SI9620121A - Coating for the internal surface of a pipe, method for applying the same on said surface, two-layered semi-finished part using said coating and method for making this part - Google Patents

Coating for the internal surface of a pipe, method for applying the same on said surface, two-layered semi-finished part using said coating and method for making this part Download PDF

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SI9620121A
SI9620121A SI9620121A SI9620121A SI9620121A SI 9620121 A SI9620121 A SI 9620121A SI 9620121 A SI9620121 A SI 9620121A SI 9620121 A SI9620121 A SI 9620121A SI 9620121 A SI9620121 A SI 9620121A
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weight
polyorganosiloxane
sheath
layer
amount
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SI9620121A
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SI9620121B (en
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Stanislav Vladimirovich Khramenkov
Vladimir Alexandrovich Zagorsky
Evgeny Petrovich Pavlov
Lidiya Nikolaevna Loskutova
Vladimir Konstantinovich Maryashin
Tatyana Valentinovna Aslamova
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Moskovskoe Gosudarstvennoe Predpriyatie "Mosvodokanal"
Dochernee Gosudarstvennoe Unitarnoe
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Publication of SI9620121A publication Critical patent/SI9620121A/en
Publication of SI9620121B publication Critical patent/SI9620121B/en

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L58/00Protection of pipes or pipe fittings against corrosion or incrustation
    • F16L58/02Protection of pipes or pipe fittings against corrosion or incrustation by means of internal or external coatings
    • F16L58/04Coatings characterised by the materials used
    • F16L58/10Coatings characterised by the materials used by rubber or plastics
    • F16L58/1009Coatings characterised by the materials used by rubber or plastics the coating being placed inside the pipe
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L55/00Devices or appurtenances for use in, or in connection with, pipes or pipe systems
    • F16L55/16Devices for covering leaks in pipes or hoses, e.g. hose-menders
    • F16L55/162Devices for covering leaks in pipes or hoses, e.g. hose-menders from inside the pipe
    • F16L55/165Devices for covering leaks in pipes or hoses, e.g. hose-menders from inside the pipe a pipe or flexible liner being inserted in the damaged section

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)

Abstract

The present invention relates to a coating applied onto the internal surface of a pipe, wherein said coating consists of two coaxial tubular and film-type envelopes (2, 3) made of a thermoplastic polymer. The outer envelope (2) rests against the pipe (1) internal surface, while the inner envelope (3) is separated from the first by a coaxial main reinforcement layer (4) impregnated with a solidified polymeric binder. The inner envelope (3) is made in the shape of a multiple-component homogeneous system that comprises at least one polymer selected from the group of thermoplastic polymers having a relative stretching ratio of at least 200 % and a melting point of at least 100 degrees Centigrade. This homogeneous system also comprises a structural modifier of the selected polymer. The envelope (3) and the layer (4) are formed with unjoined edges in at least one place along the coating axis, wherein said edges (6, 7) are sealed together so that the envelope (3) and the layer (4) form a monolithic structure. The present invention also relates to a two-layered semi-finished part that comprises the inner envelope (3) linked to the reinforcement layer (4), wherein said envelope is obtained from the multiple-component homogeneous system having the above-mentioned composition

Description

PLAŠČ NOTRANJE POVRŠINE CEVI, METODA ZA NJEGOVO NAMESTITEV NA OMENJENO POVRŠINO, DVOSLOJNI POLIZDELEK OMENJENEGA PLAŠČA IN NAČIN IZDELAVE TEGA POLIZDELKATUBE INTERNAL SURFACE TUBE, METHOD FOR ITS ATTACHMENT TO THE RESTRICTED SURFACE, TWO-LAYER SEMI-PRODUCT OF THE SUSPENDED TIRE AND METHOD OF MANUFACTURING

Tehnično področjeTechnical area

Predmetni izum se nanaša na področje gradbeništva, še posebej na zaščito notranjih površin cevi pred mehanskimi poškodbami, korozijo ali pred nastajanjem nezaželjenih oblog, natančneje opisuje plašč notranje površine cevi, način njegove uporabe, dvoslojni polizdelek omenjenega plašča in način izdelave omenjenega polizdelka.The present invention relates to the field of construction, in particular to the protection of the inner surfaces of the pipe against mechanical damage, corrosion or the formation of unwanted linings, more specifically describes the coat of the inner surface of the pipe, the method of its use, a two-layer semi-finished product of said coat and the method of manufacture of said semi-finished product.

Stanje tehnikeThe state of the art

Poznan je plašč notranje površine cevi, predstavljen kot tro-slojna struktura, ki vključuje dve soosno postavljeni plasti ovoja, ki sta zgrajeni iz termoplastičnega materiala, med kateri je postavljen ojačevalni sloj, impregniran z ojačevalcem vezi (FR, A, 2592457) .The inner surface of the tube is known to be represented as a three-layer structure comprising two coaxially arranged layers of sheath, which are constructed of thermoplastic material, between which a reinforcement layer impregnated with a bond enhancer (FR, A, 2592457) is placed.

Poznan je tudi način, s pomočjo katerega se omenjeni plašč, oziroma ovoj na notranjo površino cevi nanaša, in sicer se cevasti ovoji, narejeni na osnovi termoplastičnega polimernega materiala postavijo soosno na zunanjo stran cevi, kjer je zunanji sloj namenjen zlepljanju z notranjo površino cevi, notranji sloj opravlja funkcijo napihovanja, oba sloja pa sta medsebojno ločena z ojačevalnim slojem, ki je impregniran s termično utrjeno vezjo, s čimer dobimo troslojni polizdelek, ki ga vstavimo v notranjost cevi, nato pa pod tlakom v votlino notranjega sloja uvedemo še nosilec toplote in segrevamo do popolnega utrjevanja vezivnega sredstva (FR, A, 2592457). S tem se iz sloja polimernega materiala izdela notranji ovoj, ki vsebuje vlakna (poliesterska ali steklena) implantirana s pomočjo valjanja po zunanji površini, ki je obrnjena proti ojačevainemu sloj u.Also known is the method by which said sheath or sheath is applied to the inner surface of the tube, namely, tubular sheaths made on the basis of thermoplastic polymeric material are placed coaxially on the outside of the tube, where the outer layer is intended to adhere to the inner surface of the tube, the inner layer performs the function of inflating, and the two layers are separated from each other by a reinforcement layer impregnated with a thermally hardened bond, thereby obtaining a three-layer semi-finished product, which is inserted into the inner tube, and then a heat carrier is introduced under pressure into the cavity of the inner layer. heated to complete curing of the binder (FR, A, 2592457). In this way, an inner sheath containing fibers (polyester or glass) implanted by rolling along an external surface facing the reinforcing layer u is produced from the layer of polymeric material.

Pri prilagajanju soosno postavljenega ojačevalnega sloja okoli takega notranjega ovoja, kakor tudi med transportom takega polizdelka plašča v notranjost cevi, je mogoče delno lepljenje notranjega sloja z ojačevalno plastjo, kar ima za posledico nastajanje gub, neravnin notranjega sloja ovoja in tako naprej, kar seveda poslabša kvaliteto omenjenega plašča.When adjusting the coaxially positioned reinforcement layer around such an inner envelope, as well as during the transport of such a semi-finished jacket to the inside of the tube, partial adhesion of the inner layer to the reinforcement layer is possible, resulting in the formation of wrinkles, irregularities of the inner layer of the envelope, and so on, which of course the quality of said coat.

Poznan je tudi plašč za notranjo površino cevi, ki je sestavljen iz dveh cevastih slojev, osnovanih na termoplastičnem polimernem materialu, ki sta postavljena soosno in od katerih se zunanji prilepi na notranjo površino cevi, notranji pa je od njega ločen z utrjeno polimerno vezjo (RU, A, 2037734).Also known is a jacket for the inner surface of the tube, which consists of two tubular layers based on thermoplastic polymer material, which are arranged coaxially and from which the outer one adheres to the inner surface of the tube and is separated from the inner surface by a cured polymeric bond (RU , A, 2037734).

Pri tej vrsti plašča je notranji sloj z ojačevalnim slojem povezan le z adhezijo med omenjenim slojem in z utrjeno vezjo, ki impregnira ta ojačevalni sloj, kar pa ne zagotavlja učinkovite povezave notranjega sloja celotnega ovoja s celotno površino ojačevalnega sloja in trdnosti plašča notranjega sloja cevi v celoti in ima tako za posledico delno luščenje plašča ter slabšanje lastnosti ovoja.In this type of jacket, the inner layer with the reinforcing layer is only associated with the adhesion between said layer and with the hardened bond impregnating this reinforcing layer, which does not ensure effective connection of the inner layer of the entire envelope with the entire surface of the inner layer of the tube in This results in a partial peeling of the coat and a deterioration of the envelope.

Znan je tudi postopek za izdelavo plašča, pri katerem se cevaste plasti ovoja, izdelane na osnovi termoplastičnega polimernega materiala sestavijo zunaj cevi in kjer je zunanji sloj namenjen združevanju z notranjim slojem cevi, drugi - notranji sloj pa je od tega ločen z ojačevalnim slojem in je impregniran s termično utrjeno vezjo. S tem postopkom dobimo trislojen, delno dokončan del plašča, ki ga vstavimo v cev, nato pa z vročim toplotnim medijem pod tlakom znotraj votline cevi vez strdimo (RU, A, 2037734).A method is also known for making a jacket in which the tubular layers of the sheath made on the basis of thermoplastic polymeric material are assembled outside the tube and where the outer layer is intended to join with the inner layer of the tube and the second inner layer is separated from it by a reinforcing layer and is impregnated with thermally cured bond. This process gives a three-layer, partially finished part of the jacket, which is inserted into the pipe, and then the bond is hardened with hot thermal medium under pressure inside the pipe cavity (RU, A, 2037734).

Med vnašanjem takega plašča v cev z ene strani pa se lahko pojavijo deformacije, neravnine in defektna področja na ovoju zaradi prostega združevanja notranjega sloja ovoja z ojačevalnim slojem, kar privede do komplikacij tehnološkega postopka vstavljanja plašča in zmanjšanja kvalitete tega, saj pride do nastajanja naborkov, gub na površini plašča in tako dalje. Posledica takih nepravilnosti je sprememba v turbulentnem toku transportiranega medija, povečanje energije, potrebne za transportiranje in zmanjšanje dobe uporabnostni takega plašča.However, deformation, unevenness, and defective areas of the envelope may occur during insertion of such a jacket on the tube, due to the free association of the inner layer of the jacket with the reinforcement layer, which complicates the technological process of insertion of the jacket and diminishes the quality of the wrinkles, folds on the surface of the coat and so on. The consequence of such irregularities is a change in the turbulent flow of the transported medium, an increase in the energy required to transport and a decrease in the useful life of such a mantle.

Poznan je tudi postopek izdelovanja plašča, kjer se dvoslojni nedokončani produkt (GB, A, 1569675), ki je sestavljen iz notranjega cevastega ovoja, povezanega z ojačevalnim slojem uporabi za učinkovito povezovanje notranjega sloja ovoja z utrjeno vezjo in ojačevalnim sloj em.A method of manufacturing a jacket is also known, wherein a two-layer unfinished product (GB, A, 1569675) consisting of an inner tubular sheath connected to the reinforcing layer is used to effectively bond the inner layer of the sheath to the hardened bond and the reinforcing layer em.

Tak nedokončan produkt dobimo (GB, A, 1569675) ob uporabi sloja poliuretana na vlaknu sintetičnega polsta, iz katerega iz katerega se pozneje izdela cevasta konstrukcija. Povezava polimernega sloja s sintetičnim polstnim materialom se naredi le z mehansko adhezijo, ki ne nudi vedno dovolj velike moči; luščenje notranjega ovoja in ojačevalnega sloja ovoja je mogoča med izdelavo takega plašča, kakor tudi med samo uporabo, kar posledično zniža kvaliteto celotnega plašča.Such an unfinished product is obtained (GB, A, 1569675) using a layer of polyurethane on a synthetic felt fiber from which a tubular structure is subsequently made. The bonding of the polymer layer to the synthetic felt material is made only by mechanical adhesion, which does not always provide sufficient strength; peeling of the inner sheath and the reinforcement layer of the sheath is possible during the manufacture of such a sheath as well as during use, which in turn reduces the quality of the whole sheath.

Povzetek izumaSummary of the Invention

Naloga je izdelati plašč, oziroma ovoj za notranjo površino cevi, ki bi imel tako sestavo, da bi znatno povišal kvaliteto oplaščenja. Poleg tega je potrebno razviti postopek vnašanja omenjenega plašča na notranjo površino cevi, po katerem bi bil omenjen plašč vnešen na tak način, da bi se izključile možnosti sprememb v turbulentnem toku transportiranega medijna skozi cev in bi se znižala potrošnja energije, potrebne za tak transport, ter bi se povečalo trajanje uporabnosti takega dvoslojnega delno dokončanega dela omenjenega plašča, oziroma polizdelka.The task is to create a jacket, or sheath, for the inner surface of the pipe, which would have a structure that would significantly increase the quality of the coating. In addition, it is necessary to develop a method of inserting said jacket on the inner surface of the pipe, by which said jacket would be inserted in such a way as to exclude the possibility of changes in the turbulent flow of the transported medium through the pipe and to reduce the energy consumption required for such transport, and would increase the useful life of such a two-layer partially completed part of said coat or semi-finished product.

Poleg tega je zaželjen tudi postopek za izdelavo tega dvoslojnega polizdelka, po katerem bi imel ta del visoko adhezijsko moč povezovanja notranjega sloja ovoja in ojačevalnega sloja ovoja.In addition, it is desirable to provide a process for the manufacture of this two-layer semi-finished product, according to which this part would have a high adhesive power of connecting the inner layer of the sheath and the reinforcing layer of the sheath.

To dosežemo tako, da je plašč notranjosti cevi sestavljen iz dveh vzporedno postavljenih cevastih slojev ovoja, ki sta izdelana iz polimerne termoplastične snovi, kjer pride zunanji sloj ovoja v stik z notranjo površino cevi, notranji sloj ovoja pa je od predhodnjega ločen z vzporedno postavljenim glavnim ojačevalnim slojem, ki je impregniran z utrjeno polimerno vezjo. Glede na ta izum je notranji ovoj izdelan z večkomponentnim homogenim sistemom, ki vsebuje vsaj en polimer, izbran iz skupine termoplastičnih materialov katerih koeficient relativnega raztezka ni manjši od 200%, točka taljenja pa ni pod 100°C, ter strukturni modifikator izbranega polimera, s katerima se notranji sloj ovoja loči od ojačevalnega sloja plašča vzdolž osi tega na vsaj enem mestu, ločena robova pa sta hermetično povezana tako, da ta ovoj oblikuje monolitno strukturo, ki vključuje tudi glavni ojačevalni sloj.This is achieved by the fact that the inner tube jacket consists of two parallel tubular sheath layers, which are made of polymer thermoplastic material, where the outer layer of the sheath comes in contact with the inner surface of the tube, and the inner layer of the sheath is separated from the previous main reinforcement layer impregnated with a cured polymeric bond. According to this invention, the inner sheath is made by a multi-component homogeneous system containing at least one polymer selected from the group of thermoplastic materials whose coefficient of relative elongation is not less than 200% and the melting point is not below 100 ° C, and a structural modifier of the selected polymer, with which separate the inner layer of the sheath from the reinforcement layer of the sheath along the axis thereof in at least one location, and the separate edges are hermetically connected such that this sheath forms a monolithic structure including the main reinforcement layer.

Če pri izdelavi večkomponentnega homogenega sistema uporabimo termoplastični material, katerega koeficient relativnega raztezka ni večji od 200%, dobimo preveč trd sistem, ki nadalje zaustavlja proces izdelave ovoja, ki je opisan v nadaljevanju opisa predmetnega izuma. Pri uporabi termoplastičnega materiala, katerega točka taljenja ni nad 100° C pa obstaja nevarnost poslabšanja tesnjenja notranjega sloja ovoja v primeru prisotnosti vročega medija, kakršni so na primer nasičeni vodni hlapi, v votlino take cevi.If a thermoplastic material with a coefficient of relative elongation of not more than 200% is used in the manufacture of a multicomponent homogeneous system, an excessively rigid system is obtained which further stops the process of fabrication of the sheath, which is described below in the description of the present invention. The use of thermoplastic material, whose melting point does not exceed 100 ° C, is liable to deteriorate the sealing of the inner layer of the envelope in the presence of a hot medium, such as saturated water vapor, into the cavity of such a tube.

Skupina termoplastičnih polimerov, katerih koeficient relativnega raztezka ni manjši od 200% in katerih talilna točka je nad 100°C lahko vključuje polietilene nizke gostote, super-visoko-molekularne polietilene, polipropilen, kopolimer propilena z vinilacetatom, polivinilklorid in termoplastični poliuretan, strukturni modifikator izbranega polimera pa je poliorganosiloksan izbran iz skupine, ki vključuje polimetilsiloksan, polimetilfenilsiloksan, polifenilsiloksan in polietilfenilsiloksan.A group of thermoplastic polymers having a coefficient of relative elongation of less than 200% and a melting point above 100 ° C may include low density polyethylene, super-high molecular weight polyethylene, polypropylene, propylene copolymer with vinyl acetate, polyvinyl chloride and thermoplastic polyurethane, structural modi of the polymer, however, the polyorganosiloxane is selected from the group consisting of polymethylsiloxane, polymethylphenylsiloxane, polyphenylsiloxane and polyethylphenylsiloxane.

Zaradi visoke termične stabilnosti in nizke stopnje medmolekulskih interakcij, poliorganosiloksani v termoplastičnem polimeru ne oblikujejo velikih aglomeratov in so enakomerno porazdeljeni v nezasedeni prostornini, kjer višajo mobilnost strukturnih elementov danega termoplastičnega polimera in pomagajo tvoriti bolj gosto in urejeno pakiranje velikih molekularnih verig. Take spremembe sestave termoplastičnega polimera povišajo odpornost tega na abrazivno utrujanje snovi in povečajo lepljenje z drugimi snovmi, še posebej s sintetičnimi ojačevalnimi snovmi.Due to their high thermal stability and low intermolecular interaction, polyorganosiloxanes do not form large agglomerates in thermoplastic polymer and are evenly distributed in the unoccupied volume, where they increase the mobility of the structural elements of a given thermoplastic polymer and help to form a more dense and orderly packing of large molecular chains. Such changes in the composition of the thermoplastic polymer increase its resistance to abrasive fatigue and increase adhesion to other substances, especially synthetic reinforcing agents.

Notranja cevasta plast ovoja se lahko izdela z večkomponentnim homogenim sistemom, ki vsebuje en polimer ali mešanico dveh polimerov, izbranih iz omenjene skupine termoplastičnih polimerov v količini 99,3-99,7 masnih %, relativno glede na celotno maso notranje plasti ovoja, vsebnost poliorganosiloksana pa se giblje v količinah od 0,3 do 0,7 masnih %, relativno glede na celotno maso notranje plasti ovoja.The inner tubular layer of the sheath may be produced by a multi-component homogeneous system containing one polymer or a mixture of two polymers selected from the said group of thermoplastic polymers in an amount of 99.3-99.7% by weight relative to the total weight of the inner layer of the sheath, the content of polyorganosiloxane however, it ranges from 0.3 to 0.7% by weight relative to the total weight of the inner layer of the wrapper.

Če je vstavljen večkomponentni homogeni sistem enega ali mešanice dveh termoplastičnih polimerov v količini, ki je manjša od 99,3 masnih % in poliorganosiloksana - v količini večji od 0,7 masnih %, se fizikalne in mehanske lastnosti takega sloja ovoja znatno poslabšajo. Če je vsebnost termoplastičnega polimera ali mešanice dveh takih polimerov večja od 99,7 masnih %, poliorganosiloksana pa je manj od 0,3 masnih %, se učinek izboljšanja nove, spremenjene strukture ne opazi.If a multi-component homogeneous system of one or a mixture of two thermoplastic polymers in an amount of less than 99.3% by weight and polyorganosiloxane - in an amount greater than 0.7% by weight is inserted, the physical and mechanical properties of such a layer of coating are significantly impaired. If the content of a thermoplastic polymer or a mixture of two such polymers is greater than 99.7% by weight and the polyorganosiloxane is less than 0.3% by weight, the effect of improving the new, modified structure is not observed.

Kot izbrani termoplastični polimer je dovoljeno uporabiti polietilen nizke gostote, kot poliorganosiloksan pa polimetilsiloksan.Low density polyethylene may be used as the selected thermoplastic polymer and polymethylsiloxane as polyorganosiloxane.

Kot izbrani termoplastični polimer je možno uporabiti supervisoko-molekularni polietilen, ter kot poliorganosiloksan polimetilsiloksan. Kot izbrani termoplastični polimer je mogoče uporabiti tudi polipropilen, ter kot poliorganosiloksan - polipenilsiloksan.Super-high molecular weight polyethylene and polyorganosiloxane polymethylsiloxane can be used as the selected thermoplastic polymer. Polypropylene and polyorganosiloxane - polyphenylsiloxane can also be used as the selected thermoplastic polymer.

Kot izbrani termoplastični polimer je mogoče uporabiti tudi kopolimer propilena z vinilacetatom, kot poliorganosiloksan - polimetilfenilsiloksan.As the selected thermoplastic polymer, it is also possible to use a copolymer of propylene with vinyl acetate, such as polyorganosiloxane - polymethylphenylsiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti tudi polivinilklorid in kot poliorganosiloksan polietilfenilsiloksan.Polyvinyl chloride and polyorganosiloxane polyethylphenylsiloxane may also be used as the selected thermoplastic polymer.

Kot izbrani termoplastični polimer se lahko uporabi tudi termoplastični poliuretan, kot poliorganosiloksan pa polimetilfenilsiloksan.Thermoplastic polyurethane may be used as the selected thermoplastic polymer and polymethylphenylsiloxane as the polyorganosiloxane.

Poleg tega je mogoče kot mešanico dveh termoplastičnih polimerov uporabiti tudi polietilen nizke gostote v količiniIn addition, low density polyethylene can be used as a mixture of two thermoplastic polymers

5-95 masnih % in polipropilen v količini 4,3 - 94,7 masnih %, relativno glede na celotno maso notranjega sloja ovoja, kjer je kot poliorganosiloksan uporaben polifenilsiloksan. Navedeno razmerje komponent omogoča izdelavo multikomponentnega homogenega sistema, katerega lastnosti niso enake lastnostim posamičnih termoplastičnih polimerov, vsebovanih v tej strukturi in imajo povišano moč ob zadostni elastičnosti. Če je v strukturi manj kot 5 masnih % polietilena nizke gostote, polipropilena pa je več kot 94,7 masnih %, ima večkomponentni homogeni sistem lastnosti modificiranega polipropilena, če pa je vsebnost v mešanici taka, da je polietilena nizke gostote manj od 95 masnih % in manj kot 4,3 masnih % polipropilena, pa ima sistem lastnosti modificiranega polietilena.5-95% by weight and polypropylene in an amount of 4.3-94.7% by weight, relative to the total weight of the inner layer of the shell, where polyphenylsiloxane is used as polyorganosiloxane. The aforementioned component ratio makes it possible to produce a multicomponent homogeneous system whose properties are not identical to those of the individual thermoplastic polymers contained in this structure and have increased strength with sufficient elasticity. If the structure contains less than 5% by weight of low density polyethylene and polypropylene is more than 94.7% by weight, the multi-component homogeneous system has the properties of modified polypropylene, but if the content in the mixture is such that low density polyethylene is less than 95% by weight and less than 4.3% by weight of polypropylene, however, the system has the properties of modified polyethylene.

