TWI255193B - High-colority composition of titanium oxide, coating compositions, cosmetic compositions and processes thereof - Google Patents
High-colority composition of titanium oxide, coating compositions, cosmetic compositions and processes thereof Download PDFInfo
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1255193 ， 1 弊I# S修(更) 九、發明說〖月一·----------------—^ 【發明所屬之技術領域】 本發明係有關高虹彩色氧化鈦組成物；具體而言，係有 關於薄片狀基質表面被覆組成物，進而使該被覆鈦組成物剝 離’形成-種韻鈦組成物。本發明另有關配合上述剝離組 成物，以製作化妝品。詳細言之，此化妝品組成物使用觸感 滑潤、透雖自^、且其干涉_可抑制色斑(肌膚缺陷補 正效果），並具UV防曬與光致變Mph〇t〇chr〇mic)效果。 【先前技術】 於天然雲母上被魏化鐵、氧化鈦等金屬氧化物，藉以 產生珍珠鮮之塗料，係屬f知技術。此種習知珍珠光澤塗 料，具有輝度不足、色彩残鮮盤、餘色渾濁等缺點。若以 合成雲母為原料，則能得透明度極高之製品’可用作優里之 珍珠光澤塗料。但合成雲母結晶過硬，易生劈理，若以通常 处里/、表面平雜反劣於域雲母；蝴其透明性與 白色度均南’可作為被霜氕几& & ^ 设魏鈦等薄膜之珍珠光澤塗料美 二另為:高干涉色輝度’亦叫狀氧化㈣狀氧化:為 土貝 魏鈦等_以作為珍珠光澤塗料。 1255193 料，_、、/化鈦所特有白色性、遮蔽紫外線等特徵之塗 為羽矣^用於化妝品、樹脂或_添加材，但因其利用者 為白知方法所製造之等粒狀微极子，因此於塗布性、穷著 性、分散性等方面皆有缺憾。而片狀氧化鈦之製造方法，雖 冒見於日本特許請9132_，但_具光澤及干涉色 之氧化鈦。 色彩係影響人類心理、生理之重要因素。為求活用色彩 =影響人類身心之所及範圍’以創造安全、高效率之工作環 兄以及健康舒適之生活壞境，遂將色彩學調整技術活用於 各個領域上。 -般而言，欲賦予物體色彩，係利用各種著色塗料。此 類著色塗料係藉光之吸收、反射等現象以呈現各種不同色 彩；但光靠著色塗料，逐漸無法應付近年來增加之多樣化感 性以及眾人要求。因此，將光干涉現象加入著色塗料中，含 有—氧化欽被復雲母專珍珠光澤塗料遂而誕生。此珍珠塗料 一大特徵，係隨觀察角度不同，其色調亦隨之變化，此即所 謂「變色龍效果（flip-flop)」。 此類珍珠光澤塗料，可用於化妝品、塗料、枯著劑、印 刷墨水、樹脂混合（incorporation)等這種領域；但卻明顯 1255193 存有下列缺點，例如··珍珠光澤塗料若以天然雲母、合成雲 母氧化I呂、—氣化石夕、石夕酸玻璃 '石朋酸玻璃等薄片狀、片 狀粒子為核，後被覆二氧化鈦，藉控制該二氧化鈦被覆量使 其壬現具各種干涉色之珍珠光澤。若將此類珍珠光澤塗料以 外用組成物塗料用作化妝品、塗料、印刷墨水、粘著劑、樹 脂混合上時，將產生粒子過厚無法形成超薄膜，且粒子邊緣 光散亂過強，無法有效發揮應有之「變色龍效果」。 另，關於氧化鈦片狀粒子之合成，如特許第2979132號 記載薄片狀氧化鈦，係於具大比面積之多孔f體上，使欽酸 鉋接觸氫氧溶液以使層狀結晶_、加熱，後得薄片狀氧化 鈦。將鈦酸所得層狀結晶獅至—層後，可得厚度僅達納米 等級之超薄氧化鈦。但因厚度過薄，致使該薄片狀氧化欽不 具任何干涉色。 另，特開昭62-237936、特開昭62-247834、特開昭 62-213833號所記片狀氧化鈦，係贼氧基金屬以溶膠—凝 膠方式（Sol Gel)附於輥箱後加熱，形成氧化物，再以刮 刀將其自觀綱離’加熱燒成若干珍珠狀片狀氧化鈦；但為 求刮刀剝離，粒子須呈細狀，且粒子厚度係微料級，導 致所有干涉色皆無法發色。 1255193 【發明内容】 jtAt -λ» J,CC» 一種具干涉色新穎卓1255193, 1 Disadvantages I# S repair (more) IX, invention 〖月一·-----------------^ [Technical field of invention] The present invention relates to Gao Hong The colored titanium oxide composition; specifically, the composition of the surface of the flaky substrate is coated, and the titanium composition is peeled off to form a titanium composition. The present invention further relates to the above-mentioned exfoliation composition to produce a cosmetic. In particular, this cosmetic composition uses a smooth touch, is transparent, and interferes with it, and can suppress color spots (skin defect correction effect), and has UV sunscreen and photoinduced Mph〇t〇chr〇mic effect. . [Prior Art] A metal oxide such as fertilized iron or titanium oxide is used on natural mica to produce a coating of pearl fresh. Such conventional pearlescent coatings have disadvantages such as insufficient brightness, color residual discs, and turbidity of the remaining color. If synthetic mica is used as the raw material, the product with high transparency can be used as the pearlescent paint of Youli. However, the synthetic mica crystals are too hard and easy to produce, if it is in the usual place, the surface is evenly inferior to the domain mica; the transparency and the whiteness of the butterfly are both as the frosty few && The pearl gloss coating of titanium and other films is also the second: high interference color brightness 'also known as oxidized (four) oxidation: for soil shell Wei titanium, etc. as a pearl gloss coating. 1255193 Material, _, / / Titanium is characteristic of whiteness, UV-shielding, etc. It is used as a cosmetic, resin or _ additive, but its user is a granular micro-manufactured by Baizhi method. Polar, therefore, there are shortcomings in coating, exhaustion, dispersion and so on. The method for producing sheet-like titanium oxide, although it is found in Japan, is licensed to 9132_, but has a gloss and an interference color of titanium oxide. Color is an important factor affecting human psychology and physiology. In order to use the color = influence the scope of the human body and mind to create a safe and efficient work environment and a healthy and comfortable life environment, the use of color adjustment technology in various fields. In general, to impart color to an object, various coloring paints are utilized. Such pigmented coatings exhibit various colors by absorption, reflection, and the like of light; however, coloring coatings are gradually unable to cope with the increased sensibility and demands of various people in recent years. Therefore, the phenomenon of light interference is added to the coloring paint, and the oxidized capsule is born by the pearlescent paint of the complex mica. This pearl paint is characterized by a change in color tone depending on the angle of observation. This is called "flip-flop". Such pearlescent coatings can be used in the fields of cosmetics, coatings, drying agents, printing inks, resin incorporation, etc. However, it is obvious that 1255193 has the following disadvantages, such as pearlescent coatings, natural mica, synthetic Mica oxidizes Ilu, gasified fossils, ashes acid glass, 'shipeng acid glass, and other flake-like, flaky particles are cores, and then coated with titanium dioxide. By controlling the amount of titanium dioxide coated, it has a pearl luster with various interference colors. . When such a pearlescent paint composition coating is used as a cosmetic, a coating, a printing ink, an adhesive, or a resin, the particles are too thick to form an ultrathin film, and the edge of the particles is too scattered, and the film cannot be excessively scattered. Effectively play the proper "chameleon effect". Further, regarding the synthesis of the titanium oxide flake particles, the flake-shaped titanium oxide described in Japanese Patent No. 2979132 is attached to a porous body having a large specific area, and the acid is immersed in a contact with the hydrogen-oxygen solution to cause lamellar crystal _, heating Then, flaky titanium oxide is obtained. After the layered crystal lion obtained from the titanic acid is layered, an ultrathin titanium oxide having a thickness of only nanometers can be obtained. However, since the thickness is too thin, the flaky oxide does not have any interference color. In addition, the sheet-like titanium oxide described in JP-A-62-237936, JP-A-62-247834, JP-A-62-213833, is attached to the roll box by a sol-gel method (Sol Gel). Heating, forming an oxide, and then firing it with a spatula to 'heat and burn a number of pearl-like flakes of titanium oxide; but in order to remove the scraper, the particles must be fine, and the particle thickness is micro-level, resulting in all interference No color can be colored. 1255193 [Summary of the Invention] jtAt -λ» J,CC» A novel with interference color
斑’並具uv防曬與光致變色效果。The spot has a uv sunscreen and photochromic effect.
