SK286948B6 - Spôsob výroby syntetických sklených vlákien a briketa na ich výrobu - Google Patents
Spôsob výroby syntetických sklených vlákien a briketa na ich výrobu Download PDFInfo
- Publication number
- SK286948B6 SK286948B6 SK795-2000A SK7952000A SK286948B6 SK 286948 B6 SK286948 B6 SK 286948B6 SK 7952000 A SK7952000 A SK 7952000A SK 286948 B6 SK286948 B6 SK 286948B6
- Authority
- SK
- Slovakia
- Prior art keywords
- alumina
- aluminum
- mineral
- weight
- briquette
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 42
- 239000000835 fiber Substances 0.000 title claims abstract description 36
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 23
- 239000004484 Briquette Substances 0.000 title claims abstract description 22
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 61
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 57
- 239000011707 mineral Substances 0.000 claims abstract description 57
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 56
- 239000000155 melt Substances 0.000 claims abstract description 32
- 239000000463 material Substances 0.000 claims abstract description 31
- 238000002844 melting Methods 0.000 claims abstract description 15
- 230000008018 melting Effects 0.000 claims abstract description 15
- 229910052782 aluminium Inorganic materials 0.000 claims description 52
- 239000002893 slag Substances 0.000 claims description 40
- 239000002699 waste material Substances 0.000 claims description 37
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 18
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 17
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 13
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 8
- 229910052736 halogen Inorganic materials 0.000 claims description 7
- 150000002367 halogens Chemical class 0.000 claims description 7
- VRAIHTAYLFXSJJ-UHFFFAOYSA-N alumane Chemical compound [AlH3].[AlH3] VRAIHTAYLFXSJJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000003365 glass fiber Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 238000002074 melt spinning Methods 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 2
- 229910052731 fluorine Inorganic materials 0.000 claims 2
- 239000011737 fluorine Substances 0.000 claims 2
- 229910052593 corundum Inorganic materials 0.000 abstract description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 229910001570 bauxite Inorganic materials 0.000 description 19
- 239000000843 powder Substances 0.000 description 14
- 239000004568 cement Substances 0.000 description 13
- 239000011230 binding agent Substances 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 239000004927 clay Substances 0.000 description 7
- 238000009987 spinning Methods 0.000 description 7
- 229910010413 TiO 2 Inorganic materials 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 239000004576 sand Substances 0.000 description 5
- 239000004575 stone Substances 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 239000000571 coke Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 235000013379 molasses Nutrition 0.000 description 3
- 239000011435 rock Substances 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 229910000640 Fe alloy Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 150000004673 fluoride salts Chemical class 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000002440 industrial waste Substances 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000011490 mineral wool Substances 0.000 description 2
- 238000005065 mining Methods 0.000 description 2
- 239000011236 particulate material Substances 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- NJFMNPFATSYWHB-UHFFFAOYSA-N ac1l9hgr Chemical compound [Fe].[Fe] NJFMNPFATSYWHB-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- UPHIPHFJVNKLMR-UHFFFAOYSA-N chromium iron Chemical compound [Cr].[Fe] UPHIPHFJVNKLMR-UHFFFAOYSA-N 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 239000010791 domestic waste Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000000099 in vitro assay Methods 0.000 description 1
