SU952101A3 - Способ получени диметилового эфира - Google Patents
Способ получени диметилового эфира Download PDFInfo
- Publication number
- SU952101A3 SU952101A3 SU731978809D SU1978809D SU952101A3 SU 952101 A3 SU952101 A3 SU 952101A3 SU 731978809 D SU731978809 D SU 731978809D SU 1978809 D SU1978809 D SU 1978809D SU 952101 A3 SU952101 A3 SU 952101A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- catalyst
- temperature
- zinc
- dme
- reactor
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 29
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 title 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims abstract description 72
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 57
- 239000003054 catalyst Substances 0.000 claims abstract description 44
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 23
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims description 27
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 23
- 239000007789 gas Substances 0.000 claims description 15
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 13
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 10
- 239000001569 carbon dioxide Substances 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- XUZDJUDKWXESQE-UHFFFAOYSA-N chromium copper zinc Chemical compound [Cr].[Zn].[Cu] XUZDJUDKWXESQE-UHFFFAOYSA-N 0.000 claims description 6
- DQIPXGFHRRCVHY-UHFFFAOYSA-N chromium zinc Chemical compound [Cr].[Zn] DQIPXGFHRRCVHY-UHFFFAOYSA-N 0.000 claims description 6
- 239000011541 reaction mixture Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 239000000047 product Substances 0.000 claims description 4
- 239000006227 byproduct Substances 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 239000000320 mechanical mixture Substances 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 2
- 239000005751 Copper oxide Substances 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 claims description 2
- 239000003245 coal Substances 0.000 claims description 2
- 229910000431 copper oxide Inorganic materials 0.000 claims description 2
- 238000002309 gasification Methods 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- -1 zinc-chromium-copper-aluminum Chemical compound 0.000 claims 2
- 238000012824 chemical production Methods 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- 239000004927 clay Substances 0.000 claims 1
- VODBHXZOIQDDST-UHFFFAOYSA-N copper zinc oxygen(2-) Chemical compound [O--].[O--].[Cu++].[Zn++] VODBHXZOIQDDST-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 abstract 2
- 238000003786 synthesis reaction Methods 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 230000018044 dehydration Effects 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- 238000002317 scanning near-field acoustic microscopy Methods 0.000 abstract 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- YXSIKEMDQWEQTO-UHFFFAOYSA-N copper zinc chromium(3+) oxygen(2-) Chemical compound [O-2].[Zn+2].[Cr+3].[Cu+2] YXSIKEMDQWEQTO-UHFFFAOYSA-N 0.000 description 1
- 229960004643 cupric oxide Drugs 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
- C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Pyrane Compounds (AREA)
- Steroid Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT33276/72A IT972655B (it) | 1972-12-20 | 1972-12-20 | Procedimento per la produzione di dimetil etere |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU952101A3 true SU952101A3 (ru) | 1982-08-15 |
Family
