TR201902099T4 - Ham petrolden veya onun fraksiyonlarından itibaren düşük kaynama noktalı yakıt üretimi için fraksiyonsuz yöntem. - Google Patents

Ham petrolden veya onun fraksiyonlarından itibaren düşük kaynama noktalı yakıt üretimi için fraksiyonsuz yöntem. Download PDF

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TR201902099T4
TR201902099T4 TR2019/02099T TR201902099T TR201902099T4 TR 201902099 T4 TR201902099 T4 TR 201902099T4 TR 2019/02099 T TR2019/02099 T TR 2019/02099T TR 201902099 T TR201902099 T TR 201902099T TR 201902099 T4 TR201902099 T4 TR 201902099T4
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gas
liquid
crude oil
metal catalyst
reaction product
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TR2019/02099T
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W Gunnerman Rudolf
W Gunnerman Peter
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W Gunnerman Rudolf
W Gunnerman Peter
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Priority claimed from US12/551,264 external-priority patent/US7806947B2/en
Priority claimed from US12/651,592 external-priority patent/US8226817B2/en
Application filed by W Gunnerman Rudolf, W Gunnerman Peter filed Critical W Gunnerman Rudolf
Publication of TR201902099T4 publication Critical patent/TR201902099T4/tr

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/10—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with stationary catalyst bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G15/00—Cracking of hydrocarbon oils by electric means, electromagnetic or mechanical vibrations, by particle radiation or with gases superheated in electric arcs
    • C10G15/08—Cracking of hydrocarbon oils by electric means, electromagnetic or mechanical vibrations, by particle radiation or with gases superheated in electric arcs by electric means or by electromagnetic or mechanical vibrations
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/007—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 in the presence of hydrogen from a special source or of a special composition or having been purified by a special treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • C10G49/04—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing nickel, cobalt, chromium, molybdenum, or tungsten metals, or compounds thereof
    • B01J35/58—
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1025—Natural gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1051—Kerosene having a boiling range of about 180 - 230 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1055—Diesel having a boiling range of about 230 - 330 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1059—Gasoil having a boiling range of about 330 - 427 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature

Abstract

Mevcut buluş, bilhassa, hacim itibariyle en azından yaklaşık %50 metan içeren bir gazdan sıvı yakıt üretmek için aşağıdakileri içeren bir yönteme ilişkindir: (a) bu gaz (i) ham petrol veya sıvı petrol fraksiyonundan oluşan sıvı besleme stoku ve (ii) metal katalizör ızgarası ile temas ettirilir; bu sıvı besleme stoku ile bu metal katalizör ızgarasının her ikisi de bir reaksiyon kabı içinde, ham petrolün kaynama noktasının altında ve yaklaşık 80°C veya üzerinde bir sıcaklıkta bulunur; bu metal katalizör ızgarasının, demir çerçeve üzerinde destekli geçiş metali sargıları vardır; (b) bu reaksiyon kabında oluşan gaz tepkime ürününün geri kazanılır; ve (c) bu gaz tepkime ürününün bu sıvı yakıt haline yoğunlaştırılır.

Claims (4)

