RU2407762C2 - Водные полиуретан-поликарбамидные дисперсии, способ их получения и их применение - Google Patents
Водные полиуретан-поликарбамидные дисперсии, способ их получения и их применение Download PDFInfo
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- RU2407762C2 RU2407762C2 RU2005138509/04A RU2005138509A RU2407762C2 RU 2407762 C2 RU2407762 C2 RU 2407762C2 RU 2005138509/04 A RU2005138509/04 A RU 2005138509/04A RU 2005138509 A RU2005138509 A RU 2005138509A RU 2407762 C2 RU2407762 C2 RU 2407762C2
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- Russia
- Prior art keywords
- dispersion
- dispersions
- polycarbamide
- polyurethane
- fractions
- Prior art date
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- 239000000853 adhesive Substances 0.000 claims abstract description 5
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- 239000000203 mixture Substances 0.000 abstract description 18
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- 125000003277 amino group Chemical group 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
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- JGFZNNIVVJXRND-UHFFFAOYSA-N N,N-Diisopropylethylamine (DIPEA) Chemical compound CCN(C(C)C)C(C)C JGFZNNIVVJXRND-UHFFFAOYSA-N 0.000 description 5
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 5
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- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
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- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 3
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- SWVGZFQJXVPIKM-UHFFFAOYSA-N n,n-bis(methylamino)propan-1-amine Chemical compound CCCN(NC)NC SWVGZFQJXVPIKM-UHFFFAOYSA-N 0.000 description 1
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- ISRXMEYARGEVIU-UHFFFAOYSA-N n-methyl-n-propan-2-ylpropan-2-amine Chemical compound CC(C)N(C)C(C)C ISRXMEYARGEVIU-UHFFFAOYSA-N 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
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- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
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- 229910052573 porcelain Inorganic materials 0.000 description 1
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- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
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- 229910052708 sodium Inorganic materials 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6633—Compounds of group C08G18/42
- C08G18/6659—Compounds of group C08G18/42 with compounds of group C08G18/34
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0828—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing sulfonate groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
- C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/44—Polycarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
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- Engineering & Computer Science (AREA)
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- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
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| DE102004060139.9 | 2004-12-13 |
Publications (2)
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| RU2005138509A RU2005138509A (ru) | 2007-06-27 |
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| EP (1) | EP1669382A3 (enExample) |
| JP (1) | JP2006199935A (enExample) |
