RU2487753C2 - Топливная добавка, содержащая наночастицы диоксида церия с измененной структурой - Google Patents
Топливная добавка, содержащая наночастицы диоксида церия с измененной структурой Download PDFInfo
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- RU2487753C2 RU2487753C2 RU2011129305/04A RU2011129305A RU2487753C2 RU 2487753 C2 RU2487753 C2 RU 2487753C2 RU 2011129305/04 A RU2011129305/04 A RU 2011129305/04A RU 2011129305 A RU2011129305 A RU 2011129305A RU 2487753 C2 RU2487753 C2 RU 2487753C2
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- Prior art keywords
- nanoparticles
- cerium dioxide
- cerium
- transition metal
- dioxide nanoparticles
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- 239000002105 nanoparticle Substances 0.000 title claims abstract description 233
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 title claims abstract description 174
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 title claims abstract description 173
- 239000002816 fuel additive Substances 0.000 title description 19
- 238000000034 method Methods 0.000 claims abstract description 89
- 239000003381 stabilizer Substances 0.000 claims abstract description 86
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 74
- 239000000203 mixture Substances 0.000 claims abstract description 73
- 150000003624 transition metals Chemical class 0.000 claims abstract description 73
- 150000002500 ions Chemical class 0.000 claims abstract description 61
- -1 hydroxide ions Chemical class 0.000 claims abstract description 60
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 53
- 239000004094 surface-active agent Substances 0.000 claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 37
- 238000002485 combustion reaction Methods 0.000 claims abstract description 29
- 235000008504 concentrate Nutrition 0.000 claims abstract description 24
- 239000012141 concentrate Substances 0.000 claims abstract description 24
- 239000003054 catalyst Substances 0.000 claims abstract description 23
- 239000007800 oxidant agent Substances 0.000 claims abstract description 23
- 239000011541 reaction mixture Substances 0.000 claims abstract description 22
- 230000003197 catalytic effect Effects 0.000 claims abstract description 20
- 239000007970 homogeneous dispersion Substances 0.000 claims abstract description 20
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 20
- 230000003647 oxidation Effects 0.000 claims abstract description 16
- UNJPQTDTZAKTFK-UHFFFAOYSA-K cerium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Ce+3] UNJPQTDTZAKTFK-UHFFFAOYSA-K 0.000 claims abstract description 15
- 239000003085 diluting agent Substances 0.000 claims abstract description 15
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- 230000000694 effects Effects 0.000 claims abstract description 11
- 238000006722 reduction reaction Methods 0.000 claims abstract description 11
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical group [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims abstract description 10
- 235000020573 organic concentrate Nutrition 0.000 claims abstract description 7
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- 239000000446 fuel Substances 0.000 claims description 54
- 229910052742 iron Inorganic materials 0.000 claims description 32
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 30
- 229910052726 zirconium Inorganic materials 0.000 claims description 27
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 claims description 25
- 238000009826 distribution Methods 0.000 claims description 23
- 229930195733 hydrocarbon Natural products 0.000 claims description 21
- 150000002430 hydrocarbons Chemical class 0.000 claims description 21
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- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 15
- 239000012528 membrane Substances 0.000 claims description 15
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 14
- 239000002283 diesel fuel Substances 0.000 claims description 14
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 13
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 12
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- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 7
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- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 6
- LCTONWCANYUPML-UHFFFAOYSA-N Pyruvic acid Chemical compound CC(=O)C(O)=O LCTONWCANYUPML-UHFFFAOYSA-N 0.000 claims description 6
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 6
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- 239000005642 Oleic acid Substances 0.000 claims description 5
