RU99112176A - Катализаторы селективной гидрогенизации, содержащие палладий и, по меньшей мере, один металл группы ivа - Google Patents
Катализаторы селективной гидрогенизации, содержащие палладий и, по меньшей мере, один металл группы ivаInfo
- Publication number
- RU99112176A RU99112176A RU99112176/04A RU99112176A RU99112176A RU 99112176 A RU99112176 A RU 99112176A RU 99112176/04 A RU99112176/04 A RU 99112176/04A RU 99112176 A RU99112176 A RU 99112176A RU 99112176 A RU99112176 A RU 99112176A
- Authority
- RU
- Russia
- Prior art keywords
- catalyst according
- paragraphs
- particles
- metal
- catalyst
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims 15
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 title claims 12
- 229910052763 palladium Inorganic materials 0.000 title claims 6
- 239000002245 particle Substances 0.000 claims 7
- 229910052751 metal Inorganic materials 0.000 claims 4
- 239000002184 metal Substances 0.000 claims 4
- 239000000969 carrier Substances 0.000 claims 3
- 150000002430 hydrocarbons Chemical class 0.000 claims 3
- 229910052718 tin Inorganic materials 0.000 claims 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 3
- 239000004215 Carbon black (E152) Substances 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N al2o3 Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 238000005984 hydrogenation reaction Methods 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 229910000323 aluminium silicate Inorganic materials 0.000 claims 1
- 125000004432 carbon atoms Chemical group C* 0.000 claims 1
- -1 diolefin hydrocarbons Chemical class 0.000 claims 1
- 230000003993 interaction Effects 0.000 claims 1
- 150000005673 monoalkenes Chemical class 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 238000004230 steam cracking Methods 0.000 claims 1
Claims (14)
1. Катализатор селективной гидрогенизации, отличающийся тем, что он включает частицы пористого носителя, состоящего по меньшей мере из неорганического огнеупорного оксида, выбираемого из окисей алюминия, двуокисей кремния, алюмосиликатов и глин, и, в качестве активных элементов, из палладия, распределенного по периферии частиц, и по меньшей мере один элемент M, выбираемый из олова или свинца.
2. Катализатор по п.1, отличающийся тем, что на носителе по меньшей мере 80% палладия входит в объем частиц, определенный между периферией названных частиц и толщиной, равной 500 мкм.
3. Катализатор по п. 1 или 2, отличающийся тем, что содержание палладия в нем равно 0,025-1,0 мас.%.
4. Катализатор по любому из пп. 1-3, отличающийся тем, что содержание палладия в нем равно 0,03-0,5 мас.%.
5. Катализатор по любому из пп. 1-4, отличающийся тем, что содержание в нем элемента M, выбираемого из олова и свинца, равно 0,05-4 мас.%.
6. Катализатор по любому из пп. 1-5, отличающийся тем, что металл M - это олово, и его содержание в катализаторе равно 0,2-4 мас.%.
7. Катализатор по любому из пп. 1-5, отличающийся тем, что металл M - это свинец, и его содержание в катализаторе равно 1-4 мас.%.
8. Катализатор по любому из пп. 1-7, отличающийся тем, что атомное соотношение элемент M/палладий равно 0,1-3.
9. Катализатор по любому из пп. 1-8, отличающийся тем, что на носителе металл M распределен по периферии частиц.
10. Катализатор по п. 9, отличающийся тем, что на носителе по меньшей мере 80% металла группы IVA входит в объем частиц, определенный между периферией названных частиц и толщиной в 500 мкм.
11. Катализатор по любому из пп. 1-10, отличающийся тем, что названный носитель состоит из окиси алюминия, удельная поверхность которой равна 5-200 м2/г, а пористый объем - 0,3-0,95 см3/г.
12. Способ селективной гидрогенизации углеводородной фракции, содержащей в основном моно- и диолефиновые углеводороды, отличающийся тем, что названную углеводородную фракцию приводят во взаимодействие с катализатором по одному из пп. 1-11.
13. Способ по п. 12, отличающийся тем, что названная фракция включает в основном углеводороды с 4 атомами углерода.
