RU98102132A - Способ и устройство для получения синтез-газа - Google Patents
Способ и устройство для получения синтез-газаInfo
- Publication number
- RU98102132A RU98102132A RU98102132/12A RU98102132A RU98102132A RU 98102132 A RU98102132 A RU 98102132A RU 98102132/12 A RU98102132/12 A RU 98102132/12A RU 98102132 A RU98102132 A RU 98102132A RU 98102132 A RU98102132 A RU 98102132A
- Authority
- RU
- Russia
- Prior art keywords
- catalyst
- heat exchanger
- tubular reactor
- synthesis gas
- reforming
- Prior art date
Links
- 230000015572 biosynthetic process Effects 0.000 title claims 5
- 238000003786 synthesis reaction Methods 0.000 title claims 5
- 230000002194 synthesizing Effects 0.000 title claims 5
- 239000003054 catalyst Substances 0.000 claims 8
- 239000004215 Carbon black (E152) Substances 0.000 claims 5
- 239000007789 gas Substances 0.000 claims 5
- 150000002430 hydrocarbons Chemical class 0.000 claims 5
- 238000002407 reforming Methods 0.000 claims 5
- 239000000969 carrier Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 239000003546 flue gas Substances 0.000 claims 1
- 238000000629 steam reforming Methods 0.000 claims 1
Claims (10)
1. Способ получения синтез-газа паровым реформингом горячего углеводородного сырья в присутствии катализатора на носителе в нагреваемом трубчатом реакторе с последующим отводом синтез-газа, отличающийся тем, что реакцию проводят в присутствии катализатора, выполненного в виде тонкого слоя на внутренней стенке нагреваемого трубчатого реактора.
2. Способ по п. 1, отличающийся тем, что горячее углеводородное сырье представляет собой продукт, полученный путем непрямого теплообмена с топочными газами в присутствии катализатора реформинга, выполненного в виде тонкого слоя на внутренней стенке теплообменника.
3. Способ по п.2, отличающийся тем, что дополнительное количество горячего углеводородного сырья добавляют к продукту непрямого теплообмена.
4. Способ по п.1, отличающийся тем, что газ, полученный на стадии реформинга, подвергают дополнительной стадии реформинга в присутствии неподвижного слоя катализатора.
5. Устройство для получения синтез-газа, содержащее нагреваемый трубчатый реактор с катализатором на носителе, расположенным в нем, при этом реактор имеет ввод для подачи горячего углеводородного сырья и выход для вывода синтез-газа, отличающееся тем, что катализатор выполнен в виде тонкого слоя на внутренней стенке трубчатого реактора.
6. Устройство по п.5, отличающееся тем, что выход трубчатого реактора сообщен с дополнительным аппаратом реформинга с неподвижным слоем катализатора реформинга, расположенным в нем.
7. Устройство по п.5, отличающееся тем, что содержит теплообменник непрямого типа, имеющий катализатор, выполненный в виде тонкого слоя на внутренней стенке теплообменника.
8. Устройство по п.7, отличающееся тем, что теплообменник непрямого типа сконструирован в виде предварительно подогреваемой спирали.
9. Устройство по пп.7 и 8, отличающееся тем, что выход теплообменника непрямого типа присоединен к вводу трубчатого реактора.
