SU615853A3 - Способ получени акрилонитрила - Google Patents
Способ получени акрилонитрилаInfo
- Publication number
- SU615853A3 SU615853A3 SU752114574A SU2114574A SU615853A3 SU 615853 A3 SU615853 A3 SU 615853A3 SU 752114574 A SU752114574 A SU 752114574A SU 2114574 A SU2114574 A SU 2114574A SU 615853 A3 SU615853 A3 SU 615853A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- propylene
- catalyst
- acrylonitrile
- converted
- oxides
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 20
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 title claims 14
- 239000003054 catalyst Substances 0.000 claims 24
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 22
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 22
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims 9
- 229910052751 metal Inorganic materials 0.000 claims 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 8
- 238000006243 chemical reaction Methods 0.000 claims 8
- 239000010949 copper Substances 0.000 claims 8
- 239000002184 metal Substances 0.000 claims 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 8
- 229910052721 tungsten Inorganic materials 0.000 claims 7
- 239000010937 tungsten Substances 0.000 claims 6
- -1 acrylic nitrile Chemical class 0.000 claims 5
- 229910021529 ammonia Inorganic materials 0.000 claims 5
- 238000005915 ammonolysis reaction Methods 0.000 claims 5
- 229910052802 copper Inorganic materials 0.000 claims 5
- 150000002739 metals Chemical class 0.000 claims 5
- 239000000203 mixture Substances 0.000 claims 5
- 230000001590 oxidative effect Effects 0.000 claims 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 4
- 229910052783 alkali metal Inorganic materials 0.000 claims 4
- 239000010941 cobalt Substances 0.000 claims 4
- 229910017052 cobalt Inorganic materials 0.000 claims 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 4
- 229910052742 iron Inorganic materials 0.000 claims 4
- 239000007788 liquid Substances 0.000 claims 4
- 238000003756 stirring Methods 0.000 claims 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 3
- 150000001340 alkali metals Chemical class 0.000 claims 3
- 229910002090 carbon oxide Inorganic materials 0.000 claims 3
- 238000001816 cooling Methods 0.000 claims 3
- 239000008246 gaseous mixture Substances 0.000 claims 3
- 239000000843 powder Substances 0.000 claims 3
- 238000002360 preparation method Methods 0.000 claims 3
- 150000003839 salts Chemical class 0.000 claims 3
- 239000011135 tin Substances 0.000 claims 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 2
- 229910052787 antimony Inorganic materials 0.000 claims 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 239000010439 graphite Substances 0.000 claims 2
- 229910002804 graphite Inorganic materials 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims 2
- 229910052700 potassium Inorganic materials 0.000 claims 2
- 239000011591 potassium Substances 0.000 claims 2
- 239000000725 suspension Substances 0.000 claims 2
- 229910052718 tin Inorganic materials 0.000 claims 2
- 229910002651 NO3 Inorganic materials 0.000 claims 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical class [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims 1
- SKYGTJFKXUWZMD-UHFFFAOYSA-N ac1l2n4h Chemical compound [Co].[Co] SKYGTJFKXUWZMD-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910000410 antimony oxide Inorganic materials 0.000 claims 1
- GVFOJDIFWSDNOY-UHFFFAOYSA-N antimony tin Chemical compound [Sn].[Sb] GVFOJDIFWSDNOY-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- 238000000975 co-precipitation Methods 0.000 claims 1
- 239000000470 constituent Substances 0.000 claims 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- 239000003701 inert diluent Substances 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 150000002823 nitrates Chemical class 0.000 claims 1
