SU306115A1 - - Google Patents

Info

Publication number

SU306115A1

SU306115A1 SU1257156A SU1257156A SU306115A1 SU 306115 A1 SU306115 A1 SU 306115A1 SU 1257156 A SU1257156 A SU 1257156A SU 1257156 A SU1257156 A SU 1257156A SU 306115 A1 SU306115 A1 SU 306115A1

Authority

SU

USSR - Soviet Union

Prior art keywords

aldehyde

catalyst

aldehydes

reaction

aluminum

Prior art date

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• 150000001299 aldehydes Chemical class 0.000 description 18
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
• 239000003054 catalyst Substances 0.000 description 12
• 238000000034 method Methods 0.000 description 12
• 238000006243 chemical reaction Methods 0.000 description 11
• 150000002148 esters Chemical class 0.000 description 6
• 229910052782 aluminium Inorganic materials 0.000 description 5
• -1 aluminum alkoxides Chemical class 0.000 description 5
• 238000009833 condensation Methods 0.000 description 5
• 230000005494 condensation Effects 0.000 description 5
• RXGUIWHIADMCFC-UHFFFAOYSA-N 2-Methylpropyl 2-methylpropionate Chemical compound CC(C)COC(=O)C(C)C RXGUIWHIADMCFC-UHFFFAOYSA-N 0.000 description 4
• AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 description 4
• XUPYJHCZDLZNFP-UHFFFAOYSA-N butyl butanoate Chemical compound CCCCOC(=O)CCC XUPYJHCZDLZNFP-UHFFFAOYSA-N 0.000 description 4
• 239000000203 mixture Substances 0.000 description 4
• 238000002360 preparation method Methods 0.000 description 4
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
• 239000002253 acid Substances 0.000 description 2
• 239000012190 activator Substances 0.000 description 2
• 239000000654 additive Substances 0.000 description 2
• 230000015572 biosynthetic process Effects 0.000 description 2
• 238000004587 chromatography analysis Methods 0.000 description 2
• 238000004821 distillation Methods 0.000 description 2
• 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
• MYWQGROTKMBNKN-UHFFFAOYSA-N tributoxyalumane Chemical compound [Al+3].CCCC[O-].CCCC[O-].CCCC[O-] MYWQGROTKMBNKN-UHFFFAOYSA-N 0.000 description 2
• DAOVYDBYKGXFOB-UHFFFAOYSA-N tris(2-methylpropoxy)alumane Chemical compound [Al+3].CC(C)C[O-].CC(C)C[O-].CC(C)C[O-] DAOVYDBYKGXFOB-UHFFFAOYSA-N 0.000 description 2
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
• 239000010457 zeolite Substances 0.000 description 2
• XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
• 238000009835 boiling Methods 0.000 description 1
• 238000005352 clarification Methods 0.000 description 1
• 238000000354 decomposition reaction Methods 0.000 description 1
• 238000001035 drying Methods 0.000 description 1
• 150000002170 ethers Chemical class 0.000 description 1
• 238000001914 filtration Methods 0.000 description 1
• 239000002044 hexane fraction Substances 0.000 description 1
• XBFMJHQFVWWFLA-UHFFFAOYSA-N hexane;pentane Chemical compound CCCCC.CCCCCC XBFMJHQFVWWFLA-UHFFFAOYSA-N 0.000 description 1
• 238000007037 hydroformylation reaction Methods 0.000 description 1
• 238000004321 preservation Methods 0.000 description 1
• QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
• 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
• 239000012429 reaction media Substances 0.000 description 1
• 230000035484 reaction time Effects 0.000 description 1
• 238000001577 simple distillation Methods 0.000 description 1
• 239000002904 solvent Substances 0.000 description 1
• ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 1