物被覆層，_該被覆層後即可得足以解決上述問題之勒新 本發明為解決上述習知問題，遂 高虹彩色氧化鈦組成物。 具體而言，薄片狀基質表面上，形成以銳鈦礦型或金紅 石型氧化鈦為基礎之金屬氧化物，或金屬氫氧化物所被覆之 被覆層，此被覆層添加驗化合物後，即可得自薄片狀基質表 面所剝離之剝離組成物。此剝離組成物，能做為同時具有理 想光澤且發出干涉色之組成物。 亦即本發明所涉組成物，係自天然雲母、合成雲母、破 璃薄片、二氧化矽薄片、氧化鋁薄片、硫酸鋇中任選一種或 二種以上薄片狀基質，以及於其表面被覆氧化鈦組成物、或 氫氧化鈦組成物所成。因此，高虹彩色氧化鈦組成物之剝離 組成物，係自該被覆組成物所剝離出之鈦組成物。 1255193 關於上述剝離組成物之光澤；將壓克力系透明硝基漆3〇 部與上述剝離組成物1部加以混合，後用塗布機於白黑隱蔽 率試紙JISK5400上行4密耳塗布；後以堀場製光澤測定器 1330 _試該隱蔽率試紙之黑底，求其光澤值於啊下 為55,。係—以光干涉_進行發色之高虹彩氧化欽組成 物0 【實施方式】 本發明之高虹彩色氧化鈦域物之被餘成物，以及高 品等廣泛領域上， 發色。 虹彩色氧化鈦組成物製法，係提供―種於薄ϋ狀基質表面， 由乳化鈦、魏化鈦之鈦組成物所形成之簡層組成物，自 該被覆層剝離厚所得剝離組成物，以及其製法。與習知技術 相異處在於，藉該特定條件所得之娜組成物，可用作化妝 可藉光干涉側得顺所未有之高虹彩色 _十㈣色氧化鈦組成物被肢成物，如第i圖 所不’料狀基質丨表面含有峨鈦_或金紅石型氧化截 為基礎之金屬氧化物或金屬氫氧化物被覆層2。為一具光 澤、其特定厚度〇· 〇5〜Q. 6卵之被覆組成物。 1255193 範圍以100〜700_為理想，若低於1〇〇//m，則後述剝 離組成物粒子過細，高虹彩色之干涉色發色過弱。弱基質粒 :徑大於脚m，職虹彩色之干涉色發色過強，粒子即易 ▼有粗趟感。再者處於⑽_間，則光澤夠強且容 易剝離。 具體而言，能符合錄子徑細之薄4狀基質卜以天 然雲母、合成雲母、玻璃薄片、二氧化石夕薄片、氧化銘薄片、 ^酸鋇等域表。二氧化其形狀、表面平滑性皆容易 控制’再者，其表面均—被覆層2因易帶光澤，因此以其作 為薄片狀基質1甚為理想。薄片狀基質1粒子厚度雖無特 限但以〇 · ；!〜；! 0 // m為理想。粒子厚度若低於〇.工卿基質 周邊即易彎曲，導致被覆之氧化鈦、氫氧化鈦干涉光澤無法 完全發揮。另，粒子厚度若超過心m，顺覆於粒子平面、 4面之氧化鈦、虱氧化鈦則與剝離之氧化鈦、氫氧化鈦干涉 色相異，導致全體干涉光澤不足。 被设層2 ’包含乳化鈦、氫氧化鈦組成物，被覆特定厚 又直至㈣光料止。以麵二氧化鈦或四氯化鈦可溶性水 溶液或鈦絲基錢加水分解崎者為理想。另，被覆層2 合有二氧切、氧化銘、Zr、以、Zn等補強劑，可提高耐光 10 1255193 性、剝離組成物粉碎強度。 ^各粒子之大小為〇1〜 4之集合體’基fl粒子大小為3gg_時，以0〇2//之 乳化欽或氫氧化鈦組成為最易剝離，基質1粒子大小為腦 «時，被覆層2即使為G.心m之細小粒子徑亦可輕易剝 離，基質1粒子徑小於刚_，被覆層2粒子徑若無〇 〇5 M則無法_。亦即基質1粒子徑與被覆層2粒子徑互成 反比。 ★本發明中，先完成上述第1圖所示被覆組成物，次而如 第2圖所不，自馳覆組成物娜出被制2，得剝離組成 物2a。亦即本發明之高虹彩色氧化鈦組賴，料將此被覆 組成物被覆層2之金屬氧化物，或金屬氫氧化物，自薄片狀 基貝1表面剝離所形成之剝離組成物2a。 薄片狀基質卜可利用市售薄片狀粉體，或天然雲母、 口成农母玻璃薄片、二氧化石夕薄片、氧化銘薄片、硫酸鎖 等。例如將印度片狀天然雲母置於大氣800°C溫度下2小時， 後將燒成之片狀天然雲母浸於飲用水中5日，再以超微粒磨 碎機粉碎片狀天然雲母，經分級後即可得。 另，剝離别先以水玻璃、有機二氧化矽、可溶性鋁鹽等 1255193 -氧切或!g化合物被覆表面，侧離被覆喊物後，可得 一耐候性良好且不彎曲之剝離組成物。 被覆組成物，如上所述，先於薄片狀基質丨表面被覆特 疋厚度之氧化鈦或氫氧化鈦組成物直至發出餅為止，此即 被覆層2。#中以硫酸二氧化鈦或四氣化鈦可溶性水溶液或 鈦烷氧基金屬加水分解所得者為理想。 欲得剝離組成物時，須預先將被覆組成物經300〜800°C 燒成，置於鹼性環境下（pH8以上），自薄板狀基質剝離出被 覆層，得一無捲曲且具優異平滑性之剝離組成物。 藉此提高剝離組成物光澤與干涉色。若燒成溫度低於 3〇〇°C，剝離組成物粒子即有捲曲現象，若高K8〇〇t：，剝離 組成物之氧化鈦或氫氧化鈦即行凝集，造成剝離後光澤與干 涉色低劣。 剝離組成物經過濾、水洗、乾燥後，行5〇〇〜9〇〇π燒成， 以保持光澤、防止捲曲。另，其他剝離後置處理，尚包括外 覆氧化鐵、钻、鎳、經、鈉、鉀、著色無機化合物，或有機 塗料著色物，可II各種公知枝實現。此财摘得剝離組 成物之尚虹彩色鈦組成物，厚度可選擇0.05〜0.6#m，又以 光‘厚度0· 1〜0· 9#m範圍為理想。組成物過薄，即不易生 1255193 成所奴干涉色’·反之若組成物過厚，干涉色強度會因厚度而 產生散亂，致使干涉強度低劣。 •將本發明之高虹彩色鈦組成物塗布於紙帶上，將此塗布 紙帶置於黑底上，其干涉色與鈦組成物之幾何學厚度間關 係，示於第1表。 本發明之高虹彩色餘成錄徑，越㈣其紅彩色彩度 即越高。脚’薄嫌高虹彩色鈦喊物粒子_—，但2 散亂光仍可得所欲干涉色。 另’本發明中’具體的高虹彩色鈦組成物粒徑與薄板形 狀若整齊劃-，雷射繞射散亂徑之平均粒徑為_，而以處 於A± 範圍内分布_以上體積，甚或以上頻度 為理想；另，關於薄板形狀，以掃瞒式電子顯微鏡觀察粒子， 倍率2000倍計算粒子數目時，薄板形與粒子接線，以厚度 超過1· 5倍以上粒子數未滿1〇%為理想。 為保持粒徑均-性，於調整薄片狀基f平滑性時，謹慎 施行粉碎與絲為理想。若天縫母，叫;讀摔粉碎 2〜8網眼之原礦石，後行水力淘析，以選擇均—性優異者為 佳。 更甚者，粒子徑平滑整齊之薄片狀基質表面，均句被覆 1255193 鈦組成物，剝離該鈦組成物之後，可使干涉色更為均質。 照上述方摘得_組·，本㈣紘彩色氧化欽组 成物之被额摘，騎光澤响輕定厚度。細於塗料 等用途時，於直接表面反射从射、穿透同時，所反射之反 射光互行干涉，因位相差異即可得高虹彩色干涉色。 本發明之高虹彩色氧化鈦組成物均一塗布於塗布面 時’-旦細光線，來自塗布面粒子表面之反射光，以及因 屈折率不同齡所反射之餘成物粒子透過光，互起干涉， 遂得特定干涉色。此干涉色可藉被覆組成物之被覆層厚度加 以控制決定。 (對照例1) 第8圖係本發明剝離組成物之氧化鈦組成物，經三次元 光澤計分析結果圖表。 將本發明剝離組成物1部，與壓克力系透明硝基漆30 部加以混合，後用塗布機於白黑隱蔽率試紙JISK54〇〇上行4 密耳塗布；後對準隱蔽率試紙黑底，以三次元光澤計gcms〜4 型、入射角45° 、反射角（測色角）〇〜75。間，以每5°為 間隔進行測色，求其Lab。 14 1255193 其對照塗料’則使用德國默克(^61\:1〇公司所製11^〇(^[1 珠光塗料（以下簡稱IR)225、219、235。自分析結果可看出 本發明氧化鈦組成物可表現廣泛之干涉色。 以下列舉具體製造範例，另，此製造例並不限於本發明 技術範圍。 (製造例1) 將印度片狀天然雲母1· 〇公斤置於大氣別0^溫度下2 小時燃燒，冷卻後將此片狀天然雲母浸於飲用水10升中， 於至/JDL下放置5日，後以增幸產業社製超微粒磨碎機處理該 片狀燒成天然雲母2回以行粉坪，將粉碎後之燒成天然雲母 移入谷罝50升之聚乙稀水槽中，加入〇· 〇2%之六偏磷酸水溶 液，總計45升。 以螺旋攪拌機攪拌，靜置5分鐘，將上層澄清液移至其 他各為’反覆此步驟3次，分粒出〇· imm以上大粒子，用標 準篩10網眼(800Μ)與65網眼(203//m)進行篩選分粒，得 到10〜65網眼粒子徑150g。 之後將分粒後雲母150g加入硫酸鈦400g與飲用水4. 5 升中，以螺旋式攪拌機攪拌、溶解硫酸鈦。待其溶解後，攪 15 1255193 拌並同時加熱，於9〇t：以上溫度行4小時加水分解處理。冷 卻後經水洗、濾過、150°C乾燥。而後經300°C燒成2小時。 為觀察表面狀態取1部，以日立(Hitachi)S-2100B型電子顯 微鏡(SEM)放大20000倍觀察，其結果即如第4圖所示，被 覆組成物粒子徑為0· 02//m之集合體。 將水洗粉末加入10%之荷性鹼水溶液，調整為pH11後行 浸潰靜置。以傾析法分粒上層浮離粉末，濾過並水洗分粒粉 末。將水洗分粒粉末加上硫酸銨8· 325公克後溶解成5升水 溶液，後再加上羥氣化鍅4公克與尿素18公克。螺旋攪拌 同時加熱，行5小時80°C以上加水分解處理。冷卻後經水洗、 ◎、:150°C乾燥。將此乾燥粉末置於大氣中行7〇〇〇c燒成2小 曰守。付粉末140公克。 以理學電機社製X射線繞射儀MniFlex測定該粉末，其 X光線繞射如第3 @ G所示，幅度雖大但氧減之闊銳鈦礦 型。另，以掃瞄式電子顯微鏡(SEM)放大2〇〇〇倍與2〇〇〇〇倍 之結果如第1 _示，呈薄片狀。板徑平均為，板厚 度為〇· 24//m。將壓克力系透明硝基漆3〇部與丨公克本品混 16 1 後用塗布機於白黑隱蔽率試紙JISK5400上行4密耳塗 布後以堀場製光澤測定器、IG_33〇型求得該黑底於·下 1255193 為85。 另為求得黑底色調角度依存性’因此用村上色彩研究所 製3次元光澤度計GCMS-4型，以入射角度45。、測色取出 角0°〜75°間，每隔5°行測色。變換L · a · b，將色相ab 予以平面化，結果如第8圖所示，從綠色至青綠色、藍色幅 度間變化。 為求調查本品構成成分，取〇· 2公克正確秤量，並加入 硫酸與硫酸銨，加熱後溶解。冷卻後再添加水、鹽酸、金屬 鋁，以還原鈦；冷卻後之硫氰酸鉀溶液作為指示劑，滴定硫 酸銨鐵(III)溶液，求魏化鈦量(％)。其結果，氧化欽為 95.0%。另’為使贿較量’目此以理學電機社製波長分 型求得銨為394.40nm、鍅 散型螢光X射線分析裝置ZSXIOOe 為343. 82mn ’根據檢量線法予以定量。其結果銨與氧化狀 1.15% ’且錯為氧化鍅之丨._。亦即，本品即為構成成分氧 化欽95. 〇%、氧化銨為h 15%、氧化锆為L _之組成物。 (製造例2) 合成雲母⑽y工業製)之雷射徑為⑽场m，平均 經30_ ’將H)公斤放入容_升之付蓋錢水槽。加 1255193 入飲用水400升與氯化錫175公克與1摩爾/升硫酸水溶 液，調整為ρΗ1· 9。攪拌同時加熱，使溫度升至8〇。匸後，用 1/3摩爾/升之四氯化鈦鹽酸水溶液與15%苛性鹼水溶液以 保持pH值，並以每分鐘〇· 12公斤流速滴入四氣化鈦鹽酸水 溶液，進行10小時反應。 冷卻後，停止攪拌，傾析上層液體。將殘留粉末加上飲 用水400升後攪拌，加入15%苛性鹼水溶液調整pjj至& 5〜7. 5 後濾過、水洗、以150°C乾燥。將乾燥粉末於大氣8〇〇°c下 燒成2小時。與製造例1相同，以SEM觀察其表面狀態，發 現其被覆粒子大小為0· 016 之集合體。 將燒成粉末浸潰於pHl2之碳酸鈉水溶液4〇〇升中，5日 後以螺旋充分攪拌，加入六偏鱗酸鹼2%水溶液2升後攪拌。 均勻分散後，以傾析法分離上層粉末。反覆此步驟以回收上 層粉末。 將上層粉末經水洗、濾過後，將濾過之粉末浸潰於ρΗ9· 2 之可丨生驗水〉谷液400升中’並以螺旋擴;掉均勻分散。保持pH 為9· 2的狀態下加熱至8〇°C，並將3摩爾/升的矽酸鈉水溶 液與_的鹽酸水溶液，以矽酸鈉水溶液每分鐘〇· 〇85升流 逮連續添加2小時。待2小時成化後冷卻、濾過、水洗後， 18 1255193 以150°C乾燥、得18公斤粉末。 6與製造m相同，明樣裝置測以光線繞射。χ光線 凡射、、口果錢金紅石型氧化鈦。SEM觀察則如第7圖所示係 一薄片狀、板徑平均15//m、厚度〇.45//m。 與衣造例1相同，以白黑隱蔽率試紙JISK54〇〇以及三 次凡光澤度計料測色，並進行組成分析。絲其光澤測試 值為60至8〇 ，測色色調角度依存性介於黃綠色至綠色、 月、、亲色fell間變化。另，組成分析結果，氧化鈦為88·5%、 二氧化矽則為10. 3%。 (製造例3) 將雷射徑50〜200//m、平均140//m之玻璃薄片（曰本 板硝子社製RCF140) 1公斤置入40升之琺螂容器内，加入 10%硫酸鈦水溶液Π升、〇· 〇6莫爾/升之硫酸水溶液5升、 尿素100公克及飲用水10升，行螺旋攪拌並同時加熱至9〇 °C以上行6小時加水分解處理。 冷卻後反覆傾析水洗。加入10%荷性鈉與30升飲用水， 使pH值為8· 8後加熱至80°C。保持pH值同時以每分鐘q 升之速加入1吴爾/升之水玻璃水>谷液〇· 85升，以及in 1255193 之硫酸水溶液持續“、時，後行3小時熟成。 冷卻後與製造例1相同， ^ 布 W SEM硯祭其表面狀態，測得 其粒子為a〇4//m之大粒子。 於熟成後之分散射加人1制/升之碳_水溶液使 pH值為12 ’放置4日。後再以螺旋授拌行傾析法分離上層 澄清液之粉末。域此步驟_收上層澄清财粉末。將回 收之秦末、l水洗、過濾、150〇c乾燥。乾燥後置於大氣中以 3〇〇°C燒成1小時。得到粉末65〇公克。 所得粉末以X光繞射結果，可知係闊銳欽礦型。鯽觀 察結果’得知薄板狀形其板徑平均為8m、厚度為〇.35_。 與製造例1進行_雛實驗。其結果可得知光澤測試 值為60 ’且測色之色調角度依存性為介於紅紫色至紅色· 黃色範關變化。科，從組齡析的絲來看，可得知氧 化鈦係70%、二氧化矽2· 8%，且另有水分。 (製造例4) 將印度製片狀天然雲母以製造例1相同條4牛於以解碎分 級。將此雲母lkg裝入4〇升之琺瑯容器中，加入1〇%硫酸 鈦水溶液17升、0· 06莫爾/升之硫酸水溶液5升、尿素1〇〇g 1255193 及飲用水10升，行螺旋攪拌，加熱至9〇°C以上後行6小時 加水勿處理。 冷部後，經水洗、濾過。加入10%荷性訥水溶液與飲用 水30升’將液體pH值保持於10狀況下，以氮氣行攪拌並 加熱至80°c。保持PH與溫度下加入〇·5莫爾/升之硫酸第 一鐵水溶液〇· 2升、10%荷性鈉水溶液，且以每分鐘〇. 〇14 升之流速持續加入硫酸第一鐵水溶液15分鐘。再以氮氣持 績換氣5小時。 冷部後，與製造例1相同以SEM觀察表面狀態，披覆粒 子大小為0· 〇4//m，甚有〇· 3//m之粒子散佈表面。 於热成後之分散液中加入1莫爾/升之碳酸鈉水溶液， 使其pH值為12，放置4日。後再以螺旋攪拌行傾析法分離 上層澄清液之粉末。反覆此步驟以回收上層澄清液中粉末。 將回收之粉末經水洗、濾過、15(rc乾燥。乾燥後置於大氣 中以500 C燒成1小時。得到粉末公克。 所得粉末以X光繞射結果，可知係闊銳鈦礦型與氧化鐵 ⑽03>SEM觀察結果，得知薄板狀形其板徑平均為8m、 厚度為G.36 _。與製造例1進行相_性實驗。其結果可 得知光澤測紐為6『，且測色之色则度依存性為介於紅 21 1255193 糸色至紅色·黃色範圍間變化 乃卜’從組成分析的結果來 看，可得知有氧化鈦99%、氧化鐵1%。 本發明中，以上述方造之_組成物，可用作化妝 品。 另’化妝品之剝離組成物配合量，則.5〜50重量％為 理想。配合量未滿5重量％時，缺乏抑制色斑之效果。另， 超過50重量％時則其紅彩色過強，亦不理想。 本發明可用作例如護膚霜、粉底、防曬乳液、粉底霜、 泰餅、乾粉餅、眼線筆、齡、口紅、指甲油等皮膚用化妝 品，其型態並無特限。另，此類化妝品除了和上述本發明之 剝離組成物配合之外，其餘都與一般化妝品製造方式相同。 本考X明之化妝υσ，除上述剝離組成物外，另可應需要加 上一般化妝品所配合使用之粉體（塗料、色素、樹脂）、油、 介面活性劑、FU素化合物、樹脂、酒精類、高分子化合物、 紫外線防禦劑、抗氧化劑、黏劑、防腐劑、香料、保濕劑、 生理活性成分、鹽類、溶制、螯合劑、中和劑、pH調整劑、 水、以及其他成分等。 以粉體為例，如紅色104號、紅色201號、黃色4號、 藍色1號、黑色401號等色素，黃色4號A1胭脂、黃色2〇3 22 1255193 ㈣姻脂等胭㈣，尼龍粉、絲粉、酯粉、特氣隆粉、 矽粉、纖維素粉、石夕合成橡膠、幾丁質M 等高分子、普氧 、双來糖、褐藻酸， 群主、鐵、黑氧化鐵、氧化鉻、黑碳、 月掛月荨著色塗料、4务谷 Λ=-塗料、讲石干 、太、乳化亞鉛、氧化鈽等白色 石夕m、騎、絹料、陶土、赌鋇、氧触、氧化 酸鎂、頻銘、频鎂等體f塗料、微粒子 2、雜子統亞錯、微粒子氧⑽、等料線防紫粉 -、纖物_、4土1㈣。編體形狀、 大小並無特限。 f，上述粉體’可㈣知各種方錢行絲處理，例如 h夕氧炫處理、魏處理、氟素化合物處理、金屬息處理、 蠛處理、脂肪酸處理、N—醯化職酸處理、水雜高分子化 合物處理、樹脂處理、等離子處理、機器化學處理等方式皆 可0 油，可分為流動石壤、三十碳烧、2_乙基己醇十六烧基、 十四炫酉文/、丙基撖欖油、论麻油等液體油、凡士林、固體 石堰、牛脂、含水羊毛脂、密壤、錄壞、膽巢醇等半固體〜 固體脂’錄鑛、22燒醇等高級醇、棕櫚酸、甘油三硬脂酸 醋等高級麟酸、聚魏錄·、聚魏麟導體等。 23 1255193 介面活性劑，可分為山梨糖醇酐脂肪酸酯、甘油脂肪酸The coating layer, which is sufficient to solve the above problems, can solve the above problems, and the high-color titanium oxide composition is solved. Specifically, a metal oxide based on anatase or rutile type titanium oxide or a coating layer coated with a metal hydroxide is formed on the surface of the flaky substrate, and the coating layer is added to the coating layer. A peeling composition obtained by peeling off the surface of the flaky substrate. This peeling composition can be used as a composition which simultaneously has an ideal gloss and emits an interference color. That is, the composition of the present invention is one or more flaky substrates selected from natural mica, synthetic mica, glass flakes, ceria flakes, alumina flakes, and barium sulfate, and coated on the surface thereof. A titanium composition or a titanium hydroxide composition. Therefore, the peeling composition of the high iridescent titanium oxide composition is a titanium composition peeled off from the coated composition. 