SU665773A3 - Insecticide composition - Google Patents

Insecticide composition

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Publication number
SU665773A3
SU665773A3 SU772525402A SU2525402A SU665773A3 SU 665773 A3 SU665773 A3 SU 665773A3 SU 772525402 A SU772525402 A SU 772525402A SU 2525402 A SU2525402 A SU 2525402A SU 665773 A3 SU665773 A3 SU 665773A3
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SU
USSR - Soviet Union
Prior art keywords
dimethyl
solvent
active
active substance
emulsifier
Prior art date
Application number
SU772525402A
Other languages
Russian (ru)
Inventor
Маурер Фритц
Рибель Ганс-Иохем
Шредер Рольф
Гамманн Ингеборг
Хомайер Бернхард
Штендель Вильгельм
Original Assignee
Байер Аг (Фирма)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Байер Аг (Фирма) filed Critical Байер Аг (Фирма)
Application granted granted Critical
Publication of SU665773A3 publication Critical patent/SU665773A3/en

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/18One oxygen or sulfur atom
    • C07D231/20One oxygen atom attached in position 3 or 5
    • C07D231/22One oxygen atom attached in position 3 or 5 with aryl radicals attached to ring nitrogen atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/18Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/18One oxygen or sulfur atom
    • C07D231/20One oxygen atom attached in position 3 or 5

Description

(54) ИНСЕКТИЦИДНОЕ СРЕДСТВО(54) INSECTICIDE MEANS

Ё Присутствии растворител  или разбавител .In the presence of a solvent or diluent.

Таким образом, получают следующие соединени  общей формулы I, представленные в табл. 1.Thus, the following compounds of general formula I are obtained, presented in Table. one.

Таблица 1Table 1

Действующие начали, kOHueHTpaiiHH их Длительность оценки и результаты видны из табл. 2.The active ones began, kOHueHTpaiiHH their Duration of assessment and the results are visible from the table. 2

Таблица 2table 2

Опыт с MyzusExperience with Myzus

Формы применени  средств - обычные; растворы, эмульсии, порошки, суспензии. Их приготавливают методами общими при изготовлении препаративных форм пестицидов .Forms of application are common; solutions, emulsions, powders, suspensions. They are prepared by methods common in the manufacture of preparative forms of pesticides.

Пример 1. Опыт с тлей (контактное действие).Example 1. Experience with aphids (contact action).

Растворитель: 3 вес. ч. ацетона.Solvent: 3 wt. including acetone.

Эмульгатор: 1 вес. ч. алкиларилполигликолевого эфира.Emulsifier: 1 weight. including alkylaryl polyglycol ether.

Дл  получени  препарата действующего начала 1 вес. ч. его смешивают с указанным количеством растворител  и эмульгатора и разбавл ют концентрат водой до желаемой концентрации.In order to obtain an active drug, start 1 wt. it is mixed with the indicated amount of solvent and emulsifier and the concentrate is diluted with water to the desired concentration.

Препаратом действующего начала обры:згивают до образовани  капель растени  капусты (Brassica oleracea), сильно пораженные тлей (Myzus persicae).The preparation of the current beginning of the crop: zgivayut before the formation of cabbage plants (Brassica oleracea), strongly affected by aphids (Myzus persicae).

По истечении указанного времени определ ют степень умерщвлени . При этом 100% обозначает, что вс  тл  умерщвлена, 0% -ни одна тл  не yмepu влeнa.After a specified time, the degree of killing is determined. At the same time, 100% means that all the animals have been euthanized, 0% - or only one person has not died.

Пример 2. Опыт с личинками листо &amp;да.Example 2. Experiment with larvae of leaf &amp; yes.

Растворитель: 3 вес. ч. ацетона.Solvent: 3 wt. including acetone.

Эмульгатор: 1 вес. ч. алкиларилпоЛиМйколевого эфира.Emulsifier: 1 weight. including alkylaryl ethers.

Дл  получений препарата действующего начала 1 вес. ч. его смешивают с указанным количеством растворител  и эмульгатора и разбавл ют концентрат водой до желаемой концентрации.To obtain the drug active start 1 wt. it is mixed with the indicated amount of solvent and emulsifier and the concentrate is diluted with water to the desired concentration.

Препаратом действующего начала обрызгивают до образовани  капель листь  каиусты н сажают на них личинки хренового листоеда (Phaeilon cochlearial).The drug of the beginning of the beginning is sprayed before the formation of kajusta leaves and the larvae of the crap leaves (Phaeilon cochlearial) are planted on them.

По истечении указанного времени определ ют степень умерщвлени . При этом 100% означает, что все личинки умерщвлень1 , 0%-ни одна личинка не умерщвлена .After a specified time, the degree of killing is determined. At the same time, 100% means that all larvae are killed, 0% - and one larva is not killed.

Действующие начала, концентрации их, длительность оценки и результаты видны из табл. 3.The active principles, their concentrations, the duration of the assessment and the results are visible from the table. 3

Таблица 3 Опыт с Phaedch - личинками.Table 3 Experience with Phaedch - larvae.

