SU481161A3 - Стабилизированна композици на основе гомо или сополимеров олефинов - Google Patents
Стабилизированна композици на основе гомо или сополимеров олефиновInfo
- Publication number
- SU481161A3 SU481161A3 SU1658619A SU1658619A SU481161A3 SU 481161 A3 SU481161 A3 SU 481161A3 SU 1658619 A SU1658619 A SU 1658619A SU 1658619 A SU1658619 A SU 1658619A SU 481161 A3 SU481161 A3 SU 481161A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- acid
- methyl
- copolymers
- compounds
- butyl
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title description 7
- 229920001577 copolymer Polymers 0.000 title description 6
- 229920001519 homopolymer Polymers 0.000 title description 3
- 150000001336 alkenes Chemical class 0.000 title description 2
- -1 hexadiene Chemical class 0.000 description 23
- 239000002253 acid Substances 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 11
- 150000002148 esters Chemical class 0.000 description 8
- GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- RMSGQZDGSZOJMU-UHFFFAOYSA-N 1-butyl-2-phenylbenzene Chemical group CCCCC1=CC=CC=C1C1=CC=CC=C1 RMSGQZDGSZOJMU-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000006078 metal deactivator Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- JXSRRBVHLUJJFC-UHFFFAOYSA-N 7-amino-2-methylsulfanyl-[1,2,4]triazolo[1,5-a]pyrimidine-6-carbonitrile Chemical compound N1=CC(C#N)=C(N)N2N=C(SC)N=C21 JXSRRBVHLUJJFC-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 229920002367 Polyisobutene Polymers 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 150000001559 benzoic acids Chemical class 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229920003020 cross-linked polyethylene Polymers 0.000 description 2
- 239000004703 cross-linked polyethylene Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- URGSMJLDEFDWNX-UHFFFAOYSA-N 1-butylnaphthalene Chemical compound C1=CC=C2C(CCCC)=CC=CC2=C1 URGSMJLDEFDWNX-UHFFFAOYSA-N 0.000 description 1
- ZNRLMGFXSPUZNR-UHFFFAOYSA-N 2,2,4-trimethyl-1h-quinoline Chemical compound C1=CC=C2C(C)=CC(C)(C)NC2=C1 ZNRLMGFXSPUZNR-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- UDRQSYOGRUGDNA-UHFFFAOYSA-N 2-butyloxane Chemical compound CCCCC1CCCCO1 UDRQSYOGRUGDNA-UHFFFAOYSA-N 0.000 description 1
- YHEYEPDRELFHFM-UHFFFAOYSA-N 2-methyl-2-phenylhexanoic acid Chemical compound CCCCC(C)(C(O)=O)C1=CC=CC=C1 YHEYEPDRELFHFM-UHFFFAOYSA-N 0.000 description 1
- JHVMLJXYLFVIBM-UHFFFAOYSA-N 3-octadecoxy-3-oxopropanoic acid Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CC(O)=O JHVMLJXYLFVIBM-UHFFFAOYSA-N 0.000 description 1
- ISAVYTVYFVQUDY-UHFFFAOYSA-N 4-tert-Octylphenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(O)C=C1 ISAVYTVYFVQUDY-UHFFFAOYSA-N 0.000 description 1
- DOFLWDGGNKBGSL-UHFFFAOYSA-N 6-dodecyl-2,2,4-trimethyl-1h-quinoline Chemical compound N1C(C)(C)C=C(C)C2=CC(CCCCCCCCCCCC)=CC=C21 DOFLWDGGNKBGSL-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 241000195940 Bryophyta Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 241000243251 Hydra Species 0.000 description 1
- 235000003325 Ilex Nutrition 0.000 description 1
