present invention is mixed in three dimensions, and then mixed with a coating machine, and then coated with a coating machine in Bailiyin糸 30 mils of transparent nitro lacquer; test the upward concealment rate by 4 π ..., bottom, based on three-dimensional gloss. Page 13 $ 14 1200410726 5. Description of the invention (9) with GCMS-4 type, incidence angle 45. Reflection angle (color measurement angle) 〇 ~ 75 Measure color at intervals of 5 °, and determine its Lab. For its reference coating, use Iriodin pearlescent coating (hereinafter referred to as Π0 225, 219, 235. From the analysis results, it can be seen that the titanium oxide composition of the present invention can exhibit a wide range of interference colors. Specific manufacturing examples are listed below, and this manufacturing example is not limited to the technical scope of the present invention. (Manufacturing Example 1) Indian tablets Natural Mica 1 · 0 kg was burned in the atmosphere at 8000 t for 2 hours. After cooling, this flake-shaped natural mica was immersed in drinking water 〇 liter, and left at room temperature for 5 days. The crusher processed the flaked calcined natural mica 2 times for pulverization. The pulverized calcined natural mica was transferred to a 50 liter polyacetic acid water tank of Gusao, and a 2% aqueous solution of hexamethylene partial filling in QQ was added, which totaled 45 liters. Stir with a spiral agitator, leave it for 5 minutes, move the upper clear liquid to other containers, repeat this step 3 times, and separate out large particles above 0 · 丨 mm, use a standard sieve 10 mesh (800 // m) and 65 The mesh (203 / zm) was screened and classified to obtain 150 g of 10 to 65 mesh particles. Thereafter, 150 g of the granulated mica was added to 400 g of titanium sulfate and 4.5 liters of drinking water, and the titanium sulfate was stirred and dissolved with a spiral mixer. After it is dissolved, stir and heat at the same time, and add water for 4 hours at a temperature above 90 ° C. After cooling, it was washed with water, filtered, and 150. (: Dry. Then fired at 300 t for 2 hours. Take one to observe the surface state and use Hitachi S 2100B type
第14頁 200410726 電子顯微鏡(SEM)放大20000倍觀察,其結果即如第4圖所 示,被覆組成物粒子徑為0.02//m之集合體。 # =水洗粉末加入10%之荷性鹼水溶液,調整為㈤丨丨後行 =潰靜置。以傾析法分粒上層浮離粉末,濾過並水洗分粒 叙末。將水洗分粒粉末加上硫酸銨8 · 3 2 5公克後溶解成5升 水溶液,後再加上羥氣化錘4公克與尿素18公克。螺旋攪 拌同時加熱,行5小時80。(:以上加水分解處理。冷卻後經 水洗、濾過、150 t乾燥。將此乾燥粉末置於大氣中行7〇〇 °C燒成2小時。得粉末14〇公克。Page 14 200410726 Observed at 20,000 magnification with an electron microscope (SEM). As a result, as shown in Figure 4, the aggregate of the coating composition has a particle diameter of 0.02 // m. # = Washing powder, add 10% alkaline alkaline solution, adjust it to ㈤ 丨 丨 and then go down = stand still. The powder was separated from the upper layer by decantation, filtered and washed with water. The washed and granulated powder was added with 8 · 3 2 5g of ammonium sulfate and dissolved into a 5 liter aqueous solution, followed by addition of 4g of hydroxyl gas hammer and 18g of urea. Spiral stir while heating for 5 hours and 80 minutes. (: The above is hydrolyzed. After cooling, it is washed with water, filtered, and dried at 150 t. This dried powder is placed in the air at 700 ° C for 2 hours to obtain 14 g of powder.
以理學電機社製X射線繞射儀MniFlex測定該粉末,其χ 光線繞射如第3圖C所示,幅度雖大但氧化鈦。另,以掃瞄 式電子顯微鏡(SEM)放大2000倍與20000倍之結果如第6圖 所示,呈薄片狀。板徑平均為10/zm ,板厚度°為〇.24/^。 將壓克力系透明硝基漆30部與1公克本品混合,後用塗布 機於白黑隱蔽率試紙JISK5400上行4密耳塗布,後以堀場 製光澤測定器IG-330型求得該黑底於6(rc下為85。苟The powder was measured with an X-ray diffractometer MniFlex manufactured by Rigaku Denki Co., Ltd., and its χ-ray diffraction was shown in FIG. 3C. Although the amplitude was large, the powder was titanium oxide. In addition, the scanning electron microscope (SEM) magnifications of 2000 and 20000 times are shown in Fig. 6 and are thin. The average plate diameter is 10 / zm and the plate thickness ° is 0.24 / ^. 30 parts of acrylic transparent nitro lacquer were mixed with 1 gram of this product, and then coated with a coater on a white and black concealment rate test paper JISK5400 upward 4 mils, and the black was measured with a RI-330 type gloss tester Base at 6 (85 at rc.
另為求得黑底色調角度依存性,因此用村上色彩研究 製3次元光澤度計GCMS-4型,以入射角度讪。、測^取九出 角〇 °〜75 °間,每隔5 °行測色。變換l · a · b /將色相吡 予以平面化,結果如第8圖所示,從綠色至青 a A5由日日辦、、承巴、監色 為求調查本品構成成分,取0.2公克正確秤量,並加 硫酸與硫酸銨,加熱後溶解。冷卻後再添加水£、趟酸0、入 屬銘,以還原鈦;冷卻後之硫氰酸鉀溶液作二二金 队邛馬指不劑,滴In order to obtain the angle dependence of the black background hue, Murakami Color Research made a three-dimensional gloss meter GCMS-4, and the angle of incidence was 讪. 2. Measure the angle between 0 ° and 75 °, and measure the color every 5 °. Transform l · a · b / flatten the hue phase. The result is shown in Figure 8. From green to blue a A5 is determined by the Japanese, Japanese, Japanese, Japanese, and Japanese. To investigate the composition of this product, take 0.2 g. Weigh correctly, add sulfuric acid and ammonium sulfate, and dissolve after heating. After cooling, add water £, acid 0, and enter the name to reduce titanium; the solution of potassium thiocyanate after cooling is used as a gold and silver alloy, drop
