SE400552B - Forfarande for asymmetrisk hydrering av en beta-substituerad alfa-acylaminoakrylsyra i nervaro av en katalysator i form av ett metallkoordinationskomplex i kombination med en optiskt aktiv ligande - Google Patents
Forfarande for asymmetrisk hydrering av en beta-substituerad alfa-acylaminoakrylsyra i nervaro av en katalysator i form av ett metallkoordinationskomplex i kombination med en optiskt aktiv ligandeInfo
- Publication number
- SE400552B SE400552B SE7106040A SE604071A SE400552B SE 400552 B SE400552 B SE 400552B SE 7106040 A SE7106040 A SE 7106040A SE 604071 A SE604071 A SE 604071A SE 400552 B SE400552 B SE 400552B
- Authority
- SE
- Sweden
- Prior art keywords
- beta
- catalyst
- procedure
- combination
- coordination complex
- Prior art date
Links
- 239000002253 acid Substances 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
- 150000004696 coordination complex Chemical class 0.000 title 1
- 230000036571 hydration Effects 0.000 title 1
- 238000006703 hydration reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 230000003287 optical effect Effects 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2291—Olefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0073—Rhodium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/32—Esters thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/34—Halides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/66—Arsenic compounds
- C07F9/70—Organo-arsenic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/825—Osmium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/827—Iridium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/828—Platinum
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US3647170A | 1970-05-11 | 1970-05-11 | |
US12211671A | 1971-03-08 | 1971-03-08 |
Publications (1)
Publication Number | Publication Date |
---|---|
SE400552B true SE400552B (sv) | 1978-04-03 |
Family
ID=26713195
Family Applications (5)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SE7106040A SE400552B (sv) | 1970-05-11 | 1971-05-10 | Forfarande for asymmetrisk hydrering av en beta-substituerad alfa-acylaminoakrylsyra i nervaro av en katalysator i form av ett metallkoordinationskomplex i kombination med en optiskt aktiv ligande |
SE7409525A SE410463B (sv) | 1970-05-11 | 1974-07-22 | Metylcyklohexyl-o-anisylfosfin till anvendning som mellanprodukt for framstellning av optiskt aktiva hydreringskatalysatorer |
SE7409524A SE412394B (sv) | 1970-05-11 | 1974-07-22 | Forening for anvendning som katalysator vid asymmetrisk hydrering. |
SE7900354A SE430219B (sv) | 1970-05-11 | 1979-01-15 | Forening till anvendning som katalysator for asymmetrisk hydrering av beta-substituerade alfa-acylaminoakrylsyror och/eller salter derav |
SE7900355A SE430220B (sv) | 1970-05-11 | 1979-01-15 | Forening till anvendning som katalysator for asymmetrisk hydrering av beta-substituerade alfa-acylaminoakrylsyror och/eller salter derav |
Family Applications After (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SE7409525A SE410463B (sv) | 1970-05-11 | 1974-07-22 | Metylcyklohexyl-o-anisylfosfin till anvendning som mellanprodukt for framstellning av optiskt aktiva hydreringskatalysatorer |
SE7409524A SE412394B (sv) | 1970-05-11 | 1974-07-22 | Forening for anvendning som katalysator vid asymmetrisk hydrering. |
SE7900354A SE430219B (sv) | 1970-05-11 | 1979-01-15 | Forening till anvendning som katalysator for asymmetrisk hydrering av beta-substituerade alfa-acylaminoakrylsyror och/eller salter derav |