1255193 The gloss of the above-mentioned peeling composition; mixing the crepe-based transparent nitrocellulose varnish 3 part with the above-mentioned peeling composition, and then coating it with a coater on a white-black concealment test paper JISK5400 4 mils;堀 制 光泽 13 13 13 13 13 13 13 试 试 试 试 试 试 试 试 试 试 试 试 13 13 试 13 13 13 试 13 13 13 试The high-color oxidized composition of the high-color colored titanium oxide domain of the present invention, and the color of the high-yield titanium oxide domain of the present invention, and high-quality products. The method for preparing a rainbow colored titanium oxide composition, which comprises providing a thin layer composition formed of a titanium composition of emulsified titanium or Wei-titanium on a surface of a thin enamel substrate, and peeling off the thickness of the coating layer to obtain a peeling composition, and Its method of production. What is different from the prior art is that the composition of Na, which is obtained by the specific conditions, can be used as a makeup material, and the high-color color of the titanium (tetra) color titanium oxide composition can be used as an object. As shown in Fig. i, the surface of the material matrix contains a metal oxide or metal hydroxide coating layer 2 based on a cerium-titanium- or rutile-type oxidized cut. It is a coating composition of a light, a specific thickness of 〇·〇5~Q. 6 eggs. The range of 1255193 is preferably 100 to 700 mm. If it is less than 1 〇〇//m, the particles of the peeling composition described later are too fine, and the interference color of the high rainbow color is too weak. Weak base plasmid: The diameter is larger than the foot m, and the interfering color of the occupational color is too strong, and the particles are easy to be ▼ with a rough feeling. In addition, between (10)_, the gloss is strong enough and easy to peel off. Specifically, it can conform to a thin 4-shaped matrix with a small diameter of the recording surface, such as natural mica, synthetic mica, glass flakes, cerium oxide thin flakes, oxidized ingot flakes, and acid strontium. The shape and surface smoothness of the dioxide are easily controlled. Further, since the surface-coating layer 2 is easily glossy, it is preferable as the sheet-like substrate 1. Although the thickness of the flaky substrate 1 is not limited, it is ideal for 〇· ;!~;! 0 // m. If the particle thickness is lower than 〇. The periphery of the granule is easy to bend, and the interference between the coated titanium oxide and the titanium oxynitride cannot be fully exerted. On the other hand, when the particle thickness exceeds the center m, the titanium oxide and the titanium oxide which are applied to the particle plane and the four sides are different from the exfoliated titanium oxide and the titanium hydroxide, resulting in insufficient interference gloss. The layer 2' contains an emulsified titanium or a titanium hydroxide composition, and the coating is thick to a specific thickness until the (four) light is stopped. It is ideal for the surface titanium dioxide or titanium tetrachloride soluble water solution or titanium wire based water plus water. Further, the coating layer 2 is provided with a reinforcing agent such as dioxo, oxidized, Zr, or Zn, and the light-resistant 10 1255193 and the pulverization strength of the peeling composition can be improved. ^The size of each particle is 集合1~4. When the size of the fl particle is 3gg_, the composition of the emulsified or titanium hydroxide of 0〇2// is the most easily stripped, and the particle size of the matrix 1 is the brain. The coating layer 2 can be easily peeled off even if it is a small particle diameter of the G. heart m. The particle diameter of the matrix 1 is smaller than that of the steel layer _, and the particle diameter of the coating layer 2 cannot be _ 5 M. That is, the particle diameter of the matrix 1 is inversely proportional to the particle diameter of the coating layer 2. In the present invention, the coating composition shown in Fig. 1 is completed first, and if it is not shown in Fig. 2, the composition 2 is peeled off from the coating composition to obtain the peeling composition 2a. That is, the high iridescent titanium oxide composition of the present invention is coated with the metal oxide of the composition coating layer 2 or the metal hydroxide, and the peeling composition 2a formed by peeling off the surface of the flaky base 1 is used. The flaky substrate may be a commercially available flaky powder, or a natural mica, a mother glass sheet, a cerium oxide sheet, an oxidized sheet, a sulfuric acid lock or the like. For example, the Indian flake natural mica is placed in the atmosphere at 800 ° C for 2 hours, and then the calcined natural mica is immersed in drinking water for 5 days, and then the flake-shaped natural mica is pulverized by a superfine grinder. You can get it later. Further, the surface of the coating is coated with 1255193-oxygen or ?g compound, such as water glass, organic cerium oxide, or soluble aluminum salt, and the coating material is removed from the coated object to obtain a peeling composition having good weather resistance and no bending. As described above, the coating composition is coated with a titanium oxide or a titanium hydroxide composition having a specific thickness before the surface of the flaky substrate, until the cake is formed. It is desirable to use #TiO2 or a titanium tetrahydrate soluble aqueous solution or a titanium alkoxide metal to be decomposed by water. When the composition is to be peeled off, the coated composition is fired at 300 to 800 ° C in advance, and placed in an alkaline environment (pH 8 or higher), and the coating layer is peeled off from the thin plate-like substrate to obtain a curl-free and excellent smoothness. Stripping composition of sex. Thereby, the gloss and interference color of the peeling composition are improved. If the firing temperature is lower than 3 〇〇 ° C, the particles of the peeling composition are curled. If the height is K8 〇〇 t:, the titanium oxide or the titanium hydroxide of the peeled composition is agglomerated, resulting in poor gloss and interference color after peeling. . After the peeling composition is filtered, washed with water, and dried, it is fired at 5 〇〇 to 9 〇〇 π to maintain gloss and prevent curling. In addition, other post-peeling treatments include over-coated iron oxide, diamond, nickel, warp, sodium, potassium, colored inorganic compounds, or organic paint colorants, which can be achieved by various known branches. This financial extract has a peeling composition of the Shanghong color titanium composition, the thickness can be selected from 0.05 to 0.6 #m, and the range of light 'thickness 0·1~0·9#m is ideal. If the composition is too thin, it is not easy to produce 1255193. If the composition is too thick, the interference color intensity will be scattered due to the thickness, resulting in poor interference strength. • The high iridescent titanium composition of the present invention is applied to a paper tape, and the coated paper tape is placed on a black substrate, and the relationship between the interference color and the geometric thickness of the titanium composition is shown in Table 1. According to the high-intensity color recording of the present invention, the