SA517390095B1 - محفز تلمرة بيوتادايين وتحضيره - Google Patents

محفز تلمرة بيوتادايين وتحضيره

Info

Publication number
SA517390095B1
SA517390095B1 SA517390095A SA517390095A SA517390095B1 SA 517390095 B1 SA517390095 B1 SA 517390095B1 SA 517390095 A SA517390095 A SA 517390095A SA 517390095 A SA517390095 A SA 517390095A SA 517390095 B1 SA517390095 B1 SA 517390095B1
Authority
SA
Saudi Arabia
Prior art keywords
ligand
trioxa
dimethoxyphenyl
tetramethyl
palladium
Prior art date
Application number
SA517390095A
Other languages
English (en)
Inventor
آر. بريجز جون
إل. كلينكنبيرج جيسيكا
Original Assignee
داو جلوبال تكنولوجيز إل إل سي
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by داو جلوبال تكنولوجيز إل إل سي filed Critical داو جلوبال تكنولوجيز إل إل سي
Publication of SA517390095B1 publication Critical patent/SA517390095B1/ar

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/38—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of dienes or alkynes
    • C07C2/40—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of dienes or alkynes of conjugated dienes
    • C07C2/403—Catalytic processes
    • C07C2/406—Catalytic processes with hydrides or organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
    • C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
    • B01J31/2438—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member and further hetero atoms as ring members, excluding the positions adjacent to P
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

يتعلق الاختراع بتركيبات محفز catalyst compositions يتم تحضيرها من خلال ملامسة مصدر للبلاديوم palladium source ومركب 1، 3، 5، 7-تترا ميثيل-6-(2، 4-داي ميثوكسي فينيل)-2، 4، 8-ترايوكسا-6-فوسفا أدمنتان 1,3,5,7-tetramethyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaadamantane وميثوكسي أوكتا-دايين methoxyocta-diene، في كحول أليفاتي أولي primary aliphatic alcohol، في ظروف مناسبة تتضمن نسبة مكافئات من البالاديوم palladium إلى مكافئات من 1، 3، 5، 7-تترا ميثيل-6-(2، 4-داي ميثوكسي فينيل)-2، 4، 8-ترايوكسا-6-فوسفا أدمنتان 1,3,5,7-tetramethyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaadamantane تتراوح من أكبر من 1: 1 إلى 1: 1.3. وتكون النتيجة معقد من البالاديوم palladium، مركب ترابطي ligand من 1، 3، 5، 7-تترا ميثيل-6-(2، 4-داي ميثوكسي فينيل)-2، 4، 8-ترايوكسا-6-فوسفا أدا-مانتان 1,3,5,7-tetramethyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaada-mantane، ومركب ترابطي ligand مختار من مركب ترابطي من ميثوكسي أوكتادايين methoxyoctadiene ligand، مركب ترابطي من أوكتا داينيل octadienyl ligand، أو أو
SA517390095A 2015-04-10 2017-10-02 محفز تلمرة بيوتادايين وتحضيره SA517390095B1 (ar)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201562145650P 2015-04-10 2015-04-10
PCT/US2016/025472 WO2016164258A1 (en) 2015-04-10 2016-04-01 Butadiene telomerization catalyst and preparation thereof

Publications (1)

Publication Number Publication Date
SA517390095B1 true SA517390095B1 (ar) 2021-06-23

Family

ID=55754444

Family Applications (1)

Application Number Title Priority Date Filing Date
SA517390095A SA517390095B1 (ar) 2015-04-10 2017-10-02 محفز تلمرة بيوتادايين وتحضيره

Country Status (8)

Country Link
US (3) US11312670B2 (ar)
EP (1) EP3280690B1 (ar)
CN (1) CN107438630B (ar)
BR (1) BR112017021125B1 (ar)
CA (1) CA2981600C (ar)
ES (1) ES2736109T3 (ar)
SA (1) SA517390095B1 (ar)
WO (1) WO2016164258A1 (ar)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015088867A2 (en) 2013-12-13 2015-06-18 Dow Global Technologies Llc Butadiene telomerization catalyst precursor preparation
US11628430B2 (en) 2017-02-27 2023-04-18 Kuraray Co., Ltd. Method for manufacturing catalyst liquid
WO2018175671A1 (en) * 2017-03-23 2018-09-27 Dow Global Technologies Llc Methods for forming 1,3,5,7-tetraalkyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaadamantane

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3050531A (en) 1960-07-06 1962-08-21 American Cyanamid Co Substituted 10-phosphatricyclo [3.3.1.1] decanes and methods of preparing same
IT1240737B (it) * 1990-04-02 1993-12-17 Snam Progetti Sistema catalitico e procedimento per la produzione selettiva di isoprenil-alchileteri da isoprene
WO1992010450A1 (en) 1990-12-13 1992-06-25 Dow Benelux N.V. Process for producing 1-octene
TWI301481B (en) * 2002-08-10 2008-10-01 Lucite Int Uk Ltd A catalyst system
CN1795164A (zh) * 2003-05-22 2006-06-28 国际壳牌研究有限公司 共轭二烯的羰基化方法
WO2010019360A2 (en) 2008-08-12 2010-02-18 Dow Global Technologies Inc. An improved process for telomerization of butadiene
ES2420755T3 (es) 2009-05-14 2013-08-26 Dow Global Technologies Llc Complejos de fosfina-paladio para la telomerización de butadieno
CA2789984A1 (en) 2010-02-17 2011-08-25 Petrus V. Leeuwen Novel phosphine-based catalysts useful for the telomerization of butadiene
WO2011113196A1 (zh) 2010-03-16 2011-09-22 台州太法药业有限公司 屈螺酮制备方法
US9174905B2 (en) * 2010-12-21 2015-11-03 Dow Global Technologies Llc Process for telomerization of butadiene using a mono-orthoalkoxy substituted catalyst
WO2015088867A2 (en) 2013-12-13 2015-06-18 Dow Global Technologies Llc Butadiene telomerization catalyst precursor preparation

Also Published As

Publication number Publication date
US11312670B2 (en) 2022-04-26
CA2981600A1 (en) 2016-10-13
CN107438630B (zh) 2020-09-15
US20230331643A1 (en) 2023-10-19
BR112017021125B1 (pt) 2021-06-01
US20180072637A1 (en) 2018-03-15
EP3280690A1 (en) 2018-02-14
ES2736109T3 (es) 2019-12-26
CN107438630A (zh) 2017-12-05
BR112017021125A2 (pt) 2018-07-03
EP3280690B1 (en) 2019-06-19
CA2981600C (en) 2023-09-05
US11713286B2 (en) 2023-08-01
US20220213006A1 (en) 2022-07-07
WO2016164258A1 (en) 2016-10-13

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