TR201809535T4 - 1,3,3,3-tetrafloropropen bazlı bileşim. - Google Patents
1,3,3,3-tetrafloropropen bazlı bileşim. Download PDFInfo
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- TR201809535T4 TR201809535T4 TR2018/09535T TR201809535T TR201809535T4 TR 201809535 T4 TR201809535 T4 TR 201809535T4 TR 2018/09535 T TR2018/09535 T TR 2018/09535T TR 201809535 T TR201809535 T TR 201809535T TR 201809535 T4 TR201809535 T4 TR 201809535T4
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- 239000000203 mixture Substances 0.000 title claims abstract description 21
- CDOOAUSHHFGWSA-OWOJBTEDSA-N (e)-1,3,3,3-tetrafluoroprop-1-ene Chemical compound F\C=C\C(F)(F)F CDOOAUSHHFGWSA-OWOJBTEDSA-N 0.000 title claims abstract description 12
- 239000003507 refrigerant Substances 0.000 claims abstract description 17
- 229920005862 polyol Polymers 0.000 claims abstract description 11
- -1 polyol esters Chemical class 0.000 claims abstract description 8
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000001816 cooling Methods 0.000 claims description 12
- 239000012530 fluid Substances 0.000 claims description 12
- 238000004378 air conditioning Methods 0.000 claims description 8
- 150000003077 polyols Chemical class 0.000 claims description 3
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 2
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 229920001289 polyvinyl ether Polymers 0.000 abstract description 14
- 239000000314 lubricant Substances 0.000 abstract description 7
- 239000000463 material Substances 0.000 description 10
- 239000003921 oil Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 230000001050 lubricating effect Effects 0.000 description 7
- 229920001515 polyalkylene glycol Polymers 0.000 description 7
- 238000000034 method Methods 0.000 description 5
- 238000005057 refrigeration Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 4
- 150000001735 carboxylic acids Chemical group 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical compound CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- QAERDLQYXMEHEB-UHFFFAOYSA-N 1,1,3,3,3-pentafluoroprop-1-ene Chemical compound FC(F)=CC(F)(F)F QAERDLQYXMEHEB-UHFFFAOYSA-N 0.000 description 1
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- 241001465805 Nymphalidae Species 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001336 alkenes Chemical group 0.000 description 1
- ZRYCZAWRXHAAPZ-UHFFFAOYSA-N alpha,alpha-dimethyl valeric acid Chemical compound CCCC(C)(C)C(O)=O ZRYCZAWRXHAAPZ-UHFFFAOYSA-N 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- UGODCLHJOJPPHP-AZGWGOJFSA-J tetralithium;[(2r,3s,4r,5r)-5-(6-aminopurin-9-yl)-4-hydroxy-2-[[oxido(sulfonatooxy)phosphoryl]oxymethyl]oxolan-3-yl] phosphate;hydrate Chemical compound [Li+].[Li+].[Li+].[Li+].O.C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP([O-])(=O)OS([O-])(=O)=O)[C@@H](OP([O-])([O-])=O)[C@H]1O UGODCLHJOJPPHP-AZGWGOJFSA-J 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M171/00—Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
- C10M171/008—Lubricant compositions compatible with refrigerants
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/126—Unsaturated fluorinated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/22—All components of a mixture being fluoro compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
- C10M2207/2835—Esters of polyhydroxy compounds used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
- C10M2209/043—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical used as base material
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- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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Abstract
Bileşim poliol esterler (POE) veya polivinil eterden (PVE) yapılmış en az bir yağlayıcı madde ve ağırlık olarak %1 ila 99 oranında trans-1,3,3,3-tetrafloropropen (trans HFO-1234ze) ve ağırlık olarak %1 ila 99 oranında 1,1,1,2-tetrafloroetan içeen bir soğutucu akışkan (F) içermektedir.
