RU2565035C1 - Multifunctional indicator formulation for complex treatment of objects - Google Patents

Abstract

FIELD: chemistry.

SUBSTANCE: invention represents a multifunctional indicator formulation for complex treatment of objects containing didicyldimethylbenzylammonium chloride, alkyldimethylamine, alkyl benzene sulphonate, glutaric aldehyde, methyl alcohol, non-ionic surfactant OP-7, oxalic acid, sodium hexametaphosphate, dithizone and water; the ingredients of the formulation are taken in certain ratio, wt %.

EFFECT: invention provides the single-step complex deactivation, disinfection of object surfaces and instant detection of dinitrotoluene explosive traces on the surfaces.

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Description

The invention relates to the field of multifunctional compositions for the integrated conduct of decontamination, disinfection and rapid detection of traces of explosives based on dinitrotoluene.

In the complex of anti-epidemic and sanitary-hygienic measures carried out in infectious foci, an important element is the disinfection of surfaces of objects.

In view of the complex nature of possible infection, it is important to develop a multifunctional indicator composition for the simultaneous decontamination and disinfection of the surfaces of infected objects.

In the case of the possible commission of acts of sabotage with the use of explosives, the detection of traces of explosives in the foci of destruction is also relevant.

Known aerosol decontaminating agent containing monohydric alcohol, propellant, alkylbenzenesulfonate, nonionic surfactant, organic acid, complexing agent and water in the following ratio of components, wt.% (Patent for the invention No. 2290208 from 11.16.2004):

alkylbenzenesulfonate or sulfonol 0.5-5 polyphosphate (sodium hexametaphosphate) 0.3-0.5 monohydroxy alcohol 2.0-5.0 nonionic surfactant (OP-7 or OP-10) 0.1-1.5 organic acid 0.5-2.0 anticorrosive substance (sodium hexametaphosphate) 0.5-1.0 complexing agent (dithizone) 0.02-0.04 water 90.0-95.0 propellant (dichlorodifluoromethane) 8.0-85.0

However, this tool is suitable only for decontamination.

Known application for disinfection of surfaces of objects of formulations based on Quaternary ammonium compounds (hereinafter referred to as HOUR). The well-known disinfectant VTS 50 RU manufactured by STEPAN EUROPE France (Stepan Europe, France) (benzalkonium chloride) is an aqueous solution of the main substance - alkyldimethylbenzylammonium chloride - 51% and impurities alkyl (C ₁₂ -C ₁₆ ) dimethylamine - not more than 1%. Using this recipe, you can only disinfect the surfaces of objects.

The disadvantage of the above existing compounds is their monofunctionality, that is, the use only for decontamination (first composition) or disinfection (second composition) of the surfaces of objects.

It is known to use a quaternary ammonium compound such as didecyl methylammonium halide clathrate with carbamide as an active agent providing a complex action, in particular for degassing, disinfection, disinsection, decontamination and shielding, while the composition based on this active substance is used in the form of a foam (patent for invention No. 2290208 of November 16, 2004).

The disadvantage of this composition is the need for subsequent application to the foam layer of another composition effective to inactivate the active substance, and / or application of an antifoam on the foam layer to destroy it.

Previously, the ability of compounds belonging to the HOUR class to be used to detect explosives based on dinitrotoluene was established.

Thus, a formulation containing an alcoholic solution of tetrabutylammonium chloride allows for the rapid detection of these substances on the surfaces of various objects (patent for invention No. 2290208 of November 16, 2004).

The technical result achieved by the present invention is to expand operational capabilities due to the simultaneous disinfection, decontamination of the surfaces of objects and rapid detection on the surfaces of traces of explosives based on dinitrotoluene.

This technical result is achieved by the fact that we propose a multifunctional indicator composition for complex processing of objects, which is a water-alcohol solution of alkylbenzenesulfonate, nonionic surfactant, organic acid, anti-corrosive substance and complexing agent, at the same time provides disinfection, decontamination of surfaces of objects and express detection on the surfaces of traces of dinitrotoluene-based explosives, the following is used other components in their quantitative ratio, wt.%:

didyldimethylbenzylammonium chloride 25.0-30.0 alkyldimethylamine 1,0 alkylbenzenesulfonate 5.5-7.0 glutaraldehyde 1,0 methyl alcohol 2.0-5.0 nonionic surfactant (OP-7) 0.5-1.5 oxalic acid 0.5-2.0 sodium hexametaphosphate 0.5-1.0 dithizon 0.04-0.07 water up to 100%

A multifunctional indicator composition for complex processing of objects, which is a water-alcohol solution of alkylbenzenesulfonate, a nonionic surfactant, an organic acid, an anti-corrosive substance and a complexing agent, in which for the simultaneous disinfection, decontamination of surfaces of objects and rapid detection on the surfaces of traces of explosives on dinitrotoluene base, the following components are used in the ratio, wt.%:

didyldimethylbenzylammonium chloride 25.0-30.0 alkyldimethylamine 1,0 alkylbenzenesulfonate 5.5-7.0 glutaraldehyde 1,0 methyl alcohol 2.0-5.0 nonionic surfactant (OP-7) 0.5-1.5 oxalic acid 0.5-2.0 sodium hexametaphosphate 0.5-1.0 dithizon 0.04-0.07 water up to 100%

In the case of surface treatment with this multifunctional composition, it is decontaminated and disinfected.

