SU425386A3 - - Google Patents
Info
- Publication number
- SU425386A3 SU425386A3 SU1453496A SU1453496A SU425386A3 SU 425386 A3 SU425386 A3 SU 425386A3 SU 1453496 A SU1453496 A SU 1453496A SU 1453496 A SU1453496 A SU 1453496A SU 425386 A3 SU425386 A3 SU 425386A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- thallium
- reaction
- mixture
- temperature
- flask
- Prior art date
Links
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 16
- 229910052716 thallium Inorganic materials 0.000 description 12
- OGRAOKJKVGDSFR-UHFFFAOYSA-N 2,3,5-trimethylphenol Chemical compound CC1=CC(C)=C(C)C(O)=C1 OGRAOKJKVGDSFR-UHFFFAOYSA-N 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 150000003475 thallium Chemical class 0.000 description 10
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 9
- YTQVHRVITVLIRD-UHFFFAOYSA-L thallium sulfate Chemical compound [Tl+].[Tl+].[O-]S([O-])(=O)=O YTQVHRVITVLIRD-UHFFFAOYSA-L 0.000 description 8
- QQOMQLYQAXGHSU-UHFFFAOYSA-N 236TMPh Natural products CC1=CC=C(C)C(O)=C1C QQOMQLYQAXGHSU-UHFFFAOYSA-N 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
- 229940119523 thallium sulfate Drugs 0.000 description 6
- 229910000374 thallium(I) sulfate Inorganic materials 0.000 description 6
- -1 aromatic cyclic compound Chemical class 0.000 description 5
- 150000002989 phenols Chemical class 0.000 description 5
- 150000004053 quinones Chemical class 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- QIXDHVDGPXBRRD-UHFFFAOYSA-N 2,3,5-trimethylcyclohexa-2,5-diene-1,4-dione Chemical compound CC1=CC(=O)C(C)=C(C)C1=O QIXDHVDGPXBRRD-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- AUFZRCJENRSRLY-UHFFFAOYSA-N 2,3,5-trimethylhydroquinone Chemical compound CC1=CC(O)=C(C)C(C)=C1O AUFZRCJENRSRLY-UHFFFAOYSA-N 0.000 description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000005228 aryl sulfonate group Chemical group 0.000 description 1
- 239000012455 biphasic mixture Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- FYWSTUCDSVYLPV-UHFFFAOYSA-N nitrooxythallium Chemical compound [Tl+].[O-][N+]([O-])=O FYWSTUCDSVYLPV-UHFFFAOYSA-N 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- WKMKTIVRRLOHAJ-UHFFFAOYSA-N oxygen(2-);thallium(1+) Chemical compound [O-2].[Tl+].[Tl+] WKMKTIVRRLOHAJ-UHFFFAOYSA-N 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910021515 thallium hydroxide Inorganic materials 0.000 description 1
- 229910003438 thallium oxide Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C50/00—Quinones
- C07C50/24—Quinones containing halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C46/00—Preparation of quinones
- C07C46/02—Preparation of quinones by oxidation giving rise to quinoid structures
- C07C46/06—Preparation of quinones by oxidation giving rise to quinoid structures of at least one hydroxy group on a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C50/00—Quinones
- C07C50/02—Quinones with monocyclic quinoid structure
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR6922816A FR2053457A5 (enExample) | 1969-07-04 | 1969-07-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU425386A3 true SU425386A3 (enExample) | 1974-04-25 |
Family
ID=9037002
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1453496A SU425386A3 (enExample) | 1969-07-04 | 1970-07-03 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3671552A (enExample) |
| JP (1) | JPS4940219B1 (enExample) |
| BE (1) | BE753013A (enExample) |
| CH (1) | CH516498A (enExample) |
| DE (1) | DE2033136C3 (enExample) |
| FR (1) | FR2053457A5 (enExample) |
| GB (1) | GB1244470A (enExample) |
| NL (1) | NL144259B (enExample) |
| SE (1) | SE366292B (enExample) |
| SU (1) | SU425386A3 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3215095A1 (de) * | 1982-04-23 | 1983-10-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von 2,3,5-trimethyl-l-p-benzochinon |
| US4394369A (en) * | 1982-05-24 | 1983-07-19 | Fmc Corporation | Hydrogen peroxide process |