Description
TARIFNAME
1,3,3,3-TETRAFLOROPROPEN BAZLI BILESIM
madde içeren, sogutma, klimatizasyon ve Elîpompasia kullanmaya uygun bir bilesim ile
Atmosferik ozon tabakaleb zarar veren maddelerin teskil ettigi problemler,
kloroflorokarbonlarI (CFC) üretimi ve kullanIiIlEl azaItIJBiasIEI dayatan protokolün
imzalandlglüMontreal'de ele allEmlStlEl Bu protokol, CFC'nin kullanllIhamalelEldayatan
düzeltmelerin konusudur ve düzeltme hidrokloroflorokarbonlar (HCFC) gibi diger ürünleri de
kapsayacak sekilde genisletilmistir.
Sogutma ve klimatizasyon endüstrisi, bu sogutucu aklgkanlarl ikamesine çok yatlîlm
yapmlStlElve bu sayede hidroflorokarbonlar (HFC) ticarilestirilmistir.
Otomobil endüstrisinde, çok saylöh ülkede pazarlanan tasltîl klima sistemleri,
kloroflorokarbonlu (CFC-12) bir sogutucu aklgkandan ozon tabakasüçin daha az zararlljblan
hidroflorokarbonlu bir aklgkana ( geçmistir. Bununla birlikte,
Kyoto protokolü ile ortaya konan amaçlara istinaden, HFC- yüksek
düzeyde Eltîlna kuwetine sahip olarak varsayllBiaktadlEl Bir aklgkan sera etkisine katklgljbir
ölçüt ile belirtilmektedir; bu ölçüt, karbondioksit için 1 refereans degerini alan ElEma
kuvvetini gösteren GWP'dir (Global Warming Potential).
Hidroolefinler (HFO), düsük bir @Etna kuvvetine sahiptir ve dolaylgýla Kyoto protokolü ile
belirlenen amaçlara karsllâmaktadß JP 4-110388 numarallîpatent dokümanÇl Eljaktarli
maddesi olarak hidrofloropropenleri açllZlamaktadlB
Endüstriyel alanda, en çok kullanlßn sogutma makineleri, slîElbir sogutucu aklgkanl
buharlasma ile sogumalea dayanmaktadlEl Buharlasmadan sonra, slîljhale geçmesi ve
döngüyü takip etmesi amacMa aklgkan SIKIStlBEnakta, daha sonra sogutulmaktadlE
Kullanllân sogutma kompresörleri alternatif, kaydlElna, santirfüj veya vidalEltürdedir.
Genellikle kompresörlerin yaglanmaslZl hareket halinde olan araçlari aslEinaleI ve
Elihiasll azaltllBiasÇl bunlar. slîüünazlllîlarll ve korozyona karslîlkorunmalarll
tamamlanmasüçin zorunludur.
edilmesi için, özellikle yaglaylEEmaddeler ile uygunluk ve termik bir stabilite sergilemesi
gerekmektedir. Nitekim sogutucu aklg
kompresörde bulunan yaglaylEElmadde ile uyumlu olmasEloldukça arzu edilmektedir. Bu
sogutucu akiskan ve yaglayüjnadde birlesimi, sogutma sisteminin uygulanmasÜ/e etkinligi
için önemlidir, özellikle yaglaylîünadde, tüm çallgma süresi arallgllEUa sogutucu aklgkan
içinde yeterince çözünebilmek veya karlglabilmek zorundadlEl
DolayElýla polialkilen glikol (PAG), otomobil klimatizasyonunda HFC-134a yaglaylîünadde
olarak gelistirilmistir.
