SU1131471A3 - Способ получени полихлорфосфазенов - Google Patents
Способ получени полихлорфосфазенов Download PDFInfo
- Publication number
- SU1131471A3 SU1131471A3 SU802985051A SU2985051A SU1131471A3 SU 1131471 A3 SU1131471 A3 SU 1131471A3 SU 802985051 A SU802985051 A SU 802985051A SU 2985051 A SU2985051 A SU 2985051A SU 1131471 A3 SU1131471 A3 SU 1131471A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- linear
- reaction
- obtaining
- cyclic
- polychlorophosphazenes
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract description 12
- 229920000642 polymer Polymers 0.000 claims abstract description 12
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 238000009833 condensation Methods 0.000 claims abstract description 5
- 230000005494 condensation Effects 0.000 claims abstract description 5
- 239000000178 monomer Substances 0.000 claims abstract description 5
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 125000004122 cyclic group Chemical group 0.000 description 9
- 239000002904 solvent Substances 0.000 description 7
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000006068 polycondensation reaction Methods 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- -1 RS () and Chemical class 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 150000008040 ionic compounds Chemical class 0.000 description 2
- GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical compound CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 description 2
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 description 2
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 2
- 229920002627 poly(phosphazenes) Polymers 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000004809 thin layer chromatography Methods 0.000 description 2
- 101001120868 Homo sapiens Meckel syndrome type 1 protein Proteins 0.000 description 1
- 102100026048 Meckel syndrome type 1 protein Human genes 0.000 description 1
- 229910019213 POCl3 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- ZSTLPJLUQNQBDQ-UHFFFAOYSA-N azanylidyne(dihydroxy)-$l^{5}-phosphane Chemical compound OP(O)#N ZSTLPJLUQNQBDQ-UHFFFAOYSA-N 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- MAXUIBVITJKGMP-UHFFFAOYSA-N diphosphazene Chemical compound PN=P MAXUIBVITJKGMP-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- IFVGFQAONSKBCR-UHFFFAOYSA-N n-[bis(aziridin-1-yl)phosphoryl]pyrimidin-2-amine Chemical compound C1CN1P(N1CC1)(=O)NC1=NC=CC=N1 IFVGFQAONSKBCR-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 150000002829 nitrogen Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 201000003033 pontocerebellar hypoplasia type 5 Diseases 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000007363 ring formation reaction Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- LOZAIRWAADCOHQ-UHFFFAOYSA-N triphosphazene Chemical compound PNP=NP LOZAIRWAADCOHQ-UHFFFAOYSA-N 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
- 238000000214 vapour pressure osmometry Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
- C08G79/025—Polyphosphazenes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/097—Compounds containing nitrogen and non-metals and optionally metals containing phosphorus atoms
- C01B21/098—Phosphonitrilic dihalides; Polymers thereof
- C01B21/0986—Phosphonitrilic dichlorides; Polymers thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7924037A FR2466435A1 (fr) | 1979-09-27 | 1979-09-27 | Nouveaux polychlorophosphazenes et leur procede de preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU1131471A3 true SU1131471A3 (ru) | 1984-12-23 |
Family
ID=9230065
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU802985051A SU1131471A3 (ru) | 1979-09-27 | 1980-09-23 | Способ получени полихлорфосфазенов |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US4377558A (enExample) |
| EP (1) | EP0026685B1 (enExample) |
| DE (1) | DE3071484D1 (enExample) |
| FR (1) | FR2466435A1 (enExample) |
| SU (1) | SU1131471A3 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2645682C1 (ru) * | 2017-05-25 | 2018-02-27 | Михаил Владимирович Горлов | Способ получения олигогалогенфосфазенов и полигалогенфосфазенов с регулируемой молекулярной массой взаимодействием галогенфосфоранов с гексаалкилдисилазанами |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2466435A1 (fr) * | 1979-09-27 | 1981-04-10 | Inst Mondial Phosphate | Nouveaux polychlorophosphazenes et leur procede de preparation |
| FR2548652B1 (fr) * | 1983-07-06 | 1985-11-22 | Elf Aquitaine | Polychlorophosphazenes lineaires possedant un groupement terminal dichlorothiophosphoryle, procede de preparation de ces composes, et leur utilisation |
| FR2571710B1 (fr) * | 1984-10-17 | 1986-12-26 | Elf Aquitaine | Procede de preparation de polychlorophosphazenes lineaires possedant un groupement terminal pxcl2, x designant o ou s, par polycondensation en solution des monomeres p2nxcl5 |
| US4524052A (en) * | 1984-12-24 | 1985-06-18 | The Firestone Tire & Rubber Company | Borate chloride polymerization catalysts |