more (4) the red color chroma is higher. The foot 'thin is too high-color titanium to shout particles _-, but 2 scattered light can still get the desired interference color. In the 'invention of the present invention, the specific particle size of the high-yellow titanium composition and the shape of the thin plate are neatly drawn, the average particle diameter of the laser diffraction scattered diameter is _, and the volume is distributed within the range of A±. Even the above frequency is ideal; in addition, regarding the shape of the thin plate, the particles are observed by a bronzing electron microscope, and when the number of particles is calculated by a magnification of 2000 times, the thin plate shape and the particle are connected, and the thickness is more than 1.5 times or more and the number of particles is less than 1%. Ideal. In order to maintain the uniformity of the particle size, it is desirable to carefully perform the pulverization and the sizing when adjusting the smoothness of the flaky base f. If the seam is sewed, it is called; the original ore of 2~8 mesh is read and smashed, and then the hydraulic analysis is carried out, so that it is better to choose the average-sex. What is more, the surface of the flaky substrate having a smooth and uniform particle diameter is coated with a titanium composition of 1255193, and the interference color is more uniform after the titanium composition is peeled off. According to the above-mentioned party, the _ group·, the (4) 纮 color oxidation composition is picked up, and the thickness of the gloss is light. When it is finer than coatings and other applications, the direct surface reflection is reflected and penetrated, and the reflected reflected light interferes with each other. The high-color interference color can be obtained due to the difference in phase. When the high iridescent titanium oxide composition of the present invention is uniformly applied to the coated surface, the fine light rays, the reflected light from the surface of the coated surface particles, and the residual particles reflected by the inflection rate of different ages transmit light, and interfere with each other. , get a specific interference color. This interference color can be determined by controlling the thickness of the coating layer of the coating composition. (Comparative Example 1) Fig. 8 is a graph showing the results of analysis of the titanium oxide composition of the peeling composition of the present invention by a three-dimensional gloss meter. The present invention is peeled off one part of the composition, and mixed with 30 parts of acrylic transparent nitrocellulose lacquer, and then coated with a coater on a white-black concealment test paper JISK54 〇〇 up 4 mil; followed by a concealment rate test paper black bottom , gcms~4 type with three-dimensional gloss, incident angle of 45°, reflection angle (color measurement angle) 〇~75. For color measurement, the measurement is performed at intervals of 5°. 14 1255193 The control paint 'uses Germany's Merck (^61\:1〇 company's 11^〇(^[1 pearlescent coatings (hereinafter referred to as IR) 225, 219, 235. From the analysis results can be seen that the oxidation of the present invention The titanium composition can exhibit a wide range of interference colors. Specific manufacturing examples are listed below, and the production examples are not limited to the technical scope of the present invention. (Manufacturing Example 1) Indian flake natural mica 1·〇 kg is placed in the atmosphere 0^ After burning for 2 hours at a temperature, the sheet of natural mica was immersed in 10 liters of drinking water after cooling, and placed under /JDL for 5 days, and then treated with a superfine particle mill manufactured by Zengxing Industrial Co., Ltd. to treat the flakes. Mica 2 is back to the powder floor, and the pulverized fired natural mica is transferred into a 50 liter polyethylene sump, and a 2% hexametaphosphoric acid aqueous solution is added, totaling 45 liters. Stirring with a screw mixer, static After 5 minutes, the upper clear liquid was moved to the other ones to 'repeated this step 3 times, and the large particles above the 〇·imm were separated, and the standard sieve 10 mesh (800 Μ) and 65 mesh (203//m) were used. Screening and granulating to obtain a particle diameter of 150 g of 10 to 65 mesh. After that, 150 g of mica was added to the sulphur after centrifugation. Titanium 400g and drinking water 4.5 liters, stir and dissolve titanium sulphate in a spiral mixer. After it is dissolved, stir 15 1255193 and heat at the same time, and then hydrolyze at 9 〇t: above temperature for 4 hours. After cooling It was washed with water, filtered, and dried at 150 ° C. Then it was baked at 300 ° C for 2 hours. One surface was observed for observation of the surface state, and it was observed by Hitachi S-2100B electron microscope (SEM) at 20000 times. As shown in Fig. 4, the coating composition has a particle diameter of 0·02//m. The water-washed powder is added to a 10% aqueous alkali solution, adjusted to pH 11, and then immersed and allowed to stand. The upper part of the granules floated off the powder, filtered and washed with water. The water-washed granulated powder was added with ammonium sulphate 8·325 g and dissolved into 5 liters of aqueous solution, followed by 4 g of hydroxy-gasified hydrazine and 18 g of urea. At the same time, heating, 5 hours 80 ° C or more plus water decomposition treatment, after cooling, washed with water, ◎,: 150 ° C. The dry powder was placed in the atmosphere, 7 〇〇〇 c burned into 2 small 曰 。.克. The powder was measured by MniFlex, an X-ray diffractometer manufactured by Rigaku Electric Co., Ltd. Its X-ray diffraction is shown as the third @G, but the amplitude is large but the oxygen is reduced to the wide anatase type. In addition, it is magnified 2 times and 2 times by scanning electron microscope (SEM). The results are shown in the first sheet, and are in the form of flakes. The average plate diameter is 〇·24//m. The acrylic nitrocellulose lacquer 3 丨 is mixed with 丨 gram of this product and coated with 16 1 The black and white concealment rate test paper JISK5400 was coated with 4 mils, and the black matrix was obtained by the 光泽 制 光泽 光泽 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 In addition, the black matrix tone angle dependence was determined. Therefore, a three-dimensional gloss meter GCMS-4 type was manufactured by Murakami Color Research Laboratory at an incident angle of 45. The color measurement is taken out at an angle of 0° to 75°, and the color is measured every 5°. Transforming L · a · b, the hue ab is flattened, and as shown in Fig. 8, the color changes from green to cyan and blue. In order to investigate the composition of this product, weigh 2 g of the correct amount, add sulfuric acid and ammonium sulfate, and dissolve after heating. After cooling, water, hydrochloric acid, and aluminum metal are added to reduce titanium; after cooling, the potassium thiocyanate solution is used as an indicator to titrate the ammonium iron(III) sulfate solution to determine the amount of titanium (%). As a result, the oxidation was 95.0%. In addition, in order to make a bribe, the ammonium was determined to be 394.40 nm by wavelength and the ZSXIOOe was 343. 82mn was quantified according to the calibration method. As a result, the ammonium and the oxidized form were 1.15% Å and the erbium was 鍅. That is, the product is a constituent of the composition of oxidized phlegm 95. 