14. Способ по п. 13, отличающийся тем, что названная фракция появляется при операции парового крекинга.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR96.13576 | 1996-11-07 | ||
| FR9613576 | 1996-11-07 | ||
| FR9613576A FR2755378B1 (fr) | 1996-11-07 | 1996-11-07 | Catalyseurs d'hydrogenation selective contenant du palladium et au moins un metal du groupe iva |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU99112176A true RU99112176A (ru) | 2001-04-27 |
| RU2192306C2 RU2192306C2 (ru) | 2002-11-10 |
Family
ID=9497410
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU99112176/04A RU2192306C2 (ru) | 1996-11-07 | 1997-10-28 | Катализаторы селективной гидрогенизации, содержащие палладий и, по меньшей мере, один металл группы ivа |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US5955397A (ru) |
| EP (1) | EP0946299A1 (ru) |
| JP (1) | JP2001503324A (ru) |
| KR (1) | KR100485239B1 (ru) |
| CN (1) | CN1107547C (ru) |
| AU (1) | AU731009B2 (ru) |
| BR (1) | BR9712929A (ru) |
| CA (1) | CA2270574A1 (ru) |
| FR (1) | FR2755378B1 (ru) |
| RU (1) | RU2192306C2 (ru) |
| WO (1) | WO1998019793A1 (ru) |
Families Citing this family (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6239322B1 (en) | 1996-11-07 | 2001-05-29 | Institut Francais Du Petrole | Selective hydrogenation catalysts containing palladium, also tin and/or lead, and the preparation and use thereof |
| TW377306B (en) * | 1996-12-16 | 1999-12-21 | Asahi Chemical Ind | Noble metal support |
| DE19840373A1 (de) * | 1998-09-04 | 2000-03-09 | Basf Ag | Katalysator und Verfahren zur Selektivhydrierung ungesättigter Verbindungen in Kohlenwasserstoffströmen |
| GB0119327D0 (en) * | 2001-08-08 | 2001-10-03 | Johnson Matthey Plc | Catalyst |
| GB0223300D0 (en) * | 2002-10-08 | 2002-11-13 | Bp Chem Int Ltd | Process |
| US20040192994A1 (en) * | 2003-03-26 | 2004-09-30 | Bridges Robert S. | Propylene production |
| US6872862B2 (en) * | 2003-06-25 | 2005-03-29 | Equistar Chemicals, Lp | Propylene production |
| US7074976B2 (en) * | 2003-08-19 | 2006-07-11 | Equistar Chemicals, Lp | Propylene production |
| CN1313205C (zh) * | 2004-04-02 | 2007-05-02 | 中国石油天然气股份有限公司 | 一种选择加氢、单烯烃异构催化剂、制备方法及应用 |
| US7453016B1 (en) * | 2005-12-20 | 2008-11-18 | Uop Llc | Selective hydrogenation process using layered catalyst composition and preparation of said catalyst |
| US7749375B2 (en) | 2007-09-07 | 2010-07-06 | Uop Llc | Hydrodesulfurization process |
| DE102008000290A1 (de) * | 2008-02-13 | 2009-08-20 | Evonik Degussa Gmbh | Lagerstabile Produktsyteme für Prämixformulierungen |
| CN101628843B (zh) * | 2008-07-18 | 2013-11-27 | 环球油品公司 | 利用层状催化剂组合物的选择性加氢方法和所述催化剂的制备 |
| US8637714B2 (en) | 2008-07-31 | 2014-01-28 | Celanese International Corporation | Process for producing ethanol over catalysts containing platinum and palladium |
| US8680317B2 (en) | 2008-07-31 | 2014-03-25 | Celanese International Corporation | Processes for making ethyl acetate from acetic acid |
| US8471075B2 (en) * | 2008-07-31 | 2013-06-25 | Celanese International Corporation | Processes for making ethanol from acetic acid |
| US8309772B2 (en) | 2008-07-31 | 2012-11-13 | Celanese International Corporation | Tunable catalyst gas phase hydrogenation of carboxylic acids |
| US8546622B2 (en) | 2008-07-31 | 2013-10-01 | Celanese International Corporation | Process for making ethanol from acetic acid using acidic catalysts |
| US8304586B2 (en) | 2010-02-02 | 2012-11-06 | Celanese International Corporation | Process for purifying ethanol |
| US8309773B2 (en) | 2010-02-02 | 2012-11-13 | Calanese International Corporation | Process for recovering ethanol |
| US8338650B2 (en) | 2008-07-31 | 2012-12-25 | Celanese International Corporation | Palladium catalysts for making ethanol from acetic acid |