Kot mešanico dveh izbranih termoplastičnih polimerov je mogoče uporabiti mešanico super-visoko-molekularnega polietilena v količini 5-95 masnih % in kopolimer propilena z vinilacetatom pri vsebnosti 4,3-94,7 masnih %, relativno glede na celotno maso notranjega sloja ovoja cevi, kot poliorganosiloksan pa je mogoče uporabiti polimetilsiloksan. Navedeno razmerje sestavin omogoča izdelavo večkomponentnega homogenega sistema z lastnostmi, ki so različne od lastnosti posameznih termoplastičnih polimerov vključenih v tej strukturi: povišana kemična odpornost v kombinaciji z visoko močjo in zadostno elastičnostjo. Če je vsebnost supervisoko-molekularnega polietilena v sistemu manjša od 5 masnih % kopolimera propilena pa je več kot 94,7 masnih % z vinilacetatom, ima tak sistem lastnosti modificiranega kopolimera propilena z vinilacetatom; če je vsebnost supervisoko-molekularnega polietilen v mešanici nad 95 masnih %,vsebnost kopolimera propilena pa je nižja od 4,3 masne % skupaj z vinilacetatom, pa ima sistem lastnosti modificiranega super-visoko-molekularnega polietilena.As a mixture of two selected thermoplastic polymers, a mixture of super-high molecular weight polyethylene in an amount of 5-95% by weight and a propylene copolymer with vinyl acetate at a content of 4.3-94.7% by weight relative to the total weight of the inner layer of the tube sheath can be used, however, as polyorganosiloxane, polymethylsiloxane can be used. The aforementioned ratio of constituents enables the production of a multicomponent homogeneous system with properties different from those of the individual thermoplastic polymers included in this structure: increased chemical resistance in combination with high strength and sufficient elasticity. If the content of super-high molecular weight polyethylene in the system is less than 5% by weight of propylene copolymer and more than 94.7% by weight with vinyl acetate, such system has the properties of modified propylene copolymer with vinyl acetate; if the content of super-high molecular weight polyethylene in the mixture is above 95% by weight, and the content of propylene copolymer is less than 4.3% by weight together with vinyl acetate, then the system has the properties of modified super-high molecular weight polyethylene.

Kot mešanico dveh izbranih termoplastičnih polimerov je priporočena uporaba mešanico polivinilklorida v količini 595 masnih % in termoplastičnega poliuretana v količini 4,3 94,7 masnih %, relativno glede na maso notranjega sloja ovoja, kot poliorganosiloksan pa se uporabi polimetilfenilsiloksan ali polietilfenilsiloksan.As a mixture of the two selected thermoplastic polymers, it is recommended to use a mixture of polyvinyl chloride in an amount of 595% by weight and thermoplastic polyurethane in an amount of 4.3 94.7% by weight, relative to the weight of the inner layer of the wrapper, and polymethylphenylsiloxane or polyethylphenyloxy or polyethylphenylsiloxane.

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Predstavljeno razmerje sestavin omogoča izdelavo večkomponentnih homogenih sistemov z lastnostmi, različnimi od lastnosti posamičnih termoplastičnih polimerov, ki so vključeni v to strukturo: visoka odpornost na abrazivno obrabo materiala, v povezavi s povišanim koeficientom lepljenja na druge snovi, še posebej sintetični ojačevalni material ob zadostni elastičnosti. Če je vsebnost termoplastičnega poliuretana v sistemu nižja od 5 masnih %, vsebnost polivinilklorida pa je višja od 94,7 masnih %, ima sistem lastnosti modificiranega polivinilklorida; pri vsebnosti več kot 95 masnih % termoplastičnega poliuretana in manj kot 4,3 masnih % vsebnosti polivinilklorida pa ima sistem lastnosti modificiranega termoplastičnega poliuretana.The presented component ratio makes it possible to produce multicomponent homogeneous systems with properties different from the properties of the individual thermoplastic polymers included in this structure: high abrasion resistance of the material in conjunction with increased adhesion to other substances, especially synthetic reinforcing material with sufficient elasticity . If the thermoplastic polyurethane content of the system is less than 5% by weight and the polyvinyl chloride content is higher than 94.7% by weight, the system has the properties of modified polyvinyl chloride; and having a content of more than 95% by weight of thermoplastic polyurethane and less than 4.3% by weight of polyvinyl chloride content, the system has the properties of modified thermoplastic polyurethane.

Pri izdelavi plašča cevi se lahko uporabi vsaj še en dodaten ojačevalni sloj, ki ga postavimo vzporedno med zunanji cevasti sloj ovoja in glavni ojačevalni sloj.At least one additional reinforcement layer may be used in the manufacture of the tube jacket, which is placed parallel to the outer tubular layer of the jacket and the main reinforcement layer.

Priporočamo, da se glavni ojačevalni sloj izdela iz sintetičnega netkanega vlaknastega materiala.It is recommended that the main reinforcement layer be made of synthetic non-woven fibrous material.

Ločeni robovi notranjega sloja ovoja se lahko z glavnim ojačevalnim slojem ovoja hermetično povežejo preko robov ali pa s prekrivanjem teh.Separate edges of the inner layer of the wrapper can be hermetically connected to the main reinforcing layer of the wrapper over the edges or by overlapping them.

To dosežemo tudi tako, da se v skladu z metodo vnašanja plašča na notranjo površino cevi, posamezni sloji sestavijo zunaj te. Pri tem je zunanji sloj namenjen zlepljanju z notranjo površino cevi, notranji sloj ovoja pa je od predhodnega ločen z glavnim ojačevalim slojem, ki je impregniran s termično utrjeno polimerno vezjo, tako da v končni fazi dobimo nedokončan produkt plašča, ki ga vstavimo v notranjost cevi, nato pa se v votlino notranjega ovoja cevi vstavi nosilec toplote pod tlakom. Toplota in utrjevanje vezi povzročita da se glavni ojačevalni sloj poveže z notranjim slojem ovoja tako, da se oba po površini medsebojno zlepita. Notranji sloj ovoja je sestavljen iz tanke plasti dobimo iz večkomponentnega homogenega sistema, kjer mešamo staljen vsaj en polimer, izbran iz skupine termoplastičnih polimerov, katerih koeficient relativnega raztezka ni manjši od 200%, tališčna točka pa ni pod 100°C. Omenjeni sistem vsebuje tudi struktirni modifikator izbranega polimera. S hermetičnim povezovnjem stranskih robov plasti skupaj z ojačevalnim slojem dobimo dvoplastni, nedokončani del plašča, ki je glede na zunanji sloj takega ovoja postavljen v notranjosti.This is also achieved by the fact that, in accordance with the method of insertion of the jacket on the inner surface of the pipe, the individual layers are assembled outside it. The outer layer is intended to adhere to the inner surface of the tube, and the inner layer of the envelope is separated from the previous by a main reinforcement layer impregnated with a thermally cured polymeric bond, so that ultimately an unfinished product of the jacket is inserted, which is inserted inside the tube. , and then a pressurized heat carrier is inserted into the cavity of the inner tube casing. The heat and hardening of the bonds cause the main reinforcement layer to bond to the inner layer of the sheath so that the two bond to one another over the surface. The inner layer of the sheath consists of a thin layer obtained from a multi-component homogeneous system, where the molten at least one polymer is selected from the group of thermoplastic polymers whose relative elongation coefficient is not less than 200% and the melting point is not below 100 ° C. Said system also comprises a structural modifier of the selected polymer. By sealing the side edges of the layers together with the reinforcement layer, we get a two-layer, unfinished part of the coat, which is placed inside with respect to the outer layer of such a covering.

Skupina termoplastičnih polimerov katerih koeficienti relativnega reaztezka niso manjši od 200% in katerih točke taljenja niso pod 100°C, lahko vključujejo polietilene nizke gostote, super-visoko-molekularne polietilene, polipropilen, kopolimer propilena z vinilacetatom, polivinilklorid in termoplastični poliuretan, ter strukturni modifikator izbranega polimera, ki jih predstavljajo poliorganosiloksan, izbran iz skupine, ki vključuje polimetilsiloksan, polimetilfenilsiloksan, polifenilsiloksan in polietilfenilsiloksan.A group of thermoplastic polymers whose relative elongation coefficients are not less than 200% and whose melting points are not below 100 ° C may include low density polyethylene, super-high molecular weight polyethylene, polypropylene, propylene copolymer with vinyl acetate, polyvinyl chloride and thermoplastic polyurethane, selected polymers represented by polyorganosiloxane selected from the group consisting of polymethylsiloxane, polymethylphenylsiloxane, polyphenylsiloxane and polyethylphenylsiloxane.

Notranji sloj ovojna cevi se lahko izdela tudi iz večkomponentnega homogenega sistema z mešanjem staljenega enega ali dveh polimerov, ki so izbrani iz omenjene skupine termoplastičnih polimerov v količini 99,3-99,7 masnih % relativno glede na celotno maso notranjega ovoja in poliorganosiloksana v količini 0,3 - 0,7 masnih % relativno glede na celotno maso notranjega ovoja.The inner layer of the jacket tube may also be made from a multi-component homogeneous system by mixing molten one or two polymers selected from said group of thermoplastic polymers in an amount of 99.3-99.7% by weight relative to the total weight of the inner jacket and polyorganosiloxane in an amount of 0.3 - 0.7% by weight relative to the total weight of the inner sheath.

Kot izbrani termoplastični polimer je mogoče uporabiti polietilen nizke gostote, kot poliorganosiloksan pa polimetilsiloksan.Low density polyethylene can be used as the selected thermoplastic polymer and polymethylsiloxane as polyorganosiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti super-visoko-molekularni polietilen, kot poliorganosiloksan pa polimetilsiloksan.Super-high molecular weight polyethylene can be used as the selected thermoplastic polymer and polymethylsiloxane as polyorganosiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti tudi polipropilen, ter kot poliorganosiloksan polifenilsiloksan.Polypropylene and polyorganosiloxane polyphenylsiloxane may also be used as the selected thermoplastic polymer.

Kot izbrani termoplastični polimer je mogoče uporabiti tudi polivinilklorid ter kot poliorganosiloksan polimetilfenilsiloksan.Polyvinyl chloride and polyorganosiloxane polymethylphenylsiloxane may also be used as the selected thermoplastic polymer.

Kot mešanico dveh izbranih termoplastičnih polimerov je mogoče uporabiti mešanico super-visoko-molekularnega polietilena v količini 5-95 masnih % in kopolimer propilena z vinilacetatom v količini 4,3 - 94,7 masnih %, relativno glede na celotno maso notranjega sloja ovoja cevi, ter kot poliorganosiloksan - polifenilsiloksan.As a mixture of two selected thermoplastic polymers, a mixture of super-high molecular weight polyethylene in the amount of 5-95% by weight and a propylene copolymer with vinyl acetate in the amount of 4.3-94.7% by weight relative to the total weight of the inner layer of the tube sheath can be used, and as polyorganosiloxane - polyphenylsiloxane.

Poleg mešanice dveh izbranih termoplastičnih polimerov je mogoče uporabiti tudi mešanico super-visoko-molekularnega polietilena v količini 5-95 masnih % in kopolimer propilena t vinilacetatom v količini 4,3 - 94,7 masnih %, relativno glede na maso notrnajega ovoja, ter kot poliorganosiloksan polimetilsiloksan.In addition to the mixture of two selected thermoplastic polymers, a mixture of super-high molecular weight polyethylene in the amount of 5-95% by weight and a copolymer of propylene t vinyl acetate in the amount of 4.3-94.7% by weight, relative to the weight of the inner sheath, and as polyorganosiloxane polymethylsiloxane.

Kot mešanico dveh izbranih termoplastičnih polimerov je mogoče uporabiti mešanico polivinilklorida v količini 5-95 masnih % in termoplastični poliuretan v količini 4,3 - 94,7 masnih %, relativno glede na maso notranjega ovoja, kot poliorganosiloksan pa je uporaben polimetilfenilsiloksan ali polietilfenilsiloksan.As a mixture of the two selected thermoplastic polymers, a mixture of polyvinyl chloride in an amount of 5-95% by weight and thermoplastic polyurethane in an amount of 4.3-94.7% by weight, relative to the weight of the inner envelope, can be used, and polymethylphenylsiloxane or polyethylphenylsiloxane is used as the polyorganosiloxane.

Med zunanjo plastjo ovoja in glavnim ojačevalnim slojem je priporočeno postaviti vsaj en dodaten ojačevalni sloj. Priporočljivo je tudi, da se glavni ojačevalni sloj izdela iz sintetičnega vlaknastega netkanega materiala.It is recommended to place at least one additional reinforcement layer between the outer layer of the sheath and the main reinforcement layer. It is also recommended that the main reinforcement layer be made of synthetic fibrous non-woven material.

Prav tako je priporočljivo tudi, da se omenjeni sloj z glavnim ojačevalnim slojem pričvrsti hermetično ob robovih ali pa z medsebojnim prekrivanjem stranskih robov.It is also advisable to attach said layer with the main reinforcement layer hermetically along the edges or by overlapping the lateral edges.

Dosegli smo tudi, da je dvo-slojni polizdelek omenjenega plašča cevi, sestavljen iz ojačevalnega sloja, povezanega z notranjo plastjo ovoja plašča notranje površine cevi, narejenega na osnovi termoplastičnega polimernega materiala, ki je glede na ta izum oblikovan iz večkomponentnega homogenega sistema, ki vsebuje vsaj en polimer, izbran iz skupine termoplastičnih polimerov, katerih koeficient relativnega raztezka ni manjši od 200 %, tališčna točka pa ni pod 100°C, skupaj s strukturnim modifikatorjem izbranega polimera. Tako sta notranji sloj ovoja in povezani ojačevalni sloj sestavljena tako, da sta prekinjena na vsaj enem mestu koaksialno glede na os takega polizdelka, oba prekinjena robova pa sta medsebojno hermetično povezana in kot taka oblikujeta soosno postavljen del celotnega ovoja. Skupina termoplastičnih polimerov, katerih koeficienti relativnega raztezka niso manjši od 200% in katerih tališčne točke ne padejo pod 100°C, lahko vsebujejo polietilen nizke gostote, super-visoko-molekularen polietilen, polipropilen, kopolimer propilena z vinilacetatom, polivinilklorid in termoplastičen poliuretan, ter strukturni modifikator izbranega polimera, predstavljen s skupino poliorganosiloksanov, ki jih izbiramo iz skupine, sestavljene iz polimetilsiloksana, polimetilfenilsiloksana, polifenilsiloksana in polietilfenilsiloksana.We have also achieved that a two-layer semi-fabricated tube casing comprising a reinforcement layer coupled to an inner coating layer of the inner tube surface made from a thermoplastic polymeric material, which according to the invention is formed from a multi-component homogeneous system comprising at least one polymer selected from the group of thermoplastic polymers having a relative elongation coefficient of not less than 200% and a melting point below 100 ° C, together with a structural modifier of the selected polymer. Thus, the inner layer of the envelope and the associated reinforcement layer are assembled such that they are interrupted in at least one location coaxially with respect to the axis of such a semi-finished product, and the two interrupted edges are hermetically interconnected and as such form a coaxially arranged part of the entire envelope. A group of thermoplastic polymers whose relative elongation coefficients are not less than 200% and whose melting points do not fall below 100 ° C may contain low density polyethylene, super-high molecular weight polyethylene, polypropylene, propylene copolymer with vinyl acetate, polyvinyl chloride and thermoplastic, structural modifier of the selected polymer represented by a group of polyorganosiloxanes selected from the group consisting of polymethylsiloxane, polymethylphenylsiloxane, polyphenylsiloxane and polyethylphenylsiloxane.

Notranji sloj ovoja cevi je lahko izdelan iz večkomponentnega homogenega sistema, ki vsebuje vsaj en polimer pa mešanico dveh polimerov, ki so izbrani iz omenjene skupine termoplastičnih polimerov v količini 99,3 99,7 masnih %, relativno glede na celotno maso notranjega sloja ovoja cevi, ter poliorganosiloksan v količini 0,3 0,7 masnih %, relativno glede na celotno maso notranjega sloja ovoja cevi.The inner layer of the tube sheath may be made of a multi-component homogeneous system containing at least one polymer and a mixture of two polymers selected from said group of thermoplastic polymers in an amount of 99.3 99.7% by weight relative to the total weight of the inner layer of the tube sheath , and polyorganosiloxane in an amount of 0.3 0.7% by weight relative to the total weight of the inner layer of the tube sheath.

Kot izbrani termoplastični polimer je mogoče uporabiti polietilen z nizko gostoto, kot poliorganosiloksan pa polimetilsiloksan.Low density polyethylene can be used as the selected thermoplastic polymer and polymethylsiloxane as polyorganosiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti super-visoko-molekularni polietilen, ter kot poliorganosiloksan polimetilsiloksan.Super-high molecular weight polyethylene and polyorganosiloxane polymethylsiloxane can be used as the selected thermoplastic polymer.

Kot izbrani termoplastični polimer je mogoče uporabiti polipropilen in kot poliorganosiloksan - polifenilsiloksan.Polypropylene and polyorganosiloxane - polyphenylsiloxane can be used as the selected thermoplastic polymer.

Kot izbrani termoplastični polimer je mogoče uporabiti tudi kopolimer propilena z vinilacetatom, ter kot poliorganosiloksan - polimetilfenilsiloksan.The selected thermoplastic polymer can also be used as a copolymer of propylene with vinyl acetate and as polyorganosiloxane - polymethylphenylsiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti poliviniloklorid ter kot poliorganosiloksan polietilfenilsiloksan.Polyvinylchloride and polyorganosiloxane polyethylphenylsiloxane may be used as the selected thermoplastic polymer.

Kot izbrani termoplastični polimer je mogoče uporabiti tudi termoplastični poliuretan ter kot poliorganosiloksan polimetilfenilsiloksan.Thermoplastic polyurethane and polyorganosiloxane polymethylphenylsiloxane may also be used as the selected thermoplastic polymer.

Poleg tega je kot mešanico dveh izbranih termoplastičnih polimerov mogoče uporabiti mešanico polietilena nizke gostote v količini 5-95 masnih % in propilena v količiniIn addition, a mixture of two selected thermoplastic polymers can be used a mixture of low density polyethylene in the amount of 5-95 wt.% And propylene in the amount

4,3 - 94,7 masnih %, relativno glede na maso notranjega ovoja, ter kot poliorganosiloksan - polifenilsiloksan.4.3 to 94.7% by weight, relative to the weight of the inner sheath, and as polyorganosiloxane - polyphenylsiloxane.

Kot mešanico dveh izbranih termoplastičnih polimerov je mogoče uporabiti tudi mešanico super-visoko-molekularnega polietilena v količini 5-95 masnih % in kopolimer propilena z vinilacetatom v količini 4,3 - 94,7 masnih %, relativno glede na maso notranje plasti ovojna, ter kot poliorganosiloksan uporabiti polimetilsiloksan.As a blend of two selected thermoplastic polymers, a mixture of super-high molecular weight polyethylene in an amount of 5-95% by weight and a propylene copolymer with vinyl acetate in an amount of 4.3-94.7% by weight relative to the weight of the inner layer of the envelope can also be used, and use polymethylsiloxane as polyorganosiloxane.

Kot mešanico dveh izbranih termoplastičnih polimerov je zaželjeno uporabiti mešanico polivinilklorida v količini 5 95 masanih % in termoplastični poliuretan v količini 4,3 94,7 masnih %, relativno glede na maso notranjega sloja ovojna cevi. Kot poliorganosiloksan pa se lahko uporabi polimetilfenilsiloksan ali polietilfenilsiloksan. Priporočljivo je, da se ojačevalni sloj izdela iz sintetičnega netkanega vlaknastega materiala.As a mixture of the two selected thermoplastic polymers, it is desirable to use a mixture of polyvinyl chloride in an amount of 5 95% by weight and a thermoplastic polyurethane in an amount of 4.3 94.7% by weight, relative to the weight of the inner layer of the wrapping tube. However, polyorganosiloxane may be polymethylphenylsiloxane or polyethylphenylsiloxane. It is recommended that the reinforcement layer be made of synthetic non-woven fibrous material.

Ločene robove notranjega cevastega sloja ovoja cevi je mogoče z ojačevalnim slojem hermetično povezati, tako da se rob stika z robom ali pa tako, da se soosno takemu delno dokončanemu delu plašča oba robova prekrivata.Separate edges of the inner tubular layer of the tube envelope may be hermetically connected to the reinforcing layer by contacting the edge with the edge or by overlapping the two edges with such a partially completed sheath.

Cilj tega izuma je dosegljiv tudi tako, da se v postopku za izdelavo omenjenega dvoslojnega polizdelka omenjenega plašča notranje površine cevi, po katerem se notranji sloj ovoja plašča cevi, izdelan na osnovi termoplastičnega polimernega materiala poveže z ojačevalnim slojem v skladu z izumom, kjer je notranji sloj omenjenega ovoja izdelan kot pola, narejena iz večkomponentnega homogenega sistema z mešanjem vsaj enega utekočinjenega polimera, izbranega iz skupine termoplastičnih polimerov, katerih koeficienti relativnega raztezka niso manjši od 200%, točke taljenja pa niso pod 100°C, skupaj s strukturnim modifikatorjem izbranega polimera. Površini plasti ovoja povežemo, stranski robovi pa se skupaj z ojačevalnim slojem povežejo hermetično, s čimer dobimo dvoslojni delno dokončani del plašča iz soosno postavljenih in medsebojno povezanih ojačevalnega sloja in notranjega sloja ovoja cevi.The object of the present invention is also achievable by the process for the manufacture of said two-layer semi-finished product of said inner tube surface, by which the inner layer of the tube outer layer is made on the basis of a thermoplastic polymeric material in accordance with the invention, wherein the inner a layer of said sheath made as a pole made from a multi-component homogeneous system by mixing at least one liquefied polymer selected from the group of thermoplastic polymers having a coefficient of relative elongation of not less than 200% and melting points not below 100 ° C, together with a structural modifier of the selected polymer . The surface of the coating layer is bonded, and the lateral edges together with the reinforcement layer are hermetically sealed, resulting in a two-layer partially finished portion of the coating from a coaxially positioned and interconnected reinforcement layer and an inner layer of the tube wrapper.

Skupina termoplastičnih polimerov, katerih koeficient relativnega raztezanja ne pad pod 200% in katerih točke tališča niso pod 100°C, lahko vsebujejo polietilen z nizko gostoto, super-visoko-molekularni polietilen, polipropilen, kopolimer propilena z vinilacetatom, polivinilklorid in termoplastični poliuretan, ter strukturni modifikator izbranega polimera, ki je predstavljen kot poliorganosiloksan, izbran iz skupine, ki vključuje polimetilsiloksan, polimetilfenilsiloksan, polifenilsiloksan in polietilfenilsiloksan.A group of thermoplastic polymers, whose relative elongation coefficient does not drop below 200% and whose melting points are not below 100 ° C, may contain low density polyethylene, super-high molecular weight polyethylene, polypropylene, propylene copolymer with vinyl acetate, polyvinyl chloride and thermoplastic polyurethane, structural modifier of the selected polymer represented as polyorganosiloxane selected from the group consisting of polymethylsiloxane, polymethylphenylsiloxane, polyphenylsiloxane and polyethylphenylsiloxane.