YaglayIEEmaddeler ile 1,1,3,3,3-pentafloropropen ve 1,3,3,3-tetrafloropropenin karlgbilirlik
Uygunluk deneyleri aynEtamanda polialkilen glikoller ile örnek 3'te açlElanmlStB Bununla
birlikte bu deneyler, 1,3,3,3-tetraflor0propenin izomerinin dogaslßelirtmemektedir.
patent dokümanlj bir yaglayEEl madde ve bir sogutucu aklgkan içeren bilesimleri
açIamaktadlB YaglaylEljnadde; poliol esterleri, polialkilen glikoller, polivinil etler, mineral
yaglarlZlalkilbenzenler, sentetik parafinler, sentetik naftenler ve poli(alfa)olef`inlerden olusan
grup araleUan seçilmektedir. Çok saylöla sogutucu aklskan kombinasyonlarüiçlElanmlStEl US
propen içeren bir bilesigi ve bir hidrofloroalken, bir iyodokarbür, bir poliol ester içeren bir ED
aktarIi bilesimi açiElamaktadlEl
YakI zamanda 2,3,3,3-tetrafl0ropropen, otomobil klimatizasyonunda HFC-134a'nI
degistirilmesi Için sogutucu aklQ
Basvuru sahibi simdi, sogutma, klimatizasyon ve IîüJompaleUa kullanlliiaya uygun olan bir
yaglaylEIjlnadde ve sogutucu aklSkanEbaglaslglâllîgelistirmistir.
Mevcut basvuru, poliol esterler (POE) veya polivinileter (PVE) bazllîdzn az bir yaglayiElIrlnadde
ve aglEliiKJ olarak %1 ila 99 oranIa trans- ve
aglElllKl olarak %1 ila 99 oran a 1,1,1,2-tetraflor0etan içeren bir sogutucu aklgkan (F) içeren
bir bilesimi amaçlamaktadlü
Tercihen, bulusa göre bilesim, poliol esterler (POE) veya polivinileter (PVE) bazlEén az bir
yaglaylElîl madde ve agElilE olarak %5 ila 95 oranIa trans-1,3,3,3-tetraflor0pr0pen
sogutucu aklgkan (F) içermektedir.
Özellikle tercih edilen bilesim, poliol esterler (POE) veya polivinileter (PVE) bazlEén az bir
yaglaylElîlmadde ve aglEllllZJ olarak %30 ila 91 oranIa trans-1,3,3,3-tetraflor0propen
sogutucu aklgkan (F) içermektedir.
Aklgkan (F) ayrlîla diger hidrofiorokarbonlarma içerebilmektedir.
Aklgkan (F), trans-HFO-1234ze ve ayrlEa POE veya PVE'nin varllgiIa aklSkan stabilitesi PAG
varliglüla trans-HFO-1234ze'ninkine göre daha yüksek oldugu için daha verimli olma
avantaj. sahiptir.
Poliol esterleri, bir monofonksiyonel karboksilik asit karlgiîlüle veya monofonksiyonel veya
plurifonksiyonel bir karboksilik asit ile bir poliolün (en az 2 hidroksi grubu, -OH Içeren bir
alkol) reaksiyonu ile elde edilmektedir.
Bu reaksiyon süsia olusan su, ters reaksiyonun (baska bir ifadeyle hidrolizin) önlenmesi
için elimine edilmektedir.
Mevcut bulusa göre, tercih edilen polioller; neopentil glikol gibi neopentil, trimetilol propan,
pentaeritritol ve dipentaeritritol çerçevesine sahip olanlardlü
Karboksilik asitler 2 ila 15 karbon atomu içerebilmektedir, çerçeve dogrusal veya dallanmlg
olabilmektedir. Özellikle n-pentanoik asit, n-heksanoik asit, n-heptanoik asit, n-oktanoik asit,
2-etilheksanoik asit, 2,2-dimetilpentan0ik asit, 3,5,5-terimetilheksanoik asit, adipik asit,
süksinik asit ve bunlari karElînllarIan bahsedilebilmektedir.
