SE459260B - Foerfarande foer avlaegsnande av cerium fraan polymerdispersioner - Google Patents
Foerfarande foer avlaegsnande av cerium fraan polymerdispersionerInfo
- Publication number
- SE459260B SE459260B SE8102841A SE8102841A SE459260B SE 459260 B SE459260 B SE 459260B SE 8102841 A SE8102841 A SE 8102841A SE 8102841 A SE8102841 A SE 8102841A SE 459260 B SE459260 B SE 459260B
- Authority
- SE
- Sweden
- Prior art keywords
- cerium
- resin
- dispersion
- iii
- process according
- Prior art date
Links
- 239000006185 dispersion Substances 0.000 title claims description 58
- 229910052684 Cerium Inorganic materials 0.000 title claims description 37
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 title claims description 37
- 238000000034 method Methods 0.000 title claims description 30
- 229920000642 polymer Polymers 0.000 title claims description 7
- 239000011347 resin Substances 0.000 claims description 82
- 229920005989 resin Polymers 0.000 claims description 82
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 34
- 239000002244 precipitate Substances 0.000 claims description 28
- 229920002472 Starch Polymers 0.000 claims description 27
- 235000019698 starch Nutrition 0.000 claims description 27
- 239000008107 starch Substances 0.000 claims description 27
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 22
- 235000011152 sodium sulphate Nutrition 0.000 claims description 22
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 14
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 12
- 229920000578 graft copolymer Polymers 0.000 claims description 12
- 238000000926 separation method Methods 0.000 claims description 12
- XQTIWNLDFPPCIU-UHFFFAOYSA-N cerium(3+) Chemical compound [Ce+3] XQTIWNLDFPPCIU-UHFFFAOYSA-N 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 9
- 239000003729 cation exchange resin Substances 0.000 claims description 9
- 230000003647 oxidation Effects 0.000 claims description 9
- 238000007254 oxidation reaction Methods 0.000 claims description 9
- 239000011734 sodium Substances 0.000 claims description 9
- 229910052708 sodium Inorganic materials 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 9
- 150000001768 cations Chemical class 0.000 claims description 8
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical group [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000004815 dispersion polymer Substances 0.000 claims description 5
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 claims description 5
- 229940039790 sodium oxalate Drugs 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 4
- 239000012736 aqueous medium Substances 0.000 claims description 4
- ITZXULOAYIAYNU-UHFFFAOYSA-N cerium(4+) Chemical compound [Ce+4] ITZXULOAYIAYNU-UHFFFAOYSA-N 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- OZECDDHOAMNMQI-UHFFFAOYSA-H cerium(3+);trisulfate Chemical group [Ce+3].[Ce+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O OZECDDHOAMNMQI-UHFFFAOYSA-H 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- ZMZNLKYXLARXFY-UHFFFAOYSA-H cerium(3+);oxalate Chemical compound [Ce+3].[Ce+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O ZMZNLKYXLARXFY-UHFFFAOYSA-H 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 2
- WHXSMMKQMYFTQS-BJUDXGSMSA-N (6Li)Lithium Chemical compound [6Li] WHXSMMKQMYFTQS-BJUDXGSMSA-N 0.000 claims 1
- 229940039748 oxalate Drugs 0.000 claims 1
- 239000000243 solution Substances 0.000 description 29
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 25
- 239000000178 monomer Substances 0.000 description 9
- 239000000725 suspension Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 7
- 239000000908 ammonium hydroxide Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- 239000012607 strong cation exchange resin Substances 0.000 description 7
- -1 bromate ion Chemical class 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 6
- 239000003999 initiator Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 239000003456 ion exchange resin Substances 0.000 description 4
- 229920003303 ion-exchange polymer Polymers 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Substances [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 description 3
- 150000000703 Cerium Chemical class 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 102000004139 alpha-Amylases Human genes 0.000 description 3
- 108090000637 alpha-Amylases Proteins 0.000 description 3
- 229940024171 alpha-amylase Drugs 0.000 description 3
- 239000007900 aqueous suspension Substances 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 3