10. Устройство по п.9, отличающееся тем, что выход теплообменника непрямого типа снабжен линией для подачи дополнительного количества углеводородного сырья.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US3539697P | 1997-01-22 | 1997-01-22 | |
| US60/035,396 | 1997-01-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU98102132A true RU98102132A (ru) | 2000-01-10 |
| RU2218301C2 RU2218301C2 (ru) | 2003-12-10 |
Family
ID=21882426
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU98102132/15A RU2218301C2 (ru) | 1997-01-22 | 1998-01-21 | Способ и устройство для получения синтез-газа |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US5932141A (ru) |
| EP (1) | EP0855366B1 (ru) |
| JP (1) | JP4521735B2 (ru) |
| KR (1) | KR100547540B1 (ru) |
| CN (1) | CN1269724C (ru) |
| AT (1) | ATE200884T1 (ru) |
| AU (1) | AU728728C (ru) |
| CA (1) | CA2227598C (ru) |
| DE (1) | DE69800734T2 (ru) |
| DK (1) | DK0855366T3 (ru) |
| ES (1) | ES2158621T3 (ru) |
| NO (1) | NO318107B1 (ru) |
| NZ (1) | NZ329613A (ru) |
| RU (1) | RU2218301C2 (ru) |
| TW (1) | TW482741B (ru) |
| UA (1) | UA61888C2 (ru) |
Families Citing this family (63)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK173496B1 (da) * | 1998-07-16 | 2001-01-02 | Topsoe Haldor As | Fremgangsmåde til fremstilling af syntesegas ved vanddampreformering under anvendelse af en katalyseret metaloverflade |
| CZ294907B6 (cs) | 1998-07-21 | 2005-04-13 | Haldor Topsoe A/S | Způsob výroby plynu bohatého na vodík a oxid uhelnatý parním reformováním uhlovodíkové vsázky |
| DK173742B1 (da) * | 1998-09-01 | 2001-08-27 | Topsoe Haldor As | Fremgangsmåde og reaktorsystem til fremstilling af syntesegas |
| DK173897B1 (da) | 1998-09-25 | 2002-02-04 | Topsoe Haldor As | Fremgangsmåde til autotermisk reforming af et carbonhydridfødemateriale indeholdende højere carbonhydrider |
| ATE308482T1 (de) | 1999-05-27 | 2005-11-15 | Haldor Topsoe As | Synthesegasherstellung durch dampfreformierung |
| EP1584603A3 (en) * | 1999-05-27 | 2007-06-13 | Haldor Topsoe A/S | Steam reforming reactor for synthesis gas production |
| ATE535495T1 (de) * | 1999-07-15 | 2011-12-15 | Haldor Topsoe As | Verfahren zur katalytischen dampfreformierung eines kohlenwasserstoffeinsatzes |
| US20040161381A1 (en) * | 1999-12-02 | 2004-08-19 | Thomsen Soren Gyde | Process and reactor for carrying out non-adiabatic catalytic reactions |
| PT1106570E (pt) * | 1999-12-02 | 2013-10-15 | Haldor Topsoe As | Processo e reactor para realizar reacções catalíticas não adiabáticas |
| AU2002211388A1 (en) | 2000-10-02 | 2002-04-15 | Chevron U.S.A. Inc. | Process for reducing coke formation in hydrocarbon processing by application of radio frequency electromagnetic radiation |
| RU2167808C1 (ru) * | 2000-10-09 | 2001-05-27 | Пискунов Семен Евсеевич | Способ получения синтез-газа |
| US6890672B2 (en) | 2001-06-26 | 2005-05-10 | Idatech, Llc | Fuel processor feedstock delivery system |
| US6818028B2 (en) * | 2001-07-18 | 2004-11-16 | Kellogg Brown & Root, Inc. | Steam-methane reformer furnace with convection-heated pre-reformer |
| AU2003219821A1 (en) * | 2002-02-22 | 2003-09-09 | Chevron U.S.A. Inc. | Process for reducing metal catalyzed coke formation in hydrocarbon processing |
| US20030223926A1 (en) * | 2002-04-14 | 2003-12-04 | Edlund David J. | Steam reforming fuel processor, burner assembly, and methods of operating the same |
| EP1403215B1 (en) * | 2002-09-26 | 2013-03-13 | Haldor Topsoe A/S | Process and apparatus for the preparation of synthesis gas |
| EP1413547A1 (en) | 2002-09-26 | 2004-04-28 | Haldor Topsoe A/S | Process for the production of synthesis gas |