Пример 3. Опыт с предельной концентрацией (системное действие через корни).Example 3. Experience with limiting concentration (systemic action through the roots).

Подопытные насекомые. Myzus persieae.Experimental insects. Myzus persieae.

Растворитель: 3 вес. ч ацетона.Solvent: 3 wt. h acetone.

Эмульгатор: 1 вес. ч. алкиларилполигликолевого эфира.Emulsifier: 1 weight. including alkylaryl polyglycol ether.

Дл  получени  препарата действующего начала 1 вес. ч. его смешивают с указанным количеством растворител  и эмульгатора и разбавл ют концентрат водой до желаемой концентрации.In order to obtain an active drug, start 1 wt. it is mixed with the indicated amount of solvent and emulsifier and the concentrate is diluted with water to the desired concentration.

Препарат действующего начала тщательно смешивают е землей. При этом решающим  вл етс  только количество действующего начала на объемную единицу земли, которое выражают в част х на млн. или мг/л. Обработанную землю засыпают в горшки и сажают в них капусту (Brassicu oleraceu). Действующее начало воспринимаетс  растени ми из земли и передаетс  в листь .The preparation of the active principle is thoroughly mixed with earth. In this case, the decisive factor is only the amount of active principle per volumetric unit of earth, which is expressed in parts per million or mg / l. The cultivated land is poured into pots and planted in cabbage (Brassicu oleraceu). The active principle is perceived by plants from the ground and transmitted to the leaves.

Дл  дбказаГельства систбммб1 о действи  через корни по истечении 7 дней иа листь  Сажают указанных подопытных насекомых. По истечении дальнейших 2 дней осуществл ют оценкупутем подсчета или определени  мертвых насекомых. Из числа умерщвленных насекомых вывод т системное действие действующего начала. Она составл ет 100%, если все насекомые умерщвлены, и 0% -если осталось в живых столько же насекомых, сколько при необработанном контроле.For sbstbmmb1 action through the roots after 7 days, these insect insects are planted. After a further 2 days, an evaluation is made of the counting or determination of dead insects. From the number of dead insects, a systemic action of the active principle is derived. It is 100% if all insects are euthanized, and 0% if as many insects are alive as with the untreated control.

Действующие иачала и результаты опыта .Existing and the results of the experiment.

1515

СтепеньPower

умерщвлени  приkilling at

концентрацииconcentration

Действующее началоActive principle

действующегоacting

начала 20 частейstart 20 pieces

на млн.per million

2525

С-0-С-11(,СНз);C-0-C-11 (, CH3);

30thirty

9 7 5 4 2 6 1 39 7 5 4 2 6 1 3

100 100 100 100 100 100 100 100100 100 100 100 100 100 100 100

Пример 4. Опыт с паразитирующими личинками мух.Example 4. Experience with parasitic larvae of flies.

Растворитель: 35 вес. ч. этнленполнгликольмонометрилового эфира.Solvent: 35 wt. including ethnlen-complete glycol monomethyl ether.

Эмульгатор: 35 вес. ч. ноннлфенолролигликолевого эфира.Emulsifier: 35 wt. including nonnofenololiglycol ether.

Дл  получени  препарата действующего начала 30 вес. ч. соответствующего активного вещества смешивают с указанным количеством растворител , содержащего указанное количество эмульгатора и полученный таким образом концентрат разбавл ют водой до желаемой концентрации.To obtain a drug of the current beginning, 30 wt. the part of the corresponding active substance is mixed with the indicated amount of solvent containing the indicated amount of emulsifier and the concentrate thus obtained is diluted with water to the desired concentration.

Приблизительно 20 личинок мух (Lucillia cuprina) сажают в пробирку, в которой находитс  приблизительно 2 см конины. На эту конину нанесены 0,5 мл препарата действующего начала. По истечении 24 определ ют степень умерщвлени . При этом 100% означает, что все личинки умерщвлены , а 0% -ни одна личинка не умерщвлена .Approximately 20 fly larvae (Lucillia cuprina) are planted in a test tube containing approximately 2 cm of horse meat. On this horse meat 0.5 ml of the active ingredient is applied. After 24, the killing degree is determined. At the same time, 100% means that all the larvae are euthanized, and 0% - and one larva is not killed.

Таким образом, предложенные соединени  обладают хорошей инсектицидной активностью .Thus, the proposed compounds have good insecticidal activity.

