JP7145211B2 - 二酸化炭素の分離のためのポリアミン付加金属-有機骨格 - Google Patents
二酸化炭素の分離のためのポリアミン付加金属-有機骨格 Download PDFInfo
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- JP7145211B2 JP7145211B2 JP2020523309A JP2020523309A JP7145211B2 JP 7145211 B2 JP7145211 B2 JP 7145211B2 JP 2020523309 A JP2020523309 A JP 2020523309A JP 2020523309 A JP2020523309 A JP 2020523309A JP 7145211 B2 JP7145211 B2 JP 7145211B2
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
- B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
- B01J20/3206—Organic carriers, supports or substrates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
- B01J20/3244—Non-macromolecular compounds
- B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
- B01J20/3248—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
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- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3425—Regenerating or reactivating of sorbents or filter aids comprising organic materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
- B01J20/3458—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
- B01J20/3466—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase with steam
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3483—Regenerating or reactivating by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3491—Regenerating or reactivating by pressure treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/20—Organic adsorbents
- B01D2253/202—Polymeric adsorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/20—Organic adsorbents
- B01D2253/204—Metal organic frameworks (MOF's)
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/25—Coated, impregnated or composite adsorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/05—Biogas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40086—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by using a purge gas
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treating Waste Gases (AREA)
- Separation Of Gases By Adsorption (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762579717P | 2017-10-31 | 2017-10-31 | |
| US62/579,717 | 2017-10-31 | ||
| PCT/US2018/058287 WO2019089649A1 (en) | 2017-10-31 | 2018-10-30 | Polyamine-appended metal-organic frameworks for carbon dioxide separations |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| JP2021503366A JP2021503366A (ja) | 2021-02-12 |
| JP2021503366A5 JP2021503366A5 (https=) | 2022-07-07 |
| JPWO2019089649A5 JPWO2019089649A5 (https=) | 2022-07-07 |
| JP7145211B2 true JP7145211B2 (ja) | 2022-09-30 |
Family
ID=64427211
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020523309A Active JP7145211B2 (ja) | 2017-10-31 | 2018-10-30 | 二酸化炭素の分離のためのポリアミン付加金属-有機骨格 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US11014067B2 (https=) |
| EP (1) | EP3703842A1 (https=) |
| JP (1) | JP7145211B2 (https=) |
| KR (1) | KR102361888B1 (https=) |
| CN (1) | CN111225730B (https=) |
| AU (1) | AU2018360565B2 (https=) |
| CA (1) | CA3078968A1 (https=) |
| SG (1) | SG11202003119RA (https=) |
| WO (1) | WO2019089649A1 (https=) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11458431B2 (en) * | 2017-02-17 | 2022-10-04 | The Regents Of The University Of California | Amine-appended metal-organic frameworks exhibiting a new adsorption mechanism for carbon dioxide separations |
| WO2019108847A1 (en) | 2017-11-29 | 2019-06-06 | The Regents Of The University Of California | A vanadium metal-organic framework for selective adsorption |