Bazüalkol fonksiyonlarlîlesterlesmemektedir, bununla birlikte oranlarEldüsük kalmaktadlE
Dolaylgýla PEO, -CHz-O-(C=O)- motiflerine göre CHz-OH motiflerinden %0 ila 5'i oranlEUa
içerebilmektedir.
cSt ve avantajllîblmasßç-an 30 ila 80 cSt'lik bir viskoziteye sahip olanlardlE
Polivinileter yaglarllPVE) tercihen asag-ki 2 motifin kopolimerleridir:
ÃCHÄCHLI/ ÄCHgCH/,Y
YagI özellikleri (viskozite, aklgkan çözünebilirligi ve özellikle aklgkan ile karlglabilirlik), m/n
oranü/e m+n toplamIEdegistirecek sekilde ayarlanabilmektedir. Tercih edilen PVE yaglarÇI
aglEIIDZJ olarak %50 ila 95 oranlEtla motif 1 içerenlerdir.
Bulusun tercih edilen bir biçimine göre yaglaylEElnadde, aglEIlllZl olarak bilesimin %10 ve
50'sini olusturmaktadlB
Aklgkan (F) aynüamanda koku verici bilesikler gibi katkünaddeleri içerebilmektedir.
Mevcut bulus aynüamanda, sogutma, özellikle de ev tipi, ticari sogutma, soguk odalar, g.
endüstrisi, proses, sogutmalEtasIia (kamyonlar, gemiler); klimatizasyon, özellikle ev tipi,
ticari veya endüstriyel klimatizasyonda; burada kullanilân teçhizatlar, sogutucular, dogrudan
genlesmeli teçhizatlardEve Egompalarüözellikle orta ve yüksek leiakHKta Ellompalaria
bahsedilen bilesimin kullanllßîaslßmaçlamaktadlü
Düsük lelaklilZJ kaymasEl(veya süzülme) sayesinde, mevcut bulusa göre bilesimler, kuru
genlesmeli buharlastlEEllâr ile ve Elak düzende çallglan buharlastlEIlIIE riIe tesitlerde
kullanilâbilmektedir.
DENEYSEL KISIM
Termik stabilite deneyleri, ASHRAE 97-2007: "sealed glass tube method to test the Chemical
stability of materials for use within refrigerant systems" standard. göre gerçeklestirilmistir.
Test kosullarüsaglki gibidir:
aklSkan kütlesi: 2,2 9
yaglaylEElmadde kütlesi: 5 g
slîlaklllîl 200°C
süre: 14 gün
YaglaylîElmadde 42,2 ml'Iik cam bir tüp içine koyulmustur. Tüp daha sonra vakumla
çekilmistir, bundan sonra da aklgkan (F) eklenmistir. Tüp böylece kapatilîhak üzere
Testin sonunda farlenalizler gerçeklestirilmistir:
-gaz fazÇlgaz fazEl
GC/MS tarafIan belirlenmektedir (kütle spektrometresi baglasllîl gaz fazEkromatograÜsi).
Böylece aklgkandan (F) gelen ve yaglayEEInaddeclen gelen katEkiIâr toplanmaktadE
- yaglaylîljmadde analiz edilmektedir: renk (spektrokolorimetre, Labomat DR Lange LIC0220
Model MLG131), nemlilik (Karl Fischer, Mettler DL37 kulonölçer ile) ve asit indisi (0,01 N
metanolik potas ile dozlama ile). 3 adet ticari yaglaylEÜlnadde test edilmistir: PAG ND8 yagü
POE Ze-GLES R868 yag Ele PVE FVC 68D yaglZl
PAG ND8 POE Ze-GLES RBGS PVE FVC 68D
1234ze 1234ze
ürünler: (HFO-
POE veya PVE varliglIa trans-HF01234ze'nin yaglaylîlîlnaddenin stabilitesini iyilestirildigi
belirlenmistir. Ayrüa POE varl[g]ia, aklgkan stabilitesi de iyilesmistir.
UYGU LAMALAR
Söz konusu karlSlElilarElkullanan sistemlerin termodinamik performansIZI
Hesaplama aletleri
RK-Soave denklemi, karlgiîllarl slîlîlbuharII denge verileri, yogunluklarü entalpileri,
entropilerinin hesaplanmasEliçin kullanHB1aktadB Bu denklemin kullanllüiasü söz konusu
karEIEJllarda kullanilân saf cisimlerin özelliklerinin ve her bir ikili için etkilesim katsayilârII
bilinmesini gerektirmektedir.