In addition, in the presence of traces of dinitrotoluene-based explosives on the surface, characteristic brown spots appear on the surface and remain for several hours.

This multifunctional composition is used in a special aerosol device. The aerosol device is a spray can of various volumes, equipped with a sprayer and filled with a multifunctional formulation. Formulation is sprayed using compressed air pressure generated by a spray pump.

The detection of polynitroaromatic compounds based on dinitrotoluene is based on the reaction that occurs when a substance belonging to the class of quaternary ammonium compounds reacts with a solution of dinitrotoluene, which leads to the appearance of a characteristic brown stain, and the staining that appears remains for a long time (more than 5 days).

The advantages of using this multifunctional composition in an aerosol device over known compositions are as follows:

no need for direct contact of the operator with the analyzed surface;

the multiple use of one package (at least 100 times), which allows you to repeatedly process the surface of the object;

maintaining operability in the temperature range from 0 ° C to plus 50 ° C;

provides a large area of processing and control;

the formulation used is not toxic;

Freon with its ozone-depleting potential is not used;

the aerosol device is made of polymeric materials and is corrosion-resistant and shockproof;

in case of detection of dinitrotoluene, sampling is not required with their subsequent processing and analysis in a specialized laboratory;

convenience and safety in use;

preservation of properties in the presence of possible impurities (oil, fuel, etc.);

allows for processing and rapid detection on vertical, inclined and horizontal surfaces;

the formulation is prepared on the basis of alcohol solutions and is non-toxic, in case of contact with exposed skin, it is enough to wash it off with soap and water;

provides a contrasting and time-stable indicative effect upon detection of dinitrotoluene, which lasts a long time.

Conducted experimental storage showed the stability of the formulation when stored in an aerosol device and the preservation of its performance for at least 2 years.

Experimental studies have shown that the best effect is achieved when using a composition consisting of (wt.%):

didyldimethylbenzylammonium chloride 30,0 alkyldimethylamine 1,0 alkylbenzenesulfonate 7.0 glutaraldehyde 1,0 methyl alcohol 5,0 nonionic surfactant (OP-7 or OP-10) 0.5-1.5 oxalic acid 2.0 sodium hexametaphosphate 1,0 dithizon 0,07 water up to 100

With a lower content of didyldimethylbenzylammonium chloride (25.0%) and alkylbenzenesulfonate (5.5%), the required quality of disinfection, deactivation and visualization of the obtained indicator effect is not ensured, and the use of their higher concentrations is impractical (30.0% and 7.0, respectively) %) due to a further slight increase in the disinfecting effect, an increase in the destructive effect on the processed products and adverse effects on human health.

To carry out disinfection, decontamination and detection of traces of explosives directly on the surface of objects using an aerosol device, the following operations are carried out:

remove the cap from the spray pump, bring the aerosol device at a distance of 10-20 cm from the surface to be monitored, taking into account the direction of the wind;

repeatedly pressing the button or handle of the spray pump, spray the indicator solution on the surface to be examined;

in the case of traces of dinitrotoluene, observe the appearance of an indication effect on the controlled surface. The appearance of a brown color in accordance with the standard indicates the presence on the surface of explosives based on dinitrotoluene compounds. The indication effect persists for a long time (several days).

In cases where the indication effect is not obvious, and also when the surface color coincides with the color of the indication effect, a cotton-gauze disk or a strip of filter paper was wetted with a multifunctional formulation, they wiped the analyzed surface with an area of about 100 cm ² and the appearance of the indication effect on the surface of the filter paper was observed . It is possible to apply the formulation directly to the surface to be examined, followed by wiping it with a cotton-gauze disk.

In order to detect dinitrotoluene under the conditions of the experiment, they were applied onto stainless steel, aluminum, and tile plates and painted with XB-518 paint with an area of 100 cm by irrigation using a 1% alcohol solution of dinitrotoluene. The application of dinitrotoluene solution on the surface was carried out by spraying it using an aerosol device. The dispersion of the aerosol formulation was 100-200 μm. After applying the solution, the surfaces were kept at the test temperature (0 ° C, plus 20 and plus 50 ° C) for at least 0.5 hours.

