CH302036A - Process for the preparation of a chromable disazo dye. - Google Patents
Process for the preparation of a chromable disazo dye.Info
- Publication number
- CH302036A CH302036A CH302036DA CH302036A CH 302036 A CH302036 A CH 302036A CH 302036D A CH302036D A CH 302036DA CH 302036 A CH302036 A CH 302036A
- Authority
- CH
- Switzerland
- Prior art keywords
- chromable
- disazo dye
- mol
- parts
- preparation
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B31/00—Disazo and polyazo dyes of the type A->B->C, A->B->C->D, or the like, prepared by diazotising and coupling
- C09B31/02—Disazo dyes
- C09B31/025—Disazo dyes containing acid groups, e.g. -COOH, -SO3H, -PO3H2, -OSO3H, -OPO2H2; Salts thereof
Description
<B>Zusatzpatent</B> zum Hauptpatent Nr. 297842. Verfahren zur Herstellung eines ehromierbaren Disazofarbstoffes. Gegenstand des vorliegenden Patentes ist ein Verfahren zur Herstellung eines chromier- baren Disazofarbstoffes, welches darin besteht,
dass man 1 Mol der Diazoverbindung aus der durch Kuppeln von diazotierter 1-Aminonaph- tlia.lin-5-sulfonsäure mit 1-Oxy-2-acetylamino- benzol. und anschliessendes Verseifen der Ace- iylaminogruppe erhältlichen Aminomonoazo- verbindung mit 1 Mol 2-Oxynaphthalin kup pelt.
Im nachfolgenden Beispiel bedeuten die Teile Gewichtsteile.
Beispiel: 34,3 Teile der durch Kuppeln von diazo- tierter l.-Aminonaphthalin-5-sulfonsäure mit 1-Oxy-2-acetylaminobenzol und anschliessendes Verseifen der Acetylaminogruppe erhältlichen Aminomonoazoverbindung werden in 400 Tei len Wasser und 4 Teilen Natriumhydroxyd geli3st. Man versetzt die Lösung mit 6,9 Teilen Natriumnitrit und tropft sie in eine Mischung von 36 Teilen konzentrierter Salzsäure und <B>100</B> Teilen Eiswasser.
Den so erhaltenen Diazo- körper trägt man unter Eiskühlung in eine Lösung von 14,4 Teilen 2-Oxynaphthalin und 14 Teilen Natriumhydroxyd in 150 Teilen Wasser ein. Sobald die Bildung des Disazo- farbstoffes beendigt ist, wird dieser mit Na- triumchlorid aus der Kupplungsmasse abge schieden, abfiltriert und getrocknet.
Der neue chromierbare Disazofarbstoff ist ein dunkles Pulver, das sich in verdünnter Sodalösung mit violetter, in konzentrierter Schwefelsäure mit blauer Farbe löst und Wolle nachchromiert und metachrom in graustichig braunen Tönen färbt. Die Färbungen besitzen eine vorzügliche Licht- und sehr gute Nassecht- heiten.
<B> Additional patent </B> to main patent no. 297842. Process for the production of an honorable disazo dye. The subject of the present patent is a process for the production of a chromable disazo dye, which consists in
that 1 mol of the diazo compound is obtained by coupling diazotized 1-aminonaph- tlia.lin-5-sulfonic acid with 1-oxy-2-acetylamino-benzene. and subsequent saponification of the acylamino group obtainable aminomonoazo compound with 1 mol of 2-oxynaphthalene kup pelt.
In the following example, the parts are parts by weight.
Example: 34.3 parts of the aminomonoazo compound obtainable by coupling diazo- tated l-aminonaphthalene-5-sulfonic acid with 1-oxy-2-acetylaminobenzene and subsequent saponification of the acetylamino group are dissolved in 400 parts of water and 4 parts of sodium hydroxide. 6.9 parts of sodium nitrite are added to the solution and it is added dropwise to a mixture of 36 parts of concentrated hydrochloric acid and 100 parts of ice water.
The diazo body thus obtained is introduced into a solution of 14.4 parts of 2-oxynaphthalene and 14 parts of sodium hydroxide in 150 parts of water while cooling with ice. As soon as the formation of the disazo dye is complete, it is separated from the coupling material with sodium chloride, filtered off and dried.
The new chromable disazo dye is a dark powder that dissolves in a dilute soda solution with a violet color and in concentrated sulfuric acid with a blue color and re-chromates wool and dyes it metachromically in grayish brown tones. The dyeings have excellent lightfastness and very good wetfastness.
Claims (1)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH302036T | 1951-09-04 | ||
CH297842T | 1953-01-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
CH302036A true CH302036A (en) | 1954-09-30 |
Family
ID=25733875
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH302036D CH302036A (en) | 1951-09-04 | 1951-09-04 | Process for the preparation of a chromable disazo dye. |
Country Status (1)
Country | Link |
---|---|
CH (1) | CH302036A (en) |
-
1951
- 1951-09-04 CH CH302036D patent/CH302036A/en unknown
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