SE446936B - DISPENSES FOR APPLICATION OF A PEROMON PREPARATION, CONSISTING OF CIS-VERBENOL AND METHYL BUTENOL, AGAINST BARK DRILLS AND USE THEREOF - Google Patents

DISPENSES FOR APPLICATION OF A PEROMON PREPARATION, CONSISTING OF CIS-VERBENOL AND METHYL BUTENOL, AGAINST BARK DRILLS AND USE THEREOF

Info

Publication number
SE446936B
SE446936B SE7906258A SE7906258A SE446936B SE 446936 B SE446936 B SE 446936B SE 7906258 A SE7906258 A SE 7906258A SE 7906258 A SE7906258 A SE 7906258A SE 446936 B SE446936 B SE 446936B
Authority
SE
Sweden
Prior art keywords
verbenol
cis
dispenser
preparation
pheromone
Prior art date
Application number
SE7906258A
Other languages
Swedish (sv)
Other versions
SE7906258L (en
Inventor
H-H Kauth
R L Darskus
Original Assignee
Celamerck Gmbh & Co Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celamerck Gmbh & Co Kg filed Critical Celamerck Gmbh & Co Kg
Publication of SE7906258L publication Critical patent/SE7906258L/en
Publication of SE446936B publication Critical patent/SE446936B/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N29/00Biocides, pest repellants or attractants, or plant growth regulators containing halogenated hydrocarbons
    • A01N29/04Halogen directly attached to a carbocyclic ring system
    • A01N29/06Hexachlorocyclohexane
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/18Vapour or smoke emitting compositions with delayed or sustained release
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/02Acyclic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/06Oxygen or sulfur directly attached to a cycloaliphatic ring system

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Catching Or Destruction (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

446 9560 tiden uppnås . 446 9560 time is reached.

Man har nu funnit att feromonen överraskande kan avges i önskade mängder och under en tillräckligt lång tid genom att den inne- slutes i plastfolie av lämplig sort och tjocklek. Man kunde inte vänta sig att feromonen på detta sätt skulle kunna utportioneras framgångsrikt, då betydande skillnader föreligger mellan kompo- nenterna med avseende på ångtrycket KS)-cis-verbenol: Kpzo torr l20°C; metylbutenol: Kp760 torr 99°C) såväl som på molekyl- strukturen.It has now been found that the pheromone can surprisingly be released in desired amounts and for a sufficiently long time by enclosing it in plastic foil of a suitable variety and thickness. One could not expect that the pheromone could be successfully dispensed in this way, as there are significant differences between the components with respect to the vapor pressure KS) -cis-verbenol: Kpzo dry 120 ° C; methylbutenol: Kp760 dry 99 ° C) as well as on the molecular structure.

För beläggningen lämpade plastfolier kan bestå av polyvinylklo- rid, polyamider, polyvinylidenklorid och framför allt polyeten med en tjocklek av ungefär 20-100 pm. Även sedvanliga laminat- folier, t{ex. på basis av cellulosa/polyvinylidenklorid eller polyvinylidenklorid/polyvinylklorid, kan användas. Feromonen påföres lämpligen på en bärare med sugförmåga, exempelvis en svampduk.Plastic foils suitable for the coating can consist of polyvinyl chloride, polyamides, polyvinylidene chloride and, above all, polyethylene with a thickness of approximately 20-100 μm. Even conventional laminate foils, e.g. based on cellulose / polyvinylidene chloride or polyvinylidene chloride / polyvinyl chloride, can be used. The pheromone is suitably applied to a carrier with suction power, for example a sponge cloth.