Notranji sloj ovoja cevi se lahko pridobi tudi iz večkomponentnega homogenega sistema z mešanjem staljenega vsaj enega polimera ali mešanice dveh polimerov, ki so bili izbrani iz omenjene skupine termoplastičnih polimerov in se nahajajo v količinah 99,3 - 99,7 masnih %, relativno glede na maso notranje plasti ovoja, ter poliorganosiloksan v količini 0,3 - 0,7 masnih %, relativno glede na celotno maso notranje plasti ovoja.The inner layer of the tube sheath may also be obtained from a multi-component homogeneous system by mixing molten at least one polymer or a mixture of two polymers selected from said group of thermoplastic polymers and present in amounts of 99.3-99.7% by weight relative to the weight of the inner layer of the sheath, and polyorganosiloxane in an amount of 0.3-0.7% by weight, relative to the total weight of the inner layer of the sheath.

Kot izbrani termoplastični polimer je mogoče uporabiti polietilen nizke gostote, kot poliorganosiloksan pa polimetilsiloksan.Low density polyethylene can be used as the selected thermoplastic polymer and polymethylsiloxane as polyorganosiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti super-visoko-molekularni polietilen in kot poliorganosiloksan - polimetilsiloksan.Super-high molecular weight polyethylene and polyorganosiloxane - polymethylsiloxane can be used as the selected thermoplastic polymer.

Kot izbrani termoplastični polimer je mogoče uporabiti tudi polipropilen in kot poliorganosiloksan - polifenilsiloksan. Kot izbrani termoplastični polimer je mogoče uporabiti kopolimer propilena z vinilacetatom, ter kot poliorganosiloksan - polimetilsiloksan.Polypropylene and polyorganosiloxane - polyphenylsiloxane can also be used as the selected thermoplastic polymer. The selected thermoplastic polymer can be used as a copolymer of propylene with vinyl acetate and as polyorganosiloxane - polymethylsiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti polivinilklorid in kot poliorganosiloksan polietilfenilsiloksan.Polyvinyl chloride can be used as the selected thermoplastic polymer and polyethylphenylsiloxane as polyorganosiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti termoplastični poliuretan, ter kot poliorganosiloksan polimetilfenilsiloksan.Thermoplastic polyurethane and polyorganosiloxane polymethylphenylsiloxane may be used as the selected thermoplastic polymer.

Kot mešanico dveh izbranih termoplastičnih polimerov je mogoče uporabiti mešanico polietilena nizke gostote v količini 5-95 masnih % in polipropilen v količini 4,3 94,7 masnih %, relativno glede na maso notranje plasti ovoja, kot poliorganosiloksan pa polifenilsiloksan.As a mixture of the two selected thermoplastic polymers, a low density polyethylene mixture of 5-95% by weight and polypropylene of 4.3 94.7% by weight relative to the weight of the inner layer of the wrapper may be used, as polyorganosiloxane as polyphenylsiloxane.

Kot mešanico dveh izbranih termoplastičnih polimerov je mogoče uporabiti mešanico super-visoko-molekularnega polietilena v količini 5-95 masnih % in kopolimer propilena z vinilacetatom v količini 4,3 - 94,7 masnih %, relativno glede na maso notranjega sloja ovoja cevi, kot poliorganosiloksan pa je mogoče uporabiti polimetilsiloksan Kot mešanico dveh izbranih termoplastičnih polimerov je priporočena tudi uporaba mešanice polivinilklorida v količini 5-95 masnih % in termoplastičnega poliuretana v količini 4,3 - 94,7 masnih %, relativno glede na maso notranjega sloja ovoja, kot poliorganosiloksan pa polimetilfenilsiloksan ali polietilfenilsiloksan. Priporočljivo je da se ojačevalni sloj izdela iz sintetičnega vlaknastega netkanega materiala.As a mixture of two selected thermoplastic polymers, a mixture of super-high molecular weight polyethylene in the amount of 5-95% by weight and a copolymer of propylene with vinyl acetate in the amount of 4.3-94.7% by weight, relative to the weight of the inner layer of the tube shell, can be used as polyorganosiloxane can be used polymethylsiloxane As a mixture of two selected thermoplastic polymers, it is also recommended to use a mixture of polyvinyl chloride in an amount of 5-95% by weight and thermoplastic polyurethane in an amount of 4.3 - 94.7% by weight, relative to the weight of the inner layer of the wrapper, as polyorganosiloxane and polymethylphenylsiloxane or polyethylphenylsiloxane. It is recommended that the reinforcement layer be made of synthetic fibrous non-woven material.

Poleg tega je potrebno hermetično povezati robova zlepljene notranje plasti ovoja in ojačevalna sloja na stranskih straneh ali pa ju povezati s prekrivanjem.In addition, the edges of the glued inner layer of the envelope and the reinforcement layers on the sides must be hermetically sealed, or they may be joined by overlaps.

Utemeljitve vseh mej, bodisi pri postopku uporabe omenjenega plašča in pri dvoslojnem delno dokončanem delu plašča ter pri postopku izdelave tega dela, so enake kot v sledečih patentnih zahtevkih patentiranega plašča.The substantiation of all boundaries, whether in the process of using said coat and in the two-layer partially completed part of the coat and in the process of making this work, is the same as in the following patent claims of the patented coat.

Patentirani plašč ima poleg tega še nekatere prednosti:The patented coat also has some advantages:

- visoko operativno moč in tesnost;- high operational power and tightness;

- popolno odsotnost defektov (gube, odkloni ipd.) na notranji površini, kjer jih oblikuje notranji sloj ovoja, kakor tudi popolno odsotnost luščenja omenjenega plašča, kar omogoča enakomerno gibanje transportirane tekočine preko cevi brez dodatne izgube energije;- the complete absence of defects (wrinkles, deflections, etc.) on the inner surface where they are formed by the inner layer of the sheath, as well as the complete absence of peeling of said coat, which allows the fluid to be transported uniformly through the tubes without additional energy loss;

- odpornost na abrazivno izrabo;- resistance to abrasive wear;

- stabilnost pri delovanju kemično aktivnega medija in vode, kar znatno poviša rok trajanja in zanesljivost plašča in omogoča uporabo v ceveh za različne namene.- stability in the action of the chemically active medium and water, which significantly increases the durability and reliability of the jacket and allows it to be used in tubes for various purposes.

Patentirani postopek za vstavljanje patentiranega plašča omogoča vnašanje tega in ima nekaj prednosti, ki so bile opisane zgoraj zaradi uporabe dvoslojnega delno dokončanega dela plašča, ki je sestavljen iz notranjega ovoja in glavnega ojačevalnega sloja, ki sta povezana skupaj, kar olajša tehnologijo sestavljanja večslojnega delno dokončanega dela plašča in onemogoča odklanjanje, izvijanje in raztegovanje notranje plasti celotnega ovoja med transportom tega v notranjost cevi.The patented process for inserting a patented jacket allows this to be introduced and has some of the advantages described above due to the use of a two-layer partially finished part of the jacket, which consists of an inner sheath and a main reinforcement layer, which are connected together, which facilitates multi-layer partially completed assembly technology of the jacket and prevents the inner layer of the entire wrapping from being bent, twisted and stretched while transporting it to the inside of the pipe.

Dvoslojni polizdelek celotnega plašča cevi, po predmetnem izumu se odlikuje z visoko stopnjo adhezije notranjega sloja ovoja plašča na glavni ojačevalni sloj, visoko močjo in tesnostjo, ki omogoča uporabo tega pri izdelavi ovoja z zgoraj omenjenimi prednostmi, v skladu s postopkom, ki je opisan v tem izumu.The two-layer semi-finished product of the entire tube sheath, according to the present invention, is characterized by a high degree of adhesion of the inner layer of the sheath to the main reinforcement layer, high strength and tightness, which allows it to be used in the manufacture of the sheath with the aforementioned advantages, in accordance with the procedure described in of this invention.

Opisani postopek izdelave omenjenega dvoslojnega delno dokončanega dela daje možnost izdelave takega delno dokončanega dela z zgoraj omenjenimi prednostmi.The described process of manufacturing said two-layer partially completed work gives the possibility of producing such partially completed work with the aforementioned advantages.

Kratek opis slikShort description of the pictures

Izum je nadalje pojasnjen z opisom posameznih primerov uporabe le-tega in s pomočjo priloženih slik.The invention is further explained by the description of the individual use cases and by the accompanying drawings.

Slika 1 prikazuje plašč, uporabljen po postopku v skladu izumom, na notranji površini cevi v aksonometrijiFigure 1 shows the jacket used according to the method of the invention on the inner surface of the tube in axonometry

Slika 2 enako kot slika 1, le v prečnem prerezu in povečano;Fig. 2 same as Fig. 1, only in cross section and enlarged;

Slika 3 prikazuje detalj A s slike 2, v povečanem merilu; Slika 4 prikazuje drugo varianto uporabe prikazane na sliki 3;Figure 3 shows detail A of Figure 2, on a larger scale; Figure 4 shows another embodiment shown in Figure 3;

Slika 5 prikazuje še eno varianto uporabe prikazane na sliki 3;Figure 5 shows another embodiment shown in Figure 3;

Slika 6 prikazuje drugo varianto uporabe plašča, ki je predmet tega izuma, apliciranega s postopkom po predmetnem izumu, v prečnem prerezu;Figure 6 shows another embodiment of the jacket which is the subject of the present invention, applied by the process of the present invention, in cross-section;

Slika 7 prikazuje detalj B s slike 6, v povečanem merilu; Slika 8 prikazuje drugo varianto uporabe plašča, ki je predmet tega izuma, apliciranega s postopkom po predmetnem izumu, v prečnem prerezu;Figure 7 shows the detail B of Figure 6, in enlarged scale; Figure 8 shows another embodiment of the jacket which is the subject of the present invention, applied by the process of the present invention, in cross-section;

Slika 9 prikazuje eno izmed možnih izvedb dvoslojnega polizdelka plašča, apliciranega s postopkom po predmetnem izumu v prečnem prerezu;Fig. 9 shows one of the possible embodiments of the bilayer semi-finished coat applied by the cross-sectional view of the present invention;

Slika 10 prikazuje eno izmed različic izvedbe omenjenega dvoslojnega polizdelka plašča, kot na slikah 1 in 2, dobljenega po postopku v skladu s predmetnim izumom v prečnem prerezu;Figure 10 shows one embodiment of said two-layer semi-finished coat as in Figures 1 and 2 obtained by the cross-sectional view of the present invention according to the present invention;

Slika 11 prikazuje drugo različica izvedbe omenjenega dvoslojnega polizdelka plašča, kot na sliki 6, dobljenega s postopkom v skladu s predmetnim izumom v prečnem prerezu.Figure 11 shows a second embodiment of said two-layer semi-finished coat, as in Figure 6, obtained by the cross-sectional view of the present invention.

Prednostna upodobitev izumaA preferred embodiment of the invention

Plašč notranje površine cevi (1) (sliki 1 in 2) vključuje dva soosno postavljena cevasta ovoja (2 in 3), izdelana na osnovi termoplastičnih polimernih materialov, od katerih je zunanji (2), povezan z notranjo površino cevi, drugi notranji (3) pa je od tega ločen s soosnim glavnim (4) in dodatnim (5) ojačevalnim slojem, ki sta impregnirana z utrjeno polimerno vezjo. Notranji cevasti ovoj (3) je oblikovan iz večkomponentnega homogenega sistema, ki vsebuje vsaj en polimer, izbran iz skupine termoplastičnih polimerov, katerih koeficienti relativnega raztezanja niso manjši od 200%, točke taljenja pa ne pod 100°C, dodatno pa se tu nahaja tudi strukturni modifikator izbranega polimera. S tem je implementiran notranji sloj ovoja (3) in glavni ojačevalni sloj (4), soosno pa sta ločena na vsaj enem mestu, ločena robova (6) in (7) pa sta medsebojno hermetično povezana, tako da ta ovoj (3) oblikuje monolitno strukturo z glavnim ojačevalnim slojem (4) .The inner tube surface of the tube (1) (Figures 1 and 2) includes two coaxially arranged tubular sheaths (2 and 3) made on the basis of thermoplastic polymeric materials, the outer of which (2), connected to the inner surface of the tube, the second inner (3 ) is separated from this by a coaxial main (4) and an additional (5) reinforcement layer impregnated with a cured polymeric bond. The inner tubular sheath (3) is formed from a multicomponent homogeneous system containing at least one polymer selected from the group of thermoplastic polymers having a coefficient of relative elongation of not less than 200% and a melting point not below 100 ° C, and is further located here structural modifier of the selected polymer. The inner sheath layer (3) and the main reinforcement layer (4) are thus implemented, coaxially separated in at least one place, and the separate edges (6) and (7) interconnected, so that this sheath (3) forms monolithic structure with main reinforcement layer (4).

Skupina termoplastičnih polimerov, katerih koeficient relativnega raztezanja ni manjši od 200%, tališčne točke pa so višje od 100°C, vsebuje polietilen nizke gostote, supervisoko-molekularni polietilen, polipropilen, kopolimer propilena z vinilacetatom, polivinilklorid in termoplastični poliuretan, strukturni modifikator izbranega polimera pa je poliorganosiloksan izbran iz skupine, ki vsebuje polimetilsiloksan, polimetilfenilsiloksan, polifenilsiloksan in polietilfenilsiloksan.A group of thermoplastic polymers having a coefficient of relative elongation of less than 200% and melting points higher than 100 ° C contains low-density polyethylene, super-molecular molecular polyethylene, polypropylene, propylene copolymer with vinyl acetate, polyvinyl chloride and thermoplastic polyurethane, however, the polyorganosiloxane is selected from the group consisting of polymethylsiloxane, polymethylphenylsiloxane, polyphenylsiloxane and polyethylphenylsiloxane.

Notranji sloj ovoja (3) je oblikovan iz večkomponentnega homogenega sistema, ki vsebuje en polimer ali mešanico dveh polimerov, izbranih iz omenjene skupine termoplastičnih polimerov v količini 99,3 - 99,7 masnih %, relativno glede na celotno maso notranjega ovoja in poliorganosiloksan v količini 0,3 - 0,7 masnih %, relativno glede na celotno maso notranjega ovoja (3).The inner layer of the sheath (3) is formed from a multicomponent homogeneous system containing one polymer or a mixture of two polymers selected from the said group of thermoplastic polymers in an amount of 99.3 - 99.7% by weight relative to the total weight of the inner sheath and polyorganosiloxane in 0.3 to 0.7% by weight relative to the total weight of the inner sheath (3).

Kot izbrani termoplastični polimer je mogoče uporabiti polietilen nizke gostote, kot poliorganosiloksan pa polilmetilsiloksan.Low density polyethylene can be used as the selected thermoplastic polymer and polymethylsiloxane as polyorganosiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti super-visoko-molekularni polietilen, kot poliorganosiloksan pa polimetilsiloksan.Super-high molecular weight polyethylene can be used as the selected thermoplastic polymer and polymethylsiloxane as polyorganosiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti polipropilen, kot poliorganosiloksan pa polifenilsiloksan. Kot izbrani termoplastični polimer je mogoče uporabiti tudi kopolimer propilena z vinilacetatom in kot poliorganosiloksan - polimetilfenilsiloksan.Polypropylene can be used as the selected thermoplastic polymer and polyphenylsiloxane as polyorganosiloxane. The selected thermoplastic polymer can also be used as a copolymer of propylene with vinyl acetate and as polyorganosiloxane - polymethylphenylsiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti poliviniloklorid in kot poliorganosiloksan polietilfenilsiloksan, kakor tudi v primeru izbranega polimera - termoplastični poliuretan, ter kot poliorganosiloksan - polimetilfenilsiloksan.Polyvinylchloride and polyorganosiloxane polyethylphenylsiloxane can be used as the selected thermoplastic polymer, as well as thermoplastic polyurethane in the case of the selected polymer and polyorganosiloxane - polymethylphenylsiloxane.

Poleg tega je mogoče kot mešanico dveh izbranih termoplastičnih polimerov uporabiti mešanico polietilena nizke gostote v količini 5-95 masnih % in polipropilena v količini 4,3 - 94,7 masnih %, relativno glede na maso notranjega sloja ovoja cevi (3), kot poliorganosiloksan pa polifenilsiloksan.In addition, a mixture of low density polyethylene in the amount of 5-95% by weight and polypropylene in the amount of 4.3-94.7% by weight, relative to the weight of the inner layer of the tube sheath (3), as polyorganosiloxane, can be used as a mixture of the two selected thermoplastic polymers. and polyphenylsiloxane.

Kot mešanico dveh izbranih termoplastičnih polimerov je mogoče uporabiti mešanico super-visoko-molekularnega polietilena v količini 5-95 masnih % in kopolimer polipropilena z vinilacetatom v količini 4,3 - 94,7 masnih %, relativno glede na maso notranjega ovoja (3), kot poliorganosiloksan pa polimetilsiloksan.As a mixture of two selected thermoplastic polymers, a mixture of super-high molecular weight polyethylene in the amount of 5-95% by weight and a copolymer of polypropylene with vinyl acetate in the amount of 4.3-94.7% by weight relative to the weight of the inner sheath (3) can be used, as polyorganosiloxane, polymethylsiloxane.

Kot mešanico dveh izbranih termoplastičnih polimerov je mogoče uporabiti mešanico polivinilklorida v količini 5-95 masnih % in termoplastični poliuretan v količini 4,3 - 94,7 masnih %, relativno glede na maso notranjega sloja (3), kot (10) pa poliorganosiloksan - polimetilfenilsiloksan ali polietilfenilsiloksan.As a mixture of the two selected thermoplastic polymers, a mixture of polyvinyl chloride in the amount of 5-95% by weight and thermoplastic polyurethane in the amount of 4.3 - 94.7% by weight, relative to the weight of the inner layer (3), and (10) as polyorganosiloxane - polymethylphenylsiloxane or polyethylphenylsiloxane.

Zunanji ovoj (2) se lahko izdela iz polietilena ali večslojnega polietilensko - poliamidnega sloja.The outer sheath (2) may be made of polyethylene or a multilayer polyethylene - polyamide layer.

Glavni ojačevalni sloj (4) je izdelan iz sintetičnega netkanega vlaknastega materiala, na primer iz sintetičnega polsta osnovanega na poliestru ali/in polipropilenskih vlaknih.The main reinforcement layer (4) is made of synthetic non-woven fibrous material, for example, of a synthetic felt based on polyester or / and polypropylene fibers.

Dodatni ojačevalni sloj (5) je izdelan iz sintetičnega polsta osnovanega na poliestru in/ali polipropilenskih vlaknih, stekleni tkanini, stekleno pletivo, kombinaciji steklenih materialov, mreži iz termoplastičnih materialov ali mreži iz ogljikovih vlaken.The additional reinforcement layer (5) is made of a synthetic felt based on polyester and / or polypropylene fibers, a glass cloth, a glass knit, a combination of glass materials, a thermoplastic mesh or a carbon fiber net.

Za polimerno vez se lahko uporabi poliester, epoksi, epoksipoliesterska vez, poliesterska vez, zadebeljena aerosil in/ali magnezijevim oksidom.For the polymer bond, polyester, epoxy, epoxy polyester bond, polyester bond, thickened aerosil and / or magnesium oxide may be used.

Ločena robova (6 in 7) notranjega sloja ovoja (3), sta skupaj z glavnim ojačevalnim slojem (4) hermetično povezana preko robov, kot je prikazano na slikah 1, 2 in 3. Območje povezave (šivanje ali varjenje) robu (6) (slika 3) in (7) je hermetično zaprto, oziroma zavarjeno soosno osi ovoja cevi (slika 1) s trakom (8) iz snovi, ki je identična snovi iz katere je sestavljen notranji sloj ovoja (3).Separate edges (6 and 7) of the inner layer of the sheath (3), together with the main reinforcing layer (4) are hermetically connected through the edges, as shown in Figures 1, 2 and 3. The area of connection (sewing or welding) of the edge (6) (Figure 3) and (7) is sealed or welded the axial axis of the tube sheath (Figure 1) with a strip (8) of a substance identical to the substance of which the inner layer of the sheath (3) is composed.

Na slikah 4 in 5 sta prikazani še dve različici implementacije hermetične povezave nepovezanih robov (6 in 7) notranjega sloja ovoja (3), skupaj z glavnim ojačevalnim slojem (4), ki sta tu povezana s stikanjem robov.Figures 4 and 5 show two more variants of the implementation of the hermetic connection of the unbound edges (6 and 7) of the inner layer of the sheath (3), together with the main reinforcement layer (4), which are connected here by the edge contact.

Na sliki 4 sta robova (6 in 7) prekrita z oblogo (9), ki se širi soosno osi ovoja, in je na primer iz fluoroplastike, sintetične tkanine, steklenih vlaken in je nato prekrit s trakom (8).In Figure 4, the edges (6 and 7) are covered by a lining (9) extending coaxially to the axis of the sheath and, for example, of fluoroplastics, synthetic fabric, fiberglass and then covered with tape (8).

Na sliki 5 je območje povezave (šivanje ali varjenje) robov (6 in 7) hermetično zaprto, oziroma zavarjeno soosno osi ovoja z vzorčastim trakom (10), ki ima prečni prerez v obliki črke T, ki je identičen materialu notranjega sloja ovoja cevi (3).In Fig. 5, the area of connection (sewing or welding) of the edges (6 and 7) is hermetically sealed, or welded, the coaxial axis of the sheath with a pattern strip (10) having a T-shaped cross-section identical to the material of the inner layer of the pipe sheath ( 3).

Ločena robova (6 in 7) notranjega sloja (3), skupaj z glavnim ojačevalnim slojem (4) se lahko hermetično zapreta tudi s postopkom prekrivanja, kot je prikazano na sliki 6 in 7. Zaradi tega sta stranska robova (6) (slika 7) in (7) zašita ali zavarjena, prekrivata pa se na osi ovoja, območje povezave (zašito ali zavarjeno) pa je zavarjeno s trakom (8) iz snovi, ki je identična snovi notranjega sloja ovoja (3). Na sliki 8 je prikazana različica uporabe plašča cevi, kjer je viden še dodaten ojačevalni sloj (11), postavljen med dodaten ojačevalni sloj (5) in zunanji sloj ovoja (2). Ojačevalni sloj (11) je izdelan iz sintetičnega polsta, osnovanega na poliestru in/ali polipropilenskih vlaknih, steklenih vlaknih, steklenem pletivu, kombinacijah steklenih snovi, mreži iz termoplastičnih vlaken ali mreži iz ogljikovih vlaken.The separated edges (6 and 7) of the inner layer (3), together with the main reinforcing layer (4) can also be hermetically closed by the overlapping process, as shown in Figures 6 and 7. Therefore, the lateral edges (6) (Fig. 7 ) and (7) are sewn or welded but overlap on the axis of the envelope and the connection area (sewn or welded) is welded with a strip (8) of a substance identical to that of the inner layer of the envelope (3). Figure 8 shows a variant of using a tube jacket, where an additional reinforcement layer (11) is visible, placed between the additional reinforcement layer (5) and the outer layer of the sheath (2). The reinforcement layer (11) is made of a synthetic felt based on polyester and / or polypropylene fibers, glass fibers, glass knitting, combinations of glass materials, thermoplastic fibers or carbon fiber nets.

Na sliki 9 je prikazana različica plašča cevi, v kateri je poleg ojačevalnih slojev (5 in 11), uporabljen še en dodatni ojačevalni sloj (12), vstavljen med slojem (11) in zunanjim slojem ovoja (2), izdelan pa je iz sintetičnega polsta narejenega iz poliestra in/ali polipropilenskih vlaken, steklenih vlaken, steklenega pletiva, kombinaciji steklenega materiala, mreži iz termoplastičnih vlaken ali mreži iz ogljikovih vlaken.Figure 9 shows a version of a tube sheath in which, in addition to the reinforcing layers (5 and 11), another additional reinforcing layer (12) is inserted, inserted between the layer (11) and the outer layer of the sheath (2) and made of synthetic squeegee made of polyester and / or polypropylene fibers, fiberglass, fiberglass, a combination of glass material, a thermoplastic fiber net or a carbon fiber net.

