SU843758A3 - Способ получени сополимера этиленаС буТАдиЕНОМ - Google Patents
Способ получени сополимера этиленаС буТАдиЕНОМ Download PDFInfo
- Publication number
- SU843758A3 SU843758A3 SU752159097A SU2159097A SU843758A3 SU 843758 A3 SU843758 A3 SU 843758A3 SU 752159097 A SU752159097 A SU 752159097A SU 2159097 A SU2159097 A SU 2159097A SU 843758 A3 SU843758 A3 SU 843758A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- chloride
- butadiene
- ethylene
- minutes
- bromide
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 7
- 229920001577 copolymer Polymers 0.000 title description 18
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 28
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 10
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000003054 catalyst Substances 0.000 claims abstract description 6
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 claims abstract description 6
- 238000007334 copolymerization reaction Methods 0.000 claims abstract description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 4
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 4
- 239000002904 solvent Substances 0.000 claims abstract description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 6
- JJSGABFIILQOEY-UHFFFAOYSA-M diethylalumanylium;bromide Chemical compound CC[Al](Br)CC JJSGABFIILQOEY-UHFFFAOYSA-M 0.000 claims description 4
- 238000009826 distribution Methods 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- 125000002524 organometallic group Chemical group 0.000 claims description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 3
- VUNCWTMEJYMOOR-UHFFFAOYSA-N hexachlorocyclopentadiene Chemical compound ClC1=C(Cl)C(Cl)(Cl)C(Cl)=C1Cl VUNCWTMEJYMOOR-UHFFFAOYSA-N 0.000 claims description 2
- JFICPAADTOQAMU-UHFFFAOYSA-L ethylaluminum(2+);dibromide Chemical compound CC[Al](Br)Br JFICPAADTOQAMU-UHFFFAOYSA-L 0.000 claims 2
- 241001124076 Aphididae Species 0.000 claims 1
- 238000006555 catalytic reaction Methods 0.000 claims 1
- 229920001038 ethylene copolymer Polymers 0.000 claims 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 27
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract description 10
- 239000005977 Ethylene Substances 0.000 abstract description 10
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 3
- 239000001257 hydrogen Substances 0.000 abstract description 3
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 239000007848 Bronsted acid Substances 0.000 abstract 1
- 239000002841 Lewis acid Substances 0.000 abstract 1
- 229910006124 SOCl2 Inorganic materials 0.000 abstract 1
- 150000004820 halides Chemical group 0.000 abstract 1
- 150000005826 halohydrocarbons Chemical class 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 150000003682 vanadium compounds Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 description 12
- 239000000047 product Substances 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 5
- 230000035945 sensitivity Effects 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 3
- 238000002329 infrared spectrum Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 125000005287 vanadyl group Chemical group 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- JLYXXMFPNIAWKQ-UHFFFAOYSA-N γ Benzene hexachloride Chemical compound ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 description 2
- MWDNZMWVENFVHT-UHFFFAOYSA-L (2-decoxy-2-oxoethyl)-[2-[2-[(2-decoxy-2-oxoethyl)-dimethylazaniumyl]ethylsulfanyl]ethyl]-dimethylazanium;dichloride Chemical compound [Cl-].[Cl-].CCCCCCCCCCOC(=O)C[N+](C)(C)CCSCC[N+](C)(C)CC(=O)OCCCCCCCCCC MWDNZMWVENFVHT-UHFFFAOYSA-L 0.000 description 1
- XKWSCUCLBMOHQJ-UHFFFAOYSA-N CCC1=C(C2=C(C=C1)SC(=N2)SNO)CC Chemical compound CCC1=C(C2=C(C=C1)SC(=N2)SNO)CC XKWSCUCLBMOHQJ-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 101150117564 ITR2 gene Proteins 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 239000013529 heat transfer fluid Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000003402 intramolecular cyclocondensation reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT25934/74A IT1017869B (it) | 1974-08-02 | 1974-08-02 | Procedimento per la preparazione in alta resa di copolimeri dello etilene con 1.3 butadiene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU843758A3 true SU843758A3 (ru) | 1981-06-30 |
Family
ID=11218179
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU752159097A SU843758A3 (ru) | 1974-08-02 | 1975-08-01 | Способ получени сополимера этиленаС буТАдиЕНОМ |
Country Status (27)
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1334941A (fr) * | 1961-07-22 | 1963-08-16 | Ethylene Plastique Sa | Copolymères éthylène-butadiène |
| FR1370358A (fr) * | 1962-09-28 | 1964-08-21 | Hoechst Ag | Procédé de préparation de copolymères d'alpha-oléfines et de dioléfines à l'aide de catalyseurs mixtes organo-métalliques modifiés |
-
1974
- 1974-08-02 IT IT25934/74A patent/IT1017869B/it active
-
1975
- 1975-01-01 AR AR259860A patent/AR205396A1/es active
- 1975-07-12 MW MW43/75A patent/MW4375A1/xx unknown
- 1975-07-16 IN IN1386/CAL/76A patent/IN144511B/en unknown
- 1975-07-16 AU AU83106/75A patent/AU8310675A/en not_active Expired
- 1975-07-17 GB GB30125/75A patent/GB1519474A/en not_active Expired
- 1975-07-17 GB GB3070/78A patent/GB1519475A/en not_active Expired
- 1975-07-18 IL IL47734A patent/IL47734A/xx unknown
- 1975-07-21 CA CA231,872A patent/CA1046697A/en not_active Expired
- 1975-07-22 ZM ZM101/75A patent/ZM10175A1/xx unknown
- 1975-07-29 FR FR7523697A patent/FR2280655A1/fr active Granted
- 1975-07-29 TR TR18853A patent/TR18853A/xx unknown
- 1975-07-30 ES ES440492A patent/ES440492A1/es not_active Expired
- 1975-07-31 CH CH1007575A patent/CH606148A5/xx not_active IP Right Cessation
- 1975-07-31 LU LU73119A patent/LU73119A1/xx unknown
- 1975-08-01 SU SU752159097A patent/SU843758A3/ru active
- 1975-08-01 DE DE2534497A patent/DE2534497C2/de not_active Expired
- 1975-08-01 DK DK351475A patent/DK351475A/da unknown
- 1975-08-01 AT AT599975A patent/AT341769B/de not_active IP Right Cessation
- 1975-08-01 NO NO752704A patent/NO752704L/no unknown
- 1975-08-01 HU HU75SA00002830A patent/HU171827B/hu unknown
- 1975-08-01 SE SE7508741A patent/SE7508741L/xx unknown
- 1975-08-01 BE BE158879A patent/BE832052A/xx unknown
- 1975-08-01 JP JP50093239A patent/JPS5137984A/ja active Pending
- 1975-08-01 DD DD187640A patent/DD119252A5/xx unknown
- 1975-08-02 RO RO7583050A patent/RO67245A/ro unknown
- 1975-08-04 BR BR7504974*A patent/BR7504974A/pt unknown
- 1975-08-04 NL NL7509277.A patent/NL158512B/xx not_active IP Right Cessation
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