200410726 五、發明說明(11) 定硫酸銨鐵(ΙΠ)溶液,求得氧化鈦量(%)。其结果, 鈦為95· 0%。另,為使銨盥鈐宕旦 、 氧化 波長分散型螢光X射線分析裝置zsxl〇〇e型求得銨為 I 394· 40nm、鍅為343· 82nm,根據檢量線法予以定量。豆社 果銨與氧化銨之1· 15% ,且錘為氧化錘之丨· 〇8%。亦即了 ^ 品即為構成成分氧化鈦95·〇%、氧化銨為115%、 1. 08%之組成物。 馬 (製造例2 )200410726 V. Description of the invention (11) Determine the ammonium iron sulfate (III) solution, and determine the amount of titanium oxide (%). As a result, titanium was 95.0%. In addition, in order to oxidize ammonium, the wavelength-dispersed fluorescent X-ray analyzer zsx100e type was used to determine ammonium as I 394 · 40 nm and thorium as 343 · 82 nm, and quantified by the calibration curve method. Doushe 1.15% of fruit ammonium and ammonium oxide, and the hammer is 丨 · 08% of the oxide hammer. In other words, the product is a composition consisting of 95.0% titanium oxide, 115% ammonium oxide, and 1.08%. Horse (manufacturing example 2)
合成雲母(Toby工業製)之雷射徑為15〇〜65〇,平均徑 300 /zm,將10公斤放入容量6〇〇升之付蓋搪瓷水槽。加入 飲用水400升與氯化錫175公克與i摩爾/升硫酸水溶液, 調整為ρΗ1· 9。攪拌同時加熱,使溫度升至8〇 t後,用1/3 摩爾/升之四氣化鈦鹽酸水溶液與丨5%苛性鹼水溶液以保 持pH值,並以每分鐘0· 12公斤流速滴入四氯化鈦鹽酸水溶 液,進行1 0小時反應。 冷卻後,停止攪拌,傾析上層液體。將殘留粉末加上飲 用水400升後擾拌’加入15%苛性驗水溶液調整pjj至5〜7 5後遽過、水洗、以1 5 0 C乾燥。將乾燥粉末於大氣§ 〇 〇它 下燒成2小時。與製造例1相同,以SEM觀察其表面狀態, 發現其被覆粒子大小為0.016 /zm之集合體。 將燒成粉末浸潰於pH 1 2之碳酸鈉水溶液4〇 〇升中,5曰後 以螺旋充分授拌’加入六偏麟酸驗2%水溶液2升後授拌。 均勻分散後’以傾析法分離上層粉末。反覆此步驟以回收Synthetic mica (manufactured by Toby Industrial) has a laser diameter of 150-650, an average diameter of 300 / zm, and puts 10 kg into a covered enamel sink with a capacity of 600 liters. Add 400 liters of drinking water and 175 g of tin chloride and 1 mol / L sulfuric acid aqueous solution to adjust to ρΗ1.9. Stir and heat at the same time to raise the temperature to 80t, then use 1/3 mol / l of a tetrahydrogenated titanium hydrochloric acid aqueous solution and a 5% caustic aqueous solution to maintain the pH value, and drip in at a flow rate of 0.12 kg per minute A titanium tetrachloride aqueous hydrochloric acid solution was reacted for 10 hours. After cooling, the stirring was stopped and the upper liquid was decanted. Add the remaining powder with 400 liters of drinking water and stir it 'and add 15% caustic test solution to adjust the pjj to 5 ~ 75. After that, rinse, wash and dry at 150 ° C. The dried powder was fired in the atmosphere for 2 hours. As in Production Example 1, the surface state was observed by SEM, and an aggregate having a particle size of 0.016 / zm was found. The sintered powder was immersed in 4000 liters of sodium carbonate aqueous solution at pH 12, and after 5 days, it was thoroughly mixed with a spiral ', and 2 liters of a 2% aqueous solution of hexametalic acid was added and mixed. After uniform dispersion ', the upper powder was separated by decantation. Repeat this step to recycle
&17 (12) 五、發明說明 上層粉末 將上層粉末經水洗、濾過後,將濾過之粉 主 2之苛性驗水溶液4〇〇升中,並以螺旋攪拌均勻括 水洗 狀態下加熱至8G°C,並將3摩爾/升^酸納水 ♦液與6N的鹽酸水溶液,以硅酸鈉水溶液每分鐘〇 流速連續添加2小時。待2小時成化後冷卻、濾過· 後,以150 °C乾燥、得18公斤粉末。 : = 相同,以同樣裝置測定X光線繞射。χ光線繞 射心果呈現金紅石型氧化鈦。SEM觀察則如第7圖所示係一 薄片狀、板徑平均15 //m、厚度〇· 45 //m。 、 與製造例1相同,以白黑隱蔽率試紙JISK54〇〇u及三次 元光澤度計予以測色,並進行組成分析。結果其^人 值為60。至80。,測色色調角度依存性介於黃綠色至綠 色、青綠色範圍間變化。另,組成分析結果,氧化鈦 8 8 · 5 %、二氧化硅則為1 〇. 3 %。 ' (製造例3 ) 將雷射徑50〜200 #m、平均140//ιη之玻璃薄片(日本 确子社製RCF1 40) 1公斤置入40升之琺瑯容器内,加入1〇 %硫酸鈦水溶液17升、〇·〇6莫爾/升之硫酸水溶液5升、 尿素100公克及飲用水10升,行螺旋攪拌並同時加熱至9〇 °C以上行6小時加水分解處理。 冷卻後反覆傾析水洗。加入1 〇 %荷性鈉與3〇升飲用水, 使pH值為8·8後加熱至80C。保持pH值同時以每分鐘〇〇15 200410726 五、發明說明(13)& 17 (12) V. Description of the upper layer powder After the upper layer powder was washed with water and filtered, the filtered powder was subjected to a caustic test solution of the main 2 in 400 liters, and heated to 8G ° with spiral stirring evenly under water washing C, and 3 mol / L sodium acid solution and 6N hydrochloric acid aqueous solution were added continuously at a flow rate of sodium silicate aqueous solution per minute for 2 hours. After 2 hours of cooling, it was cooled, filtered, and dried at 150 ° C to obtain 18 kg of powder. : = Same, X-ray diffraction is measured with the same device. The x-ray diffracted heart fruit showed rutile titanium oxide. The SEM observation was a thin sheet with an average plate diameter of 15 // m and a thickness of 0.45 // m as shown in Figure 7. In the same manner as in Manufacturing Example 1, the white and black concealment rate test paper JISK5400u and a three-dimensional gloss meter were used for color measurement and composition analysis. As a result, its human value was 60. Up to 80. The dependence of color measurement hue angle varies from yellow-green to green and cyan-green ranges. As a result of the composition analysis, the amount of titanium oxide was 88.5% and that of silica was 10.3%. '(Manufacturing example 3) 1 kg of glass flakes with a laser diameter of 50 to 200 #m and an average of 140 // ιη (RCF1 40 manufactured by Japan Kokuko Co., Ltd.) were placed in a 40-liter enamel container, and 10% titanium sulfate was added thereto. 17 liters of aqueous solution, 5.0 mol / L of sulfuric acid aqueous solution 5 liters, 100 grams of urea and 10 liters of drinking water, spiral stirring and heating to above 90 ° C at the same time for 6 hours and hydrolyzed. After cooling, it was decanted and washed repeatedly. 10% charged sodium and 30 liters of drinking water were added to bring the pH to 8.8 and then heated to 80C. Keep the pH value at the same time every minute 015 200410726 V. Description of the invention (13)
