SU1715206A3 - N-Алкил-2-азабицикло(2,2,1)гептан в качестве катализатора дл получени пенополиуретана - Google Patents

N-Алкил-2-азабицикло(2,2,1)гептан в качестве катализатора дл получени пенополиуретана Download PDF

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Publication number
SU1715206A3
SU1715206A3 SU884355338A SU4355338A SU1715206A3 SU 1715206 A3 SU1715206 A3 SU 1715206A3 SU 884355338 A SU884355338 A SU 884355338A SU 4355338 A SU4355338 A SU 4355338A SU 1715206 A3 SU1715206 A3 SU 1715206A3
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SU
USSR - Soviet Union
Prior art keywords
azabicyclo
heptane
alkyl
catalyst
foamed polyurethane
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SU884355338A
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English (en)
Inventor
Глузек Карл-Гейнц
Хумберт Хейко
Original Assignee
Рвэ-Деа Акциенгезельшафт Фюр Минераль Унд Хеми (Фирма)
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Application filed by Рвэ-Деа Акциенгезельшафт Фюр Минераль Унд Хеми (Фирма) filed Critical Рвэ-Деа Акциенгезельшафт Фюр Минераль Унд Хеми (Фирма)
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Publication of SU1715206A3 publication Critical patent/SU1715206A3/ru

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/686—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/52—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring condensed with a ring other than six-membered
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/20—Heterocyclic amines; Salts thereof
    • C08G18/2045—Heterocyclic amines; Salts thereof containing condensed heterocyclic rings
    • C08G18/2054—Heterocyclic amines; Salts thereof containing condensed heterocyclic rings having one nitrogen atom in the condensed ring system

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Resins (AREA)
  • Indole Compounds (AREA)
  • Medicines Containing Material From Animals Or Micro-Organisms (AREA)
  • Artificial Fish Reefs (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Superconductors And Manufacturing Methods Therefor (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Изобретение относитс  к органическим соединени м, пригодным дл  использовани  в качестве катализатора при получении пенополиуретана (ППУ). В соответствии с изобретением примен етс  соединение общей формулы(^.,.где R - алкил с 1-4атомами углерода. Полученные в результате ППУ характеризуютс  улучшенными реологическими свойствами (степень заполнени  L-формы до 87%). 1 табл.Изобретение относитс  к химии пенополиуретанов, в частности к катализатору дл  получени  пенополиуретана.Известен способ получени  производных М-алкил-2-азабйцикло

Description

на (опыт 5) 0,7, или М-изопропил-2-азабицикло (2,2,1) гептана (опыт 6) 0,6, или Nвтор .-бутил-2-азабицикло(2,2,1) гептана (опыт 7) 0,7, или Ы-изобутил-2-азабицикло (2,2,1) гептана (опыт 8) 0,7.
Данные опытов приведены в таблице. Степень заполнени  L-формы (об.%)  вл етс  мерой реологических свойств пены. Тем выше степень заполнени  формы (в %), чем лучше реологические свойства.

Claims (1)

  1. Формула изобретени  Применение М-алкил-2-азабицикло (2,2,1)-гептана общей формулы
    Q
    Ж
    R
    где R - 1-4 алкил; в качестве катализатора дл  получени  пенополиуретана .
SU884355338A 1987-03-12 1988-03-11 N-Алкил-2-азабицикло(2,2,1)гептан в качестве катализатора дл получени пенополиуретана SU1715206A3 (ru)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE3707911A DE3707911C1 (de) 1987-03-12 1987-03-12 Bicyclische Aminkatalysatoren

Publications (1)

Publication Number Publication Date
SU1715206A3 true SU1715206A3 (ru) 1992-02-23

Family

ID=6322831

Family Applications (2)

Application Number Title Priority Date Filing Date
SU884355338A SU1715206A3 (ru) 1987-03-12 1988-03-11 N-Алкил-2-азабицикло(2,2,1)гептан в качестве катализатора дл получени пенополиуретана
SU884355337A SU1598868A3 (ru) 1987-03-12 1988-03-11 Способ получени замещенных 2-азабицикло[2,2,1]-гептанов

Family Applications After (1)

Application Number Title Priority Date Filing Date
SU884355337A SU1598868A3 (ru) 1987-03-12 1988-03-11 Способ получени замещенных 2-азабицикло[2,2,1]-гептанов