En applikationsenhet enligt uppfinningen ("dispenserf) kan fram- ställas genom att man i en ungefär 9 cm lång bit av en slang av högtryckspolyeten (väggtjocklek ca. 50 pm, diameter ca. 5,5 cm) insvetsar en 6x4 cmz stor, flera mm tjock bit av en svamp- duk, indränkt med feromonlösning. Den ena svetssömmen befinner sig vid änden av slangen, den andra på ungefär 1,5 cm avstånd från slangens andra ände; därigenom erhålles en lask för att fästa dispensern, t.ex. vid fångträdet. Som feromon användes en lösning av 100 mg (S)-cis-verbenol i 1900 mg metylbutenol per dispenser. Den biologiska effekten kvarstår under minst åtta veckor, avgivningskvoten ligger vid ca. 0,025-0,04 mg/timme för (S)-cis-verbenol och ca. l,0-2,2 mg/time för metylbutenol vid en konstant temperatur av 25°C.An application unit according to the invention ("dispenser) can be manufactured by welding a 6x4 cm 2, several mm, into a piece of high-pressure polyethylene (wall thickness approx. 50 μm, diameter approx. 5.5 cm) in an approximately 9 cm long piece. thick piece of a sponge cloth, soaked with pheromone solution, one weld seam is located at the end of the hose, the other at a distance of about 1.5 cm from the other end of the hose, thereby obtaining a weld to attach the dispenser, e.g. As a pheromone, a solution of 100 mg (S) -cis-verbenol in 1900 mg methylbutenol per dispenser was used.The biological effect remains for at least eight weeks, the release rate is about 0.025-0.04 mg / hour for (S) -cis-verbenol and about 1.0-2.2 mg / hour for methylbutenol at a constant temperature of 25 ° C.

I stället fördethär använda mängdförhållandet av l:l9 kan den båda komponenterna användas i andra förhållanden mellan 1:10 och 1:30.Instead of using the ratio of 1: 19, the two components can be used in other ratios between 1:10 and 1:30.

Beståndsdelarna i den aktiva substanskombinationen kan på samma 446 936 sätt insvetsas separat. Genom användning av olika foliesorter eller folier av olika tjocklek kan avgivningskvoten och av- givningsförhållandet ändras, om så önskas.The constituents of the active substance combination can be welded separately in the same 446,936 manner. By using different foil types or foils of different thickness, the release ratio and the release ratio can be changed, if desired.

För lagringen förseglas dispensern lämpligen i en aluminium- påse för att förhindra en störande förlust av feromon.For storage, the dispenser is conveniently sealed in an aluminum bag to prevent a disturbing loss of pheromone.

Användningen av medlen enligt uppfinningen sker på så sätt att en eller flera dispenser fästes i granodlingar vid en granstam i början av borrarnas flygtid.]Istället för granstammar kan även ungefär 2 m långa stockar samt rötangripet eller av vilda djur avgnagt trä användas som fångträd. Även som fällor utformade anordningar kan användas som bärare för dispensern.The means according to the invention are used in such a way that one or more dispensers are attached to spruce plantations at a spruce trunk at the beginning of the borers' flight time.] Devices designed as traps can also be used as a carrier for the dispenser.

För att döda barkborrarna behandlas fångträden lämpligen med en mot borrarna verksam insekticid, exempelvis med lindan.To kill the bark borers, the captive trees are suitably treated with an insecticide effective against the borers, for example with linden.

Vid ett jämförande försök i granodlingar_visade det sig att dispensern enligt uppfinningen under en 8 veckors period under samma betingelser lockade till sig lika många barkborrar som de tidigare kända kapslarna med feromonlösning. Kapslarna måste dock på nytt fyllas med feromonlösning under den femte veckan.In a comparative experiment in spruce plantations it was found that the dispenser according to the invention for an 8 week period under the same conditions attracted as many bark borers as the previously known capsules with pheromone solution. However, the capsules must be refilled with pheromone solution during the fifth week.

Vid ett försök med den ovan beskrivna dispensern (1900 mg metylbutenol/100 mg S-cis-verbenol) lockades och fångades under iakttagelsetiden 6 729 barkborrar.In an experiment with the above-described dispenser (1900 mg methylbutenol / 100 mg S-cis-verbenol) 6,729 bark borers were lured and caught during the observation period.

Vid separat försegling av 2000 mg metylbutenol och 50 mg kris- tallin S-cis-verbenol i 50 pm stark polyetenfolie (avgivning vid konstant temperatur av 2500: 18-35 pg/timme) uppgick under samma tidsperiod antalet fångade barkborrar till 5 220.With separate sealing of 2000 mg of methylbutenol and 50 mg of crystalline S-cis-verbenol in 50 [mu] m strong polyethylene film (release at a constant temperature of 2500: 18-35 pg / hour), the number of bark borers caught during the same period was 5,220.

