RU2507215C2 - Способ получения гибкого пенополиуретана - Google Patents
Способ получения гибкого пенополиуретана Download PDFInfo
- Publication number
- RU2507215C2 RU2507215C2 RU2012118817/04A RU2012118817A RU2507215C2 RU 2507215 C2 RU2507215 C2 RU 2507215C2 RU 2012118817/04 A RU2012118817/04 A RU 2012118817/04A RU 2012118817 A RU2012118817 A RU 2012118817A RU 2507215 C2 RU2507215 C2 RU 2507215C2
- Authority
- RU
- Russia
- Prior art keywords
- water
- foam
- polyol
- isocyanate
- polyisocyanate
- Prior art date
Links
- 229920005830 Polyurethane Foam Polymers 0.000 title claims abstract description 22
- 239000011496 polyurethane foam Substances 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 64
- 230000008635 plant growth Effects 0.000 claims abstract description 10
- 239000001963 growth medium Substances 0.000 claims abstract description 5
- 229920005862 polyol Polymers 0.000 claims description 63
- 150000003077 polyols Chemical class 0.000 claims description 63
- 239000006260 foam Substances 0.000 claims description 58
- 239000000203 mixture Substances 0.000 claims description 42
- 239000005056 polyisocyanate Substances 0.000 claims description 39
- 229920001228 polyisocyanate Polymers 0.000 claims description 39
- 239000012948 isocyanate Substances 0.000 claims description 25
- 150000002513 isocyanates Chemical class 0.000 claims description 25
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 15
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 14
- 125000006353 oxyethylene group Chemical group 0.000 claims description 14
- 238000005187 foaming Methods 0.000 claims description 13
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 12
- 125000005442 diisocyanate group Chemical class 0.000 claims description 8
- 230000002269 spontaneous effect Effects 0.000 claims description 8
- 239000002609 medium Substances 0.000 claims description 6
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 6
- 229920002635 polyurethane Polymers 0.000 claims description 5
- 239000004814 polyurethane Substances 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- 239000004970 Chain extender Substances 0.000 claims description 2
- 239000004971 Cross linker Substances 0.000 claims description 2
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical group OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims description 2
- 239000000546 pharmaceutical excipient Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 239000000126 substance Substances 0.000 abstract description 2
- 230000006835 compression Effects 0.000 abstract 2
- 238000007906 compression Methods 0.000 abstract 2
- 238000005259 measurement Methods 0.000 abstract 2
- 230000000694 effects Effects 0.000 abstract 1
- 239000006261 foam material Substances 0.000 abstract 1
- PGYPOBZJRVSMDS-UHFFFAOYSA-N loperamide hydrochloride Chemical compound Cl.C=1C=CC=CC=1C(C=1C=CC=CC=1)(C(=O)N(C)C)CCN(CC1)CCC1(O)C1=CC=C(Cl)C=C1 PGYPOBZJRVSMDS-UHFFFAOYSA-N 0.000 description 15
- -1 gravel Substances 0.000 description 14
- 125000001261 isocyanato group Chemical group *N=C=O 0.000 description 13
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
- 239000003999 initiator Substances 0.000 description 9
- 238000009472 formulation Methods 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 8
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 6
- 229920000768 polyamine Polymers 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 3
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 3
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229920000265 Polyparaphenylene Polymers 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- VEIOBOXBGYWJIT-UHFFFAOYSA-N cyclohexane;methanol Chemical compound OC.OC.C1CCCCC1 VEIOBOXBGYWJIT-UHFFFAOYSA-N 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 229920006301 statistical copolymer Polymers 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- DDPRYTUJYNYJKV-UHFFFAOYSA-N 1,4-diethylpiperazine Chemical compound CCN1CCN(CC)CC1 DDPRYTUJYNYJKV-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- GTEXIOINCJRBIO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]-n,n-dimethylethanamine Chemical compound CN(C)CCOCCN(C)C GTEXIOINCJRBIO-UHFFFAOYSA-N 0.000 description 1