Postopek za vnašanje plašča na notranjo površino cevi, v skladu s tem izumom, se izvaja tako, da imamo na začetku zunaj cevi 1 (sliki 1 in 2), cevasta sloja ovoja (2 in 3), ki sta izdelana na osnovi termoplastičnega polimera, sta postavljeni soosno zunaj te cevi. Pri tem je zunanji sloj (2) namenjen pritrditev na notranjo površino cevi (1), notranji sloj (2) pa je od tega ločen z glavnim (4) in dodatnim ojačevalnim (5) slojem ovoja. Ojačevalni sloj je impregniran s termično strdljivim vezivnim sredstvom. Tako dobimo delno dokončani del plašča, ki ga nato vstavimo v cev (1), nakar se v notranjost te cevi pod tlakom vstavi še nosilec toplote, zaradi česar pride do posledičnega utrjevanja vezivnega sredstva. Pred sestavo neimpregniranega večslojnega delno dokončanega dela plašča, se pola materiala, ki tvori glavni ojačevalni sloj (4) poveže s polo materiala, ki tvori notranji sloj ovoja (3) in je izdelan iz večkomponentnega homogenega sistema s pomočjo mešanja staljenega vsaj enega polimera, izbranega iz skupine termoplastičnih polimerov, katerih koeficienti relativne raztegljivosti so večji od 200%, točke taljenja pa so nad 100°C, ter strukturnega modifikatorja izbranega polimera. Za tem se stranska robova (6 in 7) notranje plasti ovoja, skupaj z glavnim ojačevalnim slojem (4), ki je na to plast pričvrščen, hermetično povežeta skupaj, s čimer dobimo dvoslojni, delno dokončani del celotnega plašča, oziroma polizdelek, kar je predstavljeno na sliki 10, kjer sta postavljena soosno in medsebojno povezana ojačevalni sloj (4) in notranja cevasta plast (3), nato pa še izdelani dvoslojni, delno dokončani del plašča, skupaj z dodatnim ojačevalnim slojem (5), ki je postavljen soosno osi glede na zunanji sloj ovoja (2).The process for inserting the jacket onto the inner surface of the tube according to the present invention is carried out in such a way that, initially, outside the tube 1 (Figures 1 and 2), the tubular layers of the jacket (2 and 3) are made on the basis of a thermoplastic polymer, are positioned coaxially outside this tube. The outer layer (2) is intended to be attached to the inner surface of the tube (1), and the inner layer (2) is separated therefrom by the main (4) and an additional reinforcing (5) layer of the wrapper. The reinforcement layer is impregnated with a thermally curable binder. In this way a partially finished part of the jacket is obtained, which is then inserted into the tube (1), after which a heat carrier is inserted into the inside of this tube, which results in the subsequent hardening of the binder. Prior to assembling the non-impregnated multilayer partially completed sheath, the pole of the material forming the main reinforcing layer (4) is coupled to the polo of the material forming the inner layer of the sheath (3) and made of a multi-component homogeneous system by mixing molten at least one polymer selected from a group of thermoplastic polymers having relative elongation coefficients greater than 200% and melting points above 100 ° C, and a structural modifier of the selected polymer. Thereafter, the lateral edges (6 and 7) of the inner layer of the sheath, together with the main reinforcing layer (4) attached thereto, are hermetically joined together to give a two-layer, partially finished part of the whole sheath, or semi-finished product, which is presented in Figure 10, where a coaxially and interconnected reinforcement layer (4) and an inner tubular layer (3) are arranged, followed by a further two-layer, partially completed sheath, together with an additional reinforcement layer (5) positioned along the coaxial axes with respect to the outer layer of the wrapper (2).

Skupina termoplastičnih polimerov, katerih koeficient raztezanja je večji od 200%, točke taljenja točke pa so nad 100°C, vključujejo polietilen nizke gostote, super-visokomolekularne polietilene, polipropilen, kopolimer propilena z vinilacetatom, polivinilklorid in termoplastični poliuretan, poleg teh pa vključujejo strukturalni modifikatorji izbranega polimera skupino poliorganosiloksanov, med katerimi so polimetilsiloksan, polimetilfenilsiloksan, polifenilsiloksan in polietilfenilsiloksan.A group of thermoplastic polymers having a coefficient of elongation greater than 200% and melting points exceeding 100 ° C include low density polyethylene, super-high molecular weight polyethylene, polypropylene, propylene copolymer with vinyl acetate, polyvinyl chloride and thermoplastic polyurethane, in addition to these include the modifiers of the selected polymer are a group of polyorganosiloxanes, including polymethylsiloxane, polymethylphenylsiloxane, polyphenylsiloxane and polyethylphenylsiloxane.

Notranji sloj ovoja (3) se pridobi iz večkomponentnega homogenega sistema z mešanjem vsaj enega staljenega polimera ali pa mešanice dveh polimerov, izbranih iz omenjene skupine termoplastičnih polimerov v količini 99,3 - 99,7 masnih % relativno glede na celotno maso notranjega sloja ovoja skupaj s poliorganosiloksanom v količini 0,3 - 0,7 masnih % relativno glede na celotno maso notranjega ovoja (3).The inner layer of the sheath (3) is obtained from a multi-component homogeneous system by mixing at least one molten polymer or a mixture of two polymers selected from said group of thermoplastic polymers in an amount of 99.3-99.7% by weight relative to the total weight of the inner layer of the sheath together with polyorganosiloxane in an amount of 0.3-0.7% by weight relative to the total weight of the inner sheath (3).

Kot izbrani termoplastični polimer je mogoče uporabiti polietilen nizke gostote, kot poliorganosiloksan pa polimetilsiloksan.Low density polyethylene can be used as the selected thermoplastic polymer and polymethylsiloxane as polyorganosiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti tudi super-visoko-molekularni polietilen, kot poliorganosiloksan pa polimetilsiloksan.Super-high molecular weight polyethylene can also be used as the selected thermoplastic polymer and polymethylsiloxane as polyorganosiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti tudi polipropilen, kot poliorganosiloksan pa polifenilsiloksan. Kot izbrani termoplastični polimer je mogoče uporabiti kopolimer propilena vinilacetatom, kot poliorganosiloksan pa polimetilfenilsiloksan.Polypropylene may be used as the selected thermoplastic polymer and polyphenylsiloxane as polyorganosiloxane. The selected thermoplastic polymer can be used as a copolymer of propylene with vinyl acetate, and polyorganosiloxane as polymethylphenylsiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti polivinilklorid, kot poliorganosiloksan pa polietilfenilsiloksan.Polyvinyl chloride can be used as the selected thermoplastic polymer and polyethylphenylsiloxane as polyorganosiloxane.

Termoplastični polimer je tudi termoplastični uretan, kjer se kot poliorganosiloksan lahko uporabi polimetilfenilsiloksan.Thermoplastic polymer is also thermoplastic urethane where polymethylphenylsiloxane can be used as a polyorganosiloxane.

Poleg tega je kot mešanico dveh izbranih termoplastičnih polimerov mogoče uporabiti polietilen nizke gostote, v količini 5-95 masnih % in polipropilen v količini 4,3 94,7 masnih %, relativno glede na celotno maso notranjega ovoja (3), kot poliorganosiloksan pa uporabimo polifenilsiloksan.In addition, low density polyethylene in the amount of 5-95% by weight and polypropylene in the amount of 4.3 94.7% by weight relative to the total weight of the inner shell (3) can be used as a mixture of the two selected thermoplastic polymers, as polyorganosiloxane. polyphenylsiloxane.

Kot mešanico dveh izbranih termoplastičnih polimerov je mogoče uporabiti tudi mešanico super-visoko-molekularnega polietilena v količini 5-95 masnih % ter kopolimer propilena z vinilacetatom v količini 4,3 - 94,7 masnih %, relativno glede na maso notranjega ovoja (3), kot poliorganosiloksan pa uporabimo polietilfenilsiloksan.A mixture of two selected thermoplastic polymers can also be used with a mixture of super-high molecular weight polyethylene in an amount of 5-95% by weight, and a copolymer of propylene with vinyl acetate in an amount of 4.3-94.7% by weight, relative to the weight of the inner sheath (3) , and polyethylphenylsiloxane is used as the polyorganosiloxane.

Kot mešanico dveh izbranih termoplastičnih polimerov je mogoče uporabiti tudi mešanico polivinilklorida v količini 5As a blend of two selected thermoplastic polymers, a polyvinyl chloride blend of 5 can also be used

- 95 masnih % ter termoplastičnegapoliuretana v količini 4,3- 95% by weight and thermoplastic polyurethane in an amount of 4,3

- 94,7 masnih %, relativno glede na maso notranjega ovoja (3), kot poliorganosiloksan pa uporabimo polimetilfenilsiloksan ali polietilfenilsiloksan.- 94,7% by weight relative to the weight of the inner sheath (3), using polymethylphenylsiloxane or polyethylphenylsiloxane as polyorganosiloxane.

Zunanji sloj ovoja (2) je zgrajen iz polietilena ali večslojnega polietilen-poliamidnega sloja.The outer layer of the sheath (2) is constructed of polyethylene or a multi-layer polyethylene-polyamide layer.

Glavni ojačevalni sloj (4) je narejen iz sintetičnega vlaknastega netkanega materiala, kakršni so na primer sintetični polst osnovan na poliestru in/ali polipropilenskih vlaken.The main reinforcement layer (4) is made of synthetic fibrous non-woven material such as, for example, synthetic felt based on polyester and / or polypropylene fibers.

Dodatni ojačevalni sloj (5) je zgrajen iz sintetičnega polsta na osnovi poliestra in/ali polipropilenskih vlaken, steklenih vlaken, steklenega pletiva, kombinacije steklenih materialov, mreže termoplastičnih vlaken ali mreže ogljikovih vlaken.The additional reinforcement layer (5) is constructed of a synthetic felt based on polyester and / or polypropylene fibers, glass fibers, glass knitting, a combination of glass materials, a thermoplastic fiber network or a carbon fiber network.

Kot polimerno vezivno sredstvo se uporablja poliester, epoksi, epoksipoliestersko vezivo, poliestersko vezivo, ojačano z aerosilom in/ali magnezijevim oksidom.Polyester, epoxy, epoxy polyester binder, aerosil and / or magnesium reinforced polyester binder are used as the polymer binder.

V skladu z eno izmed različic implementacije postopka po predmetnem izumu se stranska robova (6 in 7) plasti ovoja, skupaj z glavnim ojačevalnim slojem (4), ki je s predhodnjima zlepljen, povezujeta s stikanjem robov, kot je prikazano na slikah 1 do 5, v skladu z drugo različico, pa se omenjena robova prekrivata, kot je prikazano na slikah 6 in 7.According to one embodiment of the process of the present invention, the side edges (6 and 7) of the envelope layer, together with the main reinforcement layer (4) previously bonded, are coupled to the edge contact as shown in Figures 1 to 5 , according to the second version, however, said edges overlap as shown in Figures 6 and 7.

Na slikah 8 in 9 sta prikazani različici tega izuma, kjer je med dodatnim ojačevalnim slojem (5) in zunanjim slojem ovoja (2) postavljen še en dodaten ojačevalni sloj (11), na sliki 9 pa je poleg tega še četrti ojačevalni sloj (12), ki je postavljen na vrhu ojačevalnega sloja (11). Sloja (11 in 12) sta narejena tako, kot je bilo že opisano zgoraj.Figures 8 and 9 show variants of the present invention, where another additional reinforcement layer (11) is placed between the additional reinforcing layer (5) and the outer layer of the wrapper (2), and in addition, a fourth reinforcing layer (12) ), which is placed at the top of the amplifier layer (11). The layers (11 and 12) are made as described above.

Čeprav so različice implementacije plašča in postopek za uporabo tega, v skladu s tem izumom, že bile opisane zgoraj in kjer so bile predstavljene različice z enim, dvema ali tremi dodatnimi ojačevalnimi sloji in notranjim slojem ovoja, ki je bil s predhodnjimi povezan in so bili ločeni le na enem mestu soosno osi poteka takega ovoja, pa to ne omejuje obsega predmetnega izuma, ki je formuliran v patentnih zahtevkih.Although the coat implementation variants and method for using this according to the present invention have already been described above and where variants with one, two or three additional reinforcement layers and an inner layer of the former associated with the prior art have been presented separated at only one location by the coaxial axis of such a sheath, this does not limit the scope of the present invention formulated in claims.

Spodaj sta opisana delno dokončan del zgoraj omenjanega plašča in postopek za izdelavo tega glede na izum. Patentirani dvoslojni polizdelek na sliki 10 in 11 zgoraj omenjenega ovoja na slikah 1 do 9 notranje površine cevi, vsebuje ojačevalni sloj 4, ki je povezan z notranjim slojem ovoja (3) in je narejen na osnovi termoplastičnega polimernega materiala. Notranji sloj ovoja (3) je oblikovan z večkomponentnim homogenim sistemom, ki vsebuje vsaj en polimer, izbran iz skupine termoplastičnih polimerov, ki imajo koeficient relativnega raztezanja večji od 200% in točko tališča nad 100°C, ter strukturnega modifikatorja izbranega polimera. Notranji sloj ovoja (3) je skupaj z ojačevalnim slojem (4), povezan tako, da je prekinjen na vsaj enem mestu vzdolž vzporedne osi poteka ovoja, ta ločena robova (6 in 7) pa sta hermetično povezana skupaj, s čimer oblikujeta vzdolž vzporedne osi postavljen in medsebojno povezan ojačevalni sloj (4) in notranji sloj ovoja (3). Skupina termoplastičnih polimerov, katerih koeficienti relativnega raztezanja presegajo 200% in katerih točke taljenja presegajo 100°C, vključuje polietilene nizke gostote, super-visoko-molekularni polietilen, polipropilen, kopolimer propilena z vinilacetatom, polivinilklorid in termoplastični poliuretan, kot strukturni modifikator izbranega polimera pa se uporablja skupina poliorganosiloksanov, med katerimi so polimetilsiloksan, polimerilfenilsiloksan, polifenilsiloksan in polietilfenilsiloksan.The partially completed part of the coat mentioned above and the process for making this according to the invention are described below. The patented two-layer semi-finished product in FIGS. 10 and 11 of the aforementioned envelope in FIGS. 1 to 9 of the inner surface of the tube comprises a reinforcement layer 4 connected to the inner layer of the envelope (3) and made on the basis of thermoplastic polymeric material. The inner layer of the sheath (3) is formed by a multi-component homogeneous system containing at least one polymer selected from the group of thermoplastic polymers having a relative elongation coefficient greater than 200% and a melting point above 100 ° C, and a structural modifier of the selected polymer. The inner layer of the sheath (3) is coupled with the reinforcement layer (4) so as to be interrupted in at least one location along the parallel axis of the sheath, and these separate edges (6 and 7) are hermetically sealed together, forming along the parallel axles positioned and interconnected reinforcement layer (4) and inner layer of envelope (3). A group of thermoplastic polymers having relative elongation coefficients exceeding 200% and melting points exceeding 100 ° C include low density polyethylene, super-high molecular weight polyethylene, polypropylene, a copolymer of propylene with vinyl acetate, polyvinyl chloride and thermoplastic polyurethane, as well as structured polyurethane, a group of polyorganosiloxanes is used, including polymethylsiloxane, polymerylphenylsiloxane, polyphenylsiloxane and polyethylphenylsiloxane.

Notranja plast ovoja (3) je narejena z večkomponentnim homogenim sistemom, ki vsebuje en polimer ali mešanico dveh polimerov, izbranih iz zgornje skupine termoplastičnih polimerov v količini 99,3 - 99,7 masnih %, relativno glede na skupno maso notranje plasti ovoja, ter poliorganosiloksan v količini 0,3 - 0,7 masnih %, relativno glede na skupno maso notranje plasti ovoja (3).The inner layer of the sheath (3) is made up of a multi-component homogeneous system containing one polymer or a mixture of two polymers selected from the above group of thermoplastic polymers in an amount of 99.3 - 99.7% by weight relative to the total weight of the inner layer of the sheath, and polyorganosiloxane in an amount of 0.3-0.7% by weight relative to the total weight of the inner layer of the wrapper (3).

Kot izbrani termoplastični polimer je mogoče uporabiti polietilen nizke gostote, kot poliorganosiloksan pa polimetilsiloksan.Low density polyethylene can be used as the selected thermoplastic polymer and polymethylsiloxane as polyorganosiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti tudi super-visoko-molekularni polietilen, kot poliorganosiloksan pa polimetilsiloksan.Super-high molecular weight polyethylene can also be used as the selected thermoplastic polymer and polymethylsiloxane as polyorganosiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti polipropilen, kot poliorganosiloksan pa polifenilsiloksan. Kot izbrani termoplastični polimer je mogoče uporabiti kopolimer propilena z vinilacetatom, kot poliorganosiloksan pa polietilfenilsiloksan.Polypropylene can be used as the selected thermoplastic polymer and polyphenylsiloxane as polyorganosiloxane. As the selected thermoplastic polymer, a copolymer of propylene with vinyl acetate can be used, and polyorganosiloxane as polyethylphenylsiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti polivinilklorid, kot poliorganosiloksan pa polietilfenilsiloksan, kakor tudi termoplastičen poliuretan na mestu termoplastičnega poliuretana, ter polimetilfenilsiloksan kot poliorganosiloksan.Polyvinyl chloride can be used as the selected thermoplastic polymer, poly-organosiloxane as polyethylphenylsiloxane as well as thermoplastic polyurethane in place of thermoplastic polyurethane, and polymethylphenylsiloxane as poly-organosiloxane.

Poleg tega je kot mešanico dveh izbranih termoplastičnih polimerov mogoče uporabiti polietilen nizke gostote, v količini 5-95 masnih % in polipropilen v količini 4,3 94,7 masnih %, relativno glede na celotno maso notranje plasti ovoja, kot poliorganosiloksan pa uporabimo polifenilsiloksan.In addition, low density polyethylene in the amount of 5-95% by weight and polypropylene in the amount of 4.3 94.7% by weight can be used as a mixture of the two selected thermoplastic polymers, relative to the total weight of the inner layer of the wrapper, and polyphenylsiloxane is used as the polyorganosiloxane.

Kot mešanico dveh izbranih termoplastičnih polimerov je mogoče uporabiti tudi mešanico super-visoko-molekularnega polietilena v količini 5-95 masnih % ter kopolimer propilena z vinilacetatom v količini 4,3 - 94,7 masnih %, relativno glede na maso notranje plasti ovoja, kot poliorganosiloksan pa uporabimo polietilfenilsiloksan.As a mixture of two selected thermoplastic polymers, a mixture of super-high molecular weight polyethylene in the amount of 5-95% by weight and a copolymer of propylene with vinyl acetate in the amount of 4.3-94.7% by weight, relative to the weight of the inner layer of the wrapper, can also be used. and polyorganosiloxane uses polyethylphenylsiloxane.

Kot mešanico dveh izbranih termoplastičnih polimerov je mogoče uporabiti tudi mešanico polivinilklorida v količini 5As a blend of two selected thermoplastic polymers, a polyvinyl chloride blend of 5 can also be used

- 95 masnih % ter termoplastičnegapoliuretana v količini 4,3- 95% by weight and thermoplastic polyurethane in an amount of 4,3

- 94,7 masnih %, relativno glede na maso notranje plasti ovoja, kot poliorganosiloksan pa uporabimo polimetilfenilsiloksan ali polietilfenilsiloksan.- 94,7% by weight, relative to the weight of the inner layer of the wrapper, using polymethylphenylsiloxane or polyethylphenylsiloxane as polyorganosiloxane.

Ojačevalni sloj (5) je izdelan iz sintetičnega netkanega vlaknastega materiala, na primer iz sintetičnega polsta, pridobljenega na osnovi poliestrskih in/ali polipropilenskih vlaken.The reinforcement layer (5) is made of synthetic non-woven fibrous material, for example, of synthetic felt obtained on the basis of polyester and / or polypropylene fibers.

Ločena robova (6 in 7) notranjega cevastega sloja ovoja (3), ki je povezan z ojačevalnim slojem (4), sta hermetično zaprta drug z drugim soosno osi, kot je prikazano na sliki 10, pričvrščena pa sta s šivanjem ali varjenjem.The separate edges (6 and 7) of the inner tubular layer of the sheath (3) connected to the reinforcing layer (4) are sealed with each other to the coaxial axes, as shown in Figure 10 and secured by sewing or welding.

Ločena robova (6 in 7) notranjega cevastega sloja ovoja (3), ki je povezan z ojačevalnim slojem (4), se lahko hermetično povežeta drug z drugim tako, da se v osi dvoslojnega polizdelka ovoja prekrivata, kot je prikazano na sliki 11, nato pa se na tem mestu taka robova zašijeta ali zavarita, nakar se na to območje z notranje površine notranjega sloja ovoja (3) privari trak (8), katerega material je identičen materialu, ki tvori notranji sloj ovoja (3).The separate edges (6 and 7) of the inner tubular layer of the wrapper (3) connected to the reinforcing layer (4) can be hermetically connected to each other by overlapping in the axis of the bilayer semi-finished product, as shown in Figure 11, then such edges are sewn or welded at this point, and then a strip (8) is welded to this area from the inner surface of the inner layer of the wrapper (8), the material of which is identical to the material forming the inner layer of the wrapper (3).

Postopek za izdelavo dvoslojnega polizdelka omenjenega plašča notranje površine cevi, po predmetnem izumu, je sestavljen iz notranjega sloja ovoja cevi (3), ki je narejen na osnovi termoplastičnega polimernega materiala in je povezan z ojačevalnim slojem (4). Notranji cevasti sloj (3) je izdelan iz pole filma, pridobljenega iz večkomponentnega homogenega sistema s pomočjo mešanja enega ali dveh polimerov v staljenem stanju, kjer sta polimera izbrana iz skupine termoplastičnih polimerov, katerih relativni koeficient raztezanja ne pada pod 200%, točke vrelišča pa so večje od 100°C in strukturnega modifikatorja izbranega polimera. Taka pola filma se nato poveže s polo materiala, ki oblikuje ojačevalni sloj (4), nato pa se stranska robova (6 in 7) te pole filma, skupaj s povezanim ojačevalnim slojem (4), povežeta hermetično druga z drugo, s čimer dobimo dvoslojni delno dokončani del plašča, ki je postavljen vzporedno glede na potek osi in je povezan z ojačevalnim slojem (4) in notranjim cevastim slojem ovoja (3) .The method for manufacturing a two-layer semi-finished product of said inner tube surface coat according to the present invention consists of an inner tube tube layer (3) made on the basis of a thermoplastic polymer material and connected to the reinforcement layer (4). The inner tubular layer (3) is made of a sheet of film obtained from a multicomponent homogeneous system by mixing one or two polymers in a molten state, where the polymers are selected from the group of thermoplastic polymers whose relative elongation coefficient does not fall below 200% and the boiling points are greater than 100 ° C and the structural modifier of the selected polymer. Such a pole of the film is then bonded to the polo of the material forming the reinforcement layer (4), and then the lateral edges (6 and 7) of this pole of the film, together with the associated reinforcing layer (4), are hermetically connected to each other, thereby obtaining a two-layer partially finished portion of the jacket, arranged parallel to the axis of the axle and connected to the reinforcing layer (4) and the inner tubular layer of the sheath (3).

