SG10201806669QA - Methoxycarbonylation with formic acid and methanol - Google Patents

Methoxycarbonylation with formic acid and methanol

Info

Publication number
SG10201806669QA
SG10201806669QA SG10201806669QA SG10201806669QA SG10201806669QA SG 10201806669Q A SG10201806669Q A SG 10201806669QA SG 10201806669Q A SG10201806669Q A SG 10201806669QA SG 10201806669Q A SG10201806669Q A SG 10201806669QA SG 10201806669Q A SG10201806669Q A SG 10201806669QA
Authority
SG
Singapore
Prior art keywords
methoxycarbonylation
methanol
formic acid
formic
acid
Prior art date
Application number
SG10201806669QA
Other languages
English (en)
Inventor
Sang Rui
Liu Jie
Kaiwu Dong Dr
Ralf Jackstell Dr
Dr Matthias Beller Prof
Dr Robert Franke Prof
Original Assignee
Evonik Degussa Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Degussa Gmbh filed Critical Evonik Degussa Gmbh
Publication of SG10201806669QA publication Critical patent/SG10201806669QA/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/36Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/04Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/36Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/48Separation; Purification; Stabilisation; Use of additives
    • C07C67/62Use of additives, e.g. for stabilisation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/80Constitutive chemical elements of heterogeneous catalysts of Group VIII of the Periodic Table
    • B01J2523/82Metals of the platinum group
    • B01J2523/824Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/824Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/40Non-coordinating groups comprising nitrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Pyridine Compounds (AREA)
SG10201806669QA 2017-08-08 2018-08-06 Methoxycarbonylation with formic acid and methanol SG10201806669QA (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP17185366.6A EP3441384B1 (de) 2017-08-08 2017-08-08 Methoxycarbonylierung mit ameisensäure und methanol

Publications (1)

Publication Number Publication Date
SG10201806669QA true SG10201806669QA (en) 2019-03-28

Family

ID=59683391

Family Applications (1)

Application Number Title Priority Date Filing Date
SG10201806669QA SG10201806669QA (en) 2017-08-08 2018-08-06 Methoxycarbonylation with formic acid and methanol

Country Status (8)

Country Link
US (1) US10508071B2 (de)
EP (1) EP3441384B1 (de)
JP (1) JP6823624B2 (de)
KR (1) KR102147692B1 (de)
CN (1) CN109384672A (de)
SG (1) SG10201806669QA (de)
TW (1) TWI707841B (de)
ZA (1) ZA201805275B (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024094568A1 (de) * 2022-11-04 2024-05-10 Evonik Oxeno Gmbh & Co. Kg Methoxypyridylliganden und deren einsatz in der alkoxycarbonylierung

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1176654A (en) 1966-04-04 1970-01-07 Ici Ltd Decomposition of Formic Acid.
MY127358A (en) * 2000-03-14 2006-11-30 Shell Int Research Process for the carbonylation of ethylenically unsaturated compounds
TWI301481B (en) * 2002-08-10 2008-10-01 Lucite Int Uk Ltd A catalyst system
KR101464702B1 (ko) * 2006-12-02 2014-11-26 루사이트 인터내셔널 유케이 리미티드 신규한 카르보닐화 리간드 및 에틸렌성 불포화 화합물의 카르보닐화에서 이들의 용도
GB0812297D0 (en) * 2008-07-04 2008-08-13 Lucite Int Uk Ltd Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds
GB201000078D0 (en) * 2010-01-05 2010-02-17 Lucite Int Uk Ltd Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands
DE102011007661A1 (de) 2011-04-19 2012-10-25 Leibniz-Institut Für Katalyse E.V. An Der Universität Rostock Verfahren zur Wasserstoffgewinnung durch katalytische Zersetzung von Ameisensäure
DE102011089008B4 (de) * 2011-12-19 2017-08-24 Evonik Degussa Gmbh Verfahren zur Herstellung von Estern aus Formiaten und olefinisch ungesättigten Verbindungen
MY172677A (en) * 2015-07-23 2019-12-10 Evonik Operations Gmbh Benzene-based diphosphine ligands for alkoxycarbonylation

Also Published As

Publication number Publication date
ZA201805275B (en) 2020-11-25
US10508071B2 (en) 2019-12-17
CN109384672A (zh) 2019-02-26
TWI707841B (zh) 2020-10-21
TW201910304A (zh) 2019-03-16
KR102147692B1 (ko) 2020-08-26
US20190047936A1 (en) 2019-02-14
KR20190016453A (ko) 2019-02-18
EP3441384B1 (de) 2019-12-25
JP6823624B2 (ja) 2021-02-03
EP3441384A1 (de) 2019-02-13
JP2019055939A (ja) 2019-04-11

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