SA518391793B1 - بوليمر مشترك إيثيلين وبيوتادايين ذو بنية دقيقة متجانسة - Google Patents

بوليمر مشترك إيثيلين وبيوتادايين ذو بنية دقيقة متجانسة

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Publication number
SA518391793B1
SA518391793B1 SA518391793A SA518391793A SA518391793B1 SA 518391793 B1 SA518391793 B1 SA 518391793B1 SA 518391793 A SA518391793 A SA 518391793A SA 518391793 A SA518391793 A SA 518391793A SA 518391793 B1 SA518391793 B1 SA 518391793B1
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SA
Saudi Arabia
Prior art keywords
ethylene
copolymer
butadiene copolymer
homogeneous microstructure
units
Prior art date
Application number
SA518391793A
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English (en)
Inventor
نونو باشيكو
جولين ثويليز
Original Assignee
كومباجنى جينيرال ديس اتابليسيمينتس ميكيلين
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by كومباجنى جينيرال ديس اتابليسيمينتس ميكيلين filed Critical كومباجنى جينيرال ديس اتابليسيمينتس ميكيلين
Publication of SA518391793B1 publication Critical patent/SA518391793B1/ar

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • C08F2/06Organic solvent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06Butadiene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/35Scandium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/36Yttrium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/38Lanthanides other than lanthanum
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/24Polymer with special particle form or size
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10Copolymer characterised by the proportions of the comonomers expressed as molar percentages
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Tires In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

يتعلق الاختراع الحالي ببوليمر مشترك إيثيلين/بيوتادايين ethylene/butadiene copolymer يتضمن، وحدات إيثيلين ووحدات بيوتادايين موزعة إحصائيا، الكسر الجزيئي molar fraction لوحدات إيثيلين في البوليمر المشترك المذكور أكبر من أو يساوي 50٪، نسبة إلى الرقم الكلي لجزيئات إيثيلين ووحدات بيوتادايين، يتسم بأن البنية الدقيقة للبوليمر المشترك متجانسة. يتعلق الاختراع الحالي بعملية لتحضير هذا البوليمر المشترك وأيضا باستخدامات هذا البوليمر المشترك، تحديدا في تركيبات مطاط rubber compositions للإطارات. شكل1
SA518391793A 2015-12-17 2018-06-12 بوليمر مشترك إيثيلين وبيوتادايين ذو بنية دقيقة متجانسة SA518391793B1 (ar)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1562575A FR3045613B1 (fr) 2015-12-17 2015-12-17 Copolymere d'ethylene et de butadiene de microstructure homogene
PCT/FR2016/053538 WO2017103544A1 (fr) 2015-12-17 2016-12-16 Copolymere d'ethylene et de butadiene de microstructure homogene

Publications (1)

Publication Number Publication Date
SA518391793B1 true SA518391793B1 (ar) 2021-12-13

Family

ID=55411598

Family Applications (1)

Application Number Title Priority Date Filing Date
SA518391793A SA518391793B1 (ar) 2015-12-17 2018-06-12 بوليمر مشترك إيثيلين وبيوتادايين ذو بنية دقيقة متجانسة

Country Status (10)

Country Link
US (2) US10844149B2 (ar)
EP (1) EP3390466B1 (ar)
JP (1) JP2019504148A (ar)
KR (1) KR102661586B1 (ar)
CN (1) CN108602919B (ar)
BR (1) BR112018012365B1 (ar)
FR (1) FR3045613B1 (ar)
RU (1) RU2726197C9 (ar)
SA (1) SA518391793B1 (ar)
WO (1) WO2017103544A1 (ar)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3085166B1 (fr) 2018-08-23 2020-07-17 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique
FR3085167B1 (fr) 2018-08-23 2020-07-31 Michelin & Cie Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique
FR3085165B1 (fr) 2018-08-23 2020-07-17 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique
FR3085683B1 (fr) * 2018-09-11 2020-10-23 Michelin & Cie Pneumatique
FR3088328B3 (fr) * 2018-11-09 2020-12-04 Michelin & Cie Elastomere dienique fonctionnel et composition de caoutchouc
FR3143033A1 (fr) 2022-12-12 2024-06-14 Compagnie Generale Des Etablissements Michelin Pneumatique pour véhicule portant de lourdes charges
WO2024167619A1 (en) 2023-02-08 2024-08-15 ExxonMobil Technology and Engineering Company Catalysts for copolymerizations

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CA970900A (en) * 1970-03-19 1975-07-08 Maruzen Petrochemical Co. Process for preparing a copolymer of ethylene and a conjugated diene
IN172494B (ar) 1986-12-19 1993-09-04 Exxon Chemical Patents Inc
IT1270253B (it) * 1994-06-20 1997-04-29 Spherilene Srl Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene
FR2799468B1 (fr) 1999-10-12 2006-04-28 Michelin Soc Tech Systeme catalytique utilisable pour la copolymerisation de l'ethylene et d'un diene conjugue, procede de preparation de ce systeme catalytique et d'un copolymere d'ethylene et d'un diene conjugue
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FR2858817B1 (fr) 2003-08-13 2006-02-03 Michelin Soc Tech Systeme catalytique pour l'obtention de copolymeres diene(s) conjugue(s)/ mono-olefine(s) et ces copolymeres
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Also Published As

Publication number Publication date
WO2017103544A1 (fr) 2017-06-22
US20200339716A1 (en) 2020-10-29
BR112018012365B1 (pt) 2022-03-08
US20180371129A1 (en) 2018-12-27
BR112018012365A2 (pt) 2018-12-04
EP3390466B1 (fr) 2021-06-02
US10844149B2 (en) 2020-11-24
RU2018123148A3 (ar) 2020-01-30
JP2019504148A (ja) 2019-02-14
CN108602919B (zh) 2021-05-25
RU2018123148A (ru) 2020-01-17
FR3045613B1 (fr) 2017-12-15
FR3045613A1 (fr) 2017-06-23
KR20180096694A (ko) 2018-08-29
RU2726197C2 (ru) 2020-07-09
EP3390466A1 (fr) 2018-10-24
KR102661586B1 (ko) 2024-04-30
RU2726197C9 (ru) 2020-08-31
CN108602919A (zh) 2018-09-28

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