SU709568A1 - Method of dye industry waste water purification - Google Patents
Method of dye industry waste water purification Download PDFInfo
- Publication number
- SU709568A1 SU709568A1 SU782561692A SU2561692A SU709568A1 SU 709568 A1 SU709568 A1 SU 709568A1 SU 782561692 A SU782561692 A SU 782561692A SU 2561692 A SU2561692 A SU 2561692A SU 709568 A1 SU709568 A1 SU 709568A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- waste water
- water purification
- industry waste
- dye industry
- treatment
- Prior art date
Links
- 238000000034 method Methods 0.000 title description 13
- 239000002351 wastewater Substances 0.000 title description 11
- 238000000746 purification Methods 0.000 title description 3
- 239000000460 chlorine Substances 0.000 description 12
- 229910052801 chlorine Inorganic materials 0.000 description 12
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 9
- 239000000975 dye Substances 0.000 description 9
- 238000010790 dilution Methods 0.000 description 6
- 239000012895 dilution Substances 0.000 description 6
- 238000005868 electrolysis reaction Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- -1 chlorine ions Chemical class 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 238000006298 dechlorination reaction Methods 0.000 description 2
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 2
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- ADGGJQPKBDIZMT-UHFFFAOYSA-K trisodium;4-[(4-anilino-5-sulfonatonaphthalen-1-yl)diazenyl]-5-hydroxynaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[Na+].C=12C(O)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=CC=1N=NC(C1=CC=CC(=C11)S([O-])(=O)=O)=CC=C1NC1=CC=CC=C1 ADGGJQPKBDIZMT-UHFFFAOYSA-K 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
- C02F1/4672—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
- C02F1/4674—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation with halogen or compound of halogens, e.g. chlorine, bromine
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F2001/46133—Electrodes characterised by the material
- C02F2001/46138—Electrodes comprising a substrate and a coating
- C02F2001/46142—Catalytic coating
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/308—Dyes; Colorants; Fluorescent agents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Description
(54) СПОСОБ ОЧИСТКИ СТОЧНЫХ ВОД КРАСИЛЬНЫХ ПРОИЗВОДСТВ(54) METHOD FOR CLEANING WASTE WATERS OF COLORFUL INDUSTRIES
Изобретение относитс к способам очистки сточных вод красильных производств и может быть использовано дл очистки стоков, образующихс , н пример, при производстве красителей и полупродуктов, чернил, цветной ту Известен способ очистки сточных вод красильных производств, в частности , от кубовых красителей путем электролиза с использованием анода из двуокиси свинца и при плотности тока 1,6-2,5 А/дм2 1. Однако такой способ очистки хара теризуетс значительным расходом электроэнергии, продолжительностью обработки, пассивацией анодов, а та же необходимо проводить затем доочи ку сточных вод. Наиболее близким к изобретению по технической сущности и достигаемому результату вл етс способ очистки сточных вод красильных производств, заключающийс в электролизе с исполь зованием титановых анодов, покрытых окислами рутени и титана, в присутствии хлор-ионов при плотности тока 1-2 А/дм2 2. Однако дл получени приемлемой степени очистки требуетс продолжительность обработки 15-25 мин. Кроме того, остаточна концентраци активного хлора составл ет более 600 мг/л, поэтому требуетс дехлорировагтие очищенных сточных вод перед выпуском их в канализацию. Целью изобретени вл етс сокращение продолжительности обработки и снижение остаточной концентрации актив ного хлора. Это достигаетс тем, что электролиз сточных вод провод т с нерастворимым титановым анодом, покрытым окислами рутени и титана, в присутствии хлор-ионов, при плотности тока 1-2 А/дм и при одновременном ультрафиолетовом облучении. Отличием вл етс использование одновременно с электролизом ультра-фиолетового облучени . Сущность способа состоит в том, что в процессе-электролиза сточикк вод из-за разр да на аноде хлор-ионов образуетс активный хлор, который вл етс основным окисл ющим агентом при деструкции органических красителей и поверхностноактивних вецести. Ультрафиолетовое облучение увеличивает полноту и скорость реакстП оь-щ-лени образую{цимис при элокт} -лиус активным хлором и кислородом.The invention relates to methods for treating wastewater from dye plants and can be used to clean wastewaters, for example, in the production of dyes and intermediates, inks, colored ones. A known method for cleaning