RU93034459A - Способ превращения оксимов в соответствующие амиды - Google Patents
Способ превращения оксимов в соответствующие амидыInfo
- Publication number
- RU93034459A RU93034459A RU93034459/04A RU93034459A RU93034459A RU 93034459 A RU93034459 A RU 93034459A RU 93034459/04 A RU93034459/04 A RU 93034459/04A RU 93034459 A RU93034459 A RU 93034459A RU 93034459 A RU93034459 A RU 93034459A
- Authority
- RU
- Russia
- Prior art keywords
- oxymes
- transforming
- amides
- relevant
- relates
- Prior art date
Links
- 150000001408 amides Chemical class 0.000 title claims 2
- 230000001131 transforming Effects 0.000 title 1
- 230000000875 corresponding Effects 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 2
- FZENGILVLUJGJX-NSCUHMNNSA-N Acetaldoxime Chemical compound C\C=N\O FZENGILVLUJGJX-NSCUHMNNSA-N 0.000 claims 1
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N Caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims 1
- VEZUQRBDRNJBJY-UHFFFAOYSA-N Cyclohexanone oxime Chemical compound ON=C1CCCCC1 VEZUQRBDRNJBJY-UHFFFAOYSA-N 0.000 claims 1
- SQDFHQJTAWCFIB-UHFFFAOYSA-N N-methylidenehydroxylamine Chemical compound ON=C SQDFHQJTAWCFIB-UHFFFAOYSA-N 0.000 claims 1
- 230000002378 acidificating Effects 0.000 claims 1
- 239000000969 carrier Substances 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 125000006575 electron-withdrawing group Chemical group 0.000 claims 1
- 239000002638 heterogeneous catalyst Substances 0.000 claims 1
- 150000002923 oximes Chemical class 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
Claims (1)
- Изобретение относится к способу превращения кетоксима или альдоксима в соответствующий амид, при котором раствор оксима в растворителе вводят в контакт с гетерогенным, сильно кислым катализатором, причем гетерогенный катализатор представляет собой носитель с сульфированными бензольными кольцами и сульфированные бензольные кольца также содержат электроноакцепторную группу. Изобретение относится в особенности к превращению оксима циклогексанона в соответствующий ε- капролактам.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL9201160A NL9201160A (nl) | 1992-06-30 | 1992-06-30 | Werkwijze voor de omzetting van oximen in de overeenkomstige amides. |
NL9201160 | 1992-06-30 |
Publications (2)
Publication Number | Publication Date |
---|---|
RU93034459A true RU93034459A (ru) | 1996-02-27 |
RU2101278C1 RU2101278C1 (ru) | 1998-01-10 |
Family
ID=19860992
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU93034459A RU2101278C1 (ru) | 1992-06-30 | 1993-06-29 | Способ превращения кетоксима или альдоксима в соответствующий амид |
Country Status (20)
Country | Link |
---|---|
EP (1) | EP0577203B1 (ru) |
JP (1) | JPH07300454A (ru) |
KR (1) | KR100291352B1 (ru) |
CN (1) | CN1036583C (ru) |
AT (1) | ATE148097T1 (ru) |
BR (1) | BR9302701A (ru) |
CZ (1) | CZ287271B6 (ru) |
DE (1) | DE69307608T2 (ru) |
DK (1) | DK0577203T3 (ru) |
ES (1) | ES2097968T3 (ru) |
GE (1) | GEP19971109B (ru) |
GR (1) | GR3023169T3 (ru) |
HU (1) | HU213633B (ru) |
MX (1) | MX9303897A (ru) |
NL (1) | NL9201160A (ru) |
PL (1) | PL173841B1 (ru) |
RU (1) | RU2101278C1 (ru) |
SG (1) | SG48178A1 (ru) |
TW (1) | TW223055B (ru) |
UA (1) | UA43307C2 (ru) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1095461C (zh) * | 1999-04-30 | 2002-12-04 | 中国科学院上海有机化学研究所 | 三氟乙酰基苯乙酮肟及其衍生物的合成方法 |
FR2803197B1 (fr) * | 1999-12-30 | 2002-03-15 | Oreal | Composition pour la teinture d'oxydation des fibres keratiniques comprenant un polymere epaississant comportant au moins une chaine grasse et un alcool gras ayant plus de vingt atomes de carbone |
CN100389107C (zh) * | 2003-06-30 | 2008-05-21 | 中国石油化工股份有限公司 | 一种制备己内酰胺的方法 |
CN1312133C (zh) * | 2004-03-15 | 2007-04-25 | 中国石油化工股份有限公司 | 一种从离子液体中分离贝克曼重排反应产物的方法 |
CN101250148B (zh) * | 2008-03-14 | 2010-08-25 | 湘潭大学 | 一种环己酮肟液相重排制取己内酰胺的方法 |
CN102863385B (zh) * | 2012-10-09 | 2014-01-01 | 清华大学 | 一种由环己酮直接合成己内酰胺的方法 |
CN108080027B (zh) * | 2017-12-23 | 2021-05-28 | 中国天辰工程有限公司 | 一种液相贝克曼重排制己内酰胺的树脂催化剂处理工艺 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH394212A (de) * | 1962-01-13 | 1965-06-30 | Inventa Ag | Verfahren zur Umlagerung cyclischer Oxime |
US3944542A (en) * | 1971-05-15 | 1976-03-16 | Stamicarbon, B.V. | Conversion of ketoximes into lactams in organic sulfoxide solvents |
NL9001545A (nl) * | 1990-07-06 | 1992-02-03 | Stamicarbon | Werkwijze voor het behandelen van amides. |
-
1992
- 1992-06-30 NL NL9201160A patent/NL9201160A/nl not_active Application Discontinuation
-
1993
- 1993-06-08 TW TW082104548A patent/TW223055B/zh active
- 1993-06-11 UA UA93002178A patent/UA43307C2/ru unknown
- 1993-06-21 GE GEAP1993912A patent/GEP19971109B/en unknown
- 1993-06-23 KR KR1019930011444A patent/KR100291352B1/ko not_active IP Right Cessation
- 1993-06-25 ES ES93201841T patent/ES2097968T3/es not_active Expired - Lifetime
- 1993-06-25 SG SG1996007654A patent/SG48178A1/en unknown
- 1993-06-25 DK DK93201841.9T patent/DK0577203T3/da active
- 1993-06-25 EP EP93201841A patent/EP0577203B1/en not_active Expired - Lifetime
- 1993-06-25 DE DE69307608T patent/DE69307608T2/de not_active Expired - Fee Related
- 1993-06-25 AT AT93201841T patent/ATE148097T1/de not_active IP Right Cessation
- 1993-06-28 CZ CZ19931290A patent/CZ287271B6/cs not_active IP Right Cessation
- 1993-06-28 JP JP5156825A patent/JPH07300454A/ja active Pending
- 1993-06-29 BR BR9302701A patent/BR9302701A/pt not_active IP Right Cessation
- 1993-06-29 HU HU9301895A patent/HU213633B/hu not_active IP Right Cessation
- 1993-06-29 CN CN93107880A patent/CN1036583C/zh not_active Expired - Fee Related
- 1993-06-29 RU RU93034459A patent/RU2101278C1/ru active
- 1993-06-29 MX MX9303897A patent/MX9303897A/es not_active IP Right Cessation
- 1993-06-29 PL PL93299511A patent/PL173841B1/pl unknown
-
1997
- 1997-04-18 GR GR970400826T patent/GR3023169T3/el unknown
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