〇%, ammonium oxide is h 15%, and zirconia is L _. (Manufacturing Example 2) The synthetic laser mica (10) y industrial system has a laser path of (10) field m, and an average of 30 ft. Add 1255193 to 400 liters of drinking water and 175 grams of tin chloride and 1 mole/liter of aqueous sulfuric acid solution, adjusted to ρΗ1·9. Stir while heating to raise the temperature to 8 Torr. After the crucible, a 1/3 mol/liter aqueous solution of titanium tetrachloride hydrochloride and a 15% aqueous caustic solution were used to maintain the pH, and a tetrahydrogenated titanium hydrochloric acid aqueous solution was added dropwise at a flow rate of 〇·12 kg per minute for 10 hours. . After cooling, the stirring was stopped and the supernatant liquid was decanted. The residual powder was added to 400 liters of water and stirred, and a 15% aqueous caustic solution was added to adjust pjj to & 5 to 7. 5, followed by filtration, washing with water, and drying at 150 °C. The dried powder was fired at 8 ° C for 2 hours in the atmosphere. In the same manner as in Production Example 1, the surface state was observed by SEM, and an aggregate having a coated particle size of 0·016 was found. The calcined powder was immersed in 4 liters of a sodium carbonate aqueous solution of pH 12, and after 5 days, the mixture was sufficiently stirred by a helix, and 2 liters of a hexamic acid 2% aqueous solution was added thereto, followed by stirring. After uniform dispersion, the upper layer powder was separated by decantation. This step is repeated to recover the upper layer of powder. After the upper layer of the powder was washed with water and filtered, the filtered powder was immersed in a water-repellent water solution of 400 liters of ρΗ9·2 and spirally expanded; While maintaining the pH of 9.2, the mixture was heated to 8 ° C, and a 3 mol / liter aqueous solution of sodium citrate and aqueous hydrochloric acid was continuously added with a sodium citrate aqueous solution of 〇 〇 85 liters per minute. hour. After cooling for 2 hours, filtration, and washing with water, 18 1255193 was dried at 150 ° C to obtain 18 kg of powder. 6 is the same as the manufacturing m, and the clear device measures the light diffraction. χ光 凡,,,,,,,,,,,,,,,,,,,, The SEM observation was as shown in Fig. 7 as a sheet, with an average plate diameter of 15/m and a thickness of 4545/m. In the same manner as in the first embodiment, the white and black concealment rate test paper JISK54〇〇 and the three times of gloss measurement were used for color measurement, and composition analysis was performed. The silk gloss test value is 60 to 8 〇, and the color tone angle dependence varies from yellow-green to green, moon, and color. 3%。 The composition of the analysis results, the titanium oxide was 88.5%, and the cerium oxide was 10.3%. (Production Example 3) 1 kg of a glass flake having a laser diameter of 50 to 200//m and an average of 140/m, which is RCF140 (manufactured by Ryukyu Seiki Co., Ltd.), was placed in a 40-liter helium container, and a 10% titanium sulfate aqueous solution was added thereto. 5 liters of sulphuric acid aqueous solution, 5 liters of urea and 10 liters of drinking water are stirred, 〇· 〇 莫 莫 莫 , , , , , , , 螺旋 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 After cooling, the mixture was washed with water. Add 10% sodium and 30 liters of drinking water to bring the pH to 8.8 and heat to 80 °C. While maintaining the pH, add 1 ul/liter of water glass water at a rate of q liters per minute, > glutamine 〇·85 liters, and an aqueous solution of sulfuric acid in 1255193 for a while, after 3 hours of ripening. After cooling, Production Example 1 is the same, ^W SEM 砚 其 其 其 其 其 , , , , , 其 其 其 其 其 其 其 其 砚 砚 砚 砚 砚 砚 砚 砚 砚 砚 砚 砚 砚 砚 砚 砚 砚 砚 砚 砚 砚 砚 砚 熟 砚12 'Place for 4 days. Then separate the powder of the upper clear liquid by the spiral decantation method. This step _ take the upper layer to clarify the powder. The recovered Qin, l water, filter, 150 〇 c dry. Dry After being placed in the atmosphere, it was fired at 3 ° C for 1 hour to obtain a powder of 65 〇g. The obtained powder was diffracted by X-ray, and it was found that it was a broad-cut type. The average diameter is 8 m and the thickness is 〇.35_. The experiment is carried out in the same manner as in Production Example 1. The result shows that the gloss test value is 60 ' and the color angle dependence of the color measurement is between reddish purple and red. Change. From the perspective of the age of the group, it can be seen that 70% of titanium oxide and 2.8% of cerium oxide, and another (Production Example 4) An Indian-made flake-form natural mica was fractionated by the same strip of 4 cows in Production Example 1. This mica lkg was placed in a 4 liter helium vessel, and a 1% by weight titanium sulfate aqueous solution was added. 17 liters, 0. 06 Mohr / liter of sulfuric acid aqueous solution 5 liters, urea 1 〇〇 g 1255193 and drinking water 10 liters, spiral agitation, heating to 9 〇 ° C or more after 6 hours of water do not handle. After the cold After washing with water and filtering, add 10% aqueous solution of tonic solution and 30 liters of drinking water. Keep the pH of the liquid at 10, stir with nitrogen and heat to 80 ° C. Keep the pH and temperature and add 〇·5 Mo 1 / liter of the first aqueous solution of sulfuric acid 〇 · 2 liters, 10% aqueous sodium solution, and continuously added sulphuric acid first iron aqueous solution for 15 minutes at a flow rate of 〇 14 liters per minute. After the cold portion, the surface state was observed by SEM in the same manner as in Production Example 1, and the particle size of the coating was 0·〇4//m, and even the particles of 〇·3//m were scattered on the surface. Add 1 mol/L of sodium carbonate aqueous solution to pH 12 and let it stand for 4 days. The powder of the supernatant liquid was separated. This step was repeated to recover the powder in the supernatant liquid. The recovered powder was washed with water, filtered, and dried (15 rc). After drying, it was placed in the atmosphere and calcined at 500 C for 1 hour to obtain a powder gram. The obtained powder was subjected to X-ray diffraction, and it was found that the broad anatase type and the iron oxide (10)03> SEM observation showed that the sheet shape was 8 m in average and the thickness was G.36 _. _ Sexual experiment. The result shows that the gloss measurement is 6′′, and the color dependence depends on the red 21 1255193. The color changes from red to yellow. The result is analyzed from the composition analysis. It can be seen that there are 99% of titanium oxide and 1% of iron oxide. In the present invention, the composition described above can be used as a cosmetic. Further, the amount of the peeling composition of the cosmetic is preferably from 5 to 50% by weight. When the amount is less than 5% by weight, the effect of suppressing color spots is lacking. On the other hand, when it exceeds 50% by weight, the red color is too strong, which is not preferable. The present invention can be used as a skin cosmetic such as a skin cream, a foundation, a sunscreen lotion, a foundation cream, a Thai cake, a dry powder cake, an eyeliner, an age, a lipstick, a nail polish, and the like, and the form thereof is not limited. Further, such a cosmetic is the same as the general cosmetic manufacturing method except that it is blended with the above-mentioned peeling composition of the present invention. In addition to the above-mentioned peeling composition, in addition to the above-mentioned peeling composition, powders (paints, pigments, resins), oils, surfactants, FU compounds, resins, alcohols, which are used in combination with general cosmetics, may be added as needed. , polymer compounds, UV inhibitors, antioxidants, adhesives, preservatives, fragrances, moisturizers, physiologically active ingredients, salts, dissolution, chelating agents, neutralizers, pH adjusters, water, and other ingredients, etc. . Take powder as an example, such as red 104, red 201, yellow 4, blue 1, black 401, etc., yellow 4 A1 rouge, yellow 2〇 3 22 1255193 (four) marshmallow, etc. (four), nylon Powder, silk powder, ester powder, special gas powder, strontium powder, cellulose powder, Shixi synthetic rubber, chitin M and other polymers, oxygen, double sugar, alginic acid, group main, iron, black oxidation Iron, chrome oxide, black carbon, moon-hanging enamel coloring paint, 4 gluten Λ = - paint, stone dry, too, emulsified lead, bismuth oxide, etc. white stone m, riding, dip, clay, gambling , oxygen touch, magnesium oxyacid, frequency Ming, frequency magnesium and other body f paint, fine particles 2, miscellaneous sub-error, microparticle oxygen (10), and other materials anti-purple powder -, fiber _, 4 soil 1 (four). The shape and size of the chore are not limited. f, the above powder 'may (4) know various kinds of money and silk treatment, such as h oxime treatment, Wei treatment, fluorochemical treatment, metal treatment, hydrazine treatment, fatty acid treatment, N- hydrazine acid treatment, water Heterogeneous polymer compound treatment, resin treatment, plasma treatment, machine chemical treatment, etc. can be classified into zero oil, which can be divided into mobile stone soil, thirty carbon burned, 2-ethylhexanol hexadecane, and fourteen /, propyl eucalyptus oil, sesame oil and other liquid oil, petrolatum, solid sarcophagus, tallow, water-containing lanolin, dense soil, recorded bad, cholestyritol and other semi-solid ~ solid fat 'mine mining, 22 burning alcohol and other advanced Alcohol, palmitic acid, glycerol tristearic acid vinegar and other high-grade linonic acid, poly Weilu, and Wei Weilin conductor. 23 1255193 Interface active agent, can be divided into sorbitan fatty acid ester, glycerol fatty acid
酉曰♦環氧乙烯（以下簡稱POE)、山梨糖醇酐脂肪酸酯、poE 甘油脂肪酸酯、P0E烷基醚、P〇E聚環氧丙烯烷基醚、p〇E聚 環氧丙烯協體、P〇E烷基苯基醚、P〇E硬化毘麻油、聚乙二 醇月曰肪酸自旨、十甘油脂細瓣、烧基二乙醇胺等非等離子性 ;1面活性劑、烧基硫酸鹽、POE烧基醚硫酸鹽、poe烧基醚 醋酸鹽、烷基磷酸鹽、POE烷基醚磷酸鹽、高級脂肪酸鹽、 高級脂肪酸加水分解膠元鹽、氨基酸系負離子性介面活性 劑、_脂、醋酸甜菜驗系等兩性介面活性劑、氯化烧三甲 基叙、氣化二絲二甲基銨、氯化二絲二曱基絲銨等正 離子性介面活性劑。 醇，可分為乙醇、丙醇、苯甲醇等一價醇，1，3 丁二醇、 丙一酉子、一縮二丙二醇、丙三醇、聚乙二醇、山梨糖醇等多 價醇。 而刀子化&物可分為聚乙烯比⑥酮、乙烯基比各烧 酮酉曰酉夂乙烯’“物、丙烯基樹脂烧醇胺、醋酸乙烯基丁烯酸 聚合物 '曱基乙_順丁烯二酸單絲酯聚合物、N—甲基丙 稀竜乙基-N、N-二甲基銨1—N—甲基麟甜菜驗/甲 基丙稀酸細旨聚合物、二乙基魏〔縣祕細—N、N— 24 1255193 二甲基氨基乙基甲基丙烯酸聚合物、羧基乙基纖維素二曱基 鄰笨一甲酸銨氯、缓基乙稀高分子、羧基甲基纖維素鹽、經 乙基纖維素等。 工 除上述成分外，另可加上氨基酸、透明質酸等保溫劑、 羥基苯、對氨基笨酸等紫外線吸收劑、維生素E、二丁_甲 苯等抗氧化劑、苯氧基乙醇等防腐劑、異丙基甲基_婦等 殺菌劑、膠原、絹等蛋白f加水分解物、檸檬酸、棒樣酸納 等PH調整劑、植物抽出濃縮液、氨基乙酸等消炎劑、氯化 鈉等無機鹽、螯合劑、色素、香料等。 以下，就代表性實關加以綱，另，鱗方並不限於 本發明之技術範圍内。且化妝品配合量表示，若無特別標 明’皆以質频為單位。在正式制實施例之前，先就本發 明所用效果貫驗方法加以說明。 實驗方法：評價項目分為__、自然透明感、補正 肌膚缺陷（細紋、色斑等）效果，由2〇位專業受驗者進行 使用測試。基於町所舰準合計各受驗者評價。 (評價分數基準） 5分：非常優異。 25 1255193 4分：優異。 3分：普通。 2分：惡劣。 1分：非常惡劣。 (評價基準） ◎:合計分數80分以上。 〇：合計分數60分以上，未滿80分。 △:合計分數40分以上，未滿60分。 X:合計分數未滿40分。 列於第1表實施例1〜2、對照例1〜2處方中之粉餅， 與第1表所示1〜12加以攪拌混合後，均一加熱混合後與13 〜20混合。粉碎所得混合物，以容器成形後所調製而成。 第1表 實施例 對照例 成分 1 2 1 2 1 滑石 9 9 9 9 2 雲母 10 10 10 10 3 絹雲母 18 18 18 18 4 合成雲母 15 15 15 15 5 本發明製造例3之剝離組成物 15 6 本發明製造例4之剝離組成物 15 7 硫酸鋇 5 5 5 5 8 氧化鈦 12 12 12 12 1255193 9 氧化鐵 4 4 4 4 10 氧化鈦被覆雲母（紅干涉） 15 11 氧化鈦被覆雲母（黃干涉） 15 12 氮化硼 2 2 2 2 13 凡士林 2 2 2 2 14 二甲基聚矽氧烷 3 3 3 3 15 液體石鱲 2 2 2 2 16 三異辛酸甘三醇 2 2 2 2 17 倍半異硬脂酸甘三醇 1 1 1 1 18 防腐劑 適量 適量 適量 適量 19 防氧化劑 適量 適量 適量 適量 20 香料 適量 適量 適量 適量 上述實施例1〜2，對照例1〜2之感官實驗評價結果列 於第2表。 第2表酉曰♦Epoxyethylene (hereinafter referred to as POE), sorbitan fatty acid ester, poE glycerin fatty acid ester, P0E alkyl ether, P〇E polyepoxy propylene alkyl ether, p〇E polyepoxypropylene copolymer Body, P〇E alkylphenyl ether, P〇E hardened sesame oil, polyethylene glycol ruthenium acid, non-plasma such as decaglycerin fine valvule, decyl diethanolamine; 1 surface active agent, burning Sulphate, POE alkyl ether sulfate, poe alkyl ether acetate, alkyl phosphate, POE alkyl ether phosphate, higher fatty acid salt, higher fatty acid plus water-decomposing gelatin salt, amino acid negative ion interface, _ Lipid, acetic acid beet test and other amphoteric surfactants, chlorinated trimethyl sulphide, gasified di- dimethylammonium chloride, chlorinated diterpene sulphate ammonium and other positive ionic surfactants. Alcohol can be divided into monovalent alcohols such as ethanol, propanol and benzyl alcohol, polyvalent alcohols such as 1,3 butanediol, propylene glycol, dipropylene glycol, glycerol, polyethylene glycol and sorbitol. . The knife and the material can be divided into a polyethylene ratio of 6 ketone, a vinyl ratio of each ketone oxime ethylene '", a propylene-based resin, an alkanolamine, a vinyl acetate butyric acid polymer, a thiol _ Maleic acid monofilament ester polymer, N-methyl propyl hydrazine ethyl-N, N-dimethylammonium 1-N-methyl lin beet test / methyl acrylate acid fine polymer, two Ethyl Wei [County Secret - N, N - 24 1255193 Dimethylaminoethyl methacrylic acid polymer, carboxyethyl cellulose dimercapto-indolyl ammonium chloroformate, sulphur-based ethylene polymer, carboxyl group Base cellulose salt, ethyl cellulose, etc. In addition to the above ingredients, an amino acid, hyaluronic acid and other heat insulating agents, hydroxybenzene, amino acid and other ultraviolet absorbers, vitamin E, dibutyl-toluene may be added. Such as antioxidants, phenoxyethanol and other preservatives, isopropyl methyl _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ An anti-inflammatory agent such as glycine, an inorganic salt such as sodium chloride, a chelating agent, a coloring matter, a fragrance, etc. In addition, the scales are not limited to the technical scope of the present invention, and the amount of cosmetic ingredients indicates that unless otherwise specified, 'all are in mass frequency. Before the formal embodiment, the effect of the invention is tested first. The method is described. Experimental methods: The evaluation items are divided into __, natural transparency, and correction of skin defects (fine lines, stains, etc.), which are tested by 2 professional subjects. Evaluation by the subject. (Evaluation score benchmark) 5 points: Very good. 25 1255193 4 points: Excellent. 3 points: Normal. 2 points: Bad. 1 point: Very bad. (Evaluation criteria) ◎: Total score of 80 points or more 〇: The total score is 60 or more, less than 80. △: The total score is 40 or more, less than 60. X: The total score is less than 40. Listed in Table 1 Example 1~2, Comparative Example 1 The powder cake in the prescription of 2 is stirred and mixed with 1 to 12 shown in Table 1, and then uniformly mixed by heating and mixed with 13 to 20. The obtained mixture is pulverized and prepared by molding the container. Example composition 1 2 1 2 1 slip 9 9 9 9 2 Mica 10 10 10 10 3 Sericite 18 18 18 18 4 Synthetic mica 15 15 15 15 5 Release composition of Production Example 3 of the present invention 15 6 Release composition of Production Example 4 of the present invention 15 7 Barium sulfate 5 5 5 5 8 Titanium oxide 12 12 12 12 1255193 9 Iron oxide 4 4 4 4 10 Titanium oxide coated mica (red interference) 15 11 Titanium oxide coated mica (yellow interference) 15 12 Boron nitride 2 2 2 2 13 Vaseline 2 2 2 2 14 dimethyl polyoxyalkylene 3 3 3 3 15 liquid sarcophagus 2 2 2 2 16 triisooctanoic acid glycerol 2 2 2 2 17 sesquiisostearic acid 1 1 1 1 18 preservative Appropriate amount of appropriate amount of appropriate amount of 19 antioxidants appropriate amount of appropriate amount of appropriate amount of 20 flavor appropriate amount of appropriate amount of the appropriate amount of the above Examples 1 to 2, the results of sensory evaluation of Comparative Examples 1 to 2 are listed in the second table. Table 2
實施例 對照例 1 2 1 2 滑順使用觸感 ◎ ◎ 〇 〇 自然透明感 ◎ ◎ X X 可抑制色斑之干涉作用 (肌膚缺陷補正效果） 〇 〇 〇 〇 光致變色效果 X ◎ X X 另，表中所列光致變色效果，印有◎表示非常高，X則無。EXAMPLES Comparative Example 1 2 1 2 Smooth touch feeling ◎ ◎ 〇〇 Natural transparency ◎ ◎ XX can suppress interference of color spots (skin defect correction effect) 〇〇〇〇 Photochromic effect X ◎ XX The photochromic effects listed are marked with ◎ indicating very high and X being absent.