- YSAANLSYLSUVHB-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]ethanol Chemical compound CN(C)CCOCCO YSAANLSYLSUVHB-UHFFFAOYSA-N 0.000 description 1
- NCUPDIHWMQEDPR-UHFFFAOYSA-N 2-[2-[2-(dimethylamino)ethoxy]ethyl-methylamino]ethanol Chemical compound CN(C)CCOCCN(C)CCO NCUPDIHWMQEDPR-UHFFFAOYSA-N 0.000 description 1
- GVGWZCPKZOZRMX-UHFFFAOYSA-N 3-amino-6-(dimethylamino)-3-[3-(dimethylamino)propyl]hexan-2-ol Chemical compound CN(C)CCCC(N)(C(O)C)CCCN(C)C GVGWZCPKZOZRMX-UHFFFAOYSA-N 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 244000035744 Hura crepitans Species 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920002522 Wood fibre Polymers 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- 229940043276 diisopropanolamine Drugs 0.000 description 1
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- GFMIDCCZJUXASS-UHFFFAOYSA-N hexane-1,1,6-triol Chemical compound OCCCCCC(O)O GFMIDCCZJUXASS-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- XZZXKVYTWCYOQX-UHFFFAOYSA-J octanoate;tin(4+) Chemical compound [Sn+4].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O XZZXKVYTWCYOQX-UHFFFAOYSA-J 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000002025 wood fiber Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/485—Polyethers containing oxyethylene units and other oxyalkylene units containing mixed oxyethylene-oxypropylene or oxyethylene-higher oxyalkylene end groups
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G2/00—Vegetative propagation
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G24/00—Growth substrates; Culture media; Apparatus or methods therefor
- A01G24/30—Growth substrates; Culture media; Apparatus or methods therefor based on or containing synthetic organic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G24/00—Growth substrates; Culture media; Apparatus or methods therefor
- A01G24/40—Growth substrates; Culture media; Apparatus or methods therefor characterised by their structure
- A01G24/48—Growth substrates; Culture media; Apparatus or methods therefor characterised by their structure containing foam or presenting a foam structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G24/00—Growth substrates; Culture media; Apparatus or methods therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0058—≥50 and <150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0075—Foam properties prepared with an isocyanate index of 60 or lower
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Botany (AREA)
- Developmental Biology & Embryology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Cultivation Of Plants (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09172422.9 | 2009-10-07 | ||
| EP09172422 | 2009-10-07 | ||
| PCT/EP2010/063467 WO2011042284A2 (en) | 2009-10-07 | 2010-09-14 | Process for making a flexible polyurethane foam |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2012118817A RU2012118817A (ru) | 2013-11-20 |
| RU2507215C2 true RU2507215C2 (ru) | 2014-02-20 |
Family
ID=41650267
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2012118817/04A RU2507215C2 (ru) | 2009-10-07 | 2010-09-14 | Способ получения гибкого пенополиуретана |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US8809410B2 (enExample) |
| EP (1) | EP2344560B1 (enExample) |
| JP (1) | JP5588011B2 (enExample) |
| KR (1) | KR101746885B1 (enExample) |
| CN (1) | CN102695737B (enExample) |
| AU (1) | AU2010305647B2 (enExample) |
| BR (1) | BR112012006850B1 (enExample) |
| CA (1) | CA2771268C (enExample) |
| DE (1) | DE10751971T8 (enExample) |
| DK (1) | DK2344560T3 (enExample) |
| ES (1) | ES2366628T3 (enExample) |
| IN (1) | IN2012DN01470A (enExample) |
| MX (1) | MX2012003891A (enExample) |
| NZ (1) | NZ598608A (enExample) |
| PL (1) | PL2344560T3 (enExample) |
| RU (1) | RU2507215C2 (enExample) |
| SG (1) | SG178418A1 (enExample) |
| WO (1) | WO2011042284A2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2829440C1 (ru) * | 2019-11-12 | 2024-10-30 | ХАНТСМЭН ИНТЕРНЭШНЛ ЭлЭлСи | Формирование in situ термопластичных полиуретановых эластичных пен низкой плотности |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5902719B2 (ja) * | 2011-02-14 | 2016-04-13 | ダウ グローバル テクノロジーズ エルエルシー | 低密度ポリウレタンフォーム |