| FR2606396B1 (fr) * | 1986-11-12 | 1989-02-10 | Atochem | Procede d'obtention de n(dichlorophosphoryl) trichlorophosphazene a partir de pentachlorure de phosphore et de chlorure d'ammonium |
| FR2612172B1 (fr) * | 1987-03-10 | 1989-06-16 | Atochem | Procede de preparation de polychlorophosphazene |
| FR2612170B1 (fr) * | 1987-03-10 | 1989-06-16 | Atochem | Procede de preparation de polychlorophosphazene en presence de bis(dichlorophosphoryl)imide |
| FR2612169B1 (fr) * | 1987-03-10 | 1989-06-16 | Atochem | Procede de preparation de n(dichlorophosphoryl)trichlorophosphazene |
| DE3874035T2 (de) * | 1987-07-02 | 1993-03-18 | Atochem Elf Sa | Verfahren zur regulierung des molekulargewichts von polychlorphosphazenen und davon abgeleiteten polyorganophosphazenen und die in diesem verfahren angewandten regulierungsmittel. |
| US4806322A (en) * | 1987-11-16 | 1989-02-21 | The Firestone Tire & Rubber Company | Process for the production of linear polyphosphazenes |
| FR2629442B1 (fr) * | 1988-03-29 | 1990-11-23 | Atochem | Procede de preparation de compositions de polydichlorophosphazenes a taux controle d'oligomeres cycliques et les compositions resultant de la mise en oeuvre de ce procede |
| FR2647100A1 (fr) * | 1989-05-19 | 1990-11-23 | Atochem | Procede de polycondensation en masse du n-dichlorophosphoryl- ou n-dichlorothiophosphoryl-p-trichlorophosphazene |
| FR2653423A1 (fr) * | 1989-10-20 | 1991-04-26 | Atochem | Procede de regulation des masses moleculaires de polydichlorophosphazenes. |
| FR2682391A1 (fr) * | 1991-10-11 | 1993-04-16 | Atochem | Procede de preparation de polyalkyl ou arylchlorophosphazenes. |
| DE4317909A1 (de) * | 1993-05-28 | 1994-12-01 | Wacker Chemie Gmbh | Verfahren zum Kondensieren und/oder Äquilibrieren von Organosiliciumverbindungen |
| DE4317978A1 (de) * | 1993-05-28 | 1994-12-01 | Wacker Chemie Gmbh | Organosiliciumreste aufweisende Phosphazene, Verfahren zu deren Herstellung und deren Verwendung |
| US5403909A (en) * | 1993-07-15 | 1995-04-04 | General Electric Company | Catalysts for polycondensation and redistribution of organosiloxane polymers |
| FR2709256B1 (fr) * | 1993-07-15 | 1997-05-30 | Gen Electric | Procédé de préparation d'une composition catalytique de phosphazène utile pour la polycondensation et la redistribution de polymères d'organosiloxane. |
| US6309619B1 (en) * | 1998-07-14 | 2001-10-30 | Bechtel Bwxt Idaho, Llc | Solid state synthesis of poly(dichlorophosphazene) |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA572951A (en) * | 1959-03-24 | Barth-Wehrenalp Gerhard | Phosphorus compounds and process for making | |
| US2925320A (en) * | 1956-02-16 | 1960-02-16 | Pennsalt Chemicals Corp | Compounds of the class p2x5no and process for producing same |
| US2980506A (en) * | 1956-09-27 | 1961-04-18 | Henkel & Compagnie G M B H | Nitrogen-phosphoric acid compounds containing active chlorine |
| GB1321102A (en) * | 1970-04-09 | 1973-06-20 | Castrol Ltd | Method for preparing trihalophosphazine phosphoryl dihalides |
| FR2466435A1 (fr) * | 1979-09-27 | 1981-04-10 | Inst Mondial Phosphate | Nouveaux polychlorophosphazenes et leur procede de preparation |
-
1979
- 1979-09-27 FR FR7924037A patent/FR2466435A1/fr active Granted
-
1980
- 1980-09-02 DE DE8080401248T patent/DE3071484D1/de not_active Expired
- 1980-09-02 EP EP80401248A patent/EP0026685B1/fr not_active Expired
- 1980-09-15 US US06/187,184 patent/US4377558A/en not_active Expired - Lifetime
- 1980-09-23 SU SU802985051A patent/SU1131471A3/ru active
-
1983
- 1983-03-21 US US06/477,397 patent/US4544536A/en not_active Expired - Lifetime
Non-Patent Citations (1)
| Title |
|---|
| 1. Lund L.G. The preparation of Cyclic and Linear Phosphonitrilic chlorides - J. org. Chem., 1960, ;2542, 2.Allcock H.R. и др. Phosphonitrilic compounds VI. High molecular; weight poly (aikoxy - and aryloxyphosphazenes. - J.brg. Chem, 1966, 1-5, 1709. 3.Becke M. и-др. Die Verbindungen mit der Zusammensetzung Pj-NClyZ. anorg. AEEg; .Chera, 1963, 325, c. 287. 4.Володий A.A., Киреев В.В. и др. Синтез и исследование алкокситрифосфазофосфенилов. Журнал общей химии, 1972, т. 42, 510. 5.Von. L Riesel и др. Synthese und Eigenshaffen tinearer.phpsphoril chlorphosphazene, - Z.anorg. allg. Chem. t975, 411, s. 148. 6.Авторское свидетельство СССР 176416, кл. С 08 G 79/02, 1963 (прототип). * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2645682C1 (ru) * | 2017-05-25 | 2018-02-27 | Михаил Владимирович Горлов | Способ получения олигогалогенфосфазенов и полигалогенфосфазенов с регулируемой молекулярной массой взаимодействием галогенфосфоранов с гексаалкилдисилазанами |
Also Published As
| Publication number | Publication date |
|---|---|
| US4544536A (en) | 1985-10-01 |
| EP0026685B1 (fr) | 1986-03-12 |
| US4377558A (en) | 1983-03-22 |
| DE3071484D1 (en) | 1986-04-17 |
| EP0026685A1 (fr) | 1981-04-08 |
| FR2466435A1 (fr) | 1981-04-10 |
| FR2466435B1 (enExample) | 1983-01-07 |
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