  1. ISTEMLER 1) Yöntem olup, hacim itibariyle en azindan yaklasik %50 metan içeren bir gazdan sivi yakit üretmek içindir; özelligi asagidakileri içermesidir: (a) bu gaz (i) ham petrol veya sivi petrol fraksiyonundan olusan sivi besleme stoku ve 5 (ii) metal katalizör izgarasi ile temas ettirilir; bu sivi besleme stoku ile bu metal katalizör izgarasinin her ikisi de bir reaksiyon kabi içinde, ham petrolün kaynama noktasinin altinda ve yaklasik 80°C veya üzerinde bir sicaklikta bulunur; bu metal katalizör izgarasinin, demir çerçeve üzerinde destekli geçis metali sargilari vardir; (b) bu reaksiyon kabinda olusan gaz tepkime ürününün geri kazanilir; ve 10 (o) bu gaz tepkime ürününün bu sivi yakit haline yogunlastirilir.
  2. 2) Istem 1'e uygun yöntem olup, özelligi bu gazin dogal gaz olmasidir.
  3. 3) Istem Te uygun yöntem olup, özelligi gazin dogal gaz olmasi ve sivi besleme stokunun ya ham petrol ya da dizel yagi olmasidir.
  4. 4) Istem 1'e uygun yöntem olup, özelligi sunlardir: 15 sivi besleme stoku, reaksiyon kabinin bir bölümünü kaplar ve böylece reaksiyon kabi içinde bir sivi seviyesi ve bu sivi seviyesinin üzerinde bir bosluk olusturur; metal katalizör izgarasi bu boslukta bulunur, (a) asamasi gazin bu reaksiyon kabina sivi seviyesinin altindan beslenmesini içerir ve (b) asamasi, gaz tepkime ürününün bu bosluktan geri kazanilmasini içerir. arasinda bir sicaklikta ve yaklasik 1 atmosfer ile yaklasik 1,5 atmosfer arasinda bir basinçta gerçeklestirilmesidir. 6) Istem 1'e uygun yöntem olup, özelligi çerçevenin, çeperin içinde destek çubuklari veya demir çubuklarla dis çap açisindan dairesel olmasi ve sargilarin çerçevenin merkezinde 25 birlesmesidir. 7) Istem 1'e uygun yöntem olup, özelligi bu sargilarin birçok geçis metalinden olmasi, bunlara demir bir çerçeve üzerinde kobalt, nikel, tungsten, krom ve alüminyum'un dâhil olmasidir. 8) Istem 1”e uygun yöntem olup, buradaki bu gaz birinci gaz olarak, bu gaz tepkime ürünü 30 birinci gaz tepkime ürünü olarak ve bu sivi yakit birinci kondensat olarak tanimlanmistir; özelligi ayrica asagidakileri içermesidir: (b) birinci kondensat ile metal katalizör izgarasindan hacim itibariyle en azindan yaklasik %50 metan içeren ikinci gaz geçirilir; bu birinci kondensat ile bu metal katalizör izgarasinin her ikisi de ikinci bir reaksiyon kabi içinde bulunur, bu birinci kondensat birinci kondensatin kaynama noktasinin altinda ve yaklasik 80°C veya üzerinde bir sicaklikta bulunur; bu metal katalizör izgarasinin, demir çerçeve üzerinde destekli geçis metali sargilari vardir; (0) ikinci gaz tepkime ürünü bu ikinci reaksiyon kabindan geri kazanilir; ve (d) bu ikinci gaz tepkime ürünü yogunlastirilarak bu sivi yakit olusturulur. 9) Istem 87e uygun yöntem olup, özelligi sivi besleme stokunun ham petrol olmasi ve hem birinci gazin hem de ikinci gazin her ikisinin de dogal gaz olmasidir. 10) Yöntem olup, ham petrolü boru hattiyla tasimak içindir; özelligi asagidakileri içermesidir: (a) hacim itibariyle en azindan yaklasik %50 metan içeren bir gaz, (i) ham petrol veya sivi petrol fraksiyonundan olusan sivi besleme stoku ve (ii) metal katalizör izgarasi ile temas ettirilir; bu sivi besleme stoku ve bu metal katalizör izgarasinin her ikisi de bir reaksiyon kabi içinde ham petrolün kaynama noktasinin altinda ve yaklasik 80°C veya üzerinde bir sicaklikta bulunur; bu metal katalizör izgarasinin, demir çerçeve üzerinde destekli geçis metali sargilari vardir; (b) bu reaksiyon kabinda olusan gaz tepkime ürünü geri kazanilir; ve (o) bu gaz tepkime Ürünü bu sivi yakit haline yogunlastirilir; (d) bu ham petrol olusan sivi yakitla harmanlanarak bir harman olusturulur; ve (e) bu harman bu boru hattindan pompalanir. 11) Istem 10'a uygun yöntem olup, özelligi sivi besleme stokunun ham petrol olmasi ve gazin dogal gaz olmasidir. 12) Istem 10`a uygun yöntem olup, özelligi (d) asamasinin yaklasik 150°C ile yaklasik 200°C arasinda bir sicaklikta ve yaklasik 1 atmosfer ile yaklasik 1,5 atmosfer arasinda bir basinçta gerçeklestirilmesidir. 13) Istem 10,a uygun yöntem olup, özelligi bu katalizörün demir çerçeve üzerinde kobalt, nikel, tungsten, krom ve alüminyum sargilar içermesidir.
TR2019/02099T 2009-08-31 2010-07-27 Ham petrolden veya onun fraksiyonlarından itibaren düşük kaynama noktalı yakıt üretimi için fraksiyonsuz yöntem. TR201902099T4 (tr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/551,264 US7806947B2 (en) 2009-08-31 2009-08-31 Liquid hydrocarbon fuel from methane assisted by spontaneously generated voltage
US12/651,592 US8226817B2 (en) 2010-01-04 2010-01-04 Non-fractionation process for production of low-boiling fuel from crude oil

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US8226817B2 (en) 2010-01-04 2012-07-24 Gunnerman Rudolf W Non-fractionation process for production of low-boiling fuel from crude oil
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