升=加入!莫爾/升之水玻璃水溶液〇 85升以及U 之硫I水溶液持續1小時,後行3小時熟成。 冷卻後與製造例1相同 S e Μ _致甘生π , 子為0.04…大粒Ξ。湖觀察其表面狀態,測得其粒 二後i分散液中加入1莫爾,升之碳酸鈉水溶液使 p八”二ΐ置4曰。後再以螺旋授拌行傾析法分離上層 H it反覆此步驟以回收上層澄清液中粉末。將 =二洗、過攄、150。。乾燥。乾燥後置於大氣 中以3 0 0 C k成1小時。得到粉末μ 〇公克。 :得光繞射結果,可知係闊銳鈦礦型eSE 結果’付知薄板狀形其板徑平均為8Μ、厚度為 m ° 與製造例1進行相同物性實驗。其結果可得知光澤測試 值為60。,且測色之色調角度依存性為介於紅紫色至紅 色.黃色範圍間變化。另外’從組成分析的結果來看,可 得知乳化鈦係70 %、二氧化硅2. 8 %,且另有水分。 (製造例4 ) 將印度製片狀天然雲母以製造例丨相同條件於以解碎分 級。將此雲母lkg裝入40升之琺瑯容器中,加入1〇%硫酸 鈦水溶液17升、〇· 06莫爾/升之硫酸水溶液5升、尿素 100g及飲用水10升,行螺旋攪拌,加熱至9〇()(:以上後 小時加水分解處理。 冷卻後,經水洗、濾過。加入10%荷性訥水溶液與飲用 第18頁 200410726 五、發明說明(14) --- 水30升。,將液體pH值保持於1〇狀況下,以氮氣行攪拌並加 熱至80 °C。保持pH與溫度下加入〇· 5莫爾/升之硫酸第一 鐵水溶液0 · 2升、1 〇 %荷性鈉水溶液,且以每分鐘〇 〇 1 4升 之流速持續加入硫酸第一鐵水溶液丨5分鐘。再以氮氣持續 換氣5小時。 、、 披覆粒子 冷卻後,與製造例1相同以SEM觀察表面狀態 大小為0.04/ΖΠ1,甚有o.gem之粒子散佈表面£ 於熟成後之分散液中加入丨莫爾/升之碳酸鈉水溶液,使 其pH值為12,放置4日。後再以螺旋攪拌行傾析法分離上 層澄清液之粉末。反覆此步驟以回收上 f : ^ ^ μ „ ^ ^ 5 〇 t 〇 £ Λ 軋中以5 0 0 C燒成1小時。得到粉末6 5 〇公克。 所得粉末以X光繞射結果,可知係闊銳鈦礦型與氧化 Fe203 ) 。SEM觀察結果,得知薄板狀形其板徑平均為8 、厚度為〇.36#m。與製造例i進行相同物性實驗。复 光澤測試值為60。,且測色之色調角度依存性 , 兔色至紅色.黃色範圍間變化。另外,從組成分 析的結果來看,可得知有氧化鈦99 %、氧化鐵i %。 本:月中’以上述方式製造之剝離組成物,彳 ::另’化妝品之剝離組成物配合量,以05〜50重量; 為:4二配合量未滿5重量%時’缺乏抑制色斑之效果。 ^,超過50重量%時則其紅彩色過強,亦不理想。 本發:::作例如護膚霜、粉底、防曬乳液、粉底霜、 4、乾私餅、眼線筆、腮紅、〇紅、指甲油等皮膚用化Liter = Add! Moore / liter of water glass aqueous solution. 85 liters and U of sulfur I aqueous solution were continued for 1 hour, and then matured in 3 hours. After cooling, it was the same as that in Production Example 1. S e M _ induced Gansheng π, the seed was 0.04 ... The surface state of the lake was observed. It was measured that 1 mol was added to the i-dispersion of the granules, and the sodium carbonate solution was added to make the p-8 "disulfonate 4. Then, the upper layer was separated by decantation with a spiral mixing method. Repeat this step to recover the powder in the clear solution of the upper layer. It will be washed twice, rinsed, and dried at 150 ° C. After drying, it will be placed in the air at 300 C for 1 hour. The powder will be μg. The results show that the broad anatase type eSE result is that the thin plate-like shape has an average plate diameter of 8M and a thickness of m °. The same physical property test was performed as in Manufacturing Example 1. As a result, the gloss test value was 60. The hue angle dependency of the color measurement ranges from red-purple to red-yellow. In addition, from the results of the composition analysis, it can be seen that the emulsified titanium system is 70%, the silica is 2.8%, and (Production Example 4) The flake-shaped natural mica made in India was classified under the same conditions as in Production Example 丨 and pulverized. 1 kg of this mica was placed in a 40-liter enamel container, and 17 liters of a 10% titanium sulfate aqueous solution was added. · 06 mol / L of 5 liters of sulfuric acid aqueous solution, 100 g of urea and 10 liters of drinking water. Rotate to stir, heat to 90 () (: after the above hours, add water decomposition treatment. After cooling, wash with water and filter. Add 10% aqueous solution and drink, page 18 200410726 V. Description of the invention (14) --- Water 30 liters, maintaining the pH of the liquid at 10, stirring with nitrogen and heating to 80 ° C. Maintaining the pH and temperature, add 0.5 mol / L of sulfuric acid first iron aqueous solution 0.2 L, 10% sodium-aqueous aqueous solution, and the first ferric sulfuric acid aqueous solution was continuously added at a flow rate of 0.01 liters per minute for 5 minutes. The air was continuously vented with nitrogen for 5 hours. After the coated particles were cooled, the production examples were 1Same as observed by SEM. The surface state size is 0.04 / ZΠ1, and there are o.gem particles scattered on the surface. To the dispersion after ripening, add Moore / liter of sodium carbonate aqueous solution to make the pH value of 12, and place 4 Then, the powder of the upper clear liquid was separated by decantation with spiral stirring. Repeat this step to recover the upper f: ^ ^ μ „^ ^ 5 〇t 〇 £ Λ Calcined at 500 ° C for 1 hour during rolling. 650 g of powder was obtained. As a result of X-ray diffraction of the obtained powder, it was found that it was broad anatase Type oxide Fe203). As a result of SEM observation, it was found that the sheet-like shape had an average plate diameter of 8 and a thickness of 0.36 # m. The same physical property test was performed as in Production Example i. The complex gloss test value is 60. , And the hue angle dependence of the color measurement ranges from rabbit to red and yellow. From the results of the composition analysis, it was found that titanium oxide was 99% and iron oxide was i%. This: "Mid-month" peeling composition manufactured in the above-mentioned way, 彳 :: Another "cosmetic peeling composition compounding amount, 05 ~ 50 weight; for: 4 when the compounding amount is less than 5% by weight," lack of pigmentation inhibition The effect. ^, If it exceeds 50% by weight, the red color is too strong, which is also not ideal. Hair: :: For skin creams, foundations, sun lotions, foundation creams, 4, dry cakes, eyeliners, blushers, reds, nail polishes, etc.
