SU843758A3 - Способ получени сополимера этиленаС буТАдиЕНОМ - Google Patents
Способ получени сополимера этиленаС буТАдиЕНОМ Download PDFInfo
- Publication number
- SU843758A3 SU843758A3 SU752159097A SU2159097A SU843758A3 SU 843758 A3 SU843758 A3 SU 843758A3 SU 752159097 A SU752159097 A SU 752159097A SU 2159097 A SU2159097 A SU 2159097A SU 843758 A3 SU843758 A3 SU 843758A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- chloride
- butadiene
- ethylene
- minutes
- bromide
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 7
- 229920001577 copolymer Polymers 0.000 title description 18
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 28
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 10
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000003054 catalyst Substances 0.000 claims abstract description 6
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 claims abstract description 6
- 238000007334 copolymerization reaction Methods 0.000 claims abstract description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 4
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 4
- 239000002904 solvent Substances 0.000 claims abstract description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 6
- JJSGABFIILQOEY-UHFFFAOYSA-M diethylalumanylium;bromide Chemical compound CC[Al](Br)CC JJSGABFIILQOEY-UHFFFAOYSA-M 0.000 claims description 4
- 238000009826 distribution Methods 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- 125000002524 organometallic group Chemical group 0.000 claims description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 3
- VUNCWTMEJYMOOR-UHFFFAOYSA-N hexachlorocyclopentadiene Chemical compound ClC1=C(Cl)C(Cl)(Cl)C(Cl)=C1Cl VUNCWTMEJYMOOR-UHFFFAOYSA-N 0.000 claims description 2
- JFICPAADTOQAMU-UHFFFAOYSA-L ethylaluminum(2+);dibromide Chemical compound CC[Al](Br)Br JFICPAADTOQAMU-UHFFFAOYSA-L 0.000 claims 2
- 241001124076 Aphididae Species 0.000 claims 1
- 238000006555 catalytic reaction Methods 0.000 claims 1
- 229920001038 ethylene copolymer Polymers 0.000 claims 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 27
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract description 10
- 239000005977 Ethylene Substances 0.000 abstract description 10
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 3
- 239000001257 hydrogen Substances 0.000 abstract description 3
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 239000007848 Bronsted acid Substances 0.000 abstract 1
- 239000002841 Lewis acid Substances 0.000 abstract 1
- 229910006124 SOCl2 Inorganic materials 0.000 abstract 1
- 150000004820 halides Chemical group 0.000 abstract 1
- 150000005826 halohydrocarbons Chemical class 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 150000003682 vanadium compounds Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 description 12
- 239000000047 product Substances 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 5
- 230000035945 sensitivity Effects 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 3
- 238000002329 infrared spectrum Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 125000005287 vanadyl group Chemical group 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- JLYXXMFPNIAWKQ-UHFFFAOYSA-N γ Benzene hexachloride Chemical compound ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 description 2
- MWDNZMWVENFVHT-UHFFFAOYSA-L (2-decoxy-2-oxoethyl)-[2-[2-[(2-decoxy-2-oxoethyl)-dimethylazaniumyl]ethylsulfanyl]ethyl]-dimethylazanium;dichloride Chemical compound [Cl-].[Cl-].CCCCCCCCCCOC(=O)C[N+](C)(C)CCSCC[N+](C)(C)CC(=O)OCCCCCCCCCC MWDNZMWVENFVHT-UHFFFAOYSA-L 0.000 description 1
- XKWSCUCLBMOHQJ-UHFFFAOYSA-N CCC1=C(C2=C(C=C1)SC(=N2)SNO)CC Chemical compound CCC1=C(C2=C(C=C1)SC(=N2)SNO)CC XKWSCUCLBMOHQJ-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 101150117564 ITR2 gene Proteins 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 239000013529 heat transfer fluid Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000003402 intramolecular cyclocondensation reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT25934/74A IT1017869B (it) | 1974-08-02 | 1974-08-02 | Procedimento per la preparazione in alta resa di copolimeri dello etilene con 1.3 butadiene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU843758A3 true SU843758A3 (ru) | 1981-06-30 |
Family
ID=11218179