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| WO2020190452A1 (en) | 2019-03-15 | 2020-09-24 | Dow Global Technologies Llc | Moduluar water-retaining tiles and green/blue roof structures containing an assembly of such tiles |
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| CN111285992A (zh) * | 2020-03-17 | 2020-06-16 | 浙江工业大学 | 一种采用竹材液化树脂制备发泡栽培基质材料的方法 |
| US20230114154A1 (en) | 2020-04-09 | 2023-04-13 | Dow Global Technologies Llc | Coated sponges |
| EP4486838A1 (en) | 2022-03-03 | 2025-01-08 | Dow Global Technologies LLC | Coated polyurethane foams |
| CN115024189A (zh) * | 2022-05-07 | 2022-09-09 | 大连地拓环境科技有限公司 | 一种多功能立体绿化海绵基质及其制备方法 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3970618A (en) * | 1973-02-01 | 1976-07-20 | Bayer Aktiengesellschaft | Process for the production of polyurethane foams |
| EP0365096A2 (en) * | 1988-10-20 | 1990-04-25 | Shell Internationale Researchmaatschappij B.V. | Method of growing plants |
| WO1996016099A1 (en) * | 1994-11-22 | 1996-05-30 | Imperial Chemical Industries Plc | Process for making flexible foams |
| RU2220156C2 (ru) * | 1998-08-07 | 2003-12-27 | Хантсмэн Интернэшнл Ллс. | Способ получения эластичного пенополиуретана |
| US20050131095A1 (en) * | 2002-08-02 | 2005-06-16 | Jianming Yu | Novel polyols |
| EA007015B1 (ru) * | 2003-01-13 | 2006-06-30 | Роквул Интернэшнл А/С | Способ и устройство для выращивания растений |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE795476A (fr) | 1972-02-17 | 1973-08-16 | Bayer Ag | Procede de preparation de mousses hydrophiles utilisables comme substraits pour la croissance de vegetaux |
| US3889417A (en) | 1972-08-10 | 1975-06-17 | Grace W R & Co | Method for preparing horticultural foam structures |
| US3798836A (en) | 1972-12-04 | 1974-03-26 | Dow Chemical Co | A hydroponic bed for growing plants |
| US4365025A (en) | 1981-12-08 | 1982-12-21 | W. R. Grace & Co. | Flexible polyurethane foams from polymethylene polyphenyl isocyanate containing prepolymers |
| DE3710731A1 (de) | 1987-03-31 | 1989-04-27 | Stankiewicz Alois Dr Gmbh | Polyurethanweichschaumstoff mit schallisolierenden und entdroehnenden eigenschaften |
| DE3721058A1 (de) * | 1987-06-26 | 1989-01-05 | Bayer Ag | Verfahren zur herstellung von kalthaertenden polyurethan-weichformschaumstoffen |
| NZ226008A (en) | 1987-09-21 | 1990-11-27 | Ici Plc | Process for manufacture of polyurethane foams using methylene diphenyl isocyanates and optionally water as blowing agent |
| NZ226009A (en) | 1987-09-21 | 1990-11-27 | Ici Plc | Process for manufacture of polyurethane foams using methylene diphenyl isocyanates with water as blowing agent |
| US5155931A (en) | 1988-10-20 | 1992-10-20 | Shell Internationale Research Maatschappij B.V. | Method of growing plants and growth substrate for use in the method |
| US5114989A (en) * | 1990-11-13 | 1992-05-19 | The Dow Chemical Company | Isocyanate-terminated prepolymer and polyurethane foam prepared therefrom |
| GB9126740D0 (en) | 1991-12-17 | 1992-02-12 | Ici Plc | Polyol compositions |
| US5621016A (en) * | 1992-04-16 | 1997-04-15 | Imperial Chemical Industries Plc | Polyisocyanate compositions and low density flexible polyurethane foams produced therewith |
| US5459170A (en) | 1993-04-13 | 1995-10-17 | Imperial Chemical Industries Plc | Polyurethane foams |
| TW290564B (enExample) * | 1994-06-16 | 1996-11-11 | Ici Plc | |
| US5436277A (en) * | 1994-07-28 | 1995-07-25 | Basf Corporation | Polyisocyanate compositions for the preparation of flexible polyurethane foams |
| US5591779A (en) | 1994-11-22 | 1997-01-07 | Imperial Chemical Industries Plc | Process for making flexible foams |
| US5510053A (en) * | 1994-12-29 | 1996-04-23 | Basf Corporation | Water-blown polyurethane sealing devices and compositions for producing same |
| EP0863929B1 (en) * | 1995-11-30 | 2002-04-24 | Huntsman International Llc | Process for preparing a flexible polyurethane foam |
| BR9807217A (pt) * | 1997-02-11 | 2000-05-23 | Huntsman Ici Chem Llc | Pré-polìmero terminado com isocianato, processo para sua preparação, e, espuma de poliuretano. |
| SK170899A3 (en) * | 1997-06-13 | 2000-06-12 | Huntsman Ici Chemicals Llc The | Isocyanate compositions for blown polyurethane foams |
| DE19823393A1 (de) * | 1998-05-26 | 1999-12-02 | Basf Ag | Isocyanatgruppenhaltige Prepolymere und Verfahren zu ihrer Herstellung |
