SE400552B - PROCEDURE FOR ASYMMETRIC HYDRATION OF A BETA-SUBSTITUTED ALFA ACYLAMINOACRYLIC ACID IN THE PRESENCE OF A CATALYST IN THE FORM OF A METAL COORDINATION COMPLEX IN COMBINATION WITH AN OPTICAL ACTIVE - Google Patents

PROCEDURE FOR ASYMMETRIC HYDRATION OF A BETA-SUBSTITUTED ALFA ACYLAMINOACRYLIC ACID IN THE PRESENCE OF A CATALYST IN THE FORM OF A METAL COORDINATION COMPLEX IN COMBINATION WITH AN OPTICAL ACTIVE

Info

Publication number
SE400552B
SE400552B SE7106040A SE604071A SE400552B SE 400552 B SE400552 B SE 400552B SE 7106040 A SE7106040 A SE 7106040A SE 604071 A SE604071 A SE 604071A SE 400552 B SE400552 B SE 400552B
Authority
SE
Sweden
Prior art keywords
beta
catalyst
procedure
combination
coordination complex
Prior art date
Application number
SE7106040A
Other languages
Swedish (sv)
Inventor
W S Knowles
M J Sabacky
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of SE400552B publication Critical patent/SE400552B/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073Rhodium compounds
    • C07F15/008Rhodium compounds without a metal-carbon linkage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2291Olefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/36Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073Rhodium compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/30Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/32Esters thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/30Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/34Halides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40Esters thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/50Organo-phosphines
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/50Organo-phosphines
    • C07F9/53Organo-phosphine oxides; Organo-phosphine thioxides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/66Arsenic compounds
    • C07F9/70Organo-arsenic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60Reduction reactions, e.g. hydrogenation
    • B01J2231/64Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/821Ruthenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/824Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/825Osmium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/827Iridium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/828Platinum

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Indole Compounds (AREA)
SE7106040A 1970-05-11 1971-05-10 PROCEDURE FOR ASYMMETRIC HYDRATION OF A BETA-SUBSTITUTED ALFA ACYLAMINOACRYLIC ACID IN THE PRESENCE OF A CATALYST IN THE FORM OF A METAL COORDINATION COMPLEX IN COMBINATION WITH AN OPTICAL ACTIVE SE400552B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US3647170A 1970-05-11 1970-05-11
US12211671A 1971-03-08 1971-03-08

Publications (1)

Publication Number Publication Date
SE400552B true SE400552B (en) 1978-04-03

Family

ID=26713195

Family Applications (5)

Application Number Title Priority Date Filing Date
SE7106040A SE400552B (en) 1970-05-11 1971-05-10 PROCEDURE FOR ASYMMETRIC HYDRATION OF A BETA-SUBSTITUTED ALFA ACYLAMINOACRYLIC ACID IN THE PRESENCE OF A CATALYST IN THE FORM OF A METAL COORDINATION COMPLEX IN COMBINATION WITH AN OPTICAL ACTIVE
SE7409525A SE410463B (en) 1970-05-11 1974-07-22 METHYLYCLOHEXYL-O-ANISYLPHOSPHINE FOR USE AS AN INTERMEDIATE FOR THE PREPARATION OF OPTICALLY ACTIVE HYDRATION CATALYSTS
SE7409524A SE412394B (en) 1970-05-11 1974-07-22 ASSOCIATION FOR APPLICATION AS A CATALYST AT THEY ASYMMETRIC HYDROGEN.
SE7900354A SE430219B (en) 1970-05-11 1979-01-15 SUMMARY OF USE AS A CATALYST FOR ASYMMETRIC HYDRATION OF BETA-SUBSTITUTED ALFA ACYLAMINOACRYL ACIDS AND / OR SALTS THEREOF
SE7900355A SE430220B (en) 1970-05-11 1979-01-15 SUMMARY OF USE AS A CATALYST FOR ASYMMETRIC HYDRATION OF BETA-SUBSTITUTED ALFA ACYLAMINOACRYL ACIDS AND / OR SALTS THEREOF

Family Applications After (4)

Application Number Title Priority Date Filing Date
SE7409525A SE410463B (en) 1970-05-11 1974-07-22 METHYLYCLOHEXYL-O-ANISYLPHOSPHINE FOR USE AS AN INTERMEDIATE FOR THE PREPARATION OF OPTICALLY ACTIVE HYDRATION CATALYSTS
SE7409524A SE412394B (en) 1970-05-11 1974-07-22 ASSOCIATION FOR APPLICATION AS A CATALYST AT THEY ASYMMETRIC HYDROGEN.
SE7900354A SE430219B (en) 1970-05-11 1979-01-15 SUMMARY OF USE AS A CATALYST FOR ASYMMETRIC HYDRATION OF BETA-SUBSTITUTED ALFA ACYLAMINOACRYL ACIDS AND / OR SALTS THEREOF
SE7900355A SE430220B (en) 1970-05-11 1979-01-15 SUMMARY OF USE AS A CATALYST FOR ASYMMETRIC HYDRATION OF BETA-SUBSTITUTED ALFA ACYLAMINOACRYL ACIDS AND / OR SALTS THEREOF

Country Status (16)