- 241000209035 Ilex Species 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 241000282806 Rhinoceros Species 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000005036 alkoxyphenyl group Chemical group 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- ALHNLFMSAXZKRC-UHFFFAOYSA-N benzene-1,4-dicarbohydrazide Chemical compound NNC(=O)C1=CC=C(C(=O)NN)C=C1 ALHNLFMSAXZKRC-UHFFFAOYSA-N 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 125000006487 butyl benzyl group Chemical group 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- XEVRDFDBXJMZFG-UHFFFAOYSA-N carbonyl dihydrazine Chemical compound NNC(=O)NN XEVRDFDBXJMZFG-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000012505 colouration Methods 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- SWRGUMCEJHQWEE-UHFFFAOYSA-N ethanedihydrazide Chemical compound NNC(=O)C(=O)NN SWRGUMCEJHQWEE-UHFFFAOYSA-N 0.000 description 1
- AEOCXXJPGCBFJA-UHFFFAOYSA-N ethionamide Chemical compound CCC1=CC(C(N)=S)=CC=N1 AEOCXXJPGCBFJA-UHFFFAOYSA-N 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- QRXWMOHMRWLFEY-UHFFFAOYSA-N isoniazide Chemical compound NNC(=O)C1=CC=NC=C1 QRXWMOHMRWLFEY-UHFFFAOYSA-N 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 235000011929 mousse Nutrition 0.000 description 1
- FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical compound C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 description 1
- 150000003941 n-butylamines Chemical class 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- PSIKPHJLTVSQFO-UHFFFAOYSA-N propanedihydrazide Chemical compound NNC(=O)CC(=O)NN PSIKPHJLTVSQFO-UHFFFAOYSA-N 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 230000003612 virological effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/22—Compounds containing nitrogen bound to another nitrogen atom
- C08K5/24—Derivatives of hydrazine
- C08K5/25—Carboxylic acid hydrazides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Organic Insulating Materials (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH737170A CH529803A (de) | 1970-05-19 | 1970-05-19 | Verwendung von Diacyldihydraziden als Stabilisatoren für Polyolefine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU481161A3 true SU481161A3 (ru) | 1975-08-15 |
Family
ID=4324077
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1658619A SU481161A3 (ru) | 1970-05-19 | 1971-05-17 | Стабилизированна композици на основе гомо или сополимеров олефинов |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3734885A (enExample) |
| JP (1) | JPS508097B1 (enExample) |
| AT (1) | AT304875B (enExample) |
| CA (1) | CA970091A (enExample) |
| CH (1) | CH529803A (enExample) |
| DE (1) | DE2124641A1 (enExample) |
| ES (1) | ES391307A1 (enExample) |
| FR (1) | FR2091804A5 (enExample) |
| GB (1) | GB1319367A (enExample) |
| NL (1) | NL7106826A (enExample) |
| SU (1) | SU481161A3 (enExample) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4038247A (en) * | 1970-05-19 | 1977-07-26 | Ciba-Geigy Corporation | Stabilizing polyolefins with diacyl dihydrazides |
| US3894990A (en) * | 1971-05-06 | 1975-07-15 | Ciba Geigy Corp | Stabilization of homo-or copolymeric polyolefins with diacyl dihydrazides |
| US3907925A (en) * | 1973-10-10 | 1975-09-23 | Ciba Geigy Corp | Metal deactivators as adhesion promotors for vulcanizable elastomers to metals |
| US3994987A (en) * | 1973-10-10 | 1976-11-30 | Ciba-Geigy Corporation | Metal deactivators as adhesion promotors for vulcanizable elastomers to metals |