wastewater dye plants, in particular, from bottom dyes by electrolysis using anode from lead dioxide and at a current density of 1.6-2.5 A / dm2 1. However, this cleaning method is characterized by significant power consumption, processing time, passivation of the anodes, and the same necessity to spend then doochi ku wastewater. The closest to the invention according to the technical essence and the achieved result is the method of wastewater treatment of dye plants, which consists in electrolysis using titanium anodes coated with ruthenium and titanium oxides in the presence of chlorine ions at a current density of 1-2 A / dm 2. However, to obtain an acceptable degree of purification, a treatment time of 15-25 minutes is required. In addition, the residual concentration of active chlorine is more than 600 mg / l; therefore, dechlorination of the treated wastewater is required before it is released into the sewage system. The aim of the invention is to reduce the processing time and reduce the residual concentration of active chlorine. This is achieved by the fact that the electrolysis of wastewater is carried out with an insoluble titanium anode coated with ruthenium and titanium oxides in the presence of chlorine ions, at a current density of 1-2 A / dm, and with simultaneous ultraviolet irradiation. The difference is the use simultaneously with the electrolysis of ultraviolet irradiation. The essence of the method lies in the fact that in the process of electrolyzing the waste water, due to the discharge on the anode of chlorine ions, active chlorine is formed, which is the main oxidizing agent during the destruction of organic dyes and surface active supernatants. Ultraviolet irradiation increases the completeness and rate of reactivity of o-sch-leni, forming {Tsimis with elokt} -lius with active chlorine and oxygen.
« 4toA 4H f . «"4toA 4H f. "
709568709568
. .
Пример. Раствор красител кислотного синего 2К (100 мг/л) и кревоцелла (40 мг/л) с исходной величиной ХПК 220 мг 02/л и интенсивностью окраски по кратности разбавлени 1:500 обрабатьюают в электролизере из кварцевого стекла,под которым поме- дают ртутно-кварцевую лампу IIPK-2M на рассто нии 100 мм. Тот же раствор обрабатывают по известной технологии. В обоих случа х плотность анодного тока составл ет около 2 А/дм2, исходна концентраци хлористого натри - 5 г/л.Example. An acid blue 2K dye solution (100 mg / l) and krevozella (40 mg / l) with an initial COD value of 220 mg 02 / l and a color intensity at a dilution ratio of 1: 500 are processed in a quartz glass electrolyzer under which mercury is placed. -quartz IIPK-2M lamp at a distance of 100 mm. The same solution is treated by known technology. In both cases, the anode current density is about 2 A / dm 2, the initial concentration of sodium chloride is 5 g / l.
Через 5 мин обработки по предлагаемому способу получают жидкость с ХПК 150 мг Ой/л, интенсивностью окраски по кратности разбавлени 1:30 и остаточным содержанием активного хлора 130 мг/л.After 5 min of treatment by the proposed method, a liquid is obtained with a COD of 150 mg Oi / l, a color intensity at a dilution rate of 1:30, and a residual content of active chlorine 130 mg / l.
Через 5 и 15 мин обработки по известной технологии получают жидкость с ХПК 190 и 140 мг О2/Л, интенсив .дюстью обработки окраски по кратно 5ти разбавлени 1:160 и 1:32 и с остаточным содержанием активного хлора 200 и 700 мг/л соответственно.After 5 and 15 minutes of treatment according to a known technology, a liquid with COD 190 and 140 mg O2 / L is obtained, with an intensity of color treatment by multiple dilutions of 1: 160 and 1:32 and with a residual content of active chlorine of 200 and 700 mg / l, respectively. .
П р и м е р 2, Раствор красител пр мого черного 2С (100 мг/л) и превоцелла (40 мг/л) с исходной величиной ХПК 300 мг Ог/л и интенсивностью окраски по кратности разбавлени / 1:480 обрабатывают при тех же услови х , что и в примере .1.EXAMPLE 2 A direct black 2C dye solution (100 mg / l) and precella (40 mg / l) with an initial COD value of 300 mg Og / l and a color intensity according to the dilution ratio / 1: 480 is processed with those the same conditions as in example .1.
Через 5 мин обработки по предлагаемому способу получают жидкость с АПК 140 мг Ог/л, интенсивностью окраки по кратности разбавлени 1:100 и остаточным содержанием активного хлора 135 мг/л.After 5 min of treatment by the proposed method, a liquid is obtained with an APC of 140 mg Og / l, a color intensity at a dilution ratio of 1: 100, and a residual content of active chlorine of 135 mg / l.