Her bir saf cisim içinde gereken veriler asag-ki gibidir:
Kaynama lelakligiÇl kritik lebkllEl ve basü, kaynama noktasIan kritik noktaya kadar
lehkligla göre baslik; egrisi, lelakllgb göre doymus slîEI/e doymus buhar yogunluklarEl
HFC'ye iliskin veriler ASHRAE Handbook 2005 bölüm 20'de yayIiIanmlgtlElve ayrlîla Refrop
altIa mevcuttur (sogutucu aklgkanlarl özelliklerinin hesaplanmasüçin NIST tarafIan
gelistirilen yazll]]îli).
HFO'nun slîlaklilîlbaslüç egrisine iliskin veriler statik yöntem ile ölçülmüstür. Kritik slîlaklilîlve
balelç, Setaram tarafIan pazarlanan bir C80 kalorimetresi ile ölçülmüstür. Slîlakligb göre
doymus olarak yogunluklar, Mines de Paris okulu Iaboratuvarlarlîltaraflüdan gelistirilen
titresimli tüpün yogunluk ölçer teknolojisi ile ölçülmüstür.
Ikili etkilesim katsaylêlü
RK-Soave denklemi, karSlEJi halindeki ürünlerin davranislar.. temsil edilmesi için ikili
etkilesim katsayiJârIEkuIlanmaktadlEl Katsayiiâr, slîElbuhar dengesine iliskin deneysel veriler
dogrultusunda hesaplanmlgtlîl SlîEbuhar dengesi ölçümleri için kullanllân teknik, analitik
statik hücre yöntemidir. Buhar dengesi, bir satir tüp içermektedir ve iki adet elektromanyetik
ROLSITM numune aIlElEDIe donatllBwlStE Bir sogutma termostatEbanyosu (HUBER HS40)
içine daldlEllmlgtlîl Degisken hlîüa dönen alan tarafIan tahrik edilen manyetik bir
çalkalama, dengelere ulasllB'iasIlj'ilîlandIEinak için kullanilIhIStE Numunelerin analizi, bir
katarometre (TCD) kullanan gaz fazlEUa kromatografi (HP5890 seri II) ile gerçeklestirilmistir.
HFC-134a / trans HFO-1234ze
HFC-134a / trans HFO-1234ze ikilisi üzerinde SEEbuhar dengesi ölçümleri asaglElhki izoterm
için gerçeklestirilmistir: 20°C
Baslik; sistemi
Burada bir buharlastlElEübir yogunlastlüELîlbir leHhuhar degistirici (dahili degistirici), vidaIEl
bir kompresör ve bir genlestirici ile donatilBiEkompresyon sistemi varsayilBiaktadlB
Sistem 15°C asIEDEIIîlna ve buharlastIEEB'e yogunlastlElEIZtElSIarßrasIa bir dahili degistirici
ile çallglnaktadlü
Kompresörlerin izentropik verimi kompresyon oranII fonksiyonudur. Bu verim, asagldhki
denkleme göre hesaplanmlgtlîi
nizen =a-b(r-c)2-T (1)
Bir vidalleompresör için, izentropik verim denklemi (1)nin a, b, c ve d sabitleri, Handbook
dogrultusunda hesaplanmlgtß
Performans katsaymCOP), sistem tarafIan tüketilen veya tedarik edilen güç üzerinde
sistem tarafIian saglanan kullanllân güç olarak belirlenmistir.