| US3888825A (en) * | 1973-10-19 | 1975-06-10 | American Cyanamid Co | Copper inhibitors for polyolefins |
| US4012360A (en) * | 1973-12-03 | 1977-03-15 | Ciba-Geigy Corporation | Bis-salicyloyl-dicarboxylic acid dihydrazides as stabilizers for polyolefines |
| JPS542226B2 (enExample) * | 1973-12-31 | 1979-02-03 | ||
| US3951911A (en) * | 1974-04-26 | 1976-04-20 | Dart Industries Inc. | Stabilized propylene-based polymer compositions |
| US3931103A (en) * | 1974-10-18 | 1976-01-06 | American Cyanamid Company | Copper inhibitors for polyolefins |
| US4035325A (en) * | 1975-06-16 | 1977-07-12 | Standard Oil Company (Indiana) | Use of organometallic salts and metal deactivators as flame retardants for polyolefins |
| US4077948A (en) * | 1975-07-30 | 1978-03-07 | Ciba-Geigy Corporation | Metal deactivators as adhesion promotors for vulcanizable elastomers to metals |
| US4061845A (en) * | 1976-11-04 | 1977-12-06 | The General Tire & Rubber Company | Copolymers of hydrazides and certain unsaturated esters |
| US4087405A (en) * | 1977-08-26 | 1978-05-02 | Eastman Kodak Company | Polyhydrazides as stabilizers for polyolefins |
| US4145556A (en) * | 1977-12-21 | 1979-03-20 | Monsanto Company | Oxamide stabilizers for organic materials |
| US4154723A (en) * | 1977-12-21 | 1979-05-15 | Monsanto Company | Stabilization of organic materials |
| DE2933870A1 (de) * | 1979-08-21 | 1981-03-12 | Siemens AG, 1000 Berlin und 8000 München | N.n'-bis-salicyloyl-hydrazin als metalldesaktivator. |
| US4874803A (en) * | 1987-09-21 | 1989-10-17 | Pennwalt Corporation | Dianhydride coupled polymer stabilizers |
| EP0333643A3 (de) * | 1988-02-12 | 1990-01-31 | Ciba-Geigy Ag | Stabilisierte Zusammensetzungen |
| JP5461952B2 (ja) * | 2009-10-23 | 2014-04-02 | 株式会社Ａｄｅｋａ | ポリオレフィン系樹脂組成物 |
| CN102976969B (zh) * | 2012-11-27 | 2015-04-29 | 山西省化工研究所 | 一种提高脂肪二羧酸二酰肼类成核剂收率的制备方法 |
| WO2016209663A1 (en) * | 2015-06-22 | 2016-12-29 | 3M Innovative Properties Company | Hydrazide compounds suitable for nucleating polylactic acid polymer |
| CN117106237B (zh) * | 2023-07-05 | 2024-03-26 | 湖南联塑科技实业有限公司 | 一种复合改性剂及其聚丙烯组合物 |
-
1970
- 1970-05-19 CH CH737170A patent/CH529803A/de not_active IP Right Cessation
-
1971
- 1971-05-06 US US00141027A patent/US3734885A/en not_active Expired - Lifetime
- 1971-05-17 SU SU1658619A patent/SU481161A3/ru active
- 1971-05-18 ES ES391307A patent/ES391307A1/es not_active Expired
- 1971-05-18 JP JP46033550A patent/JPS508097B1/ja active Pending
- 1971-05-18 CA CA113,252A patent/CA970091A/en not_active Expired
- 1971-05-18 NL NL7106826A patent/NL7106826A/xx unknown
- 1971-05-18 GB GB1555871*[A patent/GB1319367A/en not_active Expired
- 1971-05-18 DE DE19712124641 patent/DE2124641A1/de active Pending
- 1971-05-18 AT AT430371A patent/AT304875B/de active
- 1971-05-19 FR FR7118213A patent/FR2091804A5/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ES391307A1 (es) | 1974-11-16 |
| CA970091A (en) | 1975-06-24 |
| NL7106826A (enExample) | 1971-11-23 |
| AT304875B (de) | 1973-01-25 |
| CH529803A (de) | 1972-10-31 |
| FR2091804A5 (enExample) | 1972-01-14 |
| JPS508097B1 (enExample) | 1975-04-02 |
| US3734885A (en) | 1973-05-22 |
| GB1319367A (en) | 1973-06-06 |
| DE2124641A1 (de) | 1971-12-02 |
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