SG127828A1 - Fluorinated alkyl substituted-.thieno[3,4-B]thiophene monomers and polymers therefrom - Google Patents

Fluorinated alkyl substituted-.thieno[3,4-B]thiophene monomers and polymers therefrom

Info

Publication number
SG127828A1
SG127828A1 SG200603239A SG200603239A SG127828A1 SG 127828 A1 SG127828 A1 SG 127828A1 SG 200603239 A SG200603239 A SG 200603239A SG 200603239 A SG200603239 A SG 200603239A SG 127828 A1 SG127828 A1 SG 127828A1
Authority
SG
Singapore
Prior art keywords
thieno
alkyl substituted
fluorinated alkyl
thiophene monomers
polymers therefrom
Prior art date
Application number
SG200603239A
Other languages
English (en)
Inventor
Steffen Zahn
Gauri Sankar Lal
William Franklin Burgoyne Jr
Kristen Elaine Minnich
Andrew Francis Nordquist
Lloyd Mahlon Robeson
Francis Joseph Waller
Original Assignee
Air Prod & Chem
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/128,538 external-priority patent/US7432340B2/en
Application filed by Air Prod & Chem filed Critical Air Prod & Chem
Publication of SG127828A1 publication Critical patent/SG127828A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D495/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/02—Magnesium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124—Intrinsically conductive polymers
    • H01B1/127—Intrinsically conductive polymers comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/30—Electrodes characterised by their material
    • H01G11/48—Conductive polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/14—Side-groups
    • C08G2261/146—Side-chains containing halogens
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/324—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed
    • C08G2261/3243—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed containing one or more sulfur atoms as the only heteroatom, e.g. benzothiophene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C08L25/12—Copolymers of styrene with unsaturated nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/18—Homopolymers or copolymers of aromatic monomers containing elements other than carbon and hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
    • H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13—Energy storage using capacitors

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
SG200603239A 2005-05-13 2006-05-11 Fluorinated alkyl substituted-.thieno[3,4-B]thiophene monomers and polymers therefrom SG127828A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/128,538 US7432340B2 (en) 2002-07-11 2005-05-13 Fluorinated alkyl substituted-thieno[3,4-]thiophene monomers and polymers therefrom
US11/418,317 US7572879B2 (en) 2002-07-11 2006-05-05 Fluorinated alkyl substituted-thieno[3,4-b]thiophene monomers and polymers therefrom

Publications (1)

Publication Number Publication Date
SG127828A1 true SG127828A1 (en) 2006-12-29

Family

ID=36937003

Family Applications (1)

Application Number Title Priority Date Filing Date
SG200603239A SG127828A1 (en) 2005-05-13 2006-05-11 Fluorinated alkyl substituted-.thieno[3,4-B]thiophene monomers and polymers therefrom

Country Status (7)

Country Link
US (1) US7572879B2 (ja)
EP (1) EP1728810B1 (ja)
JP (1) JP2006348019A (ja)
KR (2) KR100824915B1 (ja)
AT (1) ATE383385T1 (ja)
DE (1) DE602006000414T2 (ja)
SG (1) SG127828A1 (ja)

