SU548201A3 - Способ получени четыреххлористого углерода и перхлорэтилена - Google Patents
Способ получени четыреххлористого углерода и перхлорэтиленаInfo
- Publication number
- SU548201A3 SU548201A3 SU1704907A SU1704907A SU548201A3 SU 548201 A3 SU548201 A3 SU 548201A3 SU 1704907 A SU1704907 A SU 1704907A SU 1704907 A SU1704907 A SU 1704907A SU 548201 A3 SU548201 A3 SU 548201A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- hexachlorobutadiene
- octachlorobutene
- mixture
- chlorination
- reactor
- Prior art date
Links
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 title claims description 12
- 229950011008 tetrachloroethylene Drugs 0.000 title claims description 12
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 title claims description 10
- 238000004519 manufacturing process Methods 0.000 title description 4
- RWNKSTSCBHKHTB-UHFFFAOYSA-N Hexachloro-1,3-butadiene Chemical compound ClC(Cl)=C(Cl)C(Cl)=C(Cl)Cl RWNKSTSCBHKHTB-UHFFFAOYSA-N 0.000 claims description 40
- 238000005660 chlorination reaction Methods 0.000 claims description 20
- 239000000460 chlorine Substances 0.000 claims description 20
- 229910052801 chlorine Inorganic materials 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 18
- 239000012808 vapor phase Substances 0.000 claims description 15
- 239000007791 liquid phase Substances 0.000 claims description 14
- CAEGINLAOUNGOL-UHFFFAOYSA-N 1,1,2,3,3,4,4,4-octachlorobut-1-ene Chemical compound ClC(Cl)=C(Cl)C(Cl)(Cl)C(Cl)(Cl)Cl CAEGINLAOUNGOL-UHFFFAOYSA-N 0.000 claims description 11
- 239000002699 waste material Substances 0.000 claims description 11
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 238000004821 distillation Methods 0.000 claims description 7
- VHHHONWQHHHLTI-UHFFFAOYSA-N hexachloroethane Chemical compound ClC(Cl)(Cl)C(Cl)(Cl)Cl VHHHONWQHHHLTI-UHFFFAOYSA-N 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000000376 reactant Substances 0.000 claims description 5
- 238000000926 separation method Methods 0.000 claims description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000003153 chemical reaction reagent Substances 0.000 claims description 4
- 238000005336 cracking Methods 0.000 claims description 4
- 239000012295 chemical reaction liquid Substances 0.000 claims description 3
- -1 1,2-Dichloroperchlorethylene propane Chemical compound 0.000 claims description 2
- 239000001294 propane Substances 0.000 claims description 2
- JLYXXMFPNIAWKQ-UHFFFAOYSA-N γ Benzene hexachloride Chemical compound ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 4
- QQAHAGNPDBPSJP-UHFFFAOYSA-N 1,1,1,2,2,3,3,3-octachloropropane Chemical compound ClC(Cl)(Cl)C(Cl)(Cl)C(Cl)(Cl)Cl QQAHAGNPDBPSJP-UHFFFAOYSA-N 0.000 claims 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- HBPQNLRAPCSQGW-UHFFFAOYSA-N 1,2,3,4,5,6-hexachlorobenzene;1,1,2,3,4,4-hexachlorobuta-1,3-diene Chemical compound ClC(Cl)=C(Cl)C(Cl)=C(Cl)Cl.ClC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl HBPQNLRAPCSQGW-UHFFFAOYSA-N 0.000 claims 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims 1
- 206010026749 Mania Diseases 0.000 claims 1
- 229910000831 Steel Inorganic materials 0.000 claims 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical group ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 claims 1
- 238000002474 experimental method Methods 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- 101150101156 slc51a gene Proteins 0.000 claims 1
- 239000010959 steel Substances 0.000 claims 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 18
- 239000000047 product Substances 0.000 description 15
- 229910052799 carbon Inorganic materials 0.000 description 5
- KNKRKFALVUDBJE-UHFFFAOYSA-N 1,2-dichloropropane Chemical compound CC(Cl)CCl KNKRKFALVUDBJE-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- CKAPSXZOOQJIBF-UHFFFAOYSA-N hexachlorobenzene Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl CKAPSXZOOQJIBF-UHFFFAOYSA-N 0.000 description 4
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- UMGQVBVEWTXECF-UHFFFAOYSA-N 1,1,2,3-tetrachloroprop-1-ene Chemical compound ClCC(Cl)=C(Cl)Cl UMGQVBVEWTXECF-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RKVAJLMJTGTGRC-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4,4-decachlorobutane Chemical compound ClC(Cl)(Cl)C(Cl)(Cl)C(Cl)(Cl)C(Cl)(Cl)Cl RKVAJLMJTGTGRC-UHFFFAOYSA-N 0.000 description 1
- QVLAWKAXOMEXPM-UHFFFAOYSA-N 1,1,1,2-tetrachloroethane Chemical class ClCC(Cl)(Cl)Cl QVLAWKAXOMEXPM-UHFFFAOYSA-N 0.000 description 1