- 238000005462 in vivo assay Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 229910052609 olivine Inorganic materials 0.000 description 1
- 239000010450 olivine Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000010801 sewage sludge Substances 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000004056 waste incineration Methods 0.000 description 1
- 238000007704 wet chemistry method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C13/00—Fibre or filament compositions
- C03C13/06—Mineral fibres, e.g. slag wool, mineral wool, rock wool
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/002—Use of waste materials, e.g. slags
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/02—Pretreated ingredients
- C03C1/026—Pelletisation or prereacting of powdered raw materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2213/00—Glass fibres or filaments
- C03C2213/02—Biodegradable glass fibres
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Glass Compositions (AREA)
- Processing Of Solid Wastes (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97309674 | 1997-12-02 | ||
EP97309675 | 1997-12-02 | ||
PCT/EP1998/007821 WO1999028252A1 (fr) | 1997-12-02 | 1998-12-02 | Briquettes pour la production de fibres minerales et leur utilisation |
Publications (2)
Publication Number | Publication Date |
---|---|
SK7952000A3 SK7952000A3 (en) | 2001-03-12 |
SK286948B6 true SK286948B6 (sk) | 2009-08-06 |
Family
ID=26147717
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SK795-2000A SK286948B6 (sk) | 1997-12-02 | 1998-12-02 | Spôsob výroby syntetických sklených vlákien a briketa na ich výrobu |
Country Status (13)
Country | Link |
---|---|
EP (2) | EP1911729A1 (fr) |
JP (1) | JP2001524447A (fr) |
AU (1) | AU2156999A (fr) |
CA (1) | CA2312838C (fr) |
CZ (1) | CZ302028B6 (fr) |
DE (2) | DE69838798T2 (fr) |
ES (1) | ES2291000T3 (fr) |
HU (1) | HUP0004516A3 (fr) |
PL (1) | PL193566B1 (fr) |
PT (1) | PT1037861E (fr) |
SI (1) | SI1037861T1 (fr) |
SK (1) | SK286948B6 (fr) |
WO (1) | WO1999028252A1 (fr) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000076929A1 (fr) * | 1999-06-10 | 2000-12-21 | Rockwool International A/S | Briquettes, leur utilisation dans la fabrication de fibres minerales et leur production |
FI110607B (fi) * | 2000-06-20 | 2003-02-28 | Paroc Group Oy Ab | Menetelmä briketin ja mineraalivillan valmistamiseksi |
DE50205240D1 (de) * | 2001-02-21 | 2006-01-19 | Rockwool Mineralwolle | Verfahren zur Herstellung von Dämmstoffen aus Mineralfasern |
DE10114985C5 (de) * | 2001-03-26 | 2017-08-24 | Hans-Peter Noack | Verfahren zur Herstellung von Mineralwolle |
DE10352323B4 (de) * | 2002-11-06 | 2011-09-15 | Deutsche Rockwool Mineralwoll Gmbh + Co Ohg | Verfahren zur Herstellung einer mineralischen Schmelze |
RU2370461C2 (ru) * | 2002-11-06 | 2009-10-20 | Роквул Интернэшнл А/С | Способ получения минеральных волокон |
DE102005040268A1 (de) * | 2004-10-20 | 2006-05-04 | Deutsche Rockwool Mineralwoll Gmbh + Co Ohg | Formkörper für die Erzeugung einer zu zerfasernden mineralischen Schmelze zur Herstellung von Dämmstoffen aus Mineralfasern |
DE102005040269B4 (de) * | 2004-10-20 | 2007-11-08 | Deutsche Rockwool Mineralwoll Gmbh & Co. Ohg | Formkörper für die Erzeugung einer zu zerfasernden mineralischen Schmelze zur Herstellung von Dämmstoffen aus Mineralfasern sowie Verfahren zur Herstellung derartiger Formkörper |
DE102005001570A1 (de) * | 2004-10-20 | 2006-04-27 | Deutsche Rockwool Mineralwoll Gmbh + Co Ohg | Formkörper für die Erzeugung einer zu zerfasernden mineralischen Schmelze zur Herstellung von Dämmstoffen aus Mineralfaser |
US8148518B2 (en) | 2007-02-14 | 2012-04-03 | Eastman Chemical Company | Cellulose esters and their production in carboxylated ionic liquids |
GB2454231B (en) * | 2007-11-01 | 2012-10-03 | Advanced Mineral Recovery Technologies Ltd | Method of and system for processing red mud |
US8158777B2 (en) | 2008-02-13 | 2012-04-17 | Eastman Chemical Company | Cellulose esters and their production in halogenated ionic liquids |
KR101477733B1 (ko) * | 2011-04-12 | 2014-12-30 | 주식회사 케이씨씨 | 생용해성 미네랄울 섬유 조성물 및 미네랄울 섬유 |
