RU2764070C2 - Метастабильный бета-титановый сплав, часовая пружина на основе такого сплава и способ ее изготовления - Google Patents
Метастабильный бета-титановый сплав, часовая пружина на основе такого сплава и способ ее изготовления Download PDFInfo
- Publication number
- RU2764070C2 RU2764070C2 RU2019133673A RU2019133673A RU2764070C2 RU 2764070 C2 RU2764070 C2 RU 2764070C2 RU 2019133673 A RU2019133673 A RU 2019133673A RU 2019133673 A RU2019133673 A RU 2019133673A RU 2764070 C2 RU2764070 C2 RU 2764070C2
- Authority
- RU
- Russia
- Prior art keywords
- alloy
- less
- phase
- metastable
- niobium
- Prior art date
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- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 200
- 239000000956 alloy Substances 0.000 title claims abstract description 200
- 229910001040 Beta-titanium Inorganic materials 0.000 title claims abstract description 31
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 22
- 239000010955 niobium Substances 0.000 claims abstract description 22
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 22
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000001301 oxygen Substances 0.000 claims abstract description 13
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 13
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 13
- 239000010703 silicon Substances 0.000 claims abstract description 13
- 229910052715 tantalum Inorganic materials 0.000 claims abstract description 13
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 238000005482 strain hardening Methods 0.000 claims description 55
- 238000010438 heat treatment Methods 0.000 claims description 31
- 239000002244 precipitate Substances 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 22
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
- 238000000151 deposition Methods 0.000 claims description 13
- 230000008021 deposition Effects 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 238000001556 precipitation Methods 0.000 claims description 12
- 229910002804 graphite Inorganic materials 0.000 claims description 10
- 239000010439 graphite Substances 0.000 claims description 10
- 239000011159 matrix material Substances 0.000 claims description 9
- 230000009467 reduction Effects 0.000 claims description 9
- 229910001566 austenite Inorganic materials 0.000 claims description 8
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 239000011651 chromium Substances 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 239000011733 molybdenum Substances 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 229910052718 tin Inorganic materials 0.000 claims description 6
- 229910052720 vanadium Inorganic materials 0.000 claims description 6
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000011135 tin Substances 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 238000005097 cold rolling Methods 0.000 claims description 2
- 238000005491 wire drawing Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 9
- 230000035945 sensitivity Effects 0.000 abstract description 7
- 238000005272 metallurgy Methods 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 1
- 239000012071 phase Substances 0.000 description 77
- 239000000463 material Substances 0.000 description 38
- 230000015572 biosynthetic process Effects 0.000 description 7
- 230000008859 change Effects 0.000 description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 230000002441 reversible effect Effects 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 230000001050 lubricating effect Effects 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 238000004630 atomic force microscopy Methods 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000002524 electron diffraction data Methods 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 238000005240 physical vapour deposition Methods 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000001771 vacuum deposition Methods 0.000 description 2
- PVWMAOPFDINGAY-UHFFFAOYSA-N 2-(3-methylbutanoyl)indene-1,3-dione Chemical compound C1=CC=C2C(=O)C(C(=O)CC(C)C)C(=O)C2=C1 PVWMAOPFDINGAY-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910001339 C alloy Inorganic materials 0.000 description 1
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- 229910000942 Elinvar Inorganic materials 0.000 description 1
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 description 1
- 229910001075 Nivarox Inorganic materials 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- 238000003917 TEM image Methods 0.000 description 1