Skupina termoplastičnih polimerov, katerih koeficienti relativnega raztegovanja ne padejo pod 200% in katerih tališčne točke segajo nad 100°C, vključujejo polietilen nizke gostote, super-visoko-molekularen polietilen, polipropilen, kopolimer propilena z vinilacetatom, polivinilklorid in termoplastičen poliuretan, kot strukturni modifikator izbranega polimera pa uporabljamo poliorganosiloksane, med katere uvrščamo tudi polimetilsiloksan, polimetilfenilsiloksan, polifenilsiloksan in polietilfenilsiloksan.A group of thermoplastic polymers whose relative elongation coefficients do not fall below 200% and whose melting points reach above 100 ° C include low density polyethylene, super-high molecular weight polyethylene, polypropylene, propylene copolymer with vinyl acetate, polyvinyl chloride and thermoplastic polyurethane polyurethane, of the selected polymer, polyorganosiloxanes are used, including polymethylsiloxane, polymethylphenylsiloxane, polyphenylsiloxane and polyethylphenylsiloxane.

Notranji sloj ovoja (3) je izdelan s pomočjo večkomponentnega homogenega sistema z mešanjem enega ali dveh staljenih polimerov, ki sta bila izbrana iz zgoraj omenjene skupine termoplastičnih polimerov v količini 99,3 99,7 masnih %, relativno glede na celotno maso notranjega sloja ovoja, ter poliorganosiloksan v količini 0,3 - 0,7 masnih %, relativno glede na celotno maso notranjega sloja ovoja (3).The inner layer of the sheath (3) is made by means of a multi-component homogeneous system by mixing one or two molten polymers selected from the above-mentioned group of thermoplastic polymers in an amount of 99.3 99.7% by weight relative to the total weight of the inner layer of the sheath , and polyorganosiloxane in an amount of 0.3-0.7% by weight relative to the total weight of the inner layer of the sheath (3).

Kot izbrani termoplastični polimer je mogoče uporabiti polietilen nizke gostote, kot poliorganosiloksan pa polimetilsiloksan.Low density polyethylene can be used as the selected thermoplastic polymer and polymethylsiloxane as polyorganosiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti tudi super-visoko-molekularni polietilen, kot poliorganosiloksan pa polimetilsiloksan.Super-high molecular weight polyethylene can also be used as the selected thermoplastic polymer and polymethylsiloxane as polyorganosiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti polipropilen, kot poliorganosiloksan pa polifenilsiloksan. Kot izbrani termoplastični polimer je mogoče uporabiti kopolimer propilena z vinilacetatom, kot poliorganosiloksan pa polietilfenilsiloksan.Polypropylene can be used as the selected thermoplastic polymer and polyphenylsiloxane as polyorganosiloxane. As the selected thermoplastic polymer, a copolymer of propylene with vinyl acetate can be used, and polyorganosiloxane as polyethylphenylsiloxane.

Kot izbrani termoplastični polimer je mogoče uporabiti polivinilklorid, kot poliorganosiloksan pa polietilfenilsiloksan, kakor tudi termoplastičen poliuretan na mestu termoplastičnega poliuretana, ter polimetilfenilsiloksan kot poliorganosiloksan.Polyvinyl chloride can be used as the selected thermoplastic polymer, poly-organosiloxane as polyethylphenylsiloxane as well as thermoplastic polyurethane in place of thermoplastic polyurethane, and polymethylphenylsiloxane as poly-organosiloxane.

Poleg tega je kot mešanico dveh izbranih termoplastičnih polimerov mogoče uporabiti polietilen nizke gostote, v količini 5-95 masnih % in polipropilen v količini 4,3 94,7 masnih %, relativno glede na celotno maso notranje plasti ovoja, kot poliorganosiloksan pa uporabimo polifenilsiloksan.In addition, low density polyethylene in the amount of 5-95% by weight and polypropylene in the amount of 4.3 94.7% by weight can be used as a mixture of the two selected thermoplastic polymers, relative to the total weight of the inner layer of the wrapper, and polyphenylsiloxane is used as the polyorganosiloxane.

Kot mešanico dveh izbranih termoplastičnih polimerov je mogoče uporabiti tudi mešanico super-visoko-molekularnega polietilena v količini 5-95 masnih % ter kopolimer propilena z vinilacetatom v količini 4,3 - 94,7 masnih %, relativno glede na maso notranje plasti ovoja, kot poliorganosiloksan pa uporabimo polietilfenilsiloksan.As a mixture of two selected thermoplastic polymers, a mixture of super-high molecular weight polyethylene in the amount of 5-95% by weight and a copolymer of propylene with vinyl acetate in the amount of 4.3-94.7% by weight, relative to the weight of the inner layer of the wrapper, can also be used. and polyorganosiloxane uses polyethylphenylsiloxane.

Kot mešanico dveh izbranih termoplastičnih polimerov je mogoče uporabiti tudi mešanico polivinilklorida v količiniAs a blend of two selected thermoplastic polymers, it is also possible to use a mixture of polyvinyl chloride in an amount of

5-95 masnih % ter termoplastičnegapoliuretana v količini5-95% by weight and thermoplastic polyurethane in an amount

4,3 - 94,7 masnih %, relativno glede na maso notranje plasti ovoja, kot poliorganosiloksan pa uporabimo polimetilfenilsiloksan ali polietilfenilsiloksan.4.3 to 94.7% by weight relative to the weight of the inner layer of the envelope, using polymethylphenylsiloxane or polyethylphenylsiloxane as polyorganosiloxane.

Ojačevalni sloj (4) je izdelan iz sintetičnega vlaknastega netkanega materiala, na primer iz sintetičnega polsta, pridobljenega na osnovi poliesterskih in/ali polipropilenskih vlaken.The reinforcement layer (4) is made of synthetic fibrous non-woven material, for example synthetic felt obtained on the basis of polyester and / or polypropylene fibers.

Stranska robova (6 in 7) ovoja, ki sta povezana z ojačevalnim slojem 4, sta medsebojno hermetično povezana preko stikanja robov, kot je prikazano na sliki 10, s pomočjo varjenja, kjer se nato na notranji plasti ovoja privari trak (8) iz materiala, identičnega materialu notranjega sloja ovoja (3).The lateral edges (6 and 7) of the envelope, which are connected to the reinforcing layer 4, are sealed to one another by contacting the edges, as shown in Figure 10, by welding, where a material strip (8) is then welded to the inner layer of the envelope. , identical to the material of the inner layer of the sheath (3).

Čeprav so bile različice implementacije patentiranega dvoslojnga polizdelka plašča, v skladu s tem izumom, že opisane, in je bil prav tako predstavljen tudi postopek za izdelavo tega delno dokončanega dela, kjer pride do implementacije notranjega ovoja skupaj z ojačevalnim slojem, ki je od predhodnega ločen le na enem samem mestu na vzporedno osi, to ne omejuje naših pravic, ki so formulirane v patentnih zahtevkih.Although embodiments of the patented two-layer semi-finished coat according to the present invention have already been described, a process for producing this partially completed work has also been presented, wherein the implementation of the inner jacket together with the reinforcement layer is separated from the previous only one position on the parallel axis does not limit our rights as formulated in the claims.

Spodaj so opisani določeni primeri implementacije patentiranega plašča, uporabljenega z metodo v skladu z izumom, v katerih bo podrobno opisan tudi patentirani polizdelek plašča, pridobljen s postopkom, ki je v skladu z izumom.Below are some examples of implementation of a patented coat used by the method according to the invention, which will also detail the patented semi-finished coat obtained by the method according to the invention.

Primer 1Example 1

Zunaj cevi 1 (sl. 1 in 2) sta soosno postavljena zunanji cevasti sloj ovoja (2) iz termoplastičnega materiala, še posebej polietilena, ter notranji cevasti sloj ovoja (3). Poleg teh je tu postavljen tudi glavni ojačevalni sloj (4), ki je vstavljen med zunanji (2) in notranji sloj (3) in z njima oblikuje dvoslojni delno dokončani del plašča cevi.Outside of tube 1 (Figures 1 and 2), the outer tubular layer of the sheath (2) of thermoplastic material, especially polyethylene, and the inner tubular layer of the sheath (3) are coaxially positioned. In addition, a main reinforcement layer (4) is inserted here, inserted between the outer (2) and the inner layer (3), forming with them a two-layer partially finished part of the tube jacket.

Za izdelavo notranjega ovoja cevi (3) takega polizdelka, se uporabi pola materiala, pridobljena na osnovi termoplastičnega polimernega materiala, oziroma homogenega sistema, ki ga dobimo z mešanjem staljenega polietilena nizke gostote v količini 99,7 masnih %, relativno glede na celotno maso notranjegasloja (3), ter strukturnega modifikatorja izbranega polimea -polimetilsiloksan v količini 0,3 masnih %, relativno glede na celotno maso notranjega sloja ovoja (3). Pola materiala se poveže s pomočjo valjanja s polo ojačevalnega sloja (4) sintetičnega vlaknastega netkanega materiala, iz sintetičnega polsta osnovanega na poliesterskih vlaknih; stranska robova (6 in 7) povezanih pol sta prišita tako, da se robova stikata drug drugega, omenjeno območje pa je na strani notranjega sloja ovoja (3) zaprto oziroma zavarjeno s trakom (8), ki je narejen iz istega materiala kot notranji sloj ovoja (3).For the manufacture of the inner tube sheath (3) of such a semi-finished product, a pole of material obtained from a thermoplastic polymeric material, or a homogeneous system, obtained by mixing molten low density polyethylene in an amount of 99.7% by weight relative to the total weight of the inner layer, is used (3), and the structural modifier of the selected polymer-polymethylsiloxane in an amount of 0.3% by weight, relative to the total weight of the inner layer of the wrapper (3). The half of the material is joined by rolling from the polo reinforcement layer (4) of synthetic fibrous non-woven material, made of synthetic felt based on polyester fibers; the lateral edges (6 and 7) of the connected poles are sewn so that the edges contact each other, and said area is closed or welded on the side of the inner layer of the wrapper (3) by a strip (8) made of the same material as the inner layer sheath (3).

Tako dobimo dvoslojni delno dokončni del celotnega plašča cevi (slika 10).This gives a two-layer partially definitive part of the entire tube sheath (Figure 10).

Med zunanjo cevasto plastjo (2) in glavnim ojačevalnim slojem (4) je postavljen dodatni ojačevalni sloj (5) iz steklenih vlaken.An additional fiberglass reinforcement layer (5) is placed between the outer tubular layer (2) and the main reinforcement layer (4).

Glavni sloj (4) in dodatni ojačevalni sloj (5) sta impregnirana z vezivnim sredstvom, tvorj enim na osnovi nenasičenih poliesterskih smol.The main layer (4) and the additional reinforcement layer (5) are impregnated with a binder formed on the basis of unsaturated polyester resins.

Tako dobljena struktura večplastnega delno dokončanega dela plašča se vstavi v notranjost cevi (1), ki se jo popravlja ali na novo postavlja, vstavimo pa jo s pomočjo posebnih naprav in napeljav (ni prikazano na slikah). Deformiranju, zvijanju ali uničenju notranjega sloja ovoja (3) se izognemo zaradi povezave slednjega z glavnim ojačevalnim slojem (4) v opisanem dvoslojnem polizdelku (slika 10) ovoja, izdelanem na način, ki je predmet tega izuma.The structure of the multilayered partially finished part of the jacket thus obtained is inserted into the interior of the pipe (1), which is being repaired or re-erected, and is inserted by means of special devices and installations (not shown in the figures). Deforming, twisting or destroying the inner layer of the envelope (3) is avoided due to the connection of the latter with the main reinforcing layer (4) in the described two-layer semi-finished product (Figure 10) made in the manner that is the subject of the present invention.

Vpeljava nosilca toplote v notranjost notranjega sloja ovoja (3) in utrjevanje vezivnega sredstva se opravi pri naslednjih pogojih:The insertion of the heat carrier into the inner layer of the sheath (3) and the curing of the binder are carried out under the following conditions:

- nosilec toplote - nasičena vodna para- heat carrier - saturated water vapor

- temperatura nosilca toplote - 100°C- temperature of heat carrier - 100 ° C

- tlak 0,05 MPa- pressure 0,05 MPa

- čas utrjevanja - 2 uri.- Hardening time - 2 hours.

Kot rezultat nastane monolitna struktura notranjega sloja ovoja (3), skupaj z glavnim ojačevalnim slojem (4), kar vodi do znatnega povišanja kvalitete plašča, uporabljenega s tem postopkom, ter posledično, povišanje operativnih lastnosti cevi zaradi visokih fizičnih in mehanskih karakteristik plašča, hidrostabilnosti in kemične odpornosti:The result is a monolithic structure of the inner layer of the sheath (3), together with the main reinforcing layer (4), which leads to a significant increase in the quality of the jacket used by this process and, consequently, an increase in the operational properties of the pipe due to the high physical and mechanical characteristics of the jacket, its hydro-stability. and chemical resistance:

rušilni tlak na zavoju, MPa: 140 - 200; odpornost na luščenje, MPa: 8 - 12; absorbnost vode, masni %: 0,4 - 0,5;breaking pressure at turn, MPa: 140 - 200; peeling resistance, MPa: 8 - 12; water absorption,% by weight: 0.4 - 0.5;

odpornost na 10% H2SO4 - uničenje patentiranega plašča se ne zgodi med 1 mesečno ekspozicijo pri temperaturi 20 22°C.resistance to 10% H 2 SO 4 - destruction of the patented coat does not occur during the 1 month exposure at 20 22 ° C.

Primer 2Example 2

Proces se izvede podobno kot v primeru 1.The process is carried out similarly to Example 1.

Za plašč so uporabljeni enaki materiali kot v primeru 1, z izjemo materiala notranjega sloja ovoja (3) in dodatnega ojačevalnega sloja (5).The same materials as in Example 1 are used for the jacket, with the exception of the material of the inner layer of the sheath (3) and the additional reinforcement layer (5).

Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje polietilen nizke gostote v količini 99,5 masnih %, relativno glede na celotno maso notranjega sloja ovoja (3), ter polimetilsiloksan v količini 0,5 masnih %, relativno glede na maso notranjega sloja ovoja (3).The inner layer of the sheath (3) is formed by a homogeneous system containing low density polyethylene in an amount of 99.5% by weight relative to the total weight of the inner layer of the sheath (3) and polymethylsiloxane in an amount of 0.5% by weight relative to the mass of the inner layer of the sheath (3).

Dodatni ojačevalni sloj (5) je izdelan iz sintetičnega polsta na osnovi poliesterskih vlaken.The additional reinforcement layer (5) is made of a synthetic polyester fiber based felt.

Med dodatnim ojačevalnim slojem (5) (slika 8) in soosno postavljenim zunanjim slojem ovoja (2), je postavljen dodatni ojačevalni sloj (11) iz sintetičnega polsta na osnovi poliesterskih vlaken.Between the additional reinforcement layer (5) (Figure 8) and the coaxially positioned outer layer of the sheath (2), an additional reinforcing layer (11) of polyester fiber based synthetic felt is placed.

Pogoji utrjevanja so enaki kot v primeru (1), z izjemo časa utrjevanja, ki znaša 3,5 ur.The curing conditions are the same as in Example (1), with the exception of the curing time of 3.5 hours.

Dobljeni rezultati so enaki tistim iz primera 1.The results obtained are the same as those of Example 1.

Primer 3Example 3

Proces se izvede na podoben način kot v primeru 2.The process is carried out in the same way as in Example 2.

Uporabijo se enaki materiali kot v primeru 1, z izjemo materiala notranjega sloja ovoja (3) in dodatnega ojačevalnega sloja (5).The same materials as in Example 1 are used, with the exception of the material of the inner coating layer (3) and the additional reinforcing layer (5).

Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje polietilen nizke gostote v količini 99,3 masnih %, relativno glede na celotno maso notranjega sloja ovoja (3), ter polimetilsiloksan v količini 0,7 masnih %, relativno glede na celotno maso notranjega sloja (3). Dodatni ojačevalni sloj (5) je narejen iz mreže ogljikovih vlaken.The inner layer of the sheath (3) is formed by a homogeneous system containing low density polyethylene in an amount of 99.3% by weight relative to the total weight of the inner layer of the sheath (3) and polymethylsiloxane in an amount of 0.7% by weight relative to the total mass of the inner layer (3). The additional reinforcement layer (5) is made of carbon fiber mesh.

Pogoji utrjevanja so enaki kot v primeru 2, z izjemo temperature nosilca toplote, ki znaša 90°C.The curing conditions are the same as in Example 2, except for the heat carrier temperature of 90 ° C.

Dobljeni rezultati so enaki kot v primeru 1.The results obtained are the same as in Example 1.

Primer 4Example 4

Proces se izvede na podoben način kot v primeru 1, z izjemo faze hermetičnega povezovanja stranskih robov (6 in 7) in sintetičnih netkanega materialov, ki so narejeni s pomočjo varjenja robov (6 in 7) tako, da se robova stikata.The process is carried out in the same way as in Example 1, except for the phase of sealing the side edges (6 and 7) and the synthetic nonwovens made by welding the edges (6 and 7) by contacting the edges.

Za plašč so bili uporabljeni isti materiali kot v primeru 1 z izjemo materiala za notranji sloj ovoja (3) in vezivnega sredstva.The same materials were used for the jacket as in Example 1 with the exception of the material for the inner lining (3) and the binder.

Notranji sloj ovoja (3) je oblikovan iz homogenega sistema, in vsebuje super-visoko gost polietilen v količini 99,7 masnih % relativno glede na maso celotnega notranjega sloja (3) , kot strukturni modifikator polimera pa se uporabi polimetilsiloksan v količini 0,3 masnih %, relativno glede na maso celotnega notranjega sloja (3).The inner layer of the sheath (3) is formed from a homogeneous system and contains super-dense polyethylene in an amount of 99.7% by weight relative to the weight of the entire inner layer (3), and polymethylsiloxane in an amount of 0.3 is used as a structural modifier of the polymer % by weight relative to the weight of the entire inner layer (3).

Epoksipoliesterska vez se uporabi za impregnacijo ojačevalnega sloja (4 in 5).The epoxy polyester bond is used to impregnate the reinforcement layer (4 and 5).

Pogoji utrjevanja so enaki kot v primeru 3, z izjemo tlaka pare, ki znaša 0,07 Mpa.The curing conditions are the same as in Example 3, with the exception of the vapor pressure of 0.07 Mpa.

Rezultati so enaki kot v primeru 1.The results are the same as in Example 1.

Primec 5Example 5

Proces se izvede na enak način kot v primeru 4.The process is performed in the same way as in Example 4.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 4, z izjemo materiala notranjega sloja ovoja (3) in materiala za dodatni ojačevalni sloj (5).The same materials as in Example 4 are used for the design of the jacket, with the exception of the inner layer material (3) and the additional reinforcement layer material (5).

Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje super-visoko gost polietilen v količini 99,5 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polimetilsiloksan v količini 0,5 masnih %, relativno glede na maso notranjega sloja (3).The inner layer of the sheath (3) is formed by a homogeneous system containing super-dense polyethylene in an amount of 99.5% by weight relative to the weight of the inner layer (3) and polymethylsiloxane in an amount of 0.5% by weight is used as a structural modifier % relative to the mass of the inner layer (3).

Dodatni ojačevalni sloj (5) je narejen iz mreže poliesterskih vlaken.The additional reinforcement layer (5) is made of a polyester fiber net.

Pogoji utrjevanja so enaki kot v primeru 4, z izjemo temperature nosilca toplote, ki znaša 800°C in tlaka pare, ki znaša 0,1 Mpa.The curing conditions are the same as in Example 4, except for the heat carrier temperature of 800 ° C and the steam pressure of 0.1 Mpa.

Rezultati so enaki kot v primeru 1.The results are the same as in Example 1.

Primer 6Example 6

Proces se izvede na enak način kot v primeru 4.The process is performed in the same way as in Example 4.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 4, z izjemo materiala notranjega sloja ovoja (3). Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje super-visoko gost polietilen v količini 99,3 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polimetilsiloksan v količini 0,7 masnih %, relativno glede na maso notranjega sloja (3).The same materials as in Example 4 are used for the design of the jacket, with the exception of the inner liner material (3). The inner layer of the sheath (3) is formed by a homogeneous system containing super-dense polyethylene in an amount of 99.3% by weight relative to the weight of the inner layer (3), and polymethylsiloxane in an amount of 0.7% by weight is used as a structural modifier % relative to the mass of the inner layer (3).

Dodatnega ojačevalnega sloja 5 v tem primeru ni.There is no additional reinforcement layer 5 in this case.

V cev se pred uporabo nosilca toplote uvaja zrak pri tlaku 0,01 Mpa v trajanju 20 minut, nato pa se uvede nosilec toplote za utrjevanje vezi, ki poteka enako kot v primeru 1. Rezultati so enaki kot v primeru 1.Prior to the use of the heat carrier, air is introduced into the pipe at a pressure of 0.01 Mpa for 20 minutes, and then the heat carrier is used to harden the bond, which is the same as in Example 1. The results are the same as in Example 1.

Primec 7Example 7

Proces se izvede na enak način kot v primeru 4.The process is performed in the same way as in Example 4.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 1, z izjemo materiala notranjega sloja ovoja (3) in materiala za glavni ojačevalni sloj (4).The same materials as in Example 1 are used for the design of the jacket, with the exception of the material of the inner coating layer (3) and the material for the main reinforcing layer (4).

Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje polipropilen v količini 99,7 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polifenilsiloksan v količini 0,7 masnih %, relativno glede na maso notranjega sloja (3). Glavni ojačevalni sloj (4) je narejen iz sintetičnega polsta osnovanega na polipropilenskih vlaknih.The inner layer of the sheath (3) is formed by a homogeneous system containing polypropylene in an amount of 99.7% by weight relative to the weight of the inner layer (3) and polyphenylsiloxane in an amount of 0.7% by weight relative to the weight to the mass of the inner layer (3). The main reinforcement layer (4) is made of a synthetic felt based on polypropylene fibers.

Pogoji utrjevanja so enaki kot v primeru 3, z izjemo tega, da je temperatura nosilca toplote 110°C.The curing conditions are the same as in Example 3 except that the heat carrier temperature is 110 ° C.

Rezultati so enaki kot v primeru 1.The results are the same as in Example 1.

Primer 8Example 8

Proces se izvede podobno kot v primeru 7, z izjemo stopnje hermetičnega povezovanja stranskih robov pol materiala za ovoj (6 in 7) ki se povežeta tako, da se robova prekrivata (sliki 7 in 11).The process is carried out similarly to Example 7, except for the degree of hermetic sealing of the side edges of the semi-wrapped material (6 and 7), which are joined so that the edges overlap (Figures 7 and 11).

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 7, z izjemo materiala notranjega sloja ovoja (3) in materiala za dodatni ojačevalni sloj (5).The same materials as in Example 7 are used for the design of the jacket, with the exception of the inner layer material (3) and the additional reinforcement layer material (5).

Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje polipropilen v količini 99,5 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polifenilsiloksan v količini 0,5 masnih %, relativno glede na maso notranjega sloja (3). Dodatni ojačevalni sloj (5) je narejen iz sintetičnega polsta na osnovi polipropilenskih vlaken.The inner layer of the sheath (3) is formed by a homogeneous system containing polypropylene in an amount of 99.5% by weight relative to the weight of the inner layer (3), and polyphenylsiloxane in an amount of 0.5% by weight relative to the weight is used as a structural modifier. to the mass of the inner layer (3). The additional reinforcement layer (5) is made of a polypropylene based synthetic felt.

Pogoji utrjevanja so enaki kot v primeru 7, z izjemo tega, da utrjevanje traja 5 ur.The curing conditions are the same as in Example 7 except that the curing lasts for 5 hours.

Rezultati so enaki kot v primeru 7.The results are the same as in Example 7.