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| NO (1) | NO20055851L (enExample) |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2678012C2 (ru) * | 2014-12-09 | 2019-01-22 | БАСФ Коатингс ГмбХ | Водная дисперсия полиуретан-полимочевины и краска на водной основе, содержащая указанную дисперсию |
Families Citing this family (44)
| Publication number | Priority date | Publication date | Assignee | Title |
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| FR2888243B1 (fr) * | 2005-07-06 | 2007-09-14 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique renforcee de plaquettes d'hydroxyde de magnesium. |
| DE102005040130A1 (de) * | 2005-08-25 | 2007-03-01 | Bayer Materialscience Ag | Polyurethanpolyharnstoff-Dispersionen |
| EP2045278A1 (de) * | 2007-10-05 | 2009-04-08 | Bayer MaterialScience AG | Verfahren zur Herstellung von Polyurethan-Schäumen |
| US8629195B2 (en) | 2006-04-08 | 2014-01-14 | Bayer Materialscience Ag | Production of polyurethane foams |
| DE102006021728A1 (de) * | 2006-05-09 | 2007-11-15 | Bayer Materialscience Ag | Wässrige Dispersionen mit bimodaler Teilchengrößenverteilung |
| JP2010513702A (ja) * | 2006-12-19 | 2010-04-30 | ダウ グローバル テクノロジーズ インコーポレイティド | 高固体含量を有するポリウレタン分散体を含む組成物 |
| EP2015014A1 (de) * | 2007-07-11 | 2009-01-14 | Bayer MaterialScience AG | Verfahren zur Trocknung von Schäumen aus wässrigen PUR-Dispersionen |
| US7452525B1 (en) * | 2007-08-08 | 2008-11-18 | Yuliya Berezkin | Polyurethane dispersions based on polycarbonate polyols and suitable for use in personal care products |
| EP2183293B1 (de) * | 2007-08-28 | 2015-09-09 | Mankiewicz Gebr. & Co. Gmbh & Co Kg | Beschichtungszusammensetzung für die herstellung von flüssigfolien |
| CL2008003124A1 (es) * | 2007-11-07 | 2009-11-27 | Bayer Materialscience Ag | Dispersiones acuosas de poliuretano-urea acuosa de; poliol(es) difuncional (es) o funcionalidad superior, compuestos(s) monofuncional (es) con la menos 50% p/p de óxido de etileno, componente(s)di o poliiocianato; y mezcla de compuestos monoamina primarios y/o secundarios; procedimiento; uso; composición; y compuesto adhesivo. |
| DE102008009192A1 (de) | 2008-02-15 | 2009-08-20 | Bayer Materialscience Ag | Hochflexibles flächiges Verbundmaterial |
| EP2103316A1 (de) * | 2008-03-20 | 2009-09-23 | Bayer MaterialScience AG | Hydrophile Polyurethandispersionen |
| DE102008024299B3 (de) | 2008-05-20 | 2010-04-15 | Adidas International Marketing B.V. | Sporthandschuh |
| DE102008025613A1 (de) * | 2008-05-28 | 2009-12-03 | Bayer Materialscience Ag | Hydrophile Polyurethanbeschichtungen |
| DE102008025614A1 (de) * | 2008-05-28 | 2009-12-03 | Bayer Materialscience Ag | Hydrophile Polyurethanbeschichtungen |
| TWI461453B (zh) * | 2008-05-30 | 2014-11-21 | Bayer Materialscience Llc | 基於聚碳酸酯－多元醇之聚胺基甲酸酯－聚脲分散液 |
| CN102112529B (zh) * | 2008-06-03 | 2014-10-15 | 陶氏环球技术有限责任公司 | 复合分散体、其制备方法、以及由其得到的制品 |
| KR101679871B1 (ko) * | 2008-06-03 | 2016-11-25 | 다우 글로벌 테크놀로지스 엘엘씨 | 감압성 접착제 조성물 및 그의 제조 방법 |
| EP2303942A1 (en) * | 2008-06-03 | 2011-04-06 | Dow Global Technologies Inc. | Heat activated adhesive compositions and method of making the same |
| US20100258371A1 (en) * | 2008-07-01 | 2010-10-14 | Desai Umesh C | Waterborne film-forming compositions having heat reflective properties |
| DE102008031183A1 (de) * | 2008-07-03 | 2010-01-07 | Paul Hartmann Ag | Wundauflage |
| ATE547135T1 (de) | 2008-09-04 | 2012-03-15 | Bayer Materialscience Ag | Tcd-basierte hydrophile polyurethanlösungen |
| EP2177551A1 (de) | 2008-10-15 | 2010-04-21 | Bayer MaterialScience AG | Wässrige Polyurethan-Polyharnstoff-Dispersionen |
| US10233279B2 (en) * | 2009-06-10 | 2019-03-19 | Covestro-Deutschland AG | Poly(THF)-based polyurethane dispersions |