- 238000000089 atomic force micrograph Methods 0.000 description 1
- SZMZREIADCOWQA-UHFFFAOYSA-N chromium cobalt nickel Chemical compound [Cr].[Co].[Ni] SZMZREIADCOWQA-UHFFFAOYSA-N 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 230000005489 elastic deformation Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000004627 transmission electron microscopy Methods 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21F—WORKING OR PROCESSING OF METAL WIRE
- B21F3/00—Coiling wire into particular forms
- B21F3/08—Coiling wire into particular forms to flat spiral
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/16—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon
- C22F1/18—High-melting or refractory metals or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/16—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon
- C22F1/18—High-melting or refractory metals or alloys based thereon
- C22F1/183—High-melting or refractory metals or alloys based thereon of titanium or alloys based thereon
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B17/00—Mechanisms for stabilising frequency
- G04B17/04—Oscillators acting by spring tension
- G04B17/06—Oscillators with hairsprings, e.g. balance
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B17/00—Mechanisms for stabilising frequency
- G04B17/04—Oscillators acting by spring tension
- G04B17/06—Oscillators with hairsprings, e.g. balance
- G04B17/066—Manufacture of the spiral spring
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B17/00—Mechanisms for stabilising frequency
- G04B17/32—Component parts or constructional details, e.g. collet, stud, virole or piton
- G04B17/34—Component parts or constructional details, e.g. collet, stud, virole or piton for fastening the hairspring onto the balance
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Springs (AREA)
- Heat Treatment Of Steel (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Silicon Compounds (AREA)
- Heat Treatment Of Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1752503 | 2017-03-24 | ||
| FR1752503A FR3064281B1 (fr) | 2017-03-24 | 2017-03-24 | Alliage de titane beta metastable, ressort d'horlogerie a base d'un tel alliage et son procede de fabrication |
| PCT/EP2018/056440 WO2018172164A1 (fr) | 2017-03-24 | 2018-03-14 | ALLIAGE DE TITANE ß METASTABLE, RESSORT D'HORLOGERIE A BASE D'UN TEL ALLIAGE ET SON PROCEDE DE FABRICATION |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| RU2019133673A RU2019133673A (ru) | 2021-04-26 |
| RU2019133673A3 RU2019133673A3 (https=) | 2021-06-03 |
| RU2764070C2 true RU2764070C2 (ru) | 2022-01-13 |
Family
ID=59325385
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2019133673A RU2764070C2 (ru) | 2017-03-24 | 2018-03-14 | Метастабильный бета-титановый сплав, часовая пружина на основе такого сплава и способ ее изготовления |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US11913106B2 (https=) |
| EP (1) | EP3601628B1 (https=) |
| JP (1) | JP7169336B2 (https=) |
| KR (2) | KR20220156678A (https=) |
| CN (1) | CN110573636B (https=) |
| FR (2) | FR3064281B1 (https=) |
| RU (1) | RU2764070C2 (https=) |
| WO (1) | WO2018172164A1 (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3422116B1 (fr) | 2017-06-26 | 2020-11-04 | Nivarox-FAR S.A. | Ressort spiral d'horlogerie |
| EP3422115B1 (fr) | 2017-06-26 | 2021-08-04 | Nivarox-FAR S.A. | Ressort spiralé d'horlogerie |
| EP3502288B1 (fr) * | 2017-12-21 | 2020-10-14 | Nivarox-FAR S.A. | Procédé de fabrication d'un ressort spiral pour mouvement d'horlogerie |
| EP3502785B1 (fr) * | 2017-12-21 | 2020-08-12 | Nivarox-FAR S.A. | Ressort spiral pour mouvement d'horlogerie et son procédé de fabrication |
| EP3671359B1 (fr) * | 2018-12-21 | 2023-04-26 | Nivarox-FAR S.A. | Procédé de formation d'un ressort spirale d'horlogerie à base titane |
| EP3796101B1 (fr) * | 2019-09-20 | 2025-02-19 | Nivarox-FAR S.A. | Ressort spiral pour mouvement d'horlogerie |
| EP4009114B1 (fr) | 2019-12-31 | 2024-10-16 | Nivarox-FAR S.A. | Ressort spiral pour mouvement d'horlogerie et son procede de fabrication |
| EP4060425B1 (fr) * | 2021-03-16 | 2024-10-16 | Nivarox-FAR S.A. | Spiral pour un mouvement horloger |
| EP4060424B1 (fr) | 2021-03-16 | 2024-11-20 | Nivarox-FAR S.A. | Spiral pour mouvement d'horlogerie |
| EP4123393B1 (fr) * | 2021-07-23 | 2025-04-16 | Nivarox-FAR S.A. | Ressort spiral pour mouvement d'horlogerie |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2095455C1 (ru) * | 1996-07-16 | 1997-11-10 | Научно-производственный центр "ИНОР" | Неферромагнитный инварный сплав и изделие, выполненное из него (их варианты) |