| KR102902679B1 (ko) | 2019-07-15 | 2025-12-22 | 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 | 기체 분리를 위한 국부적 결함을 갖는 금속-유기 골격구조 |
| WO2021010597A1 (ko) * | 2019-07-16 | 2021-01-21 | 삼성전자주식회사 | 이산화탄소 흡착제 및 이를 포함하는 공기정화장치 |
| US11739274B2 (en) | 2019-08-20 | 2023-08-29 | Exxon Mobil Technology and Engineering Company | Metal-organic framework catalysts and their use thereof in catalytic cracking |
| CN116133744A (zh) * | 2020-07-22 | 2023-05-16 | 马修·阿特伍德 | 利用电磁激发辐射解吸固体胺吸附剂以释放二氧化碳的直接空气捕集的设备、方法和系统 |
| US11872537B2 (en) | 2020-08-06 | 2024-01-16 | ExxonMobil Technology and Engineering Company | Metal-organic frameworks for carbon dioxide capture |
| JP7707282B2 (ja) * | 2020-08-13 | 2025-07-14 | エクソンモービル テクノロジー アンド エンジニアリング カンパニー | 金属有機構造体の合成方法およびリサイクル方法 |
| WO2022240659A1 (en) * | 2021-05-12 | 2022-11-17 | The Regents Of The University Of California | Direct air capture and bioelectrochemical conversion of co2 |
| CN113663649A (zh) * | 2021-08-05 | 2021-11-19 | 华东师范大学 | 一种mof成型材料应用于低温二氧化碳捕获 |
| CN116063688B (zh) * | 2021-11-01 | 2024-07-16 | 广东美的白色家电技术创新中心有限公司 | 一种柔性金属-有机骨架材料及其制备方法 |
| CA3236700A1 (en) * | 2021-11-24 | 2023-06-01 | ExxonMobil Technology and Engineering Company | Appending amines to metal organic frameworks |
| US20230302393A1 (en) * | 2022-03-25 | 2023-09-28 | Xiwang Qi | System and method for direct air capture of carbon dioxide utilizing a microwave desorption technique |
| JP2023161224A (ja) * | 2022-04-25 | 2023-11-07 | 株式会社デンソー | 二酸化炭素回収システム |
| GB202206101D0 (en) * | 2022-04-27 | 2022-06-08 | Mof Tech Limited | Method and apparatus for carbon dioxide separation |
| KR20240108990A (ko) | 2023-01-03 | 2024-07-10 | 박승우 | 분수 노즐장치 |
| WO2024205921A1 (en) * | 2023-03-28 | 2024-10-03 | ExxonMobil Technology and Engineering Company | Systems and methods for optimizing carbon dioxide uptake in amine-appended metal-organic frameworks |
| US20250250290A1 (en) * | 2023-06-08 | 2025-08-07 | Numat Technologies, Inc. | Metal-Organic Framework (MOF) Compositions, Process of Making and Process of Use Thereof |
| WO2024258549A1 (en) * | 2023-06-13 | 2024-12-19 | ExxonMobil Technology and Engineering Company | Amine-modified metal organic framework composition |
| AU2024355392A1 (en) * | 2023-10-03 | 2026-03-12 | The Regents Of The University Of California | Direct air capture of carbon dioxide with molecular polyamines |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015504000A (ja) | 2011-10-18 | 2015-02-05 | ザ レジェンツ オブ ザ ユニヴァーシティー オブ カリフォルニア | 混合ガス分離用アルキルアミン官能化金属有機骨格 |
| US20150158013A1 (en) | 2012-08-10 | 2015-06-11 | King Abdullah University Of Science And Technology | Metal-organic materials (moms) for co2 adsorption and methods of using moms |
| WO2015126945A1 (en) | 2014-02-18 | 2015-08-27 | University Of South Florida | Metal-organic materials for c02 adsorption |
| US20170087531A1 (en) | 2011-10-18 | 2017-03-30 | The Regents Of The University Of California | Cooperative chemical adsorption of acid gases in functionalized metal-organic frameworks |
| WO2017059130A2 (en) | 2015-09-30 | 2017-04-06 | The Regents Of The University Of California | Gas purification with diamine-appended metal-organic frameworks |
| US20170106348A1 (en) | 2015-10-14 | 2017-04-20 | Korea Institute Of Energy Research | Metal-organic frameworks and process of preparing the same |
| US20170113204A1 (en) | 2012-08-10 | 2017-04-27 | University Of South Florida | Metal-organic materials for c02 adsorption |
| JP2017518169A (ja) | 2014-04-22 | 2017-07-06 | ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア | 官能化された金属−有機フレームワーク内における酸性ガスの協同化学吸着 |