獅410726 五、發明說明(15) 妝品,其型態並無特限。另,此類化妝品除 明之剝離組成物配合之外,其餘都與一般化 相同。 本發明之化妝品,除上述剝離組成物外, 上一般化妝品所配合使用之粉體(塗料、色 油、介面活性劑、FU素化合物、樹脂、酒精 合物、紫外線防禦劑、抗氧化劑、黏劑、防 保濕劑、生理活性成分、鹽類、溶劑、螯合 pH調整劑、水、以及其他成分等。 以粉體為例,如紅色104號、紅色2〇1號、 色1號、黑色401號等色素,黃色4號“胭脂、 胭脂等胭脂色素,尼龍粉、絲粉、酯粉、特 粉 '纖維素粉、硅合成橡膠、幾丁質、殼聚 等高分子、黃氧化鐵、紅氧化鐵、黑氧化鐵 ,、群青、柑青等著色塗料、氧化鈦、氧化 等白色塗料、滑石、雲母、絹雲母、陶土、 鋁、氧化硅、碳酸鈣、碳酸鎂、硅酸鋁、硅 料、微粒子氧化鈦、微粒子氧化亞鉛、微粒 紫外線防禦粉體、雲母鈦等珍珠塗料、皂土 此類粉體形狀、大小並無特限。 X另二上述粉體,可以習知各種方式進行表 聚硅氧烷處理、硅烷處理、氟素化合物處理 理、蠟處理、脂肪酸處理、N_醯化賴氨酸處 分子化合物處理、樹脂處理、等離子處理、 了和上述本發 妝品製造方式 另可應需要加 素、樹脂)、 類、高分子化 腐劑、香料、 劑、中和劑、 黃色4號、藍 黃色203號Ba 氟隆粉、硅 糖、褐藻酸鈣 、氧化鉻、黑 亞典、氧化鈽 硫酸鋇、氧化 酸鎂等體質塗 子氧化鈽、等 、蒙脫石等。 面處理,例如 、金屬皂處 理、水溶性高 機器化學處理Lion 410726 5. Description of the invention (15) There are no particular restrictions on the makeup. In addition, this type of cosmetics is the same as the general one except that the exfoliating composition is formulated. In addition to the above-mentioned peeling composition, the cosmetics of the present invention are powders (paints, color oils, surfactants, FU pigment compounds, resins, alcohol compounds, ultraviolet shielding agents, antioxidants, adhesives) used in general cosmetics. , Anti-humectants, physiologically active ingredients, salts, solvents, chelating pH adjusters, water, and other ingredients, etc. Take powders as examples, such as red 104, red 201, color 1, black 401 No. and other pigments, yellow No. 4 "rouge, rouge and other rouge pigments, nylon powder, silk powder, ester powder, special powder 'cellulose powder, silicone synthetic rubber, chitin, chitin and other polymers, yellow iron oxide, red Iron oxide, black iron oxide, coloring paints such as ultramarine, citrus, titanium oxide, white paints such as talc, mica, sericite, clay, aluminum, silicon oxide, calcium carbonate, magnesium carbonate, aluminum silicate, silicon material , Fine particles of titanium oxide, fine particles of lead oxide, fine particles of ultraviolet defense powder, pearl paint such as mica titanium, bentonite and other powders are not limited in shape and size. X The other two powders can be learned in various ways. Table polysiloxane treatment, silane treatment, fluorine compound treatment, wax treatment, fatty acid treatment, molecular compound treatment at N-methylated lysine, resin treatment, plasma treatment, and the above-mentioned manufacturing method of the hair cosmetic Can be added with vegetarian, resin), kind, polymerized preservatives, flavors, agents, neutralizers, yellow No. 4, blue-yellow No. 203 Ba Fluoron powder, silicon sugar, calcium alginate, chromium oxide, heya Physical coatings such as dysprosium oxide, barium sulfate, barium sulfate, magnesium oxide, etc., thoron oxide, etc., montmorillonite, etc. Surface treatment, for example, metal soap treatment, water-soluble high-mechanical chemical treatment
第20頁 200410726Page 20 200410726
油,可分為流動石蠟、三十碳烷、2-乙基己醇十六烷 基、十四烷酸異丙基、撖欖油、芘麻油等液體油、凡士 ,、固體石蠟、牛脂、含水羊毛脂、密蠟、鯨蠟、膽巢醇 等半固體〜固體脂,鯨蠟醇、22烷醇等高級醇、棕搁酸、 甘油三硬脂酸酯等高級脂肪酸、聚硅氧烷系油劑、 烷誘導體等。 土乳 介面活性劑,可分為山梨糖醇酐脂肪酸酯、甘油脂肪酸 S旨、聚壤氧乙烯(以下簡稱Ρ0Ε)、山梨糖醇酐脂肪酸s旨、 Ρ0Ε甘油脂肪酸酯、P0E烷基醚、p〇E聚環氡丙烯烷基醚、 Ρ0Ε聚環氧丙烯協體、P0E烷基苯基醚、p〇E硬化毘麻油、 聚乙二醇脂肪酸酯、十甘油脂肪酸醇、烷基二乙醇胺等非 等離子性介面活性劑、烷基硫酸鹽、p〇E烷基醚硫酸鹽、 Ρ0Ε烷基醚醋酸鹽、烷基磷酸鹽、p〇E烷基醚磷酸鹽、高級 脂肪酸鹽、高級脂肪酸加水分解膠元鹽、氨基酸系負離子 性介,活性劑、卵磷脂、醋酸甜菜鹼系等兩性介面活性 劑、氯化烷三甲基銨、氯化二烷基二甲基銨、氯化二烷基 二甲基戊基銨等正離子性介面活性劑。 土 醇,可分為乙醇、丙醇、苯甲醇等一價醇,丨,3 丁 醇、丙二醇、一縮二丙二醇、 醇等多價醇。 丙三醇、聚乙二醇、山梨糖 高分子化合物,可分為聚乙烯比咯烷酮、乙烯基比各烷 酮醋酸乙烯聚合物、丙烯基樹脂烷醇胺、醋酸乙烯基丁烯 酸聚合物、曱基乙烯醚順丁烯二酸單烷基酯聚合物、N—曱Oil, can be divided into liquid paraffin, tridecane, 2-ethylhexanol hexadecyl, isopropyl myristate, olive oil, ramie oil and other liquid oils, petrol, solid paraffin, tallow , Semi-solids such as lanolin, dense wax, cetyl wax, and cholic alcohol ~ solid fats, higher alcohols such as cetyl alcohol and 22 alkanol, palmitic acid, higher fatty acids such as glyceryl tristearate, polysiloxane Oil-based agent, alkane inducer, etc. Soil emulsion surfactants can be divided into sorbitan fatty acid esters, glycerol fatty acid S, polyoxyethylene (hereinafter referred to as POE), sorbitan fatty acid s, POE glyceryl fatty acid esters, and POE alkyl ethers. , POE polycycloalkylene alkyl ether, POE polyoxypropylene synergist, POE alkyl phenyl ether, POE hardened vitex oil, polyethylene glycol fatty acid ester, ten glyceryl fatty acid alcohol, alkyl di Non-plasmonic surfactants such as ethanolamine, alkyl sulfates, POE alkyl ether sulfates, POE alkyl ether acetates, alkyl phosphates, POE alkyl ether phosphates, higher fatty acid salts, higher fatty acids Hydrolyzed colloidal salts, amino acid-based anionic agents, active agents, lecithin, betaine acetate and other amphoteric surfactants, alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, and dioxane chloride Positive ionic surfactants such as dimethyl pentyl ammonium. The tertiary alcohol can be divided into monovalent alcohols such as ethanol, propanol, benzyl alcohol, and polyvalent alcohols such as 3-butanol, propylene glycol, dipropylene glycol, and alcohol. Glycerol, polyethylene glycol, and sorbose polymer compounds can be divided into polyvinyl thanrolidone, vinyl than each alkanone vinyl acetate polymer, acrylic resin alkanolamine, vinyl butyrate polymerization Polymer, fluorenyl vinyl ether maleic acid monoalkyl ester polymer, N-fluorene