- MINPZZUPSSVGJN-UHFFFAOYSA-N 1,1,1,4,4,4-hexachlorobutane Chemical compound ClC(Cl)(Cl)CCC(Cl)(Cl)Cl MINPZZUPSSVGJN-UHFFFAOYSA-N 0.000 description 1
- WDVHFYFQERYTAX-UHFFFAOYSA-N 1,1,2,2,2-pentachloroethyl hypochlorite Chemical compound ClOC(C(Cl)(Cl)Cl)(Cl)Cl WDVHFYFQERYTAX-UHFFFAOYSA-N 0.000 description 1
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
- 239000008000 CHES buffer Substances 0.000 description 1
- MKWKNSIESPFAQN-UHFFFAOYSA-N N-cyclohexyl-2-aminoethanesulfonic acid Chemical compound OS(=O)(=O)CCNC1CCCCC1 MKWKNSIESPFAQN-UHFFFAOYSA-N 0.000 description 1
- SPSGYTWOIGAABK-DQEYMECFSA-N [4-[(2s)-2-acetamido-3-[[(5s)-3-carbamoyl-2-(cyclohexylmethoxy)-6,7,8,9-tetrahydro-5h-benzo[7]annulen-5-yl]amino]-3-oxopropyl]-2-phosphonophenyl]phosphonic acid Chemical compound C([C@H](NC(=O)C)C(=O)N[C@@H]1C2=CC(=C(OCC3CCCCC3)C=C2CCCC1)C(N)=O)C1=CC=C(P(O)(O)=O)C(P(O)(O)=O)=C1 SPSGYTWOIGAABK-DQEYMECFSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 241001233037 catfish Species 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 244000144992 flock Species 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- RTJNXKVJEDTNAD-UHFFFAOYSA-N molecular chlorine hydrochloride Chemical compound Cl[H].ClCl RTJNXKVJEDTNAD-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/361—Preparation of halogenated hydrocarbons by reactions involving a decrease in the number of carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/395—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to a chemical modification of at least one compound
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C19/00—Acyclic saturated compounds containing halogen atoms
- C07C19/01—Acyclic saturated compounds containing halogen atoms containing chlorine
- C07C19/03—Chloromethanes
- C07C19/041—Carbon tetrachloride
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C21/00—Acyclic unsaturated compounds containing halogen atoms
- C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
- C07C21/04—Chloro-alkenes
- C07C21/12—Tetrachloro-ethylene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7037413A FR2126899B1 (enrdf_load_stackoverflow) | 1970-10-16 | 1970-10-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU548201A3 true SU548201A3 (ru) | 1977-02-25 |
Family
ID=9062850
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1704907A SU548201A3 (ru) | 1970-10-16 | 1971-10-12 | Способ получени четыреххлористого углерода и перхлорэтилена |
Country Status (9)
| Country | Link |
|---|---|
| BE (1) | BE774021A (enrdf_load_stackoverflow) |
| CA (1) | CA953306A (enrdf_load_stackoverflow) |
| DE (1) | DE2151546B2 (enrdf_load_stackoverflow) |
| ES (1) | ES396037A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2126899B1 (enrdf_load_stackoverflow) |
| GB (1) | GB1316709A (enrdf_load_stackoverflow) |
| IT (1) | IT939574B (enrdf_load_stackoverflow) |
| NL (1) | NL7113635A (enrdf_load_stackoverflow) |
| SU (1) | SU548201A3 (enrdf_load_stackoverflow) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7112709B2 (en) * | 2003-09-09 | 2006-09-26 | Vulcan Chemicals | Method for reusing heavy end by-products in the manufacture of polychlorinated alkanes |
| ES2854833T3 (es) | 2011-10-14 | 2021-09-23 | Honeywell Int Inc | Proceso para producir 2,3,3,3-tetrafluoropropeno |
| CN103588615B (zh) * | 2013-11-01 | 2014-12-10 | 聊城市鲁西化工工程设计有限责任公司 | 一种回收四氯乙烯的装置及工艺 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL132115C (enrdf_load_stackoverflow) * | 1966-02-09 |
-
1970
- 1970-10-16 FR FR7037413A patent/FR2126899B1/fr not_active Expired
-
1971
- 1971-10-05 NL NL7113635A patent/NL7113635A/xx unknown
- 1971-10-12 SU SU1704907A patent/SU548201A3/ru active
- 1971-10-14 IT IT5347171A patent/IT939574B/it active
- 1971-10-15 CA CA125,281A patent/CA953306A/en not_active Expired
- 1971-10-15 BE BE774021A patent/BE774021A/xx unknown
- 1971-10-15 DE DE19712151546 patent/DE2151546B2/de active Granted
- 1971-10-15 ES ES396037A patent/ES396037A1/es not_active Expired
- 1971-10-15 GB GB4812771A patent/GB1316709A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2126899A1 (enrdf_load_stackoverflow) | 1972-10-13 |
| DE2151546A1 (de) | 1972-04-20 |
| DE2151546B2 (de) | 1975-11-27 |
| NL7113635A (enrdf_load_stackoverflow) | 1972-04-18 |
| ES396037A1 (es) | 1974-04-01 |
| CA953306A (en) | 1974-08-20 |
| BE774021A (fr) | 1972-04-17 |
| FR2126899B1 (enrdf_load_stackoverflow) | 1974-04-26 |
| IT939574B (it) | 1973-02-10 |
| GB1316709A (en) | 1973-05-16 |
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