SG11201807943UA - High metals content hydrolysis catalyst for catalytic reduction of sulfur in a gas stream - Google Patents

High metals content hydrolysis catalyst for catalytic reduction of sulfur in a gas stream

Info

Publication number
SG11201807943UA
SG11201807943UA SG11201807943UA SG11201807943UA SG11201807943UA SG 11201807943U A SG11201807943U A SG 11201807943UA SG 11201807943U A SG11201807943U A SG 11201807943UA SG 11201807943U A SG11201807943U A SG 11201807943UA SG 11201807943U A SG11201807943U A SG 11201807943UA
Authority
SG
Singapore
Prior art keywords
sulfur
gas stream
catalytic reduction
hydrolysis catalyst
metals content
Prior art date
Application number
SG11201807943UA
Other languages
English (en)
Inventor
Karl Marvin Krueger
Fernando Gabriel MALDONADO
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of SG11201807943UA publication Critical patent/SG11201807943UA/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/653—500-1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/657—Pore diameter larger than 1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20746—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20769—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/209—Other metals
    • B01D2255/2092—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/90—Physical characteristics of catalysts
    • B01D2255/92—Dimensions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Nanotechnology (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
SG11201807943UA 2016-03-23 2017-03-21 High metals content hydrolysis catalyst for catalytic reduction of sulfur in a gas stream SG11201807943UA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201662312010P 2016-03-23 2016-03-23
PCT/US2017/023318 WO2017165353A1 (fr) 2016-03-23 2017-03-21 Catalyseur d'hydrolyse à haute teneur en métaux pour réduction catalytique du soufre dans un flux gazeux

Publications (1)

Publication Number Publication Date
SG11201807943UA true SG11201807943UA (en) 2018-10-30

Family

ID=59896294

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201807943UA SG11201807943UA (en) 2016-03-23 2017-03-21 High metals content hydrolysis catalyst for catalytic reduction of sulfur in a gas stream

Country Status (12)

Country Link
US (2) US10562014B2 (fr)
EP (1) EP3433005B1 (fr)
JP (1) JP7000338B2 (fr)
KR (1) KR102353682B1 (fr)
CN (1) CN108883361B (fr)
BR (1) BR112018069469B1 (fr)
CA (1) CA3018210C (fr)
DK (1) DK3433005T3 (fr)
RU (1) RU2735774C2 (fr)
SG (1) SG11201807943UA (fr)
WO (1) WO2017165353A1 (fr)
ZA (1) ZA201806129B (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2023534281A (ja) 2020-07-17 2023-08-08 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー ガス流に含まれる硫黄の触媒還元に使用するための触媒並びにそのような触媒の製造方法及び使用方法
FR3116832B1 (fr) * 2020-11-27 2023-11-03 Ifp Energies Now Procede d’hydrodesulfuration de finition en presence d’un catalyseur sur support meso-macroporeux
FR3116829B1 (fr) * 2020-11-27 2023-11-03 Ifp Energies Now Procede d’hydrodesulfuration en presence d’un catalyseur sur support meso-macroporeux

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL6615007A (fr) 1966-10-24 1968-04-25
US3692698A (en) * 1970-12-28 1972-09-19 Exxon Research Engineering Co Hydroprocessing catalyst
US4097413A (en) * 1976-12-17 1978-06-27 Union Oil Company Of California Desulfurization process and catalyst
US4456701A (en) * 1980-06-09 1984-06-26 Chevron Research Company Hydroprocessing catalyst having bimodal pore distribution and process for preparing the catalyst
GB2135546B (en) 1983-02-23 1986-03-19 Philips Electronic Associated Polar loop transmitter
DE3429394A1 (de) 1984-08-09 1986-02-13 Süd-Chemie AG, 8000 München Verfahren und katalysator zur selektiven katalytischen hydrolyse von anorganischen schwefelverbindungen
US4945079A (en) * 1984-11-13 1990-07-31 Aluminum Company Of America Catalyst of nickel and molybdenum supported on alumina
JPS61138537A (ja) * 1984-12-11 1986-06-26 Nikki Universal Co Ltd 水素化脱硫触媒の製造方法
FR2589082B1 (fr) 1985-10-25 1989-12-01 Elf Aquitaine Procede d'elimination des composes soufres contenus dans un gaz residuaire, notamment issu d'une usine a soufre claus, avec recuperation desdits composes sous la forme de soufre
SU1373429A1 (ru) * 1986-08-01 1988-02-15 Научно-производственное объединение по разработке и внедрению нефтехимических процессов Катализатор дл гидроочистки бензиновых фракций и способ его приготовлени
FR2722429B1 (fr) 1994-07-13 1996-10-04 Rhone Poulenc Chimie Catalyseur a base d'alumine pour le traitement de gaz contenant des composes soufres, utilisation deces catalyseurs pour le traitement et procedes de traitement desdits gaz
RU2074025C1 (ru) * 1994-07-20 1997-02-27 Рашид Кулам Насиров Способ получения катализатора гидроочистки нефтяных фракций
US5609845A (en) * 1995-02-08 1997-03-11 Mobil Oil Corporation Catalytic production of hydrogen from hydrogen sulfide and carbon monoxide
IT1312337B1 (it) 1999-05-07 2002-04-15 Agip Petroli Composizione catalitica per l'upgrading di idrocarburi aventi punti di ebollizione nell'intervallo della nafta
WO2003082455A2 (fr) * 2002-03-25 2003-10-09 Tda Research, Inc. Catalyseurs et procedes d'oxydation de sulfure d'hydrogene en dioxyde de soufre et en soufre
EP2823886B1 (fr) * 2005-12-14 2019-08-14 Advanced Refining Technologies, LLC Procede de fabrication de catalyseur d'hydrotraitement
DE102007011471B4 (de) * 2006-03-09 2021-09-30 Shell Internationale Research Maatschappij B.V. Katalysatorkombination für die hydrierende Verarbeitung von Vakuumgasölen und/oder Visbreakergasölen
CN101516500A (zh) * 2006-08-03 2009-08-26 国际壳牌研究有限公司 含有钼和第ⅷ族金属的催化剂及其用于加氢脱硫氢馏分油的用途
US8142748B2 (en) 2007-09-17 2012-03-27 Shell Oil Company Catalyst composition useful in the catalytic reduction of sulfur compound contained in a gas stream and a method of making and using such composition
US20090098032A1 (en) * 2007-10-11 2009-04-16 Basf Catalysts Llc Methods of making aluminosilicate coated alumina
EP2362849A1 (fr) * 2008-11-28 2011-09-07 Shell Internationale Research Maatschappij B.V. Procédé d oxydation sélective de sulfure d'hydrogène
JP5535990B2 (ja) * 2010-08-27 2014-07-02 株式会社日立製作所 シフト触媒、ガス精製方法及び設備
EP4242171A3 (fr) * 2011-05-06 2023-11-29 Stamicarbon B.V. acting under the name of MT Innovation Center Procédé de récupération de soufre à zéro émission avec production d'hydrogène simultanée
SG2014011894A (en) * 2011-09-01 2014-05-29 Advanced Refining Technologies Llc Catalyst support and catalysts prepared therefrom
US10864503B2 (en) * 2012-09-17 2020-12-15 Shell Oil Company Process for the preparation of a hydrocracking catalyst
CN104812699B (zh) * 2012-11-08 2017-09-26 代表Mt创新中心的斯塔米卡邦有限公司 从含有nh3的进料回收硫并同时制造氢的方法
WO2015167911A1 (fr) * 2014-05-01 2015-11-05 Shell Oil Company Catalyseur et son utilisation pour l'hydrodésulfuration sélective d'un produit de départ d'hydrocarbures contenant des oléfines