IM 第21頁 Γ4 / / 200410726 五、發明說明(17) 基丙烯酰乙基-N、N-二甲 基丙烯酸烷酯聚合物、二 二甲基氨基乙基甲基丙烯 基鄰苯二甲酸銨氣、缓基 鹽、羥乙基纖維素等。& 除上述成分外,另可加 羥基苯、對氨基笨酸等紫 甲苯等抗氧化劑、笨氧基 烯等殺菌劑、膠原、頌等 檬酸納等p Η調整劑、植物 劑、氣化鈉等無機鹽、螯 以下,就代表性實施例 本發明之技術範圍内。且 明,皆以質量%為單位。 發=所用效果實驗方法加 實驗方法:評價項目分 肌膚缺陷(細紋、色斑等 使用测試。基於以下所列 (評價分數基準) 5分··非常優異。 基銨-α-Ν-甲基羧基甜菜鹼/甲 乙基硫酸乙烯基比各烷酮-Ν、Ν-酸聚合物、羧基乙基纖維素二甲 乙烯高分子、羧基甲基纖維素 上氨基 外線吸 乙醇等 蛋白質 抽出濃 舍劑、 加以說 化妝品 在正式 以說明 為滑順 )效果 基準合 酸、透明質 收劑、維生 防腐劑、異 加水分解物 縮液、氨基 色素、香料 明,另,該 配合量表示 說明實施例 〇 觸感、自然 ,由20位專 計各受驗者 酸等保溫劑、 素Ε、二丁經 丙基甲基環戊 、擰檬酸、檸 乙酸等消炎 等。 處方並不限於 ’若無特別標 之前,先就本 透明感、補正 業受驗者進行 評價。 4分 3分 2分 優異 普通 惡劣IM Page 21 Γ4 // 200410726 V. Description of the invention (17) Acryloylethyl-N, N-dimethacrylate polymer, dimethylaminoethylmethacrylammonium phthalate Gas, slow salt, hydroxyethyl cellulose, etc. & In addition to the above ingredients, antioxidants such as hydroxybenzene and p-aminobenzyl acid such as purple toluene, bactericides such as oxybenzene, collagen, sodium citrate such as sodium citrate, plant agents, gasification Inorganic salts such as sodium and the like are within the technical scope of the present invention with respect to representative examples. In addition, all are expressed in mass%. Hair = used effect test method plus test method: evaluation items are divided into skin defects (use of fine lines, stains, etc.). Based on the following (evaluation score criteria) 5 points ... Very good. Ammonium-α-Ν- 甲Extraction of proteins such as ethyl carboxy betaine / vinyl methyl sulphate than each alkanone-N, N-acid polymer, carboxyethyl cellulose dimethyl ethylene polymer, amino external absorption of ethanol on carboxymethyl cellulose, etc. (In addition, cosmetics are officially described as smooth.) The effect is based on acid, hyaluronic acid, vitamin preservatives, iso-hydrolysate shrinkage, amino pigment, and fragrance. In addition, the compounding amount indicates the description of the example. Tactile and natural, by 20 persons, anti-inflammation agents such as acid, heat preservation agent E, dibutyl via propylmethylcyclopentane, citric acid, citric acid and so on. The prescription is not limited to ‘If there is no special mark, evaluate the subject of transparency and correction. 4 points 3 points 2 points Excellent Normal Harsh
200410726 五、發明說明(18) 1分:非常惡劣。 (評價基準) ◎:合計分數80分以上。 〇:合計分數60分以上,未滿80分。 △:合計分數40分以上,未滿60分。 X :合計分數未滿40分。 - 列於第1表實施例1〜2、對照例1〜2處方中之粉餅,與 第1表所示1〜12加以攪拌混合後,均一加熱混合後與13〜 2 0混合。粉碎所得混合物,以_容器成形後所調製而成。 第1表 實ί 酬 對照例 成分 1 2 1 2 1 滑石 9 9 9 9 2 雲母 10 10 10 10 3 絹雲母 18 18 18 18 4 合成雲母 15 15 15 15 5 本發明製造例3之剝離組成物 15 6 本發明製造例4之剝離組成物 15 7 硫酸鋇 5 5 5 5 8 氧化鈦 12 1 12 12 12 9 氧化鐵 4 4 4 4200410726 V. Description of the invention (18) 1 point: Very bad. (Evaluation criteria): A total score of 80 points or more. 〇: The total score is 60 points or more and less than 80 points. △: The total score is 40 points or more and less than 60 points. X: The total score is less than 40 points. -The powders listed in the formulations of Examples 1 to 2 and Comparative Examples 1 to 2 in Table 1 are stirred and mixed with 1 to 12 shown in Table 1, and then uniformly heated and mixed with 13 to 20. The obtained mixture was pulverized and prepared by forming a container. Table 1 shows the composition of the comparative example 1 2 1 2 1 Talc 9 9 9 9 2 Mica 10 10 10 10 3 Sericite 18 18 18 18 4 Synthetic mica 15 15 15 15 5 Peeling composition 15 of Production Example 3 of the present invention 15 6 Peeling composition of Production Example 4 of the present invention 15 7 Barium sulfate 5 5 5 5 8 Titanium oxide 12 1 12 12 12 9 Iron oxide 4 4 4 4
第23頁 200410726 五、發明說明(19) 10 氧化鈦被覆雲母(紅干涉) 15 11 氧化鈦被覆雲母(黃干涉) 15 12 氮化硼 2 2 2 2 13 凡士林 2 2 2 2 14 二甲基聚硅氧烷 3 3 3 3 15 液體石蠟 2 2 2 2 16 三異辛酸甘三醇 2 2 2 2 17 倍半異硬脂酸甘三醇 1 1 1 1 18 防腐劑 適量 適量 適量 適量 19 防氧化劑 適量 適量 滴量 卜適量 20 香料 適量 適量 適量 適量 上述實施例1〜2,對照例1〜2之感官實驗評價結果列於第 2表。 另,表中所列光致變色效果,印有◎表示非常高,x則無。Page 23 200410726 V. Description of the invention (19) 10 Titanium oxide-coated mica (red interference) 15 11 Titanium oxide-coated mica (yellow interference) 15 12 Boron nitride 2 2 2 2 13 Vaseline 2 2 2 2 14 Dimethyl poly Silicone 3 3 3 3 15 Liquid paraffin 2 2 2 2 16 Glycerol triisooctanoate 2 2 2 2 17 Glycerol semi-isostearate 1 1 1 1 18 Preservatives moderately moderately moderately 19 Antioxidants moderately Appropriate amount of drop, appropriate amount of 20, appropriate amount of perfume, appropriate amount, and appropriate amount of the above-mentioned Examples 1 to 2, and the results of sensory experiment evaluation of Comparative Examples 1 to 2 are listed in Table 2. In addition, the photochromic effects listed in the table are marked with ◎ to indicate very high, and x is not.