- 229910017604 nitric acid Inorganic materials 0.000 claims 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims 1
- 238000001556 precipitation Methods 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- 238000010186 staining Methods 0.000 claims 1
- 239000006228 supernatant Substances 0.000 claims 1
- 229920003051 synthetic elastomer Polymers 0.000 claims 1
- 239000012209 synthetic fiber Substances 0.000 claims 1
- 229920002994 synthetic fiber Polymers 0.000 claims 1
- 239000005061 synthetic rubber Substances 0.000 claims 1
- 238000005979 thermal decomposition reaction Methods 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/843—Arsenic, antimony or bismuth
- B01J23/8435—Antimony
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7410754A FR2265732B1 (enExample) | 1974-03-28 | 1974-03-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU615853A3 true SU615853A3 (ru) | 1978-07-15 |
Family
ID=9136956
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU752114574A SU615853A3 (ru) | 1974-03-28 | 1975-03-25 | Способ получени акрилонитрила |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4035410A (enExample) |
| JP (1) | JPS50130695A (enExample) |
| BE (1) | BE826892A (enExample) |
| DE (1) | DE2513320C3 (enExample) |
| ES (1) | ES436089A1 (enExample) |
| FR (1) | FR2265732B1 (enExample) |
| GB (1) | GB1509221A (enExample) |
| IT (1) | IT1030153B (enExample) |
| NL (1) | NL7503738A (enExample) |
| SU (1) | SU615853A3 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4115434A (en) * | 1976-06-04 | 1978-09-19 | Produits Chimiques Ugine Kuhlmann | Catalysts and processes for preparing unsaturated nitriles |
| US4229374A (en) * | 1977-10-17 | 1980-10-21 | Shell Oil Company | Amine process using Cu-Sn-Na catalyst |
| US4309361A (en) * | 1977-12-20 | 1982-01-05 | Standard Oil Company | Ammoxidation of olefins with novel antimonate catalysts |
| US4316855A (en) * | 1979-12-28 | 1982-02-23 | The Standard Oil Co. | Multiply promoted Sn-Sb oxide catalysts |
| US4532083A (en) * | 1982-10-29 | 1985-07-30 | The Standard Oil Company | Multiply promoted Sn/Sb oxide catalysts |
| US4801568A (en) * | 1987-10-22 | 1989-01-31 | The Standard Oil Company | Catalyst for ammoxidation of paraffins |
| US4866195A (en) * | 1987-10-22 | 1989-09-12 | The Standard Oil Company | Method for ammoxidation of paraffins and catalyst system therefor |
| US6916763B2 (en) * | 2002-11-27 | 2005-07-12 | Solutia Inc. | Process for preparing a catalyst for the oxidation and ammoxidation of olefins |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1195036A (en) * | 1967-11-06 | 1970-06-17 | Ici Ltd | Ammoxidation of Hydrocarbons. |
| GB1364587A (en) * | 1972-03-17 | 1974-08-21 | Bp Chem Int Ltd | Catalyst composition |
-
1974
- 1974-03-28 FR FR7410754A patent/FR2265732B1/fr not_active Expired
-
1975
- 1975-02-13 JP JP50017546A patent/JPS50130695A/ja active Pending
- 1975-02-14 IT IT67395/75A patent/IT1030153B/it active
- 1975-03-20 BE BE154505A patent/BE826892A/xx unknown
- 1975-03-24 GB GB12198/75A patent/GB1509221A/en not_active Expired
- 1975-03-25 SU SU752114574A patent/SU615853A3/ru active
- 1975-03-25 US US05/561,700 patent/US4035410A/en not_active Expired - Lifetime
- 1975-03-26 DE DE2513320A patent/DE2513320C3/de not_active Expired
- 1975-03-26 ES ES436089A patent/ES436089A1/es not_active Expired
- 1975-03-27 NL NL7503738A patent/NL7503738A/xx not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| BE826892A (fr) | 1975-07-16 |
| JPS50130695A (enExample) | 1975-10-16 |
| DE2513320C3 (de) | 1979-03-29 |
| FR2265732B1 (enExample) | 1978-07-28 |
| FR2265732A1 (enExample) | 1975-10-24 |
| US4035410A (en) | 1977-07-12 |
| ES436089A1 (es) | 1977-01-01 |
| NL7503738A (nl) | 1975-09-30 |
| DE2513320B2 (de) | 1978-08-10 |
| IT1030153B (it) | 1979-03-30 |
| DE2513320A1 (de) | 1975-10-02 |
| GB1509221A (en) | 1978-05-04 |
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