| US8501652B2 (en) * | 2008-07-31 | 2013-08-06 | Celanese International Corporation | Catalysts for making ethanol from acetic acid |
| US8772561B2 (en) * | 2008-11-19 | 2014-07-08 | Uop Llc | Methods for selective hydrogenation performance using a layered sphere catalyst with new formulations |
| US8026194B2 (en) * | 2008-11-19 | 2011-09-27 | Uop Llc | Layered sphere catalyst formulations for selective hydrogenation performance |
| US20100152026A1 (en) * | 2008-12-16 | 2010-06-17 | Gajda Gregory J | Layered Sphere Catalysts with High Accessibility Indexes |
| US8921631B2 (en) | 2008-12-18 | 2014-12-30 | Saudi Basic Industries Corporation | Selective catalytic hydrogenation of alkynes to corresponding alkenes |
| US20100331171A1 (en) * | 2009-06-29 | 2010-12-30 | Gajda Gregory J | Layered Sphere Catalysts with High Accessibility Indexes |
| US8450535B2 (en) | 2009-07-20 | 2013-05-28 | Celanese International Corporation | Ethanol production from acetic acid utilizing a cobalt catalyst |
| US8680321B2 (en) | 2009-10-26 | 2014-03-25 | Celanese International Corporation | Processes for making ethanol from acetic acid using bimetallic catalysts |
| US8710277B2 (en) * | 2009-10-26 | 2014-04-29 | Celanese International Corporation | Process for making diethyl ether from acetic acid |
| US8211821B2 (en) | 2010-02-01 | 2012-07-03 | Celanese International Corporation | Processes for making tin-containing catalysts |
| US8747492B2 (en) | 2010-02-02 | 2014-06-10 | Celanese International Corporation | Ethanol/fuel blends for use as motor fuels |
| US8344186B2 (en) | 2010-02-02 | 2013-01-01 | Celanese International Corporation | Processes for producing ethanol from acetaldehyde |
| US8314272B2 (en) | 2010-02-02 | 2012-11-20 | Celanese International Corporation | Process for recovering ethanol with vapor separation |
| US8668750B2 (en) | 2010-02-02 | 2014-03-11 | Celanese International Corporation | Denatured fuel ethanol compositions for blending with gasoline or diesel fuel for use as motor fuels |
| US8460405B2 (en) | 2010-02-02 | 2013-06-11 | Celanese International Corporation | Ethanol compositions |
| CN102421521B (zh) | 2010-02-02 | 2015-01-07 | 国际人造丝公司 | 用于生产乙醇的包含结晶载体改性剂的催化剂的制备和用途 |
| US8858659B2 (en) | 2010-02-02 | 2014-10-14 | Celanese International Corporation | Processes for producing denatured ethanol |
| US8541633B2 (en) | 2010-02-02 | 2013-09-24 | Celanese International Corporation | Processes for producing anhydrous ethanol compositions |
| US8222466B2 (en) | 2010-02-02 | 2012-07-17 | Celanese International Corporation | Process for producing a water stream from ethanol production |
| US8728179B2 (en) | 2010-02-02 | 2014-05-20 | Celanese International Corporation | Ethanol compositions |
| US8575403B2 (en) | 2010-05-07 | 2013-11-05 | Celanese International Corporation | Hydrolysis of ethyl acetate in ethanol separation process |
| US8932372B2 (en) | 2010-02-02 | 2015-01-13 | Celanese International Corporation | Integrated process for producing alcohols from a mixed acid feed |
| US8680343B2 (en) | 2010-02-02 | 2014-03-25 | Celanese International Corporation | Process for purifying ethanol |
| US8648225B2 (en) | 2010-04-12 | 2014-02-11 | Chevron Phillips Chemical Company Lp | Process for hydrogenating highly unsaturated hydrocarbons and catalyst therefor |
| US8754267B2 (en) | 2010-05-07 | 2014-06-17 | Celanese International Corporation | Process for separating acetaldehyde from ethanol-containing mixtures |
| US8350098B2 (en) | 2011-04-04 | 2013-01-08 | Celanese International Corporation | Ethanol production from acetic acid utilizing a molybdenum carbide catalyst |