第2表Table 2
實施例 對照例 1 2 1 2 滑順使用觸感 ◎ ◎ 〇 〇 自然透明感 ◎ ◎ X X 可抑制色斑之干涉作用 (肌膚缺陷補正效果) 〇 〇 〇 〇 光致變色效果 X ◎ 1 X X 第24頁 200410726 五、發明說明(20) 從第2表可知,配合本發明製造例3、製造例1以及製造例4 之實施例2,其剝離組成物擁有滑順使用處趕及自然透明 感’且干涉作用能有效抑制色斑(肌膚缺陷補正效果)’ 另,實施例2尚且具優異光致效果。 另方面,以氧化鈦被覆雲母代替本發明剝離組成物之對照 例1、對照例2,其滑順使用觸感、自然透明感、光致效果 皆惡劣’可得知無法發揮本發明效果。 以下就各種處方列出本發明化妝品之實施例。另對此類化 妝品進行上述感官實驗,得所有實施例之本發明化妝品皆 具優異效果。 實施例3 固體粉餅 配合j ^ -- 配合量(質量%) — 1 聚硅氧烷處理絹雲母 15 2 1 硅氣院-- 15 - 3 秦硅氧院~ ^ 一 " 4 涵明iSSUggpir離組成—- T5 ' --- 5 砂處理球狀硅 ' 5 " ~- 6 mm^ - 2---~ 7 Wmmmm ~ -- To 一 — 8 访處理微粒子氧化鈦 7 7 --- 9 矽處理氧化鐵 4 - 10 \5 ——---Examples Comparative Examples 1 2 1 2 Smooth use and touch ◎ ◎ 〇〇 Natural transparency ◎ XX Can suppress the interference of pigmentation (skin defect correction effect) 〇〇〇〇Photochromic effect X ◎ 1 XX 24th Page 200410726 V. Description of the invention (20) As can be seen from Table 2, according to Example 2 of Manufacturing Example 3, Manufacturing Example 1 and Manufacturing Example 4 of the present invention, the peeling composition has a smooth use place and a natural and transparent feeling. Interference can effectively suppress pigmentation (skin defect correction effect) 'In addition, Example 2 has an excellent photo-induced effect. On the other hand, in Comparative Example 1 and Comparative Example 2 in which the titanium oxide-coated mica was used instead of the peeling composition of the present invention, it was found that the smooth feeling, the natural transparency, and the photo-induced effect were all poor. Examples of the cosmetics of the present invention are listed below for various prescriptions. In addition, the above-mentioned sensory experiments were performed on such makeup products, and it was found that the cosmetics of the present invention in all Examples have excellent effects. Example 3 Compounding of solid powder j ^-blending amount (% by mass) — 1 polysiloxane-treated sericite 15 2 1 silicon gas institute-15-3 Qin Silicon Oxygen Institute ~ ^ 一 " 4 Hanming iSSUggpir ion composition --- T5 '--- 5 Spherical silicon treated with sand' 5 " ~-6 mm ^-2 --- ~ 7 Wmmmm ~-To One— 8 Interview with fine particles of titanium oxide 7 7 --- 9 Silicon treatment Iron oxide 4-10 \ 5 ——---
200410726 五、發明說明(21) 11 三十碳院 3 12 二甲基聚硅氧烷 4 13 甲基苯基聚硅氧烷 3 14 辛甲基硅酸鹽 2 15 倍半異硬脂酸甘三醇 1 16 石蠟 適量 17 防氧化劑 適量 18 香料 適量 將1〜 以攪拌 體粉餅 1 0各成分予以混合粉碎,與11〜18成分混合後加 ,再將粉碎後所得者置入容器内填充成形,形成固 〇 實施例4 水中油性乳化化妝品 配合成分 配合量(質量%) 1 精製水 些許 2 丙二醇 4 3 丙三醇 2 4 偏磷酸鈉 適量 5 官土 1.5 5 氧氧化鉀 0.5 7 ; _酸 1.1 J 3 三甲基苯酸 1 ( ? \ 氧化鈦 10 [0 ' 1 氧化鐵 適量 1 [1 ; 东發明製造例4之剝離組成物 10 1 12 . ί 氣化鈦被覆板狀硫酸鋇 3 II 1 mi 第26頁 200410726 五、發明說明(22) 13 滑石 5 14 雲母 2 15 球狀硅 3 16 甘油一硬脂酸酯 1 17 單三甲基苯酸聚環氧山梨糖醇酐 0.5 18 十六醇 0.4 19 鯊肝醇 0.5 20 流動石鱲 5 21 二甲基聚硅氧院 5 22 對硅皮酸2-乙基 3 23 防腐劑 Μ量 24 香料 適量 將1〜5各成分均勻攪拌混合,加入6〜8中予以混合,再將 混合粉碎後之9〜1 5予以分散。加熱溶解後均勻添加1 6〜 2 5以行乳化,得水中油性乳化化妝品。 實施例5 油中水性乳化化妝品 配合J 或分 配合量(質量%) 1 聚硅氧烷處理纖維素粉 5 2 本發明製造例1之矽處理剝離組成物 12 3 聚硅氧烷處理氧化鈦被覆硫酸鋇 4 4 聚硅氧烷處理氧化鈦 10 5 聚硅氧烷處理氧化鐵 4 6 聚硅氧烷處理滑石 1 3200410726 V. Description of the invention (21) 11 Thirty Carbon Institute 3 12 Dimethyl polysiloxane 4 13 Methylphenyl polysiloxane 3 14 Octylmethylsilicate 2 15 Glyceryl hexisostearate 1 16 The right amount of paraffin 17 The right amount of antioxidant 18 The right amount of spices Mix and crush each component of 1 ~ 10 in agitated powder, mix with 11 ~ 18 and add, and then put the crushed product into a container and fill it to form a solid. Example 4 Compounding amount (mass%) of oily emulsified cosmetic ingredients in water 1 Refined water 2 Propylene glycol 4 3 Glycerol 2 4 Sodium metaphosphate 5 Amount of soil 1.5 5 Potassium oxyoxide 0.5 7 _Acid 1.1 J 3 Trimethyl Benzoic acid 1 (? \ Titanium oxide 10 [0 '1 Suitable amount of iron oxide 1 [1; Peeling composition 10 of East invention manufacturing example 4 1 12. Ί Titanium oxide coated plate-shaped barium sulfate 3 II 1 mi page 26 200410726 V. Description of the invention (22) 13 Talc 5 14 Mica 2 15 Spherical silicon 3 16 Glycerol monostearate 1 17 Monotrimethylbenzoic acid polyepoxide sorbitan 0.5 18 Cetyl alcohol 0.4 19 Squalol 0.5 20 Flowing stone concrete 5 21 Dimethyl polysiloxane 5 22 2-Ethylsilicic acid 3 23 Preservative M Amount 24 Fragrance Mix and mix 1 to 5 ingredients, add 6 to 8 After mixing, disperse 9 ~ 15 after mixing and dispersing. After heating and dissolving, evenly add 16 ~ 2 5 to emulsify to obtain oil-in-water emulsified cosmetics. Example 5 Water-in-oil emulsified cosmetics with J or partition Amount (% by mass) 1 Polysiloxane-treated cellulose powder 5 2 Silicon-treated peeling composition of Production Example 1 of the present invention 12 3 Polysiloxane-treated titanium oxide coated barium sulfate 4 4 Polysiloxane-treated titanium oxide 10 5 Polysiloxane-treated iron oxide 4 6 Polysiloxane-treated talc 1 3
第27頁 200410726 五、發明說明(23) 7 聚硅氧烷處理合成雲母 4 8 精製水 些許 9 一縮二丙二醇 8 10 十甲基環戊硅氧烷 25 11 十二甲基環六硅氧烷 15 12 二甲基聚硅氧烷 4 13 硅樹脂 2 14 聚醚變性硅 1.5 15 烷基·聚醚雙變性硅 0.5 16 二甲基苯酸 1 17 防涵劑 滴量 18 防腐劑 適量 將1 0〜1 8各成分均勻混合後加入1〜7各成分,混合粉碎後 加入分散。接著均勻混合溶解後加入8〜9予以乳化,填充 進容器後得油中水性乳化化妝品。Page 27 200410726 V. Description of the invention (23) 7 Polysiloxane-treated synthetic mica 4 8 Refined water 9 Dipropylene glycol 8 10 Decamethylcyclopentasiloxane 25 11 Dodecylcyclohexasiloxane 15 12 Dimethicone 4 13 Silicone resin 2 14 Polyether modified silicon 1.5 15 Alkyl polyether double modified silicon 0.5 16 Dimethyl benzoic acid 1 17 Anti-dropping agent amount 18 Preservative amount will be 1 0 ~ 18 Each ingredient is evenly mixed and 1 ~ 7 ingredients are added. After mixing and crushing, the ingredients are added and dispersed. Then, after mixing and dissolving uniformly, 8 to 9 are added for emulsification, and the water-in-oil emulsified cosmetic is obtained after filling into the container.