Claims (7)

44eg9se PATENTKRAV44eg9se PATENTKRAV 1. l. Dispenser för applikation av ett feromonpreparat, bestående av cis-verbenol och metylbutenol, mot barkborrar (Ips typographus), k ä n n e t e c k n a d därav, att feromonpreparatet föreligger indränkt på en porös bärare innesluten í en polyetenpåse med en väggtjocklek av 20-100 pm.1. A dispenser for the application of a pheromone preparation, consisting of cis-verbenol and methylbutenol, against bark borers (Ips typographus), characterized in that the pheromone preparation is soaked on a porous support enclosed in a polyethylene bag with a wall thickness of 20-100 pm. 2. Dispenser enligt patentkravet 1, k ä n n e t e c k n a d därav att den porösa bäraren är en svampduk.Dispenser according to claim 1, characterized in that the porous carrier is a sponge cloth. 3. Dispenser enligt patentkraven 1 och 2, k ä n n e t e c k - n a d däravj att feromonpreparatet ntgör en lösning av (S)-cis-verbenol i metylbutenol, företrädesvis i ett förhål- lande av l=lo till 1:30. 'Dispenser according to claims 1 and 2, characterized in that the pheromone preparation forms a solution of (S) -cis-verbenol in methylbutenol, preferably in a ratio of 1 = 10 to 1:30. ' 4. Dispenser enligt patentkraven l till 3, k ä n n e - t e c k n a d därav, att feromonkomponenterna föreligger insvetsade var för sig.Dispenser according to claims 1 to 3, characterized in that the pheromone components are welded separately. 5. Dispenser enligt patentkraven l till 4, k ä n n e - _ t e c k n a d därav, att polyetenpåsarna har en väggtjocklek , av 50 pm. I5. A dispenser according to claims 1 to 4, characterized in that the polyethylene bags have a wall thickness of 50 μm. IN 6. Användning av en dispenser enligt patentkravet l för bekämpning av barkborrar (Ips typographus).Use of a dispenser according to claim 1 for controlling bark borers (Ips typographus). 7. Användning enligt patentkravet 6 av dispensern fördelade ii granodlingar. 1 i x ...,..... _... 4Use according to claim 6 of the dispenser distributed in spruce plantations. 1 i x ..., ..... _... 4
SE7906258A 1978-07-22 1979-07-20 DISPENSES FOR APPLICATION OF A PEROMON PREPARATION, CONSISTING OF CIS-VERBENOL AND METHYL BUTENOL, AGAINST BARK DRILLS AND USE THEREOF SE446936B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19782832248 DE2832248A1 (en) 1978-07-22 1978-07-22 DISPENSER FOR THE APPLICATION OF PHEROMONES

Publications (2)

Publication Number Publication Date
SE7906258L SE7906258L (en) 1980-01-23
SE446936B true SE446936B (en) 1986-10-20

Family

ID=6045090

Family Applications (1)

Application Number Title Priority Date Filing Date
SE7906258A SE446936B (en) 1978-07-22 1979-07-20 DISPENSES FOR APPLICATION OF A PEROMON PREPARATION, CONSISTING OF CIS-VERBENOL AND METHYL BUTENOL, AGAINST BARK DRILLS AND USE THEREOF

Country Status (12)