| EP1403217A1 (en) | 2002-09-26 | 2004-03-31 | Haldor Topsoe A/S | Process and apparatus for the preparation of synthesis gas |
| CA2410927A1 (fr) * | 2002-11-05 | 2004-05-05 | Michel Petitclerc | Reacteur a chauffage electrique pour le reformage en phase gazeuse |
| EP1445235B1 (en) | 2003-02-05 | 2012-03-07 | Haldor Topsoe A/S | Process for treatment of synthesis gas |
| WO2004076346A2 (en) * | 2003-02-24 | 2004-09-10 | Texaco Development Corporation | Diesel steam reforming with co2 fixing |
| US7427388B2 (en) * | 2004-03-19 | 2008-09-23 | Air Products And Chemicals, Inc. | Process for improving prereforming and reforming of natural gas containing higher hydrocarbons along with methane |
| US7892511B2 (en) | 2004-07-02 | 2011-02-22 | Kellogg Brown & Root Llc | Pseudoisothermal ammonia process |
| US7320778B2 (en) * | 2004-07-21 | 2008-01-22 | Catacel Corp. | High-performance catalyst support |
| US20060230613A1 (en) * | 2005-04-14 | 2006-10-19 | Catacel Corporation | Catalytic reactor cartridge |
| US7472936B2 (en) * | 2005-04-14 | 2009-01-06 | Catacel Corp. | Tool for insertion and removal of a catalytic reactor cartridge |
| US7565743B2 (en) * | 2005-04-14 | 2009-07-28 | Catacel Corp. | Method for insertion and removal of a catalytic reactor cartridge |
| US7682580B2 (en) * | 2005-05-19 | 2010-03-23 | Catacel Corp. | Catalytic reactor having radial leaves |
| US7632322B2 (en) * | 2005-06-07 | 2009-12-15 | Idatech, Llc | Hydrogen-producing fuel processing assemblies, heating assemblies, and methods of operating the same |
| US7504048B2 (en) * | 2005-06-14 | 2009-03-17 | Air Products And Chemicals, Inc. | Axial convective reformer |
| US7501102B2 (en) * | 2005-07-28 | 2009-03-10 | Catacel Corp. | Reactor having improved heat transfer |
| US7588738B2 (en) * | 2005-08-23 | 2009-09-15 | Exxonmobil Chemical Patents Inc. | Series catalyst beds |
| JP4724029B2 (ja) * | 2006-03-27 | 2011-07-13 | アイシン精機株式会社 | 改質装置の運転停止方法 |
| US7629067B2 (en) * | 2006-05-22 | 2009-12-08 | Idatech, Llc | Hydrogen-producing fuel processing systems and fuel cell systems with a liquid leak detection system |
| US7501078B2 (en) * | 2007-01-10 | 2009-03-10 | Air Products And Chemicals, Inc. | Process for generating synthesis gas using catalyzed structured packing |
| US7771585B2 (en) | 2007-03-09 | 2010-08-10 | Southern Company | Method and apparatus for the separation of a gas-solids mixture in a circulating fluidized bed reactor |
| US7850944B2 (en) * | 2008-03-17 | 2010-12-14 | Air Products And Chemicals, Inc. | Steam-hydrocarbon reforming method with limited steam export |
| US20100147749A1 (en) * | 2008-12-11 | 2010-06-17 | American Air Liquide, Inc. | Multi-Metallic Catalysts For Pre-Reforming Reactions |
| US9561476B2 (en) | 2010-12-15 | 2017-02-07 | Praxair Technology, Inc. | Catalyst containing oxygen transport membrane |
| CN103011077B (zh) * | 2011-09-27 | 2016-04-06 | 中国科学院宁波材料技术与工程研究所 | 一种催化重整制氢方法与催化装置 |
| US9486735B2 (en) | 2011-12-15 | 2016-11-08 | Praxair Technology, Inc. | Composite oxygen transport membrane |
| EP2791082B1 (en) | 2011-12-15 | 2021-01-20 | Praxair Technology, Inc. | Method of producing composite oxygen transport membrane |
| JP2016505501A (ja) | 2012-12-19 | 2016-02-25 | プラクスエア・テクノロジー・インコーポレイテッド | 酸素輸送膜集合体をシールするための方法 |
| US9453644B2 (en) | 2012-12-28 | 2016-09-27 | Praxair Technology, Inc. | Oxygen transport membrane based advanced power cycle with low pressure synthesis gas slip stream |
| US9611144B2 (en) | 2013-04-26 | 2017-04-04 | Praxair Technology, Inc. | Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system that is free of metal dusting corrosion |