| US9073816B2 (en) | 2011-04-26 | 2015-07-07 | Celanese International Corporation | Reducing ethyl acetate concentration in recycle streams for ethanol production processes |
| CN102794173A (zh) * | 2011-05-27 | 2012-11-28 | 中国石油化工股份有限公司 | 选择加氢除炔催化剂及其制备方法 |
| US8895786B2 (en) | 2011-08-03 | 2014-11-25 | Celanese International Corporation | Processes for increasing alcohol production |
| US8658843B2 (en) | 2011-10-06 | 2014-02-25 | Celanese International Corporation | Hydrogenation catalysts prepared from polyoxometalate precursors and process for using same to produce ethanol while minimizing diethyl ether formation |
| US8536382B2 (en) | 2011-10-06 | 2013-09-17 | Celanese International Corporation | Processes for hydrogenating alkanoic acids using catalyst comprising tungsten |
| US9233899B2 (en) | 2011-12-22 | 2016-01-12 | Celanese International Corporation | Hydrogenation catalysts having an amorphous support |
| US9000234B2 (en) | 2011-12-22 | 2015-04-07 | Celanese International Corporation | Calcination of modified support to prepare hydrogenation catalysts |
| US8975200B2 (en) | 2012-01-06 | 2015-03-10 | Celanese International Corporation | Hydrogenation catalysts with cobalt-modified supports |
| US9024086B2 (en) | 2012-01-06 | 2015-05-05 | Celanese International Corporation | Hydrogenation catalysts with acidic sites |
| US8981164B2 (en) | 2012-01-06 | 2015-03-17 | Celanese International Corporation | Cobalt and tin hydrogenation catalysts |
| US9051235B2 (en) | 2012-02-07 | 2015-06-09 | Celanese International Corporation | Process for producing ethanol using a molar excess of hydrogen |
| US9050585B2 (en) | 2012-02-10 | 2015-06-09 | Celanese International Corporation | Chemisorption of ethyl acetate during hydrogenation of acetic acid to ethanol |
| US8975452B2 (en) | 2012-03-28 | 2015-03-10 | Celanese International Corporation | Process for producing ethanol by hydrocarbon oxidation and hydrogenation or hydration |
| US8772553B2 (en) | 2012-10-26 | 2014-07-08 | Celanese International Corporation | Hydrogenation reaction conditions for producing ethanol |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3691102A (en) * | 1970-05-11 | 1972-09-12 | Gulf Research Development Co | Group viii metal-tin catalyst and method of making same |
| US3844935A (en) * | 1973-01-02 | 1974-10-29 | Phillips Petroleum Co | Process for producing lead free motor fuel |
| US3900386A (en) * | 1973-05-31 | 1975-08-19 | Universal Oil Prod Co | Hydroprocessing of hydrocarbons |
| US4169815A (en) * | 1973-11-15 | 1979-10-02 | Phillips Petroleum Company | Catalyst for dehydrogenation process |
| US4051073A (en) * | 1976-02-13 | 1977-09-27 | General Motors Corporation | Pellet-type oxidation catalyst |
| US4221738A (en) * | 1979-03-05 | 1980-09-09 | Uop Inc. | Production of acrylonitrile |
| US4459372A (en) * | 1982-08-25 | 1984-07-10 | Uop Inc. | Surface-metallated refractory inorganic oxides, method of their preparation and catalyst supported on the oxides |
| FR2539647B1 (fr) * | 1983-01-24 | 1985-06-07 | Inst Francais Du Petrole | Procede de preparation de catalyseurs bimetalliques ou plurimetalliques supportes a base d'un ou plusieurs metaux du groupe viii et d'au moins un metal du groupe iv catalyseurs obtenus et leurs utilisations |
| CN85102710A (zh) * | 1985-04-01 | 1986-09-17 | 中国科学院大连化学物理研究所 | 铂、钯/氧化钛脱氧催化剂 |
| GB8620982D0 (en) * | 1986-08-29 | 1986-10-08 | Shell Int Research | Catalyst preparation |
| FR2694286B1 (fr) * | 1992-07-28 | 1994-10-14 | Inst Francais Du Petrole | Procédé de production d'alcool aromatique par hydrogénation sélective de cétone aromatique. |
| FR2704865B1 (fr) * | 1993-05-06 | 1995-07-21 | Inst Francais Du Petrole | Procédé d'hydrogénation catalytique. |
| US5858908A (en) * | 1997-04-17 | 1999-01-12 | Uop Llc | Selective multimetallic-multigradient reforming catalyst |