Country Status (14)

Country Link
US (1) US4921879A (ru)
EP (1) EP0282069B1 (ru)
JP (1) JPH0714914B2 (ru)
AT (1) ATE90368T1 (ru)
AU (1) AU616652B2 (ru)
CA (1) CA1333605C (ru)
DD (1) DD280755A5 (ru)
DE (2) DE3707911C1 (ru)
DK (1) DK135188A (ru)
ES (1) ES2058158T3 (ru)
FI (1) FI880912A (ru)
NO (1) NO177010C (ru)
SU (2) SU1715206A3 (ru)
UA (1) UA8016A1 (ru)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4798879A (en) * 1987-03-25 1989-01-17 The B.F. Goodrich Company Catalyzed fast cure polyurethane sealant composition
US4946993A (en) * 1988-11-23 1990-08-07 American Cyanamid Company 2-azabicyclo[2.2.1.]hept-5-ene-2-acetic acid, derivatives thereof and related compounds, process for the preparation of said compounds, and the use of said compounds for the manufacture of N-phosphonomethylglycine
DE102008010753A1 (de) * 2008-02-23 2009-08-27 Bayer Materialscience Ag Polyurethanelastomere, Verfahren zu ihrer Herstellung und ihre Verwendung
CN115109228A (zh) * 2022-03-30 2022-09-27 万华节能科技(烟台)有限公司 一种高储存稳定性的煤矿加固煤岩体用硅酸盐改性聚氨酯材料

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE584604A (ru) * 1958-11-14
US3169972A (en) * 1963-05-24 1965-02-16 Upjohn Co 2-azabicyclo[3.2.0]-hept-6-enes and derivatives thereof
US3483224A (en) * 1966-03-15 1969-12-09 Union Carbide Corp Preparation of dehydroacetic acid
US3539660A (en) * 1967-07-28 1970-11-10 Celanese Coatings Co Method of preparing a thermoset composition based on carboxy copolymers,epoxides,and bicyclic fused tertiary amines
IL49034A (en) * 1975-03-20 1980-02-29 Hoechst Ag 5-aryl-2-azabicycloalkanes their preparation their intermediates and pharmaceutical compositions comprising them
US4065497A (en) * 1976-03-30 1977-12-27 Merck & Co., Inc. Novel dibicyclo [3.1.1] and [2.2.1] heptyl and dibicyclo [3.1.1] and [2.2.1] heptenyl polyamines
US4028364A (en) * 1976-07-06 1977-06-07 G. D. Searle & Co. 2-Azabicyclo[2.2.2.]octan-2-yl-diphenyl-alkanones and related compounds
FR2492381A1 (fr) * 1980-10-21 1982-04-23 Science Union & Cie Nouveaux acides aza bicyclo alcane carboxyliques substitues leurs procedes de preparation et leur emploi comme inhibiteur d'enzyme
US4405787A (en) * 1982-04-05 1983-09-20 Smithkline Beckman Corporation 3-Carboxy-2-azabicyclo[2.2.1]heptane derivatives
GB8323961D0 (en) * 1983-09-07 1983-10-12 Bp Chem Int Ltd Chemical process

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
I. Am. Chem. Soc. 1978, p. 1500-1503. *

Also Published As

Publication number Publication date
EP0282069A2 (de) 1988-09-14
US4921879A (en) 1990-05-01
DK135188A (da) 1988-09-13
NO177010C (no) 1995-07-05
ATE90368T1 (de) 1993-06-15
FI880912A0 (fi) 1988-02-26
NO880733L (no) 1988-09-13
EP0282069B1 (de) 1993-06-09
UA8016A1 (ru) 1995-12-26
DK135188D0 (da) 1988-03-11
DE3707911C1 (de) 1988-03-31
EP0282069A3 (en) 1989-11-23
NO177010B (no) 1995-03-27
DE3881547D1 (de) 1993-07-15
SU1598868A3 (ru) 1990-10-07
NO880733D0 (no) 1988-02-19
FI880912A (fi) 1988-09-13
CA1333605C (en) 1994-12-20
JPS63243071A (ja) 1988-10-07
AU1302288A (en) 1988-09-15
JPH0714914B2 (ja) 1995-02-22
ES2058158T3 (es) 1994-11-01
AU616652B2 (en) 1991-11-07
DD280755A5 (de) 1990-07-18

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