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- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 239000003225 biodiesel Substances 0.000 claims description 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims description 4
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- RMIODHQZRUFFFF-UHFFFAOYSA-N methoxyacetic acid Chemical compound COCC(O)=O RMIODHQZRUFFFF-UHFFFAOYSA-N 0.000 claims description 4
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- 229910052721 tungsten Inorganic materials 0.000 claims description 4
- 229910052720 vanadium Inorganic materials 0.000 claims description 4
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 claims description 3
- 238000011437 continuous method Methods 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
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PCT/US2008/087133 WO2010071641A1 (fr) | 2008-12-17 | 2008-12-17 | Additif pour carburant contenant des nanoparticules de dioxyde de cérium modifié en treillage |
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RU2011129305A RU2011129305A (ru) | 2013-01-27 |
RU2487753C2 true RU2487753C2 (ru) | 2013-07-20 |
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US8980202B2 (en) * | 2010-11-12 | 2015-03-17 | Peter Jerome COWDERY-CORVAN | Cerium containing nanoparticles prepared in non-polar solvent |
CN102559138B (zh) * | 2010-12-23 | 2014-01-08 | 有研稀土新材料股份有限公司 | 一种掺杂氟离子和金属离子的氧化铈基纳米紫外屏蔽材料及其制备方法 |
JP6510403B2 (ja) * | 2012-05-25 | 2019-05-08 | セリオン エンタープライジズ リミテッド ライアビリティ カンパニー | 酸化鉄ナノ粒子分散液及び煤煙燃焼のための燃料添加剤 |
JP6174692B2 (ja) | 2012-06-13 | 2017-08-02 | セリオン エンタープライジズ リミテッド ライアビリティ カンパニー | 酸化ストレスの処置のためのナノセリア |
KR20150067253A (ko) * | 2012-10-08 | 2015-06-17 | 가부시키가이샤 산도쿠 | 복합 산화물의 제조 방법 및 복합 산화물 촉매 |
EP2910300A4 (fr) * | 2012-11-27 | 2016-07-27 | Laminar Co Ltd | Dispositif de réaction pour mélange et procédé de fabrication à l'aide du dispositif de réaction |
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CN103484174B (zh) * | 2013-10-15 | 2015-08-12 | 仁寿县驰骋油业有限公司 | 一种基于国标柴油的新型清洁柴油 |
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BR112017004306B1 (pt) * | 2014-09-18 | 2020-12-15 | Oerlikon Metco (Us) Inc. | Composição pulverizada adaptada para uso em processos de revestimento deespargimento térmico de suspensão |
EP3184206A1 (fr) | 2015-12-23 | 2017-06-28 | Solvay SA | Dispersions de métaux et/ou de composés métalliques |
US9969621B2 (en) * | 2016-05-04 | 2018-05-15 | Saudi Arabian Oil Company | Methods for processing fumed metallic oxides |
JP6780847B2 (ja) * | 2016-09-01 | 2020-11-04 | 国立研究開発法人日本原子力研究開発機構 | ヨウ化水素分解触媒及び水素製造方法 |
CN106930829B (zh) * | 2017-03-06 | 2019-03-05 | 桂林航天工业学院 | 生物乙醇动力系统及其控制方法 |
US10768485B2 (en) * | 2017-07-05 | 2020-09-08 | Nanoco Technologies Ltd. | Quantum dot architectures for color filter applications |
CN107552059B (zh) * | 2017-10-12 | 2020-05-12 | 浙江树人学院 | 一种铁掺杂铈基固溶体烟气脱硝催化剂的制备方法 |
GB2607851A (en) * | 2018-06-15 | 2022-12-21 | Seren Tech Limited | Rare earth metal oxide preparation |
GB201904694D0 (en) * | 2019-04-03 | 2019-05-15 | Johnson Matthey Plc | Ceria-containingmixed oxides for oxygen storage |
KR102372139B1 (ko) * | 2019-05-09 | 2022-03-08 | 단국대학교 천안캠퍼스 산학협력단 | 산화물 나노입자의 전자밴드 엔지니어링을 통한 광학적 물성 제어 |
JPWO2021132628A1 (fr) * | 2019-12-26 | 2021-07-01 | ||
US11603503B2 (en) | 2021-05-20 | 2023-03-14 | Indian Oil Corporation Limited | Additive composition as a combustion improver for liquid and gaseous fuels |
WO2023167287A1 (fr) * | 2022-03-03 | 2023-09-07 | 積水化学工業株式会社 | Réducteur, et procédé de fabrication de gaz |
CN116099354A (zh) * | 2023-02-10 | 2023-05-12 | 昆明理工大学 | 一种球形氧化铈催化剂在低温催化水解有机污染物中的应用 |
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- 2008-12-17 WO PCT/US2008/087133 patent/WO2010071641A1/fr active Application Filing
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- 2008-12-17 CN CN2008801326631A patent/CN102281945A/zh active Pending
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Publication number | Publication date |
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MX2011006461A (es) | 2011-11-18 |
CN102281945A (zh) | 2011-12-14 |
RU2011129305A (ru) | 2013-01-27 |
EP2379221A1 (fr) | 2011-10-26 |
AU2008365234A1 (en) | 2011-07-07 |
JP5438772B2 (ja) | 2014-03-12 |
BRPI0823310B1 (pt) | 2018-02-14 |
KR101605465B1 (ko) | 2016-03-22 |
CA2747547C (fr) | 2017-10-17 |
CA2747547A1 (fr) | 2010-06-24 |
BRPI0823310A8 (pt) | 2015-11-24 |
EP2379221A4 (fr) | 2013-05-15 |
WO2010071641A1 (fr) | 2010-06-24 |
JP2012512127A (ja) | 2012-05-31 |
AU2008365234B2 (en) | 2015-05-07 |
KR20110106884A (ko) | 2011-09-29 |
BRPI0823310A2 (pt) | 2015-06-23 |
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