Primer 9Example 9

Proces se izvede na podoben način kot v primeru 7.The process is carried out in a similar manner to Example 7.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 7, z izjemo materiala notranjega sloja ovoja (3). Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje polipropilen v količini 99,3 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polifenilsiloksan v količini 0,7 masnih %, relativno glede na maso notranjega sloja (3). Glavni ojačevalni sloj 4 je narejen iz sintetičnega polsta na osnovi polipropilenskih vlaken.The same materials as in Example 7 are used to form the jacket, with the exception of the material of the inner lining layer (3). The inner layer of the sheath (3) is formed by a homogeneous system containing polypropylene in an amount of 99.3% by weight relative to the weight of the inner layer (3), and polyphenylsiloxane in an amount of 0.7% by weight relative to the weight is used as a structural modifier. to the mass of the inner layer (3). The main reinforcement layer 4 is made of a synthetic polypropylene fiber based sheath.

Med dodatni ojačevalni sloj 5 (slika 8) in zunanji sloj ovoja 2, je postavljen še en dodaten ojačevalni sloj 11, narejen iz sintetičnega polsta na osnovi polipropilenskih vlaken, ki je prav tako postavljen soosno glede na potek osi cevi.Between the additional reinforcement layer 5 (Figure 8) and the outer layer of the sheath 2, another additional reinforcement layer 11 is made, made of a synthetic polypropylene fiber based sheath, which is also arranged coaxially with respect to the axis of the tube.

Pogoji utrjevanja so enaki kot v primeru 8, z izjemo tega, da je tlak 0,1 MPa.The curing conditions are the same as in Example 8, except that the pressure is 0.1 MPa.

Rezultati so enaki kot v primeru 7.The results are the same as in Example 7.

Primer 10Example 10

Proces se izvede na podoben način kot v primeru 9.The process is carried out in the same way as in Example 9.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 9, z izjemo materiala notranjega sloja ovoja (3), zunanjega sloja ovoja 2 in materiala za dodatne ojačevalne sloje 5 in 11.The same materials as in Example 9 are used to form the jacket, with the exception of the material of the inner coating layer (3), the outer coating layer 2 and the material for the additional reinforcing layers 5 and 11.

Zunanji sloj ovoja 2 je oblikovan iz večslojnega polietilenpoliamidnega filma.The outer layer of the sheath 2 is formed from a multilayer polyethylenepolyamide film.

Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje kopolimer propilena z vinilacetatom v količiniThe inner layer of the sheath (3) is formed by a homogeneous system containing a copolymer of propylene with vinyl acetate in an amount of

99,7 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polimetilfenilsiloksan v količini 0,3 masnih %, relativno glede na maso notranjega sloja (3).99.7% by weight relative to the weight of the inner layer (3) and polymethylphenylsiloxane in an amount of 0.3% by weight relative to the weight of the inner layer (3) is used as a structural modifier.

Glavni ojačevalni sloj (4) je narejen iz sintetičnega polsta na osnovi polipropilenskih vlaken.The main reinforcement layer (4) is made of a synthetic polypropylene fiber based sheath.

Dodatni ojačevalni sloj (5) je narejen iz steklenega pletiva. Dodatni ojačevalni sloj (11) je narejen iz mreže ogljikovih vlaken. Med zunanji sloj ovoja 2 (slika 9) in dodatni ojačevalni sloj 11 je postavljen še en dodaten ojačevalni sloj 12, narejen iz steklenih vlaken in je postavljen vzporedno s potekom osi cevi.The additional reinforcement layer (5) is made of glass knitting. The additional reinforcement layer (11) is made of carbon fiber mesh. Between the outer layer of the sheath 2 (Figure 9) and the additional reinforcement layer 11, another additional reinforcement layer 12 is made of fiberglass and is arranged parallel to the course of the axis of the tube.

Pogoji utrjevanja so enaki kot v primeru 8.The curing conditions are the same as in Example 8.

Rezultati so enaki kot v primeru 9.The results are the same as in Example 9.

Primer 11Example 11

Proces se izvede na podoben način kot v primeru 10.The process is carried out in the same way as in Example 10.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 10, z izjemo materiala notranjega sloja ovoja (3), materiala za dodatni ojačevalni sloj 5 in materiala za dodatni ojačevalni sloj 11.The same materials as in Example 10 are used for the design of the jacket, with the exception of the material of the inner coating layer (3), the material for the additional reinforcing layer 5 and the material for the additional reinforcing layer 11.

Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje kopolimer propilena z vinilacetatom v količiniThe inner layer of the sheath (3) is formed by a homogeneous system containing a copolymer of propylene with vinyl acetate in an amount of

99,5 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polimetilfenilsiloksan v količini 0,5 masnih %, relativno glede na maso notranjega sloja (3).99.5% by weight relative to the weight of the inner layer (3) and polymethylphenylsiloxane in an amount of 0.5% by weight relative to the weight of the inner layer (3) is used as a structural modifier.

Dodatni ojačevalni sloj (5) je narejen iz kombiniranega steklenega materiala. Dodatni ojačevalni sloj (11) je narejen iz sintetičnega polsta, izdelanega iz mešanice poliesterskih in polipropilenskih vlaken.The additional reinforcement layer (5) is made of combined glass material. The additional reinforcement layer (11) is made of a synthetic felt made from a mixture of polyester and polypropylene fibers.

Rezultati so enaki kot v primeru 10.The results are the same as in Example 10.

Primer 12Example 12

Proces se izvede na podoben način kot v primeru 10.The process is carried out in the same way as in Example 10.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 10, z izjemo materiala notranjega sloja ovoja (3), materiala za dodatni ojačevalni sloj (11) in materiala za dodatni ojačevalni sloj (12).The same materials as in Example 10 are used for the design of the jacket, with the exception of the material of the inner coating layer (3), the material for the additional reinforcing layer (11) and the material for the additional reinforcing layer (12).

Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje kopolimer propilena z vinilacetatom v količiniThe inner layer of the sheath (3) is formed by a homogeneous system containing a copolymer of propylene with vinyl acetate in an amount of

99,3 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polimetilfenilsiloksan v količini 0,7 masnih %, relativno glede na maso notranjega sloja (3).99.3% by weight relative to the weight of the inner layer (3) and polymethylphenylsiloxane in an amount of 0.7% by weight relative to the weight of the inner layer (3) is used as a structural modifier.

Dodatni ojačevalni sloj (11) je narejen iz mreže osnovane na polipropilenskih vlaknih. Dodatni ojačevalni sloj (12) je narejen iz sintetičnega polsta, osnovanega na polipropilenskih vlaknih. Vezivo je epoksi.An additional reinforcement layer (11) is made of a web based on polypropylene fibers. The additional reinforcement layer (12) is made of a synthetic felt based on polypropylene fibers. The binder is epoxy.

Pogoji utrjevanja so enaki kot v primeru 8.The curing conditions are the same as in Example 8.

Rezultati so enaki kot v primeru 10.The results are the same as in Example 10.

Primer 13Example 13

Proces se izvede na podoben način kot v primeru 2.The process is carried out in the same way as in Example 2.

Razlika je le v tem, da se na področju povezave stranskih robov (6) (slika 4) in (7) pole materiala in ojačevalnih slojev dvoslojnega polizdelka plašča in med trakom (8), ki je pripravljen iz materiala identičnega materialu notranjega sloja ovoja, nahaja meja (9) iz fluoroplastike take širine, da omogoča popolno zaprtje špranje in je poleg tega ožja kot trak (8).The only difference is that in the area of connection of the side edges (6) (Figure 4) and (7), the sheet material and reinforcement layers of the bilayer semi-finished product are coated and between the strip (8) made of material identical to the material of the inner layer of the wrapper, there is a fluoroplasty border (9) of such width that it permits complete closure of the lacunae and is further narrower than the ribbon (8).

V tem primeru se trak (8) privari na stran notranjega sloja (3), soosno glede na os delno dokončanega dela plašča, s čimer dobimo hermetično povezavo.In this case, the strip (8) is welded to the side of the inner layer (3), coaxially with respect to the axis of the partially finished part of the jacket, thereby obtaining a hermetic connection.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 2, z izjemo materiala notranjega sloja ovoja (3) in materiala za dodatni ojačevalni sloj (5) in veznega materiala.The same materials as in Example 2 are used for the design of the jacket, with the exception of the material of the inner layer of the sheath (3) and the material for the additional reinforcing layer (5) and the bonding material.

Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje polivinilklorid v količini 99,7 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polietilfenilsiloksan v količini 0,7 masnih %, relativno glede na maso notranjega sloja (3). Dodatni ojačevalni sloj (5) je narejen iz steklenega pletiva. Vez je poliesterska in odebeljena z aerosilom.The inner layer of the sheath (3) is formed by a homogeneous system containing polyvinyl chloride in an amount of 99.7% by weight relative to the weight of the inner layer (3), and polyethylphenylsiloxane in an amount of 0.7% by weight relative to the weight is used as a structural modifier. to the mass of the inner layer (3). The additional reinforcement layer (5) is made of glass knitting. The embroidery is polyester and thickened with aerosil.

Pred uporabo nosilca toplote, apliciramo zrak s tlakom 0,05 Mpa, v trajanju 10 minut. Utrjevanje se opravi na enak način kot v primeru 2. Rezultati so enaki kot v primeru 2.Prior to using the heat carrier, a pressure of 0.05 Mpa was applied for 10 minutes. The curing is carried out in the same manner as in Example 2. The results are the same as in Example 2.

Primer 14Example 14

Proces se izvede na podoben način kot v primeru 13.The process is carried out in the same way as in Example 13.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 13, z izjemo materiala notranjega sloja ovoja (3) in materiala za dodatni ojačevalni sloj (5, 11) in mejne plasti (9) .The same materials as in Example 13 are used for the design of the jacket, with the exception of the inner layer material (3) and the additional reinforcement layer material (5, 11) and the boundary layer (9).

Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje polivinilklorid v količini 99,5 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polietilfenilsiloksan v količini 0,5 masnih %, relativno glede na maso notranjega sloja (3). Dodatni ojačevalni sloj (5) je narejen iz mreže ogljikovih vlaken.The inner layer of the sheath (3) is formed by a homogeneous system containing polyvinyl chloride in an amount of 99.5% by weight relative to the weight of the inner layer (3), and polyethylphenylsiloxane in an amount of 0.5% by weight relative to the weight is used as a structural modifier. to the mass of the inner layer (3). The additional reinforcement layer (5) is made of carbon fiber mesh.

Dodatni ojačevalni sloj (11) je narejen iz kombiniranega steklenega materiala.The additional reinforcement layer (11) is made of combined glass material.

Mejna plast (9) je narejena iz sintetičnih vlaken.The boundary layer (9) is made of synthetic fibers.

Utrjevanje se izvede na enak način kot v primeru 13. Rezultati so enaki kot v primeru 13.The curing is carried out in the same manner as in Example 13. The results are the same as in Example 13.

Primer 15Example 15

Proces se izvede na podoben način kot v primeru 14.The process is carried out in the same way as in Example 14.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 13, z izjemo materiala notranjega sloja ovoja (3) in materiala za dodatni ojačevalni sloj (11) in mejno plast (9). Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje polivinilklorid v količini 99,3 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polietilfenilsiloksan v količini 0,7 masnih %, relativno glede na maso notranjega sloja (3) .The same materials as in Example 13 are used for the design of the jacket, with the exception of the material of the inner coating layer (3) and the material for the additional reinforcing layer (11) and the boundary layer (9). The inner layer of the sheath (3) is formed by a homogeneous system containing polyvinyl chloride in an amount of 99.3% by weight relative to the weight of the inner layer (3), and polyethylphenylsiloxane in an amount of 0.7% by weight relative to the weight is used as a structural modifier. to the mass of the inner layer (3).

Dodatni ojačevalni sloj (11) je narejen iz steklenega pletiva. Mejna plast (9) je narejena iz steklenih vlaken. Utrjevanje se izvede v skladu s primerom 13.The additional reinforcement layer (11) is made of glass knitting. The boundary layer (9) is made of fiberglass. Curing is carried out in accordance with Example 13.

Rezultati so enaki kot v primeru 13.The results are the same as in Example 13.

Primer 16Example 16

Proces se izvede na podoben način kot v primeru 10.The process is carried out in the same way as in Example 10.

Razlika je v tem, da se namesto traku (9), prikazenem na sliki (3) uporabi profiliran trak (10), ki ima prerez v obliki črke T in je iz identičnega materiala kot notranji sloj ovoja (3), na sliki 5.The difference is that instead of the tape (9) shown in Figure (3), a profiled tape (10) is used, which has a T-shaped cross section and is made of the same material as the inner layer of the wrapper (3) in Figure 5.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 10, z izjemo materiala notranjega sloja ovoja (3), materiala za glavni ojačevalni sloj (4) in za dodatni ojačevalni sloj (12).The same materials as in Example 10 are used for the design of the jacket, with the exception of the material of the inner coating layer (3), the material for the main reinforcing layer (4) and for the additional reinforcing layer (12).

Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje termoplastični poliuretan na osnovi preprostega poliestra v količini 99,7 masnih %, relativno glede na maso notranjega sloja (3) , kot strukturni modifikator pa se uporabi polimetilfenilsiloksan v količini 0,7 masnih %, relativno glede na maso notranjega sloja (3).The inner layer of the sheath (3) is formed by a homogeneous system containing thermoplastic polyurethane based on simple polyester in an amount of 99.7% by weight relative to the weight of the inner layer (3) and polymethylphenylsiloxane in an amount of 0.7 is used as a structural modifier % by weight relative to the weight of the inner layer (3).

Glavni ojačevalni sloj (4) je narejen iz sintetičnega polsta, ki je mešanica poliestra in polipropilenskih vlaken. Dodatni ojačevalni sloj (12) je narejen iz steklenega pletiva. Pogoji utrjevanja so enaki kot v primeru 10. Rezultati so enaki kot v primeru 10.The main reinforcement layer (4) is made of a synthetic felt which is a mixture of polyester and polypropylene fibers. The additional reinforcement layer (12) is made of glass knitting. The curing conditions are the same as in Example 10. The results are the same as in Example 10.

Primer 17Example 17

Proces se izvede na podoben način kot v primeru 16.The process is carried out in the same way as in Example 16.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 16, z izjemo materiala notranjega sloja ovoja (3) in materiala za dodatna ojačevalna sloja (11 in 12) .The same materials as in Example 16 are used for the design of the jacket, with the exception of the inner layer material (3) and the material for the additional reinforcement layers (11 and 12).

Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje termoplastični poliuretan na osnovi preprostega poliestra v količini 99,5 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polimetilfenilsiloksan v količini 0,5 masnih %, relativno glede na maso notranjega sloja (3).The inner layer of the sheath (3) is formed by a homogeneous system containing thermoplastic polyurethane based on simple polyester in an amount of 99.5% by weight relative to the weight of the inner layer (3) and polymethylphenylsiloxane in an amount of 0.5 is used as a structural modifier % by weight relative to the weight of the inner layer (3).

Dodatni ojačevalni sloj (11) je narejen iz steklenih vlaken.The additional reinforcement layer (11) is made of fiberglass.

Dodatni ojačevalni sloj (12) je narejen iz mreže poliesterskih vlaken. Pogoji utrjevanja so enaki kot v primeru 13.The additional reinforcement layer (12) is made of a polyester fiber net. The curing conditions are the same as in Example 13.

Rezultati so enaki kot v primeru 13.The results are the same as in Example 13.

Primer 18Example 18

Proces se izvede na podoben način kot v primeru 17.The process is carried out in a similar manner to Example 17.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 17, z izjemo materiala notranjega sloja ovoja (3) in materiala za dodatni ojačevalni sloj (12) .The same materials as in Example 17 are used for the design of the jacket, with the exception of the inner layer material (3) and the additional reinforcement layer material (12).

Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje termoplastični poliuretan na osnovi preprostega poliestra v količini 99,3 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polifenilsiloksan v količini 0,7 masnih %, relativno glede na maso notranjega sloja (3) .The inner layer of the sheath (3) is formed by a homogeneous system containing thermoplastic polyurethane based on simple polyester in an amount of 99.3% by weight relative to the weight of the inner layer (3) and polyphenylsiloxane in an amount of 0.7 is used as a structural modifier % by weight relative to the weight of the inner layer (3).

Dodatni ojačevalni sloj (12) je narejen iz kombiniranega steklenega materiala.The additional reinforcement layer (12) is made of combined glass material.

Pogoji utrjevanja:Curing conditions:

- nosilec toplote je voda;- the heat carrier is water;

temperatura topi. telesa je 95°C; čas utrjevanja je 6 ur.the temperature melts. body temperature is 95 ° C; curing time is 6 hours.

Rezultati so enaki kot v primeru 17.The results are the same as in Example 17.

Primer 19Example 19

Proces se izvede na podoben način kot v primeru (8), z izjemo tega, da se stranska robova (6 in 7) (slike 6, 7 in 11) privarita tako, da se robova prekrivata.The process is carried out in the same way as in Example (8), except that the side edges (6 and 7) (Figures 6, 7 and 11) are welded so that the edges overlap.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 8, z izjemo materiala notranjega sloja ovoja (3). Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje polietilen nizke gostote v količini 5 masnih %, relativno glede na maso notranjega sloja (3), polipropilen v količini 94,7 masnih %, kot strukturni modifikator pa se uporabi polifenilsiloksan v količini 0,3 masnih %, relativno glede na maso notranjega sloja (3) .The same materials as in Example 8 are used for the design of the jacket, with the exception of the material of the inner lining layer (3). The inner layer of the sheath (3) is formed by a homogeneous system containing low density polyethylene in an amount of 5% by weight relative to the weight of the inner layer (3), and polypropylene in an amount of 94.7% by weight, using polyphenylsiloxane as a structural modifier. 0.3% by weight relative to the weight of the inner layer (3).

Pogoji utrjevanja so enaki kot v primeru 18, z izjemo tega, da je temperatura nosilca toplote 80°C, tlak pare pa znašaThe curing conditions are the same as in Example 18 except that the temperature of the heat carrier is 80 ° C and the vapor pressure is

0,1 Mpa.0.1 Mpa.

Rezultati so enaki kot v primeru 7.The results are the same as in Example 7.

Primer 20Example 20

Proces se izvede na podoben način kot v primeru 18.The process is carried out in a similar manner to Example 18.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 10, z izjemo materiala notranjega sloja ovoja (3) in materiala za dodatna ojačevalna sloja (5 in 12) ter materiala za vezivo.The same materials as in Example 10 are used for the design of the jacket, with the exception of the material of the inner coating layer (3) and the material for the additional reinforcing layers (5 and 12) and the binder material.

Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje polietilen nizke gostote v količini 45 masnih %, relativno glede na maso notranjega sloja (3), polipropilen v količini 44,7 masnih %, kot strukturni modifikator pa se uporabi polifenilsiloksan v količini 0,5 masnih %, relativno glede na maso notranjega sloja (3).The inner layer of the sheath (3) is formed by a homogeneous system containing low density polyethylene in an amount of 45% by weight relative to the weight of the inner layer (3), and polypropylene in an amount of 44.7% by weight, using polyphenylsiloxane as a structural modifier. 0.5% by weight relative to the weight of the inner layer (3).

Dodatni ojačevalni sloji (5 in 12) sta narejena iz sintetičnega polsta, na osnovi mešanice poliesterskih in polipropilenskih vlaken. Vez je poliester odebeljen z mešanico aerosila in magnezijevega oksida.The additional reinforcement layers (5 and 12) are made of synthetic felt based on a mixture of polyester and polypropylene fibers. The embroidery is polyester thickened with a mixture of aerosil and magnesium oxide.

Pogoji utrjevanja so enaki kot v primeru 7.The curing conditions are the same as in Example 7.

Rezultati so enaki kot v primeru 18.The results are the same as in Example 18.

Primer 21Example 21

Proces se izvede na podoben način kot v primeru 20.The process is carried out in a similar manner to Example 20.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 20, z izjemo materiala notranjega sloja ovoja (3) in materiala za dodatni ojačevalni sloj (12).The same materials as in Example 20 are used for the design of the jacket, with the exception of the material of the inner coating layer (3) and the material for the additional reinforcing layer (12).

Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje polietilen nizke gostote v količini 95 masnih %, polipropilen v količini 4,3 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polifenilsiloksan v količini 0,7 masnih %, relativno glede na maso notranjega sloja (3).The inner layer of the sheath (3) is formed by a homogeneous system containing low density polyethylene in an amount of 95% by weight, polypropylene in an amount of 4.3% by weight relative to the weight of the inner layer (3), and polyphenylsiloxane is used as a structural modifier. 0.7% by weight relative to the weight of the inner layer (3).

Dodatni ojačevalni sloj (12) je narejen iz mreže ogljikovih vlaken.The additional reinforcement layer (12) is made of carbon fiber mesh.

Pogoji utrjevanja so enaki kot v primeru 5, z izjemo tega, da je čas utrjevanja 6 ur.The curing conditions are the same as in Example 5, except that the curing time is 6 hours.

Rezultati so enaki kot v primeru 20.The results are the same as in Example 20.

Primer 22Example 22

Proces se izvede na podoben način kot v primeru 10.The process is carried out in the same way as in Example 10.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 10, z izjemo materiala notranjega sloja ovoja (3), materiala za glavni ojačevalni sloj (4) in materiala za dodatni ojačevalni sloj (12).The same materials as in Example 10 are used for the design of the jacket, with the exception of the material of the inner coating layer (3), the material for the main reinforcing layer (4) and the material for the additional reinforcing layer (12).

Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje super-visoko-molekularen polietilen v količini 5 masnih %, kopolimer propilena z vinilacetatom v količiniThe inner layer of the sheath (3) is formed by a homogeneous system containing super-high molecular weight polyethylene in an amount of 5% by weight, a copolymer of propylene with vinyl acetate in an amount of

94,7 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polimetilsiloksan v količini 0,3 masnih %, relativno glede na maso notranjega sloja (3).94.7% by weight relative to the weight of the inner layer (3) and polymethylsiloxane in an amount of 0.3% by weight relative to the weight of the inner layer (3) is used as a structural modifier.

Glavni ojačevalni sloj (4) je narejen kot v primeru 1, dodatni ojačevalni sloj 5 pa je narejen iz sintetičnega polsta na osnovi poliesterskih vlaken.The main reinforcement layer (4) is made as in Example 1, and the additional reinforcement layer 5 is made of a synthetic polyester fiber based sheath.

Pogoji utrjevanja so enaki kot v primeru 9, z izjemo tega, da je temperatura toplotnega telesa 110°C.The curing conditions are the same as in Example 9 except that the temperature of the heat body is 110 ° C.

Rezultati so enaki kot v primeru (22).The results are the same as in (22).

Primer 23Example 23

Proces se izvede na podoben način kot v primeru 22.The process is carried out in the same way as in Example 22.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 22, z izjemo materiala notranjega sloja ovoja (3) in materiala za vezivo.The same materials as in Example 22 are used to form the jacket, with the exception of the inner lining material (3) and the binder material.

Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje super-visoko-molekularen polietilen v količini 45 masnih %, kopolimer propilena z vinilacetatom v količiniThe inner layer of the sheath (3) is formed by a homogeneous system containing super-high molecular weight polyethylene in an amount of 45% by weight, a copolymer of propylene with vinyl acetate in an amount of

44,5 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polimetilsiloksan v količini 0,5 masnih %, relativno glede na maso notranjega sloja (3).44.5% by weight relative to the weight of the inner layer (3) and polymethylsiloxane in an amount of 0.5% by weight relative to the weight of the inner layer (3) is used as a structural modifier.

Vez je osnovana na nenasičeni poliesterski smoli, odebeljeni z magnezijevim oksidom.The bond is based on unsaturated polyester resin, thickened with magnesium oxide.