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU752159097A SU843758A3 (ru) | 1974-08-02 | 1975-08-01 | Способ получени сополимера этиленаС буТАдиЕНОМ |
Country Status (27)
| Country | Link |
|---|---|
| JP (1) | JPS5137984A (enExample) |
| AR (1) | AR205396A1 (enExample) |
| AT (1) | AT341769B (enExample) |
| AU (1) | AU8310675A (enExample) |
| BE (1) | BE832052A (enExample) |
| BR (1) | BR7504974A (enExample) |
| CA (1) | CA1046697A (enExample) |
| CH (1) | CH606148A5 (enExample) |
| DD (1) | DD119252A5 (enExample) |
| DE (1) | DE2534497C2 (enExample) |
| DK (1) | DK351475A (enExample) |
| ES (1) | ES440492A1 (enExample) |
| FR (1) | FR2280655A1 (enExample) |
| GB (2) | GB1519475A (enExample) |
| HU (1) | HU171827B (enExample) |
| IL (1) | IL47734A (enExample) |
| IN (1) | IN144511B (enExample) |
| IT (1) | IT1017869B (enExample) |
| LU (1) | LU73119A1 (enExample) |
| MW (1) | MW4375A1 (enExample) |
| NL (1) | NL158512B (enExample) |
| NO (1) | NO752704L (enExample) |
| RO (1) | RO67245A (enExample) |
| SE (1) | SE7508741L (enExample) |
| SU (1) | SU843758A3 (enExample) |
| TR (1) | TR18853A (enExample) |
| ZM (1) | ZM10175A1 (enExample) |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1334941A (fr) * | 1961-07-22 | 1963-08-16 | Ethylene Plastique Sa | Copolymères éthylène-butadiène |
| FR1370358A (fr) * | 1962-09-28 | 1964-08-21 | Hoechst Ag | Procédé de préparation de copolymères d'alpha-oléfines et de dioléfines à l'aide de catalyseurs mixtes organo-métalliques modifiés |
-
1974
- 1974-08-02 IT IT25934/74A patent/IT1017869B/it active
-
1975
- 1975-01-01 AR AR259860A patent/AR205396A1/es active
- 1975-07-12 MW MW43/75A patent/MW4375A1/xx unknown
- 1975-07-16 IN IN1386/CAL/76A patent/IN144511B/en unknown
- 1975-07-16 AU AU83106/75A patent/AU8310675A/en not_active Expired
- 1975-07-17 GB GB3070/78A patent/GB1519475A/en not_active Expired
- 1975-07-17 GB GB30125/75A patent/GB1519474A/en not_active Expired
- 1975-07-18 IL IL47734A patent/IL47734A/xx unknown
- 1975-07-21 CA CA231,872A patent/CA1046697A/en not_active Expired
- 1975-07-22 ZM ZM101/75A patent/ZM10175A1/xx unknown
- 1975-07-29 TR TR18853A patent/TR18853A/xx unknown
- 1975-07-29 FR FR7523697A patent/FR2280655A1/fr active Granted
- 1975-07-30 ES ES440492A patent/ES440492A1/es not_active Expired
- 1975-07-31 CH CH1007575A patent/CH606148A5/xx not_active IP Right Cessation
- 1975-07-31 LU LU73119A patent/LU73119A1/xx unknown
- 1975-08-01 DD DD187640A patent/DD119252A5/xx unknown
- 1975-08-01 SU SU752159097A patent/SU843758A3/ru active
- 1975-08-01 HU HU75SA00002830A patent/HU171827B/hu unknown
- 1975-08-01 JP JP50093239A patent/JPS5137984A/ja active Pending
- 1975-08-01 BE BE158879A patent/BE832052A/xx unknown
- 1975-08-01 AT AT599975A patent/AT341769B/de not_active IP Right Cessation
- 1975-08-01 DE DE2534497A patent/DE2534497C2/de not_active Expired
- 1975-08-01 NO NO752704A patent/NO752704L/no unknown
- 1975-08-01 DK DK351475A patent/DK351475A/da unknown
- 1975-08-01 SE SE7508741A patent/SE7508741L/xx unknown
- 1975-08-02 RO RO7583050A patent/RO67245A/ro unknown
- 1975-08-04 BR BR7504974*A patent/BR7504974A/pt unknown
- 1975-08-04 NL NL7509277.A patent/NL158512B/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ZM10175A1 (en) | 1976-04-21 |
| IL47734A0 (en) | 1975-10-15 |
| SE7508741L (sv) | 1976-02-03 |
| ATA599975A (de) | 1977-06-15 |
| CA1046697A (en) | 1979-01-16 |
| FR2280655B1 (enExample) | 1979-06-22 |
| DE2534497C2 (de) | 1982-01-21 |
| HU171827B (hu) | 1978-03-28 |
| CH606148A5 (enExample) | 1978-10-31 |
| MW4375A1 (en) | 1976-10-13 |
| AU8310675A (en) | 1977-01-20 |
| NL7509277A (nl) | 1976-02-04 |
| IN144511B (enExample) | 1978-05-13 |
| GB1519474A (en) | 1978-07-26 |
| DK351475A (da) | 1976-02-03 |
| RO67245A (ro) | 1980-02-15 |
| IT1017869B (it) | 1977-08-10 |
| AR205396A1 (es) | 1976-04-30 |
| ES440492A1 (es) | 1977-03-01 |
| AT341769B (de) | 1978-02-27 |
| FR2280655A1 (fr) | 1976-02-27 |
| BE832052A (fr) | 1976-02-02 |
| BR7504974A (pt) | 1976-07-27 |
| DD119252A5 (enExample) | 1976-04-12 |
| TR18853A (tr) | 1978-01-01 |
| DE2534497A1 (de) | 1976-02-12 |
| IL47734A (en) | 1978-07-31 |
| LU73119A1 (enExample) | 1976-03-02 |
| NO752704L (enExample) | 1976-02-03 |
| NL158512B (nl) | 1978-11-15 |
| JPS5137984A (enExample) | 1976-03-30 |
| GB1519475A (en) | 1978-07-26 |
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