After 0.5 h, 1 h and 2 h after application of dinitrotoluene solution to the plates, cotton-gauze disks or strips of filter paper from the aerosol device were wetted with a multifunctional formulation. Then, sampling was carried out by rubbing them over the entire treated surface without violating its integrity for 1 min.

On other plates with a solution of dinitrotoluene, as well as on cotton-gauze disks and strips of filter paper obtained after surface treatment, from a distance of 10-20 cm, the proposed multifunctional formulation with a flow rate of 0.3-1.0 l / m was applied from an aerosol device ² .

The appearance of a characteristic indicator effect on cotton gauze disks and filter strips was observed.

In the case of spraying a multifunctional formulation from an aerosol device directly onto the analyzed surface, the appearance of an indication effect on this surface was observed. The time of occurrence of the indicator effect was recorded. The test results are shown in the table.

The results of the tests showed that the multifunctional indicator composition for complex processing of objects in an aerosol device without the use of additional devices and reagents maintains its operability and provides detection of traces of dinitrotoluene compounds on various surfaces in the temperature range from 0 ° C to + 50 ° C 2 hours after surface treatment with dinitrotoluene solution. As a multifunctional formulation, along with the quaternary ammonium compound (BTC 50 RU), a composition based on biguanidines and amines (catamine, catamine AB) was also tested. In all cases, a positive result of detecting traces of dinitrotoluene was obtained.

The time of occurrence of the indicator effect when applying a multifunctional composition to the test surface treated with 1% dinitrotoluene solution is 25-70 seconds, depending on the surface temperature.

Thus, the proposed multifunctional indicator composition provides rapid detection of compounds on the surfaces of objects in a wide range of operating temperatures.

The results of evaluating the bactericidal ability of a multifunctional formulation for the inactivation of microorganisms confirmed the presence of disinfectant properties at an exposure time of 30-120 minutes.

Checking the deactivating properties of the multifunctional formulation confirmed her ability to reduce the power of the exposure dose of gamma radiation.

The aerosol device (hereinafter AC) has a low cost, optimal weight and size characteristics, provides a low specific consumption of indicator formulation, when spraying, the required dispersion and uniformity of the spray torch are achieved. Each aerosol device is labeled by offset printing on self-adhesive white semi-gloss paper that is resistant to aggressive media.

Label contains:

Conditional and full name of the product;

volume of multifunctional recipes;

information about the purpose of the AU and the method of its use;

indication effect upon detection of dinitrotoluene compounds;

production date;

shelf life.

Aerosol devices can be supplied as a kit. This kit is designed for decontamination, disinfection and rapid detection of dinitrotoluene compounds on horizontal, inclined and vertical surfaces. The kit is shown below.

Aerosol device, pcs. 2 including: spray pump one case, pcs. one multifunctional formulation from 0.15 to 1.5 l - label, pcs. one Set of accessories, pcs. one

including:

spray pump one cotton-gauze disk with a diameter of 60 mm, pcs. one hundred operational documentation, set one cardboard packaging, pcs. one

The main characteristics of the kit for decontamination, disinfection and rapid detection of dinitrotoluene compounds are determined:

preparation time for work, no more, min one dinitrotoluene compounds detection time, no more than min four time to save the indicator effect, at least hours one threshold sensitivity, mg / ml 5 · 10 ^-1 operating temperature range, ° C 0 - plus 50 AC weight, kg from 0.15 to 1.5 size of detected drops, not less than, microns 150 frequency of use, not less than, times fifty warranty period of storage, not less than, years 2

Scopes of a set:

decontamination, disinfection and rapid detection of traces of dinitrotoluene compounds by aerosol irrigation of surfaces of objects;

identification of spills (spills), contamination and surface cleanliness of containers used for the transport of explosives based on dinitrotoluene;

quality control of washing surfaces of objects from traces of dinitrotoluene compounds.

The proposed technical solution is industrially applicable, since standard equipment and widespread materials and chemical reagents can be used for its implementation.

Claims (1)

Multifunctional indicator composition for complex processing of objects, which is a water-alcohol solution of alkylbenzenesulfonate, nonionic surfactant, organic acid, anticorrosive substance and complexing agent, characterized in that for simultaneous disinfection, decontamination of surfaces of objects and rapid detection on the surfaces of explosive tracks dinitrotoluene-based substances the following components are used in their quantitative ratio, wt.%:
didyldimethylbenzylammonium chloride 25.0-30.0 alkyldimethylamine 1,0 alkylbenzenesulfonate 5.5-7.0 glutaraldehyde 1,0 methyl alcohol 2.0-5.0 non-ionic surfactant OP-7 0.5-1.5 oxalic acid 0.5-2.0 sodium hexametaphosphate 0.5-1.0 dithizon 0.04-0.07 water up to 100%