Lorenz performans katsaylglîl (COPLorenz) bir referans performans katsay-lEl Bu,
lethllZIarI fonksiyonudur ve farklüiklgkanlarECOP'larII karsllâstlülîhasütin kullanüüilgtlü
Lorenz performans katsaylîljsaglalaki sekilde belirlenmektedir:
(SlElakliElar (T) K cinsindendir)
Tortalama _ Tgiris Tçikis (2)
buharlastirici _ buharlastirici _ buharlastirici
Tortalama _ Tçikis Tgi'ri's (3)
Lorenz COP'sEikIimlendiriImis hava ve sogutma durumundadlB
buharla tirici
COPlorenz _ yogusturucu _ buharlastirici (4)
ortalama ortalama
Lorenz COP'sElElBIna durumundadlB
Tyogus turucu
COPlorenz _ yogus turucu buharlastirici (5)
ortalama ortalama
Her bir bilesim için, Lorenz döngü performansü katsayisi: karsiIJIZJ gelen slîlaklllîlar
dogrultusunda hesaplanmlgtlîl
Sogutma modunda sonuçlar
Sogutma modunda, kompresyon sistemi, -5°C'lik buharlasma slîlakllglüve 50°C'lik bir
yogusma slîlakllgiüraslütla çallglriaktadlîl
Her bir bilesim için bilesen degerleri (HFC- aglElllZl olarak yüzde
biçiminde verilmektedir.
Sogutma
Bhrls giris sckl (CO)
Yogusma sckl (C a)
Genlestirici sckl
Komp çlESlsckl (CO)
komp verimi
bhrIs B (bar)
lelakllgDrasIa çalßlnaktadlü
Her bir bilesim için bilesen degerleri (HFC- aglElllZl olarak yüzde
biçiminde verilmektedir.
Claims (1)
- ISTEMLER . Poliol esterler (POE) veya PVE bazllîdzn az bir yaglaylEÜnadde ve ag lEIllKl olarak %1 ila 99 oranIa trans- ve aglîliilîi olarak %1 ila 99 oran a 1,1,1,2-tetrafloroetan bar En bir sogutucu akiskan (F) içeren bilesim. . Sogutucu aklgkanI (F) aglHllEl olarak %5 ila 95 oranIda trans-1,3,3,3-tetrafl0ropropen ile karakterize edilen, Istem 1'e göre bilesim. . Sogutucu aklgkanI (F) ag lEIlllZl olarak %30 ila 91 oranIa trans-1,3,3,3-tetraflor0propen ile karakterize edilen, Istem 1 veya Z'ye göre bilesim. . POE'Ierin neopentil glikol gibi neopentil, trimetilol propan, pentaeritritol ve dipentaeritritol çerçevesine sahip olan poliollerden elde edilmesi ile karakterize edilen, Istemler 1 ila 3'ten herhangi birine göre bilesim. . POE'Ierin dogrusal veya dallanmlg) 2 ila 15 karbon atomuna sahip olan karboksilik aistten elde edilmesi ile karakterize edilen, Istemler 1 ila 4'ten herhangi birine göre bilesim. . POE'(Ier)in bilesimin aglElllKl olarak %10 ve 50'sini olusturmasEile karakterize edilen, Istemler 1 ila 5'ten herhangi birine göre bilesim. . Sogutma, klimatizasyon ve Elibompasia Istemler 1 ila 6'dan herhangi birine göre bilesimin kullanilÜiaslZl
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1057483A FR2964976B1 (fr) | 2010-09-20 | 2010-09-20 | Composition a base de 1,3,3,3-tetrafluoropropene |
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| TR2018/09535T TR201809535T4 (tr) | 2010-09-20 | 2011-08-10 | 1,3,3,3-tetrafloropropen bazlı bileşim. |
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|---|---|
| US (3) | US10119056B2 (tr) |
| EP (2) | EP3392323A1 (tr) |
| JP (4) | JP2012062469A (tr) |
| KR (1) | KR20120030948A (tr) |
| CN (2) | CN106010454B (tr) |
| AU (1) | AU2011224133B2 (tr) |
| CA (1) | CA2749095C (tr) |
| ES (1) | ES2676871T3 (tr) |
| FR (1) | FR2964976B1 (tr) |
| PL (1) | PL2431442T3 (tr) |
| PT (1) | PT2431442T (tr) |
| TR (1) | TR201809535T4 (tr) |
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| GB201002616D0 (en) | 2010-02-16 | 2010-03-31 | Ineos Fluor Holdings Ltd | Heat transfer compositions |