Claims (2)

Формула изобретени Invention Formula Инсектицидное средство на основе производных Ы,Н-диметил-0-пиразолилкарбаминоврй кислоты, как активное веществоInsecticidal agent based on derivatives of N, N-dimethyl-0-pyrazolylcarbamic acid, as an active substance и добавки, выбранной из группы растворитель , твердый носитель, поверхностно активный агент, отличающеес  тем, что, с целью усиленна  инсектицидной активности , оно содержит в качестве производного М,М-диметил - О - пиразолилкарбаминовой кислоты соединени  общей формулыand additives selected from the group of solvents, solid carrier, surface active agent, characterized in that, in order to enhance insecticidal activity, it contains as a derivative of M, M-dimethyl - O - pyrazolylcarbamic acid compounds of the general formula R IR i NN V -о-со-г(,снз)2 i -aJ15 где R - водород, Ci-Сз-алкил, цианэтил; R - Ci-С2-алкокси, Ci-Сз-алкилтио, причем содержание активного вещества в средстве от 0,1 до 95 вес. %, остальное добавка.V -o-co-g (dbp) 2 i -aJ15 where R is hydrogen, Ci-Cs-alkyl, cyanoethyl; R - Ci-C2-alkoxy, Ci-Cz-alkylthio, and the content of the active substance in the tool is from 0.1 to 95 weight. %, the rest is additive. 20Источники информации,20 Sources of information прин ть1е во внимание при экспертизе 1. Патент Великобритании № 1233134, кл. А 01 N 9/22, опублик. 1971. take into account during the examination 1. Patent of Great Britain No. 1233134, cl. And 01 N 9/22, published. 1971. 2. Мельников Н. И. Хими  и технологи 2. Melnikov N. I. Chemistry and technologists 25 пестицидов, М., «Хими , с. 316-318.25 pesticides, M., “Himi, p. 316-318.
SU772525402A 1976-10-02 1977-09-27 Insecticide composition SU665773A3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19762644588 DE2644588A1 (en) 1976-10-02 1976-10-02 Insecticidal O-pyrazolyl (N,N)-di:methyl-carbamate derivs. - prepd. from 3-substd.-5-hydroxy-pyrazole and di:methyl carbamic acid chloride

Publications (1)

Publication Number Publication Date
SU665773A3 true SU665773A3 (en) 1979-05-30

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ID=5989532

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SU772525402A SU665773A3 (en) 1976-10-02 1977-09-27 Insecticide composition

Country Status (8)

Country Link
BE (1) BE859239A (en)
CS (1) CS194187B2 (en)
DE (1) DE2644588A1 (en)
ES (1) ES462808A1 (en)
HU (1) HU177937B (en)
PL (1) PL107883B1 (en)
SU (1) SU665773A3 (en)
ZA (1) ZA775854B (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2721188A1 (en) * 1977-05-11 1978-11-16 Bayer Ag Insecticidal O-pyrazolyl (N,N)-di:methyl-carbamate derivs. - prepd. from 3-substd.-5-hydroxy-pyrazole and di:methyl carbamic acid chloride
DE2819932A1 (en) * 1978-05-06 1979-11-15 Bayer Ag N, N-DIMETHYL-O-PYRAZOLYL-CARBAMINE ACID ESTER, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS INSECTICIDES
DE2839270A1 (en) * 1978-09-09 1980-03-20 Bayer Ag N, N-DIMETHYL-O-PYRAZOLYL-CARBAMINIC ACID ESTER, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS A PEST CONTROL
DE2912494A1 (en) * 1979-03-29 1980-10-09 Bayer Ag N, N-DIMETHYL-0-PYRAZOLYL-CARBAMINIC ACID ESTER, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS A PEST CONTROL
DE3002413A1 (en) * 1980-01-24 1981-07-30 Hoechst Ag, 6000 Frankfurt N, N-DIALKYL-O- (PYRAZOL-5-YL) -CARBAMIC ACID ESTER, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS INSECTICIDES
DE3003019A1 (en) * 1980-01-29 1981-07-30 Bayer Ag, 5090 Leverkusen N, N-DIMETHYL-O- (4,6-DIHYDRO-2H-THIENO (3,4-C) PYRAZOL-3-YL) -CARBAMINIC ACID ESTERS AND THEIR 5-OXIDES AND 5,5-DIOXIDES, METHOD FOR THEIR PROCESS PRODUCTION AND THEIR USE IN PEST CONTROL
JPS6425764A (en) * 1987-06-08 1989-01-27 Monsanto Co Substituted 3-(4-nitrophenoxy)pyrazole and herbicide
US4964895A (en) * 1987-06-08 1990-10-23 Monsanto Company Substituted 4-(4-nitrophenoxy) pyrazoles and their use as herbicides

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2420360A1 (en) * 1974-04-26 1975-11-06 Bayer Ag N, N-DIMETHYL-0- SQUARE BRACKET ON 1-METHYL-3-N-METHYL-CARBAMINYL-METHYL-PYRAZOLE (5) YL SQUARE BRACKET ON CARBAMIC ACID ESTER, THE PROCESS FOR ITS MANUFACTURING AND USE AS A SIDE

Also Published As

Publication number Publication date
PL201169A1 (en) 1978-05-08
HU177937B (en) 1982-02-28
ZA775854B (en) 1978-08-30
DE2644588C2 (en) 1987-02-19
PL107883B1 (en) 1980-03-31
ES462808A1 (en) 1978-12-16
DE2644588A1 (en) 1978-04-06
BE859239A (en) 1978-03-30
CS194187B2 (en) 1979-11-30

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