RU2329217C1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2329217C1
RU2329217C1 RU2006146112/03A RU2006146112A RU2329217C1 RU 2329217 C1 RU2329217 C1 RU 2329217C1 RU 2006146112/03 A RU2006146112/03 A RU 2006146112/03A RU 2006146112 A RU2006146112 A RU 2006146112A RU 2329217 C1 RU2329217 C1 RU 2329217C1
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RU
Russia
Prior art keywords
glaze
cao
pbo
sio
bao
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RU2006146112/03A
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Russian (ru)
Inventor
Юли Алексеевна Щепочкина (RU)
Юлия Алексеевна Щепочкина
Original Assignee
Юлия Алексеевна Щепочкина
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Юлия Алексеевна Щепочкина filed Critical Юлия Алексеевна Щепочкина
Priority to RU2006146112/03A priority Critical patent/RU2329217C1/en
Application granted granted Critical
Publication of RU2329217C1 publication Critical patent/RU2329217C1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/102Glass compositions containing silica with 40% to 90% silica, by weight containing lead
    • C03C3/108Glass compositions containing silica with 40% to 90% silica, by weight containing lead containing boron

Abstract

FIELD: chemistry.
SUBSTANCE: invention pertains to glaze compositions and can be used in making face tiles. The glaze consists of the following components in the given percentage mass ratios: SiO2 40.0-46.0; Al2O3 4.0-6.0; CaO 4.0-6.0; K2O 1.0-2.0; Na2O 1.0-2.0; B2O3 8.0-10.0; PbO 22.0-25.0; ZnO 4.0-6.0; TiO2 4.0-6.0; BaO 1.0-2.0.
EFFECT: increased frost resistance of the glaze.
1 tbl

Description

Изобретение относится к области технологии силикатов, в частности к составам фриттованных глазурей, используемых в производстве облицовочной плитки.The invention relates to the field of technology of silicates, in particular to compositions of fritted glazes used in the manufacture of facing tiles.

Известна глазурь, включающая, мас.%: SiO2 45,57; Al2O3 6,57; CaO 3,79; K2O 1,79; Na2O 7,2; B2O3 15,39; PbO 20,57; Fe2O3 0,08; MgO 0,04 /1/.Known glaze, including, wt.%: SiO 2 45.57; Al 2 O 3 6.57; CaO 3.79; K 2 O 1.79; Na 2 O 7.2; B 2 O 3 15.39; PbO 20.57; Fe 2 O 3 0.08; MgO 0.04 / 1 /.

Известна глазурь, содержащая, мас.%: SiO2 40,25-43,53; Al2O3 10,34-12,98; CaO 0,36-0,39; Fe2O3 0,27-0,29; K2O 1,54-1,95; Na2O 5,65-6,89; B2O3 6,59-7,97; MnO2 4,0-5,0; PbO 20,0-25,0; ZnO 4,0-5,0 /2/.Known glaze containing, in wt.%: SiO 2 40.25-43.53; Al 2 O 3 10.34-12.98; CaO 0.36-0.39; Fe 2 O 3 0.27-0.29; K 2 O 1.54-1.95; Na 2 O, 5.65-6.89; B 2 O 3 6.59-7.97; MnO 2 4.0-5.0; PbO 20.0-25.0; ZnO 4.0-5.0 / 2 /.

Цель изобретения - повышение морозостойкости глазури.The purpose of the invention is to increase frost resistance of glaze.

Цель достигается тем, что в состав глазури дополнительно вводят TiO2 и BaO при следующем соотношении компонентов, мас.%: SiO2 40,0-46,0; Al2O3 4,0-6,0; CaO 4,0-6,0; K2O 1,0-2,0; Na2O 1,0-2,0; B2O3 8,0-10,0; PbO 22,0-25,0; ZnO 4,0-6,0; TiO2 4,0-6,0; BaO 1,0-2,0.The goal is achieved by the fact that TiO 2 and BaO are additionally added to the glaze in the following ratio of components, wt.%: SiO 2 40.0-46.0; Al 2 O 3 4.0-6.0; CaO 4.0-6.0; K 2 O 1.0-2.0; Na 2 O 1.0-2.0; B 2 O 3 8.0-10.0; PbO 22.0-25.0; ZnO 4.0-6.0; TiO 2 4.0-6.0; BaO 1.0-2.0.