| GB201002617D0 (en) | 2010-02-16 | 2010-03-31 | Ineos Fluor Holdings Ltd | Heat transfer compositions |
| FR2957083B1 (fr) | 2010-03-02 | 2015-12-11 | Arkema France | Fluide de transfert de chaleur pour compresseur centrifuge |
| FR2959999B1 (fr) | 2010-05-11 | 2012-07-20 | Arkema France | Fluides de transfert de chaleur et leur utilisation dans des echangeurs de chaleur a contre-courant |
| FR2959997B1 (fr) | 2010-05-11 | 2012-06-08 | Arkema France | Fluides de transfert de chaleur et leur utilisation dans des echangeurs de chaleur a contre-courant |
| KR20130082095A (ko) * | 2010-05-20 | 2013-07-18 | 멕시켐 아만코 홀딩 에스.에이. 데 씨.브이. | 열전달 조성물 |
| FR2964977B1 (fr) | 2010-09-20 | 2013-11-01 | Arkema France | Composition a base de 3,3,3-tetrafluoropropene |
| FR2964975B1 (fr) | 2010-09-20 | 2012-08-24 | Arkema France | Composition a base de 2,3,3,3-tetrafluoropropene |
| FR2964976B1 (fr) * | 2010-09-20 | 2012-08-24 | Arkema France | Composition a base de 1,3,3,3-tetrafluoropropene |
| FR2976289B1 (fr) | 2011-06-07 | 2013-05-24 | Arkema France | Compositions binaires de 1,3,3,3-tetrafluoropropene et d'ammoniac |
| JP5880661B2 (ja) | 2012-12-26 | 2016-03-09 | 株式会社リコー | 光源装置及びこれを用いたプロジェクタ |
| FR3003569B1 (fr) | 2013-03-20 | 2015-12-25 | Arkema France | Composition comprenant hf et 1,3,3,3-tetrafluoropropene |
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2010
- 2010-09-20 FR FR1057483A patent/FR2964976B1/fr active Active
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2011
- 2011-08-10 TR TR2018/09535T patent/TR201809535T4/tr unknown
- 2011-08-10 EP EP18170764.7A patent/EP3392323A1/fr active Pending
- 2011-08-10 EP EP11177053.3A patent/EP2431442B1/fr not_active Revoked
- 2011-08-10 PT PT111770533T patent/PT2431442T/pt unknown
- 2011-08-10 PL PL11177053T patent/PL2431442T3/pl unknown
- 2011-08-10 ES ES11177053.3T patent/ES2676871T3/es active Active
- 2011-08-11 CA CA2749095A patent/CA2749095C/fr active Active
- 2011-08-25 TW TW107101568A patent/TWI654289B/zh active
- 2011-08-25 TW TW100130504A patent/TWI625321B/zh active
- 2011-08-25 JP JP2011183522A patent/JP2012062469A/ja active Pending
- 2011-09-14 US US13/232,106 patent/US10119056B2/en active Active
- 2011-09-16 CN CN201610365469.4A patent/CN106010454B/zh active Active
- 2011-09-16 CN CN201110274542.4A patent/CN102408876B/zh active Active
- 2011-09-16 KR KR1020110093525A patent/KR20120030948A/ko active Search and Examination
- 2011-09-20 AU AU2011224133A patent/AU2011224133B2/en active Active
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2014
- 2014-08-01 JP JP2014157797A patent/JP5974052B2/ja active Active
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2016
- 2016-05-24 JP JP2016103039A patent/JP6271639B2/ja active Active
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2017
- 2017-12-27 JP JP2017250287A patent/JP6467029B2/ja active Active
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2018
- 2018-09-27 US US16/143,505 patent/US10759983B2/en active Active
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2020
- 2020-07-13 US US16/927,242 patent/US11591504B2/en active Active
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