SU519137A3 - Способ получени дихлорангидрида 2-хлорэтилфосфоновой кислоты - Google Patents
Способ получени дихлорангидрида 2-хлорэтилфосфоновой кислотыInfo
- Publication number
- SU519137A3 SU519137A3 SU1635746A SU1635746A SU519137A3 SU 519137 A3 SU519137 A3 SU 519137A3 SU 1635746 A SU1635746 A SU 1635746A SU 1635746 A SU1635746 A SU 1635746A SU 519137 A3 SU519137 A3 SU 519137A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- acid dichloride
- chloroethylphosphonic
- chloroethylphosphonic acid
- fraction
- mol
- Prior art date
Links
- LOUZURPQCYZSJH-UHFFFAOYSA-N 1-chloro-2-dichlorophosphorylethane Chemical compound ClCCP(Cl)(Cl)=O LOUZURPQCYZSJH-UHFFFAOYSA-N 0.000 title description 22
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 description 19
- 238000005660 chlorination reaction Methods 0.000 description 15
- OWGJXSYVHQEVHS-UHFFFAOYSA-N 1-dichlorophosphorylethane Chemical compound CCP(Cl)(Cl)=O OWGJXSYVHQEVHS-UHFFFAOYSA-N 0.000 description 14
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000000460 chlorine Substances 0.000 description 9
- 229910052801 chlorine Inorganic materials 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000011541 reaction mixture Substances 0.000 description 8
- GATNOFPXSDHULC-UHFFFAOYSA-N ethylphosphonic acid Chemical compound CCP(O)(O)=O GATNOFPXSDHULC-UHFFFAOYSA-N 0.000 description 7
- SPYUGXBMJVRZBP-UHFFFAOYSA-N 1-chloro-1-dichlorophosphorylethane Chemical compound CC(Cl)P(Cl)(Cl)=O SPYUGXBMJVRZBP-UHFFFAOYSA-N 0.000 description 6
- 238000004821 distillation Methods 0.000 description 6
- CNGZUJQPNVPPCJ-UHFFFAOYSA-N 1-chloroethylphosphonic acid Chemical compound CC(Cl)P(O)(O)=O CNGZUJQPNVPPCJ-UHFFFAOYSA-N 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 4
- UDPGUMQDCGORJQ-UHFFFAOYSA-N (2-chloroethyl)phosphonic acid Chemical group OP(O)(=O)CCCl UDPGUMQDCGORJQ-UHFFFAOYSA-N 0.000 description 3
- FQHUXIRBYRGSIR-UHFFFAOYSA-N 2,2-dichloroethylphosphonic acid Chemical compound ClC(CP(O)(O)=O)Cl FQHUXIRBYRGSIR-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000004342 Benzoyl peroxide Substances 0.000 description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- HMFOJAFEYQWZBR-UHFFFAOYSA-N 1,1-dichloro-2-dichlorophosphorylethane Chemical compound ClC(Cl)CP(Cl)(Cl)=O HMFOJAFEYQWZBR-UHFFFAOYSA-N 0.000 description 2
- NHYCGSASNAIGLD-UHFFFAOYSA-N Chlorine monoxide Chemical compound Cl[O] NHYCGSASNAIGLD-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 239000012320 chlorinating reagent Substances 0.000 description 2
- 238000004508 fractional distillation Methods 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 description 2
- MRMOZBOQVYRSEM-UHFFFAOYSA-N tetraethyllead Chemical compound CC[Pb](CC)(CC)CC MRMOZBOQVYRSEM-UHFFFAOYSA-N 0.000 description 2
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- DEWLEGDTCGBNGU-UHFFFAOYSA-N 1,3-dichloropropan-2-ol Chemical compound ClCC(O)CCl DEWLEGDTCGBNGU-UHFFFAOYSA-N 0.000 description 1
- GUTLYIVDDKVIGB-OUBTZVSYSA-N Cobalt-60 Chemical compound [60Co] GUTLYIVDDKVIGB-OUBTZVSYSA-N 0.000 description 1
- 206010062717 Increased upper airway secretion Diseases 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 239000004157 Nitrosyl chloride Substances 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- -1 acetylcyclohexylsulfonyl Chemical group 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- VPCDQGACGWYTMC-UHFFFAOYSA-N nitrosyl chloride Chemical compound ClN=O VPCDQGACGWYTMC-UHFFFAOYSA-N 0.000 description 1
- 235000019392 nitrosyl chloride Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 208000026435 phlegm Diseases 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/123—Ultraviolet light
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/42—Halides thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Toxicology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19702015163 DE2015163A1 (de) | 1970-03-28 | 1970-03-28 | Verfahren zur Herstellung von 2 Chlor athanphosphonsauredichlorid |
| DE2102264A DE2102264C3 (de) | 1971-01-19 | 1971-01-19 | Verfahren zur Herstellung von 2-Chloraethanphosphonsäuredichlorid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU519137A3 true SU519137A3 (ru) | 1976-06-25 |
Family
ID=25758902
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1635746A SU519137A3 (ru) | 1970-03-28 | 1971-03-28 | Способ получени дихлорангидрида 2-хлорэтилфосфоновой кислоты |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS5441572B1 (de) |
| AT (1) | AT306053B (de) |
| BE (1) | BE764873A (de) |
| CA (1) | CA937939A (de) |
| CH (1) | CH550826A (de) |
| FR (1) | FR2085140A5 (de) |
| GB (1) | GB1283678A (de) |
| IL (1) | IL36500A (de) |
| NL (1) | NL168231C (de) |
| RO (1) | RO60462A (de) |
| SU (1) | SU519137A3 (de) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3629579A1 (de) * | 1986-08-30 | 1988-03-03 | Hoechst Ag | Verfahren zur herstellung von 2-chlorethanphosphonsaeuredichlorid |
-
1971
- 1971-03-23 NL NLAANVRAGE7103873,A patent/NL168231C/xx not_active IP Right Cessation
- 1971-03-25 FR FR7110588A patent/FR2085140A5/fr not_active Expired
- 1971-03-26 BE BE764873A patent/BE764873A/xx not_active IP Right Cessation
- 1971-03-26 JP JP1731971A patent/JPS5441572B1/ja active Pending
- 1971-03-26 CH CH445471A patent/CH550826A/de not_active IP Right Cessation
- 1971-03-26 CA CA108796A patent/CA937939A/en not_active Expired
- 1971-03-26 IL IL36500A patent/IL36500A/en unknown
- 1971-03-26 AT AT259171A patent/AT306053B/de not_active IP Right Cessation
- 1971-03-27 RO RO66405A patent/RO60462A/ro unknown
- 1971-03-28 SU SU1635746A patent/SU519137A3/ru active
- 1971-04-19 GB GB25392/71A patent/GB1283678A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CH550826A (de) | 1974-06-28 |
| GB1283678A (en) | 1972-08-02 |
| IL36500A0 (en) | 1971-05-26 |
| FR2085140A5 (de) | 1971-12-17 |
| NL7103873A (de) | 1971-09-30 |
| BE764873A (fr) | 1971-09-27 |
| RO60462A (de) | 1976-08-15 |
| CA937939A (en) | 1973-12-04 |
| AT306053B (de) | 1973-03-26 |
| JPS5441572B1 (de) | 1979-12-08 |
| NL168231C (nl) | 1982-03-16 |
| NL168231B (nl) | 1981-10-16 |
| IL36500A (en) | 1973-07-30 |
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