| US9296671B2 (en) | 2013-04-26 | 2016-03-29 | Praxair Technology, Inc. | Method and system for producing methanol using an integrated oxygen transport membrane based reforming system |
| US9938145B2 (en) | 2013-04-26 | 2018-04-10 | Praxair Technology, Inc. | Method and system for adjusting synthesis gas module in an oxygen transport membrane based reforming system |
| US9212113B2 (en) | 2013-04-26 | 2015-12-15 | Praxair Technology, Inc. | Method and system for producing a synthesis gas using an oxygen transport membrane based reforming system with secondary reforming and auxiliary heat source |
| WO2015054223A2 (en) | 2013-10-07 | 2015-04-16 | Praxair Technology, Inc. | Ceramic oxygen transport membrane array reactor and reforming method |
| CN105593162B (zh) | 2013-10-08 | 2018-09-07 | 普莱克斯技术有限公司 | 用于在基于氧输送膜的反应器中的温度控制的系统和方法 |
| US9556027B2 (en) | 2013-12-02 | 2017-01-31 | Praxair Technology, Inc. | Method and system for producing hydrogen using an oxygen transport membrane based reforming system with secondary reforming |
| WO2015123246A2 (en) | 2014-02-12 | 2015-08-20 | Praxair Technology, Inc. | Oxygen transport membrane reactor based method and system for generating electric power |
| EP3126042A1 (en) | 2014-04-02 | 2017-02-08 | Haldor Topsøe A/S | Pseudo-isothermal reactor |
| US10822234B2 (en) | 2014-04-16 | 2020-11-03 | Praxair Technology, Inc. | Method and system for oxygen transport membrane enhanced integrated gasifier combined cycle (IGCC) |
| US9789445B2 (en) | 2014-10-07 | 2017-10-17 | Praxair Technology, Inc. | Composite oxygen ion transport membrane |
| US10441922B2 (en) | 2015-06-29 | 2019-10-15 | Praxair Technology, Inc. | Dual function composite oxygen transport membrane |
| US10118823B2 (en) | 2015-12-15 | 2018-11-06 | Praxair Technology, Inc. | Method of thermally-stabilizing an oxygen transport membrane-based reforming system |
| US9938146B2 (en) | 2015-12-28 | 2018-04-10 | Praxair Technology, Inc. | High aspect ratio catalytic reactor and catalyst inserts therefor |
| EP3436185A1 (en) | 2016-04-01 | 2019-02-06 | Praxair Technology Inc. | Catalyst-containing oxygen transport membrane |
| CN110621704A (zh) * | 2017-05-09 | 2019-12-27 | 埃克森美孚化学专利公司 | 使用低聚反应器中温度控制的线性α-烯烃方法 |
| EP3797085A1 (en) | 2018-05-21 | 2021-03-31 | Praxair Technology, Inc. | Otm syngas panel with gas heated reformer |
| EP4247533A1 (en) | 2020-11-19 | 2023-09-27 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Reforming reactor comprising reformer tubes with enlarged outer surface area and structured catalyst |
| EP4155259A1 (de) | 2021-09-22 | 2023-03-29 | L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Verfahren zum herstellen von synthesegas mit reduziertem dampfexport |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1008667A (en) * | 1972-06-30 | 1977-04-19 | Foster Wheeler Corporation | Catalytic steam reforming |
| US4079017A (en) * | 1976-11-19 | 1978-03-14 | Pullman Incorporated | Parallel steam reformers to provide low energy process |
| EP0049967A1 (en) * | 1980-10-14 | 1982-04-21 | Imperial Chemical Industries Plc | Ammonia production process |
| US4844837A (en) * | 1982-09-30 | 1989-07-04 | Engelhard Corporation | Catalytic partial oxidation process |
| EP0124226B1 (en) * | 1983-03-25 | 1989-10-18 | Imperial Chemical Industries Plc | Steam reforming |
| GB8308343D0 (en) * | 1983-03-25 | 1983-05-05 | Ici Plc | Steam reforming |
| GB8309359D0 (en) * | 1983-04-06 | 1983-05-11 | Ici Plc | Synthesis gas |
| DK165946C (da) * | 1985-03-21 | 1993-07-05 | Haldor Topsoe As | Reformingproces under varmeudveksling og reaktor dertil |
| GB8728882D0 (en) * | 1987-12-10 | 1988-01-27 | Ici Plc | Hydrogen |
| DE68909979D1 (de) * | 1988-03-24 | 1993-11-25 | Ici Plc | Zweistufiges Dampfreformierungsverfahren. |