- 238000010908 decantation Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 230000000977 initiatory effect Effects 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 235000014469 Bacillus subtilis Nutrition 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 229920001612 Hydroxyethyl starch Polymers 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- XMPZTFVPEKAKFH-UHFFFAOYSA-P ceric ammonium nitrate Chemical compound [NH4+].[NH4+].[Ce+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O XMPZTFVPEKAKFH-UHFFFAOYSA-P 0.000 description 2
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000010559 graft polymerization reaction Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229940050526 hydroxyethylstarch Drugs 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- TVWAXDOYLOWHJF-UHFFFAOYSA-N potassium;lithium Chemical group [Li].[K+] TVWAXDOYLOWHJF-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 239000011800 void material Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical group [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- LOPVAWVHGAWUPS-UHFFFAOYSA-M [2-hydroxy-3-(2-methylprop-2-enoyloxy)propyl]-trimethylazanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC(O)C[N+](C)(C)C LOPVAWVHGAWUPS-UHFFFAOYSA-M 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Inorganic materials [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 description 1
- 239000008366 buffered solution Substances 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 229910000421 cerium(III) oxide Inorganic materials 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- UNJPQTDTZAKTFK-UHFFFAOYSA-K cerium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Ce+3] UNJPQTDTZAKTFK-UHFFFAOYSA-K 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000003311 flocculating effect Effects 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000007420 reactivation Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- FCZYGJBVLGLYQU-UHFFFAOYSA-M sodium;2-[2-[2-[4-(2,4,4-trimethylpentan-2-yl)phenoxy]ethoxy]ethoxy]ethanesulfonate Chemical compound [Na+].CC(C)(C)CC(C)(C)C1=CC=C(OCCOCCOCCS([O-])(=O)=O)C=C1 FCZYGJBVLGLYQU-UHFFFAOYSA-M 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 229920003176 water-insoluble polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/02—Neutralisation of the polymerisation mass, e.g. killing the catalyst also removal of catalyst residues
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/09—Reaction techniques
- Y10S423/14—Ion exchange; chelation or liquid/liquid ion extraction
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/147,775 US4279791A (en) | 1980-05-08 | 1980-05-08 | Recovery of cerium from polymer dispersions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SE8102841L SE8102841L (sv) | 1981-11-09 |
| SE459260B true SE459260B (sv) | 1989-06-19 |
Family
ID=22522858
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE8102841A SE459260B (sv) | 1980-05-08 | 1981-05-06 | Foerfarande foer avlaegsnande av cerium fraan polymerdispersioner |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US4279791A (show.php) |
| JP (1) | JPS573801A (show.php) |
| AU (1) | AU545165B2 (show.php) |
| BE (1) | BE888713A (show.php) |
| BG (1) | BG41131A3 (show.php) |
| BR (1) | BR8102672A (show.php) |
| CA (1) | CA1174856A (show.php) |
| DE (1) | DE3116794A1 (show.php) |
| ES (1) | ES502299A0 (show.php) |
| FI (1) | FI69855C (show.php) |
| FR (1) | FR2482110B1 (show.php) |
| GB (1) | GB2075479B (show.php) |
| HU (1) | HU183425B (show.php) |
| IT (1) | IT1142017B (show.php) |
| MX (1) | MX158450A (show.php) |
| NL (1) | NL8102275A (show.php) |
| NZ (1) | NZ196944A (show.php) |
| PT (1) | PT72930B (show.php) |
| SE (1) | SE459260B (show.php) |
| SU (1) | SU1228778A3 (show.php) |
| YU (1) | YU42399B (show.php) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4751061A (en) * | 1987-04-30 | 1988-06-14 | Gte Products Corporation | Process for recovering scandium from waste material |
| DE19837020C1 (de) * | 1998-08-14 | 1999-09-23 | Merck Patent Gmbh | Verfahren zur Entfernung von Initiatoren aus Pfropfprodukten |
| EP1760812B1 (en) * | 2004-06-22 | 2010-12-08 | Asahi Glass Company, Limited | Liquid composition, process for its production, and process for producing membrane electrode assembly for polymer electrolyte fuel cell |
| JP2013532208A (ja) | 2010-06-16 | 2013-08-15 | カーギル インコーポレイテッド | ラテックス置換用の澱粉ベース組成物 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2694681A (en) * | 1952-03-07 | 1954-11-16 | Univ Idaho Res Foundation Inc | Recycling the complexing agent in the separation of ions by ion exchange |
| US2897050A (en) * | 1954-04-28 | 1959-07-28 | Air Reduction | Separation of rare earth values by means of a cation exchange resin |
| US2922768A (en) * | 1956-04-12 | 1960-01-26 | Mino Guido | Process for polymerization of a vinylidene monomer in the presence of a ceric salt and an organic reducing agent |
| FR1522387A (fr) * | 1966-05-20 | 1968-04-26 | Inst Textile De France | Procédé de greffage de polymères contenant des groupes hydroxyles |