| US20170246584A1 (en) | 2014-09-02 | 2017-08-31 | King Abdullah University Of Science And Technology | Trace and low concentration co2 removal methods and apparatus utilizing metal organic frameworks |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102361678A (zh) * | 2009-03-20 | 2012-02-22 | 巴斯夫欧洲公司 | 使用用胺浸渍的金属有机骨架分离酸性气体的方法 |
| CA2788132A1 (en) * | 2010-02-12 | 2011-11-24 | Omar M. Yaghi | Organo-metallic frameworks derived from carbenophilic metals and methods of making same |
| KR101468292B1 (ko) * | 2013-03-08 | 2014-12-02 | 고려대학교 산학협력단 | 이산화탄소 흡착제 |
| CN104056598A (zh) * | 2014-06-20 | 2014-09-24 | 浙江大学 | 一种MOFs基二氧化碳吸附剂及其制备方法和应用 |
| CN104226260B (zh) * | 2014-09-19 | 2016-02-10 | 湖南大学 | 一种吸附CO2的金属-有机框架材料Bi-BTC的制备与改性方法 |
| KR101707821B1 (ko) * | 2015-08-13 | 2017-02-17 | 고려대학교 산학협력단 | 마그네슘 금속-유기 골격체(Mg-MOF)의 제조 및 이의 아민 기능화 |
| CN105771907B (zh) * | 2016-04-11 | 2018-09-14 | 华南理工大学 | 一种MOFs双配体吸附材料Fe-btc(dobdc)及其制备方法 |
-
2018
- 2018-10-30 JP JP2020523309A patent/JP7145211B2/ja active Active
- 2018-10-30 EP EP18807488.4A patent/EP3703842A1/en active Pending
- 2018-10-30 CA CA3078968A patent/CA3078968A1/en active Pending
- 2018-10-30 US US16/175,708 patent/US11014067B2/en active Active
- 2018-10-30 KR KR1020207013189A patent/KR102361888B1/ko active Active
- 2018-10-30 SG SG11202003119RA patent/SG11202003119RA/en unknown
- 2018-10-30 AU AU2018360565A patent/AU2018360565B2/en active Active
- 2018-10-30 CN CN201880067344.0A patent/CN111225730B/zh active Active
- 2018-10-30 WO PCT/US2018/058287 patent/WO2019089649A1/en not_active Ceased
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015504000A (ja) | 2011-10-18 | 2015-02-05 | ザ レジェンツ オブ ザ ユニヴァーシティー オブ カリフォルニア | 混合ガス分離用アルキルアミン官能化金属有機骨格 |
| US20170087531A1 (en) | 2011-10-18 | 2017-03-30 | The Regents Of The University Of California | Cooperative chemical adsorption of acid gases in functionalized metal-organic frameworks |
| US20150158013A1 (en) | 2012-08-10 | 2015-06-11 | King Abdullah University Of Science And Technology | Metal-organic materials (moms) for co2 adsorption and methods of using moms |
| US20170113204A1 (en) | 2012-08-10 | 2017-04-27 | University Of South Florida | Metal-organic materials for c02 adsorption |
| WO2015126945A1 (en) | 2014-02-18 | 2015-08-27 | University Of South Florida | Metal-organic materials for c02 adsorption |
| JP2017518169A (ja) | 2014-04-22 | 2017-07-06 | ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア | 官能化された金属−有機フレームワーク内における酸性ガスの協同化学吸着 |
| US20170246584A1 (en) | 2014-09-02 | 2017-08-31 | King Abdullah University Of Science And Technology | Trace and low concentration co2 removal methods and apparatus utilizing metal organic frameworks |
| WO2017059130A2 (en) | 2015-09-30 | 2017-04-06 | The Regents Of The University Of California | Gas purification with diamine-appended metal-organic frameworks |
| US20170106348A1 (en) | 2015-10-14 | 2017-04-20 | Korea Institute Of Energy Research | Metal-organic frameworks and process of preparing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2018360565B2 (en) | 2024-08-22 |
| SG11202003119RA (en) | 2020-05-28 |
| KR102361888B1 (ko) | 2022-02-15 |
| CN111225730A (zh) | 2020-06-02 |
| JP2021503366A (ja) | 2021-02-12 |
| US20190126237A1 (en) | 2019-05-02 |
| EP3703842A1 (en) | 2020-09-09 |
| CA3078968A1 (en) | 2019-05-09 |
| CN111225730B (zh) | 2022-07-05 |
| WO2019089649A1 (en) | 2019-05-09 |
| KR20200071091A (ko) | 2020-06-18 |
| US11014067B2 (en) | 2021-05-25 |
| AU2018360565A1 (en) | 2020-05-21 |
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