| EA001063B1 (ru) * | 1997-06-20 | 2000-10-30 | Монтр Ролекс С.А. | Самокомпенсирующаяся балансовая пружина для механического осциллятора системы балансовая пружина/баланс хода часового механизма и способ ее изготовления |
| EP1593004A2 (fr) * | 2003-02-06 | 2005-11-09 | ETA SA Manufacture Horlogère Suisse | Spiral de resonateur balancier-spiral et son procede de fabrication |
| RU2485197C1 (ru) * | 2011-10-03 | 2013-06-20 | Федеральное государственное автономное образовательное учреждение высшего профессионального образования "Национальный исследовательский технологический университет "МИСиС" | Металлический наноструктурный сплав на основе титана и способ его обработки |
| WO2015189278A2 (fr) * | 2014-06-11 | 2015-12-17 | Cartier Création Studio Sa | Oscillateur pour un ensemble de balancier-spiral d'une pièce d'horlogerie |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2864107B1 (fr) | 2003-12-22 | 2006-08-04 | Univ Metz | Fil en alliage de titane beta pour orthodontie, et procede d'obtention d'un tel fil. |
| CN100362122C (zh) | 2004-05-17 | 2008-01-16 | 北京有色金属研究总院 | β钛合金及其所制成的产品 |
| US7837812B2 (en) | 2004-05-21 | 2010-11-23 | Ati Properties, Inc. | Metastable beta-titanium alloys and methods of processing the same by direct aging |
| JP4302604B2 (ja) * | 2004-09-27 | 2009-07-29 | 株式会社古河テクノマテリアル | 生体用超弾性チタン合金 |
| CN101760669A (zh) | 2009-12-29 | 2010-06-30 | 沈阳铸造研究所 | 一种低弹性模量的铸造钛合金 |
| FR2982617B1 (fr) | 2011-11-10 | 2014-01-10 | Univ Paul Verlaine Metz | Procede d'elaboration d'un alliage de titane, alliage et prothese ainsi obtenus. |
| JP2013170304A (ja) | 2012-02-22 | 2013-09-02 | Toyota Central R&D Labs Inc | β型チタン合金およびその製造方法 |
| FR3027230B1 (fr) | 2014-10-17 | 2016-11-04 | Univ De Lorraine | Ressort d'orthodontie helicoidal et son procede de fabrication. |
-
2017
- 2017-03-24 FR FR1752503A patent/FR3064281B1/fr active Active
-
2018
- 2018-03-14 WO PCT/EP2018/056440 patent/WO2018172164A1/fr not_active Ceased
- 2018-03-14 RU RU2019133673A patent/RU2764070C2/ru active
- 2018-03-14 EP EP18717524.5A patent/EP3601628B1/fr active Active
- 2018-03-14 CN CN201880020510.1A patent/CN110573636B/zh active Active
- 2018-03-14 US US16/497,327 patent/US11913106B2/en active Active
- 2018-03-14 KR KR1020227040415A patent/KR20220156678A/ko not_active Ceased
- 2018-03-14 JP JP2020501590A patent/JP7169336B2/ja active Active
- 2018-03-14 KR KR1020197030323A patent/KR102488776B1/ko active Active
-
2022
- 2022-08-29 FR FR2208629A patent/FR3126511B1/fr active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2095455C1 (ru) * | 1996-07-16 | 1997-11-10 | Научно-производственный центр "ИНОР" | Неферромагнитный инварный сплав и изделие, выполненное из него (их варианты) |
| EA001063B1 (ru) * | 1997-06-20 | 2000-10-30 | Монтр Ролекс С.А. | Самокомпенсирующаяся балансовая пружина для механического осциллятора системы балансовая пружина/баланс хода часового механизма и способ ее изготовления |
| EP1593004A2 (fr) * | 2003-02-06 | 2005-11-09 | ETA SA Manufacture Horlogère Suisse | Spiral de resonateur balancier-spiral et son procede de fabrication |
| RU2485197C1 (ru) * | 2011-10-03 | 2013-06-20 | Федеральное государственное автономное образовательное учреждение высшего профессионального образования "Национальный исследовательский технологический университет "МИСиС" | Металлический наноструктурный сплав на основе титана и способ его обработки |
| WO2015189278A2 (fr) * | 2014-06-11 | 2015-12-17 | Cartier Création Studio Sa | Oscillateur pour un ensemble de balancier-spiral d'une pièce d'horlogerie |
| WO2015189278A3 (fr) * | 2014-06-11 | 2016-04-07 | Cartier International Ag | Oscillateur pour un ensemble de balancier-spiral d'une pièce d'horlogerie |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3601628B1 (fr) | 2022-05-04 |
| FR3064281B1 (fr) | 2022-11-11 |
| FR3126511B1 (fr) | 2024-03-29 |
| KR20220156678A (ko) | 2022-11-25 |
| KR102488776B1 (ko) | 2023-01-13 |
| CN110573636A (zh) | 2019-12-13 |
| RU2019133673A (ru) | 2021-04-26 |
| US11913106B2 (en) | 2024-02-27 |
| KR20190131517A (ko) | 2019-11-26 |
| FR3126511A1 (fr) | 2023-03-03 |
| JP2020515720A (ja) | 2020-05-28 |
| EP3601628A1 (fr) | 2020-02-05 |
| CN110573636B (zh) | 2022-04-08 |
| US20200308685A1 (en) | 2020-10-01 |
| RU2019133673A3 (https=) | 2021-06-03 |
| JP7169336B2 (ja) | 2022-11-10 |
| WO2018172164A1 (fr) | 2018-09-27 |
| FR3064281A1 (fr) | 2018-09-28 |
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