| US4482493A (en) * | 1982-10-22 | 1984-11-13 | Sagami Chemical Research Center | Method for preparing benzoquinones |
| ES2015006B3 (es) * | 1986-05-05 | 1990-08-01 | W R Grace & Co -Conn (A Connecticut Corp ) | Oxidacion de compuestos organicos. |
| US4692227A (en) * | 1986-12-01 | 1987-09-08 | W. R. Grace & Co. | Oxidation of organic compounds using thallium ions |
| US5175318A (en) * | 1986-06-11 | 1992-12-29 | Consiglio Nazionale Della Ricerche | Process for the preparation of quinones |
| US5340483A (en) * | 1993-06-11 | 1994-08-23 | University Of Maryland At College Park | Two step process for conversion of a weakly adsorbable compound to a strongly adsorbable compound and selective removal thereof |
| EP3543208A1 (en) | 2018-03-19 | 2019-09-25 | Solvay Sa | Process for manufacturing an aqueous hydrogen peroxide solution |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3213114A (en) * | 1962-06-19 | 1965-10-19 | Ethyl Corp | Preparation of quinones and hydroquinones |
| BE635349A (enExample) * | 1962-07-24 |
-
1969
- 1969-07-04 FR FR6922816A patent/FR2053457A5/fr not_active Expired
-
1970
- 1970-06-26 NL NL707009474A patent/NL144259B/xx not_active IP Right Cessation
- 1970-07-02 US US52071A patent/US3671552A/en not_active Expired - Lifetime
- 1970-07-02 JP JP45057330A patent/JPS4940219B1/ja active Pending
- 1970-07-03 BE BE753013D patent/BE753013A/xx unknown
- 1970-07-03 DE DE2033136A patent/DE2033136C3/de not_active Expired
- 1970-07-03 GB GB32464/70A patent/GB1244470A/en not_active Expired
- 1970-07-03 SU SU1453496A patent/SU425386A3/ru active
- 1970-07-03 CH CH1012470A patent/CH516498A/fr not_active IP Right Cessation
- 1970-07-03 SE SE09276/70A patent/SE366292B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB1244470A (en) | 1971-09-02 |
| SE366292B (enExample) | 1974-04-22 |
| DE2033136C3 (de) | 1973-11-15 |
| DE2033136A1 (de) | 1972-02-10 |
| DE2033136B2 (de) | 1973-04-19 |
| US3671552A (en) | 1972-06-20 |
| CH516498A (fr) | 1971-12-15 |
| NL144259B (nl) | 1974-12-16 |
| FR2053457A5 (enExample) | 1971-04-16 |
| BE753013A (fr) | 1971-01-04 |
| JPS4940219B1 (enExample) | 1974-10-31 |
| NL7009474A (enExample) | 1971-01-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2398418A (en) | Introduction of organic radicals into quinones | |
| Fieser | The alkylation of hydroxynaphthoquinone II. Carbon alkylation | |
| SU437270A1 (ru) | Способ получени ароматических оксиальдегидов | |
| IL45113A (en) | 6-substituted-2-benzoxyzolinone derivatives and their preparation | |
| US3671552A (en) | Process for the preparation of quinones and hydroquinones | |
| Weitl | Regiospecific 2, 4-diiodination of resorcinol with nascent iodine | |
| Kirker | An efficient synthesis of 5-sulfosalicylaldehyde sodium salt | |
| US3862952A (en) | Method for preparing 3,5,6-trichloro-2-pyridyloxyacetic acid | |
| US3153077A (en) | Process for preparing organic bis-thiosulfates | |
| Evans et al. | The mechanism of carbohydrate oxidation. V. The oxidation of dihydroxy-acetone to hydroxypyruvic aldehyde | |
| SU499806A3 (ru) | Способ получени производных пиперазина | |
| SU486509A3 (ru) | Способ получени моноциклических терпеновых сульфонов | |
| US2179978A (en) | Process for the manufacture of levo-ascorbic acid | |
| US2456395A (en) | Synthesis of riboflavin | |
| US2502325A (en) | Derivatives of hexestrol | |
| US2060181A (en) | Alkali-metal salts of antimoniothiomalic acid | |
| US3287396A (en) | Phenyldesoxythyronines | |
| US2257980A (en) | Manufacture of aliphatic ijnsatu- | |
| Korytnyk et al. | Chemistry and biology of vitamin B6. 34. Interaction of pyridoxalla with cyanide | |
| US1957089A (en) | Process of preparing nitro- | |
| JPS6121949B2 (enExample) | ||
| US2357613A (en) | Alkali metal acid salts of oxidation products of abietic acid | |
| SU406832A1 (ru) | Способ получения алкилиденпиранов или солей пирилия | |
| SU1505940A1 (ru) | Способ получени тетрафторборатов 2, 4, 6-триарилпирили | |
| US5175318A (en) | Process for the preparation of quinones |