| EP2319876A1 (de) * | 2009-10-16 | 2011-05-11 | Bayer MaterialScience AG | Aromatsiche Polyurethanharnstoffdispersionen |
| EP2377895A1 (de) | 2010-04-14 | 2011-10-19 | Bayer MaterialScience AG | Wässrige Polyurethanpolyharnstoff-Dispersionen |
| WO2012095236A1 (en) | 2011-01-13 | 2012-07-19 | Huntsman International Llc | A process for making polyurea particles |
| WO2013000910A1 (de) * | 2011-06-29 | 2013-01-03 | Bayer Intellectual Property Gmbh | Verbundschaum für wundauflagen |
| KR101245656B1 (ko) * | 2011-08-03 | 2013-03-20 | 한서대학교 산학협력단 | 유기의 보존방법 |
| EP2756020B1 (en) * | 2011-09-13 | 2020-08-19 | Covestro Deutschland AG | Aqueous polyurethane dispersion for waterproof breathable coatings |
| EP2687552A1 (en) | 2012-07-17 | 2014-01-22 | Huntsman International Llc | Use of polyurea nanoparticles as performance modifiers in polyurethane materials |
| US20150284902A1 (en) * | 2012-10-16 | 2015-10-08 | Debkumar Bhattacharjee | Polyurethane dispersion based synthetic leathers having improved embossing characteristics |
| US9499718B2 (en) * | 2013-03-21 | 2016-11-22 | Axalta Coating Systems Ip Co., Llc | Process for the production of an OEM base coat/clear top coat multi-layer coating |
| WO2014208567A1 (ja) * | 2013-06-27 | 2014-12-31 | 旭化成ケミカルズ株式会社 | ポリイソシアネート組成物及びその製造方法、ブロックポリイソシアネート組成物及びその製造方法、樹脂組成物、硬化性樹脂組成物、並びに硬化物 |
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| CN110272530A (zh) * | 2019-05-24 | 2019-09-24 | 合肥科天水性科技有限责任公司 | 一种多粒径羧酸型水性聚氨酯的制备方法及应用 |
| CN112794978A (zh) * | 2021-01-20 | 2021-05-14 | 重庆中科力泰高分子材料股份有限公司 | 一种大粒径水性聚氨酯分散体及其制备方法 |
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- 2005-11-30 EP EP05026058A patent/EP1669382A3/de not_active Withdrawn
- 2005-12-08 MX MXPA05013370A patent/MXPA05013370A/es active IP Right Grant
- 2005-12-08 US US11/298,345 patent/US20060128885A1/en not_active Abandoned
- 2005-12-08 CA CA002529349A patent/CA2529349A1/en not_active Abandoned
- 2005-12-09 NO NO20055851A patent/NO20055851L/no not_active Application Discontinuation
- 2005-12-12 UA UAA200511899A patent/UA87288C2/ru unknown
- 2005-12-12 TW TW094143772A patent/TW200634094A/zh unknown
- 2005-12-12 CN CN2005101316464A patent/CN1800232B/zh not_active Expired - Fee Related
- 2005-12-12 KR KR1020050121878A patent/KR20060066656A/ko not_active Ceased
- 2005-12-12 RU RU2005138509/04A patent/RU2407762C2/ru not_active IP Right Cessation
- 2005-12-13 BR BRPI0505497-4A patent/BRPI0505497A/pt not_active IP Right Cessation
- 2005-12-13 JP JP2005358485A patent/JP2006199935A/ja not_active Withdrawn
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| RU2678012C2 (ru) * | 2014-12-09 | 2019-01-22 | БАСФ Коатингс ГмбХ | Водная дисперсия полиуретан-полимочевины и краска на водной основе, содержащая указанную дисперсию |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2529349A1 (en) | 2006-06-13 |
| EP1669382A2 (de) | 2006-06-14 |
| BRPI0505497A (pt) | 2006-09-12 |
| EP1669382A3 (de) | 2008-04-02 |
| MXPA05013370A (es) | 2006-06-15 |
| DE102004060139A1 (de) | 2006-06-29 |
| TW200634094A (en) | 2006-10-01 |
| NO20055851L (no) | 2006-06-14 |
| RU2005138509A (ru) | 2007-06-27 |
| UA87288C2 (ru) | 2009-07-10 |
| CN1800232A (zh) | 2006-07-12 |
| KR20060066656A (ko) | 2006-06-16 |
| US20060128885A1 (en) | 2006-06-15 |
| CN1800232B (zh) | 2010-05-26 |
| JP2006199935A (ja) | 2006-08-03 |
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| MM4A | The patent is invalid due to non-payment of fees |
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