從第2表可知，配合本發明製造例3、製造例1以及製 造例4之實施例2，其剝離組成物擁有滑順使用處趕及自然 透明感，且干涉作用能有效抑制色斑（肌膚缺陷補正效果）； 27 1255193 另，實施例2尚且具優異光致效果。 另方面，以氧化鈦被覆雲母代替本發明剝離組成物之對 照例1、對照例2，其滑順使用觸感、自然透明感、光致效 果皆惡劣，可得知無法發揮本發明效果。 以下就各種處方列出本發明化妝品之實施例。另對此類 化妝品進行上述感官實驗，得所有實施例之本發明化妝品皆 具優異效果。 實施例3 固體粉餅 IB1 兰成分 1 聚矽氧院處理絹雲母 _ 15 2 聚矽氧院處理合成雲母 15 ^_ 3 氧烷處理合成滑石 些許^S---- 4 本發明製造例2之聚矽氧烷處理剝離組成物 15 ^^^_ 5 矽氧院處理球狀二氧化矽 5 ^ 6 氮化硼 2 ^__ 7 p矽氧烷處理氧化鈦 10 ^s_ 8 夕氧烷處理微粒子氧化鈦 7 ^^_ 9 聚矽氧院處理氧化鐵 4 10 聚矽氧烷處理氧化亞鉛 5 ---^-__ 11 三十碳烷 3 12 二甲基聚矽氧烷 4 ------- 13 甲基丙基聚矽氧烷 3 ^^_ 14 桂皮酸鹽（Octyl methoxy cinnamate) 15 倍半異硬脂酸甘三醇 _ 1 ^^_ 16 石蠘 適量 ''''' 一'〜—--- 17 防氧化劑 1S^^^^_ 18 香料 適量^S^ - ^^^^_ 28 1255193 將1〜10各成分予以混合粉碎，與11〜18成分混合後 加以攪拌，再將粉碎後所得者置入容器内填充成形，形成固 體粉餅。 實施例4 水中油性乳化化妝品 配 合成分 配合量（質量％) 1 精製水 a： F午 2 丙二醇 4 3 丙三醇 2 4 偏磷酸鈉 適 董 5 皂土 1.5 6 氫氧化鉀 0.5 7 棕櫚酸 1.1 8 三甲基苯酸 1 9 氧化鈦 10 10 氧化鐵 適量 11 本發明製造例4之剝離組成物 10 12 氧化鈦被覆板狀硫酸鋇 3 13 滑石 5 14 雲母 2 15 球狀二氧化矽 3 16 甘油一硬脂酸酯 1 17 單三甲基苯酸聚環氧山梨糖醇酐 0.5 18 十六醇 0.4 19 鯊肝醇 0.5 20 流動石鱲 5 21 二甲基聚矽氧烷 5 22 對桂皮酉变（para methoxy cinnamate) 2-乙基 3 23 防腐劑 適量 24 香料 適量 將1〜5各成分均勻攪拌混合，加入6〜8中予以混合， 1255193 再將混合粉碎後之9〜15予以分散。加熱溶解後均勻添加16 〜25以行乳化，得水中油性乳化化妝品。 實施例5 油中水性乳化化妝品 配 合成分 配合量（質量％) 1 聚矽氧烷處理纖維素粉 5 2 本發明製造例1之聚矽氧烷處理剝離組成物 12 3 聚矽氧院處理氧化鈦被覆硫酸鋇 4 4 聚矽氧院處理氧化鈦 10 5 聚矽氧烷處理氧化鐵 4 6 聚矽氧烷處理滑石 3 7 聚矽氧烷處理合成雲母 4 8 精製水 rp 9 一縮二丙二醇 8 10 十甲基環戊矽氧烷 25 11 十二甲基環六矽氧烷 15 12 二甲基聚聚氧烷 4 13 聚矽氧烷樹脂 2 14 聚醚變性矽 l.f 15 院基·聚醚雙變性矽 I 0.5 1 16 二甲基苯酸 1 17 防氧化劑 適量 18 防腐劑 適量 將10〜18各成分均勻混合後加入1〜7各成分，混合粉 碎後加入分散。接著均勻混合溶解後加入8〜9予以乳化， 填充進容器後得油中水性乳化化妝品。 實施例6 眼影 配合成分 |配合量（質量％) 1255193 1 滑石 些許 2 絹雲母 6 3 合成雲母 12 4 球狀PMMA粉末 3 1 5 1 板狀硫酸鋇 -1- 2 i z」 6 本發明製造例3之剝離組成物 8 7 氧化鐵 2 8 氮化硼 3 9 三十碳院 2 10 二甲基聚矽氧烷 2 11 單油酸山梨糖醇酐 1 12 防腐劑 適量 13 香料 適量 將1〜8各成分混合粉碎、加上9〜13各成分混合後擾拌， 於中皿内成形即得眼影。 實施例7 油性粉底乳 配 合成分 配合量（質量％) 1 棕櫚鱲 1 2 小燭樹鱲 2 3 純地鱲 10 4 三十碳院 些許 5 三異辛酸甘三醇 9 6 雙異硬脂酸甘三醇 11 7 高黏度二甲基聚矽氧烷 6 8 低黏度二甲基聚矽氧烷 5 9 聚矽氧烷樹脂 7 10 羥基丙基一/3 —環糊精 i 1 11 馬卡達姆堅果油脂肪酸膽巢基 3 12 矽酸鈉鎂 0.5 13 疏水性氧化矽 O.f 14 精製水 2 1255193As is apparent from the second table, in the production example 3, the production example 1 and the second embodiment of the production example 4, the peeling composition has a smooth use and a natural transparency, and the interference can effectively suppress the color spots (skin Defect correction effect); 27 1255193 In addition, Example 2 still has an excellent photo-induced effect. On the other hand, in the case of the titanium oxide-coated mica instead of the exfoliation composition of the present invention, the sliding property, the natural transparency, and the photo-effect were all poor, and it was found that the effect of the present invention could not be exhibited. Examples of the cosmetic of the present invention are listed below in terms of various prescriptions. Further, the above sensory test was carried out on such a cosmetic, and the cosmetics of the present invention of all the examples were excellent. Example 3 Solid powder cake IB1 Blue component 1 Polyxanthine treatment sericite _ 15 2 Polyoxan treatment of synthetic mica 15 ^ _ 3 Oxygen treatment of synthetic talc slightly ^ S - 4 - The invention of the production example 2 Deuterium treatment of stripping composition 15 ^^^_ 5 treatment of spherical cerium oxide 5 ^ 6 boron nitride 2 ^__ 7 p oxane treatment of titanium oxide 10 ^ s_ 8 oxirane treatment of particulate titanium oxide 7 ^^_ 9 Polyoxane treatment of iron oxide 4 10 Polyoxane treatment of lead oxide 5 ---^-__ 11 triacontan 3 12 dimethyl polyoxane 4 ------ - 13 Methylpropyl polyoxyalkylene 3 ^^_ 14 Octyl methoxy cinnamate 15 sesquisyl succinate _ 1 ^^_ 16 蠘 蠘 ' ' ' ' ' ' ' ' ' ' —--- 17 Antioxidant 1S^^^^_ 18 Perfume amount ^S^ - ^^^^_ 28 1255193 Mix 1 to 10 ingredients, mix with 11~18 ingredients, stir, then crush The latter is placed in a container and filled to form a solid powder cake. Example 4 Ingredients in water-based emulsified cosmetic compound (mass %) 1 purified water a: F noon 2 propylene glycol 4 3 glycerol 2 4 sodium metaphosphate suitable for Dong 5 bentonite 1.5 6 potassium hydroxide 0.5 7 palmitic acid 1.1 8 Trimethyl benzoic acid 19 TiO 2 10 10 Iron oxide 11 The peeling composition of the production example 4 of the present invention 10 12 Titanium oxide coated platy barium sulfate 3 13 Talc 5 14 Mica 2 15 Spherical cerium oxide 3 16 Glycerol Stearate 1 17 monotrimethyl benzoate polyepoxysorbitol 0.5 18 hexadecanol 0.4 19 shark liver alcohol 0.5 20 mobile sarcophagus 5 21 dimethyl polyoxy siloxane 5 22 桂 桂 酉Para methoxy cinnamate) 2-ethyl 3 23 Preservatives Appropriate amount 24 Perfume and appropriate ingredients 1 to 5 ingredients are uniformly stirred and mixed, added to 6 to 8 to be mixed, 1255193 and then dispersed and pulverized 9 to 15 to be dispersed. After heating and dissolving, 16 to 25 are uniformly added for emulsification to obtain an oily emulsified cosmetic in water. Example 5 Aqueous Emulsified Cosmetics in Oil Ingredients (% by mass) 1 Polysiloxane treatment of cellulose powder 5 2 Polypyrone treatment of exfoliation composition of Production Example 1 12 3 Polyoxynitride treatment of titanium oxide Coated barium sulfate 4 4 Polyoxane treatment of titanium oxide 10 5 Polyoxane treatment of iron oxide 4 6 Polyoxane treatment of talc 3 7 Polyoxane treatment of synthetic mica 4 8 Refined water rp 9 Dipropylene glycol 8 10 Decamethylcyclopentaoxane 25 11 dodecylcyclohexaoxane 15 12 dimethylpolyoxyalkylene 4 13 polydecane oxide resin 2 14 polyether denatured 矽lf 15矽I 0.5 1 16 Dimethyl benzoic acid 1 17 Antioxidant amount 18 Preservatives The ingredients of 10 to 18 are uniformly mixed, and then the components of 1 to 7 are added, mixed and pulverized, and then dispersed. Then, it is uniformly mixed and dissolved, and then 8 to 9 is added to emulsify, and after filling into a container, an aqueous emulsified cosmetic in oil is obtained. Example 6 Eyeshadow compounding component|Compounding amount (% by mass) 1255193 1 Talc a little 2 Sericite 6 3 Synthetic mica 12 4 Spherical PMMA powder 3 1 5 1 platy barium sulfate-1- 2 iz" 6 Production example 3 of the present invention Peeling composition 8 7 Iron oxide 2 8 Boron nitride 3 9 Thirty carbon yard 2 10 Dimethyl polyoxane 2 11 Monooleic acid sorbitan 1 12 Preservative amount 13 Perfume amount 1 to 8 each The ingredients are mixed and pulverized, and 9 to 13 ingredients are mixed and then scrambled, and the eyeshadow is formed by forming in the middle dish. Example 7 Oily foundation milk with ingredients (% by mass) 1 Palm 鱲 1 2 Small candle tree 鱲 2 3 Pure earth 鱲 10 4 30 carbon house slightly 5 Triisooctanoic acid glycerol 9 6 bisisostearate Triol 11 7 High viscosity dimethyl polyoxane 6 8 Low viscosity dimethyl polyoxyalkylene 5 9 Polyoxyalkylene resin 7 10 Hydroxypropyl one / 3 - Cyclodextrin i 1 11 Macadam Nut oil fatty acid cholesteryl 3 12 sodium citrate 0.5 13 hydrophobic cerium oxide Of 14 refined water 2 1255193