| US3509084A (en) * | 1966-10-26 | 1970-04-28 | Gulf Research Development Co | Ion exchange process |
| JPS5137920A (en) * | 1974-09-28 | 1976-03-30 | Dainichiseika Color Chem | Jisuazoganryo no seizoho |
-
1980
- 1980-05-08 US US06/147,775 patent/US4279791A/en not_active Expired - Lifetime
-
1981
- 1981-04-24 GB GB8112746A patent/GB2075479B/en not_active Expired
- 1981-04-27 CA CA000376280A patent/CA1174856A/en not_active Expired
- 1981-04-27 PT PT72930A patent/PT72930B/pt unknown
- 1981-04-27 AU AU69889/81A patent/AU545165B2/en not_active Ceased
- 1981-04-27 NZ NZ196944A patent/NZ196944A/xx unknown
- 1981-04-28 BG BG051872A patent/BG41131A3/xx unknown
- 1981-04-28 ES ES502299A patent/ES502299A0/es active Granted
- 1981-04-28 DE DE19813116794 patent/DE3116794A1/de not_active Withdrawn
- 1981-04-28 MX MX187046A patent/MX158450A/es unknown
- 1981-04-30 BR BR8102672A patent/BR8102672A/pt unknown
- 1981-05-04 FR FR8108778A patent/FR2482110B1/fr not_active Expired
- 1981-05-06 SE SE8102841A patent/SE459260B/sv not_active IP Right Cessation
- 1981-05-07 SU SU813280850A patent/SU1228778A3/ru active
- 1981-05-07 HU HU811222A patent/HU183425B/hu not_active IP Right Cessation
- 1981-05-07 IT IT21569/81A patent/IT1142017B/it active
- 1981-05-07 BE BE0/204717A patent/BE888713A/fr not_active IP Right Cessation
- 1981-05-08 FI FI811419A patent/FI69855C/fi not_active IP Right Cessation
- 1981-05-08 JP JP6840381A patent/JPS573801A/ja active Granted
- 1981-05-08 NL NL8102275A patent/NL8102275A/nl not_active Application Discontinuation
- 1981-05-08 YU YU1173/81A patent/YU42399B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB2075479B (en) | 1983-06-02 |
| IT8121569A0 (it) | 1981-05-07 |
| BE888713A (fr) | 1981-11-09 |
| US4279791A (en) | 1981-07-21 |
| GB2075479A (en) | 1981-11-18 |
| FI69855B (fi) | 1985-12-31 |
| AU545165B2 (en) | 1985-07-04 |
| SE8102841L (sv) | 1981-11-09 |
| NL8102275A (nl) | 1981-12-01 |
| SU1228778A3 (ru) | 1986-04-30 |
| DE3116794A1 (de) | 1982-02-11 |
| YU42399B (en) | 1988-08-31 |
| PT72930A (en) | 1981-05-01 |
| CA1174856A (en) | 1984-09-25 |
| BR8102672A (pt) | 1982-01-26 |
| ES8203395A1 (es) | 1982-04-01 |
| NZ196944A (en) | 1983-11-18 |
| YU117381A (en) | 1983-06-30 |
| IT1142017B (it) | 1986-10-08 |
| BG41131A3 (en) | 1987-04-15 |
| HU183425B (en) | 1984-05-28 |
| FI69855C (fi) | 1986-05-26 |
| JPS573801A (en) | 1982-01-09 |
| FI811419L (fi) | 1981-11-09 |
| ES502299A0 (es) | 1982-04-01 |
| AU6988981A (en) | 1981-11-12 |
| JPH0148282B2 (show.php) | 1989-10-18 |
| FR2482110A1 (fr) | 1981-11-13 |
| PT72930B (en) | 1982-04-12 |
| FR2482110B1 (fr) | 1986-03-21 |
| MX158450A (es) | 1989-02-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2366007A (en) | Production of synthetic polymeric compositions comprising sulphonated polymerizates of poly-vinyl aryl compounds and treatment of liquid media therewith | |
| US20190134607A1 (en) | Concentrating lithium carbonate after regeneration of lithium sorbent | |
| RU2362787C2 (ru) | Высокомолекулярные полимеры, содержащие боковые группы салициловой кислоты, предназначенные для осветления щелоков в способе байера | |
| KR910003970B1 (ko) | 실리카 및 실리카 콜로이드의 제조방법 | |
| NO317851B1 (no) | Fremgangsmate for fjerning av opplost organisk karbon fra vann | |
| CA2919311A1 (en) | Reverse-phase polymerisation process | |
| US20020185443A1 (en) | Process for preparing heterodisperse chelating resins | |
| US4792403A (en) | Method of removing organic impurities from aqueous solution of hydrogen peroxide | |
| SE459260B (sv) | Foerfarande foer avlaegsnande av cerium fraan polymerdispersioner | |
| JP2005097545A (ja) | 多孔質樹脂ビーズおよびその製造方法 | |
| US4358546A (en) | Spherical porous cross-linked copolymers of chloromethylstyrene and divinylbenzene and the derivative thereof | |
| KR100236809B1 (ko) | 제올라이트의 미세여과 | |
| JPH0569583B2 (show.php) | ||
| US4785020A (en) | Method for preparation of anion exchange resins having very low chlorine content | |
| EP0625994B1 (en) | Purification of vinyl lactam polymers | |
| JP2016141738A (ja) | 水処理用樹脂及びこれを用いた純水の製造方法 | |
| JPH07100375A (ja) | 高密度大表面積吸着剤 | |
| CA1174857A (en) | Recovery of cerium from ion exchange resin | |
| DE1081228B (de) | Umgekehrtes Suspensionspolymerisations- verfahren zur Herstellung von Polymerisaten und Mischpolymerisaten | |
| US2511593A (en) | Vinyl chloride polymerization | |
| CA1110223A (en) | Partially pyrolyzed polymer emulsion coagulate | |
| EP3277626B1 (en) | Treating sulfuric acid | |
| US4409377A (en) | Suspension polymerization process | |
| JPH0521123B2 (show.php) | ||
| JP2002069128A (ja) | スルホン化法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NUG | Patent has lapsed |
Ref document number: 8102841-7 Effective date: 19900706 Format of ref document f/p: F |