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US7071289B2 (en) 2002-07-11 2006-07-04 The University Of Connecticut Polymers comprising thieno [3,4-b]thiophene and methods of making and using the same
US7850871B2 (en) * 2004-10-13 2010-12-14 Air Products And Chemicals, Inc. Resistivity stable electrically conductive films formed from polythiophenes
US8178629B2 (en) * 2005-01-31 2012-05-15 University Of Connecticut Conjugated polymer fiber, preparation and use thereof
US7737247B2 (en) * 2005-07-11 2010-06-15 The University Of Connecticut Polymers of thieno[3,4-b]furan, method of making, and use thereof
US7746533B2 (en) 2005-07-11 2010-06-29 The University Of Connecticut Electrochromic devices utilizing very low band gap conjugated counter electrodes: preparation and use
DE112007000382T5 (de) 2006-02-16 2008-12-24 University of Connecticut, Farmington Leitfähige Polymere aus Precursorpolymeren; Verfahren zur Herstellung und ihre Verwendung
US8148548B2 (en) 2007-07-13 2012-04-03 Konarka Technologies, Inc. Heterocyclic fused selenophene monomers
US7981323B2 (en) 2007-07-13 2011-07-19 Konarka Technologies, Inc. Selenium containing electrically conductive copolymers
US7982055B2 (en) * 2007-07-13 2011-07-19 Konarka Technologies, Inc. Heterocyclic fused selenophene monomers
US8183319B2 (en) * 2007-10-31 2012-05-22 Air Products And Chemicals, Inc. Film forming additive formulations of conductive polymers
US8168671B2 (en) * 2008-06-26 2012-05-01 The University Of Connecticut Synthesis of thieno[3,4-b]thiophene, thieno[3,4-b]furan, related compounds and their derivatives and use thereof
JP5546142B2 (ja) * 2009-03-02 2014-07-09 株式会社ダイセル ヘテロ環縮環オリゴチオフェン及びその製造方法、並びにポリマー
JP2012524834A (ja) * 2009-04-24 2012-10-18 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 導電性ポリマー組成物およびそれから作製されたフィルム
US8769836B2 (en) 2010-06-22 2014-07-08 Nike, Inc. Article of footwear with color change portion and method of changing color
US8895693B2 (en) 2010-06-25 2014-11-25 Samsung Electronics Co., Ltd. Electron-donating polymers and organic solar cells including the same
US9287505B2 (en) 2010-07-08 2016-03-15 Merck Patent Gmbh Semiconducting polymers
JP2012207104A (ja) * 2011-03-29 2012-10-25 Mitsubishi Chemicals Corp ヨウ素化縮合チオフェン化合物を用いたコポリマーの製造方法、及びヨウ素化ジオキソピロロチオフェン化合物
KR101853395B1 (ko) 2011-05-23 2018-04-30 삼성전자주식회사 전자 공여체 고분자 및 이를 포함하는 태양 전지
KR101777326B1 (ko) 2011-10-05 2017-09-12 삼성전자주식회사 전자 공여체 고분자 및 이를 포함하는 유기 태양 전지
US9006568B2 (en) 2012-02-15 2015-04-14 Phillips 66 Company Synthesis of photovoltaic conjugated polymers
WO2014088795A1 (en) 2012-12-03 2014-06-12 Phillips 66 Company Benzo [1,2-b:4,5-b'] dithiophene-thienothiophene based conjugated polymers
US20150279320A1 (en) 2014-03-26 2015-10-01 Nike, Inc. Subtractive Color Change System and Method
US10355214B2 (en) 2014-03-27 2019-07-16 Lg Chem, Ltd. Copolymer and organic solar cell comprising same
US10099963B2 (en) 2015-10-01 2018-10-16 Phillips 66 Company Formation of films for organic photovoltaics
US9905769B2 (en) 2015-10-01 2018-02-27 Phillips 66 Company Process of manufacturing an electron transport material
US10418555B2 (en) 2015-10-01 2019-09-17 Phillips 66 Company Formation of films for organic photovoltaics
US10312448B2 (en) 2015-10-01 2019-06-04 Phillips 66 Company Process of manufacturing an electron transport material
US9911919B2 (en) 2015-10-01 2018-03-06 Phillips 66 Company Process of manufacturing an electron transport material
US9701692B1 (en) 2016-03-11 2017-07-11 International Business Machines Corporation Synthesis of thienothiophenes

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0144013B1 (de) * 1983-11-25 1989-01-18 MERCK PATENT GmbH Thienothiophenderivate
US6645401B2 (en) * 2001-08-17 2003-11-11 Merck Patent Gmbh Conjugated copolymers of dithienothiophene with vinylene or acetylene
US20040010115A1 (en) * 2002-07-11 2004-01-15 Sotzing Gregory Allen Polymers comprising thieno [3,4-b]thiophene and methods of making and using the same
US6695978B2 (en) * 2001-09-29 2004-02-24 Merck Patent Gesellschaft Mit Beschraenkter Haftung Mono-, oligo- and polymers of benzo[b]thiophene and 2,2′-bisbenzo[b]thiophene and their use as charge transport materials

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US7432340B2 (en) * 2002-07-11 2008-10-07 Air Products And Chemicals, Inc. Fluorinated alkyl substituted-thieno[3,4-]thiophene monomers and polymers therefrom
US7125479B2 (en) 2002-07-11 2006-10-24 The University Of Connecticut Polymeric compositions comprising thieno[3,4-b]thiophene, method of making, and use thereof
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Publication number Priority date Publication date Assignee Title
EP0144013B1 (de) * 1983-11-25 1989-01-18 MERCK PATENT GmbH Thienothiophenderivate
US6645401B2 (en) * 2001-08-17 2003-11-11 Merck Patent Gmbh Conjugated copolymers of dithienothiophene with vinylene or acetylene
US6695978B2 (en) * 2001-09-29 2004-02-24 Merck Patent Gesellschaft Mit Beschraenkter Haftung Mono-, oligo- and polymers of benzo[b]thiophene and 2,2′-bisbenzo[b]thiophene and their use as charge transport materials
US20040010115A1 (en) * 2002-07-11 2004-01-15 Sotzing Gregory Allen Polymers comprising thieno [3,4-b]thiophene and methods of making and using the same

Also Published As

Publication number Publication date
EP1728810B1 (en) 2008-01-09
EP1728810A1 (en) 2006-12-06
KR20080027469A (ko) 2008-03-27
KR100824915B1 (ko) 2008-04-23
US7572879B2 (en) 2009-08-11
DE602006000414D1 (de) 2008-02-21
KR20060117277A (ko) 2006-11-16
ATE383385T1 (de) 2008-01-15
JP2006348019A (ja) 2006-12-28
DE602006000414T2 (de) 2009-01-15
US20060223977A1 (en) 2006-10-05
KR100875224B1 (ko) 2008-12-19

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