Pogoji utrjevanja so enaki kot v primeru 22.The curing conditions are the same as in Example 22.

Rezultati so enaki kot v primeru 22.The results are the same as in Example 22.

Primer 24Example 24

Proces se izvede na podoben način kot v primeru 6.The process is carried out in the same way as in Example 6.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 6, z izjemo materiala notranjega sloja ovoja (3). Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje super-visoko-molekularen polietilen v količini 95 masnih %, kopolimer propilena z vinilacetatom v količini 4,3 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polimetilsiloksan v količini 0,7 masnih %, relativno glede na maso notranjega sloja (3). Pogoji utrjevanja so enaki kot v primeru 22. Rezultati so enaki kot v primeru 6.The same materials as in Example 6 are used for the design of the jacket, with the exception of the material of the inner lining layer (3). The inner layer of the sheath (3) is formed by a homogeneous system containing super-high molecular weight polyethylene in an amount of 95% by weight, a copolymer of propylene with vinyl acetate in an amount of 4.3% by weight, relative to the weight of the inner layer (3), as a structural and the modifier uses polymethylsiloxane in an amount of 0.7% by weight relative to the weight of the inner layer (3). The curing conditions are the same as in Example 22. The results are the same as in Example 6.

Primer 25Example 25

Proces se izvede na podoben način kot v primeru 13.The process is carried out in the same way as in Example 13.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 13, z izjemo materiala notranjega sloja ovoja (3). Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje polivinilklorid v količini 5 masnih %, termoplastični poliuretan osnovan na preprostem poliestru v količini 94,7 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polimetilfenilsiloksan v količini 0,3 masnih %, relativno glede na maso notranjega sloja (3).The same materials as in Example 13 are used for the design of the jacket, with the exception of the material of the inner lining layer (3). The inner layer of the sheath (3) is formed by a homogeneous system containing polyvinyl chloride in an amount of 5% by weight, thermoplastic polyurethane based on simple polyester in an amount of 94.7% by weight relative to the weight of the inner layer (3), and as a structural modifier, use polymethylphenylsiloxane in an amount of 0.3% by weight relative to the weight of the inner layer (3).

Pogoji utrjevanja so enaki kot v primeru 19, z izjemo tega, da je temperatura toplotnega telesa 50°C, čas utrjevanja pa znaša 15 ur. Rezultati so enaki kot v primeru 13.The curing conditions are the same as in Example 19, except that the heat body temperature is 50 ° C and the curing time is 15 hours. The results are the same as in Example 13.

Primer 26Example 26

Proces se izvede na podoben način kot v primeru 14.The process is carried out in the same way as in Example 14.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 14, z izjemo materiala notranjega sloja ovoja (3). Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje polivinilklorid v količini 45 masnih %, termoplastični poliuretan v količini 44,5 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polimetilfenilsiloksan v količini 0,5 masnih %, relativno glede na maso notranjega sloja (3). Pogoji utrjevanja so enaki kot v primeru 14, z izjemo tega, da tlak znaša 0,1 MPa, čas apliciranja zraka pa znaša 5 minut. Rezultati so enaki kot v primeru 14.The same materials as in Example 14 are used for the design of the jacket, with the exception of the material of the inner lining layer (3). The inner layer of the sheath (3) is formed by a homogeneous system containing polyvinyl chloride in an amount of 45% by weight, thermoplastic polyurethane in an amount of 44.5% by weight, relative to the weight of the inner layer (3), and polymethylphenylsiloxane in amount is used as a structural modifier 0,5% by weight relative to the weight of the inner layer (3). The curing conditions are the same as in Example 14, except that the pressure is 0.1 MPa and the air application time is 5 minutes. The results are the same as in Example 14.

Primer 27Example 27

Proces se izvede na enak način kot v primeru 15.The process is carried out in the same manner as in Example 15.

Za oblikovanje plašča se uporabljajo isti materiali kot v primeru 15, z izjemo materiala notranjega sloja ovoja (3). Notranji sloj ovoja (3) je oblikovan s homogenim sistemom, ki vsebuje polivinilklorid v količini 95 masnih %, termoplastični poliuretan v količini 4,3 masnih %, relativno glede na maso notranjega sloja (3), kot strukturni modifikator pa se uporabi polimetilfenilsiloksan v količini 0,7 masnih %, relativno glede na maso notranjega sloja (3). Pogoji utrjevanja so enaki kot v primeru 15, z izjemo tega, da tlak znaša 0,2 MPa, čas utrjevanja pa je 10 ur.The same materials as in Example 15 are used for the design of the jacket, with the exception of the inner lining material (3). The inner layer of the sheath (3) is formed by a homogeneous system containing polyvinyl chloride in an amount of 95% by weight, thermoplastic polyurethane in an amount of 4.3% by weight, relative to the weight of the inner layer (3), and polymethylphenylsiloxane in amount is used as a structural modifier 0.7% by weight relative to the weight of the inner layer (3). The curing conditions are the same as in Example 15, except that the pressure is 0.2 MPa and the curing time is 10 hours.

Rezultati so enaki kot v primeru 15.The results are the same as in Example 15.

Primer 28Example 28

Proces je podoben procesu primera 25, s to razliko, da je v homogenem sistemu notranjega sloja ovoja (3) namesto polimetilfenilsiloksana uporabljen polietilfenilsiloksan v isti količini. Pogoji utrjevanja so enaki kot v primeru 25. Rezultati so enaki kot v primeru 25.The process is similar to the process of Example 25, except that in the homogeneous system of the inner layer of the sheath (3), polyethylphenylsiloxane is used in the same amount instead of polymethylphenylsiloxane. The curing conditions are the same as in Example 25. The results are the same as in Example 25.

Primer 29Example 29

Proces je podoben procesu iz primera 26, s tem, da se v homogenem sistem notranjega sloja ovoja (3) uporabi polietilenilsiloksan na mesto polimetilfenilsiloksana. Pogoji utrjevanja so enaki kot v primeru 26 Rezultati so enaki kot v primeru 26.The process is similar to the process of Example 26 in that polyethylenephenyloxane is used in the homogeneous system of the inner layer of the sheath (3) to the polymethylphenylsiloxane site. The curing conditions are the same as in Example 26 The results are the same as in Example 26.

Primer 30Example 30

Proces se izvede na podoben način kot v primeru 26, s tem, da se v homogenem sistemu notranjega sloja ovoja (3), namesto polimetilfenilsiloksana uporabi polietilfenilsiloksan v isti količini.The process is carried out in a similar manner to Example 26, by using polyethylphenylsiloxane in the same amount in a homogeneous inner layer system (3) instead of polymethylphenylsiloxane.

Pogoji utrjevanja so enaki kot v primeru 27.The curing conditions are the same as in Example 27.

Rezultati so enaki kot v primeru 27.The results are the same as in Example 27.

Med opisovanjem teh različic uresničitve izuma je bila uporabljena še posebej natančna terminologija. Kljub temu pa izum ni omejen s temi izrazi in torej vsak tak izraz pokriva vse ekvivalentne izraze, ki imajo podoben pomen in se uporabljajo za opravljanje istih nalog.Particularly accurate terminology was used to describe these embodiments of the invention. However, the invention is not limited to these terms, and therefore any such term covers all equivalent terms that have a similar meaning and are used to perform the same tasks.

Čeprav je bil predmetni izum opisan v skladu s prednostimi upodobitvami je jasno, da se lahko opravijo tudi določene spremembe in raznovrstne različice, kar pa ne pomenin oddaljevanja od glavne ideje tega izuma, kar bo v stroki izkušenim razumljivo.Although the present invention has been described in accordance with the preferred drawings, it is clear that certain variations and variations may also be made, which is not a departure from the main idea of the invention, which will be understood by those skilled in the art.

Za te različice in spremembe se smatra, da ne presegajo mej bistva tega izuma in sledečih patentnih zahtevkov.These variations and variations are considered not to go beyond the scope of the invention and the following claims.

Industrijska uporabnostIndustrial applicability

Izum je uporaben pri izdelavi različnih vrst cevi, kakor tudi pri popravljanju cevi, ki so že v funkciji.The invention is useful in the manufacture of various types of tubes, as well as in the repair of tubes already in operation.

Claims (62)