В таблице приведены составы глазури.The table shows the glaze compositions.

ТаблицаTable СоставStructure Компоненты, мас.%:Components, wt.%: Морозостойкость, циклыFrost resistance cycles SiO2 SiO 2 Al2O3 Al 2 O 3 CaOCao K2OK 2 O Na2ONa 2 O B2O3 B 2 O 3 PbOPbo ZnOZno TiO2 TiO 2 BaOBao 1one 40,040,0 6,06.0 4,04.0 1,01,0 2,02.0 10,010.0 25,025.0 6,06.0 4,04.0 2,02.0 290±10290 ± 10 22 43,043.0 5,05,0 5,05,0 1,51,5 1,51,5 9,09.0 23,523.5 5,05,0 5,05,0 1,51,5 290±10290 ± 10 33 46,046.0 4,04.0 6,06.0 2,02.0 1,01,0 8,08.0 22,022.0 4,04.0 6,06.0 1,01,0 290±10290 ± 10

Фритту варят при 1300-1350°C, расплав гранулируют. Фритту размалывают с добавкой 0,1% буры, 47,5% воды. Размалывают до остатка не более 0,2% на сетке №0056. Глазурную суспензию наносят на изделия, сушат и обжигают при 950-1000°С.The frit is boiled at 1300-1350 ° C, the melt is granulated. The frit is ground with the addition of 0.1% borax, 47.5% water. Grind to a residue of not more than 0.2% on mesh No. 0056. The glaze suspension is applied to the products, dried and fired at 950-1000 ° C.

Источники информацииInformation sources

1. Орлов Е.И. Глазури, эмали, керамические краски и массы. - М. - Л.: Комиссариат местной промышленности РСФСР, 1938. - С.14.1. Orlov E.I. Glazes, enamels, ceramic paints and masses. - M. - L .: Commissariat of local industry of the RSFSR, 1938. - P. 14.

2. Авторское свидетельство СССР №1039906, С03С 9/00, 1983.2. USSR author's certificate No. 1039906, С03С 9/00, 1983.

Claims (1)

Глазурь, содержащая SiO2, Al2О3, CaO, K2O, Na2O, В2O3, PbO, ZnO, отличающаяся тем, что дополнительно содержит TiO2 и ВаО при следующем соотношении компонентов, мас.%: SiO2 40,0-46,0; Al2О3 4,0-6,0; CaO 4,0-6,0; K2O 1,0-2,0; Na2O 1,0-2,0; В2О3 8,0-10,0; PbO 22,0-25,0; ZnO 4,0-6,0; TiO2 4,0-6,0; ВаО 1,0-2,0.Glaze containing SiO 2 , Al 2 O 3 , CaO, K 2 O, Na 2 O, B 2 O 3 , PbO, ZnO, characterized in that it additionally contains TiO 2 and BaO in the following ratio, wt.%: SiO 2 40.0-46.0; Al 2 O 3 4.0-6.0; CaO 4.0-6.0; K 2 O 1.0-2.0; Na 2 O 1.0-2.0; B 2 O 3 8.0-10.0; PbO 22.0-25.0; ZnO 4.0-6.0; TiO 2 4.0-6.0; BaO 1.0-2.0.
RU2006146112/03A 2006-12-25 2006-12-25 Glaze RU2329217C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2006146112/03A RU2329217C1 (en) 2006-12-25 2006-12-25 Glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2006146112/03A RU2329217C1 (en) 2006-12-25 2006-12-25 Glaze

Publications (1)

Publication Number Publication Date
RU2329217C1 true RU2329217C1 (en) 2008-07-20

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU2006146112/03A RU2329217C1 (en) 2006-12-25 2006-12-25 Glaze

Country Status (1)

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RU (1) RU2329217C1 (en)

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
W0 99/57072 A1, 11.11.1999. *

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