ID=11237078
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU731978809D SU952101A3 (ru) | 1972-12-20 | 1973-12-19 | Способ получени диметилового эфира |
| SU731978809A SU929006A3 (ru) | 1972-12-20 | 1973-12-19 | Способ получени диметилового эфира |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU731978809A SU929006A3 (ru) | 1972-12-20 | 1973-12-19 | Способ получени диметилового эфира |
Country Status (33)
| Country | Link |
|---|---|
| JP (1) | JPS5432764B2 (enExample) |
| AR (1) | AR196959A1 (enExample) |
| AT (1) | AT327157B (enExample) |
| BE (1) | BE808845A (enExample) |
| BG (1) | BG22380A3 (enExample) |
| BR (1) | BR7309990D0 (enExample) |
| CA (1) | CA1022189A (enExample) |
| CH (1) | CH588432A5 (enExample) |
| CS (1) | CS185216B2 (enExample) |
| DD (1) | DD108967A5 (enExample) |
| DE (1) | DE2362944C3 (enExample) |
| EG (1) | EG11275A (enExample) |
| ES (1) | ES421888A1 (enExample) |
| FR (1) | FR2211437B1 (enExample) |
| GB (1) | GB1398696A (enExample) |
| HU (1) | HU174060B (enExample) |
| IE (1) | IE38619B1 (enExample) |
| IN (1) | IN140223B (enExample) |
| IT (1) | IT972655B (enExample) |
| LU (1) | LU69027A1 (enExample) |
| MW (1) | MW7373A1 (enExample) |
| MY (1) | MY7600089A (enExample) |
| NL (1) | NL179647C (enExample) |
| NO (1) | NO140731C (enExample) |
| PH (1) | PH12204A (enExample) |
| PL (1) | PL101562B1 (enExample) |
| RO (1) | RO65198A (enExample) |
| SE (1) | SE419749B (enExample) |
| SU (2) | SU952101A3 (enExample) |
| TR (1) | TR17925A (enExample) |
| YU (1) | YU35232B (enExample) |
| ZA (1) | ZA739156B (enExample) |
| ZM (1) | ZM19373A1 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4341069A (en) | 1980-04-02 | 1982-07-27 | Mobil Oil Corporation | Method for generating power upon demand |
| EP0047596B1 (en) * | 1980-09-04 | 1983-11-30 | Imperial Chemical Industries Plc | Synthesis for producing carbon compounds from a carbon oxide/hydrogen synthesis gas |
| JPS57130547A (en) * | 1981-02-06 | 1982-08-13 | Mitsubishi Gas Chem Co Inc | Catalyst for methanol synthesis |
| IT1137176B (it) * | 1981-06-02 | 1986-09-03 | Anic Spa | Procedimento per la produzione di dimetiletere |
| DE3710501A1 (de) * | 1987-03-30 | 1988-10-13 | Union Rheinische Braunkohlen | Verfahren zur herstellung von dimethylether |
| EP0340324B1 (de) * | 1988-05-04 | 1992-12-16 | RWE-DEA Aktiengesellschaft für Mineraloel und Chemie | Verbessertes Verfahren zur Herstellung von reinem Dimethylether |
| DE3817816A1 (de) * | 1988-05-26 | 1989-11-30 | Union Rheinische Braunkohlen | Verfahren zur herstellung von dimethylether |
| EP0483609A1 (en) * | 1990-10-24 | 1992-05-06 | Air Products And Chemicals, Inc. | Liquid phase process for dimethyl ether synthesis |
| DK173614B1 (da) | 1999-02-02 | 2001-04-30 | Topsoe Haldor As | Fremgangsmåde til fremstilling af methanol/dimethyletherblanding fra syntesegas |
| KR100812099B1 (ko) | 2006-11-28 | 2008-03-12 | 한국가스공사 | 디메틸에테르 제조용 혼합촉매, 이의 제조방법 및 이를 이용한 디메틸에테르 제조방법 |
| FR2909666B1 (fr) | 2006-12-08 | 2009-03-06 | Centre Nat Rech Scient | Deshydratation du methanol en dimethyl ether employant des catalyseurs a base d'une zeolithe supportee sur du carbure de silicium |
| EP2072486A1 (en) | 2007-12-17 | 2009-06-24 | BP p.l.c. | Process for the conversion of hydrocarbons to ethanol |
| EP2072492A1 (en) | 2007-12-17 | 2009-06-24 | BP p.l.c. | Process for the conversion of hydrocarbons to ethanol |
