SU52433A1 - The method of obtaining insoluble azo dyes - Google Patents
The method of obtaining insoluble azo dyesInfo
- Publication number
- SU52433A1 SU52433A1 SU52433A1 SU 52433 A1 SU52433 A1 SU 52433A1 SU 52433 A1 SU52433 A1 SU 52433A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- azo dyes
- insoluble azo
- obtaining insoluble
- obtaining
- azo
- Prior art date
Links
- 239000000987 azo dye Substances 0.000 title description 2
- 239000000463 material Substances 0.000 description 5
- 239000000306 component Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- WDJHALXBUFZDSR-UHFFFAOYSA-N Acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M Sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000000875 corresponding Effects 0.000 description 2
- 150000008049 diazo compounds Chemical class 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- SJJCQDRGABAVBB-UHFFFAOYSA-N 1-hydroxy-2-naphthoic acid Chemical compound C1=CC=CC2=C(O)C(C(=O)O)=CC=C21 SJJCQDRGABAVBB-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L Sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000005337 azoxy group Chemical group [N+]([O-])(=N*)* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 125000001891 dimethoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- -1 m-aminophenyl Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000000636 p-nitrophenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)[N+]([O-])=O 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Description
Известно, что можно получить выдающиес по прочности окраски волокнистых материалов и других носителей , примен нерастворимые азокрасители . Обычно дл их получени окрашиЕ аемый материал обрабатывают растзором азосоставл ющей компсненты и затем раствором диазосоединени .It is known that it is possible to obtain outstanding color fastness of fibrous materials and other carriers using insoluble azo dyes. Usually, to obtain them, the stained material is treated with a strain of the azo-component component and then the diazo compound solution.
В редких случа х поступают наоборот , Нсшример, волокно, окрашенное примулино.м, сначала обрабатывают пзотистой кислотой, а затем соответствующей азосоставл ющей коипонектой .In rare cases, it is the other way round that Hsshrimer, a fiber dyed with primulino.m, is first treated with pure acid, and then with the corresponding azo-compo- nent.
Авторами установлено, что (-ан:рах , номилмочевины общей фор:улыThe authors found that (-an: rah, nomilurea common form: uly
СОWITH
..
NHCONHRNH,NHCONHRNH,
Г 1G 1
СОWITH
гце R-двухвалентный органическийrz bivalent organic
радикал, например, фенилен, нафти .;гн. лифенилен и т. д.) могут бытьa radical, for example, phenylene, naphthy.; g. Liphenylene, etc.) may be
л:-: к.зк такозые или фмксироианныеl: -: k.zk takoz or fmiksiroyannye
1цг..-О:ного i-yda МП аолокне или 1tsg ..- O: foot i-yda MT a fiber or
:а г аном-лнбо субстрате диазоти- i: a g Anom-lnbo substrate diazoti i
;:уе:-1ь: и сочетаемы с грилидами, ;: ye: -1: and compatible with the Grilids,
-оксинафтойной кислоты или ацетоуксусной кислоты и др. При этом образуютс нерастворимые в воде азокрзсители.α-hydroxynaphthoic acid or acetoacetic acid, etc. The formation of water-insoluble azoxy acids.
Пример. 0,25 кг р-нитрофенил fi - антрахинонилм.очевины перевод т в куб с 1 К1 гидросульфита натри , 2,5 л раствора едкого натри 40° Вё и 25 уг воды при 60° и разбавл ют водой до 200 л. В полученном кубе крас т 5 г хлопчатобумажного материала в течение 30 минут при 40. После обычной отжимки и окислени материал мочат и затем погружают в 0,5.||-й раствор нитрита натри , подкисленный серной кислотой, имеющей температуру не выше Ю. После 10 мин. выдержки материал отжимают и непродо/икктельное рем промывают холодной водой. Затем от катый материал погружают а раствор азосоставл юшей (j.Example. 0.25 kg of p-nitrophenyl fi-anthraquinoneyl urea is cubed with 1 K1 sodium hydrosulfite, 2.5 liters of sodium hydroxide solution 40 ° Ve and 25 coal water at 60 ° and diluted with water to 200 liters. In the resulting cube, 5 g of cotton material are dyed for 30 minutes at 40. After the usual squeezing and oxidation, the material is wetted and then immersed in 0.5. The sodium nitrite solution acidified with sulfuric acid, having a temperature not higher than Y. 10 min. Exposure material is squeezed and non-food / ikktelnaya rem washed with cold water. Then, the rolled material is immersed and the solution is azo-compacted (j.
Подобным же образом получают на волокне диазосоединени , соответствующие симметричной m-аминофенил - р - антрахинонилмочевине (li) и симметричной 4 - амйно-3,3 диметокси - 4 дифенил В - антрахинонилмочевине (III).Likewise, on the fiber of the diazo compound, corresponding to symmetrical m-aminophenyl - p - anthraquinonylurea (li) and symmetric 4 - amino-3,3 dimethoxy - 4 diphenyl B - anthraquinonylurea (III) are obtained.
При сочетании получаютс следующие цвета:When combined, the following colors are obtained:
Family
ID=
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