Country Link
JP (1) JPS5320011B1 (en)
BE (1) BE766960A (en)
CA (1) CA937573A (en)
CH (1) CH563346A5 (en)
DE (1) DE2123063C3 (en)
FI (1) FI55992C (en)
FR (1) FR2100644A1 (en)
HU (1) HU164803B (en)
IL (1) IL36804A (en)
IT (1) IT1019513B (en)
NL (1) NL155004B (en)
NO (1) NO142075C (en)
RO (1) RO80693A (en)
SE (5) SE400552B (en)
SU (2) SU640659A3 (en)
YU (1) YU35559B (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4008281A (en) 1973-12-03 1977-02-15 Monsanto Company Asymmetric catalysis
US4194051A (en) 1975-08-25 1980-03-18 Monsanto Company Asymmetric catalysis
US4376870A (en) * 1980-12-05 1983-03-15 Monsanto Company Optically active phosphine compounds
EP0077099A3 (en) * 1981-10-08 1983-08-03 ANIC S.p.A. Process for preparing amino acids and their esters

Also Published As

Publication number Publication date
IT1019513B (en) 1977-11-30
FI55992B (en) 1979-07-31
DE2123063B2 (en) 1977-11-24
SU640659A3 (en) 1978-12-30
CA937573A (en) 1973-11-27
YU116071A (en) 1980-10-31
SE7900355L (en) 1979-01-15
SE7900354L (en) 1979-01-15
JPS5320011B1 (en) 1978-06-24
SE430220B (en) 1983-10-31
FR2100644B1 (en) 1973-06-08
SE430219B (en) 1983-10-31
BE766960A (en) 1971-11-10
FR2100644A1 (en) 1972-03-24
SE7409525L (en) 1974-07-22
DE2123063A1 (en) 1971-12-02
FI55992C (en) 1979-11-12
IL36804A (en) 1978-06-15
HU164803B (en) 1974-04-11
DE2123063C3 (en) 1978-07-20
YU35559B (en) 1981-04-30
SE7409524L (en) 1974-07-22
NO142075B (en) 1980-03-17
NL7106286A (en) 1971-11-15
RO80693A (en) 1982-12-06
CH563346A5 (en) 1975-06-30
SE412394B (en) 1980-03-03
SU526279A3 (en) 1976-08-25
IL36804A0 (en) 1971-07-28
NO142075C (en) 1980-06-25
NL155004B (en) 1977-11-15
SE410463B (en) 1979-10-15

Similar Documents

Publication Publication Date Title
BE768058A (en) IMPROVEMENTS TO DIAPER CARRIERS FOR BABIES
SE428761B (en) CATALYST
FI54465C (en) ANORDINATION FOR CLEANING AV ETT VERKTYG I EN GLASBEARBETNINGSMASKIN
IT963179B (en) IMPROVEMENTS IN OR RELATING TO LASERS
DK130683B (en) Pesticidally active pyrimidinylphosphoric acid esters.
IT968027B (en) IMPROVEMENTS RELATING TO DENTALS
AT314931B (en) PHOSPHATING SOLUTIONS
IT953166B (en) SPOOL BODY
FI55730B (en) GALVANISK CELL FOER BESTAEMNING AV SYREHALTEN I ETT FLUIDUM MED HOEG TEMPERATUR
SE400552B (en) PROCEDURE FOR ASYMMETRIC HYDRATION OF A BETA-SUBSTITUTED ALFA ACYLAMINOACRYLIC ACID IN THE PRESENCE OF A CATALYST IN THE FORM OF A METAL COORDINATION COMPLEX IN COMBINATION WITH AN OPTICAL ACTIVE
SU444353A3 (en) Catalyst for oxidation 02 to 03
BR7108483D0 (en) IMPROVEMENTS RELATING TO METALLURGICAL CONTAINERS
SE391711B (en) PROCEDURE FOR CATALYTIC CO-MOLIGOMERIZATION OF 1,3-DIOLEFINES WITH ALFA, BETA-UNSATURATED ETHENIC ASSOCIATIONS IN THE PRESENCE OF A CYCLOOKTENYL COBOLT CYCLOOKTADIENE COMPLEX AS A CATALYST
IT943460B (en) IMPROVEMENTS TO THE BEDS FOR THE SICK
BE790859A (en) CARBOXAMIDOBENZOIC ACIDS AS HYPOLIPEMIC AGENTS
FI55459B (en) SAEKERHETSANORDNING VID ETT ARBETSREDSKAP SAERSKILT EN MOTORSAOG
IT963967B (en) STABLE CHROME OXIDATION INHIBITORS
AT329787B (en) CONTINUOUS CASTING PLANT
IT950029B (en) IMPROVEMENTS RELATING TO MIRRORS
BR7201048D0 (en) REGULATORY MECHANISM
BE774212A (en) IMPROVED TOURBILLON PROXIMITY SENSOR
SU493688A1 (en) The way to control the tightness of products
SE382972B (en) WAY TO PRODUCE ACTINIDE NITRATE SOLUTION WITH ANJION DEFICIENCY
IT993977B (en) IMPROVEMENT TO LIFTING TROLLEYS
FI55919B (en) STYRAPPARAT MED ETT RELAE