| EP2072491A1 (en) | 2007-12-17 | 2009-06-24 | BP p.l.c. | Process for the conversion of alcohol(s) into alcohol(s) with increased carbon-chain |
| EP2898943B1 (de) | 2014-01-28 | 2016-11-16 | Linde Aktiengesellschaft | Verfahren und Anlage zur Gewinnung von Dimethylether aus Synthesegas |
| EP2902466A1 (de) | 2014-02-04 | 2015-08-05 | Linde Aktiengesellschaft | Verfahren und Anlage zur Gewinnung von Oxygenaten mit Dampferzeugung |
| DE102014016703A1 (de) | 2014-11-12 | 2016-05-12 | Linde Aktiengesellschaft | Verfahren und Anlage zur Bereitstellung eines Synthesegassammelstroms |
| DE102014016704A1 (de) | 2014-11-12 | 2016-05-12 | Linde Aktiengesellschaft | Verfahren und Anlage zur Herstellung eines oder mehrerer Reaktionsprodukte |
| EP3239121A1 (de) | 2016-04-29 | 2017-11-01 | Linde Aktiengesellschaft | Verfahren und anlage zur erzeugung von olefinen |
| WO2020150067A1 (en) * | 2019-01-18 | 2020-07-23 | Exxonmobil Research And Engineering Company | Layered catalyst loading for synthesis gas conversion |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR641580A (fr) * | 1926-09-28 | 1928-08-07 | Delco Light Co | Perfectionnements relatifs à l'obtention et à la récupération de l'oxyde de méthyle |
| DE2026182A1 (en) * | 1970-05-29 | 1971-12-09 | Badische Anilin- & Soda-Fabrik Ag, 6700 Ludwigshafen | Catalyst for methanol prepn-contng copper zinc manganese - and aluminium |
-
1972
- 1972-12-20 IT IT33276/72A patent/IT972655B/it active
-
1973
- 1973-12-07 IE IE2224/73A patent/IE38619B1/xx unknown
- 1973-12-08 ZA ZA00739156A patent/ZA739156B/xx unknown
- 1973-12-11 TR TR17925A patent/TR17925A/xx unknown
- 1973-12-11 GB GB5744373A patent/GB1398696A/en not_active Expired
- 1973-12-12 MW MW73/73*UA patent/MW7373A1/xx unknown
- 1973-12-13 FR FR7344663A patent/FR2211437B1/fr not_active Expired
- 1973-12-13 ZM ZM193/73*UA patent/ZM19373A1/xx unknown
- 1973-12-13 CH CH1748073A patent/CH588432A5/xx not_active IP Right Cessation
- 1973-12-14 YU YU3252/73A patent/YU35232B/xx unknown
- 1973-12-18 NL NLAANVRAGE7317353,A patent/NL179647C/xx not_active IP Right Cessation
- 1973-12-18 EG EG477/73A patent/EG11275A/xx active
- 1973-12-18 DE DE2362944A patent/DE2362944C3/de not_active Expired
- 1973-12-18 AR AR251595A patent/AR196959A1/es active
- 1973-12-19 CS CS7300008808A patent/CS185216B2/cs unknown
- 1973-12-19 CA CA188,556A patent/CA1022189A/en not_active Expired
- 1973-12-19 BE BE139050A patent/BE808845A/xx not_active IP Right Cessation
- 1973-12-19 NO NO4847/73A patent/NO140731C/no unknown
- 1973-12-19 RO RO7377051A patent/RO65198A/ro unknown
- 1973-12-19 SU SU731978809D patent/SU952101A3/ru active
- 1973-12-19 HU HU73SA2570A patent/HU174060B/hu unknown
- 1973-12-19 SU SU731978809A patent/SU929006A3/ru active
- 1973-12-19 LU LU69027A patent/LU69027A1/xx unknown
- 1973-12-19 AT AT1063573A patent/AT327157B/de not_active IP Right Cessation
- 1973-12-19 ES ES421888A patent/ES421888A1/es not_active Expired
- 1973-12-19 DD DD175483A patent/DD108967A5/xx unknown
- 1973-12-20 PL PL1973167493A patent/PL101562B1/pl unknown
- 1973-12-20 BR BR9990/73A patent/BR7309990D0/pt unknown
- 1973-12-20 PH PH15338A patent/PH12204A/en unknown
- 1973-12-20 SE SE7317284A patent/SE419749B/xx unknown
- 1973-12-20 JP JP14199773A patent/JPS5432764B2/ja not_active Expired
- 1973-12-20 BG BG025302A patent/BG22380A3/xx unknown
- 1973-12-21 IN IN2788/CAL/1973A patent/IN140223B/en unknown
-
1976
- 1976-12-30 MY MY89/76A patent/MY7600089A/xx unknown
Also Published As
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