將加熱至7〇1之u，分散加入12 中，再將均勻溶解之10加 入’充分搜拌。再加人另行加埶溶經 ，合解之1〜9内後充分攪拌，再加 入15 20後分散麟，最後置人容器中填充成形為油性粉底乳。 實施例8 口紅Heat to 7 〇1 u, disperse into 12, and add 10 uniformly dissolved into 'full mix. Add another person to dissolve the solution, dissolve it within 1~9, stir it, add 15 20 and then disperse the lining. Finally, fill it into a container to form oily foundation. Example 8 Lipstick
配 合 成分 ^~~~… - 配含量（質 1 聚乙 jti~~ _ —-- 1 i 2 純地鱲 - 2 —^^ 3 含水羊毛脂 ~~" 1〇丨 — 4 聚丁烯 些許 ^ 5 羊甲氧基桂皮酸鹽 9 ^ 6 一甲基聚矽氧烷 11 '^^^^~ 7 ss ^ -- 6 ^^— 8 9 氧化鈦 紅色201號 ' 5 ^^— 10 11 紅色202號 ' " 紅色223號 7 1 ； ^- 12 L_J 一—J J/J 球狀聚乙烯粉末 J 0.5 13 本發明製造例3之剝離組成物 0.5 14 防氧化劑 … 2 15 香料 2·ί; —-^ —^—J 將1〜7加熱溶解後充分混合，將此液體加入8〜11，用三 32 1255193 輥混煉機加以混煉，將混煉漿加熱至80°C後加入12〜15攪拌 混合，填充至口紅成形容器中即得口紅。 實施例9 防曬噴霧劑 配 合成分 配合量（質量％) 1 聚矽氧烷處理微粒子氧化亞鉛 11 2 本發明製造例1之聚矽氧烷處理剝離組成物 12 3 十甲基環戊矽氧烷 18 4 氟化矽樹脂 6 5 聚矽氧烷彈性體球形粉體 10 6 巷土 0.8 7 甲基丙基聚矽氧烷 35 8 二甲基聚矽氧烷 7.2 9 防腐劑 適量 將1〜9各成分以分散器混合分散後，與不鏽鋼球一同填 充至容器内其可得成品。另，本產品須先搖晃再行使用。 實施例10 打底用固態乳液 配 合成分 配合量（質量％) 1 辛甲氧基桂皮酸鹽 5 2 山梨糖酐醇倍半異硬酯 1.5 3 異硬脂酸甘三醇 1.5 4 聚環氧乙烯二甲基聚矽氧烷甲基 0.2 5 二甲基矽酮(低沸點） 26.4 6 二甲基矽酮(高沸點） 4.0 7 本發明製造例2之聚矽氧烷處理剝離組成物 2.0 8 聚矽氧烷處理氧化鈦 1.0 9 聚矽氧烷處理微粒子氧化鈦 6.0 10 聚矽氧烷處理絹雲母 2.0 11 聚矽氧烷雲母 6.0 1255193 12 旨粉末 13 防氧化劑 14 —— 15 精製水 16 17 防腐劑 _ 18With ingredients ^~~~... - with content (quality 1 polyethyl jti~~ _ —-- 1 i 2 pure earthworm - 2 -^^ 3 water-containing lanolin ~~" 1〇丨-4 polybutene ^ 5 sheep methoxy cinnamate 9 ^ 6 monomethyl polyoxane 11 '^^^^~ 7 ss ^ -- 6 ^^— 8 9 titanium oxide red 201 ' 5 ^^— 10 11 red No. 202 ' " Red 223 No. 7 1 ; ^- 12 L_J I-JJ/J Spherical polyethylene powder J 0.5 13 The peeling composition of Production Example 3 of the present invention 0.5 14 Antioxidant... 2 15 Perfume 2·ί; -^ —^—J After heating and dissolving 1~7, mix well, add this liquid to 8~11, mix with three 32 1255193 roll kneader, heat the mixing slurry to 80 °C and add 12~15 The mixture was stirred and filled, and filled into a lipstick-forming container to obtain a lipstick. Example 9 Sunscreen spray compounding amount (% by mass) 1 Polysiloxane treatment of fine particles of lead oxide 11 2 Treatment of the polyoxane of Production Example 1 of the present invention Stripping composition 12 3 decamethylcyclopentaoxane 18 4 fluorinated fluorene resin 6 5 polyoxyalkylene elastomer spherical powder 10 6 road soil 0.8 7 methyl propyl Polyoxymethane 35 8 Dimethylpolyoxane 7.2 9 Preservatives The ingredients of 1 to 9 are mixed and dispersed in a disperser, and then filled into a container together with a stainless steel ball to obtain a finished product. First, shake it and use it again.Example 10 Solid emulsion for base compounding amount (% by mass) 1 Octyloxycinnamate 5 2 Sorbitol sesquiisosyl 1.5 3 Isostearic acid 1.5 4 Polyethylene oxide dimethyl polyoxyalkylene methyl 0.2 5 dimethyl fluorenone (low boiling point) 26.4 6 Dimethyl fluorenone (high boiling point) 4.0 7 Polyoxane treatment of Production Example 2 of the present invention Stripping composition 2.0 8 Polyoxyalkylene treated titanium oxide 1.0 9 Polyoxyalkylene treated fine particles titanium oxide 6.0 10 Polyoxyalkylene treated sericite 2.0 11 Polyoxyalkylene mica 6.0 1255193 12 Purpose powder 13 Antioxidant 14 - 15 Refined water 16 17 Preservatives _ 18
之：〜6混：熱至8°。。，力，後均勻_· ^入12後Vd，於另行製作出之16中，加入η，再加 二使成均勻溶液，加入18後加熱至耽以形乳化。加入 13〜14後脫氣、填充至容軸冷卻即得成品。 實施例11 指甲油It: ~6 mixed: hot to 8 °. . , force, after uniform _· ^ into the Vd after 12, in the separately made 16, add η, add two to make a homogeneous solution, add 18 and then heat to 耽 to shape emulsification. After adding 13~14, degassing and filling to the shaft cooling to obtain the finished product. Example 11 Nail Polish
將1〜3及7〜8以熱輥混煉充分混煉，再與添加4〜6之10 充分混煉，攪拌均勻後加人9巾以行分散，填充至容器内即 34 1255193 得指甲油。 、另’本發明之高虹彩色氧化鈦組成物，除用於化妝品、 塗料、墨水外，另可有效應用於麵、戦光機能性材料上。 、2上所述，本發提供—種藉干涉色產生卓越光亮 感:高鮮明色彩’且餘色不混濁之高虹彩色氧化鈦組成物。 此间虹衫色氧化鈦組成物’係於其糾狀基質表面行程被覆 層，、薄片狀基質片形大小約50〜800//m，厚度則為m6 卿該被覆層含有7〇〜95質量％之鈦組成物。由此被覆組成 物被覆層之鈦組成物被覆層所剝離形成之剝離組成物，即為 兩虹彩氧化鈦組成物。再者，將蘭離之高虹彩色氧化鈦組 成物(本文中稱為剝離組成物），用作化妝品中，可提供優異 之滑順使削«、自然透日M、且干涉侧可抑制肌膚 色斑(肌膚触補正效果）、防紫外線效果、光致變色效果等。 【圖式簡單說明】 第1圖係本發明高虹彩色氧化鈦組成物之被覆組成物概念 圖。 第2圖係本發明高虹彩色氧化鈦組成物之製法概要圖。 第3圖係本發明被覆組成物之χ光線繞射分析結果圖表。 35 1255193 第4圖係本發明被覆組成物之氧化鈦表面狀態顯微鏡照片。 第5圖係本發明剝離組成物之氧化鈦組成物干涉色與鈦層膜 厚關係圖。 第6圖係剝離組成物之氧化鈦組成物顯微鏡照片。 第7圖係剝離組成物之氧化鈦組成物顯微鏡照片。 第8圖係本發明剝離組成物之氧化鈦組成物三次元光澤計分 析結果表。 【主要元件符號說明】 1薄片狀基質 2被覆層 2a剝離組成物Mix 1 to 3 and 7 to 8 by hot roll kneading, mix well with adding 4~6 to 10, stir evenly, add 9 towels to disperse, and fill into the container, ie 34 1255193, get nail polish. . Further, the high-yield titanium oxide composition of the present invention can be effectively applied to a surface or a calendering functional material in addition to cosmetics, paints and inks. According to the above description, the present invention provides a high iridescent titanium oxide composition which produces an excellent luminous sensation by an interference color: a high vivid color and a residual color is not turbid. Here, the rainbow-colored titanium oxide composition is attached to the surface coating layer of the shape-correcting substrate, and the sheet-like matrix has a sheet shape of about 50 to 800/m, and the thickness is m6. The coating layer contains 7 to 95% by mass. Titanium composition. The peeling composition formed by peeling off the coating layer of the titanium composition of the composition coating layer is a composition of two iridescent titanium oxides. Furthermore, the high-color titanium oxide composition of Lanhua (referred to herein as a peeling composition) is used as a cosmetic to provide excellent smoothness, natural penetration, and interference on the skin side. Color spots (skin touch positive effect), UV protection effect, photochromic effect, etc. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a conceptual view of a coating composition of a high iridescent titanium oxide composition of the present invention. Fig. 2 is a schematic view showing the production process of the composition of the high iridescent titanium oxide of the present invention. Fig. 3 is a graph showing the results of ray diffraction analysis of the coated composition of the present invention. 35 1255193 Fig. 4 is a photomicrograph of the surface state of titanium oxide of the coated composition of the present invention. Fig. 5 is a graph showing the relationship between the interference color of the titanium oxide composition of the peeling composition of the present invention and the film thickness of the titanium layer. Fig. 6 is a photomicrograph of the titanium oxide composition of the peeling composition. Fig. 7 is a photomicrograph of the titanium oxide composition of the peeling composition. Fig. 8 is a table showing the results of a three-dimensional gloss meter analysis of the titanium oxide composition of the peeling composition of the present invention. [Description of main component symbols] 1 flaky substrate 2 coating layer 2a peeling composition
3636
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