DK2697178T3 (da) | 2011-04-13 | 2019-12-09 | Rockwool Int | Fremgangsmåder til dannelse af syntetiske glasfibre |
WO2014171562A1 (fr) * | 2013-04-15 | 2014-10-23 | 주식회사 케이씨씨 | Composition pour produire de la fibre de laine minérale remarquablement soluble dans des fluides corporels et fibre de laine minérale produite à partir de celle-ci |
FR3043399B1 (fr) * | 2015-11-09 | 2018-01-05 | Eco'ring | Procede de production de laine de roche et de fonte valorisable |
FR3104568B1 (fr) * | 2019-12-11 | 2022-07-22 | Saint Gobain Isover | Procede de fabrication de laine minerale |
PL4097057T3 (pl) * | 2020-01-30 | 2024-07-01 | Rockwool A/S | Sposób wytwarzania sztucznych włókien szklistych |
US20230062262A1 (en) * | 2020-01-30 | 2023-03-02 | Rockwool A/S | Method for making man-made vitreous fibres |
JP2023553275A (ja) | 2020-11-19 | 2023-12-21 | ロックウール アクティーゼルスカブ | 人造鉱物繊維の製造のための溶融物の製造方法 |
WO2023079108A1 (fr) | 2021-11-05 | 2023-05-11 | Rockwool A/S | Procédé de préparation d'une masse fondue pour la production de fibres minérales artificielles |
WO2024047238A1 (fr) | 2022-09-02 | 2024-03-07 | Rockwool A/S | Procédé de recyclage de déchets minéraux |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6077147A (ja) * | 1983-10-04 | 1985-05-01 | Isolite Babcock Taika Kk | Al↓2O↓3−SiO↓2系セラミツク繊維とその製造法 |
FI78447C (fi) * | 1987-11-27 | 1989-08-10 | Outokumpu Oy | Tillsaettning av ferrokromslagg foer framstaellning av eldfasta och kemiskt bestaendiga fibrer. |
FI86541C (sv) * | 1990-08-29 | 1992-09-10 | Partek Ab | Råmaterialbrikett för mineralullstillverkning och förfarande för dess framställning |
DK217190D0 (da) * | 1990-09-11 | 1990-09-11 | Rockwool Int | Fremgangsmaade og ovn til fremstilling af en smelte til mineralfiberfremstilling |
US5198190A (en) * | 1990-12-21 | 1993-03-30 | Enviroscience, Inc. | Method of recycling hazardous waste |
CA2159214A1 (fr) * | 1994-02-11 | 1995-08-17 | Soren Lund Jensen | Fibres vitreuses chimiques |
EP0790962B1 (fr) * | 1994-11-08 | 1998-11-25 | Rockwool International A/S | Fibres vitreuses synthetiques |
FI960705A (fi) * | 1996-02-16 | 1997-08-17 | Paroc Oy Ab | Mineraalikuitu |
-
1998
- 1998-12-02 AU AU21569/99A patent/AU2156999A/en not_active Abandoned
- 1998-12-02 JP JP2000523160A patent/JP2001524447A/ja active Pending
- 1998-12-02 EP EP07015654A patent/EP1911729A1/fr not_active Withdrawn
- 1998-12-02 CZ CZ20001860A patent/CZ302028B6/cs not_active IP Right Cessation
- 1998-12-02 HU HU0004516A patent/HUP0004516A3/hu unknown
- 1998-12-02 DE DE69838798T patent/DE69838798T2/de not_active Expired - Lifetime
- 1998-12-02 SI SI9830901T patent/SI1037861T1/sl unknown
- 1998-12-02 PT PT98965734T patent/PT1037861E/pt unknown
- 1998-12-02 PL PL98341005A patent/PL193566B1/pl unknown
- 1998-12-02 DE DE98965734T patent/DE98965734T1/de active Pending
- 1998-12-02 SK SK795-2000A patent/SK286948B6/sk not_active IP Right Cessation
- 1998-12-02 ES ES98965734T patent/ES2291000T3/es not_active Expired - Lifetime
- 1998-12-02 EP EP98965734A patent/EP1037861B1/fr not_active Expired - Lifetime
- 1998-12-02 CA CA002312838A patent/CA2312838C/fr not_active Expired - Fee Related
- 1998-12-02 WO PCT/EP1998/007821 patent/WO1999028252A1/fr active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
PL341005A1 (en) | 2001-03-12 |
SI1037861T1 (sl) | 2008-10-31 |
DE98965734T1 (de) | 2007-01-18 |
JP2001524447A (ja) | 2001-12-04 |
DE69838798T2 (de) | 2008-04-10 |
DE69838798D1 (de) | 2008-01-10 |
EP1037861B1 (fr) | 2007-11-28 |
CA2312838C (fr) | 2008-08-26 |
HUP0004516A2 (hu) | 2001-04-28 |
EP1037861A1 (fr) | 2000-09-27 |
CZ20001860A3 (cs) | 2001-04-11 |
WO1999028252A1 (fr) | 1999-06-10 |
EP1911729A1 (fr) | 2008-04-16 |
PL193566B1 (pl) | 2007-02-28 |
AU2156999A (en) | 1999-06-16 |
HUP0004516A3 (en) | 2011-03-28 |
WO1999028252B1 (fr) | 1999-08-05 |
SK7952000A3 (en) | 2001-03-12 |
CZ302028B6 (cs) | 2010-09-08 |
ES2291000T3 (es) | 2008-02-16 |
PT1037861E (pt) | 2007-12-18 |
CA2312838A1 (fr) | 1999-06-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MK4A | Patent expired |
Expiry date: 20181202 |