| BR0107571B1 (pt) * | 2000-02-14 | 2010-10-19 | processo para preparar uma espuma de poliuretano flexìvel, e, espuma de poliuretano flexìvel moldada. | |
| US6479433B1 (en) * | 2000-10-02 | 2002-11-12 | Smithers-Oasis Company | Polyurethane foam composites for grower applications and related methods |
| EP1234843A1 (en) * | 2001-02-26 | 2002-08-28 | Huntsman International Llc | Process for preparing a flexible polyurethane foam |
| EP1456269B1 (en) | 2001-11-29 | 2016-07-20 | Huntsman International Llc | Viscoelastic polyurethanes |
| WO2004014976A1 (en) * | 2002-08-02 | 2004-02-19 | Huntsman International Llc | Prepolymer, polyol composition and process for making a flexible foam |
| WO2004014980A1 (en) * | 2002-08-02 | 2004-02-19 | Huntsman International Llc | Polyols |
| ES2353434T3 (es) * | 2006-03-24 | 2011-03-02 | Huntsman International Llc | Procedimiento para fabricar una espuma de poliuretano. |
-
2010
- 2010-09-14 DE DE10751971T patent/DE10751971T8/de active Active
- 2010-09-14 US US13/500,211 patent/US8809410B2/en active Active
- 2010-09-14 BR BR112012006850-4A patent/BR112012006850B1/pt not_active IP Right Cessation
- 2010-09-14 RU RU2012118817/04A patent/RU2507215C2/ru active
- 2010-09-14 CA CA2771268A patent/CA2771268C/en active Active
- 2010-09-14 SG SG2012010369A patent/SG178418A1/en unknown
- 2010-09-14 IN IN1470DEN2012 patent/IN2012DN01470A/en unknown
- 2010-09-14 MX MX2012003891A patent/MX2012003891A/es active IP Right Grant
- 2010-09-14 EP EP10751971A patent/EP2344560B1/en active Active
- 2010-09-14 DK DK10751971.2T patent/DK2344560T3/da active
- 2010-09-14 ES ES10751971T patent/ES2366628T3/es active Active
- 2010-09-14 PL PL10751971T patent/PL2344560T3/pl unknown
- 2010-09-14 CN CN201080045692.1A patent/CN102695737B/zh active Active
- 2010-09-14 KR KR1020127011628A patent/KR101746885B1/ko active Active
- 2010-09-14 WO PCT/EP2010/063467 patent/WO2011042284A2/en not_active Ceased
- 2010-09-14 NZ NZ598608A patent/NZ598608A/xx not_active IP Right Cessation
- 2010-09-14 JP JP2012532525A patent/JP5588011B2/ja active Active
- 2010-09-14 AU AU2010305647A patent/AU2010305647B2/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3970618A (en) * | 1973-02-01 | 1976-07-20 | Bayer Aktiengesellschaft | Process for the production of polyurethane foams |
| EP0365096A2 (en) * | 1988-10-20 | 1990-04-25 | Shell Internationale Researchmaatschappij B.V. | Method of growing plants |
| WO1996016099A1 (en) * | 1994-11-22 | 1996-05-30 | Imperial Chemical Industries Plc | Process for making flexible foams |
| RU2220156C2 (ru) * | 1998-08-07 | 2003-12-27 | Хантсмэн Интернэшнл Ллс. | Способ получения эластичного пенополиуретана |
| US20050131095A1 (en) * | 2002-08-02 | 2005-06-16 | Jianming Yu | Novel polyols |
| EA007015B1 (ru) * | 2003-01-13 | 2006-06-30 | Роквул Интернэшнл А/С | Способ и устройство для выращивания растений |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2829440C1 (ru) * | 2019-11-12 | 2024-10-30 | ХАНТСМЭН ИНТЕРНЭШНЛ ЭлЭлСи | Формирование in situ термопластичных полиуретановых эластичных пен низкой плотности |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101746885B1 (ko) | 2017-06-14 |
| BR112012006850B1 (pt) | 2019-07-30 |
| MX2012003891A (es) | 2012-05-08 |
| AU2010305647A2 (en) | 2012-03-29 |
| DE10751971T8 (de) | 2013-04-25 |
| WO2011042284A2 (en) | 2011-04-14 |
| KR20120101378A (ko) | 2012-09-13 |
| CN102695737A (zh) | 2012-09-26 |
| WO2011042284A3 (en) | 2011-10-27 |
| JP2013507460A (ja) | 2013-03-04 |
| DE10751971T1 (de) | 2012-12-06 |
| SG178418A1 (en) | 2012-03-29 |
| US20120196946A1 (en) | 2012-08-02 |
| AU2010305647A1 (en) | 2012-03-08 |
| ES2366628T3 (es) | 2013-06-24 |
| US8809410B2 (en) | 2014-08-19 |
| ES2366628T1 (es) | 2011-10-24 |
| CA2771268A1 (en) | 2011-04-14 |
| JP5588011B2 (ja) | 2014-09-10 |
| PL2344560T3 (pl) | 2013-07-31 |
| EP2344560A1 (en) | 2011-07-20 |
| NZ598608A (en) | 2013-04-26 |
| RU2012118817A (ru) | 2013-11-20 |
| CA2771268C (en) | 2013-10-29 |
| EP2344560B1 (en) | 2013-04-03 |
| BR112012006850A2 (pt) | 2016-06-07 |
| AU2010305647B2 (en) | 2013-09-12 |
| DK2344560T3 (da) | 2013-07-08 |
| CN102695737B (zh) | 2014-10-01 |
| IN2012DN01470A (enExample) | 2015-06-05 |
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