Country Link
JP (1) JPS5519276A (en)
AT (1) AT370584B (en)
CH (1) CH642230A5 (en)
CS (1) CS213311B2 (en)
DD (1) DD144856A5 (en)
DE (1) DE2832248A1 (en)
FI (1) FI64492C (en)
FR (1) FR2431254A1 (en)
NO (1) NO150302C (en)
PL (1) PL120659B1 (en)
SE (1) SE446936B (en)
SU (1) SU984393A3 (en)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2945655A1 (en) * 1979-11-12 1981-05-21 Celamerck Gmbh & Co Kg, 6507 Ingelheim DEVICE FOR THE DELIVERY OF PHERMONES
IT1194595B (en) * 1979-11-29 1988-09-22 Montedison Spa SOLID FORMULATIONS CONTAINING FERORMONES
IT1129711B (en) * 1980-01-23 1986-06-11 Montedison Spa SOLID FORMULATIONS CONTAINING FERORMONES
JPS5991174A (en) * 1982-11-15 1984-05-25 Nitto Electric Ind Co Ltd Preparation of tape with double-faced adhesive piece
NZ206613A (en) * 1982-12-20 1987-01-23 B J Morrison Making pesticidal sheets
GB2150834B (en) * 1983-10-08 1988-03-23 Fumakilla Ltd Pest control sheet and device for indicating the termination of its effectiveness
DE3430211A1 (en) * 1984-08-17 1986-02-27 Celamerck Gmbh & Co Kg, 6507 Ingelheim INSECT LURE
DE3543297C2 (en) * 1984-12-10 1994-10-27 Shell Int Research Process for controlling bark beetles
DE3541467A1 (en) * 1985-11-23 1987-05-27 Celamerck Gmbh & Co Kg Insect attractant
JPS62181203A (en) * 1986-02-05 1987-08-08 Shin Etsu Chem Co Ltd Simultaneous release controlling of sex pheromone of different insect pest
DE3628091A1 (en) * 1986-08-19 1988-02-25 Basf Ag AGENTS, ESPECIALLY FOR THE DISTRIBUTION OF PHEROMONES
GB8906382D0 (en) * 1989-03-20 1989-05-04 Univ Southampton Pheromone baits for social insects
DE3927243A1 (en) * 1989-08-18 1991-02-21 Basf Ag DEVICE FOR COMBATING BORK BEETLES, IN PARTICULAR THE BOOK PRINTER
DE4343337A1 (en) * 1993-12-18 1995-06-22 Ulrich Wilhelm Device for retaining bait for bark beetles
DE102004048579A1 (en) 2004-10-04 2006-04-13 Contitech Elastomer-Beschichtungen Gmbh Material as a pheromone dispenser for attracting in particular spruce bark beetles using a carrier material
JP4719851B2 (en) * 2005-02-18 2011-07-06 独立行政法人森林総合研究所 Oak oyster beetle assemblage pheromone, Oak moth beetle attractant and pheromone trap containing the pheromone
US8801879B2 (en) 2007-04-26 2014-08-12 Hitachi Chemical Company, Ltd. Method for manufacturing multilayer film
AR074951A1 (en) 2008-12-30 2011-02-23 Basf Se PHEROMONE DISPENSER
US20120126024A1 (en) 2010-11-18 2012-05-24 Boyd Maurice M Methods and systems to deliver volatile compounds
US9173389B2 (en) 2010-11-18 2015-11-03 Auburn University Systems and methods to deliver and maintain volatile compounds
US9185897B2 (en) 2010-11-18 2015-11-17 Auburn University Methods to deliver and maintain volatile compounds

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AR220507A1 (en) * 1975-09-26 1980-11-14 Albany Int Corp DEVICE TO SPREAD A VAPORIZABLE MATERIAL BY DIFFUSION OF STEAM, IN A DEFAULT PROPORTION
NO138235C (en) * 1977-01-13 1978-08-02 Borregaard Ind PREPARATION FOR ATTRACTION OF SPRINE BARKET BEETLES

Also Published As

Publication number Publication date
AT370584B (en) 1983-04-11
SU984393A3 (en) 1982-12-23
CH642230A5 (en) 1984-04-13
JPS5519276A (en) 1980-02-09
FI792274A (en) 1980-01-23
CS213311B2 (en) 1982-04-09
NO150302B (en) 1984-06-18
PL217278A1 (en) 1980-05-05
ATA475779A (en) 1982-09-15
PL120659B1 (en) 1982-03-31
FI64492B (en) 1983-08-31
SE7906258L (en) 1980-01-23
FR2431254A1 (en) 1980-02-15
DE2832248A1 (en) 1980-01-31
NO150302C (en) 1984-09-26
DD144856A5 (en) 1980-11-12
NO792405L (en) 1980-01-23
FI64492C (en) 1983-12-12

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