SG11202003119RA - Polyamine-appended metal-organic frameworks for carbon dioxide separations - Google Patents

Polyamine-appended metal-organic frameworks for carbon dioxide separations

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Publication number
SG11202003119RA
SG11202003119RA SG11202003119RA SG11202003119RA SG11202003119RA SG 11202003119R A SG11202003119R A SG 11202003119RA SG 11202003119R A SG11202003119R A SG 11202003119RA SG 11202003119R A SG11202003119R A SG 11202003119RA SG 11202003119R A SG11202003119R A SG 11202003119RA
Authority
SG
Singapore
Prior art keywords
polyamine
carbon dioxide
organic frameworks
appended metal
dioxide separations
Prior art date
Application number
SG11202003119RA
Other languages
English (en)
Inventor
Simon Weston
Joseph Falkowski
Jeffrey Long
Eugene Kim
Jeffrey Martell
Phillip Milner
Rebecca Siegelman
Original Assignee
Univ California
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ California, Exxonmobil Res & Eng Co filed Critical Univ California
Publication of SG11202003119RA publication Critical patent/SG11202003119RA/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3206—Organic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3248—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3425—Regenerating or reactivating of sorbents or filter aids comprising organic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3458—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
    • B01J20/3466—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase with steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3483—Regenerating or reactivating by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3491—Regenerating or reactivating by pressure treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/202—Polymeric adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/204—Metal organic frameworks (MOF's)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/25—Coated, impregnated or composite adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/05—Biogas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40086—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by using a purge gas
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Treating Waste Gases (AREA)
  • Separation Of Gases By Adsorption (AREA)
SG11202003119RA 2017-10-31 2018-10-30 Polyamine-appended metal-organic frameworks for carbon dioxide separations SG11202003119RA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201762579717P 2017-10-31 2017-10-31
PCT/US2018/058287 WO2019089649A1 (en) 2017-10-31 2018-10-30 Polyamine-appended metal-organic frameworks for carbon dioxide separations

Publications (1)

Publication Number Publication Date
SG11202003119RA true SG11202003119RA (en) 2020-05-28

Family

ID=64427211

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11202003119RA SG11202003119RA (en) 2017-10-31 2018-10-30 Polyamine-appended metal-organic frameworks for carbon dioxide separations

Country Status (9)

Country Link
US (1) US11014067B2 (https=)
EP (1) EP3703842A1 (https=)
JP (1) JP7145211B2 (https=)
KR (1) KR102361888B1 (https=)
CN (1) CN111225730B (https=)
AU (1) AU2018360565B2 (https=)
CA (1) CA3078968A1 (https=)
SG (1) SG11202003119RA (https=)
WO (1) WO2019089649A1 (https=)

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US11458431B2 (en) * 2017-02-17 2022-10-04 The Regents Of The University Of California Amine-appended metal-organic frameworks exhibiting a new adsorption mechanism for carbon dioxide separations
WO2019108847A1 (en) 2017-11-29 2019-06-06 The Regents Of The University Of California A vanadium metal-organic framework for selective adsorption
KR102902679B1 (ko) 2019-07-15 2025-12-22 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 기체 분리를 위한 국부적 결함을 갖는 금속-유기 골격구조
WO2021010597A1 (ko) * 2019-07-16 2021-01-21 삼성전자주식회사 이산화탄소 흡착제 및 이를 포함하는 공기정화장치
US11739274B2 (en) 2019-08-20 2023-08-29 Exxon Mobil Technology and Engineering Company Metal-organic framework catalysts and their use thereof in catalytic cracking
CN116133744A (zh) * 2020-07-22 2023-05-16 马修·阿特伍德 利用电磁激发辐射解吸固体胺吸附剂以释放二氧化碳的直接空气捕集的设备、方法和系统
US11872537B2 (en) 2020-08-06 2024-01-16 ExxonMobil Technology and Engineering Company Metal-organic frameworks for carbon dioxide capture
JP7707282B2 (ja) * 2020-08-13 2025-07-14 エクソンモービル テクノロジー アンド エンジニアリング カンパニー 金属有機構造体の合成方法およびリサイクル方法
WO2022240659A1 (en) * 2021-05-12 2022-11-17 The Regents Of The University Of California Direct air capture and bioelectrochemical conversion of co2
CN113663649A (zh) * 2021-08-05 2021-11-19 华东师范大学 一种mof成型材料应用于低温二氧化碳捕获
CN116063688B (zh) * 2021-11-01 2024-07-16 广东美的白色家电技术创新中心有限公司 一种柔性金属-有机骨架材料及其制备方法
CA3236700A1 (en) * 2021-11-24 2023-06-01 ExxonMobil Technology and Engineering Company Appending amines to metal organic frameworks
US20230302393A1 (en) * 2022-03-25 2023-09-28 Xiwang Qi System and method for direct air capture of carbon dioxide utilizing a microwave desorption technique
JP2023161224A (ja) * 2022-04-25 2023-11-07 株式会社デンソー 二酸化炭素回収システム
GB202206101D0 (en) * 2022-04-27 2022-06-08 Mof Tech Limited Method and apparatus for carbon dioxide separation
KR20240108990A (ko) 2023-01-03 2024-07-10 박승우 분수 노즐장치
WO2024205921A1 (en) * 2023-03-28 2024-10-03 ExxonMobil Technology and Engineering Company Systems and methods for optimizing carbon dioxide uptake in amine-appended metal-organic frameworks
US20250250290A1 (en) * 2023-06-08 2025-08-07 Numat Technologies, Inc. Metal-Organic Framework (MOF) Compositions, Process of Making and Process of Use Thereof
WO2024258549A1 (en) * 2023-06-13 2024-12-19 ExxonMobil Technology and Engineering Company Amine-modified metal organic framework composition
AU2024355392A1 (en) * 2023-10-03 2026-03-12 The Regents Of The University Of California Direct air capture of carbon dioxide with molecular polyamines

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CN102361678A (zh) * 2009-03-20 2012-02-22 巴斯夫欧洲公司 使用用胺浸渍的金属有机骨架分离酸性气体的方法
CA2788132A1 (en) * 2010-02-12 2011-11-24 Omar M. Yaghi Organo-metallic frameworks derived from carbenophilic metals and methods of making same
EP2768608A4 (en) 2011-10-18 2015-06-03 Univ California ALKYLAMINE-FUNCTIONALIZED METAL-ORGANIC FRAMING MATERIALS FOR COMPOSITE GAS SEPARATION
US10722863B2 (en) 2011-10-18 2020-07-28 The Regents Of The University Of California Cooperative chemical adsorption of acid gases in functionalized metal-organic frameworks
WO2015164543A1 (en) 2014-04-22 2015-10-29 The Regents Of The University Of California Cooperative chemical adsorption of acid gases in functionalized metal-organic frameworks
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CN105771907B (zh) * 2016-04-11 2018-09-14 华南理工大学 一种MOFs双配体吸附材料Fe-btc(dobdc)及其制备方法

Also Published As

Publication number Publication date
AU2018360565B2 (en) 2024-08-22
KR102361888B1 (ko) 2022-02-15
CN111225730A (zh) 2020-06-02
JP7145211B2 (ja) 2022-09-30
JP2021503366A (ja) 2021-02-12
US20190126237A1 (en) 2019-05-02
EP3703842A1 (en) 2020-09-09
CA3078968A1 (en) 2019-05-09
CN111225730B (zh) 2022-07-05
WO2019089649A1 (en) 2019-05-09
KR20200071091A (ko) 2020-06-18
US11014067B2 (en) 2021-05-25
AU2018360565A1 (en) 2020-05-21

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