SU35163A1 - A method for making elastic plastics for artificial leather or the like. - Google Patents
A method for making elastic plastics for artificial leather or the like.Info
- Publication number
- SU35163A1 SU35163A1 SU130758A SU130758A SU35163A1 SU 35163 A1 SU35163 A1 SU 35163A1 SU 130758 A SU130758 A SU 130758A SU 130758 A SU130758 A SU 130758A SU 35163 A1 SU35163 A1 SU 35163A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- artificial leather
- making elastic
- elastic plastics
- benzylation
- mixture
- Prior art date
Links
- 239000002649 leather substitute Substances 0.000 title description 4
- 229920003023 plastic Polymers 0.000 title description 2
- 239000004033 plastic Substances 0.000 title 1
- 238000005574 benzylation reaction Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 235000013312 flour Nutrition 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N Anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 1
- SESFRYSPDFLNCH-UHFFFAOYSA-N Benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 1
- DSSYKIVIOFKYAU-UHFFFAOYSA-N Camphor Chemical compound C1CC2(C)C(=O)CC1C2(C)C DSSYKIVIOFKYAU-UHFFFAOYSA-N 0.000 description 1
- 229960000846 Camphor Drugs 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- YNPNZTXNASCQKK-UHFFFAOYSA-N Phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 1
- 210000003491 Skin Anatomy 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229960002903 benzyl benzoate Drugs 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229930007890 camphor Natural products 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000002916 wood waste Substances 0.000 description 1
Description
способа изготовлени эластичных плаешческюс насГ дл искусственной кожи или т. п.A method of making elastic, clean skin for artificial leather or the like.
К авторскому свидетельству Б. В. Максорова и К.А. Аидркаиов , за вленному 22 ию 1933 года (спр. о перв. № 130758).To the author's certificate of B.V. Maksorov and K.A. Aidrkaiov, dated July 22, 1933 (cf. on the first. No. 130758).
О выдаче авторского сиилетельстга олубликопано 31 марта года.On the issuance of copyright sieletelstg olublikopano March 31 year.
В патентах Леона Лилиенфельда (герм. пат. KsNs 504226, 535393 и др.) предлагаютс способы получени искусственной кожи из смеси бензилцеллюлозы с бензилкрахмалом . Эти способы имеют тот недостаток, что дл них требуютс выделенные в чистом виде бензилцеллю .лоза и бензилкрахмал Хот приготовление того и другого материала не вл етс сложной операцией, особенно в от-1 ношении крахмала, но процесс очистки сложен и дорог. Бензилирование чистой целлюлозы достаточно разработано р дом американских, германских и понских исследований и у нас Институтом пластических масс Но нет нигде упоминани на возможность получени техни- j чески ценного продукта путем бензили- роваии целиком, например, древесной муки или опилок. Между тем, такое бензилиронание, как показали опыты, п определенных услови х ведет к образованию весьма интересных своеобразных продуктов. Эти продукты, после соответствующей гомогенизации, весьма напоминают кожу, резину и тому подобные материалы и могут найти широкое применение или в качестве пластификаторов, например, дл резиновых смесей, или, в смесиThe patents of Leon Lilienfeld (Germ. Pat. KsNs 504226, 535393, etc.) suggest methods for obtaining artificial leather from a mixture of benzylcellulose and benzyl starch. These methods have the disadvantage that they require pure benzylcellulum and benzyl starch. Although the preparation of this and other materials is not a difficult operation, especially in relation to starch, the cleaning process is complicated and expensive. Benzylation of pure cellulose has been sufficiently developed by a number of American, German, and Japanese studies and we have the Institute of Plastics. But nowhere is there any mention of the possibility of obtaining a technically valuable product by benzylation entirely, for example, wood flour or sawdust. Meanwhile, such benzylation as experiments have shown, under certain conditions, leads to the formation of very interesting peculiar products. These products, after appropriate homogenization, are very similar to leather, rubber and similar materials and can be widely used either as plasticizers, for example, for rubber compounds, or in a mixture
(22)(22)
с наполнител ми, дл изготовлени искус .ственной кожи.with fillers for making artificial leather.
Дл бензилировани древесных отходов (муки, опилок) авторы применили двухступенчатое бензилирование с повышением концентрации щелочи, какое рекомендуетс при бензилировании целлюлозы . Кроме того, с успехом испробовано пропускание хлора в процессе бензилировани дл большего .расшатывани молекул целлюлозы и лигнина. . В результате бензилировани получаетс смесь продуктов с различной степенью растворимости в органических растворител х. Но эта смесь при нагревании под давлением (например, в пальцах , под прессом, в мешалках) с такими веществами как: камфара, нафталин, антрацен, фенантрен, абиетаты и т. д., весьма легко образует почти прозрачную однородную, эластичную и доиольно прочную механически массу. Прочность еще больше может быть усилена овсдением каучука, полимеризующихс веществ , искусственных смол, наполнителей и т. д, .To benylate wood waste (flour, sawdust), the authors applied two-step benzylation with an increase in alkali concentration, which is recommended for cellulose benzylation. In addition, chlorine transmission during the benzylation process has been successfully tested for greater loosening of cellulose and lignin molecules. . Benzylation results in a mixture of products with varying degrees of solubility in organic solvents. But when heated under pressure (for example, in fingers, under pressure, in agitators) with such substances as camphor, naphthalene, anthracene, phenanthrene, abietates, etc., this mixture very easily forms an almost transparent homogeneous, elastic mechanically mass. Strength can be further enhanced by ovification of rubber, polymerizable substances, artificial resins, fillers, etc.
Ниже приведено несколько примеров бензилировани иизготовлени масс.Below are some examples of benzylation and mass production.
Пример 1. 250 г древесной муки Х90ЙНЫХ пород смешивают с 1000 гExample 1. 250 g of wood flour X90Y breeds mixed with 1000 g
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU35163A1 true SU35163A1 (en) | 1934-03-31 |
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