-
1996
- 1996-11-07 FR FR9613576A patent/FR2755378B1/fr not_active Expired - Fee Related
-
1997
- 1997-10-28 CN CN97199547A patent/CN1107547C/zh not_active Expired - Fee Related
- 1997-10-28 KR KR10-1999-7004008A patent/KR100485239B1/ko not_active IP Right Cessation
- 1997-10-28 JP JP52109298A patent/JP2001503324A/ja active Pending
- 1997-10-28 BR BR9712929-1A patent/BR9712929A/pt unknown
- 1997-10-28 AU AU49524/97A patent/AU731009B2/en not_active Ceased
- 1997-10-28 RU RU99112176/04A patent/RU2192306C2/ru not_active IP Right Cessation
- 1997-10-28 EP EP97912269A patent/EP0946299A1/fr not_active Withdrawn
- 1997-10-28 WO PCT/FR1997/001929 patent/WO1998019793A1/fr active IP Right Grant
- 1997-10-28 CA CA002270574A patent/CA2270574A1/fr not_active Abandoned
- 1997-11-06 US US08/964,129 patent/US5955397A/en not_active Expired - Lifetime
-
1999
- 1999-09-17 US US09/398,434 patent/US6245220B1/en not_active Expired - Lifetime
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RU99112176A (ru) | Катализаторы селективной гидрогенизации, содержащие палладий и, по меньшей мере, один металл группы ivа | |
| BR9712929A (pt) | Catalisadores de hidrogenação seletiva contendo paládio e pelo menos um metal do grupo iva. | |
| DE59610365D1 (de) | Palladium-haltiger Trägerkatalysator zur selektiven katalytischen Hydrierung von Acetylen in Kohlenwasserstoffströmen | |
| DE3360697D1 (en) | Supported palladium-gold catalyst, its preparation and its use in the selective hydrogenation of diolefinic and/or acetylenic hydrocarbons | |
| EP0140007A3 (en) | Passivation of vanadium accumulated on inert or catalytic solid fluidizable particles | |
| ES2024072B3 (es) | Procedimiento para preparar catalizadores que contienen un metal del grupo del platino, y sus usos | |
| KR960001090A (ko) | 촉매 수소화 방법 및 이 방법에 사용하기 위한 촉매 | |
| GB1381104A (en) | Hydroprocessing catalyst | |
| ES473540A1 (es) | Un metodo de fabricacion de una composicion catalitica | |
| AU3668999A (en) | Olefin purification by adsorption of acethylenics and regeneration of adsorbent | |
| MX172765B (es) | Proceso para la regeneracion de catalizadores de zeolita | |
| FR2540744B1 (fr) | Catalyseur de conversion des hydrocarbures, procede pour sa preparation et son utilisation pour le craquage catalytique | |
| EP0361424A3 (en) | Catalyst composition, process for cracking non-aromatic hydrocarbons and process for isomerizing c8-aromatic hydrocarbons | |
| IE37230B1 (en) | Reforming petroleum hydrocarbons with catalysts promoted with gallium and rhenium | |
| KR980700230A (ko) | 안트라퀴논 방법 (Anthraquinone Process) | |
| CA2104913A1 (en) | Hydroconversion catalyst | |
| AU5376890A (en) | Method and apparatus for the fluid catalytic cracking of hydrocarbon feed employinga separable mixture of catalyst and sorbent particles | |
| ZA876267B (en) | Hydrogenation catalyst | |
| DE3666356D1 (en) | Separation process for catalyst fines, of a hydrocarbon charge, by filtration through mineral barriers and a filtration loop | |
| EP0097047A3 (en) | A process for hydrogenating organic compounds by the use of group viii aluminum-silicate catalysts | |
| RU93050201A (ru) | Композиция масла, применяемого в процессе алкилирования, способ регенерации катализатора алкилирования и способ удаления примесей из катализаторов алкилирования | |
| EP0138783A3 (en) | Large pore catalysts for heavy hydrocarbon conversion | |
| IT8867373A0 (it) | Catalizzatore per l idrometallizza zione e l idroconversione simultanea dei flussi di alimentazione di idrocarburi pesanti | |
| JPS5684639A (en) | Hydrocracking catalyst composition | |
| GB1351562A (en) | Hydroreforming catalysts and a method for preparing the same |