第28頁 200410726 五、發明說明(24) 實施例6 眼影 配合成分 配合量(質量%) 1 滑石 些許 2 絹雲母 6 3 合成雲母 12 4 球狀PMMA粉末 3 5 臟硫酸鋇 2 6 本發明製造例3之剝離組成物 8 7 氧化鐵 2 8 氮化硼 3 9 三十碳院 2 10 二甲基聚硅氧烷 2 11 單油酸山梨糖醇酐 1 12 防腐劑 適量 13 香料 適量 將卜8各成分混合粉碎、加上9〜13各成分混合後攪拌,於 中孤内成形即得眼影。 實施例7 油性粉底乳 配合j 成分 ΪΒ合量(質量%) 1 mm 1 2 小燭樹鱲 2 3 純地蠟 ΙΪ0 '~~ 4 三十碳烷 些許Page 28 200410726 V. Description of the invention (24) Example 6 Eyeshadow ingredients (mass%) 1 Talc slightly 2 Sericite 6 3 Synthetic mica 12 4 Spherical PMMA powder 3 5 Dirty barium sulfate 2 6 Production example of the present invention Peeling composition of 3 8 7 iron oxide 2 8 boron nitride 3 9 thirty carbon compound 2 10 dimethyl polysiloxane 2 11 sorbitan monooleate 1 12 appropriate amount of preservative 13 appropriate amount of fragrance 8 Mix and pulverize the ingredients, add 9 ~ 13 to mix the ingredients, stir, and shape in the middle of the orphan to get an eye shadow. Example 7 Oily foundation milk Compound j component ΪΒ combined amount (% by mass) 1 mm 1 2 candelilla 鱲 2 3 pure wax ΙΪ0 '~~ 4
第29頁 200410726 五、發明說明(25) 5 三異辛酸甘三醇 9 6 雙異硬脂酸甘三醇 11 7 高黏度二甲基聚硅氧烷 6 8 低黏度二甲基聚硅氧烷 5 9 硅樹脂 7 10 羥基丙基一々一環糊精 1 11 馬卡達姆堅果油脂肪酸膽巢基 3 12 硅酸鈉鎂 0.5 13 疏水性氧化硅 0.5 14 · 精製水 2 15 板狀硫酸鋇 2.5 16 本發明製造例4之剝離組成物 8 17 氧化鐵 2 18 防氧化劑 適量 19 防腐劑 適量 20 香料 適量 將加熱至7 0 °C之1 1,分散加入1 2〜1 3中,再將均勻溶解 之10加入14,充分攪拌。再加入另行加熱溶解之1〜9内後 充分攪拌,再加入15〜20後分散攪拌,最後置入容器中填 充成形為油性粉底乳。Page 29 200410726 V. Description of the invention (25) 5 Glycerol triisooctanoate 9 6 Glycerol diisostearate 11 7 High viscosity dimethylpolysiloxane 6 8 Low viscosity dimethylpolysiloxane 5 9 Silicone resin 7 10 Hydroxypropyl 1-cyclodextrin 1 11 Macadamia nut oil fatty acid cholester 3 12 Magnesium sodium silicate 0.5 13 Hydrophobic silica 0.5 14 · Refined water 2 15 Plate-shaped barium sulfate 2.5 16 The peeling composition of Manufacturing Example 4 of the present invention 8 17 Iron oxide 2 18 Antioxidant amount 19 Preservative amount 20 Fragrance amount Heat 1 to 70 ° C, disperse and add to 1 2 ~ 1 3, and dissolve evenly Add 14 to 10 and stir well. Add 1 ~ 9, which is heated and dissolved separately, and stir well. Then add 15 ~ 20, disperse and stir, and finally put it into a container and fill it to form an oily foundation milk.
第30頁 200410726 五、發明說明(26) 實施例8 口紅 K合成分 配合量(質量%) 1 聚乙烯蠟 1 2 純地蠟 2 3 含水羊毛脂 10 4 聚丁烯 些許 5 甲基苯基聚硅氧烷 9 6 二甲基聚硅氧烷 11 7 酯油 6 8 氧化鈦 5 9 紅色201號 7 10 紅色202號 1 11 紅色223號 3 12 球狀聚乙烯粉末 0.5 13 本發明製造例3之剝離組成物 0.5 14 防氧化劑 2 15 香料 2.5 將卜7加熱溶解後充分混合,將此液體加入8〜11,用三 輥混煉機加以混煉,將混煉漿加熱至80 °C後加入1 2〜1 5攪 拌混合,填充至口紅成形容器中即得口紅。Page 30 200410726 V. Description of the invention (26) Example 8 Synthetic distribution amount (mass%) of lipstick K 1 Polyethylene wax 1 2 Pure wax 2 3 Aqueous lanolin 10 4 Polybutene slightly 5 Methylphenyl poly Silicone 9 6 Dimethicone 11 7 Ester oil 6 8 Titanium oxide 5 9 Red 201 No. 7 10 Red 202 No. 1 11 Red 223 No. 3 12 Spherical polyethylene powder 0.5 13 Production Example 3 of the present invention Peeling composition 0.5 14 Antioxidant 2 15 Fragrance 2.5 Heat and dissolve Bu 7 and mix thoroughly, add this liquid to 8-11, knead with a three-roll kneader, heat the kneaded slurry to 80 ° C, and add 1 Stir and mix with 2 to 15 and fill the lipstick forming container to obtain lipstick.
第31頁 200410726 五、發明說明(27) 實施例9 防曬噴霧劑 配合J 紛 配合量(質量%) 1 聚硅氧烷處理微粒子氧化亞鉛 11 2 本發明製造例1之聚硅氧烷處理剝離組成物 12 3 十甲基環戊硅氧烷 18 4 氟化硅樹脂 6 5 硅彈性體球形糖 10 6 皂土 0.8 7 甲基苯基聚硅氧烷 35 8 二甲基聚硅氧烷 7.2 9 防腐劑 適量 將卜9各成分以分散器混合分散後,與不鏽鋼球一同填 充至容器内其可得成品。另,本產品須先搖晃再行使用。Page 31 200410726 V. Description of the invention (27) Example 9 Blending amount (mass%) of sunscreen spray with J 1 Polysiloxane-treated fine particles of lead oxide 11 2 Polysiloxane-treated peeling of Manufacturing Example 1 of the present invention Composition 12 3 Decamethylcyclopentasiloxane 18 4 Silicone fluoride resin 6 5 Silicon elastomer spherical sugar 10 6 Bentonite 0.8 7 Methylphenyl polysiloxane 35 8 Dimethyl polysiloxane 7.2 9 After preserving an appropriate amount of each component of Bu 9 in a disperser, it is filled with a stainless steel ball into a container to obtain a finished product. In addition, this product must be shaken before use.