Через 5 и 10 мин обработки по известной технологии пол -чают жидкость с ХПК 200 и 150 мг Ог/л, интенсивностью окраски по кратности разбавлени 1:400 и 1:100 и с остаточным содержанием активного хлора 280 и 440 мг/л соответственно,After 5 and 10 minutes of treatment according to a known technology, a liquid is obtained with a COD of 200 and 150 mg Og / l, a color intensity at a dilution ratio of 1: 400 and 1: 100, and with a residual active chlorine content of 280 and 440 mg / l, respectively,
В результате обработки сточных вод красильных производств по предлагаемому способу продолжительность процесса уменьшаетс в 2-3 раза и содержание остаточной концентрации активного хлора уменьшаетс с 440-700 мг/л до 130-135 мг/л по сравнению с обработкой по известной технологии при условии достижени примерно равной степени очистки,As a result of the treatment of wastewaters of the dye productions according to the proposed method, the duration of the process is reduced by 2-3 times and the content of the residual concentration of active chlorine decreases from 440-700 mg / l to 130-135 mg / l as compared with the treatment according to the known technology, provided that equal purification
Предлагаемый способ позвол ет соответственно уменьшить количество необходимых электролизеров, снизить затраты на дехлорирование очищаемых сточных вод. The proposed method allows, respectively, to reduce the number of required electrolyzers, to reduce the cost of dechlorination of treated wastewater.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU782561692A SU709568A1 (en) | 1978-01-02 | 1978-01-02 | Method of dye industry waste water purification |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU782561692A SU709568A1 (en) | 1978-01-02 | 1978-01-02 | Method of dye industry waste water purification |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU709568A1 true SU709568A1 (en) | 1980-01-15 |
Family
ID=20740975
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU782561692A SU709568A1 (en) | 1978-01-02 | 1978-01-02 | Method of dye industry waste water purification |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU709568A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2515324A (en) * | 2013-06-19 | 2014-12-24 | Ramsey Yousif Haddad | Electrolytic advance oxidation processes to treat wastewater, brackish and saline water without hydrogen evolution |
-
1978
- 1978-01-02 SU SU782561692A patent/SU709568A1/en active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2515324A (en) * | 2013-06-19 | 2014-12-24 | Ramsey Yousif Haddad | Electrolytic advance oxidation processes to treat wastewater, brackish and saline water without hydrogen evolution |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| SU709568A1 (en) | Method of dye industry waste water purification | |
| DE68905957D1 (en) | METHOD AND SYSTEM FOR THE DISinfection of BATH WATER BY ELECTROCHEMICALLY SODUATED SODUUM HYPOCHLORITE. | |
| Vijayaraghavan et al. | In situ hypochlorous acid generation for treatment of tannery wastewaters | |
| JPS553823A (en) | Desalination of sea water | |
| SU1318535A1 (en) | Method for electrochemical treatment of waste water | |
| JP2008264668A (en) | Method and apparatus for electrolytic treatment of wastewater | |
| SU566776A1 (en) | Method of purifying waste water | |
| KR0180898B1 (en) | Waste water disposing method using electrolytic wet oximetry | |
| SU460247A1 (en) | The method of wastewater treatment dye plants | |
| SU975583A1 (en) | Process for purifying effluents containing ammonia and ethylene diamine | |
| JP2000263049A (en) | Method and apparatus for cleaning barn effluent | |
| SU1162751A1 (en) | Method of removing phenol from waste water | |
| SU1188105A1 (en) | Method of removing arsenic compounds from waste water | |
| SU1011548A1 (en) | Process for purifying effluents from dyeing and finishing production | |
| SU1318536A1 (en) | Method for removing hydrogen sulfide from waste water | |
| SU1305197A1 (en) | Method for demercurization of oxide ruthenium-titanium anodes | |
| SU518467A1 (en) | The method of wastewater treatment dyeing production | |
| Linares-Hernández et al. | Industrial wastewater treatment by electrocoagulation-direct anodic oxidation system | |
| SU1116019A1 (en) | Method of defluorinating deep-well water | |
| KR940009074A (en) | Electrolytic Wastewater Treatment Method Using Salt (NaCl) | |
| KR20040078173A (en) | Electrolysis and electro-coagulation treatment apparatus of wastewater | |
| SU947071A1 (en) | Process for purifying effluents | |
| SU700465A1 (en) | Method of purifying waste water from petroleum products | |
| SU1723047A1 (en) | Method of cleaning sewage from dissolved impurities | |
| SU1740325A1 (en) | Method of treating sewage from heavy metal ions, and device thereof |