Also Published As

Publication number Publication date
US20170274360A1 (en) 2017-09-28
JP7000338B2 (ja) 2022-01-19
RU2735774C2 (ru) 2020-11-09
US20200139352A1 (en) 2020-05-07
US10562014B2 (en) 2020-02-18
DK3433005T3 (da) 2022-08-29
BR112018069469B1 (pt) 2023-01-10
ZA201806129B (en) 2020-06-24
JP2019513542A (ja) 2019-05-30
CA3018210A1 (fr) 2017-09-28
CN108883361A (zh) 2018-11-23
WO2017165353A1 (fr) 2017-09-28
EP3433005A1 (fr) 2019-01-30
US11673124B2 (en) 2023-06-13
CN108883361B (zh) 2021-07-23
KR102353682B1 (ko) 2022-01-20
RU2018137031A (ru) 2020-04-23
EP3433005A4 (fr) 2019-12-04
EP3433005B1 (fr) 2022-08-10
CA3018210C (fr) 2023-10-10
BR112018069469A2 (pt) 2019-05-07
RU2018137031A3 (fr) 2020-04-27
KR20180124920A (ko) 2018-11-21

Similar Documents

Publication Publication Date Title
ZA201704022B (en) Exhaust gas purifying catalyst
GB2532342B (en) Catalyst for treating exhaust gas
ZA201704023B (en) Exhaust gas purifying catalyst
ZA201505399B (en) Method and catalyst for the simultaneous removal of carbon monoxide and nitrogen oxides from flue or exhaust gas
ZA201704021B (en) Exhaust gas purifying catalyst
GB2527398B (en) SCR method for reducing oxides of nitrogen and method for producing a catalyst for such method
GB201620253D0 (en) Diesel oxidation catalyst having a capture region for exhaust gas impurities
ZA201706506B (en) Exhaust gas purification catalyst
ZA201806129B (en) High metals content hydrolysis catalyst for catalytic reduction of sulfur in a gas stream
ZA201802111B (en) Method for purifying a voc-laden gas stream
EP2682206A4 (fr) Particules métalliques, catalyseur pour purification de gaz d'échappement les contenant, et procédé de production s'y rapportant
PL2566603T3 (pl) Sposób katalitycznego usuwania dwutlenku węgla i dwutlenku siarki z gazów odlotowych
SG11201502259SA (en) Reactor, method of decreasing the amount of solid particles in a gas stream from a reactor and use of the reactor
PL2782662T3 (pl) Sposób katalitycznego usuwania dwutlenku węgla i NOx z gazów odlotowych
ZA201701551B (en) Method for the catalytic removal of sulphur dioxide from exhaust gases
ZA201508158B (en) Exhaust gas purifying catalyst
PT2819766T (pt) Remoção de óxidos de enxofre a partir de uma corrente de fluido
ZA201706479B (en) A process for the removal of soot from a sulfurous gas stream
SG11201508093RA (en) Catalyst for the synthesis of methyl mercaptan and process for producing methyl mercaptan from synthesis gas and hydrogen sulphide
AP2016009056A0 (en) Method for removing dust and sulphur oxides from process gases
EP2888026A4 (fr) Systèmes et procédés d'élimination de matière particulaire contenue dans un flux de gaz
EP2870997A4 (fr) Catalyseur pour la purification de gaz d'émission, et son procédé de production
EP3378557A4 (fr) Poudre pour catalyseurs, et catalyseur pour purification de gaz d'échappement
EP3108961A4 (fr) Catalyseur de purification de gaz d'échappement et son procédé de production
PL3046657T3 (pl) Proces i układ biofiltra do usuwania H2S z zanieczyszczonego przez H2S strumienia gazu energetycznego zawierającego metan oraz zastosowanie takiego układu biofiltra