PATENTNI ZAHTEVKIPATENT APPLICATIONS 1. Oplaščenje notranje površine cevi, ki se sestoji iz dveh cevastih ovojev (2, 3), ki sta postavljena koaksialno, iz materiala na osnovi termoplastičnih polimerov, od katerih se zunanji ovoj (2) dotika notranje površine cevi (1), drugi, notranji ovoj (3) pa je od ovojnice (2) ločen s koaksialno ležečo glavno ojačitveno plastjo (4), ki je impregnirana z utrjeno polimerno vezjo, značilno po tem, da je notranji cevasti ovoj (3) formiran z multikomponentnim homogenim sistemom, ki obsega vsaj en polimer, izbran iz skupine, ki obsega tremoplastične polimere, katerih relativni raztezek ni manjši od 200%, točka taljenja pa ni pod 100°C in strukturni modifikator izbranega polimera, s čimer sta notranji cevasti ovoj (3), skupaj z glavno ojačitveno plastjo (4) ločena na vsaj enem mestu soosno osi plašča, njuna ločena robova (6, 7) pa sta drug z drugim hermetično povezana, omenjeni ovoj (3) pa, z glavno ojačitveno plastjo (4), tvori monolitno strukturo.Cladding of the inner surface of a tube consisting of two tubular sheaths (2, 3) coaxially arranged from a material based on thermoplastic polymers from which the outer sheath (2) touches the inner surface of the tube (1), the second, the inner envelope (3) is separated from the envelope (2) by a coaxial main reinforcement layer (4) impregnated with a cured polymeric bond, characterized in that the inner tubular envelope (3) is formed by a multicomponent homogeneous system which comprising at least one polymer selected from the group consisting of tremoplastic polymers having a relative elongation of not less than 200% and a melting point not below 100 ° C and a structural modifier of the selected polymer, thereby forming the inner tubular sheath (3) together with the main the reinforcing layer (4) separated at least in one location by the coaxial axis of the mantle, their separate edges (6, 7) being hermetically connected to each other, said shell (3) forming a monolithic structure with the main reinforcing layer (4). 2. Oplaščenje po zahtevku 1, značilno po tem, da skupina termoplastičnih polimerov, katerih relativni raztezek ni manjši od 200%, točka taljenja pa ni pod 100°C, obsega polietilene z nizko gostoto, super-visoko-molekularne polietilene, polipropilen, kopolimer propilena z vinilacetatom, polivinilklorid in termoplastični poliuretan, strukturni modifikator izbranega polimera pa je poliorganosiloksan izbran iz skupine, ki vključuje polimetilsiloksan, polimetilfenilsiloksan, polifenilsiloksan in polietilfenilsiloksan.Coating according to claim 1, characterized in that the group of thermoplastic polymers whose relative elongation is not less than 200% and the melting point is not below 100 ° C comprises low density polyethylene, super-high molecular weight polyethylene, polypropylene, copolymer propylene with vinyl acetate, polyvinyl chloride and thermoplastic polyurethane, and the structural modifier of the selected polymer is polyorganosiloxane selected from the group consisting of polymethylsiloxane, polymethylphenylsiloxane, polyphenylsiloxane and polyethylphenylsiloxane. 3. Oplaščenje po zahtevku 2, značilno po tem, da je notranji cevasti ovoj (3) formiran z multikomponentnim homogenim sistemom, ki obsega en polimer, ali mešanico dveh polimerov izbranih iz omenjene skupine termoplastičnih polimerov v količini od 99,3 do 99,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3) in poliorganosiloksan v količini od 0,3 do 0,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3).Coating according to claim 2, characterized in that the inner tubular sheath (3) is formed by a multicomponent homogeneous system comprising one polymer or a mixture of two polymers selected from said group of thermoplastic polymers in an amount of 99.3 to 99.7 by weight, based on the total weight of the inner sheath (3) and polyorganosiloxane in an amount of 0.3 to 0.7 weight percent, based on the total weight of the inner sheath (3). 4. Oplaščenje po zahtevku 3, značilno po tem, da je izbrani termoplastični polimer polietilen z nizko gostoto, izbrani poliorganosiloksan pa je polimetilsiloksan.Coating according to claim 3, characterized in that the selected thermoplastic polymer is low density polyethylene and the selected polyorganosiloxane is polymethylsiloxane. 5. Oplaščenje po zahtevku 3, značilno po tem, da je izbrani termoplastični polimer super-visoko-molekularni polietilen, izbrani poliorganosiloksan pa je polimetilsiloksan.5. The coating according to claim 3, characterized in that the selected thermoplastic polymer is super-high molecular weight polyethylene and the selected polyorganosiloxane is polymethylsiloxane. 6. Oplaščenje po zahtevku 3, značilno po tem, da je izbrani termoplastični polimer polipropilen, izbrani poliorganosiloksan pa je polifenilsiloksan.Coating according to claim 3, characterized in that the selected thermoplastic polymer is polypropylene and the selected polyorganosiloxane is polyphenylsiloxane. 7. Oplaščenje po zahtevku 3, značilno po tem, da je izbrani termoplastični polimer kopolimer propilena z vinilacetatom, izbrani poliorganosiloksan pa je polimetilfenilsiloksan.Coating according to claim 3, characterized in that the selected thermoplastic polymer is a copolymer of propylene with vinyl acetate and the selected polyorganosiloxane is polymethylphenylsiloxane. 8. Oplaščenje po zahtevku 3, značilno po tem, da je izbrani termoplastični polimer polivinilklorid, izbrani poliorganosiloksan pa je polietilfenilsiloksan.Coating according to claim 3, characterized in that the selected thermoplastic polymer is polyvinyl chloride and the selected polyorganosiloxane is polyethylphenylsiloxane. 9. Oplaščenje po zahtevku 3, značilno po tem, da je izbrani termoplastični polimer termoplastični poliuretan, izbrani poliorganosiloksan pa je polimetilfenilsiloksan.Coating according to claim 3, characterized in that the selected thermoplastic polymer is thermoplastic polyurethane and the selected polyorganosiloxane is polymethylphenylsiloxane. 10. Oplaščenje po zahtevku 3, značilno po tem, da mešanica dveh izbranih termoplastičnih polimerov vsebuje polietilen z nizko gostoto v količini od 5 do 95 masnih odstotkov in polipropilen v količini od 4,3 do 94,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3), izbrani poliorganosiloksan pa je polifenilsiloksan.10. Coating according to claim 3, characterized in that the mixture of the two selected thermoplastic polymers contains low density polyethylene in an amount of from 5 to 95% by weight and polypropylene in an amount of from 4.3 to 94.7% by weight, based on the total weight of the inner (3), the selected polyorganosiloxane being polyphenylsiloxane. 11. Oplaščenje po zahtevku 3, značilno po tem, da mešanica dveh izbranih termoplastičnih polimerov vsebuje supervisoko-molekularni polietilen v količini od 5 do 95 masnih odstotkov in kopolimer propilena z vinilacetatom v količini od 4,3 do 94,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3), izbrani poliorganosiloksan pa je polimetilsiloksan.Coating according to claim 3, characterized in that the mixture of the two selected thermoplastic polymers contains super-high molecular weight polyethylene in an amount of from 5 to 95% by weight and a copolymer of propylene with vinyl acetate in an amount of from 4.3 to 94.7% by weight, the total weight of the inner sheath (3) and the selected polyorganosiloxane is polymethylsiloxane. 12. Oplaščenje po zahtevku 3, značilno po tem, da mešanica dveh izbranih termoplastičnih polimerov vsebuje polivinilklorid v količini od 5 do 95 masnih odstotkov in termoplastični poliuretan v količini od 4,3 do 94,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3), izbrani poliorganosiloksan pa je polimetilfenilsiloksan ali polietilfenilsiloksan.Coating according to claim 3, characterized in that the mixture of the two selected thermoplastic polymers contains polyvinyl chloride in an amount of from 5 to 95% by weight and thermoplastic polyurethane in an amount of from 4.3 to 94.7% by weight, based on the total weight of the inner sheath ( 3) and the selected polyorganosiloxane is polymethylphenylsiloxane or polyethylphenylsiloxane. 13. Oplaščenje po zahtevku 1, ali 2 ali 3, značilno po tem, da je predvidena vsaj ena dodatna ojačitvena plast (5), ki je nameščena koaksialno med zunanjim cevastim ovojem (2) in glavno ojačitveno plastjo (4).Coating according to claim 1 or 2 or 3, characterized in that at least one additional reinforcement layer (5) is provided coaxially between the outer tubular sheath (2) and the main reinforcing layer (4). 14. Oplaščenje po zahtevku 1, ali 2 ali 3, značilno po tem, da je glavna ojačitvena plast (4) izdelana iz sintetičnega netkanega vlaknastega materiala.Coating according to claim 1 or 2 or 3, characterized in that the main reinforcing layer (4) is made of synthetic non-woven fibrous material. 15. Oplaščenje po zahtevku 1, ali 2 ali 3, značilno po tem, da sta ločena robova (6, 7) notranjega cevastega ovoja (3), skupaj z glavno ojačitveno plastjo (4), od robu do robu, hermetično povezana.Coating according to claim 1 or 2 or 3, characterized in that the separate edges (6, 7) of the inner tubular sheath (3), together with the main reinforcing layer (4), are edge-to-edge, hermetically connected. 16. Oplaščenje po zahtevku 1, ali 2 ali 3, značilno po tem, da sta ločena robova (6, 7) notranjega cevastega ovoja (3), skupaj z glavno ojačitveno plastjo (4), hermetično povezana tako, da se prekrivata.Coating according to claim 1 or 2 or 3, characterized in that the separate edges (6, 7) of the inner tubular sheath (3), together with the main reinforcing layer (4), are hermetically connected so that they overlap. 17. Metoda namestitve plašča na notranjo površino cevi, kjer zunaj cevi (1) namestimo cevasta ovoja (2, 3) na osnovi termoplastičnih polimerov, od katerih je eden zunanji (2) namenjen za stik z notranjo površino cevi (1), drugi - notranji (3) pa je od ovoja (2) ločen s pomočjo glavne ojačitvene plasti (4), ki je impregnirana s polimernim vezivom, ki se termično strdi, da dobimo tri-slojni polizdelek, ki je del plašča, katerega vstavimo v cev (1) in nato v votlino notranjega ovoja (3) pod tlakom privedemo nosilec toplote, kar ima za posledico toplotno obdelavo in utrjevanje vezi, značilna po tem, da je glavna ojačitvena plast (4) povezana z notranjim cevastim ovojem (3) s spojitvijo površin glavne ojačitvene plasti (4) in notranjega cevastega ovoja (3), ki je izdelan iz pole filma, pridobljenega iz multikomponentnega homogenega sistema, s pomočjo mešanja v raztaljenem stanju, vsaj enega polimera izbranega iz skupine termoplastičnih polimerov, katerih relativni raztezek ni manjši od 200%, točka taljenja pa ni pod17. A method of attaching a sheath to the inner surface of a tube, where tubular sheaths (2, 3) based on thermoplastic polymers are mounted outside the tube (1), one of which is external (2) intended for contact with the inner surface of the tube (1), the other - the inner (3) is separated from the sheath (2) by a main reinforcement layer (4) impregnated with a polymeric binder, which is thermally cured to give a three-layer semi-finished product which is part of a sheath, which is inserted into the tube ( 1) and then pressurized heat carrier into the cavity of the inner sheath (3), resulting in thermal treatment and bond hardening, characterized in that the main reinforcing layer (4) is connected to the inner tubular sheath (3) by joining the surfaces a main reinforcing layer (4) and an inner tubular sheath (3) made from a film sheet obtained from a multicomponent homogeneous system by mixing in the molten state at least one polymer selected from the group of thermoplastic polymers having a relative elongation is not less than 200% and the melting point is not below 100°C in strukturnega modifikatorja izbranega polimera, čemur sledi hermetična povezava vzdolžnih robov (6, 7) pole filma z glavno ojačitveno plastjo (4), s čimer dobimo dvo slojni polizdelek plašča, ki obsega ojačitveno plast (4) in notranjo cevasto ovojnico (3), ki sta nameščena koaksialno in drug z drugim povezana, nato pa dvo-slojni polizdelek namestimo koaksialno glede zunanjo cevasto ovojnico (2).100 ° C and a structural modifier of the selected polymer, followed by a hermetic connection of the longitudinal edges (6, 7) of the film sheet with the main reinforcing layer (4), thereby obtaining a two-layer semi-finished sheath comprising the reinforcing layer (4) and an inner tubular envelope ( 3), which are coaxially arranged and connected to one another, and then the two-layer semi-finished product is coaxially positioned relative to the outer tubular envelope (2). 18. Metoda po zahtevku 17, značilna po tem, da skupina termoplastičnih polimerov, katerih relativni raztezek ni manjši od 200 % in točka taljenja ni pod 100°C, obsega polietilene z nizko gostoto, super-visoko-molekularne polietilene, polipropilen, kopolimer propilena z vinilacetatom, polivinilklorid in termoplastični poliuretan, strukturni modifikator izbranega polimera pa je poliorganosiloksan izbran iz skupine, ki vključuje polimetilsiloksan, polimetilfenilsiloksan, polifenilsiloksan in polietilfenilsiloksan.18. The method according to claim 17, characterized in that the group of thermoplastic polymers whose relative elongation is not less than 200% and the melting point is not below 100 ° C comprises low density polyethylene, super-high molecular weight polyethylene, polypropylene, propylene copolymer with vinyl acetate, polyvinyl chloride and thermoplastic polyurethane, and the structural modifier of the selected polymer is polyorganosiloxane selected from the group consisting of polymethylsiloxane, polymethylphenylsiloxane, polyphenylsiloxane and polyethylphenylsiloxane. 19. Metoda po zahtevku 18, značilna po tem, da je notranji cevasti ovoj (3) pridobljen iz multikomponentnega homogenega sistema z mešanjem v raztaljenem stanju, enega polimera, ali mešanice dveh polimerov izbranih iz omenjene skupine termoplastičnih polimerov v količini odMethod according to claim 18, characterized in that the inner tubular sheath (3) is obtained from a multicomponent homogeneous molten system, one polymer, or a mixture of two polymers selected from said group of thermoplastic polymers in an amount of 99,3 do 99,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3) in poliorganosiloksan v količini od 0,3 do 0,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3).99.3 to 99.7% by weight, based on the total weight of the inner sheath (3) and polyorganosiloxane in an amount of 0.3 to 0.7% by weight, based on the total weight of the inner sheath (3). 20. Metoda po zahtevku 18, značilna po tem, da je izbrani termoplastični polimer polietilen z nizko gostoto, izbrani poliorganosiloksan pa je polimetilsiloksan.20. The method of claim 18, wherein the selected thermoplastic polymer is low density polyethylene and the selected polyorganosiloxane is polymethylsiloxane. 21. Metoda po zahtevku 18, značilna po tem, da je izbrani termoplastični polimer super-visoko-molekularni polietilen, izbrani poliorganosiloksan pa je polimetilsiloksan.21. The method of claim 18, wherein the selected thermoplastic polymer is super-high molecular weight polyethylene and the selected polyorganosiloxane is polymethylsiloxane. 22. Metoda po zahtevku 18, značilna po tem, da je izbrani termoplastični polimer polipropilen, izbrani poliorganosiloksan pa je polifenilsiloksan.22. The method of claim 18, wherein the selected thermoplastic polymer is polypropylene and the selected polyorganosiloxane is polyphenylsiloxane. 23. Metoda po zahtevku 18, značilna po tem, da je izbrani termoplastični polimer kopolimer propilena z vinilacetatom, izbrani poliorganosiloksan pa je polimetilfenilsiloksan.23. The method of claim 18, wherein the selected thermoplastic polymer is a copolymer of propylene with vinyl acetate and the selected polyorganosiloxane is polymethylphenylsiloxane. 24. Metoda po zahtevku 18, značilna po tem, da je izbrani termoplastični polimer polivinilklorid, izbrani poliorganosiloksan pa je polietilfenilsiloksan.24. The method of claim 18, wherein the selected thermoplastic polymer is polyvinyl chloride and the selected polyorganosiloxane is polyethylphenylsiloxane. 25. Metoda po zahtevku 18, značilna po tem, da je izbrani termoplastični polimer termoplastični poliuretan, izbrani poliorganosiloksan pa je polimetilfenilsiloksan.25. The method of claim 18, wherein the selected thermoplastic polymer is thermoplastic polyurethane and the selected polyorganosiloxane is polymethylphenylsiloxane. 26. Metoda po zahtevku 18, značilna po tem, da mešanica dveh izbranih termoplastičnih polimerov vsebuje polietilen z nizko gostoto v količini od 5 do 95 masnih odstotkov in polipropilen v količini od 4,3 do 94,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3), izbrani poliorganosiloksan pa je polifenilsiloksan.26. A method according to claim 18, characterized in that the mixture of the two selected thermoplastic polymers contains low density polyethylene in an amount of from 5 to 95% by weight and polypropylene in an amount of from 4.3 to 94.7% by weight, based on the total weight of the inner (3), the selected polyorganosiloxane being polyphenylsiloxane. 27. Metoda po zahtevku 18, značilna po tem, da mešanica dveh izbranih termoplastičnih polimerov vsebuje supervisoko-molekularni polietilen v količini od 5 do 95 masnih odstotkov in kopolimer propilena z vinilacetatom v količini od 4,3 do 94,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3), izbrani poliorganosiloksan pa je polimetilsiloksan.27. The method of claim 18, wherein the mixture of the two selected thermoplastic polymers contains super-molecular weight polyethylene in an amount of from 5 to 95 percent by weight and a propylene copolymer with vinyl acetate in an amount of from 4.3 to 94.7 percent by weight, the total weight of the inner sheath (3) and the selected polyorganosiloxane is polymethylsiloxane. 28. Metoda po zahtevku 18, značilna po tem, da mešanica dveh izbranih termoplastičnih polimerov vsebuje polivinilklorid v količini od 5 do 95 masnih odstotkov in termoplastični poliuretan v količini od 4,3 do 94,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3) , izbrani poliorganosiloksan pa je polimetilfenilsiloksan ali polietilfenilsiloksan.A method according to claim 18, characterized in that the mixture of the two selected thermoplastic polymers contains polyvinyl chloride in an amount of from 5 to 95% by weight and thermoplastic polyurethane in an amount of from 4.3 to 94.7% by weight, based on the total weight of the inner sheath ( 3) and the selected polyorganosiloxane is polymethylphenylsiloxane or polyethylphenylsiloxane. 29. Metoda po zahtevku 17 ali 18 ali 19, značilna po tem, da je vsaj ena dodatna ojačitvena plast (5) nameščena med zunanjo cevasto ovojnico (2) in glavno ojačitveno plastjo (4) .Method according to claim 17 or 18 or 19, characterized in that at least one additional reinforcement layer (5) is positioned between the outer tubular envelope (2) and the main reinforcing layer (4). 30. Metoda po zahtevku 17 ali 18 ali 19, značilna po tem, da je glavna ojačitvena plast (4) izdelana iz sintetičnega netkanega vlaknastega materiala.A method according to claim 17 or 18 or 19, characterized in that the main reinforcing layer (4) is made of synthetic non-woven fibrous material. 31. Metoda po zahtevku 17 ali 18 ali 19, značilna po tem, da sta ločena robova (6, 7) pole filma skupaj z glavno ojačitveno plastjo (4), od robu do robu, hermetično povezana.Method according to claim 17 or 18 or 19, characterized in that the separate edges (6, 7) of the film sheet together with the main reinforcement layer (4), from edge to edge, are hermetically connected. 32. Metoda po zahtevku 17 ali 18 ali 19, značilna po tem, da sta vzdolžna robova (6, 7) pole filma skupaj z glavno ojačitveno plastjo (4), hermetično povezana tako, da se prekrivata.A method according to claim 17 or 18 or 19, characterized in that the longitudinal edges (6, 7) of the film sheet together with the main reinforcing layer (4) are sealed so that they overlap. 33. Dvo-slojni polizdelek plašča notranje površine cevi, ki obsega ojačitveno plast (4), povezan z notranjo cevasto ovojnico (3) na bazi termoplastičnega polimernega filma, značilen po tem, da je notranji cevasti ovoj (3) formiran z multikomponentnim homogenim sistemom, ki obsega vsaj en polimer, izbran iz skupine, ki obsega tremoplastične polimere, katerih relativni raztezek ni manjši od 200%, točka taljenja pa ni pod 100°C in strukturni modifikator izbranega polimera, s čimer sta notranji cevasti ovoj (3), skupaj z glavno ojačitveno plastjo (4) izdelana ločeno na vsaj enem mestu soosno osi polizdelka, njuna ločena robova (6, 7) pa sta drug z drugim hermetično povezana in tvorita ojačitveno plast (4) in notranji cevasti ovoj (3), ki sta nameščena koaksialno in sta med seboj povezana.33. A two-layer semi-finished product of the inner surface of the tube comprising a reinforcing layer (4) connected to an inner tubular envelope (3) based on a thermoplastic polymer film, characterized in that the inner tubular envelope (3) is formed by a multicomponent homogeneous system comprising at least one polymer selected from the group consisting of tremoplastic polymers having a relative elongation of not less than 200% and a melting point not below 100 ° C and a structural modifier of the selected polymer, bringing the inner tubular sheath (3) together with the main reinforcing layer (4) made separately in at least one location the coaxial axes of the semi-finished product, and their separate edges (6, 7) are hermetically connected to each other, forming the reinforcing layer (4) and the inner tubular sheath (3), which are mounted coaxially and are interconnected. 34. Polizdelek po zahtevku 33, značilen po tem, da skupina termoplastičnih polimerov, katerih relativni raztezek ni manjši od 200%, točka taljenja pa ni pod 100°C, obsega polietilene z nizko gostoto, super-visoko-molekularne polietilene, polipropilen, kopolimer propilena z vinilacetatom, polivinilklorid in termoplastični poliuretan, strukturni modifikator izbranega polimera pa je poliorganosiloksan izbran iz skupine, ki vključuje polimetilsiloksan, polimetilfenilsiloksan, polifenilsiloksan in polietilfenilsiloksan.34. Semi-finished product according to claim 33, characterized in that the group of thermoplastic polymers whose relative elongation is not less than 200% and the melting point is not below 100 ° C comprises low-density polyethylene, super-high molecular weight polyethylene, polypropylene, copolymer propylene with vinyl acetate, polyvinyl chloride and thermoplastic polyurethane, and the structural modifier of the selected polymer is polyorganosiloxane selected from the group comprising polymethylsiloxane, polymethylphenylsiloxane, polyphenylsiloxane and polyethylphenylsiloxane. 35. Polizdelek po zahtevku 34, značilen po tem, da je notranji cevasti ovoj (3) formiran z multikomponentnim homogenim sistemom, ki obsega en polimer, ali mešanico dveh polimerov izbranih iz omenjene skupine termoplastičnih polimerov v količini od 99,3 do 99,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3) in poliorganosiloksan v količini od 0,3 do 0,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3).35. Semi-finished product according to claim 34, characterized in that the inner tubular sheath (3) is formed by a multicomponent homogeneous system comprising one polymer or a mixture of two polymers selected from said group of thermoplastic polymers in an amount of from 99.3 to 99.7 by weight, based on the total weight of the inner sheath (3) and polyorganosiloxane in an amount of 0.3 to 0.7 weight percent, based on the total weight of the inner sheath (3). 36. Polizdelek po zahtevku 35, značilen po tem, da je izbrani termoplastični polimer polietilen z nizko gostoto, izbrani poliorganosiloksan pa je polimetilsiloksan.A semi-finished product according to claim 35, characterized in that the selected thermoplastic polymer is low density polyethylene and the selected polyorganosiloxane is polymethylsiloxane. 37. Polizdelek po zahtevku 35, značilen po tem, da je izbrani termoplastični polimer super-visoko-molekularni polietilen, izbrani poliorganosiloksan pa je polimetilsiloksan.A semi-finished product according to claim 35, characterized in that the selected thermoplastic polymer is super-high molecular weight polyethylene and the selected polyorganosiloxane is polymethylsiloxane. 38. Polizdelek po zahtevku 35, značilen po tem, da je izbrani termoplastični polimer polipropilen, izbrani poliorganosiloksan pa je polifenilsiloksan.A semi-finished product according to claim 35, characterized in that the selected thermoplastic polymer is polypropylene and the selected polyorganosiloxane is polyphenylsiloxane. 39. Polizdelek po zahtevku 35, značilen po tem, da je izbrani termoplastični polimer kopolimer propilena z vinilacetatom, izbrani poliorganosiloksan pa je polimetilfenilsiloksan.A semi-finished product according to claim 35, characterized in that the selected thermoplastic polymer is a copolymer of propylene with vinyl acetate and the selected polyorganosiloxane is polymethylphenylsiloxane. 40. Polizdelek po zahtevku 35, značilen po tem, da je izbrani termoplastični polimer polivinilklorid, izbrani poliorganosiloksan pa je polietilfenilsiloksan.40. The semi-finished product of claim 35, wherein the selected thermoplastic polymer is polyvinyl chloride and the selected polyorganosiloxane is polyethylphenylsiloxane. 41. Polizdelek po zahtevku 35, značilen po tem, da je izbrani termoplastični polimer termoplastični poliuretan, izbrani poliorganosiloksan pa je polimetilfenilsiloksan.41. The intermediate product of claim 35, wherein the selected thermoplastic polymer is thermoplastic polyurethane and the selected polyorganosiloxane is polymethylphenylsiloxane. 42. Polizdelek po zahtevku 35, značilen po tem, da mešanica dveh izbranih termoplastičnih polimerov vsebuje polietilen z nizko gostoto v količini od 5 do 95 masnih odstotkov in polipropilen v količini od 4,3 do 94,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3), izbrani poliorganosiloksan pa je polifenilsiloksan.A semi-finished product according to claim 35, characterized in that the mixture of the two selected thermoplastic polymers contains low density polyethylene in an amount of from 5 to 95% by weight and polypropylene in an amount of from 4.3 to 94.7% by weight, based on the total weight of the inner (3), the selected polyorganosiloxane being polyphenylsiloxane. 43. Polizdelek po zahtevku 35, značilen po tem, da mešanica dveh izbranih termoplastičnih polimerov vsebuje supervisoko-molekularni polietilen v količini od 5 do 95 masnih odstotkov in kopolimer propilena z vinilacetatom v količini od 4,3 do 94,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3), izbrani poliorganosiloksan pa je polimetilsiloksan.A semi-finished product according to claim 35, characterized in that the mixture of the two selected thermoplastic polymers contains super-high molecular weight polyethylene in an amount of from 5 to 95% by weight and a copolymer of propylene with vinyl acetate in an amount of from 4.3 to 94.7% by weight, the total weight of the inner sheath (3) and the selected polyorganosiloxane is polymethylsiloxane. 44. Polizdelek po zahtevku 35, značilen po tem, da mešanica dveh izbranih termoplastičnih polimerov vsebuje polivinilklorid v količini od 5 do 95 masnih odstotkov in termoplastični poliuretan v količini od 4,3 do 94,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3), izbrani poliorganosiloksan pa je polimetilfenilsiloksan ali polietilfenilsiloksan.A semi-finished product according to claim 35, characterized in that the mixture of the two selected thermoplastic polymers contains polyvinyl chloride in an amount of from 5 to 95% by weight and thermoplastic polyurethane in an amount of from 4.3 to 94.7% by weight, based on the total weight of the inner sheath ( 3) and the selected polyorganosiloxane is polymethylphenylsiloxane or polyethylphenylsiloxane. 45. Polizdelek po zahtevku 33 ali 34 ali 35, značilen po tem, da je glavna ojačitvena plast (4) izdelana iz sintetičnega netkanega vlaknastega materiala.Semi-finished product according to claim 33 or 34 or 35, characterized in that the main reinforcing layer (4) is made of a synthetic non-woven fibrous material. 46. Polizdelek po zahtevku 33 ali 34 ali 35, značilen po tem, da sta ločena robova (6, 7) notranjega cevastega ovoja (3), ki je povezan z ojačitveno plastjo (4), hermetično povezana, od robu do robu, soosno osi dvo slojnega polizdelka plašča.Semi-finished product according to claim 33 or 34 or 35, characterized in that the separate edges (6, 7) of the inner tubular sheath (3) connected to the reinforcing layer (4) are hermetically connected, from edge to edge, coaxially axes of the two-layer semi-finished coat. 47. Polizdelek po zahtevku 33 ali 34 ali 35, značilen po tem, da sta ločena robova (6, 7) notranjega cevastega ovoja (3), ki je povezan z ojačitveno plastjo (4), hermetično povezana tako, da se prekrivata, soosno osi dvo slojnega polizdelka plašča.Semi-finished product according to claim 33 or 34 or 35, characterized in that the separate edges (6, 7) of the inner tubular sheath (3) connected to the reinforcing layer (4) are hermetically connected so that they overlap, coaxially axes of the two-layer semi-finished coat. 48. Metoda za izdelavo dvo slojnega polizdelka plašča notranje površine cevi, kjer se notranji cevasti ovoj (3) plašča na osnovi termoplastičnih polimerov poveže z ojačitveno plastjo (4), značilna po tem, da je notranji cevasti ovoj (3) s spojitvijo površin glavne ojačitvene plasti (4) in notranjega cevastega ovoja (3), ki je izdelan iz pole filma, pridobljenega iz multikomponentnega homogenega sistema, s pomočjo mešanja v raztaljenem stanju, vsaj enega polimera izbranega iz skupine termoplastičnih polimerov, katerih relativni raztezek ni manjši od 200%, točka taljenja pa ni pod 100°C in strukturnega modifikatorja izbranega polimera, kjer sta površini pole filma in ojačitvene plasti (4) povezani, čemur sledi hermetična povezava vzdolžnih robov (6, 7) pole filma z glavno ojačitveno plastjo (4), s čimer dobimo dvo slojni polizdelek plašča, ki obsega ojačitveno plast (4) in notranjo cevasto ovojnico (3), ki sta nameščena koaksialno in drug z drugim povezana.48. A method for producing a two-layer semi-finished product of the inner surface of a tube, where the inner tubular sheath (3) of the sheath is based on thermoplastic polymers with a reinforcing layer (4), characterized in that the inner tubular sheath (3) is joined by joining the surfaces of a reinforcing layer (4) and an inner tubular sheath (3) made from a sheet of film obtained from a multicomponent homogeneous system by mixing in the molten state at least one polymer selected from the group of thermoplastic polymers having a relative elongation of not less than 200% and the melting point is not below 100 ° C and the structural modifier of the selected polymer, where the surfaces of the film sheet and the reinforcement layer (4) are connected, followed by the hermetic connection of the longitudinal edges (6, 7) of the film sheet with the main reinforcement layer (4), s thereby obtaining a two-layer semi-finished sheath comprising a reinforcing layer (4) and an inner tubular envelope (3) coaxially and interconnected. 49. Metoda po zahtevku 48, značilna po tem, da skupina termoplastičnih polimerov, katerih relativni raztezek ni manjši od 200 % in točka taljenja ni pod 100°C, obsega polietilene z nizko gostoto, super-visoko-molekularne polietilene, polipropilen, kopolimer propilena z vinilacetatom, polivinilklorid in termoplastični poliuretan, strukturni modifikator izbranega polimera pa je poliorganosiloksan izbran iz skupine, ki vključuje polimetilsiloksan, polimetilfenilsiloksan, polifenilsiloksan in polietilfenilsiloksan.49. The method of claim 48, characterized in that the group of thermoplastic polymers whose relative elongation is not less than 200% and the melting point is not below 100 ° C comprises low density polyethylene, super-high molecular weight polyethylene, polypropylene, propylene copolymer with vinyl acetate, polyvinyl chloride and thermoplastic polyurethane, and the structural modifier of the selected polymer is polyorganosiloxane selected from the group consisting of polymethylsiloxane, polymethylphenylsiloxane, polyphenylsiloxane and polyethylphenylsiloxane. 50. Metoda po zahtevku 49, značilna po tem, da je notranji cevasti ovoj (3) pridobljen iz multikomponentnega homogenega sistema z mešanjem v raztaljenem stanju, enega polimera, ali mešanice dveh polimerov izbranih iz omenjene skupine termoplastičnih polimerov v količini odA method according to claim 49, characterized in that the inner tubular sheath (3) is obtained from a multicomponent homogeneous molten system, one polymer, or a mixture of two polymers selected from said group of thermoplastic polymers in an amount of 99,3 do 99,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3) in poliorganosiloksan v količini od 0,3 do 0,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3).99.3 to 99.7% by weight, based on the total weight of the inner sheath (3) and polyorganosiloxane in an amount of 0.3 to 0.7% by weight, based on the total weight of the inner sheath (3). 51. Metoda po zahtevku 50, značilna po tem, da je izbrani termoplastični polimer polietilen z nizko gostoto, izbrani poliorganosiloksan pa je polimetilsiloksan.51. The method of claim 50, wherein the selected thermoplastic polymer is low density polyethylene and the selected polyorganosiloxane is polymethylsiloxane. 52. Metoda po zahtevku 50, značilna po tem, da je izbrani termoplastični polimer super-visoko-molekularni polietilen, izbrani poliorganosiloksan pa je polimetilsiloksan.52. The method of claim 50, wherein the selected thermoplastic polymer is super-high molecular weight polyethylene and the selected polyorganosiloxane is polymethylsiloxane. 53. Metoda po zahtevku 50, značilna po tem, da je izbrani termoplastični polimer polipropilen, izbrani poliorganosiloksan pa je polifenilsiloksan.53. The method of claim 50, wherein the selected thermoplastic polymer is polypropylene and the selected polyorganosiloxane is polyphenylsiloxane. 54. Metoda po zahtevku 50, značilna po tem, da je izbrani termoplastični polimer kopolimer propilena z vinilacetatom, izbrani poliorganosiloksan pa je polimetilfenilsiloksan.The method of claim 50, wherein the selected thermoplastic polymer is a copolymer of propylene with vinyl acetate and the selected polyorganosiloxane is polymethylphenylsiloxane. 55. Metoda po zahtevku 50, značilna po tem, da je izbrani termoplastični polimer polivinilklorid, izbrani poliorganosiloksan pa je polietilfenilsiloksan.55. The method of claim 50, wherein the selected thermoplastic polymer is polyvinyl chloride and the selected polyorganosiloxane is polyethylphenylsiloxane. 56. Metoda po zahtevku 50, značilna po tem, da je izbrani termoplastični polimer termoplastični poliuretan, izbrani poliorganosiloksan pa je polimetilfenilsiloksan.56. The method of claim 50, wherein the selected thermoplastic polymer is thermoplastic polyurethane and the selected polyorganosiloxane is polymethylphenylsiloxane. 57. Metoda po zahtevku 50, značilna po tem, da mešanica dveh izbranih termoplastičnih polimerov vsebuje polietilen z nizko gostoto v količini od 5 do 95 masnih odstotkov in polipropilen v količini od 4,3 do 94,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3), izbrani poliorganosiloksan pa je polifenilsiloksan.57. A method according to claim 50, characterized in that the mixture of the two selected thermoplastic polymers contains low density polyethylene in an amount of from 5 to 95% by weight and polypropylene in an amount of from 4.3 to 94.7% by weight, based on the total weight of the inner (3), the selected polyorganosiloxane being polyphenylsiloxane. 58. Metoda po zahtevku 50, značilna po tem, da mešanica dveh izbranih termoplastičnih polimerov vsebuje supervisoko-molekularni polietilen v količini od 5 do 95 masnih odstotkov in kopolimer propilena z vinilacetatom v količini od 4,3 do 94,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3), izbrani poliorganosiloksan pa je polimetilsiloksan.58. A method according to claim 50, characterized in that the mixture of the two selected thermoplastic polymers contains super-high molecular weight polyethylene in an amount of from 5 to 95 percent by weight and a copolymer of propylene with vinyl acetate in an amount of from 4.3 to 94.7 percent by weight, the total weight of the inner sheath (3) and the selected polyorganosiloxane is polymethylsiloxane. 59. Metoda po zahtevku 18, značilna po tem, da mešanica dveh izbranih termoplastičnih polimerov vsebuje polivinilklorid v količini od 5 do 95 masnih odstotkov in termoplastični poliuretan v količini od 4,3 do 94,7 masnih odstotkov, glede na celotno maso notranjega ovoja (3), izbrani poliorganosiloksan pa je polimetilfenilsiloksan ali polietilfenilsiloksan.59. A method according to claim 18, characterized in that the mixture of the two selected thermoplastic polymers contains polyvinyl chloride in an amount of from 5 to 95% by weight and thermoplastic polyurethane in an amount of from 4.3 to 94.7% by weight, based on the total weight of the inner sheath ( 3) and the selected polyorganosiloxane is polymethylphenylsiloxane or polyethylphenylsiloxane. 60. Metoda po zahtevku 48 ali 49 ali 50, značilna po tem, da je glavna ojačitvena plast (4) izdelana iz sintetičnega netkanega vlaknastega materiala.60. The method of claim 48 or 49 or 50, characterized in that the main reinforcing layer (4) is made of a synthetic non-woven fibrous material. 61. Metoda po zahtevku 48 ali 49 ali 50, značilna po tem, da sta vzdolžna robova (6, 7) pole filma skupaj z glavno ojačitveno plastjo (4), od robu do robu, hermetično povezana.A method according to claim 48 or 49 or 50, characterized in that the longitudinal edges (6, 7) of the film sheet together with the main reinforcing layer (4), from edge to edge, are hermetically connected. 62. Metoda po zahtevku 48 ali 49 ali 50, značilna po tem, da sta vzdolžna robova (6, 7) pole filma skupaj z glavno ojačitveno plastjo (4), hermetično povezana tako, da se prekrivata.62. A method according to claim 48 or 49 or 50, characterized in that the longitudinal edges (6, 7) of the film sheet together with the main reinforcing layer (4) are sealed so that they overlap.
SI9620121A 1996-09-18 1996-09-18 Coating for the internal surface of a pipe, method for applying the same on said surface, two-layered semi-finished part using said coating and method for making this part SI9620121B (en)

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US8053031B2 (en) 2007-07-26 2011-11-08 Raven Lining Systems Inc. Two-part epoxy composition

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AU2002329347B8 (en) * 2001-07-17 2008-12-18 Saint-Gobain Isover Compressed heat insulation housing
US9657882B2 (en) 2013-03-11 2017-05-23 Buergofol GmbH Tubular film and the use thereof

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FR2480901B1 (en) * 1980-04-18 1985-10-11 Coopetanche Sa PROCESS FOR INTERNAL TRIM OF A PIPE
FR2571822B1 (en) * 1984-10-17 1989-05-19 Trest Juzhvodoprovod METHOD FOR PROTECTING THE INTERIOR SURFACE OF A PIPE AGAINST CORROSION
DE3614963A1 (en) * 1986-03-29 1987-10-01 Roeders Ag Geb Process for producing a renewal tube for pipelines and a renewal tube produced by this process
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US8053031B2 (en) 2007-07-26 2011-11-08 Raven Lining Systems Inc. Two-part epoxy composition

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