實施例10 打底用固態乳液 配合j 戎分 配合量(質量%) 1 甲基苯基聚硅氧烷 5 2 山梨糖酐醇倍半異硬酯 1.5 3 異硬脂酸甘三醇 1.5 4 聚環氧乙烯二甲積聚硅氧烷甲基 0.2 第32頁 200410726 五、發明說明(28) 5 二甲基硅銅(低沸點) 26.4 6 二甲基硅銅(高沸點) 4.0 7 本發明製造例2之聚硅氧烷處理剝離組成物 2.0 8 聚硅氧烷處理氧化鈦 1.0 9 聚硅氧烷處理微粒子氧化鈦 6.0 10 聚硅氧烷處理絹雲母 2.0 11 聚硅氧烷雲母 6.0 12 球狀樹脂粉末 15.0 13 防氧化劑 適量 14 石鱲 4.4 15 精製水 15.0 16 1,3 丁二醇 5.0 17 防腐劑 適量 18 草木樨抽取液 5.0Example 10 Compounding amount (mass%) of a solid emulsion for priming 1 Methylphenylpolysiloxane 5 2 Sorbitan sesquiisostearyl 1.5 3 Glycerol isostearate 1.5 4 Poly Epoxy Dimethicone Siloxane Methyl 0.2 Page 32 200410726 V. Description of the Invention (28) 5 Dimethylsilicon copper (low boiling point) 26.4 6 Dimethylsilicon copper (high boiling point) 4.0 7 Production example of the present invention Polysiloxane-treated peeling composition of 2.0 2.0 8 Polysiloxane-treated titanium oxide 1.0 9 Polysiloxane-treated fine particles of titanium oxide 6.0 10 Polysiloxane-treated sericite 2.0 11 Polysiloxane-mica 6.0 12 Spherical resin Powder 15.0 13 Antioxidant amount 14 Shizhang 4.4 15 Refined water 15.0 16 1,3 Butanediol 5.0 17 Antiseptic amount 18 Herba extract 5.0
將卜6混合加熱至80 °C,加入7〜1 1後均勻攪拌分散。之 後加入1 2後分散,於另行製作出之1 6中,加入1 7,再加入 1 5使成均勻溶液,加入1 8後加熱至70 °C以形乳化。加入 1 3〜1 4後脫氣、填充至容器内冷卻即得成品。Mix Bu 6 and heat to 80 ° C, add 7 ~ 1 1 and stir evenly after adding. Then add 12 and disperse. In 16 prepared separately, add 17 and then add 15 to make a homogeneous solution. After adding 18, heat to 70 ° C to emulsify. Add 1 3 ~ 1 4 and degas, fill into the container and cool to obtain the finished product.
第33頁 200410726 五、發明說明(29) 實施例11 指甲油 配合j ^~' - 配合量(質量%) 1 硝酸纖維素 12 2 醇酸樹脂 10 3 棒檬酸乙三酿乙基檸 6 4 醋酸醚— 30 5 醋酸丁襄 一 20 6 乙醇 5 7 1紅色202粟 2~~^ 8 氧化欽 4 9 本發明製造例3之剝離組成物 8 ' 10 巷土 I " 將卜3及7〜8以熱輥混煉充分混埤,再與添加4〜6之1〇充分 混煉,授拌均勻後加入9中以行分散,填充至容器内即得 指甲油。 另,本發明之高虹彩色氧化鈦組成物,除用於化妝品、塗 料、墨水外,另可有效應用於塑膠、觸煤光機能性材料 如上所 面鮮明 高虹彩 層,其 0· 05〜0 此被覆 組成物 虹彩色 品中, 述,本發明能提供一種藉干涉色產生卓越光亮感、 色彩’且餘色不混濁之高虹彩色氧化鈦組成物:此 色氧化鈦組成物,係於其薄片狀基質 薄片狀基質片形大小約50〜8〇〇 ,厚义户貝丨】仃為王? 、、成物被覆層之鈦組成物被覆層所剠離形雜 ’即為咼虹彩氧化鈦組成物。再者 〉 氧化鈦組成物(本文中稱為剝離組成物), 问 可提供優異之滑順使用觸感、自然透 作化^ 攻明感、且藉其 200410726 五、發明說明(30) 干涉作用可抑制肌膚色斑(肌膚缺陷補正效果)、防紫外線 效果、光致變色效果等。 第35頁 200410726 圖式簡單說明 【圖式簡單說明】 以下說明本發明實施型態: 第1圖係本發明高虹彩色氧化鈦組成物之被覆組成物概念 圖。 第2圖係本發明高虹彩色氧化鈦組成物之製法概要圖。 第3圖係本發明被覆組成物之X光線繞射分析結果圖表。 第4圖係本發明被覆組成物之氧化鈦表面狀態顯微鏡照 片0 第5圖係本發明剝離組成物之氧化鈦組成物干涉色與欽芦 膜厚關係圖。 〃曰 第6圖係剝離組成物之氧化鈦組成物顯微鏡照片。 第7圖係剝離組成物之氧化鈦組成物顯微鏡照片。 第8圖係本發明剝離組成物之氧化鈦組成物三次元光澤古十 分析結果表。 【符號說明】 1薄片狀基質 2被覆層 2a剝離組成物Page 33 200410726 V. Explanation of the invention (29) Example 11 Blending j ^ ~ '-Blending amount (mass%) 1 Nitrocellulose 12 2 Alkyd resin 10 3 Ethyl lemon citrate 6 4 Ethyl acetate — 30 5 Dingxiang acetate 20 6 Ethanol 5 7 1 Red 202 millet 2 ~~ ^ 8 Oxidation 4 9 The peeling composition of the manufacturing example 3 of the present invention 8 '10 Lane I " Will 3 and 7 ~ 8 Knead with hot roller and mix thoroughly, and then knead thoroughly with the addition of 4 to 6 of 10. After mixing well, add 9 to disperse and fill the container to obtain nail polish. In addition, in addition to cosmetics, coatings, and inks, the high iridescent titanium oxide composition of the present invention can also be effectively used in plastics and coal-coated functional materials. Among the iridescent colored products of the coating composition, it is stated that the present invention can provide a high iridescent titanium oxide composition that produces an excellent bright feeling, interference color, and non-turbidity by the interference color: this color titanium oxide composition is based on Lamellar substrate The lamellar substrate has a sheet size of about 50 ~ 800. Houyihubei 丨】 仃 is king? The titanium compound coating layer formed by the titanium coating layer of the product coating layer is the iridescent titanium oxide composition. Furthermore> Titanium oxide composition (referred to herein as a peeling composition), it can provide excellent smooth feel, natural penetration ^ Sense of clarity, and by its 200410726 V. Description of the invention (30) Interference effect Can suppress skin stains (skin defect correction effect), UV protection effect, photochromic effect, etc. Page 35 200410726 Brief description of the drawings [Simplified description of the drawings] The following describes the embodiment of the present invention: Fig. 1 is a conceptual diagram of the coating composition of the high-iridium colored titanium oxide composition of the present invention. Fig. 2 is a schematic diagram of a method for producing a high iridescent titanium oxide composition according to the present invention. Fig. 3 is a graph of X-ray diffraction analysis results of the coating composition of the present invention. Fig. 4 is a photomicrograph of the state of the titanium oxide surface state of the coating composition of the present invention. 0 Fig. 5 is a graph showing the relationship between the interference color of the titanium oxide composition of the peeling composition of the present invention and the film thickness of ginseng. Figure 6 is a photomicrograph of the titanium oxide composition of the peeling composition. FIG. 7 is a micrograph of a titanium oxide composition of a peeling composition. Fig. 8 is a table showing the three-dimensional gloss ancient ten analysis of the titanium oxide composition of the peeling composition of the present invention. [Symbol description] 1 sheet-like substrate 2 coating layer 2a peeling composition
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