SE7900355A SE430220B (sv) | 1970-05-11 | 1979-01-15 | Forening till anvendning som katalysator for asymmetrisk hydrering av beta-substituerade alfa-acylaminoakrylsyror och/eller salter derav |
Country Status (16)
Country | Link |
---|---|
JP (1) | JPS5320011B1 (no) |
BE (1) | BE766960A (no) |
CA (1) | CA937573A (no) |
CH (1) | CH563346A5 (no) |
DE (1) | DE2123063C3 (no) |
FI (1) | FI55992C (no) |
FR (1) | FR2100644A1 (no) |
HU (1) | HU164803B (no) |
IL (1) | IL36804A (no) |
IT (1) | IT1019513B (no) |
NL (1) | NL155004B (no) |
NO (1) | NO142075C (no) |
RO (1) | RO80693A (no) |
SE (5) | SE400552B (no) |
SU (2) | SU640659A3 (no) |
YU (1) | YU35559B (no) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4008281A (en) | 1973-12-03 | 1977-02-15 | Monsanto Company | Asymmetric catalysis |
US4376870A (en) * | 1980-12-05 | 1983-03-15 | Monsanto Company | Optically active phosphine compounds |
EP0077099A3 (en) * | 1981-10-08 | 1983-08-03 | ANIC S.p.A. | Process for preparing amino acids and their esters |
-
1971
- 1971-05-07 NL NL717106286A patent/NL155004B/xx not_active IP Right Cessation
- 1971-05-10 JP JP3056471A patent/JPS5320011B1/ja active Pending
- 1971-05-10 HU HUMO793A patent/HU164803B/hu not_active IP Right Cessation
- 1971-05-10 SE SE7106040A patent/SE400552B/xx unknown
- 1971-05-10 FI FI1283/71A patent/FI55992C/fi active
- 1971-05-10 IL IL36804A patent/IL36804A/xx unknown
- 1971-05-10 FR FR7116805A patent/FR2100644A1/fr active Granted
- 1971-05-10 DE DE2123063A patent/DE2123063C3/de not_active Expired
- 1971-05-10 SU SU711654953A patent/SU640659A3/ru active
- 1971-05-10 RO RO7166836A patent/RO80693A/ro unknown
- 1971-05-10 NO NO1757/71A patent/NO142075C/no unknown
- 1971-05-10 CH CH689171A patent/CH563346A5/xx not_active IP Right Cessation
- 1971-05-10 CA CA112638A patent/CA937573A/en not_active Expired
- 1971-05-10 IT IT24322/71A patent/IT1019513B/it active
- 1971-05-10 BE BE766960A patent/BE766960A/xx not_active IP Right Cessation
- 1971-05-11 YU YU1160/71A patent/YU35559B/xx unknown
-
1974
- 1974-02-14 SU SU1995600A patent/SU526279A3/ru active
- 1974-07-22 SE SE7409525A patent/SE410463B/xx unknown
- 1974-07-22 SE SE7409524A patent/SE412394B/xx unknown
-
1979
- 1979-01-15 SE SE7900354A patent/SE430219B/sv unknown
- 1979-01-15 SE SE7900355A patent/SE430220B/sv unknown
Also Published As
Publication number | Publication date |
---|---|
YU116071A (en) | 1980-10-31 |
IT1019513B (it) | 1977-11-30 |
FR2100644A1 (en) | 1972-03-24 |
FI55992B (fi) | 1979-07-31 |
SE7409524L (sv) | 1974-07-22 |
DE2123063B2 (de) | 1977-11-24 |
JPS5320011B1 (no) | 1978-06-24 |
SE430220B (sv) | 1983-10-31 |
SE410463B (sv) | 1979-10-15 |
SE7409525L (sv) | 1974-07-22 |
CH563346A5 (no) | 1975-06-30 |
FI55992C (fi) | 1979-11-12 |
IL36804A (en) | 1978-06-15 |
SU526279A3 (ru) | 1976-08-25 |
BE766960A (fr) | 1971-11-10 |
SE7900355L (sv) | 1979-01-15 |
HU164803B (no) | 1974-04-11 |
DE2123063C3 (de) | 1978-07-20 |
NO142075C (no) | 1980-06-25 |
IL36804A0 (en) | 1971-07-28 |
DE2123063A1 (de) | 1971-12-02 |
NO142075B (no) | 1980-03-17 |
YU35559B (en) | 1981-04-30 |
SU640659A3 (ru) | 1978-12-30 |
SE412394B (sv) | 1980-03-03 |
SE430219B (sv) | 1983-10-31 |
RO80693A (ro) | 1982-12-06 |
CA937573A (en) | 1973-11-27 |
NL7106286A (no) | 1971-11-15 |
FR2100644B1 (no) | 1973-06-08 |
NL155004B (nl) | 1977-11-15 |
SE7900354L (sv) | 1979-01-15 |
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