| JP2607644B2 (ja) * | 1988-10-27 | 1997-05-07 | 三菱重工業株式会社 | メタノール改質方法 |
| GB9000389D0 (en) * | 1990-01-08 | 1990-03-07 | Ici Plc | Steam reforming |
| DK167864B1 (da) * | 1990-02-02 | 1993-12-27 | Topsoe Haldor As | Fremgangsmaade og reaktorsystem til reforming af carbonhydrider under varmeveksling |
| EP0522744B1 (en) * | 1991-07-09 | 1997-08-13 | Imperial Chemical Industries Plc | Synthesis gas production |
| US5429809A (en) * | 1991-09-23 | 1995-07-04 | Haldor Topsoe A/S | Process and reactor for carrying out non-adiabatic catalytic reactions |
| JPH05155602A (ja) * | 1991-12-09 | 1993-06-22 | Sekiyu Sangyo Kasseika Center | 薄型水蒸気改質反応器 |
| JPH05186203A (ja) * | 1992-01-07 | 1993-07-27 | Toshiba Corp | 水蒸気改質用触媒エレメント |
| FR2696168B1 (fr) * | 1992-09-25 | 1994-12-09 | Inst Francais Du Petrole | Procédé et dispositif de fabrication de gaz de synthèse et utilisation associée. |
| JPH06219705A (ja) * | 1993-01-22 | 1994-08-09 | Mitsubishi Electric Corp | 燃料改質装置 |
| MY131526A (en) * | 1993-12-27 | 2007-08-30 | Shell Int Research | A process for the preparation of carbon monoxide and/or hydrogen |
-
1998
- 1998-01-16 DE DE69800734T patent/DE69800734T2/de not_active Expired - Lifetime
- 1998-01-16 EP EP98100669A patent/EP0855366B1/en not_active Expired - Lifetime
- 1998-01-16 AT AT98100669T patent/ATE200884T1/de active
- 1998-01-16 DK DK98100669T patent/DK0855366T3/da active
- 1998-01-16 ES ES98100669T patent/ES2158621T3/es not_active Expired - Lifetime
- 1998-01-17 TW TW087100593A patent/TW482741B/zh not_active IP Right Cessation
- 1998-01-21 NZ NZ329613A patent/NZ329613A/en not_active IP Right Cessation
- 1998-01-21 NO NO19980274A patent/NO318107B1/no not_active IP Right Cessation
- 1998-01-21 JP JP00985598A patent/JP4521735B2/ja not_active Expired - Fee Related
- 1998-01-21 CA CA002227598A patent/CA2227598C/en not_active Expired - Fee Related
- 1998-01-21 AU AU52158/98A patent/AU728728C/en not_active Ceased
- 1998-01-21 RU RU98102132/15A patent/RU2218301C2/ru not_active IP Right Cessation
- 1998-01-21 UA UA98010355A patent/UA61888C2/ru unknown
- 1998-01-22 KR KR1019980001842A patent/KR100547540B1/ko not_active IP Right Cessation
- 1998-01-22 CN CNB981056520A patent/CN1269724C/zh not_active Expired - Fee Related
- 1998-01-22 US US09/010,529 patent/US5932141A/en not_active Expired - Lifetime
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RU98102132A (ru) | Способ и устройство для получения синтез-газа | |
| RU2218301C2 (ru) | Способ и устройство для получения синтез-газа | |
| AU2003248392B2 (en) | Process and apparatus for the preparation of synthesis gas | |
| DE69104735T2 (de) | Dampfreformierungsverfahren mit Wärmeaustausch und Reaktorsystem. | |
| AU2003248394B2 (en) | Process and apparatus for the preparation of synthesis gas | |
| EA199800356A1 (ru) | Способ и технологический блок получения газовой смеси для синтеза аммиака | |
| RU2008102378A (ru) | Компактный риформинг-реактор | |
| WO2000003579A3 (en) | Synthesis gas production by steam reforming using reactors the walls of which are catalytic | |
| US4376717A (en) | Process for the preparation of gases which contain hydrogen and nitrogen | |
| US3743488A (en) | Synthesis gas generation process | |
| CA2326950A1 (en) | Process and reactor for carrying out non-adiabatic catalytic reactions | |
| RU2000118561A (ru) | Способ каталитического реформинга с водяным паром углеводородного сырья | |
| JPS6227033A (ja) | 反応装置 | |
| RU2007136610A (ru) | Способ риформинга для получения синтез-газа и установка для его осуществления | |
| JP2733308B2 (ja) | 水素を主成分とする改質ガスを製造する装置および方法 